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By J. Y. Liu

The comminution in a high-pressure roller mill is modeled by an energy-based population balance approach considering three aspects of breakage taking place in the active zones of the mill: the interparticle breakage in the high-compression zone, the breakage at the edges of the rolls, and the pre-breakage in the acceleration zone. Together with an appropriate model of classification, this model can be used to simulate steady-state performance of closed-circuit grindings with high-pressure roller mill. After a brief description of the basic modeling approach, the algorithm of the steady-state calculation for a generalized grinding-classification circuit is presented, from which the circuit configurations commonly met in industrial practice can be derived. With an iron ore as feed material for example, simulation results are shown and discussed in respect of circulating load, specific energy consumption and product fineness for closed-circuit grindings under various operating conditions. The effects of stressing intensity, working gap, classifier parameters as well as circuit configuration on the overall circuit performance are investigated systematically by means of computer simulation.

Jan 1, 2014

By Liu Chun-Bao Sun, Hong-Jun, Wei Zhang, Tao Xu

SABC circuits have gained widespread attention within China, and are being gradually applied to many mines. However, the domestic knowledge of comminution process is still relatively basic, and the design and production management of the application of SABC technology lack guidance of scientific theories. This research project focuses on the Phase I SABC milling circuits of Wu Shan Porphyry copper mine. Targeting the design and operation problems of existing process and circuit, and without increased investment and alterations in equipment, the new technologies will combine ordinary crushing and grinding theories as theoretical guidance, and borrow JK Simulation Software (JKSimMet) for analysis in order to optimize the comminution process, efficiently allocate production output and energy consumption, eventually resulting in increased production and energy efficiency. Using JKSimMet Simulation Software, and combining theoretical optimizing and practical production techniques, as well as the on-site situation, the eventual SABC comminution process and circuit optimization plan is: increasing the grinding Ball charge from 8% to 10% v/v in the SAG mill; Setting the Ball charge in the Ball mill to 27% v/v and the maximum operating power draw to 5 800kW; replacing the HP Series crusher with a TRIO TC84 crusher, which is without a power controller, and adding a pebble bin. The final optimization result is: Maximum system processing capacity increased between 20%-26.7%, specific energy consumption reduced by more 2.0 kWh/t, creating an economic benefit of over 300 million RMB, thus achieving the goal of increased production, reduced energy consumption, and improved profitability.

Jan 1, 2014

By L. G. Wang

The stability of foams and froth plays an important role in flotation, in which small amounts of relatively weak non-ionic surfactants (frothers) are used to produce air bubbles and foams. In the present work, factors affecting the stability of the foams produced in the presence of common frothers, such as n-pentanol, n-octanol, methyl isobutyl carbinol (MIBC), and polypropylene glycol (PPG), have been studied. We used the thin film pressure balance (TFPB) technique of Schelud-ko-Exerowa type to measure the equilibrium film thicknesses. The results were used to determine the contributions from the various surface forces to the disjoining pressures in the thin lamellae (foam) films formed between air bubbles. In addition, we used a model developed by Wang and Yoon (Colloids and Surfaces A: Physicochem. Eng. Aspects, 2006) to calculate the elasticities of the lamellae films at the critical thicknesses at which films rupture. The surface forces and elasticity da-ta were then compared with the foam stabilities in the presence of the various flotation frothers. It was found that foam stabilities are controlled by both film elasticity and surface forces, the relative contributions of which change with frother type and concentration. In general, surface forces play a more important role at relatively low frother concentrations, while elasticity plays a more important role at higher concentrations. At the frother additions usually employed in the mining industry, MIBC relies on surface forces while PPG-400 relies on film elasticity in producing stable foams. The former is capable of dampening the hydrophobic force, which is a major attractive force destabilizing lamellae films, while the latter is capable of reducing surface tensions at low concentrations.

