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By J. C. Sullivan, W. A. Knoll

The sinking of a new shaft at the Newport mine, Ironwood, Mich., was started in May 1931 and completed on Aug. 3, 1932. During this period, 2665 ft. of shaft in granite was completed, at an average advance of 6 ft. per 24 hr. In Novernber of 1930, experimental work was conducted on 65 ft. of shaft through 22 ft. of overburden where ledge was encountered, and this work convinced the operators that all drilling could be done with vertical holes with the blasting relief to a 4½-in. hole drilled vertically in the center of the cut. The reason for not adopting the conventional V-cut was to get away from damaging the shaft steel. The blasting in a V-cut naturally tends to throw the broken material upward, but with the cut as adopted the relief was in a horizontal direction to a large extent. The scheme of mucking employed made it necessary to keep the steel shaft sets within 50 ft. of the bottom at all times. This could not be done without serious damage with a V-cut when blasting in granite. The cut as drilled also broke 10.83 ft. per round of drilling, which was considerably more than the experience with a V-cut in the same material. The extended cut reduced proportionately the delays for charging, blowing smoke and handling drilling equipment in the shaft. Another advantage was the ease in drilling vertical over inclined holes, and the preservation of the proper spacing of the drill holes at the bottom of the cut. Drilling Air was carried down the shaft in an 8-in. flanged pipe line at a pressure ranging from 95 to 100 Ib. This line was extended to within 100 ft. of the bottom, where a valve and a 4 by 4 by 6-ft. tee was connected to it. To each side of the tee was connected a nipple and elbow, the resulting span of the two elbows being about 4 ft. Lengths of short 3-in. hoses

Jan 1, 1940

By Robert H. Aborn, J. J. B. Rutherford

It is now well known that troublesome intercrystalline corrosion may occur in austenitic stainless steels following exposure of the metal to a temperature within the range 1000° to 1500° F. (540° to 815° C.). The present paper describes a satisfactory method of estimating the extent of such corrosion, based on the measurement of the electrical resistance of a specimen before and after attack. This new method enabled us to study quantitatively the effect of several factors upon intergranular corrosion in the 18 Cr, 8 Ni type of alloy. The results show that susceptibility to this attack increases with increasing carbon content and grain size and appears to pass through a maximum for certain combinations of temperature of sensitization and period during which the alloy was maintained at that temperature; and are in complete accord with our interpretation of the mechanism of this phenomenon. The method is probably applicable to other metals or alloys subject to intercrystalline attack, such as the aluminum alloys of the duralumin type. The methods hitherto in use for estimating the degree of intergranular attack fall into three types: (1) microscopic examinationll (2) macroscopic examination of fractures, and (3) determination of the time required for complete failure or disintegration.2 None of these lends itself very well to a measurement of the extent of corrosion. The first two are qualitative in nature and the third provides an arbitrary value largely dependent on individual judgment, since failure is a progressive phenomenon and not a sudden event. Our experience is that weight-loss determinations, although valuable in some types of corrosion investigations, bear no simple relation to intercrystalline corrosion in this type of alloy, as is to be expected since the phenomenon probably involves only the thinnest films between adjacent metallic grains. Measurement of electrical resistance has been used recently in the study of some types of corrosion,3 but seems not to have been applied to

