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By E. A. Pelczarski

Initially, the objective of this contract was to develop a PWSCSR that could meet proposed criteria (that were different from 30 CFR 11(Title 30 of the Code of Federal Regulation part II) and that would be less than twice the size and weight of a filter self rescuer. This objective was met. Consequently, the original contract was extended to develop a PWSCSR that would meet existing CFR-30 criteria within the same size and weight constraints. This resulted in the development of a PWSCSR (the SR-100) that received NIOSH/MSHA approval (TC-239). This report presents a historical discussion of the design and development of the SR-100 as developed by CSE Corporation under Bureau of Mines contract number H0368013. The technical parameters and the test results of NIOSH/MSHA 30 CFR 11 certification are also presented.

Jan 1, 1990

By F. F. Aplan, J. A. Gutierrez-Rodriguez

"Contact-angle and flotation techniques were used to evaluate the influence of oxygen - both that inherent in the coal and that introduced by ambient temperature, aqueous oxidation - on a wide range of coal ranks. Oxidation was found to decrease the hydrophobicity and floatability of coal; with the effect being minor for coals of high rank but becoming increasingly important as the rank of coal is reduced. As an approximation, oxidation makes a coal behave as if it were one of lower rank. Frother only flotation' of coal· correlates with the captive-bubble contact angle whereas when oil is used as a collector, the flotation appears to follow the pattern shown by the water sessile drop on a fresh, un-reagentized coal surface. Coal recovery lost through oxidation may often be recovered by use of a variety of collectors, of which No. 2 foe! oil is among the best of those reagents tested. A simple alkali-extraction test may be used to estimate the influence of oxidation on coal preparation processes and use.INTRODUCTIONThe hydrophobicity of coal is not only a function of its rank but also of the extent of oxidation of the coal during and subsequent to its formation. Weathering and oxidation processes may proceed in-situ for coal deposits that outcrop near the earth's surface, or the oxidation of the coal particles may occur during mining, stockpiling or processing. Such oxidation, whether it affects the bulk-coal sample or on1y a thin outer layer on the coal surface, can dramatically influence the wettability of the particle and hence such processes as flotation, filtration, flocculation and dispersion.Many of the studies made on the oxidation of coals ·were designed to study its effect on flotation, coking or pyrolysis. The. present study 'is directed exclusively toward the effect of oxidation on the hydrophobicity and floatability of the coal. One of the first studies of the effect of oxidation on coal flotation was that of Sun [l] who found that as oxidation proceeds, coal becomes progressively more hydrophilic. Low-temperature oxidation (100-150°C for 250 h) generally lowered the coal floatability with an oily collector only slightly, but more extensive oxidation (200- 3500 C for 250 h) reduced coal floatability seriously. Sun also found that cationic amines were effective collectors for the oxidized coal which infers that oxidation makes the coal more negative in solution. He attributed the loss of floatability to be due to the accumulation of water-insoluble oxidation products at the coal surface. Gayle et al. [2] found that oxidation adversely affected coal flotation when an aliphatic-alcohol frother was used, though a small amount of oxidation appeared to improve the floatability of some coals using a kerosene-pine oil, collector-frother mixture in pilot-plant testing. Prolonged oxidation adversely affected the flotation recovery of the coals tested, the effect being more pronounced when an alcoholic-type frother only was used. They also noted that the reduction in floatability of lower rank bituminous coals was more affected by oxidation than was that of higher rank bituminous coals."

