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By J. R. Andrews, R. P. Young, J. M. Reyes-Montes

"Microseismic monitoring provides insight into the location and extent of rock-mass fracturing induced by cave mining, enabling interpretation of the cave profile and validation of predictive numerical models. Source location uncertainties can lead to misinterpretation of the inferred characteristics of the fracture network. One principal source of uncertainty is the velocity model used to invert the location algorithm. Large-scale 3D numerical models of modulus changes across a caved mass can represent such complexities in the location algorithms, allowing more accurate interpretation of the microseismic activity. A Northparkes mine case study applies this advanced approach to microseismic data interpretation.RÉSUMÉ Le suivi microsismique fournit des renseignements sur la localisation et l’étendue des fractures de la masse rocheuse induites par l’exploitation par blocs foudroyés; cela permet d’interpréter le profil de la chambre foudroyée et de valider les modèles prédictifs numériques. Les incertitudes quant à la localisation de la source peuvent conduire à des mésinterprétations des caractéristiques inférés du réseau de fractures. Une des principales sources d’incertitudes est le modèle de vitesse utilisé pour inverser l’algorithme de localisation. Des modèles numériques tridimensionnels à grande échelle des changements du module d’élasticité à travers une masse foudroyée peuvent représenter de telles complexités dans les algorithmes de localisation, permettant ainsi une interprétation plus juste de l’activité microsismique. Une étude de cas à la mine Northparkes applique cette approche avancée à l’interprétation des données de microsismicité."

Jan 1, 2016

By F. Habashi

"A short account will be presented on the extraction of rare earths from monazite sand, bastnasite ore, and phosphate rock of igneous origin. This includes mineral beneficiation, leaching methods, fractional crystallization [of historical interest], ion exchange, solvent extraction, precipitation from solution, and reduction to metals. INTRODUCTIONOriginally, the term rare earths was only used for the oxides, R2O3, which are similar to one other in their chemical and physical properties and are therefore difficult to separate. Within the rare earth group, the elements scandium, yttrium, and lanthanum differ in their atomic structure from the elements cerium to lutetium (the lanthanides, Ln). Scandium occupies a special position with respect to this classification and its other properties, and therefore does not belong to either of these groups. The rare earth elements always occur in nature in association with each other. The isolation of groups of rare earth elements or of individual elements requires costly separation and fractionation processes owing to the great similarity of the chemical and physical properties of their compounds, which explains why the history of their discovery has extended over such a long period.The word “rare”, when used to describe this group of elements, originates from the fact it was thought that these elements could only be isolated from very rare minerals. Considering their abundance in the Earth’s crust, the term rare is now inappropriate. These elements are lithophilic and are therefore concentrated in oxidic compounds such as carbonates, silicates, titano-tantalo-niobates, and phosphates.The abundance of the rare earth elements taken together is quite considerable. Cerium, the most common rare earth, is more abundant than cobalt. Yttrium is more abundant than lead, whereas Lu and Tm are as abundant as Sb, Hg, Bi, and Ag. For all practical purposes promethium does not occur in nature. It forms only in nuclear reactors."

Jan 1, 2012

By Tanai Marin

Modelling of pyrometallurgical processes can become extremely challenging when the process involves complex chemical reactions, phase change, multiphase flows, heat and mass transfer and fluid flow. Traditionally modelling involving complex thermodynamic equilibrium and thermochemistry are treated separately from problems in which transport phenomena are dominant, such as CFD and heat transfer studies. The separation is also necessary due to the lack of modelling tools that can effectively couple both solution thermodynamic and transport phenomena or even multiphysics problems. However, there are, quite often, problems in high temperature process metallurgy in which it is not possible to simplify this two modelling approaches. Typical cases of this are for example, the modelling of slag freezing on furnace walls (electric or flash furnaces) to create a protective layer in front of the refractories hot wall, the formation of build up from the matte or metal phases at the hearth of the furnace, calcine smelting from charging piles into slag phase, etc. The problem is even more challenging in nonferrous pyrometallurgy as most, if not all, of the condense phases are highly non ideal solutions involving several components and exhibiting complex crystallization paths and miscibility gaps, such as the Fe-Ni-Cu-S matte, FeO-Fe2O3-SiO2, FeO-MgO-SiO2 slags, etc. In this paper, an approach to model coupled problems involving multiphysics and solution thermodynamic is presented. The approach consists in developing in-house a library containing the Gibbs energy minimization routines and using the local equilibrium concept for process modelling from a multiphysics commercial software (COMSOL). Simple test cases, such as building a non-ideal binary phase diagram on a CFD package is presented, the limitations and of other classic approaches such as equilibrium or Scheil cooling are discussed and compared to this model.

