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By Michael Stuart Parsons

The haulage cycle is the sequence which a haulage vehicle must first arrive at the loading area, then turn around and reverse into position. Once it is loaded, the vehicle leaves and travels to the unloading area, where again it must turn around and back up to unload. The cycle is repeated over and over again. The Vector Neutral truck is a rubbertired, self-propelled hauling vehicle designed such that it eliminates the requirement to turn around and back-up to either load or unload. Vector Neutral Truck Cycle: 1.) Travel from the load station to the dump station. 2.) Stop and dump load. 3.) Travel from the dump station to the load station. 4.) Stop and load. The Advantage is in the Difference: 1.) Shorter distance traveled. 2.) Fewer brake and steering actuations. 3.) Easier to automate. 4.) Easier to adapt for remote control operation.

May 1, 2003

"4.1. IntroductionThis chapter reviews the geochemistry of the platinum-group elements (POE) in sulphur-poor silicate rocks, and the limited data on POE in silicate, oxide, sulphide, arsenide and sulpharsenide minerals. The earliest geochemical studies of POE in silicate rocks, minerals and meteorites were carried out mainly by Goldschmidt, the Noddacks and their co-workers, and are reviewed in Crocket (1969). These researchers established the siderophile character of the POE, emphasized the common association of the group with sulphides in ultramafic-mafic rocks and suggested that very low concentrations of POE are typical of sulphur-poor silicate rocks and minerals. Much of these data were for Pt and Pd only and are more than 50 years old. Because of the poor sensitivity typical of the available analytical methods, few reliable data were obtained on silicate rocks in these early studies. Surveys of POE geochemistry demonstrate that the data base for sulphur-poor silicate rocks is very restricted, although considerable highquality data for Pd and Ir have been accumulated (Wright and Fleischer 1965, Yushko-Zakharova eta/., 1967, Mertie 1969, Crocket 1969, 1979, Keays 1981).Two recent publications, Vol. 71, No. 7 (1976), of Economic Geology (An Issue Devoted to Platinum-Group Elements) and Vol. 17, Part 2 (1979), of The Canadian Mineralogist (Nickel-Sulphide and Platinum-Group-Element Deposits), are of special interest. These volumes are clear testimony to the impressive progress made in the last decade toward describing the mineralogical and geochemical aspects of POE ore deposits, but at the same time demonstrate the constraints in modelling POE ore genesis due to our meager knowledge of the. POE content and distribution among minerals in the source rocks of ultramafic and mafic magmas. It is clear that the phases hosting POE in mantle source rocks are poorly understood. Nevertheless, Naldrett and Duke (1980) have shown that the absolute and relative concentrations of POE in magmatic sulphide ores are related to the degree of partial melting of mantle peridotites, and subsequent processes of batch equilibration and fractional segregation of sulphides."

Jan 1, 1979

By A. C. Wilson

"In 1991, local prospector C. “Mickey” Clement recovered at least three alluvial diamonds from the Michipicoten River. Two of these stones were sent to the Department of Mineralogy, Royal Ontario Museum, where they were identified as industrial-grade diamonds with weights of 1.05 and 1.13 carats. Both stones were described as frosted and graphiteinclusion riddled.In 1995, prospector Sandor Surmacz and geologist Marcelle Hauseux discovered diamonds in bedrock approximately 20 km north of the Michipicoten River. An 18.1 kg bulk sample of a xenolith-rich lamprophyre, taken from an outcrop at the side of the Trans Canada Highway north of Wawa, yielded 1 macro diamond and 5 micro diamonds. All but one was gem quality (Sage, 2000).Since then, more than 36 occurrences of diamonds in bedrock have been reported in an area approximately 30 km2 in size, centred 20 km north of the town of Wawa. The occurrences are hosted within a sequence of unusual, Archean-aged, heterolithic breccias previously considered to have no economic significance. Ten kimberlite occurrences also have been confirmed in the Michipicoten greenstone belt in the last five years. Two of these kimberlites are diamondiferous.To date, expenditures on property acquisition and diamond exploration in the Wawa are estimated at CDN$120 M.This paper summarizes the geological observations made on these occurrences and describes the relationship between the occurrences and the regional geology."