Jan 1, 1989

By M. Hayashi

The Bureau of Mines conducted laboratory studies on Idaho mudstones to examine techniques for extracting vanadium. Recovery of vanadium from low-grade sources could contribute to future vanadium production and reduce reliance on imports. An Idaho mudstone surface sample containing 0.30 pct V205 and an underground sample containing 0.21 pct V205 were used in the extraction tests. Leaching of the surface sample for 18 h at 800 C with the addition of up to 1,000 lb/ton H2S04 recovered 70 pct of the vanadium. How-ever, leaching of the underground sample under the same conditions re-covered only 47 pct. By adding 15 wt pct NaCl and roasting the samples at 7500 C for 2 h, followed by leaching with 800 lb/ton H2S04, vanadium extractions were increased to 78 pct from the surface sample and 83 pct from the underground sample. Water leaching of samples roasted at 7500 C for 4 h with a 25-wt-pct NaCI addition yielded about 60 pct of the vanadium from both surface and underground samples. Autoclave leaching at 2000 C for 3 h with 1,000 Ib/ton H2S04 extracted 97 pct of the vanadium from the surface sample and 86 pct from the underground sample. An exploratory solvent extraction investigation to purify and concentrate vanadium in the leach solution using several organic reagents was also conducted.

Jan 1, 1985

By G. W. Birge

As a part of its overall program of coal carbonization, the Bureau of Mines is studying the coking properties of coals that may be used for metallurgical purposes. The objectives of this study were given in detail in a previous report.2/ The inherent suitability of coal for metallurgical use depends primarily on (1) chemical composition, (2) preparation characteristics, and (3) carbonization behavior. The first two factors, as well as the available reserves, are considered in selecting coals for carbonization tests. The selection of coal beds in Westmoreland County for coking tests was based, in part, on estimates of the coal reserves by Dowd,3/ who estimated the recoverable reserves in beds 28 inches or more thick, in thousands of tons, as follows: [ ]

Jan 1, 1957

By P. L. Swanson

Stability analyses of fractured and faulted rock masses require delineation of the position, extent, and orientation of geologic discontinuities. The size of the smallest active discontinuity that may potentially be resolved using the spatial distribution of microseismic event locations is Limited by the accuracy and precision of the location methods. At a hard-rock mine in the Coeur D'Alene mining district of northern Idaho, two data sets consisting of calibration blast signals from a known source site and origin time and microseismic event signals were recorded using a stope-wide accelerometer array. These seismic signals are used to quantify various sources of error in event location. Five factors influencing source location errors are examined in this U.S. Bureau of Mines study: (1) biases of the numerical source location techniques, (2) receiver array geometries, (3) uncertainties in receiver positions, (4) errors in picking arrival times, and (5) uncertainties in seismic velocity structure, including the effect of mine openings. In addition, synthetic data (accelerometer positions, travel-time picks and wave velocity) are used to determine the effect of known systematic and random errors on source location calculations. It is shown that the commonly accepted association of minimum travel-time residuals with the best location solution does not necessarily hold true when there is a systematic error in seismic velocity. Recommendations are made for increasing the accuracy and precision of locations of microseismic events detected under similar field conditions.

Jan 1, 2010

By Rethel L. Hubbard

Fourteen straight-run asphalts were prepared in the laboratory from bitumens obtained from three sources: (1) native bitumen from Rozel Point, Utah, (2). bitumen extracted from Athabaska bituminous sandstone at Canada, and (3) bitumen extracted from Edna bituminous sandstone outcropping in San Luis Obispo County, to seven asphalts with penetrations ranging from 19 to 287 at 77 F. were prepared from each of the bitumens. The yields of the prepared asphalts ranged from 74.5 percent for a 27-penetration asphalt from the Athabaska bitumen to 99.5 percent for a 271-penetration asphalt from the Rozel Point bitumen.

