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By D. W. Hayley

The rapid expansion of exploration drilling with anticipated production facilities for oil and gas in the Mackenzie Delta region of the Northwest Territories has created a demand for granular construction materials. This paper discusses the technique adopted and experience gained by the authors from several major resource evaluation programs in this remote area. The first part of the paper describes a methodology for deposit identification, logistics of helicopter and ground-based drilling operations and the sampling difficulties which are unique to permafrost: soils. The second part describes the exploitation of a large glaciofluvial deposit at YaYa Lake on Richards Island. Granular construction material is sparse in the delta region relative to projected demand. Exploitable sources of granular materials for aggregates or construction borrow are found in glaciofluvial deposits of Pleistocene age or in outcrops of Paleozoic bedrock. Glaciofluvial landforms can be located by reference to published surficial geology maps coupled with airphoto interpretation. Preliminary assessment of these features in a large region is most economically carried out during the summer months with a drill that is transportable by helicopter. Once prospective borrow pit sites are identified, a detailed ground-based winter drilling program must be undertaken to establish aggregate quality and quantity, and to provide information on natural features which could affect development. The glaciofluvial terrain has been highly modified by the formation of massive ground ice within the gravel deposits. This presents some unique pit development problems which are not encountered in a normal bedrock quarry operation.

Jan 1, 1977

By David A. Fawcett

"This paper presents a summary compilation of current Canadian coal research projects in the areas of exploration, mining and preparation. The compilation forms the basis for a review of present operations and technology, and of current research efforts. General research areas, requirements and priorities are suggested along with a discussion on achieving the research goals in terms of funds, facilities and staff. The current level of research funding in these areas is assessed. IntroductionCanada's coal production is expected to undergo major expansion over the next two decades in response to domestic demands on coal for electrical power generation, industrial uses and conversion to synthetic .fuels, and in response to export demands for both thermal and metallurgical coal s. Surface mining will continue to dominate, but underground mining will contribute an increasing proportion to total production.In Canada, coal research, particularly in the areas of exploration, mining and preparation (E, M & P), has been limited. Increased impetus has recently been given to this research with expansion of CANMET's activities and with the establishment of the Coal Mining Research Centre (CMRC). University researchers are branching into coal research; strata mechanics and preparation are popular in mining-related fields.With the increase in number of organizations and individuals involved in coal research, a means of keeping abreast of the ongoing work is necessary. An annual summary of the status of and developments in current research assists in providing this information. The CMRC prepared such a summary for Canadian coal E, M & P research in 1979 and it received favourable response, justifying the effort. A 1980compilation has been prepared and pro vides the basis for this paper; it is presented with a brief discussion on background, format and content.The compilation forms a basis for an examination of the current status of Canadian technology in E, M & P and of the ongoing research in each area. General research requirements are reviewed and programs and tasks are suggested, followed by a discussion of research goals in term s of priorities and achievement. An assessment is made of the level of research funding in Canada, with comparisons drawn from the United States, the United Kingdom and Australia."

Jan 1, 1980

By Arthur M. Whiteside

Discussion of the laws bearing upon the economics of mining in this province at once resolves itself under three headings: (a) The rights and obligations of holders of mineral bearing lands; (b) Taxation of mines; (c) Regulation of methods adopted in financing mining operations. Titles: The law relating to titles is contained in the Mineral Act, Placer Mining Act and Coal Mines Prospecting Act. Origin: Mining laws in force in this province and elsewhere on the continent had their origin in the rule-of-thumb regulations adopted by prospectors themselves, when, far from the centres of civilization and the seats of the courts of justice, they found it necessary, for mutual protection, to fix the conditions of possession by right of location, and to prescribe the duties to be performed in order to enable the individual to maintain his ground against all comers. These regulations have been codified and added to by legislatures, until we find adequate protection and safeguard to property in the laws of this province.

