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By W. P. Haynes

The 1938 production for all of Rumania amounted to 48.984.200 bbl., as compared with 53.239.500 bbl. in 1937. which represents a drop of 4.255.300 bbl., or 8 per cent. Of the various fields. there are only two major increases in production—Baicoi-Tintea with 3.092.400 bbl. And

Jan 1, 1939

K. T. Aust and J. W. Rutter (General Electric Research Laboratory)—We find it difficult to reconcile the activation energies determined by Gifkins with his general conclusion that "migration during both creep and grain growth can thus be treated on the basis of the same model" (that of Lucke and Detert). Gifkins finds the activation energy for grain boundary migration during creep to be 24.5 kcal per rnol and that for grain boundary migration during grain growth to be 7.5 kcal per mol. The calculation carried out by Gifkins of the activation energy for grain boundary migration during grain growth, using the Lucke and Detert model, gives a value of 20 to 24.5 kcal per mol, rather than his experimental value of 7.5 kcal per mol. The theory of Lucke and Detert was developed to account for the rates of migration of grain boundaries in the presence of impurities during grain growth. The theory does not take into account the effect on the boundary migration of another, simultaneous process such as creep deformation and would be expected, therefore, to be applicable only to migration during grain growth. The fact that Gifkins measured a different activation energy for boundary migration during grain growth (7.5 kcal per mol) from that during creep (24.5 kcal per mol), although the specimens were of the same composition, shows clearly that such an effect exists under his experimental conditions; the presence of a simultaneous creep deformation markedly affects the boundary migration process in comparison with what would be observed under the same conditions but without the creep deformation. The failure of McLean's equation (Eq. [4] of Gifkins' paper) to give a satisfactory dislocation density difference for boundary migration during creep is not surprising, since the activation energy which must be used in this equation refers only to the elementary atom transfer process of grain boundary migration. This activation energy value is approximately 6 kcal per mol for zone-refined lead, as determined in both the grain boundary migration experiments of Aust and Rutter31, 32 and the grain growth experiments of Bolling and Winegard.33 Using this activation energy value, McLean's equation gives reasonable agreement with observed migration rates for grain boundaries moving free of the influence of impurities.31, 32 The value of 24.5 kcal per mol is probably associated with the presence of impurity atoms, as Gifkins suggests. It should be noted, however, that this value was obtained using lead of only one composition and measurements at only two temperatures. The work of Aust and Rutter3"' on the effects of tin, silver, and gold on grain boundary migration in zone-refined lead in the temperature range from 320" to 200°C, as well as the work of Bolling and Winegard34 on the effect of silver and gold on grain growth in zone-refined lead, shows that the measured activation energy is markedly dependent upon the kind and amount of solute present. Gifkins' work does not permit evaluation of the effect of the 8 ppm of impurities other than oxygen present in his specimens. One incidental point: the symbols used to designate the experimental points of Fig. 6 appear to be in incorrect order in the figure caption. As the caption is printed, it would indicate that larger grain sizes were obtained after annealing at 47°C than at 100°C, which does not agree with the text (point M, p. 1019). Finally, it seems clear from Gifkins' results that any serious attempt to determine whether grain boundary migration and grain boundary sliding during creep occur with the same activation energy, as Gifkins suggests and McLean rejects, must take into account the effects of impurities on these two processes, Although the work of Weinberg35 indicated that adding small amounts of copper, iron and silicon to aluminum did not affect the grain boundary shear behavior, it should be noted that his starting material contained approximately 60 ppm of impurities. Gifkins' results indicate impurity effects at an impurity level of 8 ppm, suggesting strongly that the most significant impurity range to be investigated lies substantially below that value. R. C. Gifkins (author's reply) — As Drs. Aust and Rutter suggest, the results under discussion may have to be reinterpreted in the light of their own work on grain boundary migration, which was not available to me when the paper was written. Because of their work, Aust and Rutter attach more importance than I did to the activation energy for grain boundary migration during annealing (7.5 kcal per mol) obtained from a "direct" plot of log-rate against the reciprocal of absolute temperature. At the time it was obtained, this value seemed rather low, although it was similar to the value obtained by Bolling and Winegard.36 It was then, and still is, difficult to accept this value because of the low value of the index in the power law for grain growth, which seemed to indicate the influence of impurities. It was also concluded that the low value of the activation energy might have arisen from the manner of selecting rates of grain growth which were truly comparable at the two temperatures. There were many other indications in these experiments and those on recrystallization during creep3? that an impurity, probably oxygen, was of importance. The model for grain-boundary migration which Lucke and Detert had proposed was an obvious possibility and its use yielded an activation energy for boundary migration during annealing of 20 to 25 kcal per mol.