Jan 1, 1932

By Wilbur A. Nelson

In 1839, Gerard Troost,1 the first State Geologist of Tennessee, reported the occurrence of zinc ores in east Tennessee, in connection with the iron ores at Embreeville; in 1844,2 he refers to the zinc deposits of east Tennessee, especially the apparently rich deposits occurring in Jefferson and Claiborne Counties, while his ninth annual report 3 s a description of the zinc deposits of Jefferson County and a description of the most improved processes by which zinc is extracted from its ores. Yet, only during the last few years have these ores been successfully worked. As far as can be learned, prior to the systematic development of the Mascot district in 1911, no large-scale or successful operation of any of the zinc deposits was carried on. But in that year, after several companies had made considerable progress in developing the Mascot area and had proved a relatively extensive body of low-grade sulfide ore, the American Zinc Co. entered the field. It introduced modern methods of prospecting and mining and from the first was successful. Too great credit cannot be given this company for its pioneer work in a previously unimportant field. Throughout the history of its operations, the American Zinc Co. has confined its efforts to underground mining of the sulfide ore, sphalerite. This company has found that successful results in zinc mining in east Tennessee can be achieved only by expending large sums in prospecting and blocking out bodies of pay ore in sufficient magnitude for large-scale operations. At Mascot are located the mines of the American Zinc Co. of Tennessee, the mines being situated along the Southern Railway in the Ilolston River Valley, Knox County, about 13 miles northeast of Knox-ville. At first only open pits, which were worked for oxidized ores, were operated and the production was small. In 1900, the Roseberry Zinc Co. was organized and sank to a depth of 187 ft. what is now known as No. 3 shaft of the American Zinc Co. The upper 30 ft. was in residual clay,

Jan 1, 1925

By Michael D. Martin

Pima Mining Co., managed and 50% owned by Cyprus Mines Corp., with Union Oil of California and Utah Construction and Mining Co. sharing equally in the remaining 50%, is a medium-sized open pit copper mine situated in the very active Twin Buttes mining district, 22 miles southwest of Tucson, Ariz. In 1965, a three-part paper described Pima's growth from 3,000 tpd (tons per day) in 1957 to 18,000 tpd nine years later. Within months of the completion of the last stage of this sixfold expansion, studies were being wound up on a further major expansion, this time to 30,000 tpd. This expansion is now a reality. Details of the enlargement of the crushing and concentrating plant have already been covered in a recent paper, and the present paper will cover pit engineering studies, equipment selection, and current operating practices. Key factors in top management's decision to go ahead with the latest expansion were: (1) a substantial increase in ore reserves coupled with an appreciable decrease in grade, (2) a generally favorable outlook for copper prices, and (3) better than expected performance by mine and mill equipment purchased for the expansion to 18,000 tpd. For the pit design studies, particular attention was paid to pit stability, a problem area at times in the past, and to the location and grades of the final ramp systems. In drawing up the long-term mining schedule, the attitude of the ore, with the higher grade material lying deeper, was a critical factor and considerable stockpiling of lower-grade material in the early years had to be accepted in order to keep the annual grades close to the average of the orebody. The expansion called for major purchases of mine equipment in order to gear up the mine for delivery of 30,000 tpd to the concentrator. In general, equipment chosen was of types already proven at Pima, al- though there were some exceptions to this practice. One of these excep-

Jan 1, 1969

By J. C. Sullivan, W. A. Knoll

THE sinking of a new shaft at the Newport mine, Ironwood, Mich., was started in May 1931 and completed on Aug. 3, 1932. During this period, 2665 ft. of shaft in granite was completed, at an average advance of 6 ft. per 24 hr. In November of 1930, experimental work was con- ducted on 65 ft. of shaft through 22 ft. of overburden where ledge was encountered, and this work convinced the operators that all drilling could be done with vertical holes with the blasting relief to a 4%-in. hole drilled vertically in the center of the cut. The reason for not adopting the conventional V-cut was to get away from damaging the shaft steel. The blasting in a V-cut naturally tends to throw the broken material upward, but with the cut as adopted the relief was in a horizontal direction to a large extent. The scheme of mucking employed made it necessary to keep the steel shaft sets within 50 ft. of the bottom at all times. This could not be done without serious damage with a V-cut when blasting in granite. The cut as drilled also broke 10.83 ft. per round of drilling, which was considerably more than the experience with a V-cut in the same material. The extended cut reduced proportionately the delays for charging, blowing smoke and handling drilling equipment in the shaft. Another advantage was the ease in drilling vertical over inclined holes, and the preservation of the proper spacing of the drill holes at the bottom of the cut. DRILLING Air was carried down the shaft in an 8-in. flanged pipe line at a pres- sure ranging from 95 to 100 lb. This line was extended to within 100 ft. of the bottom, where a valve and a 4 by 4 by 6-ft. tee was connected to it. To each side of the tee was connected a nipple and elbow, the resulting span of the two elbows being about 4 ft. Lengths of short 3-in. hoses

