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By Yin Guangzhi, Song Zhenlong, Li Minghui, Li Wenpu, Deng Bozhi

"Darcy's law is widely used to describe the oil and gas flow characteristics in the multi-pore media reservoir. However, the low-velocity non-Darcy flow of oil and gas occurs in the multi-pore media reservoir under low permeability conditions. Meanwhile, the high-velocity non-Darcy flow of oil and gas occurs in the multi-pore media near the wellbore. The gas flow velocities in coal in different deformation stage under different gas pressure gradient were tested and the relationships between gas flow velocity and gas pressure gradient were discussed, which can help us to investigate the transformation conditions of gas linear flow and gas nonlinear flow in coal. The results showed that the gas flow in the coal under low effective stress environment can be described by Darcy's law. The low-velocity non-Darcy flow of gas gradually occurred and the start-up pressure gradient increased in the coal as the effective stress increased. The low-velocity non-Darcy flow of gas also occurred in the coal at the yield deformation stage, however, the start-up pressure gradient decreased as the effective stress increased in this stage. In post-peak stage, the highvelocity non-Darcy flow of gas occurred in the coal under low effective stress environment. The gas flow in the coal gradually returned to be Darcy flow as the effective stress increased. The mechanism of the phenomenon is discussed based on the experimental results. The research results can be used to guide well test analysis and prediction of oil-gas production. INTRODUCTIONThe oil and gas flow in original multi-pore media reservoir are usually regarded as steady and linear processes and can be described by Darcy’s law. However, the low-velocity non-Darcy flow of oil and gas occurs in the multi-pore media reservoir under low permeability conditions. Meanwhile, the highvelocity non-Darcy flow of oil and gas occurs in the multi-pore media near the wellbore or workface. The gas flow in the multi-pore media even may be unsteady under some conditions such as gas emission and outburst.The phenomenon of underground water low-velocity flow in clays was deviated from Darcy’s law was found in the end of the nineteenth century (King, 1898). The deviation from Darcy’s law was later reported and investigated more (Swartzendruber, 1962; Miller and Low, 1963). These researches revealed that the start-up pressure gradient exists under low permeability conditions. Klinkenberg (1941) proposed that the permeability constant as determined with gases is dependent upon the property of the gas, and is a linear function of the reciprocal mean pressure. This effect can be explained by taking into account the phenomena of slip, which are related closely to the mean free paths of the gas molecules."

Jan 1, 2015

By W E. vanSteenburgh

The Polar Continental Shelf Project was initiated in 1959 to provide an administrative and logistic vehicle for research in the physical sciences of the land, sea and channel area of the Arctic Archipelago. Most of the scientists are supplied on secondment from the professional branches of the Department. The yearly expeditions number some eighty scientists and sub-professional staff, and they are supported by a fleet of fixed-winged aircraft and helicopters. Accurate positioning is obtained by the use of a Decca Lambda navigational system which is moved as the area of interest is shifted. The Project is designed to accommodate not only physical scientists, but to provide facilities for other scientist who may have an interest in the area under study. The main research scope of the Project includes topographical surveys, hydrography, oceanography, geology, including marine sedimentary studies, gravity, magnetics, seismology, glaciology and geography. The Polar Continental Shelf Project was initiated and recommended by the Committee on Northern Development in 1958.

Jan 1, 1963

By Q. G. Reynolds, R. T. Jones

"Residence time distributions are well defined for batch and continuously stirred reactors. However, there exist many smelting furnaces that do not fit either of these classifications. A mathematical description is presented for the case of a furnace that is fed continuously, but where the liquid slag and metallic products are tapped intermittently. The effects of slag and metal tapping intervals and the fraction of liquid retained in the furnace, are shown to have a significant effect on the residence time distribution.INTRODUCTIONThere are some processes in which the time spent by the feed material in a smelting furnace plays a significant role in determining the extent of the reactions between metal and slag and influences the degree of settling of metal droplets from a molten slag.Residence time distributions are well defined for batch and continuously stirred reactors. However, there exist many smelting furnaces that do not fit either of these classifications. Here we will focus on producing a mathematical description for the case of a furnace that is fed continuously, but where the liquid slag and metallic products are tapped intermittently. The effects of slag and metal tapping intervals and the fraction of liquid retained in the furnace, are studied.Previous work (Jones, la Grange and Assis, 1997) has studied the effect of retention time on the degree of cobalt recovery achieved in a slag reduction process. In that work, a method was proposed for the calculation of the mean residence time of the contents of a pilot-plant furnace. That approach is to be extended here for the purposes of providing a more general design or scale-up tool.The maximum allowable depth of molten material in a given furnace is affected by such factors as the desired batch size (or the size of the ladles) and the pressure of the molten material that the tap-hole and surrounding system can withstand. Within these constraints, there might be some scope for choice of taphole position. The effects of this choice need to be understood mathematically."

