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By G. Merle, David L. McKay, Elmar Randveer

"THE ENGINEERING AND TECHNICAL SERVICES department is responsible for supplying the following services:1. Administration and co-ordination of the work required for capital projects.2. Engineering, design and drafting services for inplant changes or improvements as requested by the operating• and maintenance departments.3. Rock mechanics.4. Preparation of plans and layouts required for efficient extraction of the ore as mutually agreed with the mine operating departments.5. Mine planning and long-term schedules in co-operation with the mine operating departments.6. Grade control (long term and short term) and the preparation of ore and waste removal schedules to maintain a uniform grade of mill feed. This also includes the calculation of metal reserves and metal production forecasts.7. Surveying, underground and surface.8. Operations research at the mine site.9. Industrial engineering.10. Chemical analyses and assays.11. Instrumentation.12. Environmental control.A staff of approximately 35 supervisors, engineers and scientists, and 80 technicians, supply the foregoing services. Consulting engineering and drafting firms are used to supply specialized services and technical personnel in-house at Timmins to handle overloads on capital projects under the direction of Ecstall engineers.The operating and maintenance departments depend on the engineering department to supply engineering, design and drafting services for any new facilities or for any planned alteration to existing facilities. To do this efficiently requires a high level of communication and co-operation with these departments. This has been a major factor in developing the present organization of the department shown in Figure 63.The organization is predicated on a strong central technical and engineering resource from which personnel can be assigned responsibilities for different projects, and in different areas, as the work load demands. Job satisfaction is very high because of the variety and challenge in the tasks. Additionally, participation in projects with production and maintenance personnel broadens each technical employee's knowledge of operating and maintenance problems."

Jan 1, 1974

By M. Barati, K. Ebrahimi-Nasrabadi, P. W. Scott

"The conversion of cryptocrystalline magnesite to caustic magnesia was studied experimentally at temperatures of 400–1,200°C and for calcination times of up to 8 h. A differential thermal analysis– thermal gravimetric analysis showed that decomposition begins at temperatures as low as 340°C and is completed at 600°C. Specific surface area, iodine adsorption number, crystallite size, and loss on ignition were measured to characterize the product quality. It was found that high-quality caustic calcined magnesia can be produced in a narrow temperature (600–650°C) and time range (1–4 h).RÉSUMÉ La conversion de magnésite cryptocristalline en magnésie caustique a été étudiée de manière expérimentale à des températures de 400 à 1200 °C et pour des temps de calcination atteignant 8 heures. Une analyse thermique différentielle – analyse thermique gravimétrique montre que la décomposition commence à des températures aussi basses que 340 °C et qu’elle est complète à 600 °C. La surface spécifique, l’indice d’adsorption de l’iode, la taille des cristaux et la perte au feu ont été mesurés afin de caractériser la qualité du produit. Il a été trouvé qu’une magnésie caustique calcinée de grande qualité peut être produite dans un petit écart de température (600 à 650 °C) et dans une période de temps variant entre 1 et 4 heures."

Jan 1, 2015

As part of the Australian Mineral Industries Research Association (AMIRA) P9 project, methods of characterising both the ore and the machines in flotation circuits have matured considerably over the past 15 years. Machine characteristics include gas dispersion measurements, such as bubble size, gas hold-up and superficial gas velocity. Ores can be characterised in terms of floatability parameters on a size and mineral basis. Measurements have been performed on various copper plants in many countries around the world over the last 5 years. This paper outlines the cell and ore floatability characteristics of each copper plant and provides a discussion on the differences between these plants. In general, most porphyry copper ore bodies are processed at high tonnage through several parallel banks of cells at each stage of flotation. The floatability parameters of these copper ores are very similar in terms of rate of flotation and proportion of fast, slow and non-floating material. The cell characteristics are also similar, with superficial gas velocity, bubble sizes, and gas hold-up values being of similar magnitude. Investigation of the similarities and differences of the modem copper flotation circuits has allowed an increase in understanding of the particularities of copper flotation. Comparison against other copper circuits provides a benchmark and opportunities for future optimisation.

