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By Filip Rochette, Yvan De Busscher

Extraction of minerals can be achieved by a variety of technologies; one of them is ion exchange. There are several ion exchange configurations and mechanical set-ups available, but only one technology will provide more process performance and flexibility compared to the other. The multiple column Continuous Countercurrent Ion Exchange (CCIX) technology provides the highest form of process flexibility with also the highest mineral recovery feasible through ion exchange. In comparison with a fixed bed system, the PuriTech CCIX system offers the benefits of continuous counter-current contact mode. This way the resin capacity is fully exploited leading to reduction in resin inventory and, at the same time, in chemicals and water consumption, and product dilution. For any set of operating conditions the mass transfer zone has a characteristic length (MTZL). The MTZL can be expressed in duration, column length, or volume, but is the measure of the quantity of resin in the system that is doing "work" at any given moment in the process. The objective of continuous ion exchange processing is to eliminate all resin volume from the process equipment that is not within a mass transfer zone. In most commercial ion exchange processes for the recovery of metals, CCIX engineering can eliminate as much as 20 - 80 % of the ion exchange resin inventory. Consumptions of water and chemicals are typically brought down around 40% or more. For each type of resin the selectivity/affinity towards a particular metal depends on the basic process conditions such as pH, concentrations of other competing metals in solution. By changing the pH in the ion exchange process phase, the selectivity of the resin can be changed. By doing this, a split elution, or extraction of metals separately can be achieved and the effect of other competing metals (cross-contamination) can be reduced. For example the DOW resin XUS43578 is commonly used for the recovery of copper or nickel/cobalt separation.

Jan 1, 2016

By R. Dahlke, J. A. Finch

"A campaign was undertaken during the greater part of 2001 at Noranda’s Brunswick Mine Concentrator to investigate the role of gas (air) superficial rate distribution (Jg profile) to the cells in the final Zn cleaning stage (bank of seven cells). Three profiles were tested: Balanced (each cell with same Jg), Increasing (from cell 1 to 7), and Decreasing, along with an “as found” profile in a parallel control bank. The experimental design allowed for two confounding factors, changes in ore type and circulating load. The Increasing profile consistently gave the best metallurgy (down-the-bank grade / recovery). The reason for improved performance was traced to the response of the first few cells. The Increasing profile gave the highest selectivity of sphalerite against non-sulphide gangue (NSG) in these cells with relatively even recovery per cell down the bank (10-15% based on feed to each cell). The other profiles gave lower selectivity and higher zinc recovery in the first cells (up to 25% in cell 1), which combined to reduce overall bank performance. The increased selectivity with the Increasing profile is attributed to the low gas rate in the first cells reducing water recovery and hence limiting entrainment of NSG gangue. The Increasing profile was subsequently configured for all four stages in the zinc cleaner circuit.INTRODUCTIONThe performance of a flotation circuit is largely the result of the operator’s response to visual clues. This includes manipulation of the gas (air) input and how it is distributed to cells in a bank. A lack of sensors prescribes this approach. Over the past ten years the Mineral Processing Group at McGill University have developed a set of gas dispersion sensors including one to measure gas superficial rate (or simply “gas rate”), i.e., volumetric gas rate per unit cell crosssectional area, Jg (Gomez and Finch, 2002). The device collects bubbles in a tube immersed in the pulp and infers Jg from the pressure-time curve generated after a valve is closed and air starts to accumulate. The usual units are cm/s. It is robust, reliable and suited for plant use.A version of the Jg sensor was tested extensively during 2000 at Noranda’s Brunswick Mine Concentrator (Dahlke et al., 2001). The results were sufficiently encouraging that a sensor was fabricated to suit local requirements (Insta-Jg). The sensor detected malfunctioning field instruments and flotation mechanisms, and demonstrated that gas distribution to cells in a bank “as found” had no particular pattern, or profile. Preliminary testing suggested that a balanced profile (i.e., all cells with the same gas rate) gave superior metallurgy (grade / recovery down the bank) than the “as found” profile. This observation prompted a focused campaign to explore the impact of the gas rate (Jg) profile, introducing the notion of “gas distribution management”."