Jan 1, 2015

By W. A. Jankola

Teck Cominco Metals Ltd. operates an integrated zinc-lead smelter at Trail, British Columbia, Canada. The zinc circuit comprises three parallel operations: conventional fluid-bed roasting, direct zinc pressure leaching of concentrates and atmospheric leaching of zinc oxide fume recycled from the lead smelter. The products from these three areas are combined in the main leaching plant where they undergo iron purification. Unlike most leaching circuits, the leach process in Trail begins with an acid leach and is followed by a neutral leach. An evaluation was undertaken to determine if the process at Trail could be improved by converting to the conventional neutral leaching process with a subsequent acid leach of the residues. This paper explores the results of these tests and the implications for Trail Operations.

Jan 1, 2006

By S. L. Zekovic

This paper analysis the medium and long-term perspectives, framework and considered possibilities of sustainable development of RTB "Bor" (Copper mines in East Serbia) after consolidation in the period of transition. The copper mine was opened in 1903. and today is the best quality copper producer on Balcan. This paper are elaborates the problems of privatization, debt, investment, growth of copper production from own mines (and imported raw), opening of new mines, economical efficiency of production, markets, environmental problems and impacts of the recent industry consolidation. The RTB "Bor" is a serious hot spot in Serbia. Unsustainable trends and processes are identified, as follows: open-pit waste dumps, flotation tailings, mining and processing waste waters, air pollution; no efficiency (excessive) using nonrenewal resource in the copper production; inefficiency in the use of energy, water and other inputs in copper complex; transboundary character of emissions of dust; environmental degradation and quality of wide area and ecologically highly risk, etc. Analysing some trends and planning-developmental perspectives and development strategies of company, it might be assumed that in the forth coming period, in parts of the Serbia, the borders areas of Bulgaria and Romania, there is an anticipated increase of ecological risk.

Jan 1, 2007

By F. A. McLean

At the Annual Western Meeting held at Blairmore, Alta., October 1924, the writer presented a paper drawing attention -to the advantages of portable gas-driven equipment for developing isolated mining properties. This type of equipment was at that time practically in its infancy and the details of results actually accomplished were somewhat meagre. During the last year or so a number of these plants have been installed so that it is now possible to offer more definite information regarding the actual mining progress accomplished with such plants and their cost of operation in various parts of the country. This paper has been written with the idea of reviewing the work done during the past year, and to supply data which may be of interest to those wh9 are confronted with the problem of selecting equipment for development or assessment work. Because drilling operations play such an important part in mining, one of the first problems that usually confront the prospective? mine owner is the selection of the proper com-pressed-air plant. The size and type of equipment and the method of driving it require careful consideration. The size and type of equipment is determined largely by the funds available, transportation facilities, and the speed with which the programme of development is to be carried out. The selection of the proper method of drive usually depends on local conditions, such as the relative cost of various fuels, and has an important bearing on operating costs.