Jan 1, 2007

By P. Kawulka

An integrated pilot plant for the development of the S-C Copper Process was constructed at Fort Saskatchewan in 1975 and operated in 1976. The pilot plant was designed to treat 9 tonnes per day of a pyritic copper concentrate. A demonstration run conducted during the last quarter of 1976 averaged 90% on-stream time, and confirmed that the process is operable as a stable and integrated unit. The paper describes the parameters and equipment developed for thermal activation of chalcopyrite copper concentrates to make them amenable for the dissolution of iron and zinc, and their subsequent separation and recovery. The resulting high-grade copper sulphide was leached with return electrolyte and oxygen to extract 98.5% of the copper into solution. The copper was electrowon at 650 amps per square metre from purified solution, to produce cathodes analyzing 0.1 ppm Se, 0.1 ppm Bi, 4 ppm Pb and 10 ppm S. The electrical conductivity was >101% lACS and the spring elongation value [ ]350 mm. Elemental sulphur and gangue are removed from leach residues to make a concentrate containing over 95% of the silver and gold and most of the unleached copper. Conventional construction materials such as stainless steel, titanium, Hastelloy, acid brick, rubber and plastics performed well. The containment inherent in hydrometallurgy provided high standards of hygiene and safety.

Jan 1, 1978

By J R. M Hutcheson

Advocate Mines Limited came into initial production on June 30, 1963, with an annual capacity in excess of 60,000 tons of high-quality chrysotile asbestos fihres, thus strengthening Canada's position in world production. The history of this development is traced from discovery through initial exploration, financing, orebody delineation and evaluation, pilot-plant production and product evaluation, construction of the plant, construction of deep?-sea shipping facilities, provision for a closed shipping season, and provision for the remoteness and for the lack of services, through to realization of full production capacity. The many unique aspects of the project are given special attention, particularly in the light of the first year of full-capacity operation. The marketing of the products in a highly competitive world market is reviewed, with special emphasis on product evaluation, quality control and the shipping of high-quality products to consumers throughout the world. C ANADA'S newest asbestos producer, Advocate Mines Limited, is located at the north end of the Burlington Peninsula, White Bay District, Newfound-

Jan 1, 1965

ABSTRACT Inco’s Iron Ore Recovery Plant was operated by Inco from 1955 to 1980 near Sudbury, Ontario. As exposures to specific nickel substances have been associated with adverse respiratory endpoints it is important to understand processes giving rise to such substances. This manuscript discusses the process and equipment, the propensity for aerosol formation, and operational procedures used by Inco in roasting a pyrrhotite concentrate, reducing the nickel in the formed oxide, leaching the nickel in ammoniacal solution, purifying the resulting solution, making green or black NiO, and producing iron oxide pellets. Industrial hygiene measurements are also reported.

Jan 1, 2013

By L. V. Chugaev, Y. M. Shneerson, P. V. Zaytsev, I. V. Fomenko, M. A. Pleshkov

"Pressure oxidation (POX) is one of the most common and reliable methods of processing gold-bearing sulfide concentrates. However, when processing concentrates that contain natural carbonaceous matter, substantial gold losses occur due to autoclave preg-robbing. The latter involves formation of gold chloride complexes under typical POX conditions (high temperatures, high acidity and high ORP) and subsequent sorption of these complexes by carbonaceous matter. Naturally, chloride ion plays a significant role in the process of autoclave preg-robbing; its concentration in POX solution has a well-marked effect on subsequent gold recovery during cyanidation of POX residue. The previous research done by SRC Hydrometallurgy showed that autoclave preg-robbing of gold could be significantly inhibited by the addition of mercury(II) compounds to POX slurry. The positive effect of mercury(II) was well pronounced both at high (>20 mg/L) and low (<5 mg/L) Cl concentrations in POX solution. The successful bench-scale laboratory testing was followed by pilot plant trials at Ore Test Facility in Blagoveshchensk, Russia. The present paper provides the results of these trials. The bench-scale testing results were verified; the optimum oxidizing parameters and reagent dosage were specified. The behavior of mercury (II) at POX pilot plant was found to be in good consistency with industrial practice described in the literature.INTRODUCTION Pressure oxidation (POX) is one of the most common, reliable, and commercially proven methods of processing gold-bearing sulfide ores and concentrates. However, when processing double refractory materials that contain natural carbonaceous matter, POX technology advantages are compromised by autoclave preg-robbing of gold. The latter occurs when natural organic carbon and soluble halides are both present in autoclave feed. Strongly oxidizing conditions of POX (high temperature, oxidation-reduction potential or ORP, and acidity) favor formation of gold-halide (mostly, gold-chloride) complexes, which tend to bond with carbonaceous matter. The exact nature and mechanism of this bonding is unknown, but as the result of this, cyanide is unable to leach gold from POX residue and the precious metal is lost to the tails (Axenov et al., 2014; Dimov, Chryssoulis, & Sodhi, 2003; Fomenko, Zaytsev, Pleshkov, Chugaev, & Shneerson, 2013)."