Jan 1, 2004

By J. A. López-Molina, S. García, V. Castellanos-Pedroza

"Groundwater inflow into underground constructions may cause hazardous working conditions and environmental problems. It is essential to localize and characterize potential flow paths and to estimate the amount of water leakages, so that appropriate sealing works can be performed. Estimating the amount of water ingress is a multi-phase process starting from qualitative and quantitative examination of rock mass. Due to association of uncertainty, vagueness and incompleteness with the monitored data set, particularly resulted from the in situ tests, accounting relevant approaches such Fuzzy Logic and Recurrent Neural Networks, are proposed in this research for learning acquisition, extraction of rules and prediction of behaviors. The computational set of artificial tools permits using the complex information entities or information granules (rock types, geologic structures, hydro-fracture potential) for data abstraction and derivation of knowledge from records (numerical or linguistic format). This is more a theoretical perspective than a set of methods or principles. As a theoretical perspective, this proposal encourages an approach to data that recognizes and exploits the information present in indexes at various levels of resolution or scales. In this sense, it encompasses the methods which provide flexibility and adaptability in the resolution at which knowledge or information is extracted and represented. The product of merging these tools is a 3D artificial-mapping of rock classification (Qi-system), geological conditions and Lugeon units that permits, as far as possible, to understand more and better the flow behavior."

Jan 1, 2015

"The effective thermal conductivity (ETC) is one of the most important thermo-physical properties of porous media. Due to the lack of higher precision influence of temperature on thermal conductivity, we took 6 groups of experiments on rock samples (including igneous rock, sedimentary rock and metamorphic rock) under different operating temperatures from 20? to 50? by 7 acquisition points. The general equation of thermal conductivity drives the value of it increasing along with the decreases of the temperature. While in our experiments, it is easy to find a singularity among them for each sample. The experimental investigations we attempted to observe and interpret the alteration mechanism. According to the Heat Capacity Theory in solid state physics, this research gives the explanation about the “singularity” from 3 understanding of specific heat, average free path, and thermal conductivity. Our research divided the condition of the rock thermal conductivity into 3 different types. INTRODUCTION The effective thermal conductivity (ETC) is one of the most important thermo-physical properties of porous media(Huang & Han ,1988; Peierles ,1955). This parameter is necessary for analysis of heat transfer(Vaferi et al, 2014;Hans-Dieter & Rudiger,2003). It’s well known that a general equation for ?(T) was set by Sass et al. (1992) which based on the coupled effect of composition and temperature on the thermal conductivity(Jesse et al, 2013; Mongelli et al,1982).The equation was further successfully verified for other rock (Zumrud et al,2010;Abdulagatova et al,2009;Seipold& Huenges,1998).Thermal conductivity is also related to other physical proper ties of porous rock, such as thermal diffusivity, heat capacity(Brettmann et al,2011;Abuel-Naga et al,2008). It is well known that ETC and other thermo physical properties of rock materials are affected by various factors, such as temperature, pressure, mineralogical composition, porosity, stratification, size and shape of the components, and nature of pore fluid, etc. (Tiedje & Guo, 2014; Touloukian et al,1970).The understanding of heat transport processes still requires the knowledge of thermal properties of rocks."

Jan 1, 2015

"The Dumont deposit is a large (1066 Mt probable reserve) low grade (0.27% nickel), nickel sulphide project located in the Abitibi region 25km west of Amos, Quebec. Royal Nickel Corporation acquired the project in 2007 and has since taken the deposit through pre-feasibility. And updated, revised pre-feasibility was released in July 2012.The disseminated nickel sulphide and alloy mineralization is hosted within the serpentinized dunite subzone of the Dumont Sill; a differentiated, pervasively serpentinized, ultramafic sill of komatitic affinity. Pentlandite, heazlewoodite and awaruite are the dominant nickel-bearing, metallic phases and can be recovered by conventional methods (flotation, mag separation). Non-recoverable nickel is also present within the silicate matrix of the serpentinized dunite and is locked in serpentine (Fe and Mg-rich variants) and minor olivine.A detailed mineralogical program including 1097 QEMSCAN® samples and 4300 electron microprobe points were undertaken to increase the understanding of the nickel deportment in the various recoverable and non-recoverable phases in a spatial context across the deposit. Eighty-three (83) metallurgical tests performed under a standard procedure have linked the mineralogy to metallurgical performance. This has allowed the creation and modelling of geometallurgical domains on a block by block basis to understand the recovery variation and metallurgical performance throughout the deposit. Understanding the spatial variability of Ni deportment in recoverable and non-recoverable phases through mineralogy is the key to understanding metallurgical performance thus, unlocking the value of the Dumont deposit and other large tonnage low grade ultramafic nickel deposits."