Jan 1, 1924

By A. C. Atenas

The majority of refineries that operate with traditional starting sheet technology ?starting sheet- uses a relatively low current density of 250 A/m2. Industrial tests at high current density with conventional technology were carried out in Refinery of Potrerillos, getting satisfactory results that are similar the results obtained with permanent cathode technology. The series of copper refining electrolyses electrolysis trials were carried out between 300 to 325 A/m2. Electrolysis conditions, in accordance with industrial practice, were kept constant in all sets of experiments and were as follows; 45 g/L Cu 2+, 210 g/L H2SO4, 62 °C, electrolyte circulation of 14-18 L/min. The same Dosing dosing of Additives additives used in permanent cathode technology was required in these tests. In general, only not importantminor operational modifications were necessary in comparison to normal practice in the Refinery to assure the good results. Different quality of starting sheet and anodes were examined. The test included starting sheets from smelter and laminated process. Results indicate that the charge physical quality of the electrodes and the control of the process during the two first days of operation are the keys to get the best results.

Jan 1, 2007

By A. Bouchard

"Based on laboratory testwork, a two-stage cleaner / re-cleaner circuit with feed regrind was proposed to replace an existing single-stage middling circuit treating a scavenger concentrate at Inco’s Clarabelle mill. In order to effectively transfer the technology and implement the new flowsheet in the plant, an extensive on-site pilot plant campaign was conducted. After demonstrating the improved metallurgy, the two-stage middlings circuit was successfully implemented at the operation.The present paper describes the on-site pilot plant testwork and the plant metallurgical improvement after implementation of the new middlings circuit. The addition of TETA / Na2S03 greatly enhanced the pentlandite selectivity against pyrrhotite and the two-stage cleaning considerably improved the pentlandite selectivity against rock minerals. The improvement was immediate after the installation of the new middlings circuit. Size by size recovery analysis indicated that a finer regrind would further improve the metallurgy of the new two-stage cleanerhe-cleaner circuit and those modifications are in progress at the mill.INTRODUCTIONThe milling operation at Inco’s Clarabelle mill has been described elsewhere (Kerr and Kipkie, 1985; Agar, 1991). While maximizing the recoveries of chalcopyrite (Cp) and pentlandite (Pn), continuous effort has been directed toward improving pyrrhotite (Po) and rock minerals (Rk) rejection. Inco discovered diethylene triamine (DETA) and triethylene triamine (TETA) (Marticorena, et al., 1994) for pyrrhotite rejection. Falconbridge further improved pyrrhotite rejection using DETA and SO2 (Kelebek, et al., 1995). No special technologies are used in the rejection of rock minerals."

Jan 1, 2001

By M. L. Haider

Introduction I Appreciate very much the opportunity of discussing with you tonight oil developments in western Canada. These developments are of importance to all of us, first because of their great economic significance to all of Canada, and second because of the location of the new oilfields. Situated as they are in the west and northwest, they are of considerable strategic value from the standpoint of continental defence. The story of oil development in Canada covers a span of almost a century, during which time success in finding reserves of petroleum was barely sufficient to maintain interest in continuing the search. Finally, in 1947, a well of the first importance was completed in Alberta and, judging by discoveries made since then, it appears that Canada, at long last, is to become an important producer of petroleum.

Jan 1, 1950

By Suzie Nantel

Crystalline igneous rocks, known commercially as granite, are exploited in Quebec f rom more than twenty-five quarries for building, ornamental and monumental purpose$. Quebec is the main Canadian producer of construction granite, accounting for nearly 90 per cent of total production. Jn the last three years, this industry has experienced an important growth due to improved marketing and use of modern equipment in rock-cutting and polishing. Jn /983 a 35 per cent sales increase is forecast. The main rock varieties extracted are the following: porphyritic pinkish grey granite and green charnockite from Riviere-dPierre, mahogany brown granite and black anorthositic rock f rom the Lac Saint-Jean area, fine-grained pink granite from Guenette, coarse-grained brown quartz monzonitefrom SaintA lexis-des-Monts. All these rock types occur in the Grenville tectonic province whereas a medium-grained, light grey granite, Devonian in age, is extensively being quarried in the southern part of the Appalachians. In the Superior province a greenish black diabase and a deep red granite are extracted. Search for new varieties and deposits is actively being carried out by prospectors and by the minis/ere de /'Energie et des Ressources du Quebec following growing demand for granitic and gabbroic rocks as dimension stone.

