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By T. Plikas, T. Porretta, M. Al-Dojayli, B. Pretorius, J. Woloshyn, H. Ghorbani

"Water-cooled ducts represent an integral part of high temperature off-gas systems in metallurgical processes. Typically, off-gas enters these ducts at significantly elevated temperatures; therefore, water cooling may be required to maintain the duct skin temperature within allowable design limits. These off-gases are typically of high mineral content that could lead to dust buildup, and there is a possibility of slag buildup / molten metal splashing. Therefore, dust cleaning provisions may be necessary in order to remove or minimize accretion on the duct wall, which could otherwise impact the water cooling and the system process efficiency. These ducts may have complex geometry and experience a wide range of loading, including gravity loads, water and gas pressures, cyclic thermal loading and dynamic impact forces. Consequently, the thermo-mechanical assessment of such water-cooled ducts is critical and requires consideration phenomena such as high temperature gradients, potential nucleate boiling, thermal ratcheting and fatigue failures. Such assessment is not comprehensively covered by design-by-rule design codes and guidelines due to its complexity. This paper presents a successful implementation example of design-by-analysis methodology to improve the design and extend the life of a water-cooled furnace transition duct using Computational Fluid Dynamics (CFD) and Finite Element Analysis (FEA).INTRODUCTION Water-cooling represents an important part of high temperature off-gas systems in metallurgical processes. Typical temperatures of the off-gas in the furnace uptake are in excess of 1400°C, and thus there is a need to maintain the water-cooled duct and jacket skin temperatures within their material allowable design limits. Water-cooled channels have been used effectively in arc furnace roof design (Sosonkin et al., 1972; Smolyarenko and Khainson, 1988) and other furnaces as well as in furnace fuming jackets (Scholey et al., 1994). The design of these systems was based on one-dimensional analysis to ensure sufficient cooling is available under extreme furnace conditions (Smolyarenko and Khainson, 1988; Scholey et al., 1994). With advancement in furnace and fuming system designs, water-cooled duct designs have become more complicated in geometry. Numerical techniques, such as three-dimensional fluid flow and heat transfer modeling, are therefore needed to more accurately calculate water velocity, temperature and convective heat transfer coefficients in the water-cooled channels (Haywood et al., 2002; Henning et al., 2010). This is of particular importance around geometric corners where stagnant water flow may lead to local nucleate boiling at the critical heat flux, causing hot spots (Bergman et al., 2011). High wall skin temperatures increase the risk of failures due to thermal stresses as well as increasing corrosion rates (Gelfi et al., 2012), leading to costly equipment downtime and potential safety risks."

Jan 1, 2017

By T. T. Chen

The iron- and elemental sulphur-rich residues generated during batch and continuous pressure oxidative leaching of Inco Limited's Voisey's Bay nickel sulphide concentrate at 150°C in sulphate-chloride media have been characterized by X-ray diffraction analysis and scanning electron microscopy. The residues produced during the continuous leaching of the pentlandite- and pyrrhotite-rich concentrate consisted predominantly of hematite and elemental sulphur, with minor amounts of goethite. Although the iron species generated in the batch leaching tests were similar to those formed during continuous leaching, the morphologies of the hematite and goethite particles were significantly different. In addition to the tiny spheroids and bubble-like particles, the hematite and goethite generated during batch leaching occurred as larger "hollow" shell-like particles that contained residual pentlandite or sulphur cores. Although the leach solution from which the iron oxides had precipitated contained 5-15 g/L sodium, sodium jarosite was detected only in trace amounts in a few of the leach residues.

Jan 1, 2006

By N. W. Hendry

ABSTRACT Exploration by geophysical methods and diamond drilling of an occurrence of chrysotile asbestos, located ten miles east of Matheson, Ontario, was commenced on March 25th, 1949, by the Canadian Johns-Manville Company, Limited. The asbestos is associated with a narrow sill-like body of basic and ultrabasic rocks which strikes northwesterly across portions of Munro and Beatty townships. To date, asbestos zones of commercial interest, many hundreds of feet in length, width, and depth, have been outlined by diamond drilling along a 2-mile length of serpentine. The fractures occupied by the asbestos veins are closely associated with the regional faulting in the area. The mining of the first occurrence, or A orebody, will be by open-pit methods. Milling will commence at a rate of 50 tons an hour. INTRODUCTION OCCURRENCES of chrysotile asbestos in Munro township have been known at least since 1914 and references to them appear in reports published by the Ontario Department of Mines in 1915 (1) and 1919 (2). J. G. Ross (3) in his excellent publication on Chrysotile Asbestos in Canada, mentions an occurrence in Munro township. The area was first mapped in detail by J. Satterly, of the Ontario Department of Mines, in 1944, and brief mention is made of chrysotile asbestos in Satterly's preliminary report (4), which was published the following year.

