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By V. Caps

Gold has been often used as an alloying component in order to increase or modify the catalytic properties of an active metal. For example, in the hydroconversion of methylcyclopentane, Riahi et al [1] shown that the addition of gold to palladium or platinum enhances the activity which becomes greater than that of the pure metals whereas the selectivity towards products resulting from ring expansion increases. Molenbroek et al [2] presented a detailed study on Ni-Au catalysts which exhibit activity for steam reforming and have been proved to be more resistant toward carbon formation than the pure Ni catalysts. Blocking of highly reactive Ni edge and kink sites by Au atoms is assumed to be the reason for the increased robustness of the Ni-Au catalyst. Nevertheless, the own catalytic properties of pure gold have been almost ignored up to the pioneering work of Haruta et al [3] which demonstrates the high activity of gold for CO oxidation at low temperatures. Other reactions such as WGS reaction, propylene epoxidation or benzene total oxidation have then been shown to be catalyzed by gold [4]. This discovery induced the publication of papers devoted to analyze the different factors controlling the activity of gold catalysts. Among them the most relevant appears to be the gold particle size, the nature of the support [5] and the preparation methods [6]. Clearly distinguish between support and size effect is not straightforward. Indeed, the calcination step often needed to synthesize supported catalysts on different supports, leads to different particle sizes showing that particle size and support are interdependent. To circumvent this difficulty, Au-based supported catalysts have been synthesized by using laser vaporization and low energy cluster beam deposition. The as prepared catalysts have then been characterized and tested in CO oxidation reaction.

Oct 1, 2003

By Stephen Hardcastle

Personnel Heat Exposure Issues In Canada?s Deep Mechanized Mines ?Project developed in 2004 ?Base/precious metal industry identified heat stress/management as a major challenge affecting productivity and operating costs ?Project started in 2005 ?Current research nearing completion ?Guidelines, further data analysis and ?Communicating the Science? will continue into 2011

Oct 1, 2010

By Didier Fohlen

Three Policy Shifts to enhance IFC?s Accountability ? Comprehensive and dynamic treatment of social, health, safety and environmental risks ?Covers a range of risks encountered by clients in emerging markets ?Framework to anticipate risks and to address them as they arise ?Includes community development, biodiversity, human rights ... ? Effective principles to guide an outcomes-based approach ?By clients and IFC ?Focus on broad community support and value-added sustainable development initiatives Enhanced governance, transparency and disclosure

May 1, 2006

By William M. Luff

"The Bathurst area has recorded mining production as early as 1837, although the bulk of the production has come in recent years. Production has been mainly from the well-known massive sulphide deposits, but vein, gossan, and a variety of other deposits have also been mined. This paper summarizes the history of the mined deposits, along with tonnages and grades produced.A number of ""firsts"" have been noted in the Bathurst area. The A Zone deposit, located in the Heath Steele area, was the first in the world discovered using airborne electromagnetic methods. Heap leaching of gold from the gossan zone at Caribou was the first operation of its kind in Canada. The Keymet mine was the first base metal (lead-zinc) mine in New Brunswick. For the past few years, the Brunswick No. 12 mine has been one of the largest zinc mines in the world.IntroductionThe Bathurst area (Fig. I) first had mining production in 1837 when copper was mined from a deposit on the Nepisiquit river (MacKenzie, 1958). The majority of the production, however, has been in recent years from massive sulphide deposits, but there are also other significant operations.Table I is a summary of Bathurst area mineral production, showing concentrator feed tonnages and mill feed grades. The table does not include peat deposits, sand and gravel, dimension stone or rock quarries. Figure I is a general geology map of the Bathurst area, indicating deposit locations. The deposits are divided into four categories: massive sulphide, vein, gossan and other. The deposits in each category are described in chronological order of exploitation."

