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By S Jeon, K Aikawa, M Ito, A Kusano, I Park, N Hiroyoshi

In mineral processing of complex sulfide ores containing copper (Cu), lead (Pb), and zinc (Zn), flotation has been commonly used. Typical Pb mineral in the ores is galena (PbS), while some types of the ores contain anglesite (PbSO4). This article reviews our recent studies on the effects of coexisting PbSO4 on the flotation of complex sulfide ores, and a method to suppress the floatability of sphalerite (ZnS) in the presence of PbSO4 was proposed. Comparison of flotation experiments for different types of model samples showed that PbSO4 makes the separation of Zn from Cu difficult; that is, for the model sample containing PbS without PbSO4, Zn could be separated from Cu, while when the model sample containing PbSO4, Zn was recovered together with Cu as froth. Solution analysis and thermodynamic calculation suggested that Pb2+ was released from PbSO4 and reacted with ZnS to form PbS, acting as an adsorption site for the flotation collector, xanthate. This would be the main reason for high floatability of ZnS in the presence of PbSO4. As a method to suppress ZnS floatability for the ores containing PbSO4, a pre-treatment of the ores to remove PbSO4 prior to flotation was proposed. The results of model experiments using mixture of ZnS and PbSO4 showed that ~97 per cent of PbSO4 was dissolved within 30 minutes of pretreatment using ethylenediaminetetraacetic acid (EDTA) as extractant, and thus ZnS floatability was markedly suppressed. Moreover, Pb2+ extracted from PbSO4 during the pre-treatment could be recovered as zero-valent Pb by the cementation using zero-valent Fe as a reductant. The details of ZnS flotation in the presence of PbSO4 and the effects of the pre-treatment are discussed based on the results of surface analysis like XPS.

Aug 24, 2022

In North-West Nelson the Riwaka Complex, a linear basic intrusive complex, is exposed for approximately 45 kilometres. Some 500 kilometres south, across the Alpine Fault, a linear zone of similar but less well known basic intrusives that may be correlatives of the Riwaka Complex is exposed discontinuously for about 80 kilometres. The Complex was emplaced at several centers along a major tensional fracture zone that developed in upper Carboniferous to Lower Permian time. This fracture zone probably formed in response to the development of a west dipping subduction zone that gave rise to the Permian volcanic arcs in east Nelson and western Southland. The Riwaka Complex contains three rock suites. The Fractionation Suite, characterized by cyclic mineral layering and small scale cumulus banding is the largest and is divided into the Ultramafic, Hornblende and Plagioclase Series, each of which is subdivided into several units. The Cumulus Gabbros represent a restricted but important suite of unusual composition, while the third suite is the late phase Diorite Suite.

Jan 1, 1980

By M DellÆAmico, K Vining

The iron blast furnace is the most widely used and efficient producer of liquid iron; however, emissions from sintering and coking cause environmental pressure for the integrated steel works. The combustion of coke fines (breeze) during sintering contributes to greenhouse gases (GHG) (eg carbon dioxide) and is a source of SOx and NOx emissions. Coking capacity is also constrained by environmental concerns and economic factors, such as increased coke consumption, and short supply is leading to high prices. Improved coking practices, which result in reduced production of fines, are also contributing to the tight availability of breeze for sintering. This combination of factors presents an opportunity to consider alternatives to coke as a fuel for sintering. CSIRO Minerals has been investigating the use of wood biomass/char as a substitute for coke during sintering. Wood biomass, or char produced from it, is an attractive carbon source as carbon dioxide liberated during combustion can be sequestered back into growing biomass. It has great potential to reduce the emissions from integrated steelworks and improve their environmental acceptability. Harvested biomass/char is also a renewable and sustainable resource and can be integrated with good land management practices such as remediation of salinity affected land. Weeds, especially woody weeds, can also be used as a source of biomass for charcoal, and integrating char production with weed management can help address a pressing environmental issue in Australia. Previous reported preliminary testwork indicated that the use of Red Gum char as a replacement for coke resulted in a product sinter of comparable quality, improvements in productivity and significant reductions in SOx and NOx emissions. In the latest testwork, CSIRO has examined the properties of a range of potential charcoals, and has conducted a further series of granulation and small-scale sintering trials with them in simulated Japanese Steel Mill iron ore blends. Sinter fuels characterised and evaluated include industry sourced coke breeze, commercially available wood char and a charcoal from prickly acacia (acacia nilotica). Prickly acacia has been declared a noxious weed, is widespread in Australia, and is classified as a æWeed of National SignificanceÆ. The results presented in this paper support the notion that charcoal outperforms coke in many aspects of iron ore sintering and factoring in environmental considerations makes the switch to charcoal even more favourable.