Jan 1, 2012

By Seungyeol Lee

Currently, a new construction method using a robotic system is widely spreading in construction sites. This study is related to the design of glazing robot?s teach pendant which can improve convenience of handling and hence improve the productivity through the efficient interaction between an operator and a robot while doing glazing works, e.g., curtain wall installing. The suitability of selection and arrangement of control switches was assessed according to mechanical motions of a glazing robot, and design guidelines for improving convenience and productivity were drawn up through questionnaires carried out by site operators. To verify the proposed design guidelines, working time comparison of the proposed teach pendant and the existing teach pendant was executed.

Aug 1, 2013

By Jo Render

Expectations of your management approach ??Life of mine applicability ??Tailor scale of activity to scale of project ??Assess impacts, risks, and opportunities ??Use global good practice, backed up by rigorous analysis ??Support with trained monitoring and evaluation team ??Information infrastructure to allow ongoing trend analysis and tracking of progress ??Public reporting using standardized indicators Yes, we are talking about a ?management system?

May 1, 2011

By P. Morissette

Passive monitoring of support performance during rockbursts was conducted at three deep underground mines. A comprehensive database was constructed of 172 seismic events and the associated damage to support systems at 266 mine locations from January 2000 to September 2012. The majority of pertinent information was obtained through seismic system records and on-site field assessments. This work assesses the quality of collected information and evaluates the dynamic-load demand on support systems in seismically active mines.

Aug 1, 2013

By T. Bednarski, T. McCallum, L. Moya, L. Nsenga, B. Mbao

The accumulation of solids in solvent extraction (SX) circuits can cause problems with the physical and economic performance of the operation. These solids are responsible for the formation of crud, a solid stabilized emulsion containing organic, aqueous, air, and fine solid particles. The build-up of crud in SX settlers can limit SX operation throughput, require plant downtime, lead to higher organic losses, or result in higher aqueous in organic entrainment (all of which can have a significant, negative economic impact). Current practices for crud management are typically reactive. Crud is physically removed after it has been allowed to build to excessive levels in the circuit and processed mechanically using centrifuges or filtration. A new proactive solution has been developed to prevent crud formation and build-up. Low ppm dosage of an additive, ACORGA® CR60, into the pregnant leach solution (PLS) has resulted in reduced crud formation in pilot and commercial scale for a variety of PLS streams. This paper will review results from operations in North America and Africa, covering heap leach, concentrate leach, and agitated leach feeds. INTRODUCTION Crud formation and build-up in solvent extraction (SX) circuits has been a long time topic discussed and claimed to be crucial to the whole hydrometallurgical process (Liu, et al, 2006). Crud formation is present in all SX systems be it copper, uranium, zinc, etc., and Ritcey (1980) defined crud as a stabilized emulsion containing organic, aqueous, and fine solid particles. The ore type and feed composition is a major determining factor of crud formation and typically contains Si, Al, Fe, P, and sulfates (Ritcey, 1980). It typically builds at the interface between the organic and aqueous, but can also be observed as floating crud on the surface of the settler, or bottom crud, which is common to find in circuits treating agitated leach feeds such as in Africa. As crud formation has been unavoidable, many of the current crud management techniques are reactive, allowing crud to form and build in SX circuits. Once it does, it is removed and treated via different mechanical techniques, typically through some type of filtration or three-phase centrifuge, to remove the solids and recover the organic phase trapped within the emulsion (Ritcey, 1980). Automated pumping systems have also been designed and are frequently used in North American operations. The time and capital required to react to crud formation can be an overwhelming aspect to SX operation.