Jan 1, 2017

By L. C. Lien

Tower crane layout (TCL) is a typical construction site layout (CSL) problem, which is suitable for a wide range of work assignments and site conditions. Tower crane is one of the key facilities for vertical and horizontal transportation of materials, especially for heavy prefabrication units such as steel beams, ready mixed concrete, prefabricated elements and large panel formwork such as machinery and equipment, and a wide variety of other building materials within a construction site. However, it is a difficult combinatorial optimization problem to determine the locations of tower cranes with materials quantity supply and demand for engineers. Swarm intelligence (SI) was very popular and widely used in many complex optimization problems which was collective behaviour of social systems such as honey bees (bee algorithm, BA) and birds (particle swarm optimization, PSO). This study applied a hybrid swarm algorithm namely particle bee algorithm (PBA) based on a particular intelligent behaviour of honey bee and bird swarms by integrates theirs advantages. This study compares the performance of PBA with BA and PSO for a proposed hypothetical construction engineering of TCL with materials quantity supply and demand problem. Results show that PBA performs better performance than the mentioned algorithms on a proposed hypothetical TCL problem.

Aug 1, 2013

By Steven Hart

In September 2009, Newmont began the commissioning of a 3 stage crushing and milling circuit at its Boddington Gold Operation in Western Australia. The Boddington ore has been recognized as one of the hardest and most abrasive ores treated to date and this played a pivotal role in the selection of crushing and HPGR technology for this operation as opposed to the more conventional SABC circuit. This paper will examine the scale up from laboratory to pilot plant and full scale operation of the crushing circuit. There have been many challenges to overcome in the first 18 months of operation; however, the HPGRs have in general met design expectations and performance is expected to improve further with ongoing design changes

Jan 1, 2012

By John C. Robbins

A new technique for the determination of trace levels of uranium in solution has been developed. A compact laser emits short, but intense, ultraviolet pulses to excite the green fluorescence of a uranyl-complex formed by the addition of a proprietary reagent to the sample. Organic species present in most natural waters also fluoresce quite intensely, but their emission does not last appreciably longer than the excitation pulse, in contrast to the relatively long persistence of the uranyl fluorescence . Electronic &apos;gating&apos; is employed to separate the long-lived contribution, rejecting substantially the organic emission. Results using the laser fluorescence method on many sets of natural waters of various origins have been compared against corresponding values generated by independent laboratories. Correlation has been generally good over a range from less than 0.1 to more than 100 ppb U. Solid samples have also been analyzed after extraction of the uranium into solution. Accuracies adequate for most exploration purposes have been achieved, but further work is required to determine effects of interferences in samples with complex matrices. The transport and deposition of uranium in natural waters is controlled by the organic and inorganic chemistry of the waters involved. It is suggested that interpretation of very low uranium levels will be aided by additional measurements of conductivity and organic content, with subsequent statistical treatment.

Jan 1, 1978

By P. D. R. Maltby

This paper describes the background and markets for calcium carbonate and silica sand in Canada, as well as the results of recent test work carried out at the Ontario Research Foundation. Tests on sericite, tremolite, vermiculite, barite and graphite are also mentioned.

Jan 1, 1979

By M. A. Kessick

Current treatment and disposal procedures are compared for clay slimes resulting from the extraction of Alberta oil sands, the extraction of Florida phosphate matrix, the recovery of diamonds from kimberlite deposits in South Africa, the recovery of kaolin from clay deposits in southwest England and the upgrading of bauxite ore. Published research in the area is reviewed, and common trends which are emerging in the disposal of clay slimes are discussed.

