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By L. Voisin, K. Yamaguchi, D. G. Mendoza, K. Ltagaki

The behavior of arsenic and antimony in the Cu-0 system was thermodynamically investigated to understand their elimination during a blister-making stage in copper smelting. Firstly, the phase relations in a miscibility gap composed of the liquid slag and copper phases in the Cu-0-As and Cu-0-Sb systems at 1523 K were established by a quenching technique. It was found that arsenic and antimony distributed preferentially into the slag phase in the miscibility gap. Secondly, the activities of arsenic and antimony in the miscibility gap of these systems were determined at 1523 K by using a double Knudsen cell - mass spectrometer method. It was clarified that the activity of arsenic in the copper and slag phases showed the negative deviation from ideality while that of antimony in the copper phase a slightly positive deviation. These data obtained in this study suggest a possibility to eliminate arsenic and antimony by means of over-blowing in a converter after discharging the slag.

Jan 1, 2007

By H. L. Martin

A joint federal-provincial approach in gathering basic information from industry on mine production, concentrator operations and ore reserves, initiated during 1978, is a major step toward the goal of achieving better government-industry communication through a common data base. Information from questionnaires sent out by provincial governments is shared with the federal government; correct interpretation is ensured by mine visits conducted jointly by provincial and federal representatives. Initial focus is on nonferrous metal mines. The federal Department of Energy, Mines and Resources (EMR) is responsible for a national analysis that is aimed at the early detection of worrisome developments-and their reasons-in the flow from resources to reserves and from reserves to supply of these metals. The heart of the national analysis is the annual construction of a "monitoring curve", showing each metal's aggregated mine production as it would decrease over time if no new reserves and production capacity were to be added from the year of analysis. For a given metal, a comparison of monitoring curves from year to year can reveal early signs of supply stagnation. In anyone year, a monitoring curve in conjunction with foreseen needs for Canadian mine output will show the production gap that would have to be filled from reserves and production capacity yet to be developed. The production gaps for copper, nickel, zinc and lead, the four leading base metals mined in Canada, are shown for the 20-year period ahead, in the context of production achieved during the past 20 years. It is shown that reserve levels commensurate with likely future production levels would require that average annual reserve additions during 1978-98 exceed the average annual additions during the preceding 20 years. Reserve levels of all four metals have declined in recent years. A review of significant discoveries in the last five years suggests that this fall in reserves is not the result of a lack of exploration successes, but of stagnation in development for various economic reasons.

Jan 1, 1979

By G. G. Eichholz

SUMMARY RADIOACTIVE dynamite has been prepared by introducing a small amount of antimony-124 into the explosive. Test work is described on the effectiveness of this tracer, on radiation levels in its neighbourhood, and on different methods of .application. Factors determining the choice of isotope, amount of activity, and overall cost of this process are discussed. INTRODUCTION Instances are known in which dynamite remains unexploded in drill holes in mining operations. Usually such 'bootlegs' are easily located by inspection of the face and the powder is removed before subsequent drilling is started. Occasionally, however, serious accidents occur because workmen drill into an undetected piece of dynamite. In order to avoid such accidents it was suggested that a different method of location might be tied, such as that afforded by the use of radioactive tracers. This paper describes some experiments that were carried out under the auspices of the Department of Mines and Technical Surveys, with the active co-operation of Canadian Industries Ltd. and Canadian Refractories Ltd., to test the feasibility of such a scheme.

Jan 1, 1957

By K. Yoshida

Recently, light magnesium alloy with superior heat radiating ability has been attracting attention in various fields. However cold plastic working of the alloy is very difficult and hot working necessary. Furthermore, the magnesium of products with complicated shapes is difficult, the processing cost is high, and the applicability of the alloy is limited. In this study, a technique for obtaining fine wires and tubes by cold drawing is examined to obtain wires and tubes with high strength, quality and surface morphology, while decreasing production cost. In addition, the shearing strain of magnesium alloy wires and tubes drawn under various drawing conditions was calculated by FEM analysis. It was clarified that cold drawing of magnesium alloy is possible. It was also demonstrated that greater reduction of the cross-sectional area could be realized during cold wire and tube drawing by optimizing the drawing conditions.