Jan 1, 2019

By Dan Nower

Machinery Health Monitoring of Shovels MINExpo 2012: Caterpillar announced the largest Electric Rope Shovel, capable of 120 short tons The next day, JoyGlobal (P&H Mining) ?one-upped? CAT, introduced a shovel capable of 135 short tons Large Concern: breakdown (unplanned outages) of one machine will be more disruptive to production

May 1, 2013

By D. S. Evans

Major Project Blues Over the last two decades, almost every major project has suffered significant cost overruns, significant schedule delays, and/or poor quality work. Exceptions are rare and most projects that tout being ?On Time and Under Budget? have re-cast schedules, significantly modified scope or revised base estimates. The problem isn?t new. In the late 1980?s the Rand Corporation published a study showing that 80% of all major projects had significant cost and schedule overruns. The problem is not restricted to the Canadian environment, or to a specific industry. It is a global problem.

May 1, 2013

By D. Hu, L. Matzar, J. Hampton, M. Gutierrez

Nanodarcy permeability is common in many oil- and gas-bearing formations requiring unconventional stimulation technologies, such as hydraulic fracturing (HF), which can connect the isolated hydrocarbon-rich pores with a wellbore through induced fracture networks. Even though a dense induced fracture network is capable of accessing economic amounts of hydrocarbons, much of the rock between and very close to the fracture network is still un-accessed and contains extremely low permeability. Inducing fracture networks into brittle rock can create large amounts of micro failures in surrounding regions that are not connected to the wellbore, as can be seen in Fig. 1(a) from the very wide acoustic emissions (AEs) cloud associated with a narrow fracture generation. It is possible in certain types of rock to increase the effective matrix permeability in localized regions based on the damage associated with the surrounding hydraulic fractures and subsequent high stress concentrations along localized pre-existing potential failure zones. To study this problem, laboratory HF tests were performed at true-triaxial stress state in brittle crystalline rock while monitoring AEs. The AE associated with HF was analyzed for source parameters using the moment tensor inversion method called Simplified Green’s Functions for Moment Tensor Analysis (SiGMA). Using the moment tensor for each individual AE event, the mode of failure was determined. Crack slip directions and crack face normal directions were also found, along with the relative volume of individual micro failures as well as a damage parameter. The associated source parameters were used to classify differing regions of damage in the sample induced from HF and correlate these regions of differing damage to the effective drainage region. Shown in Fig. 1(b) is a near-wellbore (NWB) region that contained three times larger average relative volumetric deformation of individual tensile AE events than the average tensile AE event volume from the entire sample. Because of the large difference in micro fracture volumetric deformation for the NWB region compared to the entire sample, predictions of HF induced damage must be included in reservoir drainage predictions.

Jan 1, 2015

By Eric Johnson

"IntroductionHistoricalCyanidation is a leaching process, in world-wide use, to extract gold (and silver) from ores and concentrates. The process has many inherent advantages on account of its adaptability:a. to any scale of operation;b. to a wide range of ore types and mineral associations;c. to a wide range of physical characteristics of the gold particle size, alloy (electrum) or mineral (telluride);d. to relatively simple plant controls and operating procedures;e. to simple marketing procedures and quick cash return.The basic idea for cyanidation was first described and patented by a German chemist, L. Elsner, in 1846. Some forty years later, J.S. McArthur, a metallurgical chemist and R.W. and W. Forrest, medical doctors, all of Glasgow, Scotland, came to realize the import of the discovery and accordingly, registered patents in Great Britain in 1887 and in the United States in 1889. The keystone of the McArthur-Forrest patent registration was the use of weak (0.05o/o) instead of strong (1.0%) solution.The years 1890-1910 saw much progress in equipment design and the advance from batch to continuous processing to increase efficiency and reduce operating costs.In later years, technological progress followed advances in materials of construction and control systems. Current innovations include large-scale equipment, high-capacity thickeners, belt type filters and Steller, candle-type filters for plants using zinc dust precipitation. As well, environmental protection is increasingly a major concern.The technology of gold adsorption from cyanide solution onto activated carbon has made rapid strides in recent years. This has followed the initial efforts of Potter, Salisbury, Zadra and their colleagues of the U.S. Bureau of Mines Research Station in Salt Lake City, Utah, and the field work of Homestake Mining Company personnel, in Lead, South Dakota."

Jan 1, 1989

By A. Khan, C. Ciriello

The purpose of this paper is to demonstrate the value of constraint modelling in optimization of mineral processing systems. This will be achieved by first understanding the overall concept of variation and constraints present in any system. Next, the value of using a Constraint Model in optimization is demonstrated through comparison of business cases. The benefit of understanding the severity of constraints and movement of the bottleneck within a mineral processing system will be understood through the use of a case study. Paper will conclude with a summary of all optimization benefits that utilization of a constraint model can bring.