Jan 1, 1984

By H. C. Gunnings, C. O. Swanson

"The Sullivan mine; at Kimberley in southeastern British Columbia; is the largest silver-lead-zinc mine in the Empire and one of the largest in the world.The original discovery was made in 1892 by four prospectors. Until 1899, when the branch line of the Canadian Pacific railway from Cranbrook to Kimberley was completed, little work was done on the property. In 1900, systematic development was started, and during the next 3 years 5,000 tons of ore was shipped to the smelters at Nelson and Trail. By 1903, some 300,000 tons of ore was developed, and a smelter was started at Marysville, about 5 miles from the mine. However, this smelter closed down in 1907 because of metallurgical difficulties after treating 75,000 tons, and the property came under the control of the American Smelting and Refining Company. An option on the property was taken in 1909 by the Consolidated Mining and Smelting Company of Canada, who exercised their option in the following year. During the next 5 years by selective mining and sorting 188,000 tons of high-grade ore was produced and shipped to Trail. This tonnage came from the upper levels, about 4,600 to 4,800 feet in elevation. At the same time, deep drilling down to the 3,900-foot level showed the presence of an immense body of complex ore. In 1915, the main adit-the 3,900-foot level-was started, and by 1919 this had been driven a distance of 2 miles to develop the ore above this level. Meanwhile, progress was being made in overcoming the milling problems. An interesting account of this work was written by the staff ( 4). In 1923, the first unit of the present concentrator was erected, with a capacity of 2,500 tons a day, and thereafter the rate of production increased rapidly. In 1934 it was around 8,000 tons a day, and to date a total of about 30,000,000 tons of ore has been sent to the mill. In recent years, a considerable part of the production has come from levels between the 3,900-and 3,350-foot, which were opened by an internal incline shaft started in, 1930. In 1942, tin was added to the products separated at the concentrator."

Jan 1, 1954

"Yara Siilinjärvi in Finland is the Western Europe's only apatite mine. Annually it produces one million tons of apatite concentrate, which creates 10 million tons of tailings. At the beginning of 2017, Yara replaced their conventional TSF with a new tailings treatment plant, which increased the solids content of the slurry from 45–48% to 66–68%, making it possible to deposit as a paste. This extended the life-span of the current TSF from 2020 to 2035. This paper presents the storyline of the Yara paste plant project. The project began with laboratory testing and then progressed to pilot-scale thickening and beaching trials. After successful pilot trials, the final process design was implemented. Process automation played a key role in the project. An advanced control system is needed to maintain process stability and the desired operation point in various operational circumstances. Since commissioning the paste plant has been running consistently with an underflow solids content of 66-68%, with average beach slope angles of 3.5 degrees in the tailings disposal area. Robust thickener operation also leads to the trouble-free high-density pumping and high availability of the plan. During first year of operation the plant’s availability has been very good, over 97%, and currently, the plant is operated remotely from the main concentrator plant.INTRODUCTION The Yara Siilinjärvi Plant is owned by Yara International, a Norwegian fertiliser company. Yara Siilinjärvi is Western Europe's only apatite mine, and it primarily produces apatite concentrate for its Siilinjärvi phosphoric acid plant. A portion of the concentrate is also dried and shipped to other Yara fertiliser plants. The site annually produces one million tons of apatite concentrate, which creates approximately 10 million tons of tailings. Extending the lifespan of the 1150-hectare tailings storage facility has been studied in Siilinjärvi for a long time. The aim has been to use the same tailings area footprint, without any new land purchases or major dam increases. An important part of the process has been to study the possibilities for using new technologies, especially thickened tailings technology (Ruhanen, 2014)."