Jan 1, 1938

This report presents the comments of members of the Institute's Sub-committee on Physics of Mine Ventilation on the proposals of a special committee of the Institute of Mining Engineers (London). This report is as follows: THEORY OF MINE VENTILATION Abstract of a report submitted June 16, 1925, to the Council of The Institution of Mining Engineers by a Special Committee Laws of Flow of Aib The law of flow of air in mine galleries is, at present, expressed by two formulas differing slightly in shape but both derived from the original hydraulic formulas of Chezy and others. These formulas are: The Atlcinson Formula.—Pa = KsV2, which in transformation becomes a3 where P = pressure producing flow; K = coefficient of friction; s = surface of the mine galleries; V = velocity of flow; Q = rate of flow; a = area of mine galleries. This formula is especially applicable to mine galleries, but is unwieldy in application, as in many problems we are dealing with changes produced in the same set of airways when K, s, and a are assumed not to change, and the only variables are P and Q. Great uncertainty prevails as to the exact values to be assigned to the coefficient K in different types of airway, as different workers have given widely differing values. This formula assumes: (I) That resistance to flow is independent of the pressure within the gallery. (2) That changes in volume within the limits of pressure ordinarily met with may be neglected. (3) That changes in density and viscosity and mode of flow of the air may be neglected. (4) That the coefficient K is a constant. (5) That P is proportional to the square of the velocity. We cannot find any reliable experimental work leading us to conclude how far these assumptions are justifiable in mining practice. Equivalent Orifice Formula.—The fundamental form of this formula is Q = ~nA.\/2~11

Jan 1, 1927

By W. L. McMorris

The Convertol process was first described in Germany by Muschenborn' in 1952. In the U. S. Fraser' reported this new process in 1953, and Brisse and McMorris" presented the results of a Convertol pilot plant at the Alpheus preparation plant in Gary, W. Va., illustrating the mechanics of the process by a series of sketches. The purpose of the present investigation was threefold: 1) to determine the relative effectiveness of various oils and hydrocarbons for recovering coal by the Convertol process, 2) to ascertain the behavior of coal pulps in this process under various operational conditions, and 3) to compare Convertol with flotation in the recovery of fine coals. APPARATUS, PROCEDURE, AND COAL SAMPLES In laboratory work with the Convertol process a Waring Blender equipped with a speed-regulating rheostat was used for wetting, conditioning, inversion, and retention of the coal pulp. A 5-in. International centrifuge was adapted to dewater the agglomerated clean coal product by installation of a 100-mesh screen inside the regular bronze basket of the centrifuge. Except where otherwise stated, the Convertol testing was performed by the following steps: 1) A 450 to 500-cc coal slurry, containing 24 pct by weight of solids, was agitated in the blender for 10 min at 100 rpm to insure complete wetting and mixing. 2) Eight percent by weight of oil was added to the coal slurry in the blender and agitated for 1 min at 11,000 rpm to result in the phase inversion or agglomeration of oil-coated coal particles. 3) The agglomerated coal slurry was poured onto a 100-mesh sieve and wet-screened for about 2 min to remove most of the ash and some of the water. 4) The material remaining on the screen was transferred into the centrifuge for final dewatering. 5) A portion of the clean coal was immediately weighed out for moisture determination, while the

