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Removal of Arsenic in Fluorite Ore by Simultaneous Grinding-Leaching with NaHS Generally speaking, a high-grade fluorite ore is converted into hydrogen fluoride (HF), which is essential for the semiconductor manufacturing. With the continuous depletion of resources, novel technologies for processing low-grade fluorite ores are urgently needed, in order to lower the arsenic concentration to less than 100 mg/kg. In this study, a low-grade fluorite ore was upgraded by removing arsenic, which is difficult to remove by conventional method. The mechano-chemical leaching of fluorite ore (i.e. the sample was ground in presence of NaHS, using a beads mill) was carried out to investigate the removal of arsenic from the low-grade fluorite. Experimental results showed that the arsenic concentration was reduced to 73.2 mg/kg.

Sep 13, 2010

Despite the research interest on non-cyanide gold lixiviants over the past three decades all the non-cyanide gold processes are still at the developmental stages with limited understanding on solution and pulp chemistry in some cases. This is partly associated with:the difficulties in measuring reliable equilibrium data for various gold(I/III) complexes with non-cyanide ligands; the lack of knowledge on mixed-ligand complexes; and different kinetic stabilities of gold(I) complexes with respect to disproportionation. This paper presents reliable equilibrium data for complex formation, dissolution, precipitation, hydrolysis and disproportionation reactions of gold(I/III) compounds with a range of non-cyanide ligands: S2-, HS-, S2O32-, SO32-, SCN-, SC(NH2)2, OH-, NH3, Cl-. Solubility of gold(III) compounds with non-cyanide ligands follows the order: Cl- > NH3 > OH-. In the case of gold metal the solubility order at a given temperature is MgS > Fe(III) or Cu(II) / Cl- > Cu(II)/NH3 > NaOH, but the solubility increases with increasing temperature. Rate of gold oxidation with different non-cyanide lixiviants depends on the oxidant, ligand and temperature and follows the general order of oxidants: Fe(III) or Cu(II) > X2 or OX- > O2 (X = halogen). In the case of metal ion oxidants oxygen is required to reoxidise Cu(I) or Fe(II). Some of the reported data on chloride and thiosulfate leaching of gold are presented to highlight the effect of additives and the copper, silver and sulfur contents of the starting material on the success of non-cyanide leaching processes.

Jan 1, 2004

By D N. Castendyk, J L. Mauk

The world-class Waihi (>6.6 Moz Au, >41.8 Moz Ag) and adjacent Favona (>0.5 Moz Au) deposits are within a single volcanic-hosted epithermal Au-Ag district located in the southern Coromandel Peninsula, New Zealand. Gold and silver mineralised quartz veins at both deposits are hosted in porphyritic andesite flows of the Waipupu Formation. Both deposits have veins surrounded by intense widespread hydrothermal alteration that is characterised by the assemblage of quartz, pyrite, adularia, illite or interstratified illite-smectite, plus less common chlorite and albite, which is locally overprinted by minor calcite or rare kaolinite. Quantitative mass transfer calculations using Gresen's general metasomatic equation indicate that hydrothermally altered andesite at both deposits is enriched in silicon, potassium, rubidium, barium, sulphur, gold, arsenic and antimony, whereas sodium, strontium and calcium are mostly lost. Iron and magnesium show mixed gain and loss. Element gain or loss can be directly related to the prevailing alteration mineralogy. Addition of potassium, rubidium and barium coupled with the concomitant loss of sodium, strontium and calcium in intensely altered wall rocks corresponds to the replacement of plagioclase by adularia or illite. Partial retention of sodium and calcium reflects the presence of hydrothermal albite and calcite, respectively. Mass balance calculations show distinct element gain and loss that can be related to the intensity and type of alteration mineralogy. However, because most rocks are intensely altered and the progression into less altered peripheral rocks is not observed in this study, the lateral extent of elements gain or loss is unconstrained with anomalies extending at least 200 to 300 m away from major veins.