Jan 1, 1926

By H. L. Ramandi, P. Moore

"The corrosion of support bolts in underground mines has become an increasingly prevalent issue over the past two decades. With an increase of premature failures due to Stress Corrosion Cracking (SCC), it is evident that understanding the environmental factor influencing the cable bolt corrosion is critical for maintaining effective ground support hence the safety and productivity of underground spaces. Experimental testing of rock and cable bolts were accomplished in a variety of packings, including saturated clay, saturated coal, mine water and grout/cement to investigate their corrosion behaviours. Water samples were obtained and analysed for pH and electrical conductivity (EC) during the experiment. After a period of 76 days the bolts were retrieved and analysed visually. Primary factors were found to be the presence of geological materials and the aeration of the bolts, i.e. the vicinity to air and air flow, while secondary factors were observed to be pH levels and EC. It was also found that the coal/clay interfaces and the water/grout/cement interfaces are non-relevant to corrosion of rockbolts and cable bolts. The proposed framework can be applied to other reinforcement materials used in underground spaces for improved understanding of corrosion environment.INTRODUCTION Rock bolts and cable bolts are the major reinforcement elements used in mining industry to improve the rockmass properties for safe and productive mining. They are normally used to pin large beams or blocks of rock in underground mines to stabilise the rockmass in the roof (strata) against collapse. The rockbolts are typically low cost hot rolled rebar while cable bolts are composed of strands of wire, normally wound together around a central king wire (Hyett and Bawden, 1993; Vandermaat, 2014). The typical length of the bolts in underground mines is 2.4 m and 4–12 m for rockbolts and cable bolts, respectively (Vandermaat, 2014; Windsor and Thompson, 1997). Cable bolts are much more flexible and usually offer a much higher load capacity than rigid rockbolts. Their increased length and flexibility allows cable bolts longer than the height of a roadway to be used in underground mines."

Jan 1, 2017

By Xiong Tong, Jiushuai Deng, Yingbo Mao, Lingyun Huang

Ammonium carbamate has been used as a reagent for the leaching of copper from the copper oxide ore found in the Honghe state, Yunnan province, China. In order to find the optimal conditions for the leaching of copper from this copper oxide ore,the effects of several processing parameters, including the concentration, time, temperature, particle size and stirring intensity have been investigated. The results of these optimization experiments showed that the leaching rate of copper reached up to 72.76% under the following conditions: liquid-to-solid ratio of 10:1, ammonium carbamate concentration of 2.5mol/L, leaching temperature of 45 °C, stirring speed of 300rpm, a reaction time of 1.5 h and 85% by weight thereof passes through a sieve having 0.074 mm.

Jan 1, 2015

By D. C. R. Espinosa, P. Aliprandini, J. A. S. Tenório, M. M. Jiménez Correa

"Nickel and cobalt are the main value metals in nickel laterite ore. Cyanex 272 is an extractant used to separate nickel from cobalt present in leach solutions. Previous studies demonstrated the extraction of cobalt, magnesium and manganese at pH 5 using Cyanex 272 as extractant, while nickel remained in aqueous solution. However, it is difficult to separate cobalt from a solution containing magnesium and manganese. One possibility to change the metals’ behavior during the solvent extraction process is to change the mixture of extractants used. In order to study the solvent extraction of cobalt from a solution containing manganese, magnesium and nickel, a mixture of two extractants was investigated. Cyanex 272 (CY) and Versatic 10 (VC) were selected as extractants in the organic phase. The extractant concentrations used were: 20% CY; 15% CY, 5% VC; 10% CY, 10% VC; 5% CY, 15% VC; and 20% VC. In all cases, kerosene was used as a diluent, at 80 vol%. The synthetic leach solution used in this study was prepared according to the composition of a typical nickel laterite leach solution. The pH value of the solution used was 5, and the aqueous/organic ratio used in solvent extraction testwork was 1/1. The study has shown that the composition of the organic extractant mixture did not increase cobalt separation.INTRODUCTION Sulfide and laterite deposits are the main sources of nickel. However, production from nickel sulfide ores has been decreasing over the years, relatively speaking, increasing the focus on the exploitation of laterite nickel ores (McDonald & Whittington, 2008). Laterite ore deposits are found in tropical and subtropical regions. A characteristic of laterite ores is the presence of a complex and heterogeneous mixture of metals (Crundwell, Moats, Ramachandran, Robinson, & Davenport, 2011; Georgiou & Papangelakis, 1998; Gupta, 2003; Kesler & Simon, 2015; Moskalyk & Alfantazi, 2002; Oliveira, 1990). Nickel concentrations in laterite ores are typically 1–2% (Dalvi, Bacon, & Osborne, 2004)."