Jan 1, 1960

By L. H. Levenson, Charles S. Barrett

Since 1925, when the preferred orientations in compressed aluminum were first determined1,2 the orientations have been described as a fiber texture in which a face diagonal, [110], of the face-centered cubic lattice is parallel to the compression axis. Subsequent experiments have seemed to confirm this texture,3-5 and a number of theories (recently summarized in references 6 and 7) have been proposed to explain it and to relate it to the behavior of single crystals during compression.3,8-11 The experiments reported in this paper prove that the orientations are not adequately described as quoted above—i.e., as a [110] fiber texture—although this is a first approximation to the actual texture. They also show that the texture cannot be thought of as a stable orientati011 that is reached and maintained after a sufficient amount of deformation. The actual texture, when studied in detail at successive stages of compression, indicates that a hitherto unsuspected range of orientations is present, both in the polycrystalline metal as a whole and in various individual grains in its interior, and that a state of dynamic equilibrium exists within this range. The reasons for the failure of previous theories to predict the actual texture become obvious when the heterogeneous nature of the flow is considered. In addition to the deformation texture, the manner of its development, and its theory, this paper presents data on the following related subjects: the identity of strain markings in aluminum; the orientation changes in aluminum single crystals during compression and a comparison of these with the conditions in individual grains of a polycrystalliile specimen; the origin of asterism ill deformed single crystals, which heretofore has been regarded as a distortion localized at the surfaces or slip planes; and the relation of plastic strain in individual grains ill all aggregate to the strain of the whole.

Jan 1, 1940

By Charles S. Barrett, L. H. Levenson

Since 1925, when the preferred orientations in compressed aluminum were first determined1,2 the orientations have been described as a fiber texture in which a face diagonal, [110], of the face-centered cubic lattice is parallel to the compression axis. Subsequent experiments have seemed to confirm this texture,3-5 and a number of theories (recently summarized in references 6 and 7) have been proposed to explain it and to relate it to the behavior of single crystals during compression.3,8-11 The experiments reported in this paper prove that the orientations are not adequately described as quoted above—i.e., as a [110] fiber texture—although this is a first approximation to the actual texture. They also show that the texture cannot be thought of as a stable orientati011 that is reached and maintained after a sufficient amount of deformation. The actual texture, when studied in detail at successive stages of compression, indicates that a hitherto unsuspected range of orientations is present, both in the polycrystalline metal as a whole and in various individual grains in its interior, and that a state of dynamic equilibrium exists within this range. The reasons for the failure of previous theories to predict the actual texture become obvious when the heterogeneous nature of the flow is considered. In addition to the deformation texture, the manner of its development, and its theory, this paper presents data on the following related subjects: the identity of strain markings in aluminum; the orientation changes in aluminum single crystals during compression and a comparison of these with the conditions in individual grains of a polycrystalliile specimen; the origin of asterism ill deformed single crystals, which heretofore has been regarded as a distortion localized at the surfaces or slip planes; and the relation of plastic strain in individual grains ill all aggregate to the strain of the whole.

Jan 1, 1940

By H. P. Greenwald

THIs paper brings forward a discussion that was prepared for the meeting of the Coal Division in Chicago in 1938.1 War in Europe less than a year after that meeting, followed by our defense preparations and entry into the conflict, caused general cessation of large-scale experimentation on the subject, and it is best to confine this paper to events in the United States during the five-year period since the preceding paper was written. The views of members of the Coal Division's Committee2 on Rock-dust-ing for 1943 were obtained before this paper was written and the manuscript was reviewed by them. Extent of Rock-dusting Statistics on the use of rock dust in the United States during the years 1930-1933, appearing on page 97 of Volume 139 of the Transactions are extended in Table I herein through the year 1941. The results through 1933 did not appear encouraging, but there has been improve-ment since that date. It has always been true that the larger operations were the ones that used rock dust. In 1941 only 10 per cent of the mines in the country used rock dust, but they produced 57 per cent of the coal, employed just under 50 per cent of the miners, and accounted for 52 per cent of the man-hours. Unfortunately, collection and compilation of these statistics are slow procedures, and figures dealing with the tremendous war expansion of the industry are not likely to be available for a year or more. In 1941 the five leading states in regard to percentage of man-hours worked in mines using rock dust were: Utah, 92.1; Wyoming, 79.3; Alabama, 77.4; New Mexico, 72.5; West Virginia, 65.3. The first four states were the same as in 1933, but West Virginia displaced Washington in fifth place. On the basis of pounds of rock dust used per ton of coal, the five leading states in