Jan 1, 1961

By R. W. Titshall

WHAT IS SAMPLING? We are all involved in sampling almost every day of our lives, by tasting, feeling, or smelling. Most raw materials, food products or manufactured items are sampled several times at various stages of the production process before a commodity of suitable quality can be produced. Data obtained from sampling is used in establishing price, quality control, allocating production costs, or overall process efficiency. The area of sampling outlined in this article is the collection of a small quantity of material from large continuous bulk flows of solids and slurries. The concern in obtaining the sample is that the material obtained is truly representative of the main flow in every respect. The methods and equipment outlined are for the collection of a manageable sample. The sample has to be analyzed in a laboratory to determine its characteristics and compliance to set standards. SELECTING A SAMPLING SYSTEM When selecting a sampling system, it is essential to define the requirements, as to what the actual sample obtained will be used for and what degree of precision is required. Determine whether or not the system has to comply with any set standards such as A.S.T.M. (American Society for Testing and Materials) which have established methods for collection of a gross sample of coal. Sampling which is done for in-plant or process control is not generally governed by set procedures, but similar care should be taken during the selection process so that when the equipment is put into service it will operate reliably and produce a sample which is truly representative of the total material lot or consignment.

Jan 1, 1982

[ ] Granville S. Borden (Mining Taxation, P. 1049) has written two other published articles on the subject, Taxation and Mineral Resources, and An Income Tax Program for Mineral Producers. Both articles appeared in Mining Engineering. He is presently employed by Standard Oil Co. of California as a special tax counsel. He holds an LL. B and an LL. M from George Washington University and a Bachelor of Science in Mining from the University of California. He has been chairman of the Taxation Committee of the Minerals Economics div. of the AIME. Borden fishes, plays golf, prospects, and performs mineral analysis as hobbies. [ ] Charles C. Towle (co-author, Uranium Deposits of the Grants District, New Mexico, P. 1037) graduated from the Colorado School of Mines with a degree in Geological Engineering. He was a member of Sigma Nu; Theta Tau, an honorary professional society; Blue Key, honorary social society; the glee club and quartet, and a member of the student council. He has been a mucker, driller, flotation operator and mill shift boss for the Clear Creek-Gilpin Co., Idaho Springs, Colo.; Geologist, chief engineer, and chief geologist for Patino Mines & Enterprises Consolidated, Inc., Bolivia; appraisal engineer and part-time geology student, Denver; office geologist for Geology Dept., special Engineering div., Sea Level Canal Studies, Panama Canal; and geologist, div. of Raw Materials, USAEC, Grand Junction, Colo. He is currently chief of the Denver Exploration Branch, div. of Raw Materials, USAEC, Denver. Towle was at one time a tournament golfer, playing three and four times a week. While working in South America he played in numerous tournaments. Today, although playing only occa sionally, he shoots in the low eighties.