Jan 1, 1951

By Yongjie Bu, Wei Sun, Zhiyong Gao, Yuehua Hu, Hongbiao Tao, Runqing Liu, Central South University

"The flotation behavior of O-isopropyl-N-ethyl thionocarbamate (IPETC) and pH for chalcopyrite and galena was studied through pure mineral test, adsorption quantity determination, solution chemistry calculation and Materials Studio simulation. The results show that the recovery differential value of chalcopyrite and galena is about 20% when pH of the pulp 9.5 and IPETC is 7×10-4 mol/L, the flotability differences of the two minerals is significant. There is competitive adsorption between OH? and IPETC on mineral surfaces, it lead to galena flotability is lower than chalcopyrite flotability. IPETC can remove the hydration layer on mineral surface and adsorb on active sites for collector adsorption, minerals have a better hydrophobicity.INTRODUCTIONCopper and lead are two of the most widely used metals in industrial and living, their applications include building construction, various metal alloys, heat and electricity, machine manufacturing (Zhang et al., 2014). Chalcopyrite and galena are the major source of copper and lead, normally they associated with each other. With the growing use of these resources, high grade and dissemination large particle sizes minerals are less and less, the use of low grade and complex dissemination minerals have to be paid more attention (Chen, Ye, & Li, 2010; Liu, Sun, Hu, & Wang, 2009). As the special properties and complex composition of copper-lead sulfide ore, flotation separation of chalcopyrite from galena effective is a research emphasis and difficulty point in mineral processing (Bruckard, Sparrow, & Woodcock, 2011).In the separation process of chalcopyrite and galena, it is rather important to choose effective collector (Huang, Wang, & Liu, 2014). Enlarging and using the two mineral flotability will be a good basis and start in flotation (Reyes-Bozo et al., 2014). Qin et al. (2013) made a great deal of research on flotation separation of copper/lead concentrate, collector O-isopropyl-N-ethyl thionocarbamate (IPETC), butyl xanthate (BX) and ammonium dibutyl dithiophosphate (ADTP) were investigated, BX and ADTP floated both chalcopyrite and galena well, specific adsorption appeared in the surface of mineral, the problem was the collectors were not selective enough, however IPETC showed better selective."

Jan 1, 2016

By J. G. Stevens, S. W. Colley

"Selective separations of metals and ions in mineral extraction and refining are becoming more challenging as ore bodies become more complex and environmental pressures increase. The separation and containment of mercury produced in gold mining are a factor in the profitability and operability of mines. This paper will discuss the development and implementation of the Johnson Matthey HgFree selective mercury removal process. The process is designed to selectively recover co-leached mercury from either heap leach pregnant solutions at ambient temperature and low mercury concentrations, or electrowinning pregnant solutions at elevated temperature and high mercury concentration, without affecting gold or silver recovery. The process utilizes a highly selective adsorption-desorption step in which mercury is removed quantitatively by the HgFree adsorbent without adsorption of gold, silver or other metals present. Development of the original HgFree adsorbent has resulted in a process whereby mercury can be recovered as an inert salt and is never present as the free metal. The HgFree adsorbent can be regenerated and recycled in situ, and is capable of being reused multiple times. The overall process is compatible with existing gold mining and recovery practices and offers significant environmental and sustainability benefits, including reduction or elimination of the need to retort mercury with a subsequent reduction in potential mercury air emissions. Development of the HgFree adsorbent and process will be discussed along with a pilot operation at two operating mines.INTRODUCTIONMany gold ore bodies contain high concentrations of mercury which when extracted with cyanide, co-extract with the gold and other metals. This mercury is carried through the process with the gold, posing environmental and technical issues when it is separated from the doré. This paper describes a method to selectively adsorb mercury from the gold recovery circuit while it is in a soluble form, leaving gold to be processed as normal. The removal of mercury from the circuit eliminates the need for mercury retorting of doré and so reduces the potential environmental impact of fugitive emissions of elemental mercury."