Jan 1, 1944

By H. P. Greenwald

THIs paper brings forward a discussion that was prepared for the meeting of the Coal Division in Chicago in 1938.1 War in Europe less than a year after that meeting, followed by our defense preparations and entry into the conflict, caused general cessation of large-scale experimentation on the subject, and it is best to confine this paper to events in the United States during the five-year period since the preceding paper was written. The views of members of the Coal Division's Committee2 on Rock-dust-ing for 1943 were obtained before this paper was written and the manuscript was reviewed by them. Extent of Rock-dusting Statistics on the use of rock dust in the United States during the years 1930-1933, appearing on page 97 of Volume 139 of the Transactions are extended in Table I herein through the year 1941. The results through 1933 did not appear encouraging, but there has been improve-ment since that date. It has always been true that the larger operations were the ones that used rock dust. In 1941 only 10 per cent of the mines in the country used rock dust, but they produced 57 per cent of the coal, employed just under 50 per cent of the miners, and accounted for 52 per cent of the man-hours. Unfortunately, collection and compilation of these statistics are slow procedures, and figures dealing with the tremendous war expansion of the industry are not likely to be available for a year or more. In 1941 the five leading states in regard to percentage of man-hours worked in mines using rock dust were: Utah, 92.1; Wyoming, 79.3; Alabama, 77.4; New Mexico, 72.5; West Virginia, 65.3. The first four states were the same as in 1933, but West Virginia displaced Washington in fifth place. On the basis of pounds of rock dust used per ton of coal, the five leading states in

Jan 1, 1944

By Leon H. Nelson

Several factors which affect the segregation and solidification of killed hot-topped steel ingots are: (1) pouring temperature, (2) volume in the hot top, (3) taper in the ingot, (4) pouring rate by varying the nozzle size, (5) segregation of several elements, (6) moving ingots before completely solidified. In most of this discussion, segregation will be measured in terms of carbon variation only. All the data given are results on S.A.E. 1040 analysis of fully killed steel direct-poured in hot-topped molds giving 20-in, square ingots. Thus the variables of analysis and ingot size and contour are eliminated. Segregation results are all on the rolled-bloom size, not on the ingot itself. They are results from plant-control work and not results of special research on ingot segregation. Pouring Temperature The temperature (or, more correctly, the amount of superheat above the liquidus-solidus) of the steel entering the ingot is, of course, one of the most important factors influencing segregation and solidification. Table 1 gives the average segregation of a number of heats of S.A.E. 1040 steel with normal pouring temperatures of 2775" to 2825" F. The table also gives some data on segregation in hot heats (pouring temperature 2840" to 2870" F.) and in cold heats with some skull (poured at 2725" to 2760" F.). The results in Table 1 are on steel ingots with 20-in. square cross section and 60 in. long to the hot top. The ingot weighs 7100 lb. and the hot top contains 14.3 per cent of the total ingot volume and 11.2 per cent of the total ingot weight. The results are from drillings after rolling the ingots to bloom size. Segregation results obtained on the bloom are probably not as great as they would be in the ingot itself, since heating the ingots for rolling can perhaps cause some migration of carbon from regions of high and low carbon to those of average carbon content.

Jan 1, 1937

By J. Stubbins

1 1.4-1. Source of Water. Precipitation in the form of rain or snow is the original source of water that enters most surface mines. The precipitation, which does not escape to the atmosphere, either becomes surface run- off or infiltrates into the ground to become ground water (3,4). Evaporation and surface run-off can be measured. The water that infiltrates the ground disappears from view and is more difficult to evaluate. In general, it moves in a pattern similar to the surface run-off, but at a much slower rate, since its progress is impeded by many subsurface conditions. The infiltrating water descends through the soil and rock by whatever passageways permit flow until the water table or top of the zone of saturation is reached. Though usually pictured as a level surface, it is dependent upon the topography and the permeability of the enclosing material, and therefore it can be as erratic and unpredictable as the subsurface geology. Ground water may become surface run-off again at a lower point, and likewise, surface run-off of lakes and streams can infiltrate to become ground water. Should the ground water be confined to a permeable zone overlain by an impermeable barrier, a pressure is created. Such water is said to be artesian if the pressure head is sufficient to raise the confined water to the surface. These conditions are more commonly found in relatively flat-lying bedded formations. 11.4-2. Recognition and Estimation of Water. Dewatering and flood control should be considered by the design engineer at an early stage in all surface mine planning. Recognition of the possible problems, and making allowance for their solution, is an inexpensive precaution. Circumstances which should lead to investigation are: 1. High rainfall 2. Experience of other mines in the area 3. Evidence of water and caving in drill holes 4. Presence of springs and artesian wells 5. Geological evidence of aquifers.