Jan 1, 2004

By Richard Klimpel

"Over the last 15 years, there has been a number of plant scale sulfide mineral flotation tests organized by this author specifically aimed at understanding how flotation rate varies with reagent type and dosage. With regard to the Interaction of collector dosage, particle size, and frother type, the eight specific trends listed in the paper (Illustrated with data from two specific case studies) are qualitatively the same for almost all plants studied in some depth. The Interaction of flotation rate K and equilibrium (Infinite time) recovery R in the plant has been denoted as the R/K trade-off. The effect of collector dosage on the rate of flotation of specific particle size intervals is particularly interesting and once understood, is quite useful In understanding how industrial flotation plants respond to changing reagent type and dosage. The location and magnitude of the R/K trade-off can be different for various ores and various plant configurations, but the RIK trade-off is almost always present. The purpose of this paper is to clearly describe and illustrate the nature of this very Important flotation system Interaction so that operating engineers have a starting reference point for beginning successful plant Improvement studiesIntroductionIt is well recognized by industrial froth flotation plant operators that improving existing sulfide circuit performance is often difficult due to the self-compensating systems nature of the froth flotation system, e.g. Klimpel (1988, 1989, 1995). Extensive plant testing with existing and new reagents by this author throughout the world has clearly shown that one of the more important self-compensating mechanisms is the Interaction between collector dosage, frother type, and particle size. The term self-compensation in flotation simply means that as the plant operator consistently changes one parameter in the same direction, the nature of the froth flotation system Is such that the circuit will eventually begin to resist this controlled parameter change by automatic (uncontrolled) changes In other parameters and the overall circuit performance will go through a maximum or minimum (hence causing the operator to stop the parameter change)."

Jan 1, 1997

By K. A. Clark

SEPARATION of the oil from the bituminons sands of the Athabaska area of Alberta has been a subject of study by the Research Council of Alberta. The results of the study have been published in the Annual Reports of the Council. However, the last Annual Report in which there is mention of bituminons sand separation is that for 1934. The attention that is being directed toward the bituminons sands at the present time calls for an up-to-date summary of the work of the Research Council of Alberta on the hot-water separation process. STATEMENT OF FUNDAMENTALS OF HOT-WATER PROCESS Studies of the hot-water separation process have been largely empirical in nature. The objective sought has been a complete recovery of oil from the sand in the form of a separated oil which, itself, is free from mineral matter. Various procedures have been tried in the hope of attaining this objective and a very considerable mass of observations and background of experience have been acquired. lt is rime that a theory for hot-water separation should commence to emerge. As a start toward the formulation of such a theory, the statements which follow regarding the constitution of bituminons sand and its reactions with water and air are presented. It is not pretended that they are entirely correct, but it is believed that they lie not far from the truth. (1) Bituminons sand is an aggregate of sand, clay, oil, and water. The sand consists mainly of quartz particles of 100 ta 200 mesh size and smaller, but also of particles of other minerais including mica, rutile, ilmenite, tour-maline, zircon, spinel, garnet, pyrite, and lignite. Clay occurs interbedded with the bituminons sand, of which, also, it is a constituent. lronstone nodules of all sizes up to eight inches in diameter are likely to be present in the bituminons sand beds. The oil is viscous, naphthenic, and of a specific gravity slightly greater than that of water. The oil content ranges up to, and sometimes even exceeds, 17 per cent by weight. Rich bituminons sand from beds not invaded by water has a water content of 3 to 5 per cent by weight. The water is probably present as a film around the sand particles. The oil surrounds the moist sand grains as an envelope. (2) Water wets quartz and other siliceous minerals more readily than does mineral oil. Consequently, water tends to displace the oil film surrounding the quartz and other siliceous particles when the bituminons sand is mixed with water. Whether the oil is completely displaced depends on the properties of the water. That is to say, the materials dissolved or suspended in the water modify its wetting properties.

Jan 1, 1944

By L. Bichler, A. Siebert-Timmer

In this research, novel YSZ ceramics doped with 5 mol% Nd2O3 were manufactured via Spark Plasma Sintering (SPS) process. The sintered Nd2O3-YSZ ceramics were subjected to a static supercritical water environment at a temperature and pressure of 400 °C and 31 MPa, respectively. The weight loss and microstructure development of the sintered ceramic before and after exposure to supercritical water was studied. The results suggested that Nd2O3 addition significantly improved the degradation resistance of the YSZ ceramics. This was attributed to the improved phase stability of the 5 mol% Nd2O3-YSZ ceramics, since X-ray Diffraction (XRD) studies showed that the cubic stabilized matrix in these ceramics was retained after exposure to supercritical water. In comparison, pure YSZ ceramics exhibited a rapid degradation behavior as well as a phase change.

