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By D. A. Temple, G. O. John

Until recently, the approach to the problem of treating complex ores bas been to produce, insofar as is possible, mono-metal concentrates which are treated in traditional zinc, lead and copper smelting circuits, with the residues and by-products from some of these circuits being retreated for the recovery of contained values either by a separate residue treatment process or along with the primary feed to the appropriate circuit. The continued development of the Imperial Smelting Process, with its ability to treat poly-metal concentrates, calls for a re-examination of the traditional approach to this problem, and this the paper attempts to do. A survey of recent progress in the technical development of the process is made and a summary of current operational performance is included.

Jan 1, 1971

"6.1. Mineralogical Techniques ApplicableTo the Platinum-Group Elements6.1.1. IntroductionThe named platinum-group minerals (PGM) usually occur as grains smaller than about 200 microns and, even when present as larger grains as in nuggets, these are often complex multimineral intergrowths. Therefore, the PGM must be examined by microscopic techniques and, because all named PGM are opaque, they are suitable for microscopic study by reflected light. Special techniques for concentrating PGM and preparing suitable polished sections are detailed in Chapter 5. Another characteristic of the PGM is that the majority have very high reflectance at 589 nm, i.e., over 450Jo, but they range from about 38 to 74%. In contrast, micro-indentation hardness has a wider range from - 60 to - 3,000 kg I mm, and the PGM range from brittle to malleable.The small grain-size of PGM imposes certain limitations, or complications, on the usual mineralogical determinative methods of reflectance, micro-indentation hardness and X-ray diffraction. In addition, certain combinations of elements in some PGM render electron-probe analyses difficult. The usefulness and shortcoming of these methods, as applied specifically to the PGM, are discussed in the following sections. These are not, however, meant to be exhaustive descriptions of the techniques, which are fully described in other texts.6.1.2. Micro-Indentation HardnessDetermination of the Vickers Hardness Number (VHN) is discussed in detail in recent publications, such as Bowie and Simpson (1977) and Craig and Vaughan (1981). In addition, the recommendations of the Commission on Ore Microscopy (COM) of the International Mineralogical Association (IMA) are given by Criddle (1980). The usual small grain-size of the PGM, however, precludes the widespread use of this technique and very few PGM have, in fact, had their VHN determined at the COM-recommended standard load of 100 gf (cf. Cabri, 1981b, in Chapter 7). Examination of VHN data reported in the literature reveals that the few PGM whose microindentation hardness has been measured have incomplete VHN data, measured with loads other than 100 gf (Chapter 7). The small grain-size may also result in unreliable VHN data because, even though the correct load may have been applied, a thin grain will give erroneous data due to the matrix, or the grain may even shatter or pop out of the section. On the other hand, micro-indentations may give useful qualitative diagnostic clues. Moncheite, for example, shows fractures near the indentation (Chapter 7, Plate 1). In other cases, intergrown PGM produce different-sized indentations: e.g., froodite-michenerite-gold in Cabri (1972); isoferroplatinumtulameenite in Cabri et al. (1973); michenerite-moncheite in Cabri and Laflamme (1976) and Chapter 7, Plate 1; altaitemichenerite- testibiopalladite in Hudson eta/. (1978) and Plate 1, Chapter 7."