Jan 1, 2005

By E Werner, J J. Donovan, A J. Morris

Coal mining in the Pittsburgh coal seam, in the eastern United States, began in the late-1700s. Since that time numerous mining technologies have been used throughout the basin. Environmental concerns, particularly mine discharge quality, have only been considered since the early-1970s. During the last 20 years, many of the larger underground mines have closed and are now either flooding or already flooded. In order to understand the consequences and potential future effects of this flooding, mine mapping of the basin has been compiled utilising a geographic information system (GIS) with an emphasis on locating barrier pillars between mines. Mine flooding has been monitored at numerous sites utilising pressure transducers and data loggers. These data have been combined with historical data from mining companies and structure contour maps to yield chronological flooding maps of the basin from 1980 to present. Utilising these maps and the indicated flooding rates, future discharge locations have been identified along with estimates of when these discharges are likely to occur. Related work has identified barrier pillar hydraulic conductivities and vertical infiltration rates as a function of overburden thickness. All of this information has been integrated into a groundwater flow model that simulates mine flooding. This model is useful in defining mine to mine interactions as the various mines fill with water, and the testing of various flooding scenarios. The model will be used in evaluating mine discharge rates and evaluating the options for regional mine drainage treatment.

Jan 1, 2003

In 1972 the Marra Mamba Iron Formation in the Lower Proterozoic Hamersley Iron Province of Western Australia was recognised as a stratigraphic horizon with significant potential for high grade iron ore reserves. Within the Newman area the Marra Mamba Iron Formation has been subdivided into four strati- graphic units: Lower BIF member, Middle BIF and shale member, Upper BIF member and Upper shale member - and a standard natural gamma log reference section compiled for the entire formation. The recognition of the Upper shale member as an additional unit contrasts to the previously proposed stratigraphy. Enrichment of the Marra Mamba Iron Formation to ore grade (0)8 percent calcined Fe) in the Newman area is restricted to the Upper BIF member and to a lesser extent to the Middle BIF and shale member. Typical ore from Orebody 29 is friable interbedded martite-ochreous goethite, signifi aptly different both physically and chemically from the Brockman Iron Formation ores of the Tom Price-Whaleback type. Large scale customer acceptance trials (in excess of 4 million tonnes) have shown that Marra Mamba ore crushed to fines and blended with Mt. Whaleback fines in a ratio of up to 15:85 forms an acceptable sinter feed.

Jan 1, 1981

An understanding of the way that solutes are transported in mining or natural environments is essential to the development of sound strategies for managing waste disposal. Research on miscible pollutant movement in unsaturated porous media is carried out both experimentally and numerically. Results of numerical modelling are obtained by solving the groundwater flow equation and the solute transport equation. The finite element method is employed and comparisons between simulation results and experimental data are found in remarkable agreement.