Jan 1, 2014

By Éric Poulin, Simon Gariépy, Mario Paredes Malca

"While the design of a control strategy depends on the available process knowledge, its implementation depends on the available process information. On-line chemical analyzers are today widely spread in the mineral processing industry. A real-time concentration measurement of chemical components is valuable information that could bring control strategies to whole new levels. However, the use of these measures rarely reaches anything more than process monitoring. The reason is simple: the on-line chemical measurements quality is most of the time insufficient to be directly included in control strategies. The choice is then made to let the critical eye of the engineer or the operator appreciates the measurements before making any decision based on it.Data reconciliation through mass balance is a technique today widely used in the mineral processing industry to increase the accuracy and the reliability of plant data, mainly for accounting and survey analysis purposes. Real-time data reconciliation of on-line measurements appears as a natural coupling of technologies that could bring new process optimization trends. Once overcome the technical difficulties, full valorization of the instrumentation investment could be reached.This paper presents the application of real-time data reconciliation for process control and performance monitoring. It proposes a general approach, discusses challenges and illustrates concepts with industry experiences."

Jan 1, 2006

By Luis Magallanes-Hernández

"Industrias Peñoles, S.A. de C.V. (Peñoles) in Mexico, is a major silver producer. The Peñoles Mining Division has eight Mining Operations and in seven of them, flotation is used to concentrate the metal and mineral values. Common metals and minerals values are: metallic gold and silver, gold-silver alloys, silver sulphide minerals (acantite, pyrargirite, argentite, proustite); lead sulphide mineral, galena; zinc sulphide mineral, sphalerite; and copper sulphide minerals (chalcopyrite and bornite).In the last years, a special emphasis has been given to using modal analysis to identify ore mineralogical limitations, in order to direct efforts into key areas where opportunities exist to improve the metallurgical results.This work aims to share Peñoles mineralogical and metallurgical results, through presenting, discussing and drawing conclusions on these results; as well as pointing out areas where more work is needed to improve the Concentrator´ performance.PEÑOLES BACKGROUNDPeñoles´s mission is to add value to non-renewable natural resources on a sustainable manner. It was established in 1887, and it is a mining group with integrated operations in smelting and refining non-ferrous metals, and producing chemicals. Peñoles is the world’s top producer of refined silver, metallic bismuth, and sodium sulphate, the leading Latin American producer of refined gold, lead, and zinc.Peñoles Mining Division is integrated into eight mining business, located on five different states in Mexico. Metal productions for the Mining Division during 2003 were: 343 thousand gold ounces, 48.4 million silver ounces, 81.3 thousand tons of lead, 235.1 thousand tons of zinc, and 10.6 thousand tons of copper."

Jan 1, 2005

By F. O. Verret

Several grindability tests were developed over the years to design grinding circuits or optimize existing operations. Each test has its own strengths and weaknesses and it is imperative to select the proper test procedure(s) to meet project deliverables and minimize the risk of a project. Pilot plant testing of large bulk samples historically constituted the traditional approach for AG or SAG design, but was gradually replaced by small-scale tests. Nowadays, conducting grindability tests requiring only a few kilos of material on several samples is a more typical approach to grinding mill design. This paper summarises the requirements and deliverables of various bench-scale test procedures, their strengths and weaknesses, and cases where AG/SAG pilot testing should still be performed.

Jan 1, 2012

By Robert J. Kuhne

The Iron Ore Company of Canada has successfully employed advanced process control (APC) to optimize the operation of their induration machines. A significant increase in machine throughput and a reduction in fired pellet quality giveaway were observed following the APC implementation on all six machines. This paper discusses the opportunity for process control optimization in induration, reviews the property estimation and multivariable control technologies, and describes how the IOCC control strategy captured this opportunity. APC performance data is presented. The dependence of APC performance on control room operator acceptance, process equipment and instrumentation is highlighted.