Jan 1, 1979

By Michel L. Bilodeau, Brian W. Mackenzie, Dallas W. Davis

"The paper formulates an evaluation procedure for examining the effects of location on the economics of developing mineral deposits. This methodology is applied to assess locational aspects of Nova Scotia's competitive position f or mine development relative to other Canadian regions and provinces. The appraisal concerns two representative mine development opportunities, a medium-size open-pit tungsten deposit, and a small underground gold deposit. The influence of regional economic conditions is initially assessed. Then, the consequences of taxation are isolated. Finally, the combined impact of regional and taxation conditions is examined. SettingThe economic potential of mining may be assessed in a number of ways. One approach, increasingly used for both corporate planning and government policy purposes, is to evaluate the competitive position of an actual or potential mineral producer in the international marketplace relative to other suppliers.Such examinations of competitive position vary from cost league comparisons of breakeven costs for operating mines, through the assessment of medium-term costs associated with developing new mine capacity, to long-term evaluations of the economics of mineral supply from the start of exploration. The complexity of the analysis increase s with the scope and timeframe of interest. Many factors are involved. One component of competitive position is the quality of the mineral resources available. Other key factors include existing technology, wage and salary rates, labour productivity, the cost of capital, infra structure requirements, distances from sources of materials supply an d to mineral markets, management attributes, organizational efficiency, government mineral policies (particularly taxation), and inflation and exchange rates. The paper fits within this competitive position framework.The variable economic conditions which exist within Canada have a direct bearing on the viability of mine development and, thereby, on mineral exploration potential. The paper examines locational aspects of Nova Scotia 's competitive position."

Jan 1, 1986

By R. A. Campbell

Pig iron and silicospiegeleisen were produced experimentally from a very low-grade manganiferous iron ore from Steep Rock, Ontario, by a two-stage electric smelting process. The most favourruble operating conditions were determined for each stage. Cement clinker then was made by calcining the slag from the second stage of smelting, with additional limestone and alumina. (This slag would normally be a waste material). The cement clinker produced had the composition of commercial Portland cement, and met the physical test requirements of the Canadian Standards Association Specification A5-1951 for normal Portland cement as well as could be expected for a material produced on .such a small scale.

Jan 1, 1958

By R. F. Favreau, L. C. Lang

"In modern blasting technology blasts are designed and analysed on an energy-mass-time relationship. The energy of the explosive is derived by computer analysis and the work potential of the available energy is expressed in numerical values. The mass involved in the blast is determined by the geometry of the blast and by the rock density. Time is also a relevant parameter, because time is required to complete the three basic stages of the breakage process.For successful application of the blasting parameters the basic mechanism of the breakage process must be understood.The physical-mechanical properties of the rock, local structural geology and the thermodynamic properties of the explosives can be brought together to create a computer model of a blast with which it is possible to predict separately the results of each parameter and to express the predicted degree of change in any parameter by actual numbers.A long-range project has started to create a ""bank"" of rock properties for as many Canadian and foreign mines as possible. A computer model has been successfully applied to predicting the effect of varying the ratio of spacing to burden at constant rock volume and significantly improved results are achieved, as the S/B ratio is increased up to about 2 to 2.5.High-speed photography has been applied to determine the time that has elapsed between zero time and the beginning of movement of the mass. The results assist in determining minimum and optimum delay time required for multiple-row blasting.The approach as described in the paper is now well proven and is clearly superior to previous methods based on powder factors and human assessment."

Jan 1, 1972

By Allan P. Fawley

ONE hundred miles from Vancouver, at an elevation of 4,000 feet, is the Pioneer mine. It is situated on Cadwallader creek, a tributary of Bridge river, and is reached by travelling from Vancouver to Squamish by boat, a distance of thirty-two miles, from there by train to Bridge River (one hundred and seven miles), and finally by automobile across Mission mountain .(7,000 ft. elevation) to the mine (fifty-six miles): a total distance of one hundred and ninety-five miles. Prior to 1924, many Companies had examined the Pioneer, which had been developed by shaft to a depth of 200 feet, but, while values were good, the small size of the ore-shoot discouraged large investors. In July, of that year, opera-tions were re-commenced by the late David Sloan and, on sinking further, the ore-shoot was found to lengthen greatly as well as to ex-tend in depth, while remarkable gold values also were encountered. When, later, the price of gold rose from $20 to $35 per ounce, the mine was in an excellent position to take full advantage of the increase + and not only became an extremely profitable enterprise itself but its success greatly stimulated the search for and development of other 1-gold properties in British Columbia.