Jan 1, 1978

By C. H. Hitchcock

History In approaching the subject of diamond-drilling practice, a brief history of the origin and development of the diamond drill may be of interest. The use of black diamonds for boring holes in rock was discovered in 1863 by Rudolph Leschot, a French engineer. In 1864, he employed a diamond bit to bore holes for blasting purposes in the construction of the Mont Cenis tunnel between France and Italy. The method was introduced and developed in the United States in the late sixties. The first deep hole was drilled for coal in 1870, near Pottsville, Penn., by M. C. Bullock. This hole was seven hundred and fifty feet deep. It can be inferred that the diamond drill was introduced into Canada in 1871, when a bore-hole, known as Harper&apos;s bore-hole, was drilled for coal at Springhill, Cumberland county, Nova Scotia; and at the old Silver Islet mine, near Port Arthur, the diamond drill was in use as early as 1872. Diamond Drills While M. C. Bullock was developing the diamond drill for exploratory work, the Sullivan Machine Company, of Claremont, N.H., was developing the diamond channelers and gadders for quarry work. These quarry machines were very successful until the high price of black diamonds became prohibitive. In 1878, Albert Ball, chief engineer of the Sullivan Machine Company, designed the Sullivan diamond drill so well known today. The first of these drills went to the Lake Superior iron ranges. After 1880, use of the diamond drill expanded rapidly and spread to all parts of the world where exploratory work was being done. In recent years, the type of diamond drill has not changed much, but better material is going into its construction. Steel castings have replaced cast-iron. Ball and roller bearings are now used instead of brasses and babbits. Gun lubrication has eliminated the oil-can. These improvements make a drill that can be operated for long periods without expense for repairs.

Jan 1, 1933

By G. S. Hume

In the transformation of carbonaceous materials, such as peat, to coals of various grades, the changes are known to be both physical and chemical and the grade of coal finally produced depends on the stage to which alteration proceeded. Those changes, which are frequently spoken of as the results of metamorphism, are due to pressure with accompanying heat and, according to the amount of metamorphism to which the sediments with the included carbonaceous beds have been subjected, there is a gradation from peat to anthracite coal, and even to graphite. The improvement in the quality of the coal as a result of metamorphism is due to an increase of the carbon content of the coal and a corresponding loss of the volatile materials. This rise in the quality of the coal according to the degree of metamorphism is well illustrated by the coals of western Canada. In the Plains area, where the deformation and the attendant metamorphism of the sediments is comparatively small, the coals are lignites, whereas in the mountains, where deformation has been severe, the coals are semi-anthracites. Sub-bituminous and bituminous coals occur in the intervening areas. The same general relationship between the quality of the coal and the degree of metamorphism holds true for the Appalachian basin of the United States, where there is a progressive improvement in the quality of the coals from west to east, that is, from an area of comparatively slight metamorphism to an area of marked deformation in the Appalachian Mountain region. But while it is true that this relationship holds in a general way, it has been found that the improvement in the quality of the coal is not always uniformly progressive, and there may be local variations such that an area containing coal with a carbon content indicating low or medium metamorphism may be surrounded by areas in which the coals are of higher grade. These local variations in many cases can be explained, and they in no way detract from the general rule that, in a region exhibiting a progressive betterment in the quality of the coal from an area of low metamorphism to one of more marked deformation, the quality of the coal, i.e., the amount of fixed carbon in the coal, may be taken as an index of the degree of metamorphism of the coal as well as of the sediments in which it occurs, It has been pointed out (&apos;) that certain coals, such as cannels, are unreliable indicators of the varying degree of metamorphism because of the nature of the material from which such coal was derived. Such coals, however, are not known in western Canada and their behaviour need not here be discussed.

