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By Kimio Itagaki

The distribution ratios of Ag, Pb, As, Sb and Bi for the Cu2S-FeS or Ni3S2-FeS matte / FeOx SiO2, FeOx-SiO2-CaO or FeOx-CaO slag equilibration in a MgO crucible were determined experimentally at 1523~1573K under controlled partial pressures of S2 and O2 at given PSO2 of 10.1, 50.7 and 101.3 kPa (0.1, 0.5 and 1 atm) and be observed dependency of distribution ratio on the matte grade, SO2 pressure and slag basicity were analyzed on the basis of thermodynamics,

Jan 1, 2003

By Tao Xuea

Gold frequently occurs in nature in the form of a gold-silver alloy. Thus, investigation of the electrochemical behavior of gold-silver alloys in cyanide solution has practical significance. In this paper, the potentiodynamic method is used to determine the anodic polarization curves of gold-silver alloys (Au-10% Ag and Au-50% Ag) in cyanide solutions. To facilitate the interpretation of the results, complementary experiments conducted in NaOH solution in the absence of cyanide are also reported. The results for the Au-Ag alloys are compared with the polarization behavior of pure gold and pure silver. With the aid of potential-pH diagrams for the Au- and Ag-CN-H20 systems and electrochemical kinetics concepts, the dissolution mechanism of gold-silver alloys, the effect of the presence of silver on the cyanidation of gold, as well as the factors which control the anodic reaction rate are clarified.

Jan 1, 1998

By E. Allain

Extraction of basic metals from sulfides by conventional pyrometallurgical processing leads to the emission of SO2. To avoid this inconvenient, low temperature selective chlorination of sulfide concentrates could be an alternative. However, such process generates hazardous chlorides SxCly. A part of sulfur chlorides such as SCI2 can be recycled as a chlorinating agent of metal sulfides. Hydrolysis of sulfur chlorides, using a solution containing Na2S.9H2O, led to the recovery of more than 90 pct of elemental sulfur. Reduction of SxCly by hydrogen was investigated between 300 °C and 800 °C. About 70 and 90 pct of elemental sulfur were recovered from SC12 and S2C12, respectively. A flow sheet for the chlorination of metal sulfides and the treatment of sulfur chlorides was suggested.

Jan 1, 1998

By Naiyang Ma

High zinc concentration in basic oxygen furnace (BOF) steelmaking offgas (OG) cleaning system solid wastes is one of the main barriers for recycling of the solid wastes in sintering – blast furnace ironmaking process. One of the possible solutions is to utilize zinc-free scrap in BOF steelmaking so that the BOF OG solid wastes will not be contaminated with zinc and can be recycled through sintering – blast furnace ironmaking. This paper describes a model for helping to decide whether to use zinc-free scrap in a BOF process. A model computing marginal price increment of zinc-free scrap is developed. The marginal price increment is proportional to value change of the BOF OG solid wastes after and before using zinc-free scrap, to ratio of BOF solid waste rate to purchased galvanized scrap rate, and to price of galvanized scrap. Due to the variations of consumption rate of purchased galvanized scrap and home galvanized scrap, iron ore price, landfill cost, and price of purchased galvanized scrap, using zinc-free scrap in a BOF process might be economically feasible for some ironmaking and steelmaking plants or in some particular market circumstances.

Jan 1, 2015

By Achilles J. B. Dutra, Carlos M. Juarez

"The use of thiourea as a gold leaching reagent has been extensively studied by many researchers, and it has proved to be promising for some cases as refractory ores. Otherwise, the recovery of gold from these solutions did not receive so much attention. In this paper the electrowinning of gold in acidic thiourea solutions was studied by voltarnmetry and chronopotentiometry. An adsorption step was detected prior to Au(I) reduction and the diffusion coefficients at 25°C for Au-TU complex and FD were found to be 1.00 x 10.5 cm2 S-I and 1.98 x 10-5 cm2 S-I respectively. At -0.350 V (SCE) a passivation probably due to TU adsorption was observed. For higher overpotentials hydrogen evolution was the main reaction.IntroductionThe use of acidic thiourea solutions for the extraction of gold and silver has shown to be a promising alternative to the traditional process of cyanidation, specially for certain refractory ores (1-3) and electronic scrap (4). In some cases, the industrial scale was reached (1,5). The thiourea leaching of precious metals presents advantages over cyanidation, as faster kinetics, lower toxicity and lower sensibility to base metals; however the costs due to high thiourea consumption impairs its use.The majority of the publications on thiourea processing of gold is on leaching. Many are review papers (5-7). Recently, the adsorption and desorption of the gold-thiourea complex on activated carbon and ion exchange resins have been studied (8-11).Little research has been done on the electrowinning of gold from acidic thiourea solutions, most of it has been carried on the seventies and beginning of the eighties in the former USSR (12-17) and concerned the eletrolytic extraction of gold in tridimensional cathode cells.The present paper concerns the cathodic behavior of the gold-thiourea complex in the presence of formamidine disulfide in order to provide information on the electrowinning of gold from solutions obtained directly from leaching or from an elution process."

