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By F. Hosseini

Shaping of metals by thixoforming relies on the unusual flow behavior of semisolid slurries containing nondendritic solid phase. The Flow behavior of metallic alloys containing both solid and liquid phases is investigated in the low solid fraction range (, 55%). This behavior depends on both the solid fraction and the shear rate. Four different shear rates is applied using back extrusion technique and flow stress versus true strain in different solid fraction is compared. It is well accepted that the flow stress s of alloys in their semi-solid state obeys to a thixotropic behavior, due to agglomeration and dissagglomeration phenomena during forming. The load-displacement curves produced from the tests may show an initial peak, believed to originate from a skeletal structure which rapidly breaks down under shear. Apparent viscosity obtained from this method is compared with other works and the proper power law of pseudo plastic state is introduced.

Oct 1, 2011

By Walter K. (Cory) Conrad

Two pumping tests in the Chilson Member of the lower Lakota Formation were completed at nearly the same location in 1979 and 2008. The 1979 test consisted of a pumping well and several surrounding observation wells penetrating the full 55-m thickness of the aquifer. The 2008 test consisted of a pumping well and three surrounding observation wells screened over 10 m in one of the known uranium ore horizons in the lower portion of the Lakota penetrated only about 3 meters of the more than 55-m thick lower Lakota aquifer. The average transmissivity and storativity values determined from the 1979 tests were 17.6 m2/day and 1.8 x 10-4, respectively. Comparing median transmissivity of 13.9 m2/day and storativity of 1.2 x 10-4 determined in the 2008 test to the 1979 test, the new aquifer parameters for the lower Lakota are respectively about 80 and 70 percent of the 1979 results. Because transmissivity and storativity depend on aquifer thickness, comparing the results suggests that there may be some scaling effect between the tests due to the differing lengths of screened intervals. However, the effect cannot be predicted by calculations such as relative screen lengths or open intervals to the formation, or sandstone versus shale thicknesses on geophysical logs. The scaling effect is attributed to partial disconnection between the lower and upper portions of the Lakota Formation aquifer by locally continuous shale interbeds. Suggestions to resolve this scaling issue are presented.

Aug 1, 2010

By Trevor McGiddy

"Australia's prosperity relies significantly on income generated from exports of resources and agricultural products. In 1989-1990, coal was Australia's most valuable export commodity, contributing. A $5.7 billion or 14% of all export income.The abundance and quality of its coal resources and the proximity of Australia to the rapidly developing economies of Southeast Asia were significant factors that encouraged export-oriented growth and investment and will continue to do so. On the other hand, the 1980shighlighted the sensitivity of the industry to international changes in supply and demand, currency and socio-political forces.Following many years of disappointing returns for investors, mainly as a result of falling Australian dollar coal prices, resolve will be necessary to maintain competitiveness with resource-rich nations. In recent years, operators, unions and governments have begun to embark on a long overdue rationalization of domestic issues in a bid to increase productivity and reduce costs.The nature of mining operations is also changing; deeper surface mines and the growth of longwall mining will require the development of new technology and skills. Other challenges emerging from the international environmental debate will require that Australia responds appropriately to demands for cleaner fuels, energy efficiency and environmental responsibility.The future development of the Australian coal industry will therefore be influenced by its own ability to become more efficient and mature in the production of quality coal products and through rational international response to environmental questions."

Jan 1, 1992

By A. MacKinnon, P. W. Kingston, W. F. Caley

"Wollastonite (CaSiO3]) is experiencing increased usage in a variety of applications, such as fillers in paints, plastics and resins, as an extender to replace both non-fibrous and fibrous materials (e.g. asbestos), and in the glass and ceramics industries. Significant new deposits of wollastonite have been discovered in Marmora Township, about 175 km northeast of Toronto. The geological setting of these large-tonnage. High grade deposits has recently been investigated to assess the possibility of their development. A preliminary study of the chemistry, as well as the mineralogy of six occurrences is presented. Based upon this information, it is suggested that several of the deposits have an excellent development potential.INTRODUCTIONWollastonite is an anhydrous calcium metasilicate (CaSiO3), with a theoretical composition of 48.3% CaO and 51.7% SiO2; the calcium may be partially replaced by iron, manganese, magnesium, and strontium. Commonly associated minerals include diopside, tremolite, idocrase, grossularite andradite, quartz, and calcite. Wollastonite forms as a contact metamorphic mineral within impure limestone near intrusive bodies of granite, or other acidic rocks, as the result of metasomatism of calcareous sedimentary rocks, or by the crystallization of certain magmas (e.g. carbonautes). Generally, the reaction of calcite with silica to produce wollastonite occurs when siliceous hydrothermal fluids from a granitic intrusion or primary silica in the limestone/marble react with calcite in limestone at temperatures between 450°C and 600°C."