Jan 1, 1927

By B. C. Tripathy, S. K. Padhy, R. K. Paramguru, Pinak Patnaik

"Cobalt is regarded as technology enabling metal among the less abundant metals found in the earth crust. Electrodeposition of the metal from aqueous sulphate solutions is the preferred technology for its commercial production. Certain additives are added in the electrolytic bath during electrodeposition for the production of uniform, smooth and bright deposits of cobalt metal with higher current efficiencies and lower energy consumptions. A detailed investigation has been carried out to determine the effect of additive Sodium octyl sulphate (SOS) on the electrodeposition of cobalt. The results indicated that the additive apart from increasing the current efficiency enhanced the quality of cobalt electrodeposits. A maximum current efficiency of 98.4% was achieved at 10 mg/L SOS. The presence of SOS in the electrolytic bath did not result in any noticeable change in the crystal orientation of the cobalt electrodeposits except at higher concentrations (50 g/L) of the additive. Scanning electron micrographs indicate that smooth, compact and uniform deposits of cobalt were obtained at 10 mg/L of the additive beyond which there is detoriation in the quality of deposits. Polarisation of the cathode was seen in the presence of SOS. The effect of SOS on the electro kinetic parameters: Tafel slope (b), transfer coefficient (a) and exchange current density (I0) has also been investigated.INTRODUCTIONCobalt is recognised to be a strategic metal among the various base metals, owing to its numerous applications in various industries. Cobalt as a metal finds its use in the preparation of rechargeable batteries, as an alloying component in the manufacture of space craft and jet engines, as a drying agent for paint varnishes, ground coats for porcelain enamels and in the manufacture of the catalysts for the petroleum and chemical industries (Davis, 2000). Although there is a huge demand of the metal the supply of the metal is limited due to its scarcity in the earth crust. The metal comprises of only 0.02% of the earth’s crust for which the metal is recovered from various ores of nickel and copper as a byproduct (Hawkins, 1998). The present day techniques for cobalt production includes mostly hydrometallurgical methods which are preferred over the earlier used pryometallurgcial methods carried out for the metal production. Almost 70% of the world’s cobalt produced currently is from hydrometallurgical techniques in which electrodeposition of the metal from aqueous solutions is the final step for metal production (Verney, 1988). The most preferred route for electrodeposition of cobalt metal involves a sulphate medium (Das and Subbaiah, 1984; Lenthall and Bryson, 1997; Sharma et al., 2005)."

Jan 1, 2016

By J. E. Danoczi

Shore Gold Inc. (Shore) is presently designing a diamond processing plant for the Star and the Orion South kimberlite deposits in the Fort à la Corne (FalC) area in central Saskatchewan. The first step in the plant is diamond liberation and occurs in the comminution section. Diamond liberation is the process of breaking up the kimberlite rock, as gently as possible so as not to damage the diamonds. Autogenous grinding mills (AG mills) use a combination of impact crushing, abrasion and attrition to break up the kimberlite. The forces that occur during the actions of abrasion and attrition cause the kimberlites to break up preferentially along lines of weaknesses which offers a ?diamond friendly? method of comminution. Hard competent kimberlite is commonly found in the diatreme zone as well as the root zone of the volcanic pipe and is the source of kimberlite for most of the Southern African diamond mines. Softer kimberlite is typically found in and around the crater area of a volcanic pipe and it is this kimberlite that makes up the majority of kimberlite for both the Star and Orion South deposits. These softer kimberlites can be readily broken up using abrasion and attrition imparted by AG mills. In order for Shore to benefit from the softer kimberlite found in the Star - Orion South diamond project, two large (10.97 m diameter x 7.10 m long) AG mills were designed for the comminution section based on extensive test work and simulations by Metso Minerals (Metso).

Jan 1, 2012

By Davood Moradkhani, Maryam Rasouli

"The present study reports solvent extraction and separation of zinc from concentrated nickel sulfate solution. In our previous study, Zn and Cd in cold filter cake (CFC, 45-55% Zn, 11-16% Cd, and 2.5-4% Ni) were extracted by alkaline leaching followed by electrowinning processes respectively. The strip solution from electrowinning process, was a pregnant liquor solution (PLS) containing 16.8 g/l Ni and 4.2 g/l Zn. In this work, PLS is subjected to the solvent extraction process for separation of traces of Zn from high grade nickel. The zinc free raffinate containing 16.6 g/l Ni sulfate solution will flow to nickel electrowinning plant for cathode production. Di-(2-ethylhexyl) phosphoric acid (D2EHPA) is the organic phase used in this study. The effects of various parameters such as organic phase concentration (10- 40 % v/v), pH (1.5-3), and temperature (25 and 45°) are investigated. Zinc over nickel separation factor increases by increasing pH from1.5 to 3. The results show that 98.7% of Zn was loaded at25°C O/A ratio of 1, pH 3, and 10% vol. D2EHPA. A 10 M NaOH is used for pH control. However, replacement of pH controlling agent with ammonia solution (25%. v/v) results in interesting observations. Ammonia addition, reduces the solubility of Ni2+ cations in solution. Nickel starts to precipitate from raffinate in a crystalline bluish-green form. The obtained crystals are characterized by XRF and identified to be nickel-bearing analog of boussingaultite, a rare sulfate mineral of nickel with chemical formula of Ni (NH4)2(SO4)2.6H2O. The crystallization rate of crystals is studied. It is a slow precipitation process with 75% in 4 days.INTRODUCTION Annually, many hydrometallurgical processes such as electrowinning, solvent extraction and leaching are applied to waste filter cakes in Zanjan, Iran. These additional processes on filter cakes are critical from both environmental and economic points of view. CFC (cold filter cake) is a toxic but valuable filter cake (45-55% Zn, 11-16% Cd, 2.5-4% Ni, and 0.2-1.5% Cu) produced in many zinc production plants. Our research group at Research and Engineering Company for Non-ferrous Metals (ReCo.), developed a series of hydrometallurgical methods for extraction of zinc, cadmium and nickel from CFC (Moradkhani, & Rasouli 2012). The recovery of zinc and cadmium with alkaline leaching and electrowinning was successfully studied. The strip sulfate solution from cadmium electrowinning unit, contains high concentration of nickel with some traces of zinc impurity. This pregnant liquor solution (PLS) was analyzed and reported to contain 16.8 g/l Ni and 4.2 g/l Zn. In this work, PLS is subjected to the solvent extraction process to separate Zn from nickel (Fig. 1). The organic phase stripping solution containing 4.2 g/l zinc and 200 ppm nickel can be circulated and used in the acidic leaching step. This generates nickel solution with high purity suitable for nickel cathode production."