Jan 1, 1952

The Institute conducts jointly with the American Society of Civil Engineers, American Society of Mechanical Engineers and American Institute of Electrical Engineers, certain activities as listed below, and is joint owner with them of certain properties. United Engineering Trustees, Inc. When Mr. Carnegie made. his gift which made possible a home for the engineering societies, a separate corporation was organized to act as a holding company and to manage the common property. This was long known as the United Engineering Society, but the name has now been changed to one which more nearly reflects the real function of the corporation. It holds title to the Engineering Societies Building and to various funds placed in its charge and is managed by a Board of Trustees, of which three are chosen by each of the four societies, American Institute of Mining and Metallurgical Engineers, American Society of Mechanical Engineers, American Institute of Electrical Engineers and American Society of Civil Engineers, which have equal and undivided interests in the property. The land and building cost two million dollars. During the year 1934, the Constitution and Bylaws of The United Engineering Trustees, Inc., were thoroughly revised and a better organization of its functions was effected: The Engineering Foundation and the Engineering Societies Library were made "departments" of the United Engineering Trustees. The Founders Societies share in the property which it holds, and estimated at the present time, as follows: Real estate,. $1,993,793; Depreciation and Renewal Fund, $401,000. The U.E.T. has endowment funds amounting to $1,086,893. The A.I.M.E. trustees are W. D. B. Matter, Jr., A. L. Queneau and Albert Roberts.

Jan 1, 1939

By Duane E. Eubanks, David B. McDonald

The anticipated growth of western coal production over the next decade is expected to add approximately 274.3 million t/y (302.4 million stpy) to US capacity. The increased output, coming from both new mines and expansion of existing facilities, promises to bring with it a new set of problems for mine planners.

Jan 8, 1976

The Institute conducts jointly with the American Society of Civil Engineers, American Society of Mechanical Engineers and American Institute of Electrical Engineers, certain activities as listed below, and is joint owner with them of certain properties. United Engineering Trustees, Inc. When Mr. Carnegie made his gift which made possible a home for the engineering societies, a separate corporation was organized to act as a holding company and to manage the common property. This was long known as the United Engineering Society, but the name has now been changed to one which more nearly reflects the real function of the corporation. It holds title to . the Engineering Societies Building and to various funds placed in its charge and is managed by a Board of Trustees, of which three are chosen by each of the four societies, American Institute of Mining and Metallurgical Engineers, American Society of Mechanical Engineers, American Institute of Electrical Engineers and American Society of Civil Engineers, which have equal and undivided interests in the property. The land and building cost two million dollars. During the year 1934, the Constitution and Bylaws of The United Engineering Trustees, Inc., were thoroughly revised and a better organization of its functions was affected: The Engineering Foundation and the Engineering Societies Library were made "departments" of the United Engineering Trustees. The Founders Societies share in the property which it holds, and estimated at the present time, as follows: Real estate, $1,987,793; Depreciation and Renewal Fund, $336,992. The U.E.T. has endowment funds-' amounting to $1,107,677. The A.I.M.E. trustees are W. D. B. Motter, Jr., A. L. .Queneau and Albert Roberts.

Jan 1, 1937

By C. E. Shoenfelt

There was very little oil activity in Utah in 1938. A few wildcat tests were drilled and the well at Cane Creek, started in 1937, was in active operation, but failed to reach its objective by the close of the year. The Clay Basin field in Daggett County, northeastern Utah, was extended about a mile east by the Mountain Fuel Supply Co. with the completion early in June of No. 3-D Murphy, NW. NW. SW. of sec. 23-3N-24 E. This well had an initial production of 16,000,000 Cu. ft. of gas a day under 2160 Ib. pressure, from Dakota sand at 5918 to 5925 ft. after plugging back from a total depth of 6035 feet. The Clay Basin field, in the few years it has been in operation, has developed into a gas field of major importance. Approximately 1300 acres has now been proved by development. Six wells are on production, five of which were completed in Dakota sand and the sixth in a sand in the Frontier formation. The field was connected to the Salt Lake line