Jan 1, 2017

By J. P. Bennett, W. E. Lee, S. Zhnag, K. S. Kwong

An EAF slag properly saturated in MgO results in increased refractory service life and steelmaking efficiency. A computer model was developed using phase equilibrium data from the MgO-CaO-SiO2-FeO, MgO-CaO-Al2O3-SiO2 and SiO2-CaO-Al2O3-FeO systems to predict MgO saturated slag chemistry. This model has been successfully applied to a commercial EAF, although disciplined plant practices are required to achieve benefits from slag chemistry control.

Jan 1, 2004

By M. S. Badollet, N. W. Edgerton

"A study of the physical properties of long grades of asbestos fibers imported into the United States during the past eight years has disclosed information that will contribute materially to effective selection and use of fibers for electrical products. The study embraced fiber lengths, volume resistivity under three different conditions, total iron by chemical analysis, magnetic rating, conductivity of an aqueous ex-tract and its sodium chloride equivalent.The fibers examined included chrysotiles from Rhodesia, British Columbia, and Barberton area; marlime from Bechuanaland and Province of Quebec; amosite and crocidolites from Africa and Australia; and anthophyllites from Mozambique and from Georgia in the United States. Volume resistivity values provide a relative basis for estimating the electrical performance of end products; magnetic rating -an estimate of the quantity of iron compounds present in excess of those in the asbestos structure; conductivity of an aqueous extract; and an estimate of the ionizable impurities in fibers.Tests of these factors yield in-formation, not heretofore generally known, which may serve as a guide in the evaluation of asbestos fibers for electrical products."

Jan 1, 1960

By C. Chapman, M. G. Reading, M. P. Amsden

Ecstall Mining Limited, a subsidiary of Texasgulf Incorporated, operates the Kidd Creek mine, a 10,000- tpd base metal producer, near Timmins, Ontario. Two different ore types are mined and milled copper-zinc and silver-lead-zinc. At the highly automated Ecstall concentrator, the ores are processed by selective flotation in three individual circuits. One of the most important metallurgical tools for process control is a sample system incorporating continuous onstream X-ray analysis. Recently this system was further automated by adding computer control of reagents for two copper-zinc flotation circuits. The computer programs, utilizing optimum seeking methods and smelter contract terms, have increased copper recovery 0.8% and zinc recovery 1.6%, and reduced reagent costs by 12%. Although not anticipated, copper and zinc concentrate grades were improved modestly as well.

Jan 1, 1973

By D. G. Almond

Nkomati Nickel Mine in South Africa processes one of the world?s hardest ores in a 375k TPM autogenous grinding circuit. The plant employs an unconventional processing circuit, comprising a primary autogenous mill (AG or FAG) and pebble crushing circuit followed by a secondary hybrid pebble/ball mill and classification cyclone cluster. Advanced Process Control (APC) or Expert Control is now generally accepted as an advantage in most modern high capacity concentrator grinding circuits. This paper reviews the installation of model predictive control at Nkomati and examines the results and benefits of installation in an autogenous mill during plant ramp-up. The paper also demonstrates how predefining process control objectives together with good plant and supplier cooperation can achieve a robust and reliable APC implementation on a very short site program. The results conclusively demonstrate operational and economic benefits during circuit operation with the advanced process control system ON. Production performance and circuit stability were significantly better than during manual control.