Jan 1, 2013

By Dolea Gabriel Gheorghe

In the present paperwork is proposed an economical-mathematical model (fuzzy) that aims optimize the technological variants of the mechanized coal face. By fuzzification, the issues to solve become more flexible and allow the decision maker to acquire more variants for the functions objectively established. The description of technological solutions is carried out by a set of controllable variables of "category" type by which the type of the machinery is defined within the frame of the actual geological & mining conditions. In the paperwork are used concepts of "successions graph" and "matrix of compatibilities"; with their help a methodology to choose between different technological variants of coalfaces is proposed. It treats the problem of developing the functions that express the membership degree in vague concept. In the end it is presented an assessment procedure for the technological variants of mechanized coal face.

Oct 1, 2009

By V. Balakrishnan, A. Hewitson

"The Kudremukh Iron Ore Company Limited, a government of India enterprise, has constructed iron ore mining, crushing, handling and concentrator facilities at Kudremukh, in southwest India. Concentrate produced is pumped 65 km to dewatering, storage and ship-loading facilities which were built at the same time at the sea port of Mangalore.A computer-based distributed process control system was implemented for all operations at Kudremukh and to interface with and monitor the Mangalore plant.The control system is examined from various standpoints, beginning with a description of its architecture, method of process input/output connection, and major hardware items.Software considerations and process applications are then looked at, with a review of the integration of the computer vendor's system software with user-developed applications programming. A control example of crusher operations is provided.Following the descriptive segment is a discussion of the design considerations and decision factors involved in the implementation of such a system considering the type of process and the remote nature of the installation site. It ends with a review of actual operating experience and conclusions regarding both this system and future similar applications.ScopeThe following is a discussion of the computer-based process control system applied for the Kudremukh Iron are Company Limited's ore handling, concentrating and shipping facilities located in South India.A general description of the process and plant equipment will be followed by an examination of the control system from the points of view of hardware and signal flow, software requirements, design considerations, implementation logistics and operating experience. Conclusions will be drawn concerning this and future computer applications."

Jan 1, 1984

OBJECTIVES ??REDUCE OPERATING COSTS ??INCREASE LIFE COMPONENTS ??EXTEND LIFE of THE DOZER ??REDUCE MAINTENANCE COST ??REDUCE DOWNTIME ??IMPROVE DURABILITY & RELIABILITY ??IMPROVE BOLD JOINTS PREFORMENCE ??IMPROVE SAFETY

May 1, 2004

By R. Tipman, T. C. Burnett

"A general computer program has been written to calculate material balances using multiple regression techniques. The program can handle metal assays or size distribution data obtained in multiple surveys of the flotation circuit. The ""best fit"" weight split is calculated between the input and product streams by minimizing the sum of squares of the residual errors using all of the available data. The program includes an assay adjustment feature in which each assay is recalculated to fit the ""best fit"" mass balance. Thus assay or sampling errors can be easily identified. Also the assays can be statistically weighted so the most precise measurements are given the most influence on the material balance. The computer output reports the mass balance, the actual and corrected assays, the percent metal recoveries and the significance and confidence levels for the weight splits.The program enables a rapid and accurate evaluation of mass balances from large masses of data obtained in multiple surveys around a flotation circuit. The effects of changing process variables can be quickly evaluated with statistical confidence."