Jan 1, 1939

By C. E. Shoenfelt

There was very little oil activity in Utah in 1938. A few wildcat tests were drilled and the well at Cane Creek, started in 1937, was in active operation, but failed to reach its objective by the close of the year. The Clay Basin field in Daggett County, northeastern Utah, was extended about a mile east by the Mountain Fuel Supply Co. with the completion early in June of No. 3-D Murphy, NW. NW. SW. of sec. 23-3N-24 E. This well had an initial production of 16,000,000 Cu. ft. of gas a day under 2160 Ib. pressure, from Dakota sand at 5918 to 5925 ft. after plugging back from a total depth of 6035 feet. The Clay Basin field, in the few years it has been in operation, has developed into a gas field of major importance. Approximately 1300 acres has now been proved by development. Six wells are on production, five of which were completed in Dakota sand and the sixth in a sand in the Frontier formation. The field was connected to the Salt Lake line

Jan 1, 1939

By R. G. Stickney

INTRODUCTION The Basalt Waste Isolation Project, conducted by Rockwell Hanford Operations under contract to the U.S. Department of Energy, is assessing the feasibility of the disposal of commercial radioactive spent fuel/high-level waste in deep geologic formations in basalts beneath and within the Hanford Site in southeastern Washington State. The Basalt Waste Isolation Project mission is to identify and characterize a potential geologic repository site in basalt and to develop associated facilities and technology required for the potential permanent isolation of radioactive wastes in basalt formations. In support of the Basalt Waste Isolation Project, a laboratory testing program was conducted to evaluate the performance of the Council for Scientific and Industrial Research's "Doorstopper" biaxial strain cell. To support site characterization studies and the design of repository openings, in situ stress measurements will be conducted within the reference repository horizon (~970 m). The Doorstopper is one of the instruments being considered for use in these measurements. It was selected because it requires only a small volume of work to achieve stress relief, which is important in a closely jointed basalt. Also, test durations are short, permitting a large number of measurements to be made within a given time to increase confidence in the results. Within the reference repository horizon, temperatures are expected in the range of 40º to 60°C with a humidity of up to 100%. For this testing program, test conditions were selected to closely resemble those expected within the repository horizon. The Doorstopper test, mainly developed by Leeman (1964), is a strain rosette relief method of measuring rock stress in situ. The Doorstopper consists of a four element, 45º strain gage rosette

Jan 1, 1984

Organisation Place Date 1918 American Society of Mechanical Engineers New York, N. Y. Dec. 3-6 Society for Promotion of Engineering Education, with British Educational Mission Cambridge, Mass. Dec. 6-7 Geological Society of America Boston, Mass. Dec. 28-31 American Association for the Advancement of Science Boston, Mass. Dec. 27- Jan. 2.

Jan 12, 1918

By Albert Hahn

ABOUT three years ago John Hays Hammond took over the control of the Eureka Metallurgical Co., at Salt Lake City, Utah. Funds were advanced for investigating the process invented by R. V. Smith, for concentrating oxidized lead ores. A great deal of laboratory work was done and a reagent was developed by C. M. Nokes of Salt Lake, which was found to be particularly suitable for oxidized copper ores, refractory manganese silver ores, and oxidized gold ores. After sufficient laboratory work had been performed to demonstrate the fundamental principles of these inventions, a test mill, having a capacity, of 20 tons of ore daily, was erected at Murray, Utah. In this test mill approximately 1200 tons of various types of ores have been concentrated by means of the above-mentioned process and reagents, and this large-scale work as well as laboratory work is being continued at present. Details of these mill tests are given in Table 1, and a representative group of laboratory tests are shown in Table 2. The process requires no special machinery or appara-tus. Its success depends entirely, on the method of preparing the pulp and its subsequent flotation in clean water, as outlined in the Smith patent. The reasons for the success of the Nokes special reagent are not definitely known. The outstanding feature, which seems to be of extreme importance, is that when the concentrates are examined under the microscope, each particle of mineral appears to have a particle of paraffin, attached to it. This paraffin-mineral combination seems to be particularly suitable for flotation and it follows that any coating oils readily attach themselves to the paraffin-mineral combination.