Jan 1, 2014

By Volker Vogt, Wolfgang Sand, Eberhard Gock

"For about 20 years, the use of bacteria to control the flotation process for the production of raw material concentrates has been the subject of worldwide scientific and engineering efforts. The objective is to reduce the consumption of biologically non-degradable toxic reagents. The principle idea is to use the activity of bacteria in natural leaching processes – known since the middle of the last century – for controlling flotation processes.It was discovered that the selective activity of bacteria during the extraction of raw material concentrates by means of flotation could also be achieved with extracellular polymeric substances (EPS), excreted by bacteria. EPS, which is extracted by means of centrifuging bacterial cultures, can help to significantly reduce the use of cyanides, approximately 200,000 t/a are used for ore dressing today.The bacterium used was Acidithiobacillus ferrooxidans. In order to identify the bandwidth of the oxidation activity, 21 bacterial strains of the strain collection of the University of Hamburg were attracted to iron(II) sulfate and pyrite under defined conditions. All strains oxidized iron(II) sulfate ten times faster than pyrite.EPS has so far been derived from four strains. In general, EPS extracts are divided into a hydrophilic and a hydrophobic fraction. The hydrophilic fraction is composed of e.g. fucose, rhamnose and glucose; fatty acids such as dodecanoic acid, hexadecanoic acid, octadecanoic acid and nonadecanoic acid were found in the hydrophobic fraction. Pure mineral phases and mineral mixtures were used for the flotation tests. The outcome was reproducible results with technical flotation machines. The research results known so far are mainly based on investigations with micro flotation devices, which are usually used for the characterization of reagents and which do not allow a direct translation to the technical scale."

Jan 1, 2003

By Robert van Hille, Alison Lewis

The precipitation of a selection of metals from both a synthetic and an actual metal-rich effluent was investigated. The experimental aspects of this study were carried out in a two-stage process consisting of a pre-treatment clarifier and a fluidised bed (pellet) reactor. Each unit operation in the two-stage process was investigated separately. The pre-treatment clarification stage at pH ˜ 5 resulted in a 99.9% removal of iron and 97.3% removal of aluminium. The pellet reactor was used to precipitate nickel as nickel carbonate from a pure stream and a removal efficiency of 99.6% was achieved. The high local supersaturation at the reagent inlet points caused the formation of a large amount of fines, but these agglomerated onto the pellets up the length of the bed. For copper precipitated as copper sulphide from a pure stream, a maximum removal efficiency of 92% was achieved. The high local supersaturation at the reagent inlets also caused the formation of a large amount of fines, but the extremely sparingly soluble nature of copper sulphide meant that the fines were not agglomerated up the length of the bed. For removal of cobalt as cobalt carbonate from an actual stream, a stable cobalt removal of only 60% was achieved. This was found to be due to the presence of magnesium, which reduced the cobalt precipitation efficiency through the formation of the magnesium bicarbonate ion.

Jan 1, 2003

By O. Güven

In recent years, there is an increasing demand on manganese consumption which stems from the important role of manganese in carbon steel production. And the growing need for manganese ores makes the beneficiation of low-grade manganese ores more economical. In this study, the characterization and beneficiation studies were carried out to propose a flow sheet for typical low-grade Turkish manganese ores. For this aim, different gravity separation methods were applied. According to the mineralogical analysis, the major mineral phases are pyrolusite (MnO2) and psilomelane (MnO2) while the major gangue mineral is radiolarite. Gravity separation tests were accomplished by using jigs, shaking table, MGS (Multi Gravity Separator) and in order to obtain products with high Mn ratio, high intensity magnetic separation was also performed. As a result, different combinations of flow sheets were utilized and a concentrate assaying 56.5% Mn with 85 % recovery was obtained.