Jan 1, 2006

By J. A. Jr. Carpenter

Expanding world economic prosperity, probable peaking of conventional petroleum production in the coming decades and environmental concerns require efforts to increase the efficiency of, and the development of alternatives to, petroleum-based fuels used in automotive transportation. In January 2002, the U.S. Department of Energy (USDOE) and the U.S. Council for Automotive Research (USCAR) of the "Big Three" traditionally-USA-based automakers, DaimlerChrysler, Ford and General Motors, formed the Freedom Cooperative Automotive Research (FreedomCAR) Partnership to fund high-risk, high-payoff research into advanced automotive technologies with the potential for eventually lowering the USA's nearly complete (95%) dependence on petroleum, 55% imported, for its transportation fuels. FreedomCAR replaced the Partnership for a New Generation of Vehicles (PNGV) which existed from 1993 to 2001. In January 2003, the energy-supply industry joined with the FreedomCAR Partnership forming the FreedomCAR and Fuel Initiative (FC&FI) to develop the technologies needed for the mass production of fuel-cell vehicles using hydrogen as fuel and the infrastructure needed to deliver the hydrogen to the consumer. The goal is to enable the automotive and energy-supply industries to make commercialization decisions in 2015 on large-scale introduction of such vehicles and on developing the infrastructure beginning in 2020. In addition to work on fuel cells and hydrogen infrastructure, the FC&FI conducts research on technologies with the potential for nearer-term energy efficiency and environmental benefits, such as new engine concepts, lightweight materials, and engine-electric hybrid propulsion systems. Lightweighting is seen as crucial for shorter and for longer term benefits because hybrid and fuel-cell powertrains are expected, at least in the early stages of adoption, to be heavier and more costly per unit of power than the standard internal-combustion, gasoline- or diesel-fueled powertrains they replace. Research and development (R&D) on casting of aluminum automotive components were major parts of the PNGV and R&D on casting of magnesium automotive components have been and are so under FreedomCAR. This presentation will review those efforts.

Jan 1, 2006

By Francis Gray

Mr. F. W. Gray: It is not my intention to read my paper as it is too long, so I will touch only on the high lights. The Sydney field is the most favourable example of undersea coal mining that exists, and I have not been able to find anything like it elsewhere. The nearest approach to it is a field in England where the Whitehaven collieries are operating, but it has a lot of faults. The net result of these faults so far met with in the seaward advance of the workings has been to increase, by something over 100 feet, the gain in depth of cover, in a distance of approximately three and three-quarter miles. In the Sydney field there are no faults of any consequence. On the east side, the English measures rise. In Australia the sea bottom fell and the cover became too light. On Vancouver Island the coal ran out, and in Japan the seams are steep and contorted. The Chilian fields resemble our own to some extent. An inundation of two collieries took place there some time ago, due, it is said, to the rise workings being allowed to approach the sea bottom too closely in the vicinity of a fault. The Cape Breton undersea field has been proved over a frontage of about thirty miles and has been attacked and penetrated for a considerable distance along that front. We have passed the prospecting stage and now generally use developed land areas as points of attack to win the undersea coal. Of our mining under the sea, it can be said that, with the exception of No. 1-B and Princess colliery, Sydney Mines, no real attempt has been made to win the undersea coal.

Jan 1, 1927

By E. C. W. Perryman

BEFORE describing the methods used for fabricating uranium into various shapes and sizes it is necessary to illustrate briefly the unusual conditions under which uranium has to operate when used as a fuel element in a reactor. During reactor operation, for every fission that occurs two atoms of intensely radioactive fission products are produced together with two or three neutrons. The neutrons that are ejected possess several m.e.v. of energy and when one of them strikes an atomic nucleus, that atom acquires up to 105 e.v. of kinetic energy. This is large enough to displace the atom from its lattice position and send it shooting through the crystal, displacing other atoms out of their lattice positions. The net result is that a large number of vacancies and interstitial atoms are formed within the crystal lattice which sometimes have profound effects on the physical and mechanical properties of the material in question.