Jan 9, 1923

The Institute conducts jointly with the American Society of Civil Engineers, American Society of Mechanical Engineers and American Institute of Electrical Engineers, certain activities as listed below, and is joint owner with them of certain properties. United Engineering Trustees, Inc. When Mr. Carnegie made his gift which made possible a home for the engineering societies, a separate corporation was organized to act as a holding company and to manage the common property. This was long known as the United Engineering Society, but the name has now been changed to one which more nearly reflects the real function of the corporation. It holds title to the Engineering Societies Building and to various funds placed in its charge and is managed by a Board of Trustees, of which three are chosen by each of the four societies, American Institute of Mining and Metallurgical Engineers, American Society of Mechanical Engineers, American Institute of Electrical Engineers and American Society of Civil Engineers, which have equal and undivided interests in the property. The land and building cost two million dollars. During the year 1934, the Constitution and Bylaws of The United Engineering Trustees, Inc., were thoroughly revised and a better organization of its functions was effected: The Engineering Foundation and the Engineering Societies Library were made "departments" of the United Engineering Trustees. The Founders Societies share in the property which it holds, and estimated at the present time, as follows: Real estate, $1,993,793; Depreciation and Renewal Fund, $415,225. The U.E.T. has endowment funds amounting to $1,203,740. The A.I.M.E. trustees are W. D. B. Motter, Jr., A. L. Queneau and Albert Roberts.

Jan 1, 1940

By Joseph Chalmers

The Petroleum Experiment Station of the U. S. Bureau of Mines at Bartlesville, Okla., has for the past three and a half years maintained a laboratory with the necessary personnel for conducting research on methods of increasing the recovery of oil. Some of the preliminary problems encountered in starting this work, with the data obtained, were discussed in A. I. M. E. Technical Publication No. 144, "Oil Recovery Investigations of the Petroleum Experiment Station of the U. S. Bureau of Mines," which was presented at the October meeting of the Institute at Tulsa, Okla., in 1928. Scope of Paper The following discussion gives some of the results of the more recent work at the Oil Recovery Laboratory. These experiments were conducted to obtain laboratory data pertaining to the relative merits or efficiencies of various pressure media in the recovery of oil from a sand reservoir. Two general types of experiments were conducted. In one the various pressure media were passed through an artificial body of sand partly saturated with oil at a constant input pressure; in the other the pressure media were passed through the body of sand partly saturated with oil at a constant volume rate. No attempt will be made to discuss the ramifications of economic problems which enter into the choice of a pressure medium. Apparatus and Materials The two 6-in. by 6-ft. flow tubes described in Technical Publication 144 were used in these experiments. They consist of 6-ft. sections of 6-in. casing with a blind flange at each end. There are three 1-in. well openings in each tube, spaced 2 ft. 4 in. apart, the end wells being

Jan 1, 1930

By T. Chen

One of the limitations of the 3-dimensional Lerchs-Grossmann pit optimisation algorithm has been the difficulty in calculating an optimum pit with variable wall slopes. The difficulties have been related to establishing various wall slopes without changing the sizes of the blocks used in the normal computation, but still retaining an optimum solution.

Jan 1, 1977

By Vincent P. Gianella

THE most intense earthquake on the Pacific coast in the last several years, and probably the second most intense shock to occur in Nevada since it was settled, was felt in many Western States shortly after 10 p.m. on Dec. 20, 1932. Be- cause the rifted area contered about the northern end of Cedar Mountain it is referred to as the Cedar Mountain, Nevada, earthquake. An idea of the intensity of the shock may be gathered from the distance at which it was felt: in Wyoming, Utah, Idaho, Nevada, Washing- ton, Oregon, California and Arizona. It is the strongest quake centering in Nevada since the Pleasant Valley earthquake on Oct. 2, 1915. Despite the strength of the vibrations and the large area over which they were felt, relatively little damage was done. The extent of the damage consisted of a few old stone buildings demolished as shown in Fig. 1, much cracked and fallen plaster, many chimneys shaken down and considerable cracking of brick walls. There were no deaths and four people were but slightly injured. The small amount of damage was due, largely, to the scarcity of structures within the area of strong vibrations, but an important factor was the aridity of the region (see Fig. 2) and the shallowness of soil cover so that there was but little water-saturated loose material in which strong secondary vibrations could be formed. Had this earthquake occurred in a region of heavy precipitation and dense population the damage to property and loss of life would undoubtedly have been large, with consequently much more newspaper publicity.