Jan 1, 1995

By K. Ohto, B. B. Acihikari, H. Kawakita, M. Gurung, S. Alam

Two kinds of adsorbents were prepared from persimmon tannin extract to investigate their adsorption behavior of metal ions from hydrochloric acid solution; one was prepared by treating with concentrated sulfuric acid while another was prepared by immobilizing functional groups of quaternary amine. The former adsorbed only gold(III) and its maximum adsorption capacities was evaluated as high as 1510 g/kg while the latter adsorbed not only gold(III) but also palladium(II) and platinum(IV), the maximum adsorption capacities of which were evaluated as 820, 89 and 101 g/kg, respectively. For both adsorbents, practical adsorption of base metals was not observed.

Jan 1, 2011

By MacKenzie Dickson

"INTRODUCTIONGold is found in many natural states, native nuggets, loose grain in river sands, veins in rock, as well as associated with sulphides, oxides, etc., disseminated more or less minutely.Its high value in recent years has spawned new technologies to win values from sources once considered too lean for commercial recovery. Cyanide leaching from fine milled ore or tailings, from upstream recovery operations, coupled with adsorption onto relatively coarse granules of activated carbon, concentrate the gold enough to be converted to bullion by time-honoured methods.The carbon granules are fragile. Size degradation in handling must be minimized not only to prevent loss of gold on fine fragments of carbon that could pass with the barren tailings, but to maintain adsorption efficiency. Besides, the granulated carbon itself is costly. Circular Vibroscreens are winning acceptance for dewatering carbon granules thanks to their gentle yet effective performance in gold recovery systems around the world. The system at Equity Silver is illustrative.BackgroundEquity Silver Mines Ltd., Houston, British Columbia, first began production in September 1980. In 1984, a feasibility study showed that additional gold and silver could be economically recovered through cyanide leaching of the flotation tailing.Although the carbon-in-pulp (ClP) or carbon-in-leach (CIL) process is commonly used for extracting precious metals from slurries, the use of circular vibrating screens, and Vibroscreens in particular, for the carbon circuit is an innovation that cuts costs.Rectangular vibrating screens have been the conventional separation mechanism of choice across North America. In contrast, the use of Vibroscreens has been proven to be less costly for the initial purchase and installation. Also, these circular vibrating screens require less power and less space. A description of Equity Silver Mines' process shows how these screens have been successfully integrated into the system."

Jan 1, 1989

Superconductivity, New Mexico and Mining? ? High Temperature Superconducting cables made from ?nickel tape? ? Testing on U.S. power grid ? 25 year time horizon Purpose Create awareness about the successful application of energy management systems at a Northern Ontario mine site.

May 1, 2008

By William H. Pomroy, Kenneth E. Hjelmstad

An underground mine fire can seriously threaten the lives of all personnel in the mine. This fact makes fire emergency planning a high priority in the mining industry. A fire emergency plan includes a means of warning miners of the existence of a fire, and the need to evacuate or retreat to a place of refuge. The warning alarm must be fast and must reach all miners, regardless of their location or work activity. Means of fire warning are varied, and include such methods as stench, flashing lights, telephones, and word-of-mouth (messengers). Unfortunately, none of these methods are entirely satisfactory. Stench can be slow and seldom achieves total mine coverage, especially in high-back room-and-pillar mines with low ventilation velocity. Telephones are effective only where personnel are close enough to hear the phone ring. A novel fire warning alarm system has been developed by the U.S. Bureau of Mines which enables instantaneous warning of all underground personnel. The warning alarm is sent by an electromagnetic signal which penetrates through mine rock from a transmitter to small person-wearable receivers. Each miner's cap lamp battery could be equipped with a small receiver and when a fire or other emergency occurs the miner could be alerted to the danger by a blinking of the cap lamp. Testing of prototype equipment has demonstrated that the transmitted signal is capable of penetrating through over a mile of mine rock and activating the receiver. This paper describes the theoretical basis for through-the-rock ultra-low frequency electromagnetic transmission, design of the prototype transmitter and receiver, test results, and status of commercial development of systems utilizing this technology.

