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By D. W. Smith, J. J. Koskinen, T. A. Enwald, M. E. Ball

"A full-scale demonstration unit of Tampella's LIFAC desulphurization process was tested at SaskPower's Poplar River Power Station Unit No. I. The test program included a series of parametric tests, followed by a 1500 hour operational evaluation. This paper summarizes the results of the test program, and SaskPower's economic evaluation which led to selection of the LlFAC process for SaskPower's 300 MW Shand power station. IntroductionOne of the major influences on the coal mining industry today is public and legislative response to acid rain. When sulphur-bearing fuels such as coal are burned, the sulphur oxidizes to sulphur dioxid e (S00 which, if uncontrolled, enters the atmosphere as one of the by-products of combustion. S02 then combines with water in the air to form an acid and acid rain results. Combustion also produces nitrogen oxides (N0J which can combine with water in the air forming nitrogen based acid , also contributing to acid rain.Acid rain has become a significant international concern. Newspapers have reported on dying forests, dead lakes and crumbling statues. Papers also include articles professing that the physical results of acid rain are vastly overstated. In the United States, a IO-year, Y2-billion dollar study called the National Acid Precipitation Assessment Program (NAPAP) was commissioned to evaluate the effects of acid rain. Even this extensive scientific study did not resolve the controversy. Despite disagreement over the quantitative effects of acid rain, there is no doubt that public concern over the issue is widespread and deeply felt.In response to this concern, legislators throughout the world have reacted with programs that restrict the emission s o f SO, and NO,. To industries involved in the supply and use of coal, the impact of these legislative programs has been extensive. United States power plants will be spending 10 billion dollars in the next decade for flue gas clean-up equipment. Even all this new equipment will not stem the tide of change to low sulphur coals and to “clean “natural gas. The following summarizes legislative actions taken for Canada and the United States."

Jan 1, 1993

By Charles A. Schacht

"Relining, lining maintenance, and ladle repair can represent a significant cost in steelmaking. Therefore, the objective of all steelmaking shops is to minimize this cost and to maximize the lining life. However, the thermomechanical behaviour of the ladle lining is highly complicated and sometimes misunderstood. The ladle design also has a significant influence on lining life. Other factors which have a direct influence on lining life are the shop lining installation practices and manner in which the ladle is used. The objective of this paper is to provide an understanding of the impact of these factors as related to improving the integrity of the lining and increasing lining life.Fundamentals of Steelmaking Ladle Lining Expansion ForcesNumerous studies have been conducted by the author on steelmaking ladles with molten metal capacities ranging from 110 ton s to 350 tons. The steelmaking ladle typically has a sidewall plate with a slight taper and for analytical purposes can be classified as a cylindrical vessel.A typical ladle is described in Figure I. The ladle sidewall lining usually consists of a working lining and a safety lining. Although the type of refractory used in the working lining varies based on the type of steel produced and other metallurgical requirements, the refractories typically used are: 70% alumina brick; direct bond mag-chrome brick; resin bond dolomite brick; and direct bond dolomite brick. Fireclay brick, high alumina brick, or a similar strength brick is used as the safety lining.Normally, the ladle lining is exposed to a through-thickness temperature gradient and restrained by the ladle sidewall plate, is described in Figure 2. The hot face side of the refractory lining develops a compressive thermal force and the ladle sidewall plate develops an equilibrating tensile force. The radial joints open on the cold side of the working lining as the lining joints have little or no tensile strength. A radial compressive load (P) develops between the working lining and the vessel shell due to the thermal restraint imposed on the lining by the shell. The radial compressive load is transferred from the working lining through the safety lining onto the ladle sidewall. Therefore, the safety lining must have the strength to accommodate the radial compressive load (P)."

Jan 1, 1991

By S. S. Rahman, A. Gholami, M. A. Aghighi

"This paper provides a foundation for studying the growth of fractures in presence of other discontinuities and different anisotropies of low permeable hydrocarbon formations and helps to improve the design strategies for multistage fracturing.The multistage fracturing technology has recently been used to exploit low permeable hydrocarbon reservoirs. However, the mechanism of hydraulic fractures interaction and the impact of local heterogeneities on ultimate trajectory of the growing hydraulic fractures are not yet understood in depth. A fully coupled poroelastic Finite Element based model is developed to investigate the mixed mode propagation behaviour of growing hydraulic fractures. This model takes advantage of an explicit representation of the fracture which enables us to take the effects of rock and fluid related parameters into account. Moreover, impact of fracture geometry and leak-off phenomenon is investigated. The refined mesh around the crack provides the added advantage of more detailed stress distribution, pore pressure change and back stress in the vicinity of the fracture and in particular at the fracture tip. The potential deviation propensity of the fractures is evaluated based on the fundamental rule that fractures propagate perpendicular to the direction of the minimum horizontal stress.This study shows that pressurization of transverse hydraulic fractures results in the reorientation of local principal stresses, particularly in vicinity of fracture tips. Variation of flow patterns clearly influences the evolution of shear stress around the fracture tips which will potentially lead to mixed-mode I and II fracturing and consequently, fracture deviation. The presence of local heterogeneities such as preexisting fissures and/or fractures is a main source of such pore pressure induced stress redistribution and reorientation and potential deviation of hydraulic fractures.Most existing models ignore or simplify the effect of pore pressure/stress coupling as well as the fracture geometry and fluid flow within the fracture. Also, the fluid leak-off from the hydraulic fracture into the formation, which is a controlling factor in fracture growth, is often considered using analytical models. Taking advantage of a fully coupled porelastic model along with an explicitly discretized fracture, this study provides a more realistic insight into the complex fracture propagation processes of multistage fracturing operations particularly in presence of reservoir geo-mechanical complexities."