May 1, 2007

By Hamid Mahmoudabadi

In the present paper, the performance of four approaches based on neural networks and geostatistical method for grade estimation are compared and analyzed their performance to find a proper method. Four methods, Multi Layer Perceptron neural network (MLP), Radial Basis Function (RBF), General Regression Neural Network (GRNN) and Ordinary Kriging (OK) are selected for ore grade estimation of variable Fe in an iron deposit located in Iran. For each method, two diagnostic statistics are calculated: Mean square error (MSE) and correlation coefficient. The results show the superiority of the General Regression Neural Network.

Oct 1, 2009

By Lyn Jones, Mike Bratty, Rick Lawrence, David Kratochvil

"The treatment of water is required at many mining operations to remove metals and prevent the discharge of contaminated water to the environment. In other cases, water treatment is used to provide better quality water for recycle to the processing plant, or to process bleed streams in hydrometallurgical operations in order to prevent deterioration in metallurgical performance or process equipment. BioteQ Environmental Technologies Inc. has developed and commercialized the BioSulphide® Process which can provide an alternative for these treatment needs and which can also be used for profitable metal recovery, particularly in cases where conventional metal winning techniques are not economical. The BioSulphide® Process is a high rate anaerobic biotechnology for on-site production of H2S from sulphur species, although for smaller flows and metal loadings, the use of chemical sulphide reagent might be more cost effective. Both new projects and existing commercial operations, used for removal and/or recovery of copper, nickel, and zinc, and which range in sulphide generating capacity from 50 kg/day to 3.7 tonnes/day, are discussed. Particular focus is placed on the results of operations at the Raglan Mine in Northern Quebec where dissolved nickel is removed from contaminated water at a high efficiency through the precipitation of nickel sulphide. Plant effluent is discharged directly to the receiving environment and the high-grade nickel sulphide product is combined with the nickel flotation concentrate produced at the mine. The plant at Raglan will replace the existing conventional water treatment plant and will eliminate the need for on-site storage of treatment plant sludge.INTRODUCTIONThe BioSulphide® Process, which produces low cost H2S for use in selective metal precipitation, offers a low capital cost alternative which can operate efficiently and cost-effectively within a wide range of flows and solution grades. Since the technology can be used to recover metals from solutions with low flows and metal grades, the technology is also applicable to environmental applications for water treatment, with the sale of recovered metals providing an offset to treatment costs. For environmental control, the technology has a distinct advantage in being able to meet strict effluent discharge criteria due to the very low solubility of metal sulphides. To date, BioteQ Environmental Technologies has designed and constructed three plants for metal sulphide precipitation, with another three projects in the advanced development stage."

Jan 1, 2006

By Fred Horne

1N THIS PAPER, the writer proposes to limit his comments to few generalized phases of the subject, based on his personal experience in the midwestern United 'States and in one section .of the Coal Branch in Western Alberta. The following statistics are submitted to show the importance that strip mining has assumed in the coal mining industry of the United States. In 1914, 1,281,000 tons of strip coal were produced, amounting to 0.3 per cent of the total production. In 1948, the total was 13~,505,000 tons, representing 23.3 per cent. In 1949, the percentage figure dropped slightly and this can be partially accounted for by the labour disturbances prevalent throughout the year. In 1914, there were 48 power shovels and draglines being used in the stripping of coal; in 1949 there were 3,712, not to mention other types of coal stripping equipment such as bulldozers, tractors and scrapers, rotary excavators, and stackers. At the bituminous coal mines in Western Canada, strip mining was introduced only a few years ago, two of the major reasons for its development being the need for increased production during the war and post-war years and the need to hold the line on increasing production costs, but even in these few years the percentage of strip production has in-creased to such an extent that some mines that, five or six years ago, were producing all their tonnage from underground operations are today obtaining up to 80 per cent of their total output from strip mines.

Jan 1, 1951

By N. M. Soonawala

Detailed regional geophysical and geochemical surveys, ground surveys and drilling were undertaken to follow-up the federal-provincial Uranium Reconnaissance Program (URP) over the 27,OOO-km2 Kasmere-Munroe area in northwestern Manitoba. An analysis of the URP data showed a fair correlation between the regional airborne radiometric results and lake-bottom geochemical results, both of which also correlated with the regional geology. More detailed surveys defined anomalies with greater precision within the broad zones outlined by the URP. The ground follow-up indicated that URP anomalies can be caused by varying degrees of uranium concentration in the rocks. Mineralization of interest was found in leucogranites at several locations within the survey area. Anomalous uranium concentrations were also found in coarse pegmatites and Hudsonian granitic intrusions. It can be concluded that large-scale regional surveys can be followed up in relatively short periods of time to yield meaningful results if a properly planned exploration sequence is employed, each stage of which successively narrows the area of interest.