Jan 1, 1968

By Warren B. Weeks

Continued development in the deeper fields discovered during 1937 and 1938 was largely responsible for the 16 per cent (2,913,400-bbl.) increase in production, bringing the 1939 output to 21,376,230 bbl., the largest for South Arkansas since 1929. The older settled fields continued to decline and Rodessa was added to this classification. Magnolia field accounted for much of the increase, with Schuler field showing only a slight increase. There were 248 wells drilled during 1939, five more than during the previous year. Of 198 wells drilled in proven fields, 21 were dry; 46 of the 50 wildcats drilled were dry. The old depth record of 8332 ft. was increased to the present record of 9028. Trend of Prospecting Production from the porous " Reynolds " oolite zone of the Smackover limestone continued to be the objective of prospecting. During the year 20 seismograph, 3 gravity meter, 1 magnetometer, 1 soil analysis and 1 electromagnetic crews were reported in the state. The geophysical work was largely concentrated in three southern counties: Columbia, Lafayette and Union. As indicated in Table 2, the same three counties received most of the important drilling tests. At the end of the year only three seismograph crews remained in the areas. The area for prospecting Smackover limestone was greatly narrowed during the year by the failure of two "fault zone" wells to find satisfactory permeability in the oolite zone, and by the relatively thin sections of porosity found in wells drilled in townships 18 and 19 South. Geology Most of the wells listed in Table 2 afforded additional control on structure of the lower beds, but gave little new information on stratigraphy. Of the 248 wells drilled, 3 ended in Tertiary, 34 in Gulf, 1 in Paluxy, 29 in Glen Rose, 15 in Travis Peak, 15 in Cotton Valley, 139 in Smackover, 2 in Eagle Mills and 10 in Carboniferous. The age of the beds between the Travis Peak formation and Carboniferous is still questionable. Most

Jan 1, 1940

By Warren B. Weeks

Continued development in the deeper fields discovered during 1937 and 1938 was largely responsible for the 16 per cent (2,913,400-bbl.) increase in production, bringing the 1939 output to 21,376,230 bbl., the largest for South Arkansas since 1929. The older settled fields continued to decline and Rodessa was added to this classification. Magnolia field accounted for much of the increase, with Schuler field showing only a slight increase. There were 248 wells drilled during 1939, five more than during the previous year. Of 198 wells drilled in proven fields, 21 were dry; 46 of the 50 wildcats drilled were dry. The old depth record of 8332 ft. was increased to the present record of 9028. Trend of Prospecting Production from the porous " Reynolds " oolite zone of the Smackover limestone continued to be the objective of prospecting. During the year 20 seismograph, 3 gravity meter, 1 magnetometer, 1 soil analysis and 1 electromagnetic crews were reported in the state. The geophysical work was largely concentrated in three southern counties: Columbia, Lafayette and Union. As indicated in Table 2, the same three counties received most of the important drilling tests. At the end of the year only three seismograph crews remained in the areas. The area for prospecting Smackover limestone was greatly narrowed during the year by the failure of two "fault zone" wells to find satisfactory permeability in the oolite zone, and by the relatively thin sections of porosity found in wells drilled in townships 18 and 19 South. Geology Most of the wells listed in Table 2 afforded additional control on structure of the lower beds, but gave little new information on stratigraphy. Of the 248 wells drilled, 3 ended in Tertiary, 34 in Gulf, 1 in Paluxy, 29 in Glen Rose, 15 in Travis Peak, 15 in Cotton Valley, 139 in Smackover, 2 in Eagle Mills and 10 in Carboniferous. The age of the beds between the Travis Peak formation and Carboniferous is still questionable. Most