Jan 1, 1937

By C. E. Smith, R. J. Inglis, M. I. Brittan, J. H. Schoeman

"AbstractA number of plant-scale cyanidation tests were carried out in an attempt to uncover the causes of fluctuations in gold recovery efficiency. Computer analysis of the results verified that the treatment of reclaimed waste rock material along with normal run-of-mine ore was having an adverse effect on metallurgical efficiency. Mineralogical examinations showed that the free gold particles in the dump material were heavily tarnished or coated (predominantly by hydrated iron oxide), accounting for the lower recoveries. The indications were that the effect could be counteracted somewhat by using higher than normal cyanide and lime reagent concentrations and adequate leaching times. Analysis of the results showed further that leach pulp density was an important operating parameter affecting extraction efficiency. A variable activation energy leaching model provided an extremely good characterization of individual batch leach runs.IntroductionFLUCTUATING METALLURGICAL EFFICIENCY at the gold concentrator of the S.A. Land and Exploration Company Limited (""Sallies"") prompted some plant-scale cyanide leach studies in an endeavour to uncover the causes of the variations in gold recovery."

Jan 1, 1977

By Hani Henein

Most metals and alloys processed undergo a solidification processing step. Increasingly, there is a growing number of solidification processing routes that involve rapid solidification of the alloy. These include strip casting, high pressure die casting, 3D printing, and atomization for the production of powders or spray formed parts. By contrast, there are few experimental techniques developed to study the solidification path of alloys during rapid solidification. Amongst these laser melting and solidification, Electromagnetic Levitation (EML) and Impulse Atomization (IA) are the most prominent. Of relevance is the formulation of the solidification path of an alloy and the resultant identification and quantification of metastable phases and their relationship to processing conditions. This typically involves the understanding of the interplay between undercooling and cooling rate for the various phases that form. This presentation will outline some of the methodologies developed to quantify phase fractions and their solidification path as a function of processing conditions using EML and IA.

Jan 1, 2016

By M. A. Hardie

"CASES and mixtures of them are so common and so much a part of everyday existence that they become so taken for granted that their individual characteristics and idiosyncrasies rarely become of curiosity to others than those involved in tl1eir production, processing, treatment, transportation, and for utilization. The use of the most common and universal mixture of gases -air -is begun at birth by ail living creatures and their discontinuation of its use terminates existence. Modern man rides on air in his tires, rides through it for high-speed transportation, and uses it for his comfort in the heating and air conditioning of his domicile. It is neither the aim nor the in-tent, in the next few moments, to provide a panacea for even a portion of the problems inherent in the gas industry nor to delve deeply into any particular facet of its diversities. The purpose is primarily to touch upon some of the peculiarities and generally to consider approaches to employ in the pursuit of solutions."

Jan 1, 1959

By R. R. Irrinki

Abstract -The Key Anacon deposit consists of four sulfide zones called, from south to north : Key Anacon No. 1, Key Anacon No. 2, Key Anacon No. 3, and Key Anacon Copper Zone. Massive sulfides of zones 1, 2, and 3 are underlain by rocks correlated with the Nepisiguit Falls Formation and are overlain by matie volcanic rocks correlative with the Boucher Brook Formation. In contrast to zones 1, 2, and 3, narrow northwesterly-trend.ing, copper-rich fracture zones occur within the Patrick Brook Formation. Sulfides in zone 2 occur as three mineralogical associations, namely: pyrite-chalcopyrite, pyrite-sphalerite-galerta, and pyrrhotite-sphalerite-galerta. The distribution of lithologies and en-echelon patterns of the three sulfide lenses of Key Anacon No. 2 zone are the result of F1 and F2 folding. Zone 2 is the most promising economically, with proven reserves of 1.11 million tonnes grading 0.2207o Cu, 3.47% Pb, 8.41% Zn, and 96 g/t Ag; the zone is open below a depth of 427 m.