Jan 1, 1949

By Philip C. Good

The Bureau of Mines investigated the feasibility of utilizing low-grade phosphatic shale as a feed for phosphoric acid production. Present practice in the phosphate mining operations of southeastern Idaho is to remove and either stockpile or waste low-grade phosphatic shales as the high-grade phosphate beds are selectively mined. Acid digestion studies were performed on uncalcined shale and on shale calcined to remove free carbon to determine phosphoric acid quality, yield, and amenability to filtration. The untreated shale, containing 21.4 pct P205, was digested with sulfuric acid in a single-tank reactor to yield phosporic acid and gypsum residue. Although 96 pct P205 recovery was attained in digesting uncalcined shale, only the calcined product gave satisfactory filtration rates. Calcined shale yielded phosphoric acid recovery of about 93 pct of the contained P205. It was higher in impurities than commercially prepared acid derived from high-grade western phosphate rock. An acid filtration rate of 745 lb P205/ft2/day was attained. This value is lower than the rate of 900 lb P205/ft that is generally considered to be acceptable in industrial production of phosphoric acid from high-grade phosphate rock.

Jan 1, 1981

By Robert J. Anderson

"Introductory Statement:In melting the nonferrous metals and alloys for foundry and rolling-mill work, even with the best practice, there is always a loss, due principally to oxidation. Melting losses are a serious source of financial loss in brass and bronze practice, but they are especially serious in the case of aluminum and its light alloys because of the relatively high price of aluminum. The indications are that the melting losses in many aluminum foundries of the United States are at times high, and in some plants (especially where certain furnaces are used) they are entirely too high when compared with the average practice. The fact that the oxidation losses in melting aluminum and its light alloys are high is well known, but it is doubtful whether the factors governing the most suitable methods of melting for a minimum of dross are equally well known. The metal losses involved in melting are worthy of especial attention now because of the rapidly growing importance of the aluminum industry.Factors in the operation of furnaces which affect metal and fuel losses:The essential requirements in the commercial melting of any metal or alloy are that the melting losses should be low, the melting should be rapid, and the melting cost should be low. Certainly it may not be possible to obtain these requirements in any furnace selected at random, and it follows that the design and the operation of furnaces for melting different metals are subjects that warrant the most extensive study and tests. As a general rule, in the industrial operation of furnaces, run on aluminum and aluminum alloys, an effort is made to keep the dross and oxidation losses as low as possible. In attempting to hold dross losses low, numerous factors involved in metal melting may be overlooked, or at least disregarded, and the net practical result may be that the furnace is exceedingly wasteful of fuel. In the case of aluminum and its light alloys, the effect of increasing the temperature of melting, at least in an atmosphere containing free oxygen and nitrogen, is to increase the net melting loss."

Apr 1, 1921

Watershed Jll in Jefferson County, Ohio we instrumented in 1977 as one of three watersheds established for the purpose of investigating surface mining and reclamation effects upon local hydrology, sediment discharge, and sediment and water quality. Each watershed was less than 50-acres in size, and was in a different geologic setting within southeastern Ohio. Surface runoff and ground¬water levels were monitored. Samples were taken for sediment determination and chemical analysis prior to mining. Monitoring and sampling continued through the period of watershed disturbance caused by mining and reclamation activities, which began in May 1980 at Watershed Jll. A psuedo-postreclamation period followed the initial cessation of man-machine activity on the watershed. A second reclamation effort occurred in the fall of 1981 and was to be followed by a third in 1982 after observations ceased. A true final postreclamation period was not monitored at this site, because the erosion control practice (terrace diversions) failed after each reclamation. Watershed Jll was a small pasture and wooded watershed with sandstone and shale above the mined coal seam prior to mining. A clay layer under the coal supported a perched saturated zone, termed the top aquifer for convenience. A lower underclay supported a second saturated zone called the middle aquifer. A lower perched aquifer had been dewatered by previous deep mining. After about three years of premine data and about two and one-half years of mining reclamation and psuedo-postreclamation data, the following general observations may be made: 1. The mining-reclamation phase was very short, and the postmining period was characterized by erosion failures and remedial disturbances that kept the watershed condition and size in a state of change. It was impossible to collect sufficient data to confidently characterize the hydrologic-sediment-chemical aspects of the mining period or of a postreclamation period and, most importantly, of the future watershed after its various properties and characteristics have ceased adjusting to its severe disturbance and reconstitution. 2. A seeding of wheat followed by grasses and legumes was not a particularly successful reclamation practice in terms of stabilizing the new soil. Numerous rills and small gullies developed in spite of installed diversions. 3. Storm runoff rates and yields at the watershed outlet increased from the premine, (phase 1) to the mining-reclamation (Phase 2) periods, and remained at or near the Phase 2 level through the postreclamation (Phase 3a) period. 4. The top aquifer changed in physical and chemical character as a result of mining and was becoming reestablished as the project drew to a close; but it is impossible to predict its final configuration or character. 5. Dewatering of the top aquifer resulted in a complete cessation of baseflow because the middle aquifer water table lay below the elevation of the watershed outlet. 6. The top and middle aquifers were merged in one area of the watershed where the upper coal underclay was disturbed. 7. Failure of the diversion terraces and their outlet obscured the effects of the reclamation practice upon sediment concentration and yields. There was little difference in sediment concentrations between Phases 2 and 3a. 8. Drinking water standards were met by surface waters throughout the period of observation except for two samples that exceeded the nitrate-N allowable level of 10 mg/l. 9. In all Phase 3 surface-water samples, iron concentrations were within the limits established by OSM, and manganese concentrations exceeded the regulation level only once. pH fell below the lower regulation level of 6.0 between 10% and 20% of the time. 10. The chemical quality of sediments was generally about the same after reclamation as before mining, with the exception of organic carbon, which decreased.