Jan 1, 2016

By Takao Oishi, Go Ohara, Toru Kitazaki, Masahiro Tanaka

"The High Pressure Acid Leach (HPAL) plant for nickel-cobalt mixed sulphide production at Coral Bay Nickel Corporation (CBNC) in the Philippines has been in operation since 2005 with a capacity of 10,000 t/year of nickel. Subsequent to the commissioning of the second plant in 2008, the production capacity increased to 22,000 t/year of nickel (Llerin et al., 2011). CBNC’s annual nickel production reached more than 24,000 tons of nickel in 2014. The concepts to achieve this capacity are the high availability and the reciprocally flexible operation of both plants. The availability depends on some factors, such as the control of impurities in the process and the equipment condition, to mention a few. In the HPAL process, it is not only the autoclave operating conditions that affect nickel extraction but also the impurities in the ore greatly influence it. The major element in the ore is iron and most of this iron is precipitated as Fe2O3, while the rest remains as Fe2+ or Fe3+ sulphate in solution. These ions in solution reduce the availability, so it is important to control the formation of iron ions by controlling the impurities in feed ore as well as the HPAL conditions. This paper presents the general HPAL process and the behaviour of impurities, focusing on iron behaviour in the HPAL process.INTRODUCTIONCoral Bay Nickel Corporation ProfileCoral Bay Nickel Corporation (CBNC) was founded on April 2002, as a joint venture of four companies; namely, Mitsui Corporation (18%), Sojitz Corporation (18%), Nickel Asia Corporation (10%) and Sumitomo Metal Mining Corporation (SMM) with a controlling stake of 54%. Aside from its capital share, Nickel Asia Corporation also supplies the ore and limestone for the High Pressure Acid Leach (HPAL) plant located in Rio Tuba, Philippines, as shown in Figure 1 (Tsuchida, 2008). The objective of the CBNC project is to produce 22,000 t/year (original design) of nickel and 1,500 t/year of cobalt, as sulphide, by the treatment of nickel laterite ore which is a low grade nickel oxide ore in the Philippines (Mines and Geosciences Bureau, 2014). The sulphide product has been exported as a raw material to the SMM Nickel Refinery in Japan for 30 years. The product of this plant, a mixed (Ni/Co) sulphide, is shipped to the SMM’s Nickel Refinery in Niihama, Japan. SMM Corporation provides the technology and management personnel to the plant. SMM Corporation also supplies the sulphuric acid, which is the main reagent for the HPAL process."

Jan 1, 2016

By R. E. Legg

This paper gives a brief outline of the mining and milling methods which will be used on the Stirling zinc-lead-copper ores by Stirling Mines, Limited, who have for the past two years been developing the Stirling mine in Richmond county, Nova Scotia, and who will bring the mine into production in November, 1929. No attempt has been made to give the paper a detailed technical character, for the main reason chat, since base-metal mining is something new in Nova Scotia, it is felt that a general description would be preferable before this Society, whose membership is mainly made up of chose engaged in the coal mining and associated industries. Furthermore, as both mining and milling operations will be governed to a certain degree by the experience gained after production commences, there are many points which cannot be definitely stated now. GEOLOGY Before discussing the mining methods, it is desirable to present a general picture of the geology and occurrence of the ore-bodies. The surface rocks in the vicinity of the mine consist of rhyolites of .pre-Cambrian age. These volcanic flows outcrop in very few places, usually along' the beds of creeks or on the shores of the numerous small lakes. Consequently, a detailed geological map is not available. The exploration work carried out to date has revealed a sheared zone extending through the volcanic flows for a distance of over 1,000 feet. Along this zone, there has been a replacement of the rhyolites by a carbonate rock for widths varying from 50 to 230 feet, and it is in this carbonate formation chat the mineralization at a later date took place.