Jan 1, 1940

By J. L. Rodda

The desirability of a uniformly sized abrasive for metallographic polishing has probably been recognized in a general way for a long time. Certainly all metallographers have recognized the damage that can be done to a polished surface by a piece of grit, especially if one of the softer metals, such as zinc or aluminum, is being polished. It is to be doubted, however, whether many metallographers have had any adequate idea of the particle size of the abrasives they were using or of the range of sizes encountered in any given grade of abrasive. At any rate, the descriptions of abrasives for metallographic work found in the literature are generally very meager. It was with the idea of securing an abrasive with a limited range of particle size that a study of this problem was commenced. Commercial abrasives, even when recommended for metallographic work, are made up of particles of varying sizes. One such abrasive contains some particles so fine that they remain in suspension for days and other particles so coarse that they settle at the rate of 3 in. per minute. It is evident that the coarsest particles are over 100 times the diameter of the smallest ones, or over 1,000,000 times the volume. The hopelessness of avoiding scratches under these conditions is evident. Vanderwiltl has described a laboratory method for grading abrasives in which the elutriator is used. Le Chatelier's method, described by Goereq2 also makes use of an elutriator. However, the elutriator is too slow for this purpose and requires too delicate a control for the range of sizes desired. The method of stirring up the abrasive in water, allowing it to settle for a given time, then drawing a measured depth off the top of the suspension, has been finally adopted as the simplest procedure. The largest particle in a given portion is then determined by Stokes' law:3

Jan 1, 1932

By Alan Morris

The investigation of the hot-working properties of metals and alloys furnishes a problem which has been attacked in many ways. Tensile, impact and hardness tests on heated specimens have furnished interesting data, but in most cases either the tests are difficult to make or the results hard to translate into terms of practical value. Some investigators have used the drop hammer to advantage. It furnishes a rapid and simple method of comparing the plasticity of metals at elevated temperatures. The indications obtained by its use are of value only in so far as their significance is understood and they can be intelligently used to predict the behavior of a given metal under given hot-working conditions. The work reported here was undertaken not only to add something to the existing volume of such data but also to contribute to our understanding of the results. Doerinckel and Trockels1 used cylindrical specimens and determined the work required to reduce the specimen to one-half the original height. Ellis2 studied the effect of constitution on the malleability of steel at high temperature. His method and that of Kent3 were similar to the one used in the present work. The tests described by Kent were made on samples of tin, zinc, aluminum, copper, lead, 70:30 and 60:40 brasses, with and without a small quantity of lead. He concluded that the test would "indicate whether a material can be forged at a given temperature without cracking." This interpretation must be used with caution. While it is probably true within limits, one must consider the severity of the forging operation. Again, it will not apply strictly to forms of hot working other than forging. For instance, an alloy running 61.0 per cent. copper, 3.25 per cent. lead, remainder zinc, will crack badly in the test, yet, it is extruded commercially. When the possibility of hot-working a new alloy is being considered a study of its drop-hammer test should help

Jan 1, 1931

By Philip M. Mc Kenna

When a new material becomes available to industry, it is useful to describe its properties as a guide to its most effective application; and when the new material may be produced in compositions having a series of graded properties, tests to select the combination of properties best adapted for various uses are helpful. The class of materials to be considered in this paper are hard tool materials produced by processes of powder metallurgy from hard carbide constituents and various matrices of iron, nickel or cobalt, or alloys of them with tungsten, or tungsten and carbon. The customary use of carbide hard alloys is for metal-cutting tools; although wire-drawing dies, lathe centers, follow rests, grinding rests, burnishers, rolls, extrusion dies, measuring gauges and micrometers, and a number of other tools are also made with these hard alloys as the essential wear-resisting parts. The properties and tests to be considered are those affecting these uses. In the development of tool materials since the industrial revolution we have had carbon tool steels, Mushet steel, high-speed steels, stellites, and now cemented carbide compositions. For an understanding of the latter category of materials their properties and uses relative to the older and more familiar tool materials will be considered. Hardness has been the property of greatest practical interest in tool materials. The word "hardness" is a generalized term lacking definite-ness unless the specific test used is described. However, efforts to explain physical properties as a consequence of chemical bond, and distance between atoms in chemical compounds have been illuminating. This seems the most generalized attack on the problem, and is based upon the idea that atoms in a lattice are held together as the square of the valence and inversely as the square of the distance between the atoms. The compounds compared must all be of the same crystalline arrangement. 100 W2 It is interesting to note the values of the figure 7 A 3 /3for a number of