Jan 1, 2012

By Gavin A. Hunt

In order for mines to operate profitably throughout their life it is important to monitor and maximise ore recovery. A common problem facing many mines is the underestimation of clay type and its distribution in ore at the mine face, blast hole or in the ore stockpile. Too much clay entering the heap leach ore stream for example causes a dramatic reduction in heap leach efficacy and or increased leaching times. The end result is poor leaching performance and much reduced metal production. Poor clay identification and quantification is attributable to many factors, including costly and slow off-site mineral analysis techniques, such as XRD, XRF and petrology, the visual and subjective limitations of the core logging geologist and a lack of suitable low cost, high throughput mineral logging instruments. To get round these problems a new, non-contact, imaging spectrometer - the SpecCam - was developed by Spectra-Map Ltd, to allow high throughput identification and quantification of minerals from mineable material. Its novel imaging design can collect millions of data points (pixels) per day; each pixel contains spectral information that allows a wide variety of mineral types, including the smectite and illite clays, and phyllosilicates such as talc and kaolin, to be identified. Because all the ore can be imaged a much more reliable mineral log can be made. Hence, mapping changes in mineral composition - related to variations in phenocrysts, macrocrysts, veining or wall rock - is possible. Examples of SpecCam data from Goldfields Cerro Corona Porphyry stockpile and from Rio Tinto?s Argyle Diamond mine illustrate the mineral identification and quantification capabilities of the SpecCam. More importantly, for the first time very accurate % abundances for the different minerals can be obtained using an image-based modal count technique. The modular design of the camera, plus its extremely flexible high speed filter, mean that the SpecCam can be easily installed on different equipment, each one suited to different ore recovery problems. For example the SpecCam can be used on an automated portable logging frame to measure drill core, RC chips, hand samples or powder, or alternatively installed on a Geotek multi-sensor core logger for high-throughput, automated logging of drill or blast hole core using co-registered multi-sensor data. An exciting recent development has been the installation of the SpecCam on CommoDas ore sorting equipment, used around the world for 24 hour mill-feed monitoring and automatic ore sorting. Real-time ore sorting decisions can be made as material is monitored on a conveyor belt running at 3m s-1, from which the ore can be automatically sorted into high-grade, low-grade or waste streams for example. The three installation options for the SpecCam mean that most mineral analysis and automated core logging or ore monitoring needs can be met at the mine. For the first time rapid and automatic mineral identification and accurate quantification can be made. All of which allow the mine geologist or metallurgist to make important decisions about maximising the metal recovery process.

May 1, 2007

By A. W. Jolliffee

ANY attempt to forecast the mineral resources of a largely unknown region is hazardous and, in the case of the Northwest Territories, such a task is even more hazardous than usual. This is not merely because of the immense territory involved (over a million and a quarter square miles), only a small fraction of which has ever been explored or prospected, but also be-cause both the geology and mineral deposits thus far examined show many unique features, and, finally, because the region is being actively prospected at the present time. However, in view of the present widespread interest in Canada's mineral resources, a brief compilation of what is known regarding mineral occurrences and geology in the explored parts of the far north seems timely. From these assembled data, a few inferences are warranted as to future mineral production from this region. HISTORY The story of mineral discovery in the Canadian northwest is a fascinating one. As well, it abundantly illustrates the importance of mineral occurrences in indicating future mining possibilities. The same sequence of events has repeated itself too often to be merely fortuitous.? In most cases, the dis-covery of a mineral deposit of possible economic value has been foreshadowed by the finding of the valuable mineral or an associated mineral in the same district, generally in small quantity, by an early explorer or traveller. Thus, John Franklin reported oil seepages from the base of Bear Rock, near Nor-man, at almost the very spot where oil was struck nearly one hundred years later. Again, some would-be Klondikers, deterred by the hardships of the route, remained to prospect around Great Slave lake, and were the first to report the Pine Point lead-zinc occurrences there and the gold-bearing veins on Yellowknife bay. Sporadic prospecting followed at the latter locality for over thirty years before the recent rich strikes were made. Similarly, in 1847, Dr. John Rae picked up a boulder of copper ore south of Rankin inlet, on Hudson bay. More than eighty years later, a body of copper-nickel sulphides carrying values in platinum metals was found at this locality. Also, the report of cobalt bloom on the east coast of Great Bear lake brought back by a Geological Survey of Canada party in 1900 was a factor in the events leading to the discovery of silver and radium there in 1930.