Jan 1, 1979

By Huilan Yang, Feng He

This paper intends to introduce the development of copper smelting and converting technologies in China in recent years, with a particular emphasis on the introduction of various continuous converting technologies, and moreover, it analyzes the advantages and disadvantages of those technologies, including their impact on the downstream anode refining from different points of view. INTRODUCTION At present, many converting technologies are used in copper pyro-metallurgical plants in China, including Peirce-Smith (PS) converter, flash converting furnace, multi-lance based top blowing, bottom blowing and so on. These technologies have spanned a wide range of time. PS converter technology has been applied in copper smelters for many years and most of the blister copper have been produced by this technology; flash converting technology has been developed since 1990s and been maturely applied in several plants up until now; top blowing and bottom blowing technologies have been revived in China in the past decade and boast good environmental protection performance, energy efficiency, throughput capacity and short process flow. All of the said technologies have reference operations in treating high-grade matte. As more and more attention is paid to environmental protection globally and copper smelters continuously seek for cost reduction, it is necessary to share those converting technologies, especially those new converting technologies derived in China, with copper smelting practitioners in the world. This paper aims to analyze the advantages and disadvantages of various technologies from a macroscopic view and discuss their actual application effects, current developments and future improvements. BRIEF INTRODUCTION OF VARIOUS CONVERTING TECHNOLOGIES IN CHINA China has seen a rapid development in copper smelting industry in the past 30 years and has become the largest gathering place of copper smelters in the world, most of which are operating with PS converting furnace technology, however, with the increasingly strict environmental requirements of the Chinese government in recent years, the low-level pollution issue and the disadvantage of large gas exhaust amount per unit of copper of converting furnaces are particularly prominent.

Jan 1, 2019

Safe underground mine backfilling with hydraulic fill requires efficient fill drainage and stable fill retaining walls or bulkheads. If any or both the above two requirements are not satisfied, such a backfilling operation creates unsafe conditions and may lead to backfill retaining wall failures. Mine backfill retaining wall failures are always associated with economic losses, fatalities and interruption to mine production. Mining industry wants to either reduce or eliminate these fill retaining wall failures. The fill retaining wall failures could be effectively avoided through the use of fibre reinforced shotcrete fill retaining walls and engineered drainage systems through the retaining walls. This paper presents the experience of the author in developing, implementing, and monitoring several hundred fibre reinforced shotcrete fill retaining walls at a mine in Australia with the highest safety standard. The details on the mine backfill drainage system and fibre reinforced shotcrete fill retaining wall designs are also presented.

May 1, 2007

By H. F. Letient, D. C. Johnson

At the 25th Annual B.C. Mine Reclamation Symposium in September 2001, Huckleberry Mines Limited received the Jake MacDonald Reclamation Award for its exemplary mine waste management plan, conceived to prevent the onset of acid rock drainage (ARD) and facilitate reclamation of the site. The mine is an excellent example of a total mine waste management plan, with all materials scheduled in detail for the life of the mine. The filling plan for the waste management facility takes into consideration the requirement for permanently flooding the potentially acid-generating rock. From an acid generation point of view, the tailings fall in the zone of potentially acid-generating material. To avoid long-term ARD concerns, it is planned to float pyrite out of the tailings toward the end of the mine life, thereby generating a non-potentially acid-generating tailings stream which will be used to cap the deposited mine waste. The pyrite-rich tailings will be discharged into the deeper portion of the impoundment. On closure, a permanent water cover will be maintained over the mine waste. Only beaches of non-potentially acid-generating tailings will remain exposed. Mining will be phased to also allow one of the pits to provide storage for potentially acid-generating rock and to be flooded at the end of mine life.