Jan 1, 1978

By D. M. May

"Cut-and-fill mining is a stoping method that has been widely utilized in the mining industry over the past forty years. It took preference over shrinkage methods at Levack in the early 1930sbecause of its safety aspects; i.e., prompt support of the stope sidewalls, good working floors and better accessibility to support poor back areas. In addition, higher recoveries of ore were possible because of the flexibility of the method in that silling could take place easily at any horizon; low-grade ore could be sorted and left in the stope as fill and certain zones of rock could be left unmined. With modern techniques, a steady production rate can be established, as filling and mining can be carried out stimultaneously.AIthough there are numerous variations of cut-and-fill mining throughout the world, this paper reviews the original type of mining, with modifications and improvements through the years to present modern practices, with the Levack West operation appearing to be the most productive at this time. Stoping efficiencies have also increased substantially from the original 10 tons per manshift to the present 55 tons per manshift.The paper also outlines the many improvements that have been made with respect to mucking and ground support operations; from hand mucking in a single stope to the use of frontend loaders and haulage trucks in fully accessible stope complexes; and from timber props to roof bolts of various types. Although present methods are extremely satisfactory, experimentation is continually being conducted to improve safety and productivity for future mining.IntroductionThe major mining operations of the Ontario Division of Inco Limited are located in the Sudbury Basin (Fig. 1). Around the rim of this geological formation and within 30 miles of the City of Sudbury are nine producing mines and one ' open pit operated by the company .Ore production currently approximates 11.5 million tons per annum from underground and open-pit operations. Underground mining methods include sub-level caving, shrinkage, cut and fill, undercut and fill, blasthole and vertical retreat. The Levack Complex, the main plant of which is the central Levack Mine, produces 11,000 tons per day.The first prospecting in the Levack area, in 1887, was conducted by James Stobie, who examined rock cuts along the route of the Canadian Pacific Railway to the northwest of Sudbury. However, it wasn't until 1913 that operations commenced at Levack under the Mond Nickel Company."

Jan 1, 1981

By O. J. C. Runnalls

"Canada became the world's largest uranium producer in 1984. That leadership position is likely to be maintained for many years into the future because of a firm production base, many undeveloped known deposits with commercial promise, and a large geologicalpotential for new discoveries.There are some uncertainties on the horizon, principally because of restrictive actions in process within the U.S.A., which are aimed at preserving a deteriorating domestic uranium industry. Should such actions result in import restrictions, for example, there would be a negative effect on foreign producers at least in the short term. Canada may avoid such difficulties under a tentative U.S.-Canada free-trade agreement where restrictions on the import of Canadian uranium into the United States would be eliminated. Over the longer term, demand for Canada's uranium resources will grow because of the foreseen growth in the world's installed nuclear power capacity. IntroductionSince the phenomenon of nuclear fission was discovered in 1938, the utilization of uranium has grown substantially. Initially, the principal use for uranium was in the production of nuclear weapons. However, once civilian nuclear power reactors began to be built in the 1950s, an increasing fraction of uranium output was directed to the production of fuel elements for use in electricity generating stations.The cumulative uranium production by those countries in the World Outside Centrally-Planned-Economies Areas, WOCA, during the period 1938 to 1985 exceeded 800 000 tonnes of uranium. Some 60% of that was mined in the United States and Canada, as indicated in Figure 1. In 1986, nearly 80% of WOCA output came from five countries, Canada, United States, South Africa, Australia, and Namibia, as indicated in Table 1 and illustrated in Figure 2.During the past decade the world annual consumption of nuclear energy has more than tripled (Fig. 3). As of December 31, 1986, the world total of nuclear power reactors had reached 394 with a total net capacity of 270 GWe. The thermal output from nuclear power plants in 1985 exceeded 60% of the energy contained in all of the oil produced that year in the Middle East. Thus, nuclear power has already become an important component in the world energy supply picture."