Jan 1, 2019

By T. Verdel, Y. Gunzburger

Rockfalls are major and essentially unpredictable sources of danger, particularly along transportation routes (roads and railways). Thus, the assessment of their probability of occurrence is a major challenge for risk management. From a qualitative perspective, it is known that rockfalls occur mainly during periods of rain, snowmelt, or freeze-thaw. Nevertheless, from a quantitative perspective, these generally assumed correlations between rockfalls and their possible meteorological triggering events are often difficult to identify because i) rockfalls are too rare for the use of classical statistical analysis techniques and ii) all intensities of triggering factors do not have the same probability. In this study, we propose a new approach to investigate the correlation of rockfalls with rain, freezing periods, and strong temperature variations. This approach is tested on three French rockfall databases, the first of which exhibits an outstandingly high frequency of rockfalls (approximately 950 events over 11 years), whereas the other two databases are more typical (approximately 140 events over 11 years). These databases come from (1) the national highway RN1 on La Réunion Island, (2) a railway in the Bourgogne-Franche Comté region, and (3) a railway in the Auvergne region. Whereas a basic correlation analysis is only able to highlight an already obvious correlation in the case of the “rich” database, the newly suggested method appears to detect correlations even in the “poor” ones. Indeed, the use of this method confirms the positive correlation between rainfalls and rockfalls on La Réunion Island database. This method highlights a correlation between cumulative rainfalls and rockfalls in the Bourgogne region, and it detects a correlation between the daily minimum temperature and rockfalls in the Auvergne region. This new approach is easy to use and also serves to determine the conditional probability of rockfall function of a given meteorological factor. This approach will help to optimize risk management in the studied areas based on their meteorological conditions. Nevertheless, even if some rockfalls are correlated to meteorological factors, other seems to occur independently of these factors, which highlights the unpredictability of rockfall hazard.

Jan 1, 2015

By L. O. Thomas

THE Alaska Highway, in its course through British Columbia, traverses parts of two great physiographic divisions of Canada which are also distinctive geologically-the Cordillera in the western section and the Interior Plains in the eastern. The Cordilleran region in the portion of the Province with which this paper deals can be divided into four major northwest systems, known respectively from west to east as Coastal, Plateau, Cassiar-Omineca, and Rocky Mountains. The Coastal system consists solely of the Coast range except in the extreme northwest, where a part of the St. Elias range is included. The Coast range, characterized by mountains of great ruggedness,. is made up of an igneous complex of granitic rocks intruded chiefly as a great batholith. In places, spurs of these rocks extend into the Plateau heft, a partly mountainous tract largely occupied by quartzites, quartzose mica schists and their gneissic phases, and crystalline limestone with interbands and broad areas of chlorite, _hornblende, and sericite schists and bodies of intrusive granite gneiss-an assemblage of rocks known as the Yukon group. The Cassiar-Omineca system marks the divide between the Pacific and Arctic drainages. Its eastern boundary is well defined in the south by the Rocky Mountain Trench (see p. 229). The rocks of the system are, miainly, highly altered Palaeozoic sediments, but there are also Precambrian and Mesozoic rocks, the latter largely volcanic. The core of the system is granitic and there is evidence (see p. 221) to support the belief that it is of such a length as to constitute a batholith comparable to that of the Coastal system.

Jan 1, 1944

Iron deposits of every major type except laterite occur in Quebec, and form one of the major iron ore resources of the world. The five principal types of ore described are: (1) hematite-goethite masses derived from iron formation through the oxidation and enrichment of iron by natural processes; (2) taconites consisting of fine-grained iron formation; (3) metataconites composed of coarse-grained iron formation; (4) iron and titanium oxide minerals in massive or disseminateed deposits within gabbro and anorthositic rocks; and (5) replacement or contact? metasomatic magnetite deposits associated with complex silicate and skarn mineral assemblages. Most of the ore, although relatively low grade, is easy to concentrate. The physical properties of the ores that affect the choice and efficiency of beneficiation methods are described. The extent to which iron ore from this area can be utilized in the future will depend on the continued use and improvement of highly efficient methods of beneficiation.