Jan 1, 2015

By M. L. Jeremic

"Hydraulic mining consists of coal erosion by powerful jet s of water from hydraulic monitors operated by remote control. The broken coal is crushed and mixed with water and then transported from the face to the surface using gravity whenever possible. This is a simple, safe and productive method. It will easily satisfy North American productivity standards if the structural features and coal properties are favourable for water jet cutting technology (Kaiser Resources Ltd. , hydraulic mine). General ConsiderationIn open-pit mines, placer mining (Fig. I) and hydroelectric construction projects, hydraulic earth moving techniques have been successfully applied. The stripping and transporting of the overburden has been accomplished by means of large monitor jets augmented by slurry pumps and pipes. An extension of this technique has led to the underground extraction of coal and ores. To date, the method has been most successfully used in undergrond coal mining, because the coal can be easily cut and flushed away by water jets, and the rocks of the roof strata can be left behind. Due to this favourable situation, the hydraulic mining definition only relates to the underground coal mines.At present, there are four basic types of hydraulic mining, which can be defined according to the coal breaking technique used in each case. The methods are briefly discussed below:(1) Coal excavation may be carried out by conventional techniques, but the mine is designed and equipped for the hydraulic transport of the mineral from the working place to surface. Under these circumstances, the coal breaking may not be influenced by the water jet, however it may be indirectly involved. For example, pre-loosening of the coal may be done by water infusion-hydraulic fracturing. Water may also be used to flush the broken coal, which has been excavated either by drilling and blasting or by mechanical cutting, into the transport flumes. In other cases, a mechanical loader may load the coal directly into the hydraulic transport system, without using any water for the extraction process. This hydraulic mining concept is primarily used for hard and impermeable coal, such as anthracite."

Jan 1, 1980

By J. Elbrond

"This paper describes qualitatively the progressive are losses and rock dilution in a mining project from the geological modelling to and including the concentration. A simple theoretical model of the net present value of a deposit, assuming a log-normal grade frequency function, is used to find the pair of decisions on rate of production and cut-off grade, which maximizes the net present value. Various degrees of ore losses and rock dilution are then applied on this optimum, and the resulting decreasing net present values are calculated, as well as the increasing cost of metal and the increasing metal losses as a function of are losses and rock dilution.IntroductionDue to a variety of uncertainties, to inevitable lack of precision in deposit estimation and in mine planning, and due to production constraints, ore losses and rock dilution occur throughout the many phases of a mining project. The phases range from the geological definition of the orebody, over the cut-off grade optimization and decision, over the design of the mining method and the actual mining to the ore dressing, where the final loss of valuable ore into the tailings occurs. Quantification of ore losses and rock dilution are mostly difficult if not simply impossible to obtain. At the end-phase an estimate of the total dilution may be obtained with some degree of precision by observations of the amounts and analysis of concentrate and tailings. It is much more difficult to estimate the total ore losses because the uncertainty of the geological modelling in the initial phase and in the mining phase is very difficult to quantify, despite the use of geostatistics for grade estimation.Many attempts at quantification of ore losses and rock dilution have been made and some examples are shown in Table I. Although they differ widely from each other, it is obvious from these figures that ore losses and rock dilution are significant and have considerable effects on the economical results of a mining operation. Life length, net present value, cost of producing metal and the loss of metal are all affected."