Jan 1, 2015

By Daan Maijer, Wade Marquardt, Robert MacKay, Steven Cockcroft, Farzaneh Farhang Mehr

"To comply with the new Corporate Average Fuel Economy (CAFE) standards, the automotive industry is aiming to reduce weight and increase the power and efficiency of small displacement engines through the application of forced induction technologies. As an example, there are now several 2.0 litre turbocharged engines in production, producing in excess of 240 hp. To meet the need for improved fatigue properties in the engine blocks used in these high-output engines, a new water-cooled chill technology is under exploration at UBC in partnership with General Motors and Nemak. A series of experimental techniques were used to assess the capability of the new chill to extract heat from an A319 casting in the vicinity of the main bearing bulk head. The results show that this method has the potential to achieve a reduction in secondary dendrite arm spacing thus meeting the new microstructural specifications for these engines.INTRODUCTION The automotive industry is working to meet the stricter efficiency requirements laid out within the CAFE (Corporate Average Fuel Economy) regulations (Bastani, 2012; Cole, 1995; Mackay, 2011; Miller, 2000), while at the same time not sacrificing performance. One approach is to increase the use of lightweight materials, which leads to a decrease in the overall vehicle weight and fuel consumption (Cole, 1995; Mackay, 2011; Miller, 2000). Other approaches include smaller displacement engines and gas-electric hybrid drivetrains. However, one trend that is becoming clear, is a greater emphasis on force induction gasoline engines. This allows for weight reduction to be achieved with smaller displacement engines without sacrificing performance. One consequence of this approach is that the engine block materials are subject to higher in-service thermal and mechanical cyclic loads (Cole, 1995; Miller, 2011; Heysler, 2001) The fatigue properties of an alloy are strongly affected by a number of the, as-cast, microstructure features including, Secondary Dendrite Arm Spacing (SDAS), porosity and eutectic lamella spacing (including intermetallic ß-Al5FeSi platelets) (Mackay, 2010a; Mackay, 2010b; Viet-Duc, 2015; Casellas, 2005). It is generally accepted they can act as fatigue initiation sites and that a reduction in their size will result in an improvement in fatigue performance. For a given alloy chemistry, one of the key parameters affecting the length scale of all three is cooling rate (Mackay, 2000)."

Jan 1, 2017

By Ian Orford, Ken L. Boyd

"Can the ever-increasing tonnages of ore and waste being mined today be accommodated simply by using bigger and better crushers? This paper updates the principal author’s earlier publication, “Crushing Plant Design and Layout Considerations” (SME Mineral Processing Plant Design, Practise, and Control, 2002). It reviews the latest primary crushing and large cone crusher designs. Its goal is to help consultants and operators select the optimal equipment and custom-designed items in the material handling flowsheet from the mine to the mill, maximizing operating hours per year.INTRODUCTIONAre larger crushers the answer to meeting the demands of existing or new mining projects for increased tonnage? The principal author’s previous paper in the year 2002 on ""Crushing Plant Design and Layout Considerations"" provided a detailed design and layout review for the design of primary and fine crushing (Secondary, Tertiary, Quaternary) mineral processing facilities. Some of the conclusions in this previous paper had predicted that larger crushers for primary and fine crushing would be beneficial and contribute to the further development of mineral processing. Larger crushers for primary and fine crushing applications are now available.The rock size reduction process, from the mine to the selected milling process facility has not changed since man first broke a rock to get at the interesting mineralization within. The rock size reduction process circuit from the mine to the mill can be summarized into four (4) stages:• Stage 1: Mining ( Rock Breakage and Fragmentation)• Stage 2: Pre-Screening (Scalping)• Stage 3: Primary Crushing• Stage 4: Fine Crushing (Secondary, Tertiary and Quaternary; the crushers used in this stage are identified by the titles which usage has conferred on them)Plant throughput and ore delivery schedule will form the basis for flowsheet design and equipment selection. Once a project's design criteria and the mine plan has been established, the actual circuit's utilization percentage (percentage of hours when the circuit is being utilized) can be optimized for each of the four stages. The mining and process departments are the key stake holders in the selection of the final comminution circuit and both departments should be familiar with and contribute to the design of the circuit."

