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By E U. Petersen, D R. Cooke

Hydrogen and oxygen isotopic constraints on hydrothermal fluid composition from the Pliocene Boyongan and Bayugo porphyry copper-gold deposits (southern Philippines ) reveal mixing of magmatic and sea water reservoirs as the hydrothermal system evolved. Magmatic-equilibrated fluids (d18O: +8.3ë to +9.1ë; dD: -61ë to -51ë) are represented by hypersaline brines implicated in copper-gold transport and deposition. These dominate the fluid inclusion assemblage in early comb-quartz (unidirectional solidification textures), miarolitic quartz, and in K-silicate-stage quartz-K-feldspar ¦ biotite veins. Fluids responsible for post-K-silicate alteration assemblages of pyrite-clay (illite, pyrophyllite and kaolinite), alunite and smectite are represented by low-moderate salinity two-phase inclusions in co-existing quartz. These are interpreted as mixtures of evolved magmatic fluids (d18O dD: -42ë to -20ë) with evolved Pliocene sea water (d18O: + 4.0ë; dD: +4ë). The isotopic evidence for sea water involvement in the hydrothermal system suggests that porphyry emplacement and associated diatreme formation could have occurred in a submarine setting. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

Carbonate replacement tin deposits in the areas studiedhere are genetically related to biotite granites. Biotite in the granites is distinguished by distinctive compositional features. High MgO content is found in biotite in the Renison Bell granite; high MnO and A1203 contents in the Gejiu granite; and high FeO content in the Xinlu granite. The compositional features of biotite in the granites are reflected in skarn minerals formed around the granites.Granites associated with these tin deposits are characterized by different accessory minerals. Magnetite-bearing granite in the Xinlu deposit is related to the andraditic garnet (andradite 40-45 mole%)-hedenbergite skarn, with tin mineralization occurring in the contact skarn only. The sphene-bearing granite in the Gejiu deposit is related to the grossular garnet (grossular 50-60 mole%, almandine 20-30 mole%) -salite skarn, with tin mineralization occurring in the contact skarn, as well as stratabound replacement orebodies in the distal skarn. The ilmenite-bearing granite in the Dachang deposit and the Renison Bell deposit is related to the grossular-diopside skam, with tin mineralization occurring 500-1500 metres vertically and 1.5-3 km horizontally away from the granite contact.

Jan 1, 1990

By S Hapugoda, H Han, L Lu

Charcoal produced from Syzygium Zeylanicum trees was widely used in ancient Sri Lankan iron smelting practices. Charcoal made from Syzygium Zeylanicum tree trunks, branches and leaves were analysed by optical mineralogy and SEM and found to contain unusually high concentrations of calcium oxalate (CaC2O4.H2O – CaOx) crystals in plant cells. Partial and full reduction tests of a high-P Brockman ore were conducted at several temperatures with coke and coke doped with CaOx and CaCO3. It was observed that CaOx promoted reduction and generated comparatively more metallic iron in reduced samples. Furthermore, CaOx encouraged phosphorous partition into slag phases than into the metallic iron, suggesting CaOx can a potential alternative fluxing material to calcium carbonate for treating high-P iron ores in ironmaking processes.

Sep 18, 2023

By J P. Barkas

World demand for iron ore is far from peaking, and the substantial price decline that has captivated commentators since early 2014 is not the result of widespread misreading by producers of the prospects for global market growth. Recent price movements provide little useful insight into the industry’s longer-term fortunes, apart from reminding mining companies that their businesses need to be robust against the volatility and inescapable cyclicality of mineral commodity markets. It is timely to take a strategic view of the history and longer-term prospects for the iron ore industry and of Australia’s place in it.CITATION:Barkas, J P, 2015. Perspectives on the long-term outlook for iron ore, in Proceedings Iron Ore 2015, pp 3–6 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By Bodnaras G. E, Sceresini P. A