Jan 1, 1983

By S. S. M. Chan

The Bureau of Mines has investigated the structural aspects of shafts and support systems using the finite-element technique. In situ field measurements in deep, vein-type metal mines show that rock stresses are often higher in the horizontal direction than the vertical, and unequal in the horizontal plane. These data and laboratory and field-determined physical properties were used as input to analytical studies. Various design and construction parameters were investigated to deter-mine the effect on shaft stability. Rectangular shafts were studied in detail to determine the effects of applied stress ratio, shaft orientation and dimension, influence of interbedded quartzite and argillite, and rock fracturing. Various support systems were analyzed, including concrete lining, timber, and steel sets. Circular configurations were investigated to evaluate yield zones and liner thickness. Elliptical shafts and time effects were briefly evaluated to illustrate shape and time effects and demonstrate the methodology. It is shown that the magnitude, direction, and ratio of applied stress and rock mass anisotropy are keys to determining shaft stability. A realistic conceptual framework was developed with which to examine the rock and support interaction in deep mine shafts. Structural analysis techniques overcome some of the historical difficulties with shaft de-sign by defining the field data requirements and structural sensitivity of various design and construction parameters.

Jan 1, 1985

By Clarence Karr

In 1955 the Federal Bureau of Mines established a low-temperature tar laboratory at its new Appalachian Experiment Station in Morgantown, W. Va. The objective of the laboratory is to investigate the yields and chemical and physical properties of tars from low-temperature carbonization of coal, to investigate means of economically upgrading these tars, and to make available to industry and the public essential data for increasing coal utilization through the establishment of a new coal-chemical industry, based on the utilization of low-temperature tars. Because of the obvious economic significance of phenols, as well as the relative ease with which they can be separated and analyzed, initial research has centered mainly around this class of tar constituents. It was realized early that no listing of phenols and their physical properties existed that included enough compounds to be practicable. The purpose of this paper is to make such a compilation available.

Jan 1, 1957

By C. E. Wyndham

The occurrences of manganese In Alabama were reported to be widely scattered over the northeastern section of the State, and these were examined before a development project was started.2/ The most promising and available showings were chosen for further investigation, which include 1 deposit in Goshen Valley, 6 in the Rock Run area, and 2 in the northern section of Calhoun County. The work was performed by the Bureau of Mines from July 29, 1949, to February 17, 1950. The work consisted of power auger drilling 69 holes 3-1/2 inches in diameter and totaling 2,548.4 linear feet. The accuracy of samples from auger drill holes in this type of deposit was determined by sinking two shafts a total depth of 68.17 feet, from which channel samples were cut. Sixteen rotary core holes totaling 1,048.7 linear feet were drilled with a 3-inch, double-tube core barrel. Twenty-two diamond core holes were drilled with a 2-1/8-inch, double-tube core barrel and NX diamond bit. In addition to the above drilling 220.8 cubic yards of soil and rock was excavated by hand from 403.9 linear feet of trenches and 69.7 feet of test pita. A total of 206 samples were taken and analyzed for manganese, iron, cobalt, nickel, and insoluble.