Sep 1, 2012

There is a strong demand for nickel metal due to quick development of stainless steel and new electrical materials, most of which is extracted from sulfide resources, resulting in a serious depletion of sulfide resources. Therefore, more attentions have been paying to extracting nickel from nickel laterite, which accounts for some 50% of total nickel metal production. In this paper prereducing?magnetic separation?reduction smelting process is developed to manufacture ferronickel rom two types of nickel laterite DN and GN, assaying 1.42% 1.83% Ni and 49.09% 26.08%Fetotal, respectively. Mineralogy of two types of nickel laterite was determined and optimization of process parameters was conducted to manufacture ferronickel. Prereduction?magnetic concentration process is used to upgrade low grade nickel laterite firstly, two kinds of Ni-Fe concentrates being prepared of DN assaying 2.26% Ni and 69.45% Fetotal and GN containing 2.76% Ni and 38.00% Fetotal. Finally, two types of ferronickel were produced by reduction smelting of prereduced concentrates DN and GN, DN and GN ferronickel contains 2.97% Ni and 6.58%Ni, 89.25%Fetotal and 89.95%Fetotal, respectively. The total recoveries of Ni and Fe of the two ferronickel are beyond 90% and 80%, respectively. There is significant difference in grade of magnetic concentrates and ferronickel between DN and GN laterite due to their different mineralogy, the former belongs to limonitic laterite and the latter saponite one. There are some advantages for this process to manufacture ferronickel from nickel laterite, including effectively upgrading low grade nickel laterite by prereducing?magnetic separation technique, higher throughput and lower energy available for reduction smelting section due to some 40% gangue being rejected in pre-upgrading section, and much less metallurgical coke consumption by using non-coking coal as reductant for prereducing?magnetic separation?smelting process.

Jan 1, 2014

By U. A. Peuker, T. Mütze, F. Shayo, A. Wikedzi

"Buzwagi Gold Mine (BGM) is operated by Acacia Mining and located in the Lake Victoria Goldfields of central Tanzania. The mine treats a sulphide copper-gold ore to produce gold in form of doré bars and a concentrate containing gold, copper and silver. The BGM comminution circuit includes a primary crushing stage with a gyratory crusher and two grinding circuits using a Semi-Autogenous Grinding (SAG) mill and a ball mill. Currently, the grinding circuits are inefficient in achieving the aspired product fineness of xP,80 = 125 µm even at low to normal throughputs (450-600 t/h). An optimization study of the circuit performance was conducted to improve product fineness through circuit surveys, experimental lab work and simulations. The analysis of survey data revealed inefficient grinding operation characterized by ball mill product (xP,80 > 400 µm) coarser than designed and higher hydrocyclone cut sizes (xT > 200 µm), too. In MODSIM several options were simulated such as reduction of vortex finder and apex diameters, reduction of SAG screen aperture, and modification of cyclone feed density. An improvement of product fineness could be achieved by simulation of the cumulative changes but it was also concluded that the current equipment cannot achieve the target. Further simulations showed that a second ball mill might help to achieve the desired fineness as well as an increase of grinding throughput by up to 26 %. INTRODUCTION Simulation of comminution, particularly grinding and classification, has received great attention for many years, due to the fact that the unit operation is by far the most important both in terms of energy consumption as well as overall plant performance (King, 2001; Wills et al., 2006). The use of simulation is advantageous due to low cost as well as its ability to consider many variables simultaneously. Moreover, there are some benefits for optimizing grinding operations by simulation like decreased unit operating costs, increased capacity, and improved performance of downstream processes due to improved feed size distribution. This paper presents an optimization study for the grinding efficiency at Buzwagi Gold Mine. This was achieved through three full scale circuit surveys, lab work and simulations with MODSIM."