Jan 1, 1992

A newly developed damage model was used in the study of rock fragmentation mechanisms involved in crater blasting. Simulations show that at the detonation of the explosive charge, a crushed zone around the explosive charge is formed due to compressive failure and then a strong pressure wave is sent out forming a pressurized ring that propagates at the dilatation wave velocity. As the pressurized ring leaves the crushed zone, two tensile stress components perpendicular to the radial stress are developed in response to the action of the radial pressure, causing tensile failure and forming a damage zone around the charge. The formation of this damage zone is quite independent of the depth of the explosive charge provided there is no interference by the reflection from the free face. When the pressurized ring reaches the free face, it is reflected there and causes rock failure on the ground surface that forms another damage zone. Under the simulation conditions, it is revealed that the depth of charge is a factor controlling the relationship between the two damage zones. At a depth smaller than the optimum, the two damage zones coalesce into one and there is excessive rock breakage; otherwise, the two damage zones tend to isolate from each other with the increase in the depth of charge. Calculations of fragmentation indicate that the average fragment size increases and the uniformity of fragments decreases when the depth of charge increases as observed in practical blasting.

Jan 1, 1998

By K. G. Baxter, D. G. Dixon

The Sepon process plant utilises an autoclave to oxidize a flotation concentrate containing pyrite, residual copper minerals, and sulphur. The concentrate is produced from the residue of a preceding atmospheric copper leaching circuit. The function of the autoclave is to provide iron and acid for that atmospheric copper leaching circuit. The key issues in the operation of the autoclave are to maximise the production of acid and ferric ions and to avoid scaling issues related to sulphur balling in the autoclave. Scale control in the autoclave was examined using various dispersants and residue recycle without success. Operation of the autoclave at high temperature and high acidity addressed the scale issue through rapid oxidation of the sulphur and produced a ferric sulphate precipitate in the residue that could be re-leached to provide ferric iron. This paper presents the development steps followed, through batch and continuous piloting that resulted in an autoclave circuit design that addressed the above process requirements. Following definition of the process design basis, modelling of the autoclave operation was carried out to assist with engineering design. The model included thermodynamics and kinetics of oxidation of pyrite, elemental sulphur and covellite and also considered gas/liquid mixing, oxygen solubility as a function of temperature and solution composition, ferrous to ferric oxidation, gangue reactions with acid and precipitation/re-dissolution of basic ferric sulphate and alunite.

Jan 1, 2004

By Lassi Klemettinen, Ari Jokilaakso, Dmitry Sukhomlinov, Pekka Taskinen

The solubilities and distributions of molybdenum and iridium in iron silicate slag and copper-iron mattes were studied using an equilibration-quenching technique and subsequent direct phase composition analyses by EPMA (Electron Probe X-ray Microanalysis) and LA-ICP-MS (Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry). The equilibrations were carried out on a wide matte grade interval, ranging from 55 wt-% Cu to 75 wt-% Cu, in pSO2 = 0.1 atm at 1300°C. The results in equilibrium with a solid iridium-molybdenum alloy indicated an iridium solubility of 150–500 ppmw in the sulphide matte, depending on the matte grade, and a molybdenum solubility of 100–600 ppmw. Iridium was distributing predominantly in the sulphide matte with the distribution coefficient of 10+3 - +4 but molybdenum deported predominantly in the slag with Lm/s(Mo) = 0.02–0.1. The effects of alumina and lime additions in the smelting slag were also examined. INTRODUCTION Iridium is a highly siderophile element (HSE), which means that it is incompatible with the sulphide forming elements and possesses a small solubility in mattes, such as copper- and nickel-iron sulphide melts. Molybdenum behaves only modestly in that way (Walker & Li, 2008; Righter et al., 2017). They both are known to be trace elements accompanying copper and nickel sulphide ores. No solubility data, however, are available for them in copper-rich sulphide mattes. Geochemical data on the behaviour of Ir and Mo deal mostly with low-iron silicate systems, e.g. basaltic melts, and high-sulphur sulphide solutions and mattes (Ertel et al., 2008; Fonseca et al., 2007). They also indicate that Ir and Mo dissolve in silicate melts primarily as oxides and not as electrically neutral metal species. Most geological data of iridium focus on high-sulphur systems of the monosulphide composition and typically Fe-Ni mattes where copper is a trace element (Fleet et al., 1996; Sattari et al., 2002). Direct solubility measurements for mattes and iron-lean silicates have also been made using pure Ir or an Ir alloy as the saturation phase (Borisov & Palme, 2000; O’Neill & Eggins, 2002; Makovicky & Karup-Møller, 1999; Ertel et al., 2008; Mungall & Brenan, 2014). A recent summary about the solubilities of HSE’s in iron- and sulphur free silicates is available in Laurenz (2012). The thermodynamics of molybdenum partitioning between oxides and Fe-S-O melts was studied by Mengason et al. (2011). Their results indicate strong accumulation in the iron-rich sulphide in reducing conditions (pO2 = 10-9.6 atm in Ni-NiO equilibrium at 1050°C). Molybdenum dissolves in iron-lean silicate melts as MoO3 species in oxygen pressures above the Fe-FeO equilibrium and as MoO2 in more reducing conditions (Farges et al., 2006; Righter et al., 2017).