Jan 1, 1929

By T. H. Wilson

In 1901, the Crow's Nest Pass Coal Company, Limited, began producing industrial coke in 212 beehive ovens at Michel colliery. By 1908, 486 ovens had been installed and in that year 147,623 tons of coke were produced. Coke manufacture has been continuous from 1901 until the present time (1946), with total production of 2,795,402 tons. At present writing, only 100 beehive ovens are operating and production is reduced to 1,800 tons per month, due to the shortage of suitable labour. These ovens are drawn by hand, on contract, and the workmen are exposed to considerable heat. A man draws three ovens in eight hours, thereby producing approximately 1072 tons of coke per day. In addition to the inefficient and costly method of drawing coke in beehive ovens, tremendous losses are experienced in the wastage of gas and tar, which are driven off into the atmosphere. Also, the yield of coke per ton of coal fed to the ovens is low as part 9f the carbon is utilized in producing heat to carbonize the remainder of the coal. A recovery of only 55 per cent of the carbon, as coke, is obtained. The coking process takes place from the top of the charge, which is 21/2 feet deep, downward to the floor. Six and a half tons of coal are charged and 3.6 tons of coke are drawn from the oven after 72 hours' carbonization. The beehive ovens using Michel coal produce a very hard and tough coke, large in size and of silvery appearance, which has served the requirements of both foundry and smelter for many years. In 1938, the Company made a careful study of coking processes with a view to introducing a more economical method than beehive ovens and one that would be less dependent on skilled labour, the supply of which was rapidly diminishing at that time. Various methods of by-product coking were investigated, and it was decided that the Curran-Knowles process offered the greatest possibilities because of the low capital investment in relation to output and also because the horizontal oven design was suitable for an expanding coal. Consequently, a test on Michel B seam coal, supervised by Mr. E. Burrough, of the Fuel Research Department, Ottawa, was run in the Curran-Knowles plant at West Frankfurt, III. The results of this test led to the construction of a ten-oven battery of 32 ft. 6 in. by 8 ft. 3 in. Curran-Knowles ovens at Michel, which were completed in November, 1939. This battery was built as an experimental unit, with provision for an additional ten ovens if the coke proved satisfactory for the market. In 1942, an expanding coke market led to the construction of a second battery of ten ovens, which were completed in April, 1943.

Jan 1, 1947

By J. P. Wiser

THIS paper discusses testing and quality control of milled asbestos fibre. It has been composed with the intention of: (I) Summarizing past, present and probable future methods of testing and classifying the various grades of commercial asbestos produced by the Quebec asbestos industry. (2) Acquainting those unfamiliar with the methods used for evaluating, testing and controlling the grading and the quality of Quebec chrysotile asbestos fibres with some of the physical and chemical procedures currently used for that purpose. (3) Discussing some of the complications facing the producers, such as variations in the orebody and special requirements of asbestos manufacturers. ( 4) Detailing some of the present quality control methods. SUMMARY OF PAST, PRESENT AND PROBABLE FUTURE TESTING METHODS Past During the first years of production of commercial asbestos in the Province of Quebec, fibre testing and quality control were based principally on dry screen analysis and visual inspection. These methods were gradually expanded during the period from 18, 90 to 1932. In 1932, standardization

Jan 1, 1962

By M. W. Mikhail, R. J. Mikula

"Funding has been made available through the National Energy Program to build a mobile fine coal treatment plant. The plant is intended f or field application and also to upgrade the existing pilot plant facilities.Western Canadian coals with high proportions of fines (due 10 their friability) cause high losses of fine coal to the reject and in turn reduce the over-all recovery of saleable coal. Eastern Canadian coals with high amounts of sulphur of ten require crushing to fin e sizes to liberate pyrite and therefore need effective and efficient separation of these fine sulphur particles. The difficulties involved in solving these problems are two-fold. One is the reluctance to experiment in an operating wash plant and the other is that laboratory scale testing often cannot be extrapolated to the plant environment. The mobile fine cleaning plant with its ability to operate at existing coal preparation plants across Canada and with its flexibility in implementing flowsheet option s and close monitoring of fine coal circuit variables, is ideally suited to solve these fine coal cleaning problems. The mobile plant objectives are to design and optimize flowsheets, evaluate and improve fine cleaning circuit operations and 10 lest new process monitoring and control equipment.The schedule for construction and the required resources will be outlined along with flowsheet options and the general R&D philosophy of the mobile plant.IntroductionIn relation to coal preparation technology, Canadian coal s can be grouped as Eastern coal, Rocky Mountain metallurgical coal and Foothills high volatile bituminous coal. The eastern coals have high sulphur contents and in some cases require crushing or even grinding to liberate the fine pyrite . Rocky Mountain metallurgical coals often occur in highly sheared seams which have been subjected to rapid coalification. The high friability of these coals means that degradation during mining, handling and processing is extensive and results in large amounts of fine s ranging between 20 and 60% by mass of the wash plant feed. The widely varying geo logical structure and exposure to the elements results in partially oxidized coals which perform inconsistently in the traditional method of fine cleaning by flotation . Foothills high volatile bituminous coals for thermal use are frequently interbedded with soft shales and bentonitic clays. These clays disintegrate during washing and swell, producing large volumes of tailings. The presence of clays in plant circuits, particularly fine circuits, tends to increase the viscosity and may cause deterioration of the fines density separation and increase magnetite losses. In view of the fact that fine coal cleaning is the most difficult aspect of coal preparation , a research program is being established to study the factors involved and to offer some solutions.A recent performance evaluation of Canadian washeries showed that yield losses in the minus 2 mm coal circuits were approximately ten times those occurring in the coarse coal circuits(1). Because 2 mm x 0 coal represents 30 to 70 per cent of the raw coal, these losses can be considerable . The operating and capital costs of beneficiating minus 6 mm coal are about four to five times higher than for plus 6 mm coal. In the case o f minus 2 mm coal the costs are even higher. The economic importance of the fine coal cleaning cannot be over emphasized and as a result, the CANMET R&D program is geared for fine coal beneficiation."