The Filblast Cyanidation Process incorporates the advantages of intense high shear mixing, high dissolved oxygen concentration and high pressure to achieve extremely rapid gold dissolution rates. This is made possible by the unique design of the Filblast gas shear reactor. The reactor is a rugged and compact in-line device. The outer casing is protected by a polyurethane coating and the internal parts are of wear resistant polymer. The largest unit built to-date has overall dimensions of 1200 mm length by 300 mm diameter and has a capacity of 150 dry tonnes per hour at 40 - 45 per cent solids. Service life at this throughput is at least three months. The process may further be applied to high temperature leaching of refractory gold ores or other metals. Wear resistant metal or ceramic materials would be employed for this duty. Four mines are currently employing the Filblast Process for treating a variety of ore types ranging from highly reactive, almost impossible to treat, pyrrhotite/arsenopyrite to deeply weathered clay ore which forms a highly viscous pulp. The effect of shear thinning has resulted in improved adsorption kinetics resulting in higher carbon loading and reduced soluble gold loss. Total tonnage treated is approximately four million. Operating costs which include leasing and maintenance charges for the Filblast and pump power costs are about 16 cents per tonne. This is equivalent to about ten per cent of savings. Laboratory scale units having capacities up to 30 litres/min are available for test work but laboratory testing techniques so far developed do not accurately reflect the oxygen and cyanide savings which have been achieved in the plant.

Jan 1, 1994

By Russell P

Polyurethane resin (PUR) is extensively used in almost all coal producing countries. On the local scene, PUR components suitable for underground application were selected and subsequently, trials were carried out at several coal mines. This paper describes the work at Pikes Gully Colliery (B.P.3Coal), where water flow rates of up to 4.5 m (1000 gallons) per minute, were reduced to 1-1.5 m /minute at the tirst stage of application. Subsequent trials were carried out at West Cliff Colliery (Kembla Coal and Coke). A variety of PUR chemical mixtures were tested in coal ribs and in the roof of intersections and roadways. The trial results are presented with all particular details. Using the PUR injection method, the roof, at the most difficult intersection, was stabilised and 'de-bonded' roof bolts were re-sealed. At Pikes Gully and West Cliff Collieries, 2 tonnes and 3 tonnes of PUR chemicals were injected, respectively. The technique, primarily based on German experience (Bergwerksverband), was used by Delta Control Systems Pty. Ltd. ACIRL was closely associated with the trials, which were monitored by installation of the measuring Stations.

Jan 1, 1986

By M S. Henderson, R D. Alorro, L G. Dyer

An alternative leaching system for rare earth element recovery from monazite is under development. The initial stage utilises oxalic acid to convert the rare earth phosphate into an oxalate salt through dissolution and reprecipitation and it is the efficiency of this stage that governs the overall recovery achieved. It has previously been proposed that lixiviant consumption is the primary limitation in this process. This work further investigates a range of conditions in an attempt to further elucidate the factors influencing the achievable conversion in this stage. It has been shown that the pH may be governed by multiple reactions both consuming and producing acid (thus the mild change over time). The importance of proper mixing and potential to operate at lower temperature with only moderate impact on kinetics has also been demonstrated. Staged/sequential leaching is more effective in fresh solution as opposed to restoring the lixiviant concentration with subsequent reagent addition, suggesting some impact of solution composition. However, contrary to previous findings, subjecting the leach residue to fresh solution resulted in significant decline in leach rate and overall dissolution. This may be because a greater proportion of conversion was achieved in stage 1 in this work than in previous investigation. This may indicate that eventual passivation or the presence of some more refractory REE minerals limits dissolution. Iron dissolution was relatively consistent upon exposure to fresh solution, displaying the ability of the solution to continue to leach the goethite component of the concentrate.

Aug 24, 2022

By P Martin, A Somarin, S Bailey

Field-based research was conducted to investigate the performance of field portable X-ray fluorescence (FPXRF) in the analysis of reverse circulation (RC) drill chips in iron ore exploration. For years, FPXRF has been considered unsuitable for iron ore exploration due to the limitations of the elements it is capable of analysing for, in particular its inability to measure light elements (Mg, Al, Si, P, S). With the advent of the use of silicon drift detectors (SDD) in FPXRF, light elements are now measurable elements. However, doubt over the appropriate use of this new technology still exists due to the absence of reliable comparative field data. These doubts concerned the ability of the FPXRF data to correlate strongly with the laboratory assay of the same samples. It was believed that inconsistent grain size and other variables not being controlled would contribute greatly to this perceived unreliability.We tested RC chip samples on-site in the Pilbara, with the portable Thermo Scientific Niton XL3t X-ray fluorescence (XRF) analyser for a range of elements including Fe, Mn, Al, Si and S and then compared the results with laboratory assay data. A strong correlation indicates that the FPXRF results are reliable. Furthermore, to show the effect of simple sample preparation, we also analysed pulps of the same samples in the same way.The correlations were good for all of the elements of interest for the RC chip samples (R2 values between 0.82 and 0.9), and excellent for the pulps (R2 values between 0.89 and 1). The results also showed a direct correlation between sample preparation and improved quality of results with the FPXRF. This indicates that FPXRF can produce data from unprepared RC chips for Al and Si that, when compared with laboratory assays, is reliable for a field application in drilling and grade control. CITATION:Somarin, A, Martin, P and Bailey, S, 2013. Non-destructive analysis of diamond core for light elements using Niton field portable x-ray fluorescence, in Proceedings Iron Ore 2013 , pp 117-230 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