Jan 1, 1995

By B Washington, A Campbell, R Taylor

A sampling and measurement program was undertaken on the reaction shaft of the Olympic Dam copper flash smelting furnace. The object of the work was to provide information to validate a mathematical model of the burner and reaction shaft. Samples and measurements were undertaken through the burner inspection ports and the South East (SE) shaft sampling port about half way down the reaction shaft. Samples were collected to enable the calculation of particle loading of shaft gases, or sizing and chemical analysis of the partly-combusted feed, and the preparation of polished sections. Measurements were made of the temperature and sulfur dioxide content of the atmosphere, as well as plume velocity.To implement the program it was necessary to design and construct the following specialised items of equipment. For use at the burner inspection ports: a cup sampler for obtaining samples below the burners (temperature, solids loading and samples for characterisation).For use at the SE shaft sampling port and also at the settler level: trough sampler (plume definition and samples), isokinetic sampler (used as a velocity probe in this work), temperature probe (temperature traverses across the shaft), and sulfur dioxide probe (SO2 measurements across the shaft).The design of the sampling and measuring equipment is described, and examples are cited of the types of information obtained. The problems arising from working in a hot environment with molten or sticky particles are discussed.

Jan 1, 2005

By Callaghan T

The Henty Gold Mine is located approximately 30 km north of Queenstown, at the head waters of the Henty River on the west coast of Tasmania at 41¦50'S, 145¦40'E on the Queenstown (SK 55-5) 1:250 000 and Sophia (8014) 1:100 000 map sheets (Figure 1). The mine is accessed from Queenstown along the A10 Highway and Anthony's Road. The town of Queenstown is located 260 km north west of Hobart on the A10 Highway, and

Jan 1, 1997

Metsim is proving to be a powerful tool when designing a heap leach operation. The most useful outputs arc determining the fluctuations in pregnant solution recovery rate, make-up water rate, gold recovery rate. and pond levels. Detailed data are needed for input: a pad loading schedule, a mining rate schedule for each ore type, column leach test data for each ore type, column tests on water dynamics (ie hourly flow-out versus-in during saturation and drain-down), monthly rainfall and evaporation data, and proposed pond dimensions. These data allow 'what if' studies on application rates, leach rates, loading rates and other variables of interest. Examples will he given of modelling both a rectangular pad and a valley fill operation.

Jan 1, 1994

The original leases making up today's North Kalgurli Mines were developed by independent companies on an ad hoc basis. The major disadvantage which now arises is the varying levels of mining horizons. From Kalgurli Shaft in the south, through main Shaft and to Croesus Shaft in the north, there are three separate sets of levels. work has commenced to link the three areas with either common levels or new development which will facilitate common access and haulage via Main Shaft.Generally, the workings at North Kalgurli were established at the turn of the century. The introduction of techniques and equipment to bring the mine into the 20th Century has been difficult and slow. The general size of openings, a widespread workforce and complex ore distribution often make innovation and change more than a challenge.

Jan 1, 1985

Spatial continuity as described by a variogram is a reflection of the underlying mineralisation/geology. Modelling of the spatial continuity (variogram) must account for both the quantitative data (ie sample grades), on which the variogram calculations are based, and the qualitative information as provided by the geological interpretation. An understanding of the geology and the variogram interpretation tie together the sample values and allow us to go beyond the actual data (Journel, 1995). Variography makes geology transportable and allows the geological interpolations to be channelled downstream into mine planning, ultimately affecting the economic decisions surrounding a deposit. As such the process of variography and resource modelling is critical. Thus consistent expert decisions need to be made which force geologists to have a closer look at the available information and the geological interpretations. The aim of this paper is to provide an overview of the latest developments in visualising variography and to demonstrate their usefulness in decisions regarding the spatial continuity of mineralisation. New ideas concerning potential future developments in visualising and modelling spatial continuity through variography are introduced.