Jan 1, 2019

By James F. Allan

"The Kipawa yttrium-zirconium prospect is located about 150 km south of Noranda, Quebec. Yttrium-zirconium mineralization occurs in an elongate, regionally metamorphosed and deformed peralkaline complex in the Grenville terrain. The mineralized zone, as defined by =.0.10% Y2O3, is 1300 m long and 10 m to 30 m wide. Zirconium content typically ranges from 0.50 to 1.20% ZrO2, The mineralized zone strikes northwest and dips 20 degrees to 35 degrees to the southwest. It occurs at the structural base of the peralkaline complex in syenite gneiss and calc-silicate rocks and is conformable with both the footwall contact of the complex, and the layering and gneissosity in the enclosing rocks. Minerals of economic interest are eudialyte (sodium-zirconium silicate), mosandrite (sodium-titanium silicate), britholite (calcium-silica phosphate), and a few other uncommon zirconium and titanium silicate minerals.The highest and most continuous yttrium grades occur in the upper part of the syenite gneiss unit in areas containing eudialyte, mosandrite and minor britholite. Yttrium also occurs in britholite in calc-silicate rocks and in mosandrite in syenitic rocks in the lower part of the syenite gneiss unit. Both the yttrium-bearing minerals and yttrium grades are erratic in the lower part of the unit. Zirconium is generally more uniformly distributed than yttrium. A peralkaline granite gneiss phase of the complex intrudes the syenite gneiss and possibly truncates it, and the mineralization, near the southern boundary of the mineralized zone.The mineralized zone is coincident with a radiometric anomaly and discontinuous yttrium and zirconium soil anomalies.More drilling and metallurgical studies will be required to determine the economic viability of the yttrium and zirconium mineralization at Kipawa."

Jan 1, 1992

By James F. Allan

"The Kipawa yttrium-zirconium prospect is located about 150 km south of Noranda, Quebec. Yttrium-zirconium mineralization occurs in an elongate, regionally metamorphosed and deformed peralkaline complex in the Grenville terrain. The mineralized zone, as defined by =.0.10% Y2O3, is 1300 m long and 10 m to 30 m wide. Zirconium content typically ranges from 0.50 to 1.20% ZrO2, The mineralized zone strikes northwest and dips 20 degrees to 35 degrees to the southwest. It occurs at the structural base of the peralkaline complex in syenite gneiss and calc-silicate rocks and is conformable with both the footwall contact of the complex, and the layering and gneissosity in the enclosing rocks. Minerals of economic interest are eudialyte (sodium-zirconium silicate), mosandrite (sodium-titanium silicate), britholite (calcium-silica phosphate), and a few other uncommon zirconium and titanium silicate minerals.The highest and most continuous yttrium grades occur in the upper part of the syenite gneiss unit in areas containing eudialyte, mosandrite and minor britholite. Yttrium also occurs in britholite in calc-silicate rocks and in mosandrite in syenitic rocks in the lower part of the syenite gneiss unit. Both the yttrium-bearing minerals and yttrium grades are erratic in the lower part of the unit. Zirconium is generally more uniformly distributed than yttrium. A peralkaline granite gneiss phase of the complex intrudes the syenite gneiss and possibly truncates it, and the mineralization, near the southern boundary of the mineralized zone.The mineralized zone is coincident with a radiometric anomaly and discontinuous yttrium and zirconium soil anomalies.More drilling and metallurgical studies will be required to determine the economic viability of the yttrium and zirconium mineralization at Kipawa."