Jan 1, 1994

By J. Stiksma, R. Kalanchey, M. J. Collins, G. Owusu, R. Raudsepp, K. R. Buban, L. A. Barta, L. Masters

This paper describes the results of testwork for the treatment of Ambatovy laterite by an acid pressure leach process, with recovery of the soluble nickel and cobalt values as mixed sulphide intermediate by precipitation with hydrogen sulphide, and subsequent refining of the mixed sulphide to nickel and cobalt metals. These process development studies were carried out primarily in 2004, as part of a bankable feasibility study for the Ambatovy Nickel Project.

Jan 1, 2004

By R. M. T. Raja Ismail

Shipping and stevedoring industry is going to witness a massive increase in the amount of containers to be handled while land constraints become more critical. Offshore transfer operations hence offer a preferable solution to deal with the surge in cargos rather than to expand the port outwards. Recently, there has been increasing research interests on offshore crane automation. Suspended cargos in a ship-mounted crane system are caused to swing due to the vibratory motion of the ship induced by ocean waves, which can lead to collision between cargos and deck. Therefore, it is vital for offshore crane systems to satisfy rigorous requirements in terms of safety and efficiency. This paper presents the modelling and control development for offshore boom crane systems. A second-order sliding mode control law is proposed for trajectory tracking and sway suppression control, making use of its capability of actuator chattering alleviation while achieving high tracking performance and preserving strong robustness. The asymptotic stability of the closed-loop system is guaranteed in the Lyapunov sense. Simulation results indicate that the proposed controller can significantly reduce the effect of disturbances coming from gusty waves and other dynamic loadings.

Aug 1, 2013

The original JKMRC AG/SAG mill model was developed over 30 years ago and has been upgraded a number of times since then, with the current published version being the Variable Rates model that is now over 15 years old. Since this model was developed further enhancements have been derived, some of which are applied in-house and some which have yet to be incorporated. The published and the commercially available model in JKSimMet is currently undergoing a comprehensive overhaul with a vastly extended data base for model evolution and validation. Improvements developed within the AMIRA P9 project, in-house development and a number of collaborative projects, are being incorporated into the upgraded model structure. Enhanced capabilities will include: power-based breakage rates scaling; a far wider mill filling range (from 10% to 40%) that exhibits peak in throughput as mill filling increases; higher ball loads; improved pebble discharge function; improved slurry discharge function incorporating important mill design and operational influences; and the new size dependent breakage function. The model will also be able to accommodate some influence of liner design and multi-component ores (blends of hard and soft components). This upgrade is still a work in progress but substantial changes have been made to date. This paper presents some of the new improvements and their influence on the predictive capability of the model.

Jan 1, 2012

By N. Fukatsu

The recent development of galvanic cell-type hydrogen sensor for molten copper was outlined. The principle of the sensing mechanism, the fundamental structure of the sensor, and its performance as a process control device are discussed based on experimental work undertaken by the authors. Besides sensors based on usual perovskite-type proton conducting oxide, those using magnesium-doped alpha alumina, which was recently known as a proton conductor, were investigated and the results at the laboratory scale are reported. Considering the excellent sensitivity at high temperature and the stability to the disturbance from the attendant oxygen activity, magnesium-doped alpha alumina was regarded to be a superior material for the sensors used for such purposes.

Jan 1, 2007

By C. Caballero, M. Rosales, C. León, A. Valencia, R. Fuentes, A. Moyano

Slopping is the formation of waves in the converter due to the gas injection by tuyeres. Those waves produce a premature wearing of the refractory lining of the reactor due to its great amplitude. The affected zones are the tuyere line (outlet gas from tuyeres) and the front of this line. In the present work, a theoretical and experimental study is made to develop a theory that determines the variables involved in slopping, characterizing the more important parameters of operation in the phenomenon of slopping. In addition, this theory will allow for determination of new technological alternatives of the blast injection permitting to depress the slopping phenomenon.