Jan 1, 2017

By H. C. Boydell

Introduction Situated in the district of South Lorrain, some 16 miles southeast of Cobalt, Ontario, and reached from that centre either by branch line of the T. & N. O. railway or by what, for a mining camp, is a reasonably good road, the Keeley mine, owned by the Keeley Silver Mines,&apos; Ltd., has had its history recorded by C. W. Knight (1). Silver was first discovered in South Lorrain, in Woods&apos; vein, on Keeley property, in 1907, and the Keeley mine has been described by Knight (2) and Bell (3). The total production to February 28th, 1930, has been 10,760,107 ounces of silver and 1,285. 434 pounds (weight) of cobalt.

Jan 1, 1931

By C. Cutts, K. Wheatley

The Dragon Lake Zone (uranium prospect) comprises a N160º trending vein that is approximately 110 m long, up to 5 m wide and from 1 to 40 m high. The zone is mostly within altered sandstone of the Fair Point Formation, the basal unit of the Paleoproterozoic Athabasca Group, but it also extends downward (up to 3.5 m) into basement rocks that occupy the northerly trending Maybelle River Shear Zone (MRSZ). This subvertical shear zone separates graphitic paragneiss and weakly deformed granitoid rocks to the east from non-graphitic paragneiss and foliated granitoid rocks to the west. The Dragon Lake Zone cuts across both the MRSZ and N060º-N070º-trending cross-faults that offset the shear zone but not the mineralized vein, which contains values up to 54.5% U over 50 cm core length. Strong chloritization occurs in graphitic paragneiss and sandstone adjacent to mineralization. Silica was depleted from the basement rocks and redeposited at the borders of the 5-15-m-wide alteration zone, as well as within overlying sandstone of the Manitou Falls Formation. There are minimal alteration effects in the overlying Lazenby Lake Formation. Geochemistry shows that the alteration zone in the Fair Point Formation is highly anomalous in metals, most notably in Ni, As, U, Pb, Co, and B. Clay within this zone is illitic and Fe-rich chlorite is also present. Brittle deformation is not as widespread or as well developed in the Fair Point Formation as it is in the overlying Manitou Falls Formation, which is extensively brecciated and contains some anomalous metal values.

Jan 1, 2013

By D. M. Bastidas

The reduction of copper sulfide and copper oxides originated during artificial tarnishing of copper was studied using potentiodynamic potential/current density experiments. Six copper surface treatments were considered: mechanical polishing; indoor exposure for 7 days; chemical etching in 1.6 M nitric acid; chemical etching and heating at 160°C; and chemical etching and dipping in a 9x10-4 M or 0.9 M potassium sulfide (1(25) solution at 70°C. Cuprite (Cu20) and chalcocite (Cu2S) were the main compounds formed. A linear relationship with the square root of the scan rate (v) was obtained by plotting the potentiodynamic potential/current density for the tarnish dissolution processes. A relationship between potential and current density cathodic peaks was not obtained, according to Müller&apos;s model, showing a proportionality factor with the dimensions of a resistance.

Jan 1, 2007