Jan 1, 1937

By R. Holmwood, M. Faris, P. Holloway, M. Collins

Sulphuric acid addition is a major driver of the economics in the processing of nickel laterite ores by high pressure acid leaching (HPAL). Understanding the optimal acid addition rate is essential for the success of any HPAL operation, and this is especially true at Ambatovy, where the composition of the feed tends to vary significantly on a day-to-day basis. Most studies on the effect of acid on nickel extraction in HPAL have used laboratory testwork as their basis. Although these studies are invaluable in assessing the economics of a new project, they are limited by the range of ore composition that can be tested and the differences between the operation of the laboratory equipment and the commercial plant. To enable optimization of the acid addition at Ambatovy, operating data from the HPAL operation were obtained using OSISoft’s PI system and the data from several periods were examined to develop relationships between acid addition and nickel extraction. The initial relationships from 2014 focused on the acid required to achieve a target nickel extraction of 95%, with aluminum and magnesium in ore and feed slurry solids content as the major variables. As Ambatovy ramped up through 2015 and 2016, the calculated acid requirement was further refined to address the effects of HPAL temperature and retention time, and the oxidizing/reducing characteristics of the ore, and to generate acid requirement relationships as a function of ranges of nickel extraction. These relationships supported raising the target nickel extraction to 96% and enabled the development of an economic model between acid addition and nickel extraction.

Jan 1, 2017

"The QEMSCAN system is the third generation of automated mineral analysis systems that began with the QEM*SEM at CSIRO 30 years ago (Butcher et al. 2000). It is now a successful commercial instrument with 39 instruments in operation around the world. Back Scattered Electrons (BSE) and Energy Dispersive (EDS) X-Ray spectra are used to create digital mineral images with mineral identification occurring online. Low-count EDS spectra are used preferentially to BSE brightness, allowing minerals to be accurately identified by chemical composition. Individual minerals or groups of similar compositions are identified by comparison to a comprehensive mineral database incorporated into the QEMSCAN software. Optical mineralogy and Scanning Electron Microscopy is a metallurgists’ tool for determining the ore process mineralogy and delivering a better flowsheet. These techniques have limitations, provide limited information and sometimes fail to provide representative information. In contrast, QEMSCAN provides information on the nature and occurrence of all mineral species present plus the liberation characteristics, looking at thousands of particles in the sample presented. Some of the data presented includes:• Particle and grain sizes• Dominant mineral species• Particle shape• Calculated metal content• Density• Deportment of elements of interest between the mineral phases• Quantitative mineralogy• Mineral associations, locking and liberation• Textural relationships (particle images)It can also be used on concentrates, polished sections or drill core. This is a significant improvement in ore characterisation providing lithology, mineralogy, liberation, ore grade and porosity from a sample. Theoretical grade-recovery curves can be created to be mineralogically limited from QEMSCAN analysis which, when compared with metallurgical results, are valuable in evaluating whether liberation or chemical selectivity is driving flotation performance. A number of case study examples are given where the QEMSCAN had a significant bearing on future project development at an early stage of exploration and mine development."