Jan 1, 2007

By R. Minto, W. G. Davenport

The slag removed from the reverberatory furnaces of copper smelters contains significant copper values. A serious financial loss is involved, as further recovery operations are not normally carried out. This paper describes the factors affecting physical transport of matte into slag by gas bubbles, and the subsequent entrapment and flotation of matte drops. Three distinct patterns of transport behaviour have been identified from studies of a number of liquid/liquid systems, including liquid metal and liquid matte systems. A theoretical approach is proposed to explain these behaviour patterns, and to predict transport and entrapment behaviour in matte/slag systems. The concepts of "Film Coefficient" (ø) and "Flotation Coefficient" (?) are introduced. The effects of smelting process variables on the physical loss of copper matte in slag are also discussed.

Jan 1, 1972

By K. T. Aye

An investigation into the leaching of chalcocite and covellite in cyanide solutions at concentrations typically encountered daring gold cyanidation has been conducted. The results indicate that, for both minerals, the extent of leaching is greater under anoxic conditions, but is still incomplete even in the presence of free cyanide ions, with undissolved copper solids remaining in equilibrium with solution species. The speciation of the sulfur and cyanide reaction products in solution are interpreted in terms of the fast formation of a copper(I)- cyanide complexes in solution and a sulfur-rich copper(I) polysulfide solid phase, which then reacts more slowly to produce thiocyanate ions.

Jan 1, 2011

By F. Fournier Dit Chabert, F. Tancret, J. François Castagné, R. Le Gall

During the repair of turbine blades by a laser cladding process, it is observed that interdendritic cracking occurs in the heat affected zone (HAZ). Auger electron spectroscopy, performed on sample broken at high temperature, reveals interfacial sulfur segregation, which is known to be one of the main causes of microcraking in the HAZ during welding processes. Moreover, thermal gradients generated by the process are responsible for important thermomechanical stresses. In the present work, the finite element code Comsol Multiphysics is used to simulate the laser cladding process in order to determine both the thermal field and, using an elastoplastic law, the stress field inside the component. The originality is that the temperature history calculated in the thermomechanical model is extracted then injected in a segregation model in order to calculate the local segregation behavior. This model can be eventually used to predict the risk of cracking as a function of process parameters and alloy chemistry.

Jan 1, 2006

By Brian Hall

For some years, the mining industry has been consistently delivering returns below the market average. One of the causes is a disconnect between what is perceived to drive value creation by many industry analysts and senior corporate executives, and what actually drives the intrinsic value of mining operations. The perverse effect is that strategies that should increase value are perceived to have the potential to drive share prices down, and vice versa. This paper challenges common perceptions of what drives a mining company?s value. Anecdotal evidence suggests that the key drivers of value in the market, and hence in many boardrooms, are such things as increasing the reserves and production rate, and reducing unit operating cost. However, while the quoted reserves may satisfy ore reserves reporting code requirements to be economic, this does not imply that they are optimal. Often, a proportion of the quoted reserve reduces the potential value of the operation. Metal price increases, increased production rates, and operating cost reductions are all seen as conditions or actions that can improve value, and lead to cutoff grade reductions, thereby increasing ore reserves. However, modern cutoff theory and studies conducted by the author and his colleagues show clearly that, while breakeven cutoff grades will fall in these circumstances, optimum cutoffs may be much less volatile, and may even increase. Results from case studies indicate that value is maximised by right-sizing, not maximising, the production capacities, and by optimising the cutoff strategy. Values of many existing underground mining operations can be increased significantly by a substantial cutoff grade increase. Also, an increase in downside risk, and hence reduced returns, can occur using typical life-of-mine planning strategies if prices received are lower than predicted. Since this is often the case, low industry returns may be a direct result of typical strategic mine planning processes. Relatively simple cost-effective techniques are available to provide senior decision makers with information needed to assess the tradeoffs between their many conflicting corporate goals, and the balance between risk and reward. Often this information is not being generated at all. If it is, decisions affecting the value of the company are occurring by default at relatively low levels within the hierarchy, with senior executives apparently unaware of them or their potential impact. The paper concludes that without a re-evaluation of the way mining projects are valued, to demand proven value optimisation from mining plans by boards and mining analysts, the industry will continue to deliver below average returns.