Jan 1, 1988

By John Russell

"Faster, safer, grinding mill relining offers the obvious attractions of reduced mill relining times with the knock-on incentive to reduce all other maintenance down-time, opening the possibility for increased annual plant utilisation.Leading edge liner handler technologies by RME, focused toward even shorter relines for very large SAG and AG mills, have recently split into two quite distinct paths:•,?Single SAG/AG Mill Relining Machines (MRM’s) of very large capacity, such as Newcrest Cadia’s 40’ SAG MRM of 6000 kg capacity and P.T. Freeport’s 38’/34’ SAG MRM of 7250 kg capacity;•,?Twin-machine SAG/AG Mill Relining Systems of moderate to large capacity such as BHP Billiton’s Escondida Laguna Seca 38’ SAG MRM’s, each featuring 4500 kg capacity.RME, its customers noted above and their liner suppliers are providing leadership in this important annual utilisation advance.Once the 24 hour mill shell reline becomes reality, liners designed for maximum profit, not maximum life, albeit exchanged more frequently, become possible too.INTRODUCTIONAt most mineral grinding plants, mill relining activities dictate each maintenance shutdown’s critical path. When annualized, mill relining remains the largest, single influence in defining plant availability.Because of restricted access, both inside and outside the mill, increased application of manual labour has no effect on reducing relining downtime. The only answer for RME has been to develop and apply new relining technologies now known as RME’s Mill Relining System.RME’s primary focus for over twenty years has been the reduction of grinding mill relining times while simultaneously providing a marked improvement in relining safety. Our original (1990) target was to halve traditional (pre-RME) reline times and to eliminate accidents and injury by mechanizing all physical work."

Jan 1, 2008

By N. W. Kirshenbaum

"The Marconaflo slurry system was originally developed to reduce costs and solve technical problems in the marine transport of mineral cargoes. In the short time since its inception, it has been found to offer economies and advantages for land-based and in-plant materials handling. This efficient method of reclaiming and slurrying particulate materials at very high pulp densities can be directly utilized in a wide variety of mineral process systems. These include: storage-reclaim applications, where even cohesive, compacted materials can be reclaimed from settled storage ""on demand""; the growing number of hydrometallurgical operations wherein slurried materials are processed to extract or yield metals; certain applications associated with pyrometallurgical treatment; and as a means of augmenting the performance of conventional mineral dressing equipment, such as thickeners.INTRODUCTIONIn the continuing effort to lower costs of producing minerals and extracting metals, the field of handling and transportation often receives too little attention from those engaged in the mining and winning of ores and metals. This comment, which pertains to ferrous and non-ferrous as well as to non-metallic producers, is especially pertinent to products having relatively low value, where transport costs can be a major portion of the delivered selling price to the minerals receiver.One method which was developed recently for the purpose of reducing costs and solving technical problems in marine transport and handling of mineral cargoes is the MARCONAFLO slurry system. A notable feature of this system is its versatility; in addition to its use in marine transport1*, some of its diverse applications have included the mining and reclaiming of tailings2 and in-plant materials handling3. As the concept and fundamentals of this system have been well explained previously4,5, the mechanics of the system will not be elaborated upon here. Rather some specific ways in which MARCONAFLO can be applied to processing and extraction will be explored."

Jan 1, 1973

By G. H. Hope

"Pamour Porcupine Mines of Timmins, Ontario operates two 3,000 ton per day concentrators which receive ore from eight to ten mines in the area. The area milling concept was adopted by Pamour in 1971 and has been used successfully since then. The purpose of this paper is to discuss the advantages and the problems of area milling. Pamour Porcupine Mines Limited operates two 3,000 ton per day concentrators which receive ore from eight to ten mines in the Porcupine region. The area milling concept was adopted as the route to survival for Pamour and has worked successfully. HISTORICAL BACKGROUNDProduction of gold from the Porcupine region in Northern Ontario started in the early 1900's and has been continuous since that time. Some of the major operators were companies such as Mcintyre, Hollinger, Dome, Pamour, Paymaster and the list goes on. An underground survey would reveal hundreds of miles of drifts and raises. The main group of mines extends from South East of Timmins to the Pamour Mine, 15 miles to the east. During the lean years of the sixties when gold prices were low, labour costs were rising rapidly, and ore grades were dropping, many of the area mines closed down their operations."