Jan 1, 1997

By Shengli Wu, Fengjie Zhang, Feng Chang, Hua Lu, Kaiping Du

In order to make a complete understanding of steel plant metallurgical dusts and to realize the goal of zero-waste, a study of their properties was undertaken. For these purposes, samples of two sintering dusts (SD), two blast furnace dusts (BFD), and one electric arc furnace dust (EAFD) taken from the regular production process were subjected to a series of tests. The tests were carried out by using granulometry analysis, chemical analysis, X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy via SEM (EDS), and Fourier transform infrared spectroscopy (FTIR). The dominant elements having an advantage of reuse are Fe, K, Cl, Zn, C. The dominant mineralogical phases identified in sintering dust are KCl, Fe2O3, CaCO3, CaMg(CO3)2, NaCl, SiO2. Mineralogical phases exist in blast furnace dust are Fe2O3, Fe3O4, with small amount of KCl and kaolinite coexist. While in electric arc furnace dust, Fe3O4, ZnFe2O4, CaCO3, CaO, Ca(OH)2 are detected.

Jan 1, 2015

By Basak Anameric

Pig iron nugget process was developed by Kobe Steel as an environmentally friendlier, economical alternative to traditional blast furnace process. The process aimed to produce highly metallized, slag free pig iron nuggets throughout a single stage heat treatment, utilizing coal as a reducing ? carburizing agent. The objective of this work was to determine whether the pig iron nuggets produced at the laboratory conditions had comparable physical and chemical properties with the blast furnace pig iron. The physical and chemical properties of the pig iron nuggets were determined utilizing x-ray fluorescence spectroscopy, x-ray diffraction, optical microscopy, scanning electron microscopy, energy dispersive spectroscopy and apparent density measurements. The pig iron nuggets had similar chemical composition and apparent density values (6.7 ? 7 g/cm3) with blast furnace pig iron and they had microstructures similar to low carbon white cast iron. These properties make them a competitive alternative to blast furnace pig iron.

Jan 1, 2006

By Saynbaatar, Gangping Ma, Jianhua Fu, Qiqige, Jinghua Wang

The influence on the performance of foam concrete made by replacing cement with some industrial waste residues was researched in this paper. The result shows that the 7d and 28d compressive strength of foam concrete increases firstly and then decreases with the increasing amount of industrial waste residue. The proper added range is 10%-20% for steel slag, blast furnace slag and coal ash, but, 8% for desulfurized fly ash. With the proper adding ratio, the compressive strength of foam concrete always increased comparing with the pure cement foam concrete. When adding 48% of the compound industrial waste residues, the 28d compressive strength of the foam concrete reached the 2.9MPa which could match the pure cement foam concrete. The results indicates that there is a synergistic effect among the compound industrial waste residue, and this effect is benefit to improving the compressive strength of foam concrete.