Jan 1, 2016

By S. Hopkins, R. Preston, S. Gillis

"This paper examines typical visual inspections of operational soft rock mine shafts and discusses some of the challenges involved, many of which are associated with inconsistent inspection practices. The paper presents the development of a more standardized approach to periodic shaft inspections that supplement the more frequent inspections performed by shaft crews at the mine. This approach helps to keep an accurate record of changing conditions, compare conditions between multiple mine sites, as well as prioritize and plan potential remedial work. INTRODUCTION Shaft inspections, whether they are performed daily or weekly by members of the shaft crew at the mine, or periodically by consultants, traditionally involve a visual inspection undertaken with personnel traveling on an inspection deck on the conveyance, taking notes and photos. Inspections are typically required by mining regulations and carried out to identify and address hazards before a safety incident occurs that could cause harm to people or damage to property, as well as to help plan required maintenance work. Depending on the site, there can be many challenges associated with inspections in the shaft, especially compared to a typical inspection at surface. Some of these challenges are associated with the shaft environment itself, while others are related to the subjectivity of inspections and a lack of standardization, particularly between multiple sites within the same operating company. Recognizing these challenges, a more consistent and repeatable approach to shaft inspections in soft rock mines is evolving. This approach involves reviewing available historical data, comparing sites with similar conditions, establishing survey control, documenting observations and measurements with locations, and updating as-built or condition drawings. Part of this standardized approach is the implementation of an innovative 360-degree camera with a high-power lighting system that can be used either remotely or alongside personnel completing a traditional visual inspection. The system uses six cameras to take photos at a rate of 15 frames per second, with the image data subsequently processed and stitched, then joined into a high-resolution video. This tool improves time-efficiency, objectivity, and repeatability of inspections."

Jan 1, 2019

By R. D. Brown

For the first time in years, the spring budgets of federal and provincial governments have not brought down major new proposals affecting the tax burdens of the mining industry in Canada. It seems appropriate to use this unaccustomed period of tranquility to set out an extremely abbreviated summary of the principal features of the federal and provincial income and mining tax rules affecting the mining industry.

Jan 1, 1977

By M. Cousineau, S. Gariepy

"Current business and corporate environments push for improving metal accounting practices in smelters. The ensuing projects commonly proceed along a bottom-up approach. As such, efforts are first put on reviewing the measurement system and then on remedying the identified weaknesses. The focus is thus moved to mass/metal balance only after the measurements upgrade process has been completed. However, practice has shown that assessing the high variances related to suboptimal measurement processes is complicated without the help of statistical data reconciliation. This bottom-up approach leads to a to-do list that can not only exceed available resources but also lack prioritization in view of achieving the targeted end use. This paper describes an upgrade project done differently where all the three dimensions of the metal accounting system: hardware, software, and people were instead involved at the onset. Personnel was thus trained on data reconciliation software at the beginning of the project to make the reconciled mass balance benefits available earlier in the upgrading project. This has pinpointed the most critical measurements where accuracy and reproducibility should be improved. Overall, not only the instrumentation retrofitting process has been streamlined, but the global risk for the whole upgrading project has been significantly lowered.INTRODUCTION Mining companies are pressured to improve their production accounting practices in response to the strengthening of corporate requirements for timely and accurate production reporting (Gaylard, Randolph, & Wortley, 2014). Smelters are not spared from these changes. However, their unique situation in the mining value chain set them as strategic targets for upgrading projects. They usually have a longer lifespan than concentrators thereby offering an extended lifecycle to justify investments. Furthermore, numerous smelters have toll agreements with third parties. Accurate cost and production accounting is, therefore, a vital piece of information to fix acceptable contract conditions. Mining companies are ultimately aiming at a clearer view of the operating performance of each business unit to improve their business decisions in a competitive environment. This sought for increase in visibility through plant performance can only be achieved through an upgrade of the metal accounting system. Figure 1 shows the different components of a state of the art system (Gaylard, Morrison, Randolph, Wortley, & Beck, 2009)."

Jan 1, 2017

By R. J. Rotzinger

The Gibraltar Mine and Mill facility were commissioned in 1972 by Gibraltar Mines Ltd utilizing a flowsheet consisting of two stages of crushing followed by a rod mill / ball mill grinding circuit. During operations a number of opportunities were evaluated to expand the mill capacity; however, the economics of the day did not allow any of these projects to proceed. The mine continued to operate until late 1998 when it was shutdown and put on care and maintenance due to low commodity prices. Taseko Mines acquired Gibraltar in 1999 and in 2004, with the improvement in the metal markets, made the decision to restart operations. During the restart planning a number of opportunities for mill improvements and upgrades were identified and, after operations were successfully restarted, the decision was made to once again review expansion opportunities for Gibraltar. Taseko evaluated various expansion alternatives eventually deciding to install a SAG Mill, convert the existing rod mills to ball mills and distribute the SAG discharge to the resultant six 6 parallel ball mills. This paper discusses the design, implementation and commissioning of the SAG mill grinding circuit.