Jan 1, 1933

By Adolf Gurlt

It has long been known that minute quantities of foreign substances, when alloyed with steel, are capable of materially altering its physical properties. Thus, half a century ago, Faraday and Stodart, in England, discovered in the famous Indian steel, known as " wootz," small quantities of aluminum, from 0.0728 to 0.693 per cent., and attributed its extraordinarily good quality to the presence of such minute quantities of that metal. Since aluminum is now produced by electrolytic means on a large scale and at low cost, its addition to cast-steel has been frequently recommended of late. Chromium was alloyed with steel fifty years ago by the celebrated French metallurgist, Berthier, of Paris, and has recently been successfully applied to the same purpose by Holtzer, of Terre-Noire. In 1860 titanium was alloyed with crucible steel by Robert Mushet, of Coleford, the alloy containing up to 0.50 per cent. of titanium, which was extracted from Norwegian ilmenite. The titanium-steel was much vaunted by him for its excellent qualities. Rhodium, a very rare metal of the platinum series, was maintained by Berthier to improve steel materially in strength and hardness. Manganese has always been held by Sheffield steel-melters to provide steel with excellent qualities, and this influence was quite recently investigated by H. M. Howe and L. Campredon. Nickel was tried as an addition by Berthier, not to speak of gold, silver and platinum ; and nickel-steel has recently been brought into prominence by J. Riley and others, who recommend it for its great strength and toughness, particularly as material for armor-plates.

Jan 1, 1894

M. G. CORSON.'-I am not going to discuss any of the papers presented but merely the question of season cracking of brass in general. Alpha brass has been known for nearly 500 yr. and from the very beginning a number of articles were made from sheets of this alloy by the process of spinning. Metal turning lathes were not yet known but wood turning lathes already existed and the wood turners used to make the mandrils and do the brass spinning themselves. Cases of season cracking were known even then. In 1915 I was connected with a small company doing a certain amount of brass spinning. Before the war its products never gave cause for complaint but their war-time products were cracking too frequently. The reason was, that due to the exigencies of war an excessive speed-up was attempted and the material simply could not take it. Today corrosion cracking of brass is most important in the case of cartridges for small arms ammunition and shell cases for large guns. The cracking takes place in storage and too frequently it is explained by the hypothetical presence of vapors of ammonia. However, I had the experience of purchasing some 20,000 rounds for the old Vetterli rifle from the Swiss government in 1905. The rifle and the cartridges were obsolete for many years and those which I bought were stored for at least 10 yr. None of them was found to be cracked or to crack in use. And the reason again was in the amount of work used in manufacturing the cartridges between anneals. The machinery today is more powerful and the amount of

Jan 1, 1945

THOMAS T. READ, Palmerton, Pa. (communication to the Secretary*). -It is much to he regretted that in presenting a further discussion of these deposits, first described by myself' and later discussed by C. M. Weld,2 Mr. Wang bas not made a more complete presentation of the evidence on which he bases his conclusions as to their origin. Mr. Weld said in his paper that his visit was confined to a few hours, that he saw only one of the several exposures, and that he took away no samples for further study. My own visit was brief, and for another purpose than the study of the geological features of 'the deposits, so the fact that Mr. Weld described as a hornblende-granite the rock which I described as a "dark gray syenitic rock," and which Mr. Wang identifies as a hornblende-syenite, seems of no great importance, since this rock is generally decomposed along the contact, presumably the only place in which Mr. Weld observed it. Later in the same paper (p. 31), Mr. Weld says that his opinion is that the magnetite of the deposits is primary, but Mr. Wang makes no mention of this in stating his own conclusion to the same effect. When Mr. Weld's paper appeared, I did not discuss it, because, although I considered the evidence- that he brought forward to support his belief that the magnetite is primary too slender to support the hypothesis, my own evidence to the contrary was equally tenuous. .The opportunities for observation and study open to Mr. Wang must have provided him with