Jan 1, 1994

By C. Chapman, P. Cowx

"INTRODUCTIONTetronics Research and Development Co. Limited has installed several plasma torches for steel heating in continuous caster tundishes. An extensive demonstration program on a 14 tonne tundish reported the following advantages of plasma heating.• close control of steel temperature to ± 5°C;• a reduction of the furnace tapping temperature of up to 20ºC, leading to savings in energy and refractories costs ;• improvement in steel quality, to produce a slab product with an equi-axed crystal structure and a reduced number of large sub-surface slag inclusions;• the virtual elimination of oxygen pickup in the tundish; and• the capability of making ferroalloy trim additions to the tundish to permit a change of steel grade during casting, greatly decreasing inventory costs.The Need for Tundish HeatingIn the continuous casting of steel, the function of the tundish is to transfer the molten metal between the ladle to one or more continuously fed casting moulds. Figure I shows a typical temperature profile of molten steel in the tundish over the first cast cycle. It is observed that a rapid drop in temperature occurs both at the start of the cast, due to the tundish refractories absorbing heat, and also during ladle changeover. In addition, as a result of thermal losses through the ladle sidewalls, there is a gradual decline in the bulk steel temperature over the entire heat cycle. Consequently, in normal tundish operation, it is necessary to cast with a high superheat (25°C to 30°C + above steel liquidus temperature) in order to prevent freeze-up of the strand. Problems of high temperature variation and the potential of the steel solidifying in the tundish are greater for small caster units of low thermal mass . A high steel superheat increases the steelmaking vessel process time and refractory wear and prevents the formation of a uniform equi-axed solidification structure in the cast steel, resulting in centre line segregation and porosity. The large drop in the casting temperature that occurs during unsteady state operation causes an increase in the number of sub-surface inclusions, reducing the value of the product. Accordingly, plasma heating may be employed to maintain the molten steel at an optimum temperature to produce a slab of consistent quality."

Jan 1, 1989

By T. Bhambhani, O. Yavuzkan, D. R. Nagaraj

"Cu ore bodies commonly contain oxide Cu at the surface, with sulfide Cu content increasing with depth. The recovery of oxide Cu minerals by flotation is a longstanding challenge in the minerals industry, especially for high acid-consuming ores which would not be economical for direct acid leaching. Current practice of oxide Cu recovery involves sulfidization (often using controlled potential sulfidization or CPS) using NaSH (or Na2S) followed by flotation using traditional sulfide collectors. CPS has shown to improve recovery of oxide Cu but has the following limitations: a) HSE issues with NaSH, b) high consumption of NaSH, and c) inability to recover certain oxide Cu minerals because they are refractory to sulfidization. The oxide Cu flotation is further complicated by the presence of certain non-sulfide gangue minerals which adversely impact both recovery and selectivity.Over the past eight decades, numerous collectors have been proposed and evaluated for the direct flotation (i.e. without sulfidization) of oxide Cu minerals, the most researched of which is alkyl hydroxamate. While there are numerous publications dealing with the fundamentals of interaction of alkyl hydroxamates with single minerals, there are few publications which discuss the practical aspects of alkyl hydroxamate use in ore flotation, particularly their use with sulfidizing agents. Case studies in this paper include methods to identify optimum combinations of sulfidizing agents and oxide collectors to maximize recovery for various types of ores. It was observed that some ores do not require any sulfidization, while others require at least partial sulfidization to improve efficacy of AHX. Depending upon the ore type and mineralogy, recovery improvement in the range of 5 to 15% units, over and above that achieved with CPS, has been observed with the use of AHX. For ores requiring high dosages of NaSH, it was shown that AHX can be used to reduce the NaSH consumption significantly. The challenges associated with the presence of non-sulfide gangue minerals in oxide copper ores are included, and the use of modifiers to alleviate the associated problems and enhance the performance of AHX is discussed."

Jan 1, 2016

By G. Mihaylov

The basic principles of systems analysis are presented. A model has been designed to determine the location of the Main opening in the presence of three or more stock orebodies. The necessary condition is to find a location for the Collection point which is an essential element in opening up each orebody (stock). The model takes into account the total transportation costs from each orebody to the collection point. Three variants are considered provided that the orefield is divided into two levels at least: - a collection point is designed at every level; - a collection point is designed at the lowest level, i.e. where the so-called concentration level is formed; - the collection point is located at a point between the planes of the two levels; The effect of the depth of mining and mine output on determining the method of opening up the orefield has been analyzed by considering a vertical and/or an inclined shaft. A function has been constructed which allows for investigating in both a static and dynamic regime the capital costs for constructing the whole complex including the shaft. The character of the function does not allow finding the global limits. Therefore, it is of particular importance to specify the limiting conditions. In this case these are the flow capacity of development openings and the shaft. The basic groups of cost and natural indicators for assessing and selecting an optimal technological solution have been systematized. The combined analysis of the two approaches to finding the location of the Main opening and determining the mining method enables us to determine when an inclined shaft is best, and the depth at which opening by a vertical shaft has no alternative. Thus, a transition area is formed for which the selection of an optimal technological solution requires an analysis similar to that proposed in this paper. Conclusions are finally drawn which serve as a basis for determining the areas of application of each opening, including the use of a combined scheme of mine opening. The approach presented can be used in both investigating the possibilities for opening up new orefields and reconstructing existing ones in cases when the mining operations go deeper.