Jan 1, 1981

By E. W. Johnson

"The title of my paper is ""I 'Wonder Where The Yellow Went"". As you can readily guess, it is not related to an old-fashioned ""Pepsodent"" sales pitch! Rather, it concerns a situation which arises all too frequently in some gold milling operations, namely when actual ounces of gold production do not come up to estimated or projected ounces. The boss man scratches his head and wonders where the missing gold has gone and how it has disappeared. The problem, if one exists, is amplified if one forgets that an estimate is just that - an estimate - and not a hard fact - even though the numbers are produced by computers. And yet, from the point of view of engineering; financial and production planning and security; it is most desirable to tie together all data relating to production estimates, losses and actual production.In the course of this paper reference will be made to the term ""variance psychology"", to a few of the physical properties of gold and to the nature of its occurrence in Canadian ores, in relation to the topic under consideration. Activities which have a bearing on production estimates will be reviewed. These include: weighing, sampling, assaying, estimating residual losses and, in cyanide plants, gold precipitate production. Mention will be made of apparent, unaccounted for and unknown losses. In conclusion, I shall draw from personal experience and relate three examples of ""Where the Yellow Went''."

Jan 1, 1986

By J. M. Hemstock, H. L. Ames

THESE forums have been held annually since they were introduced by Mr. L. E. Djingheuzian in 1957. The response of millmen to questionnaires such as the one this year is ample evidence of the interest these create. This year's topic is unlike those of past years since it is an attempt to understand a new concept of grinding rather than to improve the old. Before, we were thinking in terms of 2-5 cents improvement in grinding costs, now we will be discussing savings of 15-2 5 cents. As a background for this forum we will begin by summarizing the major controversial issues relating to grinding with steel, many of which will undoubtedly apply to pebble milling. Our •task to-day is to learn what has already been done in pebble milling and obtain a fair overall view of this method of grinding.

Jan 1, 1961

By Zhibao Li, Kunming Zhai, Yan Zhang

The hydration kinetics of MgO, namely magnesia or magnesium oxide, obtained by calcination of magnesite MgCO3 or synthetic MgCO3·3H2O has been studied. Nesquehonite (MgCO3·3H2O) was prepared by the reaction of MgCl2 with Na2CO3 in a mixed-suspension mixed-product removal (MSMPR) crystallizer at 40 °C. Three magnesium oxide samples were obtained by calcination of magnesite MgCO3 or synthetic MgCO3·3H2O in muffle furnace at 900, 1100 and 1300 °C for 3 h, respectively. The hydration experiments of MgO samples were investigated at 25, 35 and 45 °C for 24 h in a stirred batch reactor. The hydration results indicate that the rate and extent of hydration of magnesia decreased remarkably with hydration temperature and increased with decreasing calcination temperature at a constant hydration temperature. The whole hydration reaction of magnesia was supposed to experience the promotive period and declining period. An empirical kinetic model ( k t p -?ln(1-??) ??) and a modification of the classical shrinking core model for diffusion control ( k t b d -?-?3 2 ????1 [1 (1 ??) ] ) have been applied to fit the experimental data of hydration in two stages, respectively. The values of kinetic parameters ( p k and d k ) were obtained by regression analysis and the activation energy of the sample at 900 °C was estimated to be 34.23 kJ/mol. The comparison between MgO from calcination of synthetic MgCO3·3H2O and a commercial MgO used in silicon steel production was carried out, indicating that special silicon steel grade MgO can be obtained by calcination of MgCO3·3H2O below 900 °C.

Jan 1, 2014

By A. H. Marquis

Since the start-up of its first Direct Reduction Module in April 1973, S1DBEC has produced over 2 million tons of prereduced iron. During this period, SIDBEC has acquired comprehensive experience in the operation of the direct reduction process and at the same time has learned to recognize the characteristics that the oxide should have to constitute an adequate feed for the process. A comparison is made as to the design and operation of the two direct reduction units now operating at Contrecoeur, Que. A description is given of a method of evaluation of a direct reduction unit, which takes into account the main process variable sand which permits comparison ofthe results on a daily basis. The paper defines the characteristics that the iron oxide and the prereduced iron pellets must have to meet the specific requirements of the direct reduction and the electric arc furnace processes. A simple model makes possible a rapid evaluation of the technical and economic effect related to the use of a given raw material. Finally, the paper outlines the advantages of prereduced iron in the steelmaking process and on the quality of the steel products.