Jan 1, 1957

By Geology Staff, C. H. Stockwell

"The Flin Flon base metal mine, owned and operated by the Hudson Bay Mining and Smelting Company, is on the Manitoba-Saskatchewan interprovincial boundary at a point 400 miles north of the International boundary. The deposit was discovered in 1914 by Thomas Creighton and the Mosher and Dion brothers. Since production commenced in 1930, 25,000,000 tons of ore have been mined. On January 1st, 1946, reserves were estimated to be 26,000,000 tons, averaging 2.99 per cent copper, 4.i4 per cent zinc, and 0.089 oz. gold and 1.25 oz. silver per ton. In addition to the four metals named, others recovered from the ore include- cadmium, selenium, and tellurium. The mine workings extend to the 3,750-foot level, but little development work has yet been carried on below 3,250 feet.The known ore occurs in six lenticular to irregular bodies within a zone 500 feet wide. These bodies average 900 feet long, 70 feet wide, 1,500 feet in vertical depth, and 2,500 feet in length along the plunge. They were formed by replacement of the country rock and include ore of two types, solid sulphides and disseminated sulphides. Seventy per cent of the total known ore is of the solid sulphide type. This consists essentially of metallic sulphides- chiefly pyrite- with included remnants of the host rock, and additional quartz and carbonate. In places, the ore exhibits banding, inherited from pre-existing structures. The disseminated ore occurs usually on the footwall side, and along the bottom of the plunge, of the solid sulphide bodies."

Jan 1, 1954

By Guy Chevalier

The QCM Mount-Wright mine and concentrator complex produces about 14 M tonnes of iron concentrate annually. Approximately 9.5 M tonnes of this concentrate are used to produce iron ore pellets at four different silica grades: Three for blast furnace operations and one for direct reduction furnaces. The paper presents the scientific approach that led to the realization of two projects where the acquisition of new process equipment led to an improved pellet plant iron recovery, a better flexibility and to lower operating costs as well as to the production of fine iron ore concentrate from the Port-Cartier tailings pond. Typical 4.8 % SiO2 concentrate is processed to achieve required pellet silica content. This is obtained with the aid of hindered settlers or hydraulic classifiers, screens, whims and, lately, spirals. The increasing demand for low silica iron ore products resulted in a greater need for upgrading. The Pellet Plant upgrading capacity being limited, more and more iron units were lost. Base on test works results and economic evaluations, QCM engineers figured out a way to increase efficiently their upgrading plant capacity and go back in the pond gather what has been lost in recent years of operation.

May 1, 2007

By Neil Westoll

But First, An Overview of the Selwyn Basin and Its Resources ?World-renowned sedimentary-exhalative (SEDEX) deposits of zinc, lead, silver +/-barite ?Significant reserves/resources remain and vast tracts of prospective stratigraphyremain under-explored and untested. ?More details are at the Yukon Geological Survey?s Selwyn Basin Metallogenysite:http://www.geology.gov.yk.ca/metallogeny/selwyn/ Overview of Metal Price and Demand Trends ?The pace of economic change in China has been extremely rapid since the start of economic reforms just over 25 years ago. According to official statistics, economic growth has averaged 9.5% over the past two decades and seems likely to continue at that pace for some time. National income has been doubling every eight years. Such an increase in output represents one of the most sustained and rapid economic transformations seen in the world economy in the past 50 years.? Organization for Economic Co-operation and Development 16-Dec-2005

May 1, 2006

By G. M. Ritcey, S. H. Lucas

"On the north shore of the St. Lawrence River, in Quebec, are located orebodies of low-grade titaniferous magnetite. The Quebec Mining Exploration Company (SOQUEM), who have an interest in the deposits, believed that beneficiation of the could generate sufficient revenue to defray the mining costs and the costs of transporting the ore to a steel production facility. A joint research project of SOQUEM and CANMET investigated alkaline roasting of a magnetic concentrate, followed by leaching of the calcine and separation and recovery of Cr and V by solvent extraction. Aluminum was recovered by precipitation.The present paper describes the roast-leach bench-scale and pilot-plant work leading to the development of the optimum conditions f or the integrated process.A plant flowsheet was developed for the treatment of 5 x 106 tons of magnetic concentrate per annum. Estimates of capital and operating costs were made.Based on a recovery of approximately 90% V, 85% Cr and 75% AI, the total hydrometallurgical plant fixed capital costs, including mining, concentration and shipping, are estimated at $1.021 x 109; the operating costs are estimated at $131.92/ton concentrate. Annual revenue from the Na2CrO4.H2O, V2O5 and A12O3 produced is calculated to be $421 x 106.IntroductionThe Quebec Mining Exploration Company (SOQUEM) acquired in 1968 an interest in four titaniferous magnetite orebodies located in Eastern Quebec. 85 miles north of Mingan on the north shore of the St. Lawrence River. The Mingan deposit, with an estimated tonnage of one billion tons, has a reported average grade of 43% Fe, 6.3% Ti , 1.60% Cr, 0.19% V and 6.1% Al with minor amounts of nickel. SOQUEM, on the basis of previous bench-scale data, believed that the recovery of chromium, vanadium and alumina by alkaline roasting would generate sufficient revenue to defray the mining costs and the costs of transporting the ore to a steel production facility on the coast. One of the approaches selected by SOQUEM for beneficiation of the ore consisted of a combination of magnetic concentration followed by alkaline roasting of the calcine."