Aug 1, 2013

By John Keay, Douglas R. Shaw, Gregory J. Olson

"The results are presented herein of on-going laboratory investigations of heap bacterial oxidation as a pretreatment method for the recovery of sulfide-encapsulated gold from ore samples of the Rhodes Mining Lahoca deposit, located in northern Hungary. The ore contains just over 2 g Ault and as much as 6% sulfide, mostly as pyrite. Laboratory aerated column tests conducted at Colorado Minerals Research Institute (CMRI) showed that mild to moderate biooxidation of the finely crushed ore occurred rapidly in approximately three months, with cyanide gold recoveries of up to approximately 60%. The results contrast cyanide gold recoveries of less than 30% from non-pretreated ore. Mineralogical examination of biooxidized residues indicated that the mechanism of biooxidation of crushed ore was related to microorganisms following pathways along structural anomalies in the pyrite grains. Such selective biooxidation is an important result to minimize the biooxidation and aeration time and effluent neutralization costs in a commercial operation.IntroductionThis paper describes the development of a heap biooxidation process for the Lahoca gold project The Lahoca deposit is situated in northern Hungary, at the site of a former copper mining area. Lahoca is a large tonnage, relatively shallow, deposit amenable to open-pit mining Lahoca has the potential to produce I 00,000 ounces of gold annually for at least ten years at its minimum reserve base.The laboratory test work conducted initially by Rhodes Mining NL demonstrated that the Lahoca refractory ore is amenable to whole ore and concentrate oxidative pretreatment and cyanidation. Capital and operating costs, however, for such milled ore treatments were considered relatively high. Rhodes Mining subsequently evaluated heap leaching methods, particularly heap biooxidation pretreatment, as a process route that promised superior economics suitable for exploiting lower gold grade refractory ores.This paper focuses on the laboratory column (simulated-heap) biooxidation test work, particularly the proposed mechanism of selective microbial oxidation, wherein only a small amount of the sulfides are oxidized sufficient to allow commercially acceptable gold recoveries by conventional cyanide heap leaching. Selective or minimal biooxidation of sulfides is considered important to minimize biooxidation time and aeration requirements, as well as acid effluent neutralization costs."

Jan 1, 1998

By A. J. Williams

"Whenever a decision is made to bring a mineral deposit into production, the Owner in actual fact has decided to convert substantial sums of capital into productive capacity with the intenti6n of making a profit from such conversion.Escalating costs of construction, frustrating and costly delays in comp1etion, the increasing tempo of technological change and the increasing size and complexity of mineral processing projects have convinced Owners that the best way of implementing their capital must be sought and utilized. This requirement has stimulated a search for ways and means of applying modern management techniques to the design and construction of mineral processing plants.This search by consulting firms has resulted in the evolution of the concept of project management and the development of planning and con trolling techniques with the result that Owners can seek and obtain better assurance that their project objectives will be fulfilled.This paper will attempt to outline how a mineral processing plant can be brought into production through the implementation of project management techniques.Definition And Objectives Of Project ManagementThe design and construction of mineral processing plants is subject to the restraints of three inter-related parameters -Quality, Cost and Time each of which influences and is influenced by the other two.Project management is a technique where the Owner delegates complete responsibility to a single organization for all phases of a project (design, procurement, construction and commissioning) for the above parameters but retains freedom for major decision making. Normally, the consultant under-takes full responsibility for all phases, but partial project management services can be provided when the Owner so desires.The objective of project management is first to devise and define and then to implement a program in which the relationship between the three parameters of Quality, Cost and Time is optimized, i.e., the desired functional and other requirements are attained (but not exceeded) at the lowest practicable overall cost in the shortest practicable time. The measure of success of a project lies in the degree to which this objective is achieved."

Jan 1, 1974

By A. Henk, C. M. Aruffo, K. Fischer

"Geomechanical reservoir modeling offers a valuable tool to predict tectonic stresses, in particular the local perturbations in orientation and/or magnitude which occur at lithological boundaries and faults. The paper presents a workflow for building and calibrating such geomechanical models. The numerical simulations are based on the Finite Element method and can range from field-scale models to smaller, highly detailed submodels of specific fault blocks. The approach considers the reservoir-specific characteristics with respect to subsurface geometry (lithostratigraphic boundaries, faults), mechanical properties and ambient stress field. During the subsequent calibration stage calculated stresses are compared to stress data actually observed in borehole data. Poorly constrained input parameters are iteratively modified within reasonable limits until a satisfactory fit between calculated and measured stresses is achieved. This validated model can then be used for stress predictions between wells and in undrilled parts of the reservoir, respectively. The workflow is applied to two case studies - a large gas field in Northern Germany and a CO2 sequestration project in Australia – to test and illustrate its practical value. INTRODUCTIONDetailed knowledge of the tectonic stress field is crucial for the optimal exploration and use not only of conventional and unconventional hydrocarbon reservoirs, but also for deep geothermal reservoirs, carbon capture and storage (CCS) projects as well as underground mining and nuclear waste repositories. Any reliable stress prediction is hindered by the observation that the magnitude and orientation of the stress field can vary significantly – not only in time, but also in space. Such spatial stress variations comprise all scales, i.e., from the scale of lithospheric plates down to the grain-scale. On the reservoir- and fault blockscale, the local stress field can be influenced by faults and different mechanical properties of lithologies (Sassi & Faure, 1997). The resulting variations in stress magnitude and/or stress orientation are commonly referred to as stress perturbations and give rise to a unique, reservoir-specific stress pattern (Yale, 2003). Thereby, local stress fields can deviate by up to 90° in orientation and several tenth of Megapascal (MPa) in magnitude from regional trends."