Jan 1, 1996

By C E. Loo

The cohesive zone has a significant influence on blast furnace operation and performance. The high-temperature behaviour of the reducing ferrous burden determines the properties of the cohesive zone and is studied in a laboratory using a softening and melting test. This paper summarises recent work aimed at better understanding the physico-chemical changes in a ferrous bed during softening and melting. Using a combination of standard, non-standard and quenched tests supported by optical image analysis, this work has highlighted some important differences in behaviour between lump, pellets and sinter as well as between the two lump ores and two acid pellets. As with the two lump ores, one pellet is denser than the other and the denser ore/pellet is also higher in silica.Within the cohesive zone, densification of the ferrous layer leads to reduced permeability and greater pressure drop. From the work presented in this paper, two key mechanisms of ferrous layer densification were identified. Firstly, the formation of fayalite, which melts at low temperatures, can act as a lubricant between particles and lead to densification of the ferrous layer under load. Secondly, reduction to metallic iron is topochemical and fayalite in the outer shell of the particle restricts gas flow to the centre and results in the formation of a wustite core. As temperatures rise, the wustite melts and eventually exudes out of the shell, occupying void spaces between particles and further reducing layer voidage and permeability.This work has shown that density and silica content are two key factors that result in increased densification of the ferrous layer. For porous Australian lump ore, the higher porosity and lower silica reduces the formation of fayalite and limits the formation of the wustite core, ultimately leading to a more permeable bed. The difference between the porous and dense ores was more pronounced with the introduction of prereduction to better simulate blast furnace conditions. This suggests that a porous ore gives significantly better cohesive zone permeability and blast furnace operations than a dense ore.The behaviour of fluxed sinter particles is different in that the silica reacts with lime to form dicalcium silicate. Minimal wustite core forms because relict hematite particles in sinter are only small and reduction occurs uniformly throughout the particle. Even with significant loss of material through prereduction, beds formed from sinter remained comparatively rigid. Studies using a typical blast furnace burden mix of 80 per cent fluxed sinter and 20 per cent porous ore showed that the structures of these beds at softening and melting temperatures are very similar to the sinter-only test. Measurements of bed contraction and pressure drop also confirmed that the introduction of 20 per cent porous ore into a sinter bed did not alter its properties. This is an indication that 20 per cent ore can be easily accommodated by blast furnace burdens.CITATION:Loo, C E, 2015. Important acid ferrous burden properties in the cohesive zone of a blast furnace, in Proceedings Iron Ore 2015, pp 367–376 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By Lewis RW, Tullemans FJ, Gallo JB

Gold mineralization at Kidston occurs in a semicontinuous zone near the margin of a large, late Palaeozoic breccia pipe. The pipe is ovoid in plan, funnel-shaped in cross section and straddles a contact between Proterozoic metamorphic and granitoid rocks which are intruded by a swarm of late Palaeozoic acid dykes. Rock fragments within the breccia pipe reflect the enclosing country rocks and mix in various proportions to form gradational lithological domains. Most of the gold is free and is located in the breccia matrix and in a set of inwardly dipping sheeted quartz veins which kink around the pipe margin. Sulphide minerals, dominantly pyrite, occur as disseminations in the breccia matrix and as aggregates in the cores of quartz veins. Hydrothermal altLration is pervasive within the breccia and is most intense in areas with the highest percentage of acid dyke fragments. Sericite and carbonate are the main alteration minerals. An empirically developed genetic theory for the formation of the breccia pipe and attendant mineralization involves magmatic and post-magmatic processes associated with the intrusion of a granitoid body to a shallow level in the crust. Economic evaluation of the deposit relied heavily on the results of diamond drilling. Both polygonal and geostatistical reserves were calculated and found to be in close agreement. Geostatistical reserves are considered to more closely reflect the tonnes and grade achievable during mining. Daily geological mine routine is strongly biased towards grade control allied with the practical aspects of open-pit mining. Tonnage/ grade correlations between ore blocks geostat- istically generated from exploration diamond core results and ore blocks generated from high

Jan 1, 1986

By Chia A. H

This paper presents an overview of the development and operation of the PT Adaro Indonesia coal mining project. This operation is an initial two million tonne per annum mine, located in South Kalimantan, Indonesia.The paper places emphasis on some of the more unique infrastructure development and operational challenges that exist in such a remote location environment.A brief summary is also given of the Indonesian coal industry, its direction and position as a significant coal producing competitor for Australia.

Jan 1, 1992

By R Linares

The efficient operation of any modern metallurgical facility depends on the accurate measurement and estimation of flow rates, inventories, and composition of their intermediate and final products. All of this information is subject to both statistical errors and gross errors, which can lead to poor estimation of efficiency, yields and specific energy consumption. The detection and the elimination of these errors require not only plant data, but also product transactions and the operational events. Once the gross errors have been eliminated, it is possible to estimate validated performance indicators, such as grade recovery or yields. This paper describes the methodology to implement a unification and gross error detection system using the available infrastructure of both information and data reconciliation system. It covers the different infrastructure layers, from the data collection layer to the data validation and reconciliation layer. In addition, the impact of these methodologies on the decision-making process is presented.

Jan 1, 2005

By Skinner W, Netting A. K O

Surface analysis of ore samples collected from corresponding concentrate and tailings process streams is now a widely used tool in many Australian base metal sulphide concentrators, particularly those involved in AMIRA projects. The use of tec

Jan 1, 1997

By Harbort G. J

Jameson cell pilot plant trials were conducted in a number of areas in the Red Dome gold/copper flotation plant during 1991. The aim of testwork was to reduce the amount of cyanide soluble copper reporting in tailing to the gold leach plant, and hence reduce cyanide consumption. A number of these tests were conducted in parallel with conventional flotation columns. Laboratory tests were conducted to simulate the performance of the existing plant when compared with the addition of the Jameson cell allowing an extra sulphidising phase. This paper reviews the comparison of the Jameson cell and conventional columns in recovering cyanide soluble copper, while maximising copper concentrate grade. Key parameters that are investigated are residence times, air/pulp ratios, superficial gas recoveries and size by size recoveries. A brief comparison of performance of the Jameson cell and column in the controlled potential sulphidisation process is also presented. An estimation of the reduction in cyanide consumption is given.

Jan 1, 1992

In early 1985, Bougainville Copper Limited commissioned an automatic truck despatch system to control its fleet of 44 trucks and 9 shovels. Productivity gains in the past have been the result of increasing equipment size then improving availabilities. The emphasis now is on improving the use of that availability and in particular for trucks, in reducing non-productive truck movement. A batch allocation computer based truck control system had been in operation since 1978, so to achieve the desired improvements it was necessary to move to an automatic dynamic control system. A description of the system installed is given, together with a review of how the project was engineered, the problems encountered and the results achieved to Date.

Jan 1, 1986

The paper reviews some characteristic features of feasibility studies and discusses the need for a wide scope at the pre-feasibility stage. The performance of recent Australian gold mines against the predictions contained in their respective feasibility studies is examined, resulting in a recommendation that feasibility studies need to be improved The advantages to be gained from having a feasibility study reviewed by an independent authority are discussed, and some of the reasons for using consultants are listed. Two examples of successful optimisations in the early stages of pre-development studies are described briefly and the benefits achieved are presented. The paper concludes that feasibility studies need improvement to enhance the confidence of investors in the mining industry.

Jan 1, 1991

By Darby H. P, Vincent R. J

Sydney's Eastern Suburbs Railway from Central to Bondi Junction required the construc- tion of 10.4 km of single-track tunnel and five underground stations. Much of this work took place beneath the commercial centre of Australia's largest city. This paper discusses the general precautions taken and the specific design solutions made for such problems as support of a 15-storey building with foundations several metres above the excavation to ensure negligible differential settlement, excavation immediately below running tunnels, underpinning of multi-storey buildings, tunnelling under massive masonry retaining walls and demolition and rebuilding of part-completed structures.

Jan 1, 1981