Jan 1, 1989

By P. R. A. Andrews, R. K. Collings

"SUMMARYIn cooperation with the Ontario Ministry of Natural Resources, selected deposits of Potsdam sandstone in the Ottawa-Kingston area were core-drilled and evaluated by CANMET as potential glass and foundry sand. Analyses of cores ranged from 84.6 to 98.5% Si02, 0.09 to 0.65% Fe203' and 0.07 to 2.10% A12°3' The cores were largely composed of white to grey, relatively tough sandstone. Impurities included iron as pyrite, iron oxides and staining on the quartz grains; carbonates as calcite; and aluminum oxide as feldspar. Beneficiation included size reduction to grain size, about 600 um, by jaw, roll and cone crushers, and grinding in a muller-mixer. Removal of fines was achieved by attrition scrubbing and washing. Further removal of impurities was achieved by reverse flotation of pyrite, iron oxide, feldspar, and carbonate minerals employing both anionic and cationic collectors. Flotation resulted in a substantial improvement in the quality of most samples; analyses of quartz concentrates showed 98.5 to 99.7% Sial> 0.022 to 0.156% Fe203' and 0.07 to 0.62% A1203. Further reduction of the iron content by wet magnetic separation and acid leaching also was investigated. On the basis of the samples submitted, sands/ones from six of the seven deposits studied have potential as sources of glass sand. Foundry sand tests were inconclusive because of the small quantities available for study."

Jan 1, 1986

By James F. Archibald

Testing has been accomplished to substantiate recent laboratory trials which have demonstrated that thin liner membranes, applied to rock core samples, can significantly enhance the structural performance of such rock materials. A range of Canadian polymer liner materials (MineguardTM, RockguardTM and RockWebTM) have been tested side-by-side to evaluate strength and other physical property improvements generated for two highly homogeneous, though differently sourced, granodioritic rock materials. Tests were conducted on physically similar core materials, utilizing 104 to 113 samples of each respective rock type. For both rock sample populations, cores were coated using linings at thicknesses varying between 1 and 7.3 mm, typical of the application range currently used underground by mines contemplating use of such membrane agents. Results of rock failure tests, following application of passive lining covers upon the very large sample populations of each rock type, have indicated that noticeable strength improvement and enhancement of post-yield failure characteristics can be developed by the entire range of spray-on liner materials evaluated. It is shown that all of the tested liner agent materials currently available can and do act to positively reinforce rock support capabilities of modeled core pillars. Where liner materials can be effectively placed underground, it is anticipated that they may provide similar benefit and be successfully used in partial replacement for either screen or shotcrete to provide advantageous area support for rock.

May 1, 2001

By R. R. Potter

"New Brunswick became a separate province in 1784, shortly after the influx of a large number of Loyalists from the United States. Many of these people settled along the Saint John River, including the area of excellent farmland near the present town of Woodstock. There were indications that some of these early settlers recognized iron formations in the vicinity of Woodstock about 1820, however the nature of the deposits was not known until 1836 when Dr. C. T. Jackson, a geologist commissioned by the State of Maine, investigated the mineral potential of the area. Jackson(1) described the ""ore"" as compact red hematite yielding 44 per cent pure metallic iron, and suggested that sizable tonnages may be present. It was about this time that an extensive limonite deposit was found in north-central Maine, near Mt. Katahdin. Other iron depostis were found in the Nictaux area of Nova Scotia, and a few years later at Londonderry* (Fig. 1). In 1837, Richard Ketchum of Jacksonville, on whose land iron ores had been found, petitioned the provincial government to incorporate a company. After much study, the York and Carleton Mining Company Bill was passed on March 15, 184 7. Several other petitions were passed permitting the company to construct roads, obtain woodland, etc. (2) . The first blast furnace was erected in 1848 on the west bank of the Saint John River near the mouth of Lanes Creek."