Jan 1, 1964

By A. E. Moss

"IntroductionTHE WORLD-WIDE search for iron ore has been vastly accelerated during the past fifteen years .and Canada is playing a most prominent role in this prospecting boom. During this period, the search for .and development of iron ore deposits in Canada bas proven eminently successful and there is every indication that exploration will continue to be active for many years.This paper has been prepared primarily for the information of those who have bad little or no experience in iron ore exploration. For convenience, it is divided into three parts: ( 1) a brief discussion of the marketing of iron ores, with special reference to Canadian production; (2) a summary of the main features to be considered when prospecting for or evaluating a potential iron ore deposit; and (3) an outline of the methods and procedures used in the search for the direct-shipping iron ores in the Quebec•-Labrador iron ore field.The Iron Ore MarketDue to the tremendous tonnages of high-grade direct-shipping iron ore indicated in the iron ore fields of the Quebec-Labrador and Steep •Rock areas, it might be assumed that there would have been a sharp decline in iron ore prospecting in this country. On the contrary, the development of these two major fields, which must be classed among the world's greatest, has been responsible for much of the current activity. The search for high and medium grade magnetite deposits is being• conducted in many parts of the country and a number of these have reached the development stage. Production is being expanded from the known fields, such as Wabana in Newfoundland and Michipicoten in Ontario."

Jan 1, 1955

By T. Joseph, E. Zheng, M. Curley

"Hydraulic transportation efficiency and production optimization are considerations in the surface extraction of Athabasca oil sand deposits. To reduce the dependence on haul trucks, it is possible to extend the hydraulic transport system to production faces using a mobile at-face slurry system (AFSS). The flexible arrangement of connected pipelines transports slurried minerals from the mining face to the processing plant. An experimentally verified mathematical model indicates the friction loss of oil sand slurry associated with the AFSS. Laboratory-scale testing enables extended analyses for examining pipeline slurry transport in an oil sands environment.RÉSUMÉ L’optimisation de l’efficacité du transport hydraulique et de la production sont des considérations importantes dans le domaine de l’exploitation à ciel ouvert des gisements de sables bitumineux de l’Athabasca. Afin de réduire la dépendance envers les camions de transport, on envisage d’étendre le système de transport hydraulique aux fronts de taille à l’aide d’un système mobile de transport des matériaux sous forme de boue à partir du front de taille (AFSS, de l’anglais at-face slurry system). L’organisation flexible des conduites reliées permet le transport de minéraux à l’état de boue du front d’exploitation jusqu’à l’usine de traitement. Un modèle mathématique vérifié de manière expérimentale indique la perte de charge par frottement des schlamms provenant du traitement des sables bitumineux associée à l’utilisation de l’AFSS. Des essais en laboratoire permettent de mener des analyses approfondies portant sur le transport de boues dans des conduites dans un environnement de sables bitumineux. INTRODUCTIONObjectives and scope of studyThe at-face slurry system (AFSS) concept has become a competitive means for materials handling to optimize haulage system efficiency and cost. The mobile and flexible arrangement of the AFSS introduces a unique set of hydraulic transport problems. This paper will focus on developing the mathematical models governing the friction and head losses within the AFSS concept.Background of the problemLarge-capacity shovels and dump trucks are increasingly used for excavation, loading, and hauling in the operation of surface mining. Production cost and efficiency optimization are demanded during the Athabasca oil sands (Alberta, Canada) mining process to secure North America’s energy supply. Increasing haulage distances, rugged terrain, and a constrained mine environment are conditions that will reduce the effectiveness of the shovel-truck haulage system (Frimpong, Szymanski, & Changirwa, 2003). In such conditions, the tire heat index and weight, distance, and time limits for truck haulage can be exceeded, simultaneously creating extreme tire wear and high maintenance costs. In addition to low production cost and equipment effectiveness, a mining environment also requires efficient waste-material recycling and distribution. Waste materials need to be recycled from the processing plant to a new destination such as a tailings dam, or replaced in mined-out areas such as backfill. The Athabasca oil sands configuration and location characteristics result in a mining environment that would benefit from flexible pipelines for constant production and an efficient waste-material recycling process."