Jan 1, 2018

By S. Saha

Minerals in coals cause operational problems in various coal utilization technology as well as act as diluents towards its heat value. Indian coals contain higher percentage of mineral matter compared to foreign coals due to its formation through drift origin. Efficient utilization of high ash coal in environment friendly manner is the driving force for the development of clean coal technology. Coal gasification offers practical means meeting stringent environment controlled parameters for producing power, chemicals, liquid fuels and clean energy on a single platform. It is well accepted that gasification technology has sufficient potential for sustainable development of clean coal technology. Gasification reactivity depends on the coal properties and operational parameters as well as minerals present in coal. Minerals not only create operational problems but on the other side also catalyze the gasification and combustion reaction. Therefore to understand the effect of minerals on the gasification reactivity, present paper proposes to study the variation of gasification reactivity with various gravity cuts such as, 1.4-1.5; 1.6-1.7; and 1.8-1.9 of a selected coal. Gasification reactivity has been studied by thermo gravimetric analyzer (TGA) using CO2 as gasifying agent. Surface properties such as, true density, apparent density, porosity, surface area of different gravity cut samples have also been measured to find out the effect of gravity separation on gasification reactivity. Keywords: gasification, reactivity, mineral matter, gravity separation

Sep 1, 2012

By Nicholas Enraght – Moony, Alvin Johns, Zhonghan Zhang, Zhang Xianhua, T. Choo

"The tungsten (WO3)-rich ores from King Island Scheelite (KIS) Mine, Australia, containing scheelite(CaWO4) were previously recovered by gravity separation and flotation of fine scheelite (1978-92) with an overall recovery of 76% when both circuits were operating. Recently extensive test work has been conducted both in China and in Australia on KIS ores, assaying from 0.50%-1.34%WO3, and tailings assaying 0.2%WO3(GZRINM 2009; 2011a; 2011b). A new approach, which aimed at improving both recovery and grade of concentrate by means of an innovative all flotation route WOF (Whole Ore Flotation), achieved excellent results: 90%-92% recovery to concentrate grade of 66%-70%WO3for the ores. The process is characterized by the use of selective reagents in flotation, including a newly developed collector for scheelite, GYWA. The WOF process also embraces the "Improved Petrov Method" in the cleaning of scheelite rougher concentrate. Earlier investigations found that the removal of sulfides by flotation prior to scheelite flotation was not necessary. It was also found that recycling of process water did not influenceresults. Two main ore types were tested as well as tailings from 2009to 2001(0.20%WO3). In addition a flow sheet using wet high gradient magnetic separation (WHGMS) in tandem with flotation was also investigated for the tailings."

Jan 1, 2014

By A. P. Chaves, D. Jose Neto, M. G. Bergerman, E. S. Mano

"More complex ore comminution and concentration operations have found increasing application in the mining industry due to lower grades and higher complexity of the available ores. An alternative to coping with the higher capital and operating costs of ore processing plants is the use of pre-concentration stages. They allow removing a significant mass of material with little or no content of the relevant mineral before the ore is fed into the processing plant, with the consequent reduction in the mass to be processed in downstream operations. Significant benefits arise out of the use of pre-concentration, such as higher contained metal output without the need to increase the grinding or flotation capacity, and longer mine life. The grade of marginal ores could be enhanced to a level that would make their exploration economically feasible, which would result in increasing exploitable reserves. Nevertheless, few studies to date have assessed the resulting impacts on ore grinding energy consumption and wear after the gangue is removed through pre-concentration operations. This study evaluated the energy consumption and wear of grinding circuits in Brazilian mining operations in which the feed has gone through a pre-concentration stage. Such assessment was based on different samples of sulfide and oxide ores. Laboratory tests were carried out to investigate the power consumption and wear of grinding circuits with and without a pre-concentration stage. Laboratory test results were used to simulate industrial grinding circuits based on both alternatives and illustrate the environmental and economic benefits of each one.INTRODUCTION Increasingly complex ore concentration operations in several stages have found broadening application in recent years in view of lower grades and higher complexity of the available ores. An alternative to coping with the higher capital and operating costs of ore processing plants is the use of pre-concentration stages. Different ore processing technologies can be used for that purpose, such as magnetic separation, density segregation, and separation methods based on high-tech sensors (ore sorting). Currently, the most common methods are gravimetric processes, in view of their low cost, particularly jigging and dense medium separation methods, such as the drum and cone separators manufactured by Western Machinery Company, Teska, Drewboy, Norwalt, Dynawhirlpool and Tri-flo, and dense medium cyclones (CAMPOS; LUZ; BRAGA, 2010). The use of dry ore sorters has also grown significantly in recent years (Jose Neto et al. 2017). The selection of the separator type depends essentially on the ore particle size, required flows, and operating density ranges. All these methods may even be used after preferential blasting in mining (Grigg & Delemontex, 2015)."