Jan 1, 2015

By O. S. Perry, D. F. Kidd

"BEAVERDELL IS IN the Interior Plateau of British Columbia, 25 miles east of Penticton, B.C. In 1897, small but rich silver-bearing veins were found on Wallace Mountain, 2 miles east of Beaverdell. Production from the camp, at first of a modest character, started in 1901 and has never ceased. Over 90 per cent of the values in the ores have been in silver. Remaining values present are in lead, gold, zinc, and cadmium.There have been four principal mines in the camp. A fifth is approaching production. The four mines lie within a northeasterly trending rectangle about 5,000 feet long and 2,000 feet wide, the fifth mine being at the northeast end. From southwest to northeast the mines, with their silver production to Sept. 30, l 955, are: -Wellington Mine - 1,463,948 oz.Sally Mine (includes Rob Roy claim) - 1,930,124 oz.Bell Mine - 3,460,815 oz.Lass Mine - 12,557,956 oz.Other production - 331,252 oz.Total, Beaverdell Camp - 19,744,095 oz.The camp is near the centre of an area geologically mapped in 19 l l by L. Reinecke for the Geological Survey of Canada (1). The rocks of the camp comprise:1. Beaverdell stock of porphyritic quartz monzonite;2. Westkettle batholith of quartz diorite;3. Wallace formation of tuffs and lavas.The Wallace formation borders the east edge of the camp, and has been intruded by the Westkettle batholith. The batholith is the host rock for the orebodies. The Wallace-batholith contact dips gently east. Some of the Beaverdell ores at depth, while in the batholith, are under Wallace formation mapped on the surface above.West of the camp, Reinecke mapped a stock one by one and one-half miles in size, of porphyritic quartz monzonite, which he considered much younger than the Westkettle quartz diorite (I). Recent petrographic work by White and Dolar-Mantuani (3) suggests that in the vicinity of the camp the Westkettle batholith is more quartz monzonite than quartz diorite, and little different in composition from the Beaverdell quartz monzonite. They suggest a consanguinity with the Westkettle batholith."

Jan 1, 1949

By A. Miura, R. Winarko, D. B. Dreisinger

Chalcopyrite leaching in acidic ferric sulfate media at ambient temperature exhibits slow kinetics and poor leaching efficiency, which is typically attributed to surface passivation. Recently, the presence of small amounts of iodide in the leaching media has been reported to significantly accelerate chalcopyrite dissolution. To further explore the behavior of chalcopyrite leaching in the presence of iodide, it is essential to determine the factors that control the leaching kinetics. In this study, we investigated the effect of initial solution potential, iodide concentration, particle size, and temperature on the kinetics of copper extraction from chalcopyrite. The key in the experimental setup was to minimize iodide loss by iodine evaporation and precipitation as cuprous iodide. The former was achieved by performing the leaching tests in fully sealed leaching systems. The latter was achieved by maintaining the solution potential higher than 420 mV (versus Ag/AgCl electrode), where formation of CuI precipitate is possible. The experimental results show that higher solution potential and higher iodide concentration had a pronounced positive effect on the rate of chalcopyrite dissolution. There was no effect associated with particle size, which might be due to the narrow size range tested. The positive effect of increasing temperature only manifested itself when the solution potential was sufficiently high. INTRODUCTION The main challenge of chalcopyrite leaching using ferric ions as the oxidant at ambient temperature is the slow kinetics and poor extraction. The reason for this leaching behavior has been attributed to passivation resulting from formation of insoluble passivating layers on chalcopyrite surfaces, which could be metal-deficient sulfides, elemental sulfur, polysulfides, and iron precipitates (Klauber, 2008). To overcome passivation, technologies using higher temperature and pressure have been developed to leach chalcopyrite concentrates, such as the CESL process (Mayhew, McCoy, Mean, & Woeller, 2013), FLSmidth Rapid Oxidative Leach (ROL) process (Mulligan et al., 2017), Galvanox (Dixon, Mayne, & Baxter, 2008), Albion process (Hourn, Turner, & Hourn, 2012), HydroCopper (Hyvärinen & Hämäläinen, 2005), TPOX (Dreisinger, 2006), and AAC/UBC process (Dreisinger, Dempsey, Steyl, Sole, & Gnoinski, 2003). Even though they are effective in accelerating copper leaching kinetics, those technologies typically have higher capital and operating costs associated with production of concentrates and application of autoclaves. This makes them unsuitable for treating low grade primary copper sulfide ores.