Jan 1, 1953

By Roger L. Williams

The Bureau of Mines investigated northern New Jersey as a potential future source of yttrium and the rare-earth elements. The studies, consisting of geophysical surveying, sampling, and exploratory drilling, began in the spring of 1959. A total of three and one-half months were spent in the field collecting data. Thirty-three deposits were investigated, of which five demonstrated some potential resources of yttrium and rare-earth minerals. Results indicate that the deposits examined do not contain quantities of yttrium and the rare-earth elements recoverable under present economic conditions. Detailed studies conducted at the Scrub Oaks mine, near Dover, N. J., delineated a yttrium and rare-earth-bearing zone within the magnetite-hematite ore body that represents a potential low-grade deposit. Beneficiation studies on this deposit indicate that a final product, averaging 31.3 percent rare-earth oxides including yttrium, could be produced through amine and fatty acid flotation procedures with 77 percent recovery. Two hundred and eighty-five feet of diamond drill core was obtained from exploration studies conducted at the Bemco prospect in Sussex County. The deposit averages 2.30 percent rare-earth oxides (including yttrium), 0.45 percent uranium and 0.24 percent thorium. Low-grade deposits were identified at the Canfield phosphat2 mine and the Tanners Brook Monazite placers in Morris County, and the Marble Mountain prospect in Warren County.

Jan 1, 1967

By A. T. Harris

Ground quartzite, known in the industry as amorphous silica, is produced from a quartzite deposit near Honey Brook, Pa., by George F. Pettinos, Inc., of Bala-Cynwyd, Pa. The quartzite is mined by the open pit method and processed in a mill at the mine. The operation regularly produces five standard grades of sand and one grade of crushed stone; however, the company accepts special orders and will produce material to meet the customer's specifications. Beneficiation (chiefly crushing and screening) is controlled by laboratory screen tests on samples taken during preparation of the sand. The chief uses of the sand are for foundry operations, furnace lining, concrete aggregate, and other specialized uses. The quartzite in this deposit is of uniform composition and does not require control by chemical analysis. However, for special purposes, analysis will be furnished.

Jan 1, 1965

By Virgil Miller, Glenn L. Allen

The purpose of this report is to present a comprehensive review of the technology of alumina and aluminum production in the former Japanese Empire , which consisted of the Japanese Home Islands and her dependencies , Formosa , Manchuria , and Korea . Pertinent background material and statistics are given when deemed necessary to make the report self - contained and to make clear the factors underlying Japan's tremendous accomplishments in the production of aluminum .

Apr 1, 1949

By R. L. Crosby

Microscopical and X-ray diffraction techniques were used to identify two intermediate phases in that part of the solid region of the magnesium-cerium system between and Mg3Ce. Previous literature had reported only one intermediate phase for this region, 1)12t chemical analysis determined the approximate composition of the two compounds to be Mg23Ce2 and Mg17Ce2. The range in composition of the two intermediate phases was found to be limited to less than 0.3 atomic percent cerium. The study did not determine the crystal structure of Mg17Ce2, but that of Mg23Ce2 is tetragonal with a = 10.33 A and c = 19.51 A.