Jan 1, 2018

By K. Yoo

Cuprous oxide is one of the oldest antifouling agents and also acts as red pigment in these paints. In printed circuit board manufacturing industries, waste etchant contains a substantial amount of copper ion. In the present study, a process was suggested for recovering cuprous oxides from the waste etchant and optimum conditions were investigated to recover the cuprous oxides. The process consists of two steps: in first step, Cu powder is added into wastewater solution, and cupric ions re-duce into cuprous ions (Cu+Cu2+?2Cu+), where cuprous ions precipitate as cuprous chloride; In second step, cuprous oxide is synthesized by adding NaOH into cuprous chloride solution (2CuCl+2NaOH?Cu2O+NaCl+H2O). Optimum conditions were investigated to recover cuprous oxide in the processes. When copper powder was added into wastewater with copper ions, Cu concentration decreased from 15.6% to 2.6% and ORP decreased from 620 mV to -59.9 mV. This result shows that cupric ions reduced into cuprous ions. XRD data indicated that the precipitate was cuprous chloride powder. Using the cuprous chloride recovered and NaOH solution, cuprous oxide was synthesized. To investigate the optimum condition, various NaOH solutions were added into water with CuCl, and then pH, ORP, Cu concentration, Cu contents in precipitates were analysed. XRD data showed that main component of precipitates was cuprous oxide.

Jan 1, 2014

By D. R. Nagaraj

The traditional (popular) approach to reagent development and optimization, which has become entrenched in both research and practice for many decades, is highly reductionistic, incremental and costly, does not produce robust chemical solutions, and is not sustainable. There are also several other key drivers and changes in the mineral industry that clearly warrant a new approach. In response to these, an intense effort was made at Cytec over the past fifteen years to develop a meaningful, efficient, and sustainable approach to develop new reagents and robust chemical solutions in mineral separations. This effort culminated in three important outcomes: a) development of the holistic approach, called FLOTATION MATRIX 100? process, b) novel reagents, and c) enhanced application knowledge for reagents. In this paper, the efficiency, utility and power of the holistic approach will be demonstrated with examples using both existing and new reagents in the processing of Cu-Au, Au and Cu-Mo ores.

Jan 1, 2014

By Sergey Ulianov, Arkady Senchenko, Alexey Shvets, Arkady Bakotin

"This paper contains description of research results of technology development for copper recovery from weathered tails of iron processing plant. The predominant host mineral that contains valuable component is chalcopyrite occurring in its free form and in associations with ore and rock-forming minerals. Copper grade is 0.26-0.30%. Emulsion inclusions of chalcopyrite in pyrite and sphalerite were noted. Major problem is low copper recovery (30-35%) by flotation. When studying chalcopyrite in primary concentrate it was determined that the surfaces of many chalcopyrite grains are covered with oxide films which prevented collector attachment onto them. Second issue was deep association of chalcopyrite with pyrite and sphalerite. Sulfidizing reagent addition did not help to reach the required level of copper recovery to concentrate. In the result of research performed the technological flowsheet was developed including preliminary treatment of head material in a special unit aiming at oxide films removal, followed by copper rougher flotation on head size tails, crude concentrate regrinding and a number of cleaner flotation operations. After the treatment of weathered tails according to the flowsheet developed, copper recovery to flotation concentrate became 71.53%, at 23.46% copper grade. The suggested technology allows one to solve the issue with treatment of technology-related copper-containing stockpile material, as well as to include the ores where copper is represented by sulfide minerals covered with oxide films into processing."