Jan 1, 2003

Removal of Dilute Toxic Anions in Wastewater Using Aluminum Hydroxides Co-Precipitation Method

Sep 13, 2010

Flotation of Composite Synthetic Particles

Sep 13, 2010

By M A. Knackstedt

Coupling between deformation processes and rock permeability is a major factor influencing the architecture of fluid migration and the localisation of ore deposition in several types of hydrothermal ore systems in middle to upper crustal regimes. Permeability in many hydrothermal systems is controlled by a dynamic competition between deformation-induced porosity-creation processes and porosity-destruction processes. Localisation of deformation within faults, fractures and shear zones leads to flow localisation, with large-scale flow systems forming when active faults and shear zones link to create percolation networks. Numerical modelling techniques are used to explore the growth of fracture networks and evolution of network connectivity during progressive deformation. Initial results indicate that networks reach a percolation threshold at very low strains. Near the percolation threshold, flow is localised along a small proportion of the total fracture population and favours localised ore deposition. At higher strains, flow is distributed more widely throughout the fracture population and may provide reduced potential for production of high-grade deposits. The distribution of mesothermal gold deposits along a small subset of the total population of co-active faults and shear zones in the Archaean Yilgarn Craton in Western Australia indicates that some hydrothermal systems maintain themselves near the percolation threshold for a substantial part of the lifetime of the system. Fluid-driven growth of fault/fracture/shear networks may lead them to self-organise near the percolation threshold.

Jan 1, 1999

By J Gresham, A Turichshev

Ore from Henderson’s 7700 Southwest panel cave is transported between the production and truck haulage levels through a series of orepasses. A typical orepass complex consolidates dump points from four production drifts into two long bored raises feeding into a single truckloading chute. The system typically covers a vertical extent of 200 m and a lateral extent of 90 m. In the process of commissioning several initial orepass complexes, challenges with preferential draw in the long bored raises were observed. Preferential draw occurs when one long orepass mobilises much sooner and/or flows significantly faster than the other orepass. This has negative implications for orepass availability in the production drifts. As future mining at Henderson relies on the construction and use of such orepass systems, the development of appropriate design criteria and practical solutions to existing flow problems was necessary.A series of PFC3D numerical models were developed to assist in identifying the factors influencing preferential draw and possible corrective measures. The models helped to identify two primary factors that caused the preferential effect: the relative elevation of the brow at the bottom of each long bored raise, and the location of the bin used to funnel fragmented rock from both raises into the chute. This paper covers the initial design of the orepass complexes at Henderson, results of the numerical models, mitigation work done to date on existing orepass complexes, and design criteria for future construction.CITATION:Gresham, J and Turichshev, A, 2016. Correcting preferential flow problems in long orepass systems at Henderson Mine, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 549–554 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

By G Sparrow

The Murray Basin is being heralded as the next major mineral sands province in Australia. Already exploration programs have delineated extensive commercial deposits and several companies are progressing with plans to produce zircon, rutile and ilmenite in the Basin. As these deposits are developed consideration will need to be given to several key issues of the Murray Darling Basin; the availability of fresh water and management of salinity in the area being two of them. In this paper ideas being developed in CSIRO that link the processing of mineral sands with the salinity problem in the Basin are presented. The proposal presented here is to process saline water to produce industrial minerals with large volume applications and to produce value-added products from the mineral sands in the Basin using reagents produced from the saline waters. Processes to produce titania pigment and zirconia consume chlorine, caustic soda, soda ash and hydrochloric acid, all derivatives of salt (sodium chloride). There may be a good economic incentive if these processing plants were located in the close vicinity of each other.

Jan 1, 2001

By R Aseervatham

The fast tracked mine development strategy attempts to blend feasibility studies and engineering/commissioning functions into a streamlined process. In this compressed process, environmental issues are difficult to control with respect to the optimisation of operational environmental performance. This paper presents a standard mine development process with specific focus on environmental issues, and contrasts this against Rio TintoÆs recent fast track experiences on the Hail Creek project (Australia), the Baranj project (India) and the Gokwe North project (Zimbabwe).

Jan 1, 1999

By D Craw, S Clearwater, S Hammit, C Smith

Prior to rehabilitation, plant cover on quartz gravel overburden at Wangaloa coal mine was highly patchy. Stabilisation techniques have since considerably altered the condition of the main overburden yet deposits in the east and west remain largely intact. On the eastern overburden, three distinct zones of revegetation have naturally developed: Zone 1 represents a dense plant cover, Zone 2 a patchy cover and Zone 3 a sparse cover of isolated plants. Aerial photographs show much of the eastern overburden was deposited between 1940 and 1960s. Yet we found that the temporal scale of deposition did not wholly account for the differences observed in vegetation development. To investigate other influential factors, we set up 12 study plots using four replicates in each vegetation zone. The diversity and density of plants in each plot were measured to quantify the degree of vegetation development. Samples from the substrate in each plot were collected using soil cores to a depth of 10 cm. Cores were analysed for indicators of nutrient availability, metal content and physical composition. We found that substrate chemistry varied between individual study plots, but showed little difference overall along the vegetation gradient. Substrate physical differences were much greater. The ratio of coarse quartz pebbles: fines was considerably higher in Zone 3 than other zones, and within zones where plants were not growing. Bulk density also increased successively from Zone 1 - 3. We found clear evidence for the reversed stratigraphy of excavation superimposed over the time scale of deposition, and the corresponding nature of fine particles. The rate of revegetation was therefore highly dependent upon the substrate composition of the last surface deposit from the dumping truck. Our data suggests an optimum ratio exists between inert coarse material and a fine matrix for progressive natural vegetation development on mine substrates.