Jan 1, 1992

By A. K. Mahto, B. Samanta

"A heuristic model was developed to simultaneously generate the ultimate pit and production scheduling at a mining project. The method consists of a preprocessing step to select a starter pit, the implementation of a genetic algorithm to optimize the pit and schedule of the starter pit, and a network-flow algorithm–based postprocessing operation to finalize the ultimate pit and production scheduling. Applied to an iron ore mine, the model pit and schedule produced a net present value 21% higher than the reference pit and schedule prepared by experienced field engineers.RÉSUMÉ Un modele heuristique a ete developpe pour generer simultanement l’ordonnancement de la fosse finale et de la production dans le cadre d’un projet minier. Cette methode comprend une etape de pretraitement visant a selectionner une premiere fosse, la mise en oeuvre d’un algorithme genetique pour optimiser la fosse et le calendrier d’execution de cette premiere fosse, ainsi qu’une operation de posttraitement basee sur des algorithmes de flux reseaux pour finaliser l’ordonnancement de la fosse finale et de la production. En l’appliquant a une exploitation de minerai de fer, ce modele de fosse et d’ordonnancement a genere une valeur actualisee nette (VAN) superieure de 21 % a l’approche de reference pour la fosse et l’ordonnancement developpee par des ingenieurs de chantier chevronnes. INTRODUCTIONLong-term planning for an open-pit mine involves two important activities: developing the ultimate pit and determining the optimum production schedule. To accomplish this, an ore deposit is discretized into a number of smallsized elements called blocks, which are presented in a 3D block model structure. Because of economic and slope criteria, only a certain set of mining blocks can be extracted from the deposit constituting a pit. During mining, these blocks must be extracted in a specific sequence known as the production schedule."

Jan 1, 2017

By A. F. Sirianni

The Peace River iron ore deposit represents the sole source of raw material for an integrated steel industry in Alberta. The ore has proved refractory to beneficiation by a number of techniques. A selective oil-phase agglomeration technique is described. Medium-grade concentrates, analyzing 48-53% Fe and 10-14% SiO2 were obtained with recoveries of about 75% of the total iron. These results appear to represent the optimum possible for this ore body.

Jan 1, 1977

By B. Yu, S. Kelebek, C. Gibson, M. Aghamirian

There are a number of high grade niobium deposits worldwide which have been deemed untreatable by flotation due to the very fine grained nature of the in situ pyrochlore, the primary niobium bearing mineral. A known method of recovering extremely fine particles is through the use of chelating reagents such as hydroxamic acids which have a strong affinity for transition metals. However, one of the major issues in the flotation of niobium bearing minerals using hydroxamic acids is the corresponding recovery of other transition metal gangue minerals including magnetite, hematite, and pyrite. In order to better understand the differences in behavior of niobium and iron bearing minerals in flotation with benzohydroxamic acid (BHA) and sodium hexametaphosphate (SHMP) at a range of pulp temperatures, a Box-Behnken experimental design was employed. Regression models for the global recovery of iron indicated that iron mineral recovery was significantly influenced by both BHA and SHMP dosage. Upon examinination of flotation products by semi-quantitative XRD, it was observed that recovery of iron oxide and sulphide minerals (hematite, magnetite, goethite, and pyrite) was problematic at high benzohydroxamic acid dosage, while sodium hexametaphosphate was mainly helpful for carbonate mineral depression. Iron rich carbonates (likely an iron rich dolomite) largely reported to the tails with increased SHMP dosage.