Jan 1, 2014

By Fang Liu, Xin Tan, Zhong-ming Wang, Yan-bo Shang, Jie Zhao

"The flotation separation of sulphides bulk concentrate containing Cu, Zn, Mo and Bi, which was obtained by both table-flotation of gross sand of gravity separation of wolframite and bulk flotation of wolframite slimes using butyl xanthate and oil No. 2, etc., has been conducted by using the cyanide process in the tungsten concentrator. The process has problems of high reagents consumption (25 tonne of cyanide dosage per year) and mineral processing cost (800~1000 RMB reagents cost per tonne of by-product concentrates), high mutual containing loss in the by-product concentrates and serious environmental pollution caused by lots of cyanide-containing wastewater. In order to solve this problem, a new cyanide-free separation technology is studied, which is used to process this sulphides bulk concentrate with 8.68% Cu, 8.98% Zn, 0.26% Mo, 1.58% Bi and 40.12% S. The results of the closed circuit test show that Cu, Zn, Mo and Bi can effectively be separated from this sulphide minerals concentrate by using the reasonable flotation-gravity flowsheet, high-efficiency collectors and regulators simultaneously. The metallurgical recovery and concentrate grade are as follows: molybdenum recovery is 94.63% with 50.62% Mo content; copper recovery is 85.18% with 29.29% Cu content; zinc recovery is 75.92% with 46.49% Zn content; total Bi recovery is 65.08% with 16.86% Bi content. The new technology is an alternative to the cyanide process due to its low cost for reagents, satisfying separation results and economic profits, and solves the problem of environmental pollution caused by the use of large quantities of cyanide. Some important parameters in separating the Cu-Zn-Mo-Bi sulphides concentrate are also introduced in this paper. This study provides pretty good technical support for separating the polymetallic sulphide ores containing Cu, Zn, Mo and Bi by cyanide-free technique."

Jan 1, 2014

By V. Panayotov, M. Panayotova

"The combined use of semiconductor properties and specific flotation characteristics of minerals under different conditions with external influences ensures a possibility for process control and management. This work presents the relations between the volumetric and surface characteristics of minerals and the minerals' flotation ability (flotability), as well as the possibility for the flotability purposeful change. Results from proprietary laboratory and industrial research are presented showing how controlled impacts on minerals and flotation pulp improve flotation technology. Such an approach reveals prospects for the creation of new technologies for the minerals' beneficiation.INTRODUCTIONThe decrease of the useful components content in the ores, the increasingly complex nature of the raw materials, the increasing energy consumption per the unit of production, and the need to solve the problems related to the environment pollution require solutions different than the existing classical ones. One of the ways to find such solutions is the detailed consideration of the fundamental properties of minerals and, in particular, of minerals having semiconductor properties. The studies of Plaksin et al. (1968), Chanturia and Shafeev (1977), Chanturia and Vigdergauz (2008), Carta et al. (1973), Hoberg and Shneider (1975), Rao et al. (1992) have given an idea of the energy state of the minerals, their flotation ability, and the ways in which this ability can be changed in one or the other direction. The main line in these works is the study and use of the relationship between bulk and flotation properties of minerals. To improve the efficiency of the process, it is also necessary to consider the relationship between the surface properties of the minerals, especially minerals-semiconductors, and their flotation ability.THEORETICAL BACKGROUND IN BRIEFA quantitative estimation of energy changes in a solid phase in the process of flotation may be made by taking in account the changes in the Fermi level. Its position in the forbidden band is an indicator about the direction and the intensity of electron exchange between solid and liquid phases. The Fermi level energy EF enables the estimation of flotability, intensity of needed external impact before flotation, as well as efficiency of the process going on. Quantitative estimation of these processes can be made by means of the flotability coefficient Kf."