Jan 1, 1984

By F. Liu, S. Rezaei, M. Muinonen, M. Barati, V. L. Lakshmanan, S. Marcuson

Canadian nickel-copper ore deposits have been a major source of nickel, copper, cobalt and precious metals for more than 100 years. The two main minerals of interest, pentlandite (Pn, (Ni,Fe)9S8) and chalcopyrite (Cp, CuFeS2), are usually accompanied by large quantities of pyrrhotite (Po, Fe1-xS). Until the 1950s, Po containing small amounts of nickel was routinely smelted as part of the valuable Ni concentrate. The rapid growth in Ni demand following the Second World War created impetus to treat the Po separately. This action would liberate a valuable smelting capacity for higher value Pn, allow for recovery of Ni locked in Po, convert the Fe to iron oxide or metallic iron pellets, and recover S as sulphuric acid or elemental sulphur. The roasting process also has the potential to produce energy due to the highly exothermic oxidation of Po. The Ni industry would then have a “waste-free” process. Both Inco (now Vale) and Falconbridge (now Glencore) developed processes and built large industrial plants for this purpose that operated with some success. But technical issues and tenuous economics were continual challenges. By the early 1980s these industrial operations were closed. Sophisticated froth flotation methods of rejecting Po were developed, and Po containing up to 1% Ni became a waste material reporting to the tailings stream. As part of a major study on possible processing methods of Po for both value recovery and waste remediation, this paper presents a historical perspective on Canadian Po tailings with regards to their generation, inventory, value, and attempts to process them.

Jan 1, 2017

By T. V. Simpkinson

Abstract A brief history of the electric arc furnace process of steel-making is given. The greater relative importance of this method of steel manufacture to the Canadian steel industry, as compared with its importance in the steel industry of the United States, is shown. The scope of the process is outlined and brief mention is made of the difficulty of obtaining melting stock low in alloy content. The physical chemistry of steel-making is discussed at length in simple terms, with emphasis on oxidation, de-oxidation, and the role of hydrogen. Carbide-type and silicon-type slags are described and the particular usefulness of each is outlined. The importance of various factors in the melting practice is evaluated on the basis of practical experience. Introduction Although electric furnace steels constitute only a small portion of the total weight of steel used in industrial operations, their importance is relatively much greater than is indicated by comparative tonnage figures. Tool steels, which are vital to all industry, are made almost exclusively by the basic electric arc furnace process, as are stainless steels, valve steels, and the higher alloy types of the class usually referred to as "alloy steels'. For many applications where steel other than electric furnace quality is often used, and when first cost is secondary to performance in service, the extra steel cost of electric furnace quality material is usually returned with interest by consistently longer service life. The electric furnace is pre-eminent in the quality alloy steel field because of the control that may be exercised over conditions of oxidation, de-oxidation, and temperature, the fundamental operations in steel making.