Jan 1, 2015

By T. Kimura, H. Ohba

"Much effort has been made to reduce the energy requirement in zinc electrowinning. In order to keep energy consumption low, either to make cell voltage low or current .efficiency high is necessary. Decrease of cell voltage practically depends on how to reduce ohmic resistance in the electrolyte and the anode crust. To realize these, new concept was proposed and the pilot plant has been operated. The space between a cathode and an anode is halved by utilizing the frame insulator. With these frames the anodes and cathodes compose of a unit of electrodes, and this unit is handled by newly designed electrode handling machine (E.H.M.). The process includes lifting up electrodes, expanding the space between a cathode and an anode, cleaning them, stripping the deposited zinc and returning the unit to the cell. As a result, cell voltage is kept as low as calculated and predictable energy reduction has been achieved. IntroductionIn the recent trend of a rapid appreciation of the Japanese yen, Akita Zinc Refinery of Mitsubishi Metal Corporation has been confronted by problems of relatively high operating costs. In order to compete with other overseas zinc refineries, it is necessary to reduce the cost of zinc production, especially the cost of electric power which now accounts for .up to 35 % of the entire cost of production. Three fourth of the electric power used at Akita Zinc Refinery is for the electrolysis. Therefore it is extremely important to reduce the cost of electrolysis.There are two possible measures for solving the problem; one is to use more nighttime electricity taking the advantage of its inexpensive power price, and the other is to reduce electric power consumption.As a part of a rationalization plan carried out in 1986, Akita Zinc Refinery increased the number of operating cells. As a result, when nighttime electricity is used, the silicone rectifier has been able to operate at full capacity. Moreover, by new schemes of ""increase of area for electrodeposition by ralslng the liquid level of electrolyte"" and ""increase of the number of electrodes in each cell"", current density could be lowered and as a result, the electric power consumption has been improved. In order to raise nighttime ratio even higher, installation of an additional rectifier and cells would be required."

Jan 1, 1988

By Ikuhiro Sumi

A new steelmaking process, in which manganese ore was intentionally reduced, was developed to achieve a higher manganese Yield using a combined blowing converter. In this study, manganese behavior was discussed through the introduction of a model. Apparent reduction rates of manganese were calculated by the two terms that were determined experimentally, with SOkg and 2S0ton combined blowing converters. The model calculated manganese changes during the operation. We applied the model to the actual operation and found that manganese behavior was predicted fairly well by this model.

Jan 1, 1996

By Fumito Tanaka

The Mitsubishi process is the sole pyrometallurgical process for the continuous production of blister copper from Copper concentrates and has been successfully operated around the world. The development of calcium ferrite slag (CaO-FeOx-Cu10), the so-called "C-slag", has enabled continuous converting from matte to blister copper in the commercial scale operations. Commercial interests in the slag led to many papers over the CaO-FeOx slag. However, Cu2O bearing slag has not been studied well due to experimental difficulties. The authors have quantified the thermodynamic properties of the CaO-FeOX-Cu2O system. The results have been utilized to analyze various issues related to the converting furnace, such as the magnetite precipitation from the slag or from blister copper and to develop better controlling criteria for the continuous converting operation. -

Jan 1, 2003

By Hubert Bril, Priscilla Pareuil, François Bordas, Emmanuel Joussein, Jean-Claude Bollinger

"According to the legislation, valorization type, origin and characteristics of waste material, various standard procedures are available to evaluate environmental impacts. A Mn-rich slag was sampled from a metallurgical plant. After its characterization (elementary analysis and mineralogy), five standard procedures were carried out (i.e. TCLP, EN 12457-1). Each fixed parameter of the standards was systematically studied in a large range: pH, Liquid/Solid ratio, contact time. For example, EN 12457-1 led to a low ME mobilization, increasing with the L/S ratio, the contact time and an acidic pH. As a conclusion, the representativeness of the considered parameters and their potential variations are predominant to assess of the real environmental impact during slag reuse. Introduction Recent studies have been carried out about environmental impacts of waste containing metallic elements (ME) because of their potential mobility [1-7]. Indeed, slags are either dumped or valorized in various activities such as building materials. In order to assess environmental risk, various standard procedures are used depending on country legislation, origin of waste and valorization way. Results of leaching tests are linked either to special legislation (e.g. Dumping: EC, Council Decision 2003/33/EC, Construction products: EC, Council Directive 89/106/EEC) or to legal levels used in drinking water (Directive 98/83/CE) when leachates could migrate to groundwater. If ME in leachates are lower than drinking water authorized levels, the waste will be considered as non-hazardous. On the contrary, if the leachable amounts exceed them, the question about the risk has to be posed. Beyond the abundance of leaching tests available, variety of operational conditions induced by these regulatory tests does not make the choice easier. According to operational conditions induced, ME release could vary from one test to another one. ME concentrations in leachates depend on pH, Liquid/Solid ratio, contact time and particle size [3]. To highlight the importance of these operational parameters, potential risk for valorization of a manganese-rich slag was assessed by comparing several standard leaching protocols [8-12] with a global study dealing with the influence of operational conditions. For each regulatory protocol, the most influential parameters (L/S ratio, pH, particle size and contact time) have been studied in a large range."