By King D

Recent field experiments in the United Kingdom (Buchanan, 1979) have shown that the in-seam technique is capable of detecting a 1m fault in a 3m seam, at a range of 280m and with a resolution of ¦40m. Comparable tests in Australian collieries are proceeding. Although the practicality of an implementation of the technique on a routine basis remains to be demonstrated, the potential of the technique for the prediction of outbursts clearly warrants detailed examination. This potential will,depend, inter alia, on the level and scale of variations in elastic (and anelastic) properties of bodies of coal undergoing stresses associated with mining. Available data, mainly from studies of the seismic properties of gas saturated reservoir rocks, confirm the intuitive view that stress increases give rise to increases in seismic wave velocity and decreases in wave attenuation, markedly at low stresses (as pore spaces close with little resistance) but less so as stress increases. Such increases are of the same order as aniso- tropic effects, but should provide impedance contrast sufficient for detection by in-seam seismic methods. At higher stresses, cracks form within the rock mass. Results from research on earthquake prediction provide some clues to the behaviour of sedimentary rocks sub- jected to large stresses. In particular, the

Jan 1, 1980

By D J. Williams, S Islam

Fine-grained coal tailings slurry undergoes only limited settling and self-weight consolidation, and tends to remain slurry-like and unsuitable for conventional laboratory consolidation testing. In addition, constant rate of loading consolidation testing is more representative of the continuous disposal of tailings slurry into a tailings storage facility (TSF) than conventional step loading. The laboratory consolidation testing of coal tailings slurry under a constant rate of loading has been carried out in a purpose-built, large-scale, slurry consolidometer, instrumented with load cells and pore water pressure (PWP) transducers. In the slurry consolidometer, the rate of loading may be varied to represent the actual rate of rise of the tailings in the TSF. A slow rate of loading increases the test duration, while too fast a rate of loading may build up very high excess PWP, without achieving significant consolidation. For the particular fine-grained coal tailings slurry tested, the rate of loading in the slurry consolidometer is varied to access its effect on the development and dissipation of excess PWP. The resulting consolidation parameters are evaluated and explained using the recorded settlement and PWP data.CITATION:Islam, S and Williams, D J, 2018. Optimisation of constant rate of loading slurry consolidometer testing of fine-grained coal tailings, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 72–80 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By H Aral, L Malishev

The carbothermic chlorination of titaniferous materials such as rutile, synthetic rutile (SR), upgraded slag and ilmenite in a fluidised bed is an established commercial process. In this work, ilmenite sourced from the Murray Basin area of South Eastern Australia was chlorinated and an assessment of the chlorination characteristics of the ilmenite, in terms of pre-treatment, type of reductant and reaction time was made. Selective chlorination of Murray Basin ilmenite to remove Fe and Mn was achieved in this work. A synthetic rutile sample containing around 93 per cent TiO2, one per cent Fe2O3 and 0.5 per cent MgO was produced at a chlorination temperature of 1000¦C with around 25 per cent loss of Ti as TiCl4. Raising the reductant to ilmenite ratio in the chlorination reactions increased the amount of Ti chlorinated. However, complete chlorination of Murray Basin ilmenite to produce FeCl3 and TiCl4, was not achieved under the conditions used in this work. Pre-oxidation of Murray Basin ilmenite before chlorination had little affect on its reactivity, compared with æas receivedÆ ilmenite. In contrast weathered West Coast ilmenite chlorinated appreciably better than West Coast primary ilmenite, in terms of bed residues remaining and amounts of elements removed. The presence of large amounts of Mg and chrome spinel grains in the Murray Basin ilmenite used in this study are likely to make it difficult to chlorinate directly in a commercial chlorinator. However, this is not to say these ilmenites will be unsuitable for chlorination applications. Further work is needed in the separation of Mg and chrome spinel grains from Murray Basin ilmenites and the products resulting from these tests could then be assessed in terms of chlorination performance, so that further processing options can be explored.