Jan 1, 1948

By G. Vibert Douglas

It often happens that the field geologist encounters a fault in ground where there is little to guide him with regard to the throw, or vertical displacement, and the heave, or horizontal displacement. The following construction gives both of these components of the fault, and the writers hope that it may prove a help to others. The construction is applicable to both normal and reversed faults. Briefly the procedure is as follows: Take a point which is common to the faulted geological feature and to the fault plane and on the downthrow side of the fault. Move this point in the horizontal plane in the direction indicated by the fault striæ. Rebat the point down to the plane of the fault and obtain its throw. Next consider the other side of the fault and truncate it down by the amount of the throw just determined. Then project the line of the geological feature through to the trace of the fault-plane at the lower horizon. The result is the relative positions of the two parts of the original geological feature as severed by the fault. In Figure r, let us consider a typical normal fault, that is, a fault in which the hanging-wall has gone down relative to the footwall. This characteristic, or its alternative, the reversed fault, is determined by observation on the ground. Let AB be the line of any geological feature such as the edge of a dyke, vein, or bedded sediment. The plane of which AB is the trace may have any dip; in the present case let us say 70° right. Let FF be the trace of a fault-plane which may have any dip; let us say 35° left in this case.

Jan 1, 1928

By A. J. Ouellet, A. Coulombe, B. Salmon

The no. 7 vein system cuts the Ventures gabbro which has undergone folding and fracturing; the latter, in response to movement on the nearby Campbell Lake fault. It fills a shear fracture which pinches and swells in the upper mine levels but has a more uniform width in the lower levels. The best copper and gold grades in the upper levels occur in the widest parts of this structure. The vein is richer in quartz on upper mine levels and in carbonate on lower levels. The north wall of the vein is more affected by major and minor element wallrock alteration than the south wall. The isocumulative ci;rves for gold and copper show a direct correlation between the two metals in the upper levels and their increased concentration in the wider parts of the vein. Gold grade decreases in lower levels. A proposed structural model identifies the no. 3 and no. 7 veins as second order conjugate fractures, related to the Campbell Lake fault. The fractures pattern suggests that a conjugate system developed between these two parallel veins as a consequence of rock competence and a relatively low confining pressure.

Jan 1, 1984

By Shin-Kun Ryi

The world nowadays faces many challenges associated with excessive utilization of fossil, fuels, such as poor air quality and greenhouse gas emissions. Hydrogen appears to be an attractive alternative to the conventional, fossil, fuels with better energy efficiency and less environmental, impact. Pd and Pd-based alloy are the most often used membranes for hydrogen separation due to their superiority over other membranes. However, the stability of the commonly-used thin Pd-based composite membranes at high temperatures still, remains a big challenge. In this presentation, we will, report our progress on thin Pd-Ru alloy composite membrane by electroless plating high temperature applications.

Jan 1, 2010

By A. Anderko, V. G. Papangelakis, G. Moldoveanu, G. Azimi, M. Carlos

"OLI Analyzer is a software package that uses the powerful Mixed Solvent Electrolyte (MSE) model to simulate the behavior of multicomponent electrolyte solutions from infinite dilution to the limit of fused salt, and from temperatures below the freezing point up to near critical temperature of the mixture. The software also allows the creation of thermodynamic parameters for new chemical systems unavailable yet in public-domain or commercial software databanks. This communication reviews the basics of the model and provides some examples of modeling hydrometallurgical applications with emphasis on high temperature applications, including calcium sulfate scale formation in autoclaves, high temperature pH inference and iron control. INTRODUCTIONModeling of electrolyte systems has been of particular interest to various industrial processes, such as separation processes (e.g., solution crystallization, extractive distillation, seawater desalination or bio-separations), environmental applications (e.g., gas treatment, wastewater treatment or chemical waste disposal) and hydrometallurgy (e.g., pH control and neutralization, iron control, scaling and fouling of equipment). Using a chemical model, time-effective predictions of various properties of electrolytes can be obtained, which is beneficial not only during process monitoring, but also during process optimization and process scale up. As a result, pilot scale studies can sometimes be eliminated where budgetary constraints exist. Development of such a powerful model requires the use of a speciation-based model, in which solution chemistry is explicitly addressed (as compared with some models that treat electrolytes either as undissociated or fully dissociated systems), despite being computationally challenging. In addition, as a feature of electrolyte systems, speciation equilibria inherently influence the phase equilibria due to complex formation, ion pairing, and acid-base reactions. Therefore, how the electrolyte solutions behave at various conditions may differ significantly due to the non-ideality, which must be carefully addressed to obtain a model that is applicable to a wide range of conditions such as concentration, temperature, pressure and solvent system."