Jan 1, 2004

By M P. Simpson

Forty one whole rock samples from the Gold Cross low-sulfidation epithermal Au-Ag deposit have d18O values that range from 4.4 to 9.3 per mil, with an average value of 7.0 per mil. Unaltered and weakly altered rocks have d18O values greater than eight per mil, and the orebody is surrounded by samples that are depleted in 18O. A strongly silicified sample adjacent to the Empire Vein System has a d18O value of 9.0 per mil, similar to previously reported analyses of vein quartz (7.0 to 11.7ë, average 9.4ë). This suggests that, in detail, Golden Cross may have a zone of 18O-enriched wall rocks in the core of the deposit, adjacent to the main underground veins. Although some workers have suggested that stable isotope geochemistry may provide useful information for epithermal mineral deposit exploration, at Golden Cross this is not the case. Alteration minerals, major elements and trace elements all define larger, less ambiguous halos than the zone of 18O-depleted wall rocks.

Jan 1, 2001

Recovery Process of Carbon Dioxide with Metal Oxides and Metal Hydroxides

Sep 13, 2010

By J Coward, S Bulatovic

There are currently two operators producing oil from the surface-mineable portions of AlbertaÆs oil sands (Syncrude Canada Ltd and Suncor Inc) and two other companies are proposing to enter the industry (Albian Sands Energy Inc in 2002 and True North Energy LP in 2004). Tailings from the two current oil sands plants contain approximately 220 000 tonnes per year of TiO2 and approximately 80 000 tonnes per year of zircon. This represents approximately six per cent of the worldÆs TiO2 consumption and approximately nine per cent of the worldÆs zircon production. With the commissioning of plants by Albian and True North, and the announced expansion of plants by Syncrude and Suncor, it is expected that these tonnages could quadruple in the next ten years. All of these operators have at least 50 years of reserves even at these expanded production rates. The occurrence of heavy minerals in AlbertaÆs oil sands has long been known and is well documented in the literature. There have been a number of attempts to produce market-grade products from this resource and the results of this work have been quite mixed. Typically, researchers have used the normal mineral dressing techniques of the industry and have found the mineral assemblage does not respond to these techniques all that well. This has led to the widely-held suspicion that there must be some difficult metallurgical problems associated with this resource. There are three main problem areas that have created difficulties for previous researchers:the bitumen coating on the sand grains; secondary mineralisation such as pyrite, siderite and calcite; and a high proportion of aluminosilicates (approximately 25 per cent) that have the same gravity, electrostatic and magnetic properties as other minerals in the heavy mineral suite. Recent work by Lakefield Research shows that these problems can be largely overcome with some novel approaches. The bitumen can be removed by washing with a solvent in the presence of a demulsifier; the pyrite can be removed by flotation; and the titanium and zircon minerals can be separated by selective flotation followed by conventional electrostatic and magnetic separation.

Jan 1, 2001

Comparison of Industrial Cyanide Destruction Processes

Sep 13, 2010

Validation and Application of Filtration Theory to Plate and Frame Pressure Filtration - From Laboratory to Full Scale

Sep 13, 2010

By D R. Carr

The installation of the Flotation Capacity Project flow sheet in the copper concentrator at Mount Isa Mines Limited has recently been completed. The project involved increasing the flotation capacity with Wemco tank cells and Jameson cells as well as changing the copper cleaner circuit layout. The engineering design and construction for the brownfield expansion had significant involvement from operational, maintenance and technical personnel adopting the same approach as the highly successful George Fisher project in the Lead/Zinc Concentrator at MIM. The involvement of people familiar with the concentrator allowed for smooth integration of the changes into an operating concentrator with minimal downtime. Detailed circuit analysis over many years identified opportunities for improvements in the flotation circuit for both grade and recovery. This paper describes the program of work that led to the Copper Concentrator Flotation Capacity Project, and the implementation of the circuit expansion and flow sheet changes that resulted in an overall improvement in the circuit recovery.