Jan 1, 1999

By J. P. Norrie

The presence of copper-bearing rocks in the Coppermine River area of Arctic Canada has long been known. Word of this was probably circulated along the Arctic and Hudson Bay coasts by the Eskimo, who no doubt traded articles made from native copper among themselves. It is not known whether any of these ever reached the southern shores of Hudson bay. The Indians, also, knew of the occurrence of copper here, as they served as guides to Hearne when he made a successful trip over land from Hudson bay to the Coppermine river. The possible commercial importance of these copper deposits was early appreciated by the Hudson's Bay Company, who on December 7th, 1770, despatched Samuel Hearne from Fort Prince of Wales, now Fort Churchill, to investigate them. He reached the then unnamed river at a point forty miles from its mouth on July 14th, 1771, and after surveying the river to its mouth and naming it the Coppermine, he retraced his steps to Fort Churchill by an overland route. Hearne's expedition was probably the most remarkable and arduous ever attempted in Arctic exploration, but the actual value derived from the trip was entirely out of proportion with the hardships he must have suffered. He verified the occurrence of native copper, but his astronomical and other observations were of little value. Until 1912 no concerted effort was made to obtain any definite information as to the geology and economic value of the Copper-mine deposits.

Jan 1, 1931

By Sadan Kelebek, S. O. Fekete, Gerhard W. Heinrich, Peter F. Wells

"For many years, rejection of pyrrhotite at the milling stage has been a viable method for sulphur dioxide abatement. Pyrrhotite rejection options have included the use of selective pyrrhotite depressants in flotation; a depressant which has recently come into use is diethylenetriamine (DETA). This reagent has been the subject of recent research and development efforts in the processing of nickel-copper sulphide ores.In the present study, adsorption trends for DETA have been monitored under the dynamic conditions of flotation using a spectrophotometric method which has been adopted for this purpose at Falconbridge Limited. The results indicate that the adsorption of DETA is quite fast and in the majority of cases, accounts for the disappearance of 75-95 % of this reagent from pulp's liquid phase. The adsorption decreases linearly with an increase in the DET A dosage from 100 git to 600 git. The tailings produced in flotation tests were subjected to washing with deionized water at 60 °C to examine the desorption of DET A. These results indicate that the amount desorbed increases with increasing DETA dosage used during flotation but is less than 7 per cent of that adsorbed. It was found that adsorption of DETA alone, even at relatively high levels, does not always cause depression of pyrrhotite. A new combination of reagents identified in the metallurgical laboratories of Falconbridge Limited utilizes sulphur dioxide with DETA. These reagents together are capable of efficient depression of pyrrhotite on a consistent basis."

Jan 1, 1995

By K. John

"THE most recent estimate of minteable coal reserves in Saskatchewan was made by the Federal Royal Commission on Coal (1944- 6). Saskatchewan was then estimated to have some 24 per cent of the Canadian reserves and two-thirds of this is located in what is called the Souris-Estevan area, which lies in the southeast corner of the Province and border's on the International boundary. It is also estimated that there are some 61/2 million thousand-tons in this area of lignite coal which grades 8,000 B.t.u. or less and has a moisture content ranging from 30 to 33 per cent. Ownership of coal rights in the Province is widely dispersed between the Crown, individuals, and corporations, and a recent survey disclosed that 40 percent of ownership was vested in the Crown and 60 per cent in private individuals and corporations. Coal rights on Crown lands may be leased at an annual rental of $ 1.00 an acre. Under such leases, a royalty of 5 cents a ton is levied on all coal mined. A royalty of 7 cents a ton is levied on coal produced from lands where mineral rights were purchased from the Federal Government prior to the transfer of jurisdiction over natural resources to the Province, in 1931. An annual mineral tax of 50 cents per acre has also been imposed by the Provincial Government on all coals within a defined producing areas."

Jan 1, 1952

By J. P. Cooney

Placer Dome is learning from experience in Latin America, Asia and Africa, as well as in North America, that contributing effectively to sustainable human progress in the areas of its operations presents unending challenges to think creatively, communicate effectively and remain culