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By P Hulteberg

In this article, an integrated catalytic reactor design approach to produce PEMFC-quality hydrogen is evaluated. The design is based on a high level of heat exchanging perfonned internally, highly active noble metal catalysts and a woven wire mesh catalyst support system. It consists of an integrated steam refonner and a catalytic burner section, a water gas shift section and a preferential carbon monoxide oxidation section. The reactor design is described and experiments perfonned to evaluate the two reactors built are reported. The two reactors have a maximum output of 3 Nm and 10 Nm3 hydrogen/h respectively. In the larger unit, a total of six fuels, three gaseous (methane, natural gas and liquid propane gas) and three liquid (naphtha, ethanol and methanol), were evaluated. The larger unit was also used to investigate how variations of parameters such as steam-to-carbon ratio in the steam reforming part of the system and the relation between oxygen and carbon monoxide in the preferential carbon monoxide oxidation affect the reactor perfonnance. The smaller unit was used, after implementing automatic control, to run a system life time test for 480 h. The refonner system perfonned according to specifications on almost every aspect.

Jan 1, 2005

By J. Guha, el, G. Bouchard, W. Zuckerk, J. Carignan, G. Archambault

The Gwillim Mine, located 8 km northwest of Chibougamau, is underlain by two mafic volcanic cycles separated by a dominantly felsic cycle. These rocks are part of the Gilman Formation of the Roy Group. The mafic rocks are cut by weak shear zones containing the "North" and "Main" veins, both east-west striking gold-bearing structures dipping 75° to the north. The felsic cycle, which is also gold-bearing, contains textures suggesting a syngenetic origin. The Gwillim Mine presents an excellent opportunity for the study of what may be two coexisting gold deposits, a volcanogenic and a veine type.

Jan 1, 1984

By Andre du Preez

Emergency Fall Arrest System Rio Tinto?s Primary Objective: ?To achieve repeatable controlled safe deceleration rates during emergency fall arrest activation (Ontario OHSA Regulations) ?Must operate effectively on mine specified steel shaft guides.

May 1, 2013

By S. B. Kang

Magnesium has poor ductility at temperatures lower than 225°C and, as a result, Mg alloy sheets are produced via fairly complex thermomechanical processes consisting of numerous sequential steps of hot (warm) rolling with low reduction and intermediate recrystallization annealing operations. In context of the present study, a simple technology for the fabrication of magnesium sheets by hot (warm) rolling was applied to various magnesium alloys. The misch metal addition in those AZ alloys was done to evaluate the deformation behavior. Tensile tests were carried out for those AZ alloys after applying different heat treatments. The precipitation of ß phase (Mg17Al12 phase) induced different microstructures with various cooling method from solution treatment temperature, and also with various annealing treatment temperatures.

Jan 1, 2006

By Georges Houlachi, Akram Alfantazi, Michael Mahon, Maysam Mohammadi

Corrosion resistance of the lead-based anodes directly influences the purity of the final product in the zinc electrowinning process. The anodic MnO2 layer that is electrodeposited on the anodes during this process can protect the anodes against corrosion. Sand-blasted anodes generate a uniform, adherent and shiny MnO2 layer, which gradually blisters and eventually sloughs off after several weeks. In this study, we attempted to develop a new method to stabilize the MnO2 protective layer on the anodes during the electrowinning process by providing suitable nucleation sites for electrodeposition of this layer. MnO2 particles (P80=40µm) were used as seed material for this purpose. Different techniques of galvanostatic and cyclic voltammetry polarizations, scanning electron microscopy (SEM) and atomic absorption spectroscopy (AAS) were employed to investigate the performances of the MnO2-seeded lead anodes. The experimental results showed that growth of the MnO2 layer is influenced by the MnO2 seed particles on the anode surface. The MnO2 layers electrodeposited on the MnO2-seeded lead anodes were uniform and strongly adherent to the substrate. This layer was more stable than those formed on the PbAg anode without MnO2 seeding. This could provide the anode with a higher level of corrosion protection. Moreover, formation of undesirable MnO2 mud in the electrolyte and the rate of manganese consumption were decreased when the MnO2-seeded lead anodes were polarized. These observations could be attributed to the different properties of the electrodeposited MnO2 layer on this anode in comparison with that formed on the PbAg anode.

Jan 1, 2016

By Y. Turen, Y. Karakas, E. Candan, C. Sahinturk

In this study, wettability between sprayable tundish lining (MgO) and molten steel was investigated by using sessile drop method. Content of glass fiber (SiO2) in the MgO varied between 0 to 8 wt% whereas mean particle sizes of the MgO were 25, 75, 150 and 300µm. Experimental results revealed that contact angle (0) of sessile drop on the MgO was not altered by the addition of glass fiber up to 1 wt.% whereas above 2 wt.% addition decreased the 0 considerably. Contact angle, 0, increased considerably with increasing MgO particle size. SEM analysis showed deposition of glass phase was present at the interface as the finer MgO particles were used.

Jan 1, 2004

By T. Plikas, L. Gunnewiek

Computational fluid dynamics (CFD) modeling was used to evaluate the performance and optimize the design of a potroom ventilation system in an aluminium smelter facility. The ventilation system must ensure the inflow of fresh air to the workplace by natural draft and the removal of heat and hazardous emissions generated from the pot cell process. A full-scale, three dimensional CFD model of the potroom was developed to predict the air temperature distribution and contaminant concentrations throughout the potroom for the purpose of verifying that the industrial workplace hygiene standards will be met by the proposed ventilation system design. The modeling work was used to optimize the size of the floor gratings around the pot cell and roof ventilator, as well as determine damper settings in the roof ventilator. The effects of outside air temperature and external wind on the performance of the ventilation system was evaluated to ensure the design performs adequately in response to seasonal variations in climatological conditions.

Jan 1, 2006

By A. Hutwalker, T. Plett

"Blast fumes are one of the major sources for NOx in underground mines. In 2016, the Occupational Exposure Limits for NOx in Germany were reduced by 90%. The task is to keep re-entry times after blasting at the present level and thereby ensure an economic operation of the mine. Measurements show that using ventilation solely is not sufficient. A new approach to reduce NOx from blast fumes is described. Laboratory experiments were performed and a reduction of NOx was observed. Measurements were conducted at an explosive factory’s testing facility and in an underground mine at blasting operations. INTRODUCTION Whether for production of ore or for drift development, the processes in an underground mine are always the same: 1) fracturing the rock, 2) loading the pile, 3) support the resulting cavity. The fracturing of the rock can be done mechanically, by cutting, for example by using continuous miners or tunnel boring machines, or by drilling and blasting. Drilling and blasting is more flexible than mechanical driving, as it can be used independently of the rock strength. Furthermore, this driving method allows a more flexible reaction to changes in geological and/or operational conditions. Thus, underground mining and blasting are almost inextricably linked with each other, and regardless of the size and level of technology of the mine, blasting is hardly avoidable. Depending on the mining method chosen and the existing framework conditions, such as the mechanical properties of the rock or the availability of machinery, blasting is an integral part of daily operations. Even in mines where blasting is not part of regular operations, it cannot be completely avoided. The blast fumes generated by the explosions are, in addition to diesel engine emissions, one of the two main sources of emissions of nitrous gases underground. Up to now, state of the art for dealing with blast fumes is ventilation. The fumes are diluted with fresh air and ventilated out of the mine. This treatment of blast fumes is more than sufficient with the former German Occupational Exposure Limits (OEL). The adaption of the OEL in Germany to the recommendations of the Committee on Occupational Exposure Limits (SCOEL), a committee of the European Commission, leads to big challenges for the mining industry in reducing the concentrations of these gases at the workplaces underground. On its meeting on May 2nd and 3rd 2016, the Committee on Hazardous Substances (Ausschuss für Gefahrstoffe, AGS), an advisory body of the German Federal Ministry of Labour and Social Affairs (BMAS), advised the BMAS to copy the OEL, as recommended by the SCOEL, to the Technical Rules for Hazardous Substances (TRGS 900). BMAS followed this advice, consequently the new OEL where published on November 4th 2016 and became part of the TRGS 900. Table 1 shows the former and new OEL for Germany. These new OEL became law after publishing, but two exceptions were made: For tunneling operations, they became law on October 31st 2017, for mining operations they will become law on October 31st 2021 (BAuA, 2004, 2016, 2017)."

Jan 1, 2019

By J. L. Gartshore

PRACTICALLY all of Quebec's chrysotile asbestos production derives from twelve mining and milling operations located in the "Eastern Townships" area of the province. The annual output of these twelve operations exceeds one million tons of chrysotile asbestos, valued at over one hundred million dollars, and is shipped to manufacturers spread over all six continental areas of the world. A total of approximately twenty million ton of asbestos ore yearly, or about seventy-five thousand tons a day, is mined. Individually, the operations vary in size from about two thousand tons to thirty thousand tons per day. Removal of waste rock and overburden to develop these ore tonnages varies greatly from one mine to another, but would probably average out at about a one to one ratio.

Jan 1, 1962

In the flotation of a copper ore, entrainment of fine silicate and iron sulfide gangue minerals resulted in poor copper concentrate grade. In the cleaning stage, rejection of these gangue minerals was particularly difficult due to severe mechanical entrainment when the rougher concentrate was ground to 10 µm. To reduce gangue entrainment, polymeric depressants were tested. The rationale being that with the use of such polymeric depressants that also possess flocculation power, not only minerals-to-be-depressed can be made hydrophilic, but their particle size can also be enlarged. In this manner both the "genuine" flotation and the mechanical entrainment can be reduced. An effective polymer to reduce entrainment of silicate gangue mineral in sulfide flotation was identified from bench flotation tests conducted on single minerals. It was then applied to the flotation of a copper-gold ore confirming the beneficial role of the polymeric depressant in the reduction of fine gangue entrainment.

Jan 1, 2007

By Thomas G. Madgwick

Introduction Development of oil and gas is still centred in the Province of Alberta, much as it was when C. C. Ross read a paper on this subject three years ago at the Annual General Meeting in Montreal; but so far as gas is concerned, its early production in Saskatchewan seems now assured. The three years that have elapsed since Mr. Ross' paper have witnessed a growth in the world's production of oil that has created a potential supply out of all proportion to the demand for petroleum products, and one that has resisted the most energetic efforts of the industry entirely to control. The natural result has been very much to retard the active prospecting of new structures in the Prairie Provinces with any immediate view to oil production, although the same factor has not hindered the search for gas to the same extent. One consequence has been to divert the attention of organized oil operators from wildcat drilling to more detailed geological investigation than had hitherto been customary, sometimes accompanied by test drilling with a view to the elucidation of geological structure rather than to the immediate development of production which at the present is not needed. Nevertheless, in spite of the growth of this phase of oil prospecting - which the writer would be the last not to welcome as a very real blessing and of far greater value than indiscriminate wildcat drilling in either the complex structures of the foothills or the simpler but largely concealed formations of the plains- it is most satisfactory to have to record that in these three years the growth of production both of naphtha and the heavier crude-oil has kept pace with the by no means inconsiderable growth in the production and utilization of natural gas.

Jan 1, 1929

"Sedimented hydrothermal precipitates of silica, now fine-grained quartz, are described from a Pb-Zn-bearing vein system. Their discrimination from the wall-accreted fine-grained quartz that is common in the shallow parts of epithermal systems is discussed. Local fine-grained (<0.3 mm) quartz accumulations occur in a suite of veins with otherwise normal drusiform and crustified infills. This sediment may fill the vein above chokes in steep segments (axial plugs), or form continuous layers within the footwall material where the vein is inclined at low to moderate angles. Pads of fine-grained sediment are deposited on the upwards-facing surfaces of wall-rock clasts and of drusiform crystals growing from the vein walls. The asymmetry of these deposits differentiates them from the more common symmetrical, crustified walllining deposits of fine-grained quartz and opaline silica, and requires a gravity-controlled, sedimentary depositional mechanism.Thin section examination shows that much of the fine-grained quartz is present as elongate prisms. The prism habit was present soon after deposition, but it is not possible to identify unequivocally the original sedimented grains. Sedimentation of vein- and wall-rock-derived detritus is also recognized. Deposition of the fine-grained sediment accompanies normal in situ drusiform growth of quartz and other vein minerals. The mammilated and spherulitic textures associated with accretion of amorphous quartz are entirely absent from the Tyndrum veins with sedimented materials. The literature on modern hydrothermal waters and physical chemistry of silica precipitation shows that precipitates of silica suspended in hydrothermal fluids are amorphous and derived from colloidal silica. It is argued that much of the suspended silica was present as quartz at the time of deposition or was converted from amorphous silica almost immediately after deposition.Hydrothermal sediments and their distribution potentially provide information on flow directions and velocity in veins. Plugs of sediment obstruct vertical flow and lead to local flows with large horizontal components. It is shown that sedimentation features occur in other deposits and can involve other minerals. If the features seen here can be scaled up to the size of major veins, they may result in up and downdip variations in mineral assemblages and abundances, which may affect grade."

Jan 1, 2007

By T. T. Chen, J. E. Dutrizac, G. Poirier

In the Waelz kiln process, EAF dust is converted to an Fe-rich slag, a (Zn, Fe)-rich dust that is recycled to the kiln and the Zn-rich Waelz oxide which is subsequently up-graded for the recovery of zinc. To clarify the reactions occurring, the Waelz kiln products from a European Waelz plant were characterized mineralogically to determine the mineral species present, their micro-textures and the metal carriers. The EAF dust contains 27 % Zn, and consists mainly of ZnFe2O4 and ZnO, together with minor to trace amounts of NaCl, PbCl2, KCl, CaO, Ca2Fe2O5, Fe203, FRO, Pb oxide and various Ca-Fe-Al-Mn silicates. The KCI and NaCI sometimes agglomerate the other particles. The slag consists of nodules which often exhibit colloform structures. The slag contains of variable amounts of Fe, FeO(OH), FeO, gypsum, Ca(OH)2, Ca2SiO4 and various Ca-Fe¬Al-Mg-Mn silicates as well as minor to trace amounts of ZnFe2O4, Cr-Fe oxide, Mn-Fe oxide and other species. The Waelz oxide contains 57-61 % Zn, and consists predominantly of ZnO, with minor to trace amounts of KCI NaCl, Pb(OH)Cl, Pb20(SO4), Pb chloride, ZnSO4, ZnFe2O4, Ca2SiO4, Ca2Fe2O5, Ca-Fe silicate and NaZn4(SO4)(OH)6Cl.6H2O. The KCI agglomerates the other particles in the Waelz oxide. The recycled dust appears to be a mixture of EAF dust and Waelz oxide, but it contains relatively more coarser-grained metallic Pb and Pb oxide particles.

Jan 1, 2004

By Catharine E. G. Farrow, David H. Watkinson

The Ni-rich Epidote Zone of the Fraser Mine at Sudbury is characterized by alteration assemblages rich in epidote, actinolite and magnetite which are roughly concentrically zoned and up to hundreds of meters in length. These zones form discrete areas within the igneous Footwall Breccia below the Sudbury Igneous Complex. The assemblages grade from epidotized Footwall Breccia matrix,through actinolite-bearing rocks with few vestiges of original Footwall Breccia textures, into the most intensely altered rock, a magnetite-rich facies. Pentlandite, pyrrhotite and pyrite are the dominant sulfdeminerals; chalcopyrite is minor. The strongest geochemical differences compared to original Footwall Breccia occur where epidote and actinolite dominate the alteration assemblage (EPDZact facies). The most intense alteration facies are typifed by low Cu/(Cu+Ni) values of <0.1. Strong positive correlations exist between Ni and Co, Cu and Au, and among Ir, Os, Ru and Rh. Chondrite-normalized Ni - PGE -Au - Cu plots display an overall increase in all elements from the least to the most intensely altered facies except for Au and Cu. As the proportion of actinolite increases in the EPDZact facies, the chondrite-normalized profles fatten considerably due to low Au and Cu contents. Abundances of Ni, Ir, Ru and Rhalmost ubiquitously increase with degree of alteration. In contrast, Cu, Zn, Ag and Au contents are low in almost all facies. It is suggested that saline hydrothermal fluids moved through the Epidote Zone formation and became more oxidized as they reacted with the Footwall Breccia and with footwall units, including ultramafic rocks. As this trend continued, magnetite-rich zones eventually developed. The occurrence of calcite locally in these magnetite-rich zones suggests that the pH of the fluid increased, causing Cu solubility to drop as activity in the hydrothermal system waned. Sudden changes in fluid composition such as this may have been due to an influx of fluid from bounding ultramafic rocks. Hydrothermal activity was focused along the margins of footwall ultramafic units. Individual hydrother-mal cells may have formed in the Footwall Breccia along pre-existing structures or sulfde concentrations. Metals may have been scavenged from sulfide-bearing Footwall Breccia and possibly Sublayer rocks. Nickel and some PGE were deposited in the Epidote Zone, whereas Cu, Au and Ag continued out-ward into the footwall where they were deposited as Cu-rich footwall veins. Copyright © 1996 Canadian Institute of Mining, Metallurgy and Petroleum.

Jan 1, 1996

By Catharine E. G. Farrow, David H. Watkinson

Abstract-The Ni-rich Epidote Zone of the Fraser Mine at Sudbury is characterized by alteration assemblages rich in epidote, actinolite and magnetite which are roughly concentrically zoned and up to hundreds of meters in length. These zones form discrete areas within the igneous Footwall Breccia below the Sudbury Igneous Complex. The assemblages grade from epidotized Footwall Breccia matrix, through actinolite-bearing rocks with few vestiges of original Footwall Breccia textures, into the most intensely altered rock, a magnetite-rich facies. Pentlandite, pyrrhotite and pyrite are the dominant sulfide minerals; chalcopyrite is minor. The strongest geochemical differences compared to original Footwall Breccia occur where epidote and actinolite dominate the alteration assemblage (EPDZact facies). The most intense alteration facies are typified by low Cu/(Cu+Ni) values of <0.1. Strong positive correlations exist between Ni and Co, Cu and Au, and among Ir, Os, Ru and Rh. Chondrite-normalized Ni - PGE - Au - Cu plots display an overall increase in all elements from the least to the most intensely altered facies except for Au and Cu. As the proportion of actinolite increases in the EPDZact facies, the chondrite-normalized profiles flatten considerably due to low Au and Cu contents. Abundances of Ni, Ir, Ru and Rh almost ubiquitously increase with degree of alteration. In contrast, Cu, Zn, Ag and Au contents are low in almost all facies. It is suggested that saline hydrothermal fluids moved through the Epidote Zone formation and became more oxidized as they reacted with the Footwall Breccia and with footwall units, including ultramafic rocks. As this trend continued, magnetite-rich zones eventually developed. The occurrence of calcite locally in these magnetite-rich zones suggests that the pH of the fluid increased, causing Cu solubility to drop as activity in the hydrothermal system waned. Sudden changes in fluid composition such as this may have been due to an influx of fluid from bounding ultramafic rocks. Hydrothermal activity was focused along the margins of footwall ultramafic units. Individual hydrothermal cells may have formed in the Footwall Breccia along pre-existing structures or sulfide concentrations. Metals may have been scavenged from sulfide-bearing Footwall Breccia and possibly Sublayer rocks. Nickel and some PGE were deposited in the Epidote Zone, whereas Cu, Au and Ag continued outward into the footwall where they were deposited as Cu-rich footwall veins.

Jan 1, 1996

By M. E. Holter

"Limestone-bearing strata are exposed in seven areas of Alberta, each situated adjacent to rail and road facilities. Six of these centers are located along the eastern edge of the Foothills and Front Ranges of the Rocky Mountains in western Alberta. The other is in northeastern Alberta, along the eastern margin of the Alberta Basin. High-grade limestones are present in Middle Cambrian, Upper Devonian and Mississippian strata. Middle Cambrian (Eldon Formation) limestones have been exploited only in the Exshaw area west of Calgary, where they formerly were used for lime production. Limestone beds of the Upper Devonian Palliser Formation are exploited at Exshaw and at Cadomin in west-central Alberta for the manufacture of cement. Reserves of high-grade limestone also are available in the Palliser Formation near Crowsnest Lake in southwestern Alberta and near BrUle, west of Edmonton. Upper Devonian limestones of the Waterways Formation are widespread in the Fort McMurray area of northeastern Alberta, but available data indicate they are of inferior quality to the limestone deposits of the Rocky Mountains regions. The Mississippian Livingstone Formation contains large reserves of high-grade limestone at several localities in the Rocky Mountains and Foothills. Commercial development of the unit is now underway at Crowsnest Lake and at Exshaw for lime production, and future exploitation of these beds is feasible at Blairmore and Nordegg."

Jan 1, 1973

By A. H. Duffield

"Forming part of the Prairie Evaporites, the sylvinite layer mined at Alwinsal underlies the Blairmore quicksands and the water-bearing Devonian formations. Production is achieved by a method of trackless, continuous mining of rooms, leaving pillars for natural support. The paper describes the development of the mine, and the equipment and organization employed in the operation and maintenance of the underground facilities."

Jan 1, 1972

By M. Kataoka, Y. Obara

It is known that compressive strength and tensile strength of rocks vary significantly with specimen size. Rocks are composed of crystals and grains in a fabric that includes flaws such as microcracks, grain boundaries and pores. As the likelihood of including severer flaws becomes greater for a larger specimen, the strengths are small. On the other hand, the size effect in the fracture toughness of rocks has not been made clear until now because there are few studies focused on it. In this paper, Semi- Circular Bend (SCB) test was performed using Kimachi sandstone with various specimen sizes. A shape of the specimen is a semi-circular disc with an artificial notch. The specimens were prepared with various thickness t and radius r as the following two groups; t was changed from 10 to 37.5 mm with r = 37.5 mm in the specimen of group (a), and r was changed from 12.5 to 150 mm with t/r = 0.8 in the specimen of group (b). As a result, there was no significant change in the fracture toughness with different t. On the other hand, the fracture toughness increased with increasing r and converged on a certain constant value in a range larger than approximately 70 mm of r. Consequently it was clear that the size effect in the fracture toughness of the sandstone exists.

Jan 1, 2015

By Jürgen Kretschmann

The Islamic Republic of Iran is a very important producer of raw materials in the world. The country holds 68 types of minerals, including salt, sand and gravel, chrome, lead, zinc, copper, coal, gold, and iron-ore. With more than 37 billion tons of measured and indicated reserves and 55 billion tons of total mineral resources, Iran is ranked among the 15 major mineral-rich countries. Sangan iron-ore mines (SIOM) is one of the biggest iron ore mining complexes in Iran, located in a remote, but strategically important area near the Afghanistan border. The Iranian government has planned several mining projects in this region for a stepwise development over the next 5 years to satisfy the growing demand of the Iranian steel industry. In cooperation with private companies, these projects shall be realized as sustainable as possible. This paper introduces SIOM and describes socially responsible activities undertaken during the initial development of this mining complex. The effects of these activities will be demonstrated. Unique attributes of the Sangan area have a significant impact on the acceptance of SIOM by regional stakeholders. The government has made several social investments that benefit workers´ families and the community. They are attempts to build social capital for the mining operations and demonstrate a commitment for socially responsible mining to the communities and the local population. They aim to create a balance between the local and regional expectations and requirements and the necessity to secure the corporate profitability at a reasonable and sustainable level. Investment in socially responsible activities is not a choice but a necessity to improve the relations between mining companies and stakeholders in the communities. It is recommended that social investments should be carefully planned and implemented from the early stages of mining activities, and should proceed throughout the life cycle of the mines.

Aug 1, 2013

By Minerals Refining Company, Gerald Luttrell, Biao Li, Robert Bratton, Roe-Hoan Yoon, Stan Suboleski, Nikhil Gupta

Flotation is regarded as the best available method of upgrading coal and mineral fines in the mining industry. However, its efficiency deteriorates rapidly with decreasing particle size. Furthermore, ultrafine concentrates are difficult to be dewatered economically. Due to these technological problems, some operators are forced to discard at least part of the ultrafine materials to tailings (or refuse) ponds, causing significant losses of valuable resources and creating environmental concerns. To address these technological issues, a new separation process named hydrophobic-hydrophilic separation has been developed on the basis of the recent advances in the science of hydrophobic interactions. The results obtained to date show that the process can recover and dewater ultrafine particles simultaneously with high separation efficiencies. Following a series of extensive laboratory tests, the process has been scaled up to proof-of-concept and pilot-scale continuous tests. The results obtained with desliming cyclone overflows, screenbowl effluents, and by-zero coal flotation feeds can be cleaned to less than 4% ash and moisture with over 97% organic matter (or coal) recoveries. The results obtained with mineral fines also showed encouraging results.

Jan 1, 2016