Jan 1, 2017

By M. Fan, H. E. Wyslouzil, J. Kohmeunch

Eriez HydroFloat(TM) separators and Canadian Process Technologies (CPT) flotation columns have been developed to overcome the limitations of traditional flotation cells in recovering coarse and fine particles, respectively. The flotation column can effectively separate 30-5 µm phosphate. Several industrial-scale HydroFloat separators have been installed in phosphate and potash beneficiation plants. Industrial-scale ultra-coarse (+850 µm) phosphate separation results suggest that a more-than 40% BonePhosphate- of-Lime (BPL) recovery increase and a 37% collector consumption reduction can be achieved. The paper describes the applications of Eriez HydroFloat separators to coarse particle separation and the CPT flotation column to fine/ultrafine particle flotation.

Jan 1, 2009

By K. D. Bulin

"An interesting brief history review of shovels as the primary excavating tool will permit the reader to see that immeasurable development and resources have preceded the shovel excavators which today are used extensively throughout the mining industry. With this as a background, the shovel manufacturer has the ability to utilize his resources best in those areas of shovel development in which the maximum benefits of increased reliability, performance and ease of maintenance will improve the operating rewards to the user of the equipment. The author explains the function of the shovel as a part of the material handling system. A detailed description of those areas of the shovel in which the most recent developments and major improvements have been implemented in the manufacture of the shovel excavator arc included."

Jan 1, 1973

"The Val d'Or Division now comprises the Lucien C. Beliveau Mine and Concentrator (formerly the Pascalis, described below) and the Chimo Mine. Cambior acquired an initial 50% interest in the Chimo Mine in May 1989 and the remaining 50% in April 1990. Cambior's share of 1989 production was 2121 ounces; the company expects to net 23 750 ounces from Chimo in 1990. Pascalis MineUPDATERenamed the Lucien C. Beliveau Mine at its official inauguration in September 1989, the mine is exceeding forecasts, producing over 11 500 ounces of gold in the first half of 1990. Cambior expects 1990 production to total 34 000 ounces.IntroductionThe Pascalis Mine is located 16 miles east o f Val d'Or, Quebec, and is accessible by a three mile gravel road off highway 117 (Fig. I).The property is wholly owned by Cambior.The Pascalis gold deposit consists o f a sub-vertical diorite dyke 1000 ft long by 30 ft wide containing quartz and tourmaline veins with inclusions of pyrite and native gold . Three vein systems ca n be seen in the deposit , the most important being tensile veins oriented at a right angle to the direction of the dyke and inclined at 40 degrees. These overlapping veins vary in thickness from 4 in. to 40 in. and occur at intervals of six to ten ft. The deposit is, therefore, very difficult to evaluate; a complete evaluation would require drifts over the whole width of the dyke combined with relatively short drill holes (Fig . 2)."