Jan 1, 1980

By N. Shi, T. G. Joseph

The design of dippers for cable shovels has essentially remained unchanged for the last 100 years. In the past 10 years, shovel manufacturers have started taking another look at dipper design, resulting in changes that have borne models from major manufacturers that address some of the wear conditions and material retention problems that dominate maintenance and operational costs. However, with the exception of added lateral curvatures to the front and corners of the dipper, the geometry is essentially unchanged. This paper looks at the criteria that have resulted in the first new cutting dipper design in a century. The design is based on kinematic considerations, reflected in a revolutionary geometry that matches the range of motions of the shovel, designed to minimize wear, impact loading and power required to dig, thus maximizing productivity for a minimum energy requirement. The shape configuration is such that the weight of the dipper is reduced through wall thickness, enabling a larger capacity dipper to be conceived for the same shovel. Benefits are reflected in reduced operational and maintenance costs and increased productivity.

Jan 1, 2006

By L. R. Bottomer, G. M. Leary

"The Copper Canyon property is located in the Galore Creek area of northwestern British Columbia. Porphyry copper-gold mineralization on the property is notable for its high gold content and close spatial relationship with a distinctive suite of high level syenitic and monzonitic intrusions, and pseudoleucite-bearing volcanic country rocks. The style of alteration and mineralization is similar in many respects to the nearby Galore Creek deposits.The current geological resource of 32.4 million tonnes grading 0.75% Cu, 1.17 g/ t Au and 17.1 g/t Ag is insufficient to support a mining operation, but definition of additional reserves combined with improved transportation infrastructure in the region may change this in the future. The climate, topography and proximity to an active glacier indicate that the most likely production scenario is an underground bulk mining operation, with the ore being milled offsite.IntroductionThe property is located at 57°07' North latitude, 131 °21' West longitude, on NTS sheet 104G/ 3W, approximately 160 km northwest of Stewart and 90 km south of Telegraph Creek (Fig. 1). The Galore Creek camp and airstrip are located 6 km to the west. Current access to the property is via helicopter either from Galore Creek, or from the Bronson Creek airstrip 32 km to the south-southeast.The deposit occurs within the Boundary Ranges of the Coast Mountains, on the north side of the east fork of Galore Creek, which flows northerly into the Scud River and thence westerly to the Stikine River.Topography is rugged. In the deposit area, elevations range from 1130 m to 1750 m. Valley glaciers and permanent snow and ice fields are characteristic of the region at these elevations, and at its southern limit, mineralization is truncated by the East Fork Glacier.The property is entirely above the treeline, and except for areas of moraine cover and talus slopes, outcrop is abundant."

Jan 1, 1995

By Derek H. C. Wilton

"The Nain Province (NP) of northern Labrador is a >600 km long by =100 km wide Archean craton that has undergone relatively little mineral exploration until economically signifcant concentrations of orthomagmatic nickel sulphide were discovered by Diamond Fields Resources (DFR) at Voisey’s Bay. Due to the great time span between crust formation andfnal intrusive activity (ca. 3.9 Ga to 1.27 Ga),there were, however, numerous metallogenic events within the NP.The NP was intruded by the ca. 1.3 Ga to1.2 Ga Nain Plutonic Suite (NPS) composite anorthosite-granite complex. The NPS dividesthe NP into the southern Hopedale Block (90 km by 150 km) and the northern SaglekBlock (375 km long by =50 km wide). These two blocks appear to represent two distinct Archean cratonic nuclei, each with its own distinct metallogenic history. The NPS is a coalesced assemblage of composite intrusions which include anorthosite, troctolite, norite, gabbro and granite.The Hopedale Block contains the Hunt River and Florence Lake greenstone belts, and the Weekes Amphibolite which represents remnantsf the older Hunt River greenstone belt. Geologically, these belts have some potential to host komatiitic Kambalda-style nickel, volcanogenic massive sulphide (VMS) and meso -thermal lode gold mineralization. The unconformity between Paleoproterozoic cover sequences and the trondhjemite-tonalite-granodiorite (TTG)suite which engulfed the greenstones was the locus for lead-zinc-bearing quartz-carbonate veins. Minor fracture-hosted uraninite showings are also present in the TTG.The Saglek Block is a high-grade gneissterrane with deformed Archean supracrustal sequences but no greenstone belts. Within the gneiss are variably-sized enclaves that range in composition from anorthositic to ultramafic; some of these latter xenoliths contain abun-dant fuchsite. There are also three small anorthositic to ultramafic meta-igneous complexes present in the gneiss near Okak Bay.Some Archean meta sedimentary and maficgneiss supracrustal sequences contain iron-oxide and sulphide members. The sulphide-bearing Tasiuyak parag neiss defines the cra-tonic suture between the NP and Churchill(Rae) Province. Along the cratonic suture between the NP and Churchill Province from Ramah Bay north are remnants of the Archean(or Paleoproterozoic) Hutton Anortho site Suite. Ultramafc layers within the suite contain chromite and elevated Ni values.Three ca. 2.0 Ga supracrustal sequenceswere deposited in small fault-bounded basins within the NP. The Snyder Group contains pyrrhotitiferous massive sulphide horizons. TheMugford Group contains SEDEX-like massive sulphide blocks in a debris fow and ultramafic sills with unusual PGE concentrations; alaskitic granite cutting basement gneiss to the group contains stockwork-like pyritiferous quartz veins. The Ramah Group contains numerous MVT-style zinc-lead sulphide occurrences.The Reid Brook Intrusion of the NPS contains enormous and high-grade nickel-copper-cobalt massive sulphide bodies at the Voisey’s Bay deposit. Exploration in the northern portions of the NPS in 1995 has indicated the presence of other potentially economic nickel sulphide horizons."