Jan 1, 2008

By G. J. Abbaschian, A. B. Gokhale, M. M. Kunjapur

"A laboratory scale model furnace was constructed for obtaining radially inward oriented columnar grains in disc shaped castings. The furnace consisted of eleven circular, concentric, equispaced resistance heaters on each half of a split graphite mold. Water or air flowing through a copper pipe along the periphery of the disc constituted the heat sink. After filling the mold, the heaters were turned off consecutively in top and bottom pairs from the rim towards the center, causing the temperature gradients to move inward. Equiaxed structure was obtained at the center by turning off the inner coils together when desired. Sn:15%Pb alloy was used to cast integral blade disc castings using the above technique to obtain dual-property discs with a central equiaxed structure and an outer columnar grain structure projecting inwards from the blades to the rim. A numerical technique was used to predict the temperature profile in the disc during solidification, and good correlation was obtained with the experimentally measured temperature profiles. The corresponding heat transfer coefficient values obtained were h = 544 Wm- 2k-1 (0.013 cal/cm2- ° C-sec) for cooling between metal and chill and h' = 71 Wm- 2k-1 (0.0017 cal/cm2- ° C-sec) for the heat input from the hot mold to the liquid metal. BackgroundHigh temperature alloys used in the current generation of gas turbine engines have evolved through two main stages of development: in 1950's, the increase in the efficiency of gas turbines was paced by improvements in alloy design, which led to the development of Ni and Co-based superalloys (1). By mid-1960's, it was realized that improved alloy chemistry alone was inadequate in meeting the increasingly stringent service requirements. The focus of research then shifted from alloy development to process development, and resulted in the introduction of directional solidification (DS) techniques for the production of turbine blades and vanes (1,2).Under typical operating conditions, the blades and vanes are subjected to aerodynamic loading, while the blades are additionally subjected to high centrifugal loading and vibratory stresses. The primary material requirements for blades may be summarized as follows (1,3):•,High creep resistance•,Good high temperature tensile strength (typically in the range of•,275 to 550 MPa at temperatures in excess of 750°C)•,Resistance to both low cycle and high cycle fatigue (LCF and HCF)•,Resistance to erosion, corrosion, and oxidation•,Resistance to thermal fatigue"

Jan 1, 1986

By E. Ozberk

The copper and nickel smelting industries are important contributors to the technical and economic well-being of Canada while some of the smelters are among the largest sources of sulphur dioxide emissions in Canada. A review of the operations in six smelters - Falconbridge Limited, Falconbridge, Ontario; Hudson Bay Mining and Smelting Co. Limited, Flin Flon, Manitoba; Inco Limited, Copper Cliff, Ontario and Thompson, Manitoba; Noranda Mines Limited, Horne Division, Noranda, Quebec and Gaspe Mines Division, Murdochville, Quebec - have shown that about 80% of the total sulphur input to these smelters was emitted to the atmosphere in 1980. A simultaneous review of the existing and emerging technologies which can directly or indirectly reduce the sulphur dioxide emissions indicated that it is possible to reduce the emissions to below 20% of the sulphur input to these smelters. This can be achieved by varying degrees of modifications to the smelting operations and installing sulphur fixation facilities at significant costs which may increase the metal production costs. This would consequently make the competitiveness of the Canadian copper and nickel producers more difficult in the already tough world metals market.

Jan 1, 1983

By S. Suda

Hydrogen storage materials have been investigated for more than 30 years, particularly on metal hydrides. These materials are, however, considered today impractical because of their poor hydrogen capacity measured by mass density and their poor surface properties and characteristics against impurities. Recent R&D activities have been located in new categories of materials such as complex hydrides and chemical hydrides. Among these materials, NaAlH4 (one of alanates), Li-based complex hydride, and NaBH4 (SBH: sodium borohydride) are 3 major candidates as hydrogen storage materials. In the presentation, SBH as a non-reversible on-site but recyclable off-site is described in view of its practical availability as the source of H- (protide) applied for a new type of fuel cell named Direct Borohydride Fuel Cell (DBFC) and H2 (hydrogen) for Proton Exchange Membrane Fuel Cell (PEMFC).

Jan 1, 2006

By Bowen Li

Copper vermiculite is a special nanomaterial with excellent antibacterial and antifungal performance. By means of ion exchange, copper vermiculite containing up to 5.8wt% copper was prepared. The chemical and mineralogical characterization of the material was investigated in this study based on the XRD, AAS, TEM and EDS analysis, as well as the calculation of crystalline parameters and crystal chemical formula. Cu2+ and Mg2+ have similar atom radius and same electrovalence. Correspondingly, the structure character of copper vermiculite is very close to that of standard Mg-vermiculite. Most of the CU21 may have occupied the interlayer cationic positions in the form of hydrate in vermiculite. However, some may have entered into octahedral coordinate positions. The values of au and bo of the copper vermiculite crystal cell have no obvious change compared to that of original vermiculite micropowder, but the Co value decreased slightly, which is desirable for the stabilization of the Cu2+ in copper vermiculite.

Jan 1, 2003

By A. V. Tarasov

One or more of the main alloying metals, i.e. copper, silicon, nickel, magnesium, zinc and other metals can form a composition with aluminum, by dissolving in the latter. The thermodynamic computations have indicated that within a range of temperatures from 700°C to 1300°C the reactions of molten aluminum with zinc and nickel oxides are shifted toward formation of free metals because it is possible to use the main alloying metals, i.e. zinc and nickel, in the form of inexpensive intermediate products and waste. The laboratory studies conducted have confirmed a possibility for production of aluminum alloys using intermediate products in the form of oxides of alloying metals.

Jan 1, 2006

By J. D. Law

The presence of long-lived radionuclides presents a challenge to the management of radioactive wastes. Separation of the radionuclides from the waste solutions has the potential of significantly decreasing the costs associated with the immobilization and disposal of the waste by minimizing waste volumes. Several solvent extraction processes have been developed at the Idaho National Engineering and Environmental Laboratory for the separation of transuranic elements (TRUs), 90 Sr, and/or 137 Cs from acidic radioactive waste solutions. The TRUEX and POR processes for the separation of TRUs, the SREX process for the separation of 90Sr, the cobalt dicarbollide process for the separation of 137Cs and and a universal solvent extraction process for the simultaneous separation of TRUs, 90Sr, and 137Cs have all been developed in centrifugal contactors using actual liquid radioactive waste solutions and simulated dissolved calcine waste solution. In addition, the behavior of metals with each of the solvent extraction processes was evaluated. This article summarizes the most recent results of the each of the flowsheet demonstrations and provides Information on the centrifugal contactor equipment used for the testing.

Jan 1, 1999

By Henrlk Gripenberg

To solve the environmental and financial problems of the traditional Rotary Salt Furnace process, a new salt-free method for aluminum dross and scrap melting, ALUREC, has been developed by AGA and its partners, Hoogovens Aluminium and MAN GHH. AGA and Hoogovens Aluminium developed the main process concept and jointly carried out trials on pilot plant scale. Owing to excellent results" the partners decided to jointly erect a commercial scale test plant. The order for the design and erection of the furnace went to MAN GHH. The three companies designed the test plant and began operation in the spring of 1994. The results have been excellent and the process is expected to be a technical and commercial success.

Jan 1, 1995

By F. Elgersma

Hydrometallurgical zinc winning processes ?are frequently based on iron containing concentrates which yield a goethite, jarosite or hematite residue. Jarosite or goethite are mostly stored in waste ponds which ,are lined with foil. Water percolating through the pond is withdrawn from the deposit ,and decontaminated before discharge. Despite these measures, more and more pressure is put upon zinc companies to treat their (historical) residues and to produce environmentally acceptable residues. The criterion which determines this acceptability is the potentiality of leaching out hazardous elements by natural processes. This paper provides the comparison of five different process designs for integrated jarosite treatment in a hydrometallurgical zinc winning plant leading to environmentally acceptable residues. The processes are esigned for producing 200 ktons/yr zinc and for treating 80 ktonslyr historical jarosite. Mass and energy balances are used to determme parameters such as: the energy use per ton waste treated and the amount and composition of final residues. The conclusion of the work is that. pyrometallurgical jarosite treatment integrated in hydrometallurgical zinc winning is preferable to hydrometallurgical jarosite treatment. Integrated pyrometallurgical processes lead to a ?smaller quantity of remaining hazardous residues and require less energy.

Jan 1, 1992