Jan 1, 1990

By Fred W. Snow

THE mines of the Consolidated Copper and Sulphur Company, consisting of the Eust1s, the Albert, and the Capel mines, are situated w Ascot township, Quebec, about ten miles southeast of Sherbrooke, on the main line of the Quebec Central railway. Of these mines, only the Eustis is now producing, and it has been operated almost continuously for the past seventy years. Mining methods have been improved in recent years but are still old fashioned when compared with those employed in more modern and up-to-date mines. The ore is of milling grade and is mined for its copper and sulphur con-tent. Silver is present in small quantity, together with a trace of gold. The ore is mined by the shrinkage stope method. Pillars are frequently left as supports for the hanging-wall to prevent serious dilution of the ore and are sometimes recovered after the ore is drawn from the stope. Occasionally, small blacks of ore in close proximity to the shaft are mined by a cut-and-fill method. HISTORY ALBERT AND CAPEL MINES: The Albert and the Capel mines, originally known as the Capelton mine, were discovered in 1863 by George Capel (1). By the end of 1866 the Albert shaft had been sunk to a depth of 121 feet on an incline of about 30 degrees where a vein five feet thick was encountered. In 1879, these mines passed into the hands of G. H. Nichols and Company, by whom they were operated practically continuously until 1907. When mining operations ceased in that year, the shafts had reached depths on the incline of approximately 2,300 feet and 1,000 feet, respectively. These mines have been allowed to cave and fill with water and have been inaccessible for many years.

Jan 1, 1936

By M. S. Fotheringham

Recognition of the Growing Importance of Iron and Steel Few Canadians have yet become aware that Canada's vast iron ore resources, the greater part of which is only now beginning to be developed, will inevitably have a profound effect on the entire Canadian economy, benefitting in some measure the lives of all Canadians. The great iron mining developments of Ontario, Newfoundland, Quebec, and Labrador are destined to make Canada one of the world's major producers and exporters of this material, on which our industrial civilization is?based. These developments will create new employment, new communities, new transportation facilities, and new investment opportunities. Iron ore is the foundation and the keystone of modern mechanized civilization. The most prosperous nations of the world are the highest per capita consumers of iron and steel, and in these countries the per capita consumption is increasing steadily despite the advent of light metals, plastics, and other competitive materials. Three-quarters of the human race have too little steel -and consequently too little mechanization -to provide for themselves the necessities and comforts of civilized living. Progressively they will demand, and acquire, the machines, the transportation and communication facilities now lacking, and they will win them by making greater use of the world's iron resources. It is the good fortune of this generation that Canada's 'iron age' is just getting well under way.

Jan 1, 1951

By R. Hammen, J. Lifton

"The purification of rare earth elements (REE) at mining operations is traditionally accomplished by multiple chemical phase-transfer processes including precipitation, solvent extraction, and ion exchange. We describe REE purification results with Solid Phase Extraction (SPE) columns that were developed to improve the speed and economy of REE purification. The SPE columns have the properties of enhanced equilibration kinetics, so that residence time of a few seconds will accomplish selective chemical transfers from solution phase to solid phase. We describe the separation of REE’s as a class from leach solutions and the further purification of REE salts. INTRODUCTIONHistorically the rare earths were first chemically separated from each other and purified by fractional crystallization. This slow, cumbersome, and laborious process was not suited to commercial production. Solvent Exchange (SX) technology was applied to the problem of separating and purifying the rare earth elements when it was determined in the late 1960s that there might be commercial uses for them individually. At the same time the very slow and expensive technique of ion exchange was applied either for ultra-purification of the desired “light” rare earths, or for the recovery and purification of the tiny amounts of higher atomic numbered, “heavy,” rare earths. Solvent Exchange (SX) has today become the standard for separating the rare earths across their atomic number spectrum. Whereas the separation of the light rare earths commercially may take 30 “cascades’ in a modern Chinese plant, the total separation of all of them from each other may take up to 80 such “cascades,” and is only even “practical’ with preconcentrated feed stocks, such as those produced in China by heap-leaching techniques performed in situ on very low grade radio-nuclide free ionic absorption clays.. Ultra-pure materials of all types are produced today by ion-exchange processing of ionic species already separated by solvent exchange.Hard rock deposits and refractory residues of tin mining and residues from uranium mining have been identified outside of China with very high ratios of dysprosium and other heavy rare earths to the majority lighter ones. Several issues face those who wish to process these materials so as to separate the heavy rare earths commercially:"

Jan 1, 2012