Jan 1, 1996

By G. E. Agar

This paper deals with the prediction of locked cycle flotation results from data developed from individual batch tests. A postulate is made that the distribution of material in a separation stage is determined by the chemical conditions and the flotation time and that this distribution can be characterized by split factors which are constants for a fixed set of conditions. With this premise, it is demonstrated that a steady-state balance can be calculated for a circuit. Although the necessary equations can be solved algebraically, a computer program was written that uses an iterative technique to arrive at the steady-state balance. The program is written so that a variety of circuits can readily be simulated. A number of examples are examined to demonstrate the validity of this simulation procedure. The sensitivity of the material balance to changes in the split factors was examined. Data developed from different flowsheets are presented on sulphide ores, on copper-nickel separation and on silver flotation.

Jan 1, 1978

By James R. Kuipers

Center for Science in Public Participation CSP2 ? Organized in 1997 to provide technical assistance to public interest groups on mining and water quality issues ? 80%of effort devoted to direct support of grassroots groups and tribal governments ? 20% of effort devoted to public-oriented education for public, tribal, state and federal regulators, and for industry ? Board represented by public interest groups, at large citizens, and academia ? Professional staff with experience from mining industry, academia and government ? website: www.csp2.org CSP2 Mission Statement The CENTER for SCIENCE in PUBLIC PARTICIPATION provides training and technical advice to grassroots groups on water pollution and natural resource development issues, especially those related to mining. CSP2 seeks to focus the debate on factual issues, as brought to light by its technical analyses, and whenever possible to seek consensus and win-win solutions. CSP2 also performs policy related work with federal and state regulatory agencies on the implementation of water quality, waste disposal, and mining reclamation regulations.

May 1, 2002

By X. Cao

Friction stir processing (FSP) is used to produce wrought microstructures at the surface of sand-cast aerospace grade magnesium alloy ZE41A-T5. It is found that the microstructure is significantly refined in the stir zone and the flow arm. The stir zone is largely comprised of equiaxed magnesium grains of approximately 4.5 pm compared with about 50 µm in the base cast material. In the stir zone, however, abnormal growth of some grains is also observed. Vickers microindentation hardness tests indicated that the stir zone experiences some increases in hardness. Single surface passes with low distortion, lack of pores and cracks were successfully obtained indicating the great potential of the FSP technique for modifying, improving and repairing magnesium alloy castings. This will probably open new opportunities to apply magnesium alloys in aerospace industry.