Jan 6, 1917

By G. H. Kesler, J. E. Oberele, C. E. Dryden, J. H. Oxley

Heat-transfer rates were measured in a model of a multifilament vapor-deposition bulb fo the preparation of high-purzty metals. Local transfer coefficients for heat transfer frow the filaments to the circuates process stream were determined as a functiol of gas flow rates and bulb, inlet, and filament, geowzetvies. These results a-e then convertted to n mass-t7,ansfer basis to provide a method of correlating vapor-deposition rates and to predict the performance of commercial urzits. The firm1 cor?,elating equation for mass transfer was found to be- wheve k, is the mass-transfer coefficient; D, is bze gas difficsivity : P is the system pressure; R is the gas constant; T is the gas temperature; Df, DB, and Di ave tlze diameters of the filament, bulb, and inlet, respectively; k is the gas conductivity; C, is the specific heat of the gas, M is the wzolecular zleight of the gas; Npr . N,,, NRe a7'e the Prandtl, Schmidt, and Reynolds numbem of the system, respectively; LB is the height of the bulb; and SB and Sf are the total suyiace area of the bulb and filaments, respectively. ONE of the more conventional methods of preparing very high-purity metals is the vapor deposition of the metal upon heated filaments. The reactions which can be employed in such a process generally fall into two classes: 1) Pyrolysis of a volatile metal compound. Generally because of their instabilities, metal iodides are used; however, other metal halides and hydrides have been employed. These processes are frequently carried out under vacuum conditions, and the filaments are maintained at high temperatures. 2) Hydrogen reduction of a volatile metal compound. A metal chloride is normally the preferred feed for these processes, but other halides are sometimes used under special conditions. These hydro- gen-reduction processes are usually operated at atmospheric pressure. Many of the current processes for the production of semiconductor materials are actually vapor-deposition processes. However, the vapor-deposition process itself is relatively old, and almost all metals can be prepared in a state of very high purity by the use of vapor-deposition techniques. Loonam has recently given an excellent review of the iodide process for metal deposition,' and Owen has started some detailed studies with a carbonyl system.' A more general treatment of all vapor-deposition processes has been outlined by Powell, Campbell, and Gonser.3 Despite the fact that vapor-deposition techniques have been employed since 1890, there is a surprising lack of fundamental information regarding the transport characteristics of even the simplest deposition system, the heated filament. The purpose of the investigation described in this paper was to extend some of the earlier data obtained at Battelle to predict deposition rates and the uniformity of deposition in large-diameter, multifilament deposition bulbs under forced convection conditions.4'5 A number of other investigators have already presented a simplified treatment of the deposition process under non-flow conditions, i.e., pure diffusion.6"9 To obtain information on the transport characteristics of a deposition bulb, a model of a typical plant deposition unit was constructed, and local heat-transfer coefficients from the filaments to a circulating air stream were determined under various conditions of air-flow rates and bulb, inlet, and filament geometries. These results were then converted to a mass-transfer basis, and consequently provided a method to correlate experimental vapor-deposition rates and to design commercial deposition units. EXPERIMENTAL WORK Description of Model. The apparatus which was used in this work was a scaled model of one type of deposition bulb. It was constructed of Lucite and was easily altered to give several combinations of diameter of bulb liner, inlet size and location, number of filaments, and outlet geometry. The model is shown in Figs. 1 and 2. The bulb shell was made octagonal for convenience in construction and observation, and the bulb liners were cylindrical. Air, introduced through one of several different jet inlets, was used as the test fluid in these model studies. Filaments for deposition of metal were simulated by metal rods 1/4-in. in diam. Two of the rods could be heated by passing electrical current through them ¦ while the remaining rods could not be heated. This procedure minimized the amount of heat which was

Jan 1, 1962