Jan 1, 2012

By David L. Anderson

"The government o f Canada has, since 1981, been under intense political pressure to modify its foreign direct investment (FOI) regulatory regime(1). To date the government's response has been limited to administrative and ""cosmetic"" changes: substantive issues have been largely ignored(2). However, as long as the economy continues to flounder , the Foreign Investment Review Agency (FIRA), as it is presently formulated , will continue to be an easy target for government critics . This phenomenon, in conjunction with the virtual certainty of a federal general election within two years, suggests that changes to the FIR Act will be seriously entertained by the present government.Recent events indicate that if change s are made, they will likely entail the adoption of a special-sector approach within the existing framework of a general screening system(3). Since this approach is currently employed in Australia(4), it would seem to be appropriate, from a public policy perspective to study that country's experience in developing and operating such a scheme. In doing so, I shall focus on the mineral sector; the rationale for doing so is as follows. First, this sector served as the focal point of the Australian FOI regulatory debater(5), Second , with the exception of the oil and gas industries, the non-petroleum mineral sector is one of the few areas of the Canadian economy wherein the Trudeau government has adopted an explicit domestic ownership target(6). Third, the non-petroleum mineral sector is, undoubtedly, a prime candidate to be denoted a s a special-sector if such a framework were to be utilized by the Canadian government!"".Although international comparisons are fraught with danger , a Canadian/Australian comparison is particularly appropriate(8). Both countries have reasonably similar economic, political and social structures . Furthermore, as noted above , Australia is the only other western country which employs a general screening mechanism for FOI. In addition, it utilizes a special area approach ; within this scheme, an explicit target of a minimum of 50% Australian ownership of all new resource projects has been formulated and clearly promulgated to all of the relevant interest groups. This policy, broadly defined, has been in place for more than six years and during this time the Australian mineral sector has, by world standards, prospered(9). Hence, the Australian experience in designating the mineral sector as a key area within a general screening system, should be of interest to Canadian policy-makers."

Jan 1, 1984

By Masashige Makifuchi, Hiroki Kumakura, Kota Nagai, Takahiro Kikuchi

"A large amount of platinum group metals (PGM) are used in automobile catalyst. It is important to recover the metals from wasted catalyst. Nomura and Kageyama (2013) suggested recovery process that PGM oxides were absorbed to perovskite-type oxide based on LaScO3. In their process, the PGM in wasted catalyst as absorbed to the perovskite-type oxide as PGM oxide. It has potential to each element in the process if the perovskite-type oxide is selected properly. In this study, the PGM oxide absorption properties of various perovskite-type oxides are investigated to develop a new recovery and separation process. The various perovskite-type oxide were synthesized with metallic platinum, palladium, rhodium at high temperature in air atmosphere. And the PGM contents in the perovskite-type oxide after the experiment are determined by chemical analysis. Some of them have the properties to absorb specific PGM oxide selectively. In addition, in order to increase the amount of absorption of PGM oxide and composition of the perovskite-type oxide experimental temperature was investigated. Then it is also found that doping another specific element to the perovskite-type oxide is effective to increase the amount of absorption of PGM oxide. Then a new recovery process of PGM from wasted automobile catalyst, in which PGM can be separate to each element, was designed.INTRODUCTIONA large amount of Platinum (Pt), Palladium (Pd), and Rhodium (Rh) are used in automobile catalysis (Figure 1) (Platinum, 2013). Natural supplies for these metals are limited and PGM mining can detrimental environmental impact. Therefore, the recycling of PGMs from wasted automobile catalysis is very important. The Rose process (Figure 2) was developed as a process to recover PGM from wasted automobile catalysis. In this process, the automobile catalysis is first crushed mechanically, and then extracting agent, copper (Cu), and flux are melted at high temperature. The mixture separates into a metal phase, (Cu alloy containing PGM) and slag. The PGM is enriched by oxidizing. Cu to Cu oxide. The PGM are then recovered and separated to each element in a wet process. However, it is hard to dissolve the PGM with acid because they are chemically stable and strong oxidation agent such as aqua regia is used. Moreover, to separate the PGM to each individual element, a solvent extraction process is required."

Jan 1, 2016