Jan 1, 2004

By Jaeheon Lee, Junmo Ahn, Jiajia Wu

In this project, low grade copper ore samples were obtained from two mining sites in the US, and they were chalcopyrite-rich (sample A) and conichalcite-rich (sample B) ore. Copper grades were 0.6% and 0.4% for the two samples, A and B, respectively. Leaching experiments were conducted by bottle roll tests for 24 hours, and various lixiviant systems were applied. Methanesulfonic acid (MSA) and glycine were used as alternative lixiviants to sulfuric acid. Oxidants including ferric ion and hydrogen peroxide were tested. The results showed the copper extraction of sample A increased after adding 1 g/L ferric ion in sulfuric acid and MSA solution, from 20% to 36%, but further increase was not observed with higher ferric ion concentration. The copper recovery increased significantly with H2O2 concentration, and over 80% copper recovery was obtained with 10% H2O2. For sample B, the copper dissolution kinetics were relatively fast and reached the maximum value in five hours. Around 60% copper were extracted in sulfuric acid and MSA solution. Copper recovery slightly increased after adding ferric ion and H2O2. Glycine is a weaker lixiviant for both samples, the copper extractions were 36% and 4% respectively. INTRODUCTION Chalcopyrite is the most abundant copper sulfide mineral on earth, and it is one of the most refractory copper minerals regarding chemical processing. The declining copper grade and depletion of copper oxide deposits stimulate the development of hydrometallurgical process to extract copper from chalcopyrite. The dissolution of chalcopyrite by ferric ion is normally illustrated as Equation (1) and (2) (Dutrizac & MacDonald, 1974): CuFeS2 + 4Fe3+ → Cu2+ + 5Fe2+ + 2S0 (1) CuFeS2 + 4Fe3+ + 3O2 + 2H2O → Cu2+ + 5Fe2+ + 2H2SO4 (2) However, slow kinetics are usually observed from chalcopyrite leaching at ambient temperature and pressure. Researchers attribute the slow kinetics to passivation during chalcopyrite dissolution, and different passivation products are also proposed (Klauber, 2008). In recent years, many efforts have made to develop new methods to extract copper from chalcopyrite, such as utilizing bacteria or stronger oxidant (Zhao et al., 2015; Ruiz-Sánchez & Lapidus, 2017).

Jan 1, 2019

By Adam Chrzanowski, Eugene E. Derenyi, Peter Wilson

"The rapid growth of the mining industry in Canada necessitates a reevaluation of existing mining surveying techniques and the development of new methods. In this connection, the Department of Surveying Engineering at the University of New Brunswick initiated a research program, and the major points of investigation conducted to date are as follows: 1. Based on practical experience and theoretical studies, all factors influencing classical shaft-plumbing procedures were analyzed. Refined methods were developed to increase accuracy. 2. The performance of electronic and optical distance-measuring instruments in underground conditions were investigated. In this connection, test measurements were made in various mines, employing four types of Tellurometers, two models of Geodimeters and a proto-type optical range-finder. 3. Tests were conducted and methods developed for the mapping of large underground chambers by photo-grammetric means. The aforementioned points are discussed at some length in the paper. The authors have also indicated areas where further research is needed and suggested ways and means to improve and modernize mining surveying as a whole throughout Canada."

Jan 1, 1967

By K. N. Bolatbaev, S. S. Naboichenko

The initial rates of dissolution of pyrite, chalcosine, sphalerite and galena in acidic sulphate solutions under oxygen pressure were measured in the range of Poe = 0.2-1 MPa, 130-180 °C, [H2SO4]0 = 0.2-0.7 M, and in the presence of surface-active agents and agitation producing Re = 4-16 x 103. Reaction orders, activation energies, and values of reaction constants for these oxidation reactions were established. The reactions also were shown to be diffusion-controlled; and the rates demonstrate a linear dependence on the surface area of the sulphides. A surface reaction model, in which oxygen is transported through a solid layer of surface products, has been advanced. The initial stage of high-temperature interaction at pH <7 is suggested to involve a chemical activation of the sulphide surface and is described by the following general reaction: MenSm + H3O+ Men-1 Sm-1 (HS-)s + H2O The subsequent oxidation of surface complex HS- to S0 or SO2-4 occurs with the assistance of Fe(III), Cu(II) ions depending on temperature and the redox potential of the medium, which are defined by oxygen pressure and composition of the reaction mixture, especially concentrations of H2SO4 and metals with variable valence. General process kinetics are complicated due to the formation of by-products on the basis of Fe3+ Pb2+, Cup ions, which displace the kinetics into the diffusion region.

Jan 1, 2004