Jan 1, 1979

By N. W. Bliss

"Bauxite has been the almost universal ore of aluminum for about 100 years, with most of the world's reserves oc¬curring in the developing countries. As a result of fiscal and political activities prompted in part by the energy crisis, the formation of the IBA combined with increasing freight and labour costs, these reserves are no longer as competitive or as secure as they once were. This has given fresh impetus to the development of processes for alumina production that utilize raw material other than bauxite. Canada has no bauxite and it is prudent to look for alter¬native raw materials within our own boundaries suitable for one of these processes.Of the three igneous rocks that have been used as a source of alumina, only anorthosite is considered as a potential source in Canada. The Al content would be extracted by a sinter process, which currently requires a raw material with a. minimum of 28% Al2O2. Thus, about 4 tons of anorthosite and 10 to 12 tons of limestone are needed to produce one ton of alumina. There are two petrologically distinct types of anorthosite, one containing the plagioclase andesine-labradorite and around 26% Al2O3, and the other containing upwards of 30% Al2O3, in by¬townite-anorthite; for our purposes they may be con¬sidered as low- and high-alumina anorthosite respectively. The high-alumina anorthosites are somewhat rare; the low-alumina anorthosites are much more common, partic¬ularly in Eastern Canada. Geologically speaking, there is no shortage of anorthosite in Canada. The reserves are im¬mense, although their low Al2O3 content coupled with con¬siderations of location, access and proximity to limestone could be constraints to their development. Fly ash from coal-fired thermal power stations and nepheline syenite can also be used in a sinter process, but neither is likely to be utilized in Canada in the immediate future.The H+ process utilizes an acid attack to leach Al from a raw material with at least 20% Al2O3. One of the best raw materials is kaolinite-bearing clay; not only is it high in Al, but most of it can be extracted. With the possible exception of the Whitemud clay in Saskatchewan, Canada is apparently deficient in clays with sufficient reserves to support an alumina plant utilizing the H+ process. Low-alumina clays with illite and montmorillonite may also prove to be a suitable raw material if advantageously sited with respect to industrial centers. The average shale con¬tains only 15% Al2O33, much of which may be contained in minerals, such as feldspar, not amenable to acid leaching. If shale is used as a source of alumina, it will be because it contains some other valuable commodity, such as oil or uranium, the extraction of which leaves the spent shale upgraded in extractable Al2O3 and lowers the over-all costs to a point where it is economic, Thus, rejects from coal washing plants are most commonly considered as a source of alumina; they are already mined, are available in large and ever increasing amounts, and may contain significant amounts of combustible material which upgrades the Al2O3, content of the resulting ash. Coal rejects from existing and developing coalfields in Alberta and British Columbia are a possible source of raw material, but present data indicate they may contain insufficient Al2O3."

Jan 1, 1976

By A. M. A. Mohamed, F. H. Samuel, S. Valtierra, H. W. Doty, A. M. Samuel

"The influence of Fe, Mn, Cu and Mg alloying additions, Sr modification and grain refinement on the microstructure of as-cast and solution heat-treated Al-10.8% Si alloys was investigated using optical microscopy and EPMA techniques. The results showed that the modification effect of Sr diminished with increasing Cu and Mg additions, due to Sr-Cu-Mg interactions. Strontium caused segregation of AlzCu in areas away from eutectic Si regions, and altered the precipitation sequence of the a-Ah5(Fe,Mn)3Siz iron intermetallic from post-dendritic to pre-dendritic, with the phase observed within the a-Al dendrites. Depending upon the alloy Fe and Mn content, a coarser variation (""sludge"") of the a-Fe phase occurred, in the form of polyhedral shaped particles. The AhCu phase dissolved almost completely during solution heat treatment, while Al5Cu2Mg8Si6, sludge, and a-Aln(Fe,Mn)3Siz phases persisted in all alloys, particularly at high Mg and Fe levels. The f3-Al5(Fe,Mn)Si phase dissolved partially in Sr-modified alloys, the dissolution becoming more pronounced after solution heat treatment."

Jan 1, 2006