Jan 1, 2000

By Stone I

Tahmoor Mine is located in the southern Sydney Basin 80km south-west of Sydney and produces 1.2 MT of Bulli Coal annually. Bord and pillar methods used to date will be supplemented by a longwall system. Difficult roof conditions have been experienced since mining began in 1979. A dominantly horizontal stressfield promotes shear failure in the thinly interbedded roof sequence of shales, laminites, siltstones and fine sandstones. General roof conditions and failure characteristics are related to the angle between the roadway direction and the principal horizontal stress direction. The apparent stressfield changes direction, magnitude and the ratio of principal horizontal components across the mine workings in response to both in situ and mining induced causes. Initial roof support of 5 x 2.1 m bolts per W-strap at in intervals, with mesh, was upgraded to include RSJ's in order to support areas of failed roof. This support system was inefficient and costly. A third system of support emphasizes roof reinforcement with full resin encapsulation of 2.1 m bolts in W-straps. The number of bolts per strap (6-8), extra butterfly straps and bolts, and W-strap spacing is determined for each area by expected roof and stress conditions. Intersections are pre-bolted and ribs are supported in some areas. Pillar dimensions, order of drivage and roadway width have each been altered to improve roof control. The intensity of roof deformation at the face varies from panel to panel and causes development rates to decrease to 30% of the maximum. 1. Manager, Tahmoor Mine, Tahmoor, N.S.W. 2. Senior Geologist, BP Coal, Picton, N.S.W. Roof conditions in each area of the mine are characterised and then projected to future development areas based on the relationship between stressfield orientation, relative roadway direction and face conditions. Planning information available includes expected development rates, roof support requirements and areas of changing conditions. Future improvements of strata control involve defining support design parameters for the range of mine conditions already seen at Tahmoor.

Jan 1, 1986

By K C. Corin, N Ndamase, M Tadie

Mining operations in arid regions are compelled to reduce their consumption of fresh water. Closed water circuits are an attractive solution and, in addition to reducing freshwater consumption, have the added benefit of reducing reagent consumption as well as the environmental impact by eliminating effluent discharge. Accumulating ionic species have been shown to hinder collector adsorption which reduces the recovery of valuable minerals. Numerous studies have investigated the effect of degrading water quality on collector adsorption however there is very limited understanding as to how this takes place from an electrochemical perspective. This study therefore aims to investigate how the presence of accumulating ionic species at varying concentrations affects the electrochemical adsorption of sodium ethyl xanthate onto galena. The synthetic plant water used in this study comprised of single salt solutions to isolate the effects of the ionic species of interest. The ionic strengths were varied between 0.0242 M, 0.0727 M, 0.1212 M and 0.2426 M which correspond to University of Cape Town (UCT) Centre for Minerals Research (CMR) synthetic plant waters of 1, 3, 5 and 10SPW, respectively. Mineral rest potentials indicated how changing water quality affected xanthate-mineral interactions. Microflotation observed the impact of changing water quality on mineral floatability.

Aug 24, 2022

By L Smith, R Beckie

Controls on environmental loading from acid rock drainage (ARD) are not well understood in waste rock material. In particular, relationships between subsurface flow and the timing, duration, and intensity of leaching of metals and acidity from waste rock dumps remain ill defined. This study investigates field-scale relationships between subsurface flow processes and geochemical processes in unsaturated waste rock. A 12-metre tall, unsaturated waste rock pile, constructed in 1994, was deconstructed and sampled at Key Lake, Saskatchewan, Canada, during the summer of 2000. A detailed sampling methodology was developed to characterise physical and chemical properties of waste rock material within the waste rock pile. Physical properties were characterised by measuring soil-water suction, volumetric water content, and grain-size distribution at 60 random locations within the pile and grain-size distribution at 20 grid locations within the pile. Attempts to develop a field-based soil water characteristic curve from physical field-data failed due to spatial variability and hysteresis of waste rock properties. As a result, grain-size distribution was used as a relative measure of subsurface flow. Paste pH, pore-water geochemistry, mineralogy, and water-soluble extraction results were used to characterise geochemical processes and sulfide oxidation at each of the 20 grid locations. Geochemical characterisation results demonstrated the preferential weathering of marcasite relative to pyrite and chalcopyrite. Dolomite was the main buffering carbonate mineral. Gyspum, jarosite and iron oxyhydroxides were the main secondary minerals. Pore-waters contained up to 800, 11.7, and 6 mMolar (78 000, 690, 1400 mg/L, respectively) of sulfate, nickel, and uranium, respectively, suggesting significant weathering has occurred. Measures of weathering indicators show no discernable correlation with grain-size distribution nor do they show any spatial relationship within the sampled grid. Reasons for this may include limited duration of waste rock exposure to weathering and development of fluid flow-paths, and limitations of characterisation methods used. Indeed, six years may not be long enough for weathering patterns to develop due to fluid flow-paths in this unsaturated waste rock pile.

Jan 1, 2003

By Garg R. K

Himalayan ranges on the northern border of India are source of many perennial rivers and suitable sites for large dams have been located therein. However, Himalayas are young mountains and comprise of comparatively weaker rocks having adverse geological features like shear seams, thrust zones, minor and major faults and intense jointing. Tehri dam project under construction, is located in lower Himalayas. It envisages construction of a 260.5 m high earth and rock fill dam and an underground power station of 2000 MW (Eight machines of 250 MW each, four of which will be reversible) installed capacity. This dam will be the highest and the underground complex will be the largest to be constructed in India in the Himalayas. The under- ground complex comprises of 25 km of tunnels varying in diameter from 6 m to 11 m and seven large cavities of various sizes, the biggest being 22 m in width, 194 m in length and 65 m in height. Rock formation in the power house complex belong to phyllites having various joint sets spaced from 0.5 m to 3 m. Due to the poor geological conditions and closely spaced net work of large cavities, the planning, analysis and design of the cavities is a challenging job. Many aspects have to be considered in determining the sizes, locations and orientations of the various cavities taking into account the properties and jointing pattern of rock mass, functional requirements and economics. Correct evaluation of loads and forces is necessary for economical design of supporting system for the various cavities. Rock loads on the roof of cavities and their supporting system will be assessed with the help of the latest methods. The stability of the rock mass around the cavity will be evaluated by elasto- plastic method using finite or boundary element techniques. A scheme of field investigations, laboratory tests and instrumentation for deter- mining rock properties in preconstruction stage and for monitoring behaviour of the underground cavities during and after construction is envisaged.

Jan 1, 1987

By P N. Holtham

Magnetic separation is routinely used in the processing of titanium minerals, and the efficiency of these operations can be determined by measuring the magnetic properties of the process streams. The valuable components in the feed to a titanium minerals plant have specific magnetic susceptibilities ranging from -10-9 m3 kg-1 (zircon) to 10-6 m3 kg-1 (ilmenite). However, in an industrial environment, in which the mineral temperature may range from 20 to 120¦C, it is difficult to measure susceptibilities lower than about 10-7 m3 kg-1. Hence laboratory testing of spot samples from magnetic separators is currently required to obtain accurate performance data. This is an inherently slow process and where feed grades are variable, optimum performance of magnetic separators is generally not achieved. This paper describes the development of an inductance-based instrument for measuring very low levels of magnetic susceptibility on-line. The signal from the instrument can be used for process control purposes to maintain optimum magnetic separator performance. A prototype instrument has been installed in the zircon scavenger circuit in an Australian titanium minerals plant. The circuit consists of a roll magnetic separator treating a feed consisting mainly of monazite and stained zircon. The monazite-rich magnetic fraction is returned to the mine site for disposal, while the non-magnetic fraction is recycled to the zircon wet circuit. Splitter positions in the separator are adjusted when the final zircon product fails to meet specification, or the magnetic fraction contains more than 30 per cent zircon. Weekly composite grain counts show that sub-optimal operation of the magnetic separator results in significant zircon losses into the magnetics fraction. Using the instrument, the zircon content of this stream can now be accurately determined from the measured magnetic susceptibility, provided a correction for the effect of mineral temperature is applied using the Curie - Weiss relationship.