Jan 1, 2015

By M. A. Rabah

This study aims to recover europium, yttrium metals, some valuable salts or oxides from the white powder (apatite) coating the inner surface of spent florescent lamps (SFLs). Pressure leaching using sulphuric/nitric acid successfully dissolved the metals of interest. Europium or yttrium metals were obtained by hydrogen reduction of their oxides. Addition of potassium thiocyanate converted the dissolved sulphates to thiocyanates. Selective separation of Eu and Y was then carried out by solvent extraction from the thiocyanate solution. The used solvent was trimethyl-benzylammonium chloride. N-trihutylphosphate in 1 M nitric acid was used to strip the metal loaded in the organic phase. Results showed that the quality of the cleaned glass tubes of the SFL met the standard requirement for the lamp manufacture. The white powder (WP) is composed of calcium sulphate 35.2%, phosphate 61.5% and oxides of europium and yttrium 1.65%wt. respectively. Autoclave digestion of the WP for 4 h at 120°C and 500 kPa in sulphuric acid/nitric acid mixture dissolved 96.4% of yttrium and 92.8% of europium. The conversion rate of sulphate to thiocyanate was favoured at low temperature. Stripping of Eu and Y from the loaded organic phase behaved in an opposite way. A metal separation factor of 9.4 was obtained. ate recovered europium and yttrium salts were selectively separated using ethyl alcohol or dilute nitric acid. Yttrium was very soluble while europium was not. Europium and yttrium metals were obtained by hydrogen gas reduction at 850°C and 1575°C respectively.

Jan 1, 2004

By O. G. Olvera

"Refractory sulfidic ores consist of materials in which gold occurs finely disseminated within metallic sulfides or forming solid solutions, with pyrite and arsenopyrite being the two sulfides most commonly associated with gold. Typical cyanide operations show poor performance and require oxidative pretreatments to increase gold recovery. Pretreatment alternatives include roasting, pre-aeration, acidic and alkaline high pressure oxidation, and bacterial oxidation. The presence of arsenic, however, introduces a serious disadvantage to the use of roasting and bacterial leaching, while high pressure oxidation involves high capital costs. This work focuses on evaluating the effect of the addition of a carbon resin as a sulfur collector on the oxidation of different arsenopyrite concentrates under atmospheric tank leaching (ATL) conditions. The addition of the resin improved the oxidation of sulfides and favored the formation of elemental sulfur over the generation of sulfate. The use of AF5 in ATL resulted in higher gold recoveries under standard cyanide carbon-in-leach and thiosulfate leaching.INTRODUCTION Refractory sulfidic ores consist of materials in which gold occurs finely disseminated within metallic sulfides or forming solid solutions, with pyrite and arsenopyrite being the two sulfides most commonly associated with gold. Gold is not readily accessible to solutions in these types of ores and typical cyanide operations show poor performance, thus making the use of oxidative pretreatments a requirement to increase gold recovery. Pretreatment alternatives include roasting, pre-aeration, acidic and alkaline high pressure oxidation, and bacterial oxidation. The presence of arsenic, however, introduces a serious disadvantage to the use of roasting and bacterial leaching, while high pressure oxidation involves high capital costs. The use of carbonaceous materials to enhance the dissolution of sulfides is not novel, and leaching additives such as coal, activated carbon and carbon powder have been considered for the improvement of bioleaching, atmospheric leaching, and pressure oxidation leaching processes. However, this type of technology has been focused mainly on the recovery of copper from copper concentrates containing chalcopyrite with less attention paid to other sulfides."

Jan 1, 2017