Jan 1, 2019

Grinding with an electrochemically inert grinding media (i.e. high chrome white iron, or Magotteaux’s Duromax® alloys) shifts the pulp potentials to more oxidising conditions, increases the dissolved oxygen content and reduces the EDTA extractable iron concentration when compared with milling with electrochemically active grinding media (forged steel). These changes in pulp chemistry produce cleaner particle surfaces, reduce reagent consumption and increase concentrate grades and recoveries. This paper presents a robust laboratory test program that is able to not only demonstrates these effects but also provide an indication of the magnitude of the improvements that are possible. While laboratory studies are interesting, the proof is in the pudding! So, the paper provides an overview of plant trials conducted at a number of operations around the world, including: Newcrest’s Cadia Operation, Oz Minerals’ Prominent Hill Mine and Glencore’s Ernest Henry Mine. These successful plant trials clearly demonstrate that selection of the right grinding media alloy will yield savings in grinding media consumption and reagent consumption as well as increases in revenue through improved copper, gold and molybdenum recoveries. INTRODUCTION The key to a successful separation in mineral processing is the preparation of particles with adequate liberation under the correct pulp chemical conditions. While the importance of liberation on flotation separations is generally understood and well documented in the literature (Johnson, 1987; Jackson, Sutherland, Gottlieb & Quittner, 1989; Young, Pease, Johnson, & Munro, 1997; Greet and Freeman, 2000), the importance of pulp chemistry is more nebulous, particularly with regard to the impact of grinding media. Extensive work examining the electrochemical interactions between grinding media and sulphide minerals has been completed (for example, Iwasaki, Reid, Lex & Smith, 1983; Natarajan and Iwasaki, 1984; Yelloji Rao and Natarajan, 1989(a); Yelloji Rao and Natarajan, 1989(b)). Broadly, these studies indicate that most sulphide minerals are more noble than the grinding media used during comminution, therefore a galvanic couple between the media and the sulphide mineral(s) exists, which increases the corrosion rate of the grinding media. The corrosion products of the grinding media, iron oxy-hydroxide species, invariably precipitate on to the surfaces of the sulphide minerals thereby affecting their floatability (Johnson, 2002).

Jan 1, 2019

By T. Moyo

Ammoniacal solutions are attractive and effective lixiviants for the dissolution of chalcopyrite, allowing for the formation of stable ammine complexes with copper while rejecting iron. Chalcopyrite dissolution in ammoniacal solutions is reviewed from literature, and results from a recently completed study evaluating it through electrochemical and controlled leach studies are discussed. Ammoniacal leaching of copper ores dates back to 1916 in the leaching of low grade copper ores in the Kennecott leaching plant and in the Calumet and Hecla mines, followed by the commercialisation of the Sherrit Gordon process for the ammoniacal leaching of sulphide copper ores in 1948. Since then ammoniacal leaching has received intermittent focus from researchers with the development of the Anaconda’s Arbiter process and the unsuccessful Escondida process. In these leaching processes, the formation of surface deposits has historically been reported to result in the passivation of the chalcopyrite surfaces, whereas oxygen mass transfer in solutions has been the focus of process design improvements. Results of studies on high grade chalcopyrite material is presented in this paper which show that although a surface deposit was formed, it did not result in the passivation of chalcopyrite in ammoniacal solutions, and that while oxygen transfer is critical, it is not the direct oxidant in the reaction. INTRODUCTION Ammonia and its salts have been used in the hydrometallurgical treatment of non-ferrous metals such as copper, cobalt and nickel from oxide ores. Its chemistry allows for the selective dissolution of desired metals, leaving behind gangue including iron. Chalcopyrite is a copper sulphide ore known to be very stable and hence recalcitrant to many hydrometallurgical processing methods. Thus, the dissolution of chalcopyrite continues to be an attractive area of research. The dissolution of chalcopyrite in ammoniacal solutions is possible due to the stabilisation of copper(I) and copper (II) ions by ammonia in alkaline media. Ammonia has become more attractive as a lixiviant during the present socio-economic climate due to its low toxicity, relatively low cost and ease of regeneration by evaporation (Meng & Han, 1996). Ammonia processes are ideal when the gangue minerals are acid consuming e.g. with calcareous or dolomitic gangue (Paynter, 1973).