Jan 1, 2003

Development of Grindability Tests Based on Direct Measurement of Energy Nowadays, for the characterisation of the grindability different grindability indices - Bond-work index (Wi), Hardgrove Grindability Index (HGI) or Zeisel specific grindability (Wt) - are used. Generally, the grindability tests are carried out under relatively simplified circumstances, in a special dry batch mill with defined feed size material until prescribed conditions are reached at room temperature. However, in the fine- and ultra fine grinding, which is a frequent task (fly ash, tailings, alumina, etc), a fine material (<50 - 200 ¦m) is usually ground down to the few micrometers. The conventional grindability testing methods and apparatuses (Bond-, Hardgrove-, Zeisel-processes) for their determination, although, are not suitable directly to measure the grindability of such fine materials, since the maximal particle size of the feed material (0.5 - 3 mm) to be tested is much higher. One of the important goals of the research carried out in our Institute was to develop the novel grindability testing methods, which are suitable for the fine and ultra fine grinding, and additionally provide the possibility for the fast determination of the grindability. In order to realise the above aim the conventional Bond- and Hardgrove- mills were modified in order to directly measure the grinding work. In particular, the Hardgrove-mill was equipped with a simple torque-meter (load cell). The Bond-mill was rigged with a digital electric power measurer. The systematic experiments were carried out parallel in both mills using the conventional and the developed methods. Finally the results of both were compared. The measuring results have proved that the Bond-work index can be determined based on the developed methods. The new grindability testing methods were applied successfully in several industrial research tasks for the determination of the specific grinding energy and the Bond-work index. These methods can be also used in the industrial practice for the control of the grinding process.

Sep 13, 2010

By M I. Pownceby, S Hapugoda, V Nunna

Deposits of low-grade iron ores containing abundant goethite are distributed across the world. A common difficulty associated with beneficiating goethitic-rich ores is the poor liberation characteristics of the iron-bearing minerals which often contain finely disseminated gangue minerals such as kaolinite, gibbsite and quartz. Microwave-assisted heating has been proposed as an effective way of inducing dehydroxylation and associated mineral transformations in order to beneficiate low-grade goethitic ores. In this research, the mineral transformations occurring in a low-grade goethite-rich sample using microwave radiation was studied. Roasting conditions (up to 1000°C and under various CO/CO2 gas atmospheres) were designed to generate a magnetic product from a goethite-rich, reject waste stream sample sourced from an iron ore processing site in the Pilbara, Western Australia. Conditions (T, pO2) for transforming the raw material from hydrated goethite to hematite and eventually to magnetite are presented. Chemical and mineralogical characterisation of the raw material and roast products were conducted using X-ray fluorescence, X-ray diffraction, optical microscopy and scanning electron microscopy techniques to identify the mineralogical and chemical changes occurring during the heat treatment. Further steps are suggested to optimise the microwave-assisted magnetising roasting and correlate it with the application of magnetic separation techniques to maximise the efficiency of upgrading the iron content in low-grade iron ores.CITATION:Nunna, V, Hapugoda, S and Pownceby, M I, 2017. Study of microwave-assisted magnetising roasting and mineral transformation of low-grade goethite iron ores, in Proceedings Iron Ore 2017, pp 575–582 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

By Jarc H

The steeply dipping silver/lead/zinc orebodies at Mount Isa mine have been extracted most recently by a combination of cut-and-fill and open stoping methods. Bench stoping was first used at Mount Isa Mine seven years ago to allow safe extraction of a highly stressed cut-and-fill stope. Subsequent benches have shown that the method offers significant cost and safety benefits through increased productivity and reduction in man exposure. The success of benching has lead to cut-and-fill mining being replaced at Mount Isa.Significant resources have been focussed to optimise benching. This paper describes the operational, planning, and research and development aspects which have contributed to the method to date. A brief look is also taken at the future direction of benching at Mount Isa.

Jan 1, 1992

The West Coast region of the South Island is situated astride the Pacific û Australian plate boundary zone. The most significant component of this zone is the Alpine Fault. A variety of reconstructions of the pre-Alpine Fault plate tectonic configuration of the New Zealand continental area have been attempted over the past 25 years or so. Most of these have not been closely constrained by a regional compilation of field data related to the age and horizontal displacement history of the Alpine Fault. A model in which the Alpine Fault was initiated no earlier than the interval 18 - 16.5 Ma (B.P.) is proposed, a significantly younger age of inception than has been widely accepted as the onset of dextral displacement along the plate boundary through the South Island. A subsequent history of displacement is presented consistent with the West Coast basin stratigraphy. The alluvial gold content of some parts of the Miocene to Pleistocene conglomerate sequences is also discussed.

Jan 1, 1996