Jan 1, 2001

By Robertson K. S, Hunter T. C

AEG-Elotherm's electromagnetic dosing channel, or Eldomet, is a recent invention enabling the transport and metering of molten metals. The development of a reliable refract- ory lining, and the use of suitable construct- ion and operating techniques has led to the successful application of the Eldomet for casting copper anodes at Copper Refineries Pty. Ltd.

Jan 1, 1974

By P Bartlett, K Naidoo

Premier Diamond Mine is planning a new, mechanised, block cave, with a production level approximately 1000 m below surface. A high degree of tunnel damage is expected, due to stress and the relatively low in situ strength of kimberlite. An evaluation of the timing of tunnel excavation, tunnel size and spacing has been carried out to define critical parameters for planning layouts and development schedules. Extensive use has been made of three-dimensional FLAC3D numerical models, calibrated against known rock mass behaviour at 650 m depth, to examine the influence of undercut advance on production level excavations. These were able to represent the effect of stress rotation on tunnels during undercut advance and the effect of an inclined undercut. The analysis has provided guidelines that are possibly applicable to any deep block cave layout. The choice of drawpoint layout is of considerably less significance than the proportion of ground extracted on the production level elevation prior to advancing the undercut. The analysis shows that damage to production development will be potentially severe if it is all excavated prior to advancing the undercut, or is mined directly beneath the undercut face. The development of the main production tunnels alone ahead of the undercut may be feasible, but no breakaways should be put in as they appear to trigger a rapid increase in the severity of damage. The optimal sequence is when all production tunnels are developed at least 10 m in plan behind the undercut, where the induced peak field stress is less than 20 MPa and a maximum support pressure of 100 to 500 kN/m2 is require to contain movement. The assessment showed that the conditions are not significantly improved by increasing drawpoint spacing from 15 m to 18 m. The vertical spacing between the undercut and production level beneath is investigated. Provided production level development is carried out beneath the undercut, there would appear to be little benefit in increasing the vertical spacing between the undercut and production level beyond the current 15 m to 18 m.

Jan 1, 2000

By A Woodley, N C. Kunz

A mine site water balance is important for communicating information to interested stakeholders, for reporting on water performance and for anticipating and mitigating water-related risks through water use/demand forecasting. Gaining accuracy over the water balance is therefore crucial for sites to achieve best practice water management and to maintain their social license to operate. For sites that are located in high rainfall environments the water received to storage dams through run-off can represent a large proportion of the overall inputs to site; inaccuracies in these flows can therefore lead to inaccuracies in the overall site water balance.Hydrological models that estimate run-off flows are often incorporated into simulation models used for water use/demand forecasting. The Australian Water Balance Model (AWBM) is one example that has been widely applied in the Australian context. However, the calibration of AWBM in a mining context can be challenging. Through a detailed case study, we outline an approach that was used to calibrate and validate AWBM at a mine site. Commencing with a data set of monitored dam levels, a mass balance approach was used to generate an observed run-off sequence. By incorporating a portion of this observed data set into the calibration routine, we achieved a closer fit between the observed versus simulated data set compared with the base case. We conclude by highlighting opportunities for future research to improve the calibration fit through improving the quality of the input data set. This will ultimately lead to better models for run-off prediction and thereby improve the accuracy of mine site water balances.CITATION:Kunz, N C and Woodley, A, 2013. Improving the accuracy of mine site water balances through improved estimation of run-off volumes, in Proceedings Water in Mining 2013 , pp 267-272 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 26, 2013

By Kajioka H, Nakamura Y

Na2CO3 is a powerful flux for both dephosphorization and desulphurization in oxidizing atmospheres. In order to study refining with Na2CO3 and the nature of the Na2CO3 slag itself, hot metal (4Kg) was melted in Al203 crucibles in a high frequency induction furnace and oxidised with oxygen under Na2CO3 slag. The behaviour of Na2CO3 at high temperature was observed by thermobalance. It was found that dephosphorization ceases in a few minutes and [,P] after refining is easily lowered to less than 0.010%. [%P] after refining is affected by [Si], [P] of hot metal, the refining temperature and the consumption of Na2CO3. Desulphurization also ceases in a few minutes but it shows curious behaviour, increase of [S], decrease of (S) and increase in sulphur lost, during the latter half of run. [%S] after refining is also affected by [P] of hot metal, the refining temperature and the consumption of Na2C03o

Jan 1, 1980