Jan 1, 2019

By Laxman M. Amaratunga

"The fine fraction of tailings is usually excluded from the backfill process and generally disposed on the surface in tailings ponds. Because of the ever increasing demand for fine grinding in the extraction process for improved liberation of valuables in the ore, increased production of fines in the tailings has resulted. The negative impact of surface impoundment of tailings on the environment is well known. Amaratunga and Annor (1989) first presented a concept of fine tailings agglomeration for backfill.This paper presents the development of the novel cold-bond tailings agglomeration (CBTA) technology for non-reactive fine gold mill tailings. For cold-bond agglomeration regular portland cement was used as a binder. In order to cut costs, alternate binders such as lime, and blast furnace slag cement were examined. The effects of binder dosage, curing time, and agglomerate size on the fracture load strength of the agglomerate were studied.Fine tailings agglomerates are mixed with coarse tailings or non-agglomerated fine tailings to make high density fill compositions to be used as underground backfill. Alternatively, the agglomerates can be used as aggregates for surface applications. The paper discusses the environmental and operational benefits of this total tailings utilization and disposal technology.IntroductionIn Canadian mines, mill tailings are probably the most commonly used material for backfill. However, only the coarse fraction of tailings is desirable for use as hydraulic fill or high density fills. The fines are disposed on the surface in tailings ponds since they are unsuitable for underground backfilling owing to the following factors:i) slow settling ratesii) longer percolation timeiii) excessive consumption of binder due to drainageiv) poor compactionFor improved value liberation more milling operations have resolved to fine grinding in their comminution circuits. Gold milling operations driven by down stream leaching processes grind their ores excessively fine. In general, gold mines use hardly any tailings for backfilling. This can result in periodic short falls and the need to search for alternate backfill material from other sources. Apparently, the gold producers are the most identifiable sector which suffer from a shortage of backfill materials ( Amaratunga and Annor, 1989)."

Jan 1, 1994

By J. F. K. Brown

MR. T. L. McCALL: Planning ahead in coal-mining is essential, but the question may be raised, just how far ahead can we plan. You can overdo it: chat is, you can get in a rut. Never let planning get a hold on you to chat extent. You must be prepared to deal intelligently with any new conditions that arise, and to apply new discoveries. It may become necessary to abandon ? .your plan, make the best you can of the ground you have developed, and start again, with a new plan. So far as the submarine workings of the Dominion Steel and Coal Company are concerned, we cannot know definitely what lies ahead of us under the sea: we must ?base our tentative plans on assumptions, and, as we meet changing conditions, we must change our plans. In the case of inland mines it is possible to bore in advance, and consequently it is generally possible to set out your plans in advance, block out a section of the mine, and develop to obtain a uniform product for a whole year, or perhaps even longer. MR. J. B. MORROW: While planning in coal mining, we must bear in mind chat the consumer also is planning ahead. Some people will tell you that, in ten years time, the demand is going to be all for pulverized co al; others believe that the field for such fuel is limited. Needless to state, planning for a pulverized-coal market is quite a different matter to planning for a general grade, ore stoker, market. In planning, therefore, our endeavour must be to keep a jump ahead of the work being undertaken by the anthracite producers. This year, they are spending about two million dollars-money contributed, not by the Government, but by the industry itself-in the study and promotion of new and improved ways of burning anthracite. For example, they are perfecting small hot-water heaters, and one they have brought out weighs only about ten pounds. I feel that research of this type must be regarded as an essential part of planning in coal mining. We, in the soft-coal industry, are also planning types of more efficient burning equipment and doing other investigational work.

Jan 1, 1937

By A. Rahimi

The smelting plant at Sarcheshmeh Copper complex commenced working with two reverbatory furnaces, four pierce smith converters, two anode furnace and one holding furnace having a known capacity of 420 metric tons of anodic copper according to the initial design in 1982 (1361 Iranian calendar). During the period from the commencement date up until now, the smelting plant has undergone changes for improvement and enhanced production by substituting holding furnace with another anode furnace, installing the fifth converter and utilizing oxyfuel burners on the ceiling of the reverberatory furnaces. According to the different operational processes in reverberatory, converter and anode furnaces different types of corrosion mechanisms and degradation can be observed in the refractories of copper smelting furnaces. In the case of reverberatory furnaces, the corrosion and degradation of refractories may be factors such as hot corrosion by melt, corrosion attack by the constituents of burning fuel, degradation of sidewalk exposed to mechanical stresses of the feed charge and the hydrostatic pressure exerted by the melt inside the furnace, all of which are due to the unique operational condition governing the reverberatory furnaces environment, i.e. burning fuel atmosphere, charge concentration and combination, furnace temperature, calm melt condition, etc. In the case of converter furnaces, the most likely corrosion and degradation of refractories may be due to the chemical reaction between the melt and degradation of tuyere zones due to sever movement of the melt and mechanical strikes of the punch rod. Also the most essential corrosion reaction occurs around the mouth of the converter because of the mechanical strikes by the cleaning device and thermal heat shock. Other parts inside the furnace are corroded due to the reactions between the fayalite slag and the furnace refractory. In anode furnaces the degradation mechanism is mostly related to the gaseous corrosion (penetration of natural gas or liquid gas inside the refractory structure due to the long period of reduction processes and refining stages. Finally another important factor responsible for destruction of refractories in these furnaces is the copper oxide slag together with the fume constituents of burning fuels.