Jan 1, 1938

By Philip M. Mc Kenna

When a new material becomes available to industry, it is useful to describe its properties as a guide to its most effective application; and when the new material may be produced in compositions having a series of graded properties, tests to select the combination of properties best adapted for various uses are helpful. The class of materials to be considered in this paper are hard tool materials produced by processes of powder metallurgy from hard carbide constituents and various matrices of iron, nickel or cobalt, or alloys of them with tungsten, or tungsten and carbon. The customary use of carbide hard alloys is for metal-cutting tools; although wire-drawing dies, lathe centers, follow rests, grinding rests, burnishers, rolls, extrusion dies, measuring gauges and micrometers, and a number of other tools are also made with these hard alloys as the essential wear-resisting parts. The properties and tests to be considered are those affecting these uses. In the development of tool materials since the industrial revolution we have had carbon tool steels, Mushet steel, high-speed steels, stellites, and now cemented carbide compositions. For an understanding of the latter category of materials their properties and uses relative to the older and more familiar tool materials will be considered. Hardness has been the property of greatest practical interest in tool materials. The word "hardness" is a generalized term lacking definite-ness unless the specific test used is described. However, efforts to explain physical properties as a consequence of chemical bond, and distance between atoms in chemical compounds have been illuminating. This seems the most generalized attack on the problem, and is based upon the idea that atoms in a lattice are held together as the square of the valence and inversely as the square of the distance between the atoms. The compounds compared must all be of the same crystalline arrangement. 100 W2 It is interesting to note the values of the figure 7 A 3 /3for a number of

Jan 1, 1938

By A. Hellawell

Binary alloys of compositions intermediate between solid-solubility limits and eutectic compositions have been completely separated into primary phases and eutectic by freezing unidirec-tionally at very slow rates (10-6 to 10-5 cm per sec). The alloys examined were Pb-1 wt pct Ag, Al-20 wt pct Cu, and Al-42 wt pct Cu. The compositions and proportions were close to those expected from the phase diagrams and provided information about the solid/liquid interface at certain free zing rates. DURING the directional freezing of an alloy the solute distribution is controlled by the efficiency of mixing in the liquid,'" whereas diffusion in the solid state is of negligible importance. It is known3 that mixing by convection is very efficient, but complete segregation is only achieved at very slow freezing rates4-6 or with forced stirring in the liquid. ' Yue9 and Yue and clark10 have previously illus- trated partial separation of primary phases in alloys close to eutectic compositions. In the present work, taking binary alloys of compositions intermediate between the limits of solid solubility and eutectic compositions, it has been possible to achieve complete separation of the primary phases by directional freezing at very slow rates. METHODS AND RESULTS The alloys concerned were Pb-1 wt pct Ag, A1-20 wt pct Cu, and A1-42 wt pct Cu. As may be seen from the relevant diagrams,11 these alloys should segregate into approximately equal proportions of primary solid solutions and alloy of eutectic compositions. Specimens, -12 cm long and 1 cm wide, were frozen in horizontal tubes by withdrawal from a furnace. The lead alloy, prepared from materials of 99.999 pct purity, was sealed into evacuated Pyrex tubes and the aluminum alloy of similar purity contained in graphite boats under vacuum. The molten alloys were seeded with some 3 cm of solid to prevent irregular initial freezing rates and the last portions to freeze were ignored. At the slow freezing

Jan 1, 1965