Jan 1, 1966

By D. E. Andrus

This paper, which describes the milling practice at the Montana mine concentrator of the Eagle-Picher Lead Co., is one of a series being prepared by the United Slates Bureau of Mines. LOCATION The Montana mine is situated on the eastern edge of the Oro Blanco mountains at an elevation of 4,300 feet. It is in the Oro Blanco mining district, Santa Cruz County, in the southern part of Arizona, about 4 miles north of the Mexican border, 30 miles northwest of Nogales and 80 miles southwest of Tucson. Amado, a station on the Southern Pacific Railroad, midway between Tucson and Nogales, and about 40 miles northeast of the mine, is the shipping point and is reached over an excellent highway.

Jan 1, 1931

By R. H. Harrison, D. R. Douslin

The thermodynamic properties H - H° , (H - H° ) /T , S - Sideal , S - S° Fide al F - F° , (F F° ) /T , and activity coefficient Y for perfluorocyclobutane were calculated as functions of temperatures ( 115.22 ° to 350 ° C) and molal density (0.75 to 6.5 moles / liter ) . Improved analytical and graphical correlating techniques are described .

Jan 1, 1964

By E. C. Lane

[This Is the ninth in a series of reports on properties of commercial motor fuels, made in accordance with a cooperative agreement between the Cooperative Fuel Research (C.F.R.) Committee and the Bureau of Mines of the United States Department of the interior. The first report gave data on motor gasoline sold during the winter of 1935-36.3/ The Present report presents analytical data for 2,033 samples, representing the products of approximately 80 companies, which, as in previous surveys, include both large and small suppliers. In addition, the Pacific coast is represented by data that were average by the Pacific Coast Technical Group before 'being submitted and are published exactly as they were received. As in previous surveys, the data are divided into the three groups of samples of regular-price, premium-price, and third-grade gasolines, and each group has been averaged separately. The cumber of samples, items, and brands comprising each group, exclusive of those of the Pacific coast, arc as follows: Regular price, 1,066 samples, 208 items, and 49 brands; premium price, 575 tamales, 154 items, and 38 brands; third-grade gasoline, 7;4 samples, 150 items, and 53 brands. The meanings of these terms as used in the surveys tar as follows: Sample: The individual supply of gasoline obtained at the filling station and analysed in the laboratory.]

Jan 1, 1940

By Gerald V. Gibbs

As a part of the Bureau of Mines long-range program in asbestos, synthetic asbestiform compounds and minerals were prepared and described. Fundamental structural data on two such compounds are given in this report. Crystallographic data are provided for the synthetic isotypic compounds potassium-lead silicate, K2.Pb4 -Si8021 (I), and lead-aluminum silicate, Pb2. Pb4 .Al2Si6O21 (II). The space group symmetry 14/mmm was assigned provisionally to I and II on evidence of single crystal and piezoelectric measurements. A statistical evalua¬tion of indexed powder diffraction data revealed the cell edtes of I to be a 11.816 and c 7.932A and those of II to be a 11.723 and c 8.044A. The phases are uniaxial with observed refractive indices eD 1.790, an ?D,699 and eD 1.884, cusp 1,807, respectively. The atomic structure of I and II may be based on a complex of chains of silicon-oxygen tetrahedra lying along the c cell edge similar to the type of chain structure postulated by Pauling for scapolite. K2.Pb4.Si8021 and Pb2.Pb4 Al2Si6021 were first described by Geller and Bunting (5, 6)4 as fibrous compounds similar in crystal habit to asbestos. These authors gave powder diffraction data, although no attempt was made to find the cell edges or to index the powder diffraction patterns. Later, Shell and others (9) conducted a crystallochemical study of these fibrous silicates in search of a substitute for strategic asbestos. Their single crystal data revealed K2.Pb4 -Si8021 to be tetragonal body-centered with cell edges a 11.66, c 7.95 A. Pb2.Pb4 Al2Si6021 was concluded to be isotypic with K2.Pb4 -Si8021 on the basis of similar powder diffraction patterns, chemistry, and physical properties. No attempt was made, however, to index the powder diffraction record nor to determine the appropriate space group of either compound.

Jan 1, 1962