Jan 1, 2018

By E. V. Leont'eva, V. R. Vafin, A. G. Kladova, N. L. Medyanik, A. P. Ponomarev

"The thermochemical technology for recovery gold, silver from mature flotation tailings of pyrite ores by two-stage sintering with chlorine-ammonium reagents and leaching of bakes with water is developed. The economic effect of the technology implementation is calculated. KEYWORDS Gold and silver recovery, mature flotation tailings, pyrite ores, chlorine-ammonium reagents, leaching INTRODUCTION The relevance of processing the technogenic reserves of ore mining and concentration wastes accumulated over the long operation periods of mineral deposits is beyond doubt. Hundreds of tons of precious and non-ferrous metals that were not recovered during the primary processing are concentrated in the accumulated wastes. For example, tailing storage facilities (TSF) at the mineral processing plants in the Southern Urals region of Russia hold more than one hundred tons of gold and thousands of tons of silver in the mature flotation tailings (MFT) of copper pyrite ores. Secondary processing of technogenic materials is facilitated by the fact that they are preprocessed — ground and compactly deposited on the surface, but complicated by the low (compared to ores) grade, uneven distribution of the valuable minerals, altered and unstable material composition of the mineral feed. This leads to low recovery rates of valuable metals by conventional physicochemical processing methods. It is necessary to develop innovative methods of deep integrated processing of industrial wastes, based on the study of the material composition of specific technogenic mineral resources and based on ensuring the environmental safety of the resulting secondary waste. MATERIALS AND METHODS The object of this study are the MFT of Uchaly Concentrator in the Republic of Bashkortostan, Russia, which processes copper pyrite and copper-zinc ores. According to the data of particle size, chemical, X-ray phase, and optical microscopic analyzes, samples of the MFT are characterized by considerable particle fineness (the fraction of the size class -41 µm is 89-90%), low grade of gold (1.7-2.0 g/t) and silver (18.0-19.5 g/t), comparable grades of iron (23.0-26.8%) and sulfur (28.1-28.7), but different grades of copper (0.12 - 0.73%) and zinc (0.34-1.26%). The most common mineral in the samples is pyrite (50 - 56%), found in intergrowth with grains of other sulfides (0.1-4%) - sphalerite, tennantite, chalcopyrite, covellite. Quartz and aluminosilicates are the dominant rock minerals (21-36%). Based on the results of the phase analysis, it was established that approximately 70% of the gold in the samples is found in a form that is resistant to cyanidation — it is locked in sulfides (52-56%) and quartz and coated by films. Along with sulfides and rock minerals, common gold and silver minerals (chalcogenides, intermetallides, native gold) in the form of submicro- and nano-sized precipitates are also associated with intergrowth of a complex structure. These features of the material composition allow classifying the MFT of the pyrite ores as a mature feed material and emphasize the need for chemical non-cyanide methods to recover gold and silver from the mature minerals and associations they are found in."

Jan 1, 2018

"The first 90 years of the last century generated a considerable volume of technical literature on the subject of grinding mill power and its prediction. It is therefore surprising that during this time there were no published models for predicting grinding mill power draw which were validated using a wide range of comprehensive industrial scale data.Notwithstanding this lack of data, the majority of models placed limited emphasis on the internal dynamics of mills and relied on simple assumptions which considered the charge to take up a fixed position and shape.Laboratory based studies (Liddell, 1986), and industrial data (Morrell, 1993), showed that these assumptions did not hold over a wide range of operating conditions, and brought into doubt the ability of the (then) existing models to accurately predict grinding mill power draw. Furthermore no model treated AG,SAG and ball mills as a single class of devices whose power draw could be predicted with the same equations.Through a detailed investigation of the charge dynamics, coupled with a large data base of industrial mill power draws, this situation was rectified by the end of the century, by which time a model had been developed and validated, which accurately predicted the power draw of all wet tumbling mills. This paper describes this model and reviews some of the earlier attempts at mill power modelling."