Jan 1, 2004

By C. A. Biley

"A dedicated iron removal stage was installed at Anglo American Platinum’s Rustenburg Base Metals Refiners (RBMR) during an expansion project which began execution in 2010. The Pressure Iron Removal (PIR) process aims to precipitate iron from a nickel leach solution under medium temperature (145 °C) oxidative conditions using caustic for neutralisation. Since commissioning, the process has been robust in removing iron from the refinery but has shown significant variability in the residues produced. These residues, which are typically comprised of ferrihydrite, hematite or natrojarosite, have varying iron contents and different physical properties which have implications for their filtration and ultimate removal from the refinery. Since over 95% of nickel plated at RBMR passes through the PIR section, volumetric constraints caused by poor filtration performance directly influence nickel production and stabilisation of this process remains central to the continued ramp-up of the refinery to full nameplate capacity. This paper details the development of the PIR process and the journey from concept to implementation. Recent laboratory and plant scale tests have highlighted the importance of the initial phase formed in the autoclave for the ultimate residue requiring filtration and how the feed acid concentration is a critical control parameter. On this basis, a new caustic dosing philosophy was implemented which improved pH control in the autoclave. Further optimisation of the PIR process is on-going.INTRODUCTIONIn 2010, an expansion of Rustenburg Base Metal Refiners (RBMR) to increase nickel production from 21 to 33 ktpa began execution. The management of iron was pivotal in the ultimate configuration in the new circuit and one of the primary differences from the original circuit was the addition of a dedicated iron removal stage: Pressure Iron Removal (PIR). A significant drive for this new unit operation was to facilitate the separation of iron from other leach residues. Not only did this result in a significant decrease in the amount of leach residue but, without the constraints associated with iron precipitation during leaching, has permitted more aggressive leaching conditions and, correspondingly, greater throughput and efficiencies.However, as with many commercial implementations of even mature technologies, the journey from development to implementation has presented challenges for the continued ramp-up of the refinery to full nameplate capacity. Specifically, since all nickel bearing leach solution must pass through the PIR section prior to the nickel purification and recovery circuit, throughput difficulties in the PIR section can directly impact supply of feed to the nickel tank house. Since commissioning, the PIR autoclave has effectively removed iron from the refinery, but has shown significant variation in the solids phases produced in the autoclave. This variation presents difficulties for the filtration of the discharge slurry and represents a key throughput limitation which periodically impacts production. Additionally, the increasing production rates associated with the ramp-up of the refinery have resulted in a significant increase in the required volumetric throughput through the PIR process. This has placed even greater emphasis on improving the stability of the solid phase produced in the autoclave, ultimately targeting an easily filterable residue with high iron content."

Jan 1, 2016

By Z. Pilecki

This work concerns the identification of weak zones in the structure of a rock mass endangered by outburst of gases and rocks in the Rudna copper ore mine at greater depths (approximately 1200 m). A special methodology has been undertaken for the recognition of that threat in the wake of an outburst in the mine in 2009. No similar phenomena have been previously recorded in KGHM Polska Miedz copper ore mines. The research described in this paper was carried out in the new part of the deposit prepared for mining. Geophysical methods were used: seismic tomography and borehole ground penetrating radar (BGPR), along with particular identifications using geological engineering methods. In the researched area, Permian layers of sandstone and shale clay (Weissliegendes formation) and of Zechstein dolomite (top of Rotliegend formation) and anhydrite occur in the copper ore deposit. The rock layers are characterized by variable thickness and intensity of mineralization, varying internal structure, and local fracturing containing different gases and water. It is assumed that accumulation of gases occurs in the tectonically fractured dolomite. The study was focused on the recognition of the structure and properties of the dolomite layer lying directly within the roof of excavations. The first tests were performed with seismic tomography for the recognition of anomalous changes in the elastic properties of the rock mass. The results of these studies were used to design a control borehole for a detailed geological engineering assessment and BGPR surveys with 100MHz antennas. Seismic tomography enabled the identification of changes in Pwave and S-wave velocity, the Vp/Vs ratio, dynamic Poisson's ratio and dynamic Young's modulus. It was clear that seismic anomalies required verification by other methods. The BGPR survey was performed in a specially designed borehole, passing through the selected seismic anomalies. While the borehole was being drilled, the outflow of gases was identified, with varying amounts of CH4, CO2, and H2S detected, as well as water outflow. The results of BGPR confirmed the location of a reservoir of water and gases, about 30 m in length, found in layer of dolomite. The direct cause of the BGPR anomaly was assumed to be intensive fracturing, a greater content of clay material in the dolomite, and the presence of water in the fractured zone. The BGPR image was correlated with information on lithology, fracturing based on the RQD index and additional information acquired during drilling about water and gases surveys and other symptoms. The achieved results also showed a very strong correlation between the location of the zone containing gases and water and the anomalous S-wave velocity and field of dynamic Poisson?s ratio, and to a lesser extent other seismic parameters. It was found that the other measured seismic anomalies may be of the same nature as those identified in the control borehole and accordingly will require the implementation of detailed identification. The performed tests have also shown the usefulness of geophysical methods to identify geodynamic hazards under the geological and mining conditions of the copper ore deposit in the Rudna mine.

Aug 1, 2013