Jan 1, 2012

By Ho-Sung Yoon, Jyothi Rajesh Kumar, Chul-Joo Kim, Sung-Don Kim

A recovery process for rare earths (REs) such as dysprosium and neodymium from the leach liquor of permanent magnet scrap (PMS) was developed. The two hydrometallurgical routes namely liquid-liquid extraction (solvent extraction) and selective stripping were implemented. The present study deals with the separation and recovery process development by using organo-phosphorous based extractant di-(2-ethylhexyl phosphoric acid (D2EHPA) as reagent for REs processing. Initial studies considered the influence of time on the extraction process, as well as pH and extractant concentration effects. This suggested the aqueous mechanism and separation factors played a role in process during development. McCabe-Thiele diagrams for extraction isotherms were developed. Counter current extraction (CCE) using various phase ratios influenced metals separation. Maximum loading capacity of the D2EHPA was determined. The loaded organic generated by the CCE process was water washed followed by a scrubbing process to remove the other metal ion from targeted metal. Finally, a stripping process was tested using various mineral acids.

Jan 1, 2015

By Himanshu Dehra

The pre-fabricated outdoor rooms are often utilised near the mines and construction sites for office purposes. The paper has presented modelling and simulation results of the integration of commercially available glass coated photovoltaic (PV) energy technology and solar ventilation technology into a pre-fabricated outdoor room. The pre-fabricated outdoor room has been setup at Concordia University, Montréal for full scale testing of the glass coated PV modules with solar air ventilation. The computer simulation model has been developed for PV modules installed on a double wall wooden frame in an outdoor room based on its preliminary field testing. The testing apparatus was a wooden frame assembly of double wall with solar air ventilation: two adjacent glass coated PV modules, air column and plywood board filled with polystyrene. The measurement data collected from various sensors were: solar intensity, ambient air temperature, room air temperature, electric power, surface temperatures of PV modules and plywood board, air velocities and air temperatures in the air column. The enhancement in the air velocity of the air column was achieved with an exhaust fan fixed in an outdoor room. The simulation model is used to perform the two dimensional energy analyses with applied one dimensional solution of steady state heat conduction equations. The simulation model is based on conjugate heat exchange paths with network boundary conditions of convection, radiation heat exchange and solar air ventilation heat transport. The model parameters are based on measured values of ambient air temperature, room air temperature, air velocity at outlet of air column in double wall, electric power and available solar intensity. The model has predicted fairly well energy performance of glass coated PV modules with solar air ventilation installed on a wooden frame. The model is also useful for predicting heating, ventilating and air-conditioning (HVAC) requirements for the pre-fabricated outdoor rooms.

May 1, 2007

By M. S. Moats, F. Elnathan

"The effect of current reversal on two commercially manufactured electrodes (RuO2-TiO2 and IrO2-Ta2O5 coated Ti) in a chloride bearing electrolyte was evaluated. Accelerated lifetimes were found to decrease with increasing current density and increasing reversal frequency. Ru: Ti coated electrodes exhibited longer lifetimes than Ir: Ta coated electrodes even though they had one-third as much precious metal content. Chloride concentration did not affect lifetime in the range examined. Using energy dispersive X-ray spectroscopy (EDS), scanning electron microscopy (SEM) and electrochemical impedance spectroscopy (EIS), the failure mode of the electrodes was determined to be coating dissolution leading ultimately to passivation by the presumed growth of a highly resistive oxide at the coating/substrate interface.INTRODUCTIONCatalytic titanium anodes (CTAs) were developed in the 1960’s to replace graphite anodes in chlor-alkali cells. CTAs exhibited much better dimensional stability than graphite leading to lower operating potentials by promoting smaller electrode gaps and better operational efficiencies as they had to be replaced less often. CTAs are simply Ti substrates coated with precious metal oxides (such as IrO2 and RuO2) mixed with other components (such as TiO2 and TasO5) (Trasatti, 2000).CTAs are used in many other electrochemical industries, including water disinfection, wastewater treatment, cathodic protection and metal plating. RuO2 based coatings are typically used for chlorine evolution. IrO2 based coatings are for the most part utilized for oxygen evolution (Comninellis & Nerini, 1991; Forti, Olive, & De Andrade, 2001; Kotz, Stucki & Carcer, 1991; Trasatti & Lodi, 1981)"

Jan 1, 2016