Jan 1, 2007

By M. K. Jain, Z. T. Xu, M. Bruhis, V. Hegedekatte

"Strain rate and temperature dependent deformation conditions are present during elevated temperature forming of aluminum and other metallic materials. While many constitutive laws have been proposed to represent such deformation conditions, a closer investigation often reveals their limited applicability in terms of fit to the experimental data, and interpolation within and extrapolation outside of the range of experimental stress-strain curves. This is often because material-specific primary deformation mechanisms of temperature-dependent strain and strain rate hardening are poorly captured. In the present work, the Voce-Kocks constitutive model based on mechanics of dislocations storage and annihilation has been found to be suitable for many metallic materials. The model was modified to include the effect of temperature dependent shear modulus. The modified model is then employed to represent the experimental data obtained from uniaxial tensile tests on AA7075-O sheet at elevated temperatures and strain rates. Also, hot gas bulging tests were conducted to verify the applicability of this model. Further, finite element simulation of the hot gas bulge test was performed by incorporating the model as a user material subroutine. Good general agreement was observed between the experimental and FE model predicted results. Some sources of discrepancy in the prediction are also discussed.INTRODUCTION There has been much interest in light-weighting of automobiles from automotive related industries to reduce overall carbon footprint and increase energy efficiency of the vehicles. Aluminum alloys, and especially the medium-strength 5xxx and 6xxx series alloys, have been the primary focus in the last 3 decades to reach the above environmental goals (Huo, Hou, Zhang, & Zhang, 2016) whereas aerospace industry has traditionally focused on high strength 7xxx series aluminum (Al-Zn-Mg-Cu) alloys for structural components (Deng, Yin, & Huang, 2011). Recently, there has been much interest in high strength 7xxx series aluminum as a replacement for heavier steel automotive structural parts such as A-pillar, B-pillar, side impact beams etc. (Harrison & Luckey, 2014). This is both interesting and challenging since the above aluminum structural parts will need to not only meet impact safety standards but also possess sufficient formability for manufacturing such complex parts. Since the formability of high strength 7xxx series materials is quite poor at room temperature, much interest has focused on improving both formability and final part strength via high rate hot stamping, in-die quenching, and subsequent artificial ageing process steps (Kumar & Ross, 2016)."

Jan 1, 2018

By Milton Fies

Introduction The first experiment in underground gasification of coal in the United States was conducted at Gorgas, Walker county, Alabama, under a co-operative arrangement between the U.S. Bureau of Mines and the Alabama Power Company, at the suggestion of the Power Company. The test was conducted on property of the Alabama Power Company, that owns some 19,000 acres of coal-bearing lands on which there is developed a highly mechanized mine producing some 2,500 cons of good quality steam coal per day. At the same locality ?there is a 200,000 kilowatt steam plant one of the largest in the southern portion of the United States. The Alabama Power Company owes much of its beginning in 1912 to British vision and courage. The original plans for building hydroelectric plants in Alabama, and for the construction of necessary transmission lines, were submitted to Sperling & Company, bankers of London, who agreed to underwrite certain bond issues, the proceeds of which would be used in launching the new Company on its programme. The set-up by which these funds from England were received was through an intermediary Canadian company, which the English investors desired. The Canadian company - Alabama Traction, Light and Power Company, Ltd. became owner of the securities of the Alabama Power Company and marketed its own securities through the banking house of Sperling & Company. Without assistance at this time the Alabama Power Company could not have gone ahead with its programme of expansion and the bringing together of the properties necessary for laying the foundation for a strong Company, fortified with ample power resources essential for future requirements and for dependable service to the public.

Jan 1, 1948

By T. C. Cheng, G. P. Demopoulos

It is the object of this paper to discuss various options for improving the hematite process in terms of increased throughput hence lower capital cost and production of saleable quality hematite. With reference to increasing the throughput of the process, it has now been determined via the analysis of Akita Zinc Co's continuous industrial autoclave performance data that the process kinetics is limited by the rate of the hydrolytic precipitation reaction. By correlating the hydrolytic precipitation rate to supersaturation ratio, it is shown that accelerated kinetics can be achieved via the following measures: (1) in-situ neutralization with addition of zinc calcine; (2) elevation of temperature; and (3) dilution of feed; of which, the first one was retained for further evaluation. According to presented estimates, addition of calcine, amounting to only 2.6% of the total zinc calcine processed, can allow for shortening the retention time by at least 50%. Such drastic shortening of retention time may be either used to increase the throughput of a given autoclave circuit or alternatively to release autoclave capacity for clean hematite production. Hydrothermal treatment of the crude hematite product proved effective in producing clean hematite as according to laboratory tests, hence allowing the sulphur content of hematite to be reduced from around 4% to less than 1%. A conceptual flowsheet incorporating in-situ neutralization for accelerated kinetics with hydrothermal upgrading of crude hematite without sacrificing production capacity and with minimum upset of the plant's water balance is described.

Jan 1, 2004