May 1, 2003

By R. D. Brown

"AbstractOver the past five years, tax rates in the Canadian mining industry have skyrocketed upward across Canada, as both federal and provincial governments have sought to increase their share of mining revenues.However, the past few years have not only brought high tax rates to the industry, but also a number of important new federal and provincial tax incentives.In large part, these incentives ~ special credits or reduction in tax for carrying out specific exploration, processing or other activities - have helped to moderate the adverse effects of the higher tax rates and have provided inducements for exploration and processing activities which might not otherwise have been undertaken.However, the effectiveness of certain of these incentives can be questioned: our over-all tax structure now consists in large part of punitively high marginal rates with some extraordinarily generous but capricious tax reductions for specific activities and may not be in the best long-term interest of either the industry or the nation.A rational tax structure, with moderate and stable tax rates, together with reasonable incentives confined to activities specifically requiring them, could be a more effective spur to investment than the present tax and incentive jungleIntroductionIN THE YEARS since federal tax reform, the mining industry in Canada has faced a continued escalation in its tax burdens as federal and provincial governments have leapfrogged each other in imposing new and higher taxes on the industry. The result has been that marginal tax rates imposed on mining and processing activities throughout Canada have jumped to hitherto unparalleled levels."

Jan 1, 1977

By Malcolm Scobie

"This paper reviews the evolution of Canadian surface and underground mining automation, principally relating to: advances in communications, initial development of machine teleoperation from line-of-sight remote control, and islands of automation. The eventual role of teleroboties and minewide robotic mining remains to be resolved. The progress and approaches adopted have tended to vary within each sector of the mining industry. Recent information technology advances have made possible the Digital Mine; in which information associated with all mining processes, however dispersed, would be integrated with support systems using new communications technology. The Digital Mine will provide the information infrastructure to serve as the foundation for minewide automation. This paper concludes by reviewing the issues likely to govern implementation success, relating to: mining process design, machine design, machine intelligence, and mine planning and control.IntroductionSignificant advances have recently been made in underground hardrock mine communications and teleoperation. Subsequent R&D efforts are mainly focussing on control systems for various types of machines. In underground potash mining, the realization of automated continuous mining systems appears to be imminent. Recent advances in surface mine dispatching, machine monitoring and global positioning systems (GPS) have tended to reactivate some of the initial R&D enthusiasm developed in the '70s for surface mine automation. Mines at large are approaching a major milestone: the implementation of comprehensive communications infrastructure which proves to be sufficiently reliable and economical to support the automation of routine mine production, either using teleoperated or autonomous machines. This then should motivate a deeper commitment to real time monitoring and management. The communications advances make possible the Digital Mine; in which information associated with all mining processes, however dispersed, would be integrated with support systems using information engineering. The Digital Mine will provide the information infrastructure to serve as the likely foundation for a wide range of automation scenarios. This paper surveys the status and directions of automation development in both surface and underground Canadian mines, pointing to what are seen to represent key technology development issues."

Jan 1, 1995

By I Wilkomirsky, F. Parada, R. Parra, E. Balladares

"The neutral roasting of As bearing copper concentrates is confirmed well established and promising option for the treatment of this type of complex concentrate. The AS elimination by volatilization allows subsequent treatment of the calcines produced in a conventional pyrometallurgical process, by blending this product with standard concentrates.Several tests were performed using the fluidized bed pilot plant at the University of Concepción with different types of concentrates. Calcines, fines from two hot cyclones and flue dust from the ESP were collected. These materials were characterized using QEMSCAN® and the results used for the development of a mass and energy balance which took into consideration the specific chemical transformations that occurred in the reactor.A physico-chemical/kinetic model is proposed to explain the formation of bornite, chalcopyrite and magnetite. The mechanism involves solid-gas reactions between chalcocite, pyrrhotite and gaseous sulfur that without the mineralogical characterization would not have been possible to propose"

Jan 1, 2014