Jan 1, 2003

By Ali Dehghani Ahmad Abady

In Sarcheshmeh Copper Complex, a molybdenite floatation concentrate was produced by selective removal of copper impurities with 7 stages of cleaner floatation banks, that contains around 1% copper and 54.5% molybdenum. Mineralogical studies, physical and chemical characterizations showed that the sample contained 91% molybdenite (MoS2), 2.6% chalcopyrite (CuFeS2), 0.2%Covellite (CuS), 1.6% pyrite (FeS2) and 4.6% other nonmetallic impurities. In the present study, the removal of the copper sulfide was investigated by ferric chloride leaching for achieving a molybdenite concentrate with copper content less than 0.3%. Therefore, the application of response surface methodology (RSM) for modeling and optimization of the influence of three control parameters including ferric chloride (FeCl3) dosage, reaction temperature and reaction time, each varying in five levels, were considered, and the mathematical model for prediction of %Cu removal from molybdenite concentrate was derived. This study showed that RSM could effectively be applied for the modeling of ferric chloride leaching, and finding an economical optimum condition to achieve maximum de-coppering efficiency while consuming minimum leaching reagents. The optimum dissolution conditions to maximize Cu extraction were 200 kg/t for ferric chloride dosage, 120 min for reaction time and 80 °C for reaction temperature with a prediction of 83.20% Cu dissolution. Keywords: molybdenite concentrate, ferric chloride, leaching, response surface methodology (RSM)

Sep 1, 2012

"The first 90 years of the last century generated a considerable volume of technical literature on the subject of grinding mill power and its prediction. It is therefore surprising that during this time there were no published models for predicting grinding mill power draw which were validated using a wide range of comprehensive industrial scale data.Notwithstanding this lack of data, the majority of models placed limited emphasis on the internal dynamics of mills and relied on simple assumptions which considered the charge to take up a fixed position and shape.Laboratory based studies (Liddell, 1986), and industrial data (Morrell, 1993), showed that these assumptions did not hold over a wide range of operating conditions, and brought into doubt the ability of the (then) existing models to accurately predict grinding mill power draw. Furthermore no model treated AG,SAG and ball mills as a single class of devices whose power draw could be predicted with the same equations.Through a detailed investigation of the charge dynamics, coupled with a large data base of industrial mill power draws, this situation was rectified by the end of the century, by which time a model had been developed and validated, which accurately predicted the power draw of all wet tumbling mills. This paper describes this model and reviews some of the earlier attempts at mill power modelling.INTRODUCTIONThe early 1900?s saw the beginnings of published papers which tackled the problem of what influenced the power draw of tumbling mills and what equations (models) were suitable for predicting power draw. This interest continued for the rest of the 20th century and the literature contains many papers that attempted to satisfactorily answer these questions. A common and disappointing theme in the majority of them, however, is the distinct lack of suitable experimentally derived power draw data. This deficiency consequently limited the practical application of many of the attempts at modelling mill power draw. Prior to the early 1990?s some limited data on the power draw of grinding mills in the literature can be found, but as Harris et al (1985) remarked they are ?... too frequently unusable simply because one or more essential variables have been omitted?. The absence of published results, from vigorous experimental testing of the various models, has resulted in a general lack of evaluation of the validity of assumptions and hypotheses that such models contain. Harris et al (1985) however, did make some efforts in attempting to evaluate the performance of various power prediction equations and in so doing further developed a semi-empirical one of their own. However, in using manufacturers? published data, which themselves were undoubtedly generated by proprietary equations of unproven validity, they probably succeeded in generating little more than a consensus of the various errors in these models."

Jan 1, 2003