Jan 1, 2012

By José L. Carvalho

"Time-dependent swelling deformation of several shaley rock formations in Ontario is a wellknown phenomenon. In shales and mudstones with a higher salt concentration in the pore fluid than the ambient fluid, the outward gradient generates an osmotic pressure which acts as the driving force for swelling. The swelling phenomenon appears to be related to ion exchange between the rock porewater and the surrounding water.The swelling potential is expressed as the percent swelling strain that occurs per log cycle of time, in either the vertical (perpendicular to bedding) or horizontal (parallel to bedding) directions. In addition, the swelling potential is also noted to be stress dependent. In practice, therefore, the conditions required for swelling are (i) the accessibility to water, and (ii) an outward salt concentration gradient from pore fluid of the rock to the ambient fluid. The relief of in-situ rock stress during excavation serves an initiating mechanism (Lo and Micic, 2010).INTRODUCTIONTime-dependent swelling deformation of several shaley rock formations in Ontario is a well-known phenomenon. In shales and mudstones with a higher salt concentration in the pore fluid than the ambient fluid, the outward gradient generates an osmotic pressure which acts as the driving force for swelling. Swelling is also controlled by the inter-particle bonding; if the bond strength exceeds the osmotic pressure, swelling will not occur, and vice-versa. The bond strength can be reflected by the calcite content which forms cementation bond between rock particles."

Jan 1, 2015

By C. Dupuis, P. Waite, S. Leboeuf

Casthouses throughout the aluminium industry commonly use chlorine gas as a fluxing agent for furnace and in-line treatment of molten aluminium alloys. Its positive impact on the removal of alkali elements and non-metallic inclusions is well known. Nevertheless, the elimination of its use is highly desirable due to the safety and environmental risks associated with storage and handling. Over the past decade, the aluminium industry has significantly reduced its chlorine consumption. This has been achieved by maximizing the chlorine gas utilization efficiency during metal processing, and by the chlorine replacement for crucible and furnace metal treatment applications. Operation of sealed in-line treatment units without chlorine is now possible, but with lower or inconsistent removal efficiency penalties for alkali and inclusions respectively. This paper reviews the progress made at Arvida Research and Development Centre regarding the reduction of chlorine and the development of an alternative to chlorine for in-line metal treatment without penalizing the metallurgical performance.

Jan 1, 2006

By A. Blackmore, D. Baker, L. Human

"Mechanical mixing equipment is common in a wide variety of mining, metals and process applications, such as hydrometallurgical reactors, solvent extraction, digestors, and tanks for storage of slurry or hydrocarbons. Computational Fluid Dynamics (CFD) has been applied successfully to single-phase mechanical mixing problems for several decades and is established as a reliable design tool. As computational power and CFD codes have improved over the years, there have been significant advances in modelling capabilities including improved models of turbulence, interaction of rotating and stationary components, multiphase flows, and modelling of free surface interfaces, for example. This paper will provide an overview of the application of CFD to mechanical mixing problems. First, it will review the traditional single phase Multiple Reference Frame (MRF) approach and introduce a range of advanced modelling techniques. Three examples of the application of CFD to industrial mixing problems will be given. It will be demonstrated that CFD is an effective tool for reducing technical risk in design, for identifying the root-cause of mixing problems, and testing modifications to existing operations."

Jan 1, 2015

By M. S. Badollet

"The study of the physical properties of asbestos minerals requires a careful isolation of the fiber from the wall rock and, at a later stage, a comparison of these physical properties with those of fibers that have passed through the milling and beneficiation processes.The effects of mineral impurities, loss of fiber length and the formation of extreme fines (asbestic and/or associated minerals) often show up in the formation of special asbestos products as well as in the commercial production of asbestos papers, mill-boards, asbestos cement products, plastics and insulation materials, and in the filtration of blood plasma and wines.Numerous test methods have been developed in Canada and in England for use in the asbestos industry. Special treatments of asbestos fibers have been used to improve their physical and chemical properties and to eliminate impurities.Numerous problems connected with the use of asbestos fibers are discussed, such as the effects of asbestos on filtration, surface area, surface treatments using organic or inorganic materials, the surface charge on the fiber, the presence of magnetite and air pollution elimination. Biological studies on finely ground asbestos, when dispersed in 0.9 per cent sodium chloride solution and then sterilized and injected into hamsters, show that by reducing the dose, the tissue damage can be largely avoided. In these experiments, Arizona asbestos fibers were carefully extracted from the wall rock, finely ground, and examined chemically and micros-copically for any mineral impurities that might be present so that any effect on the hamsters would be directly due to the presence of the asbestos. The harsh Arizona fiber induced more extensive tissue response than the soft fiber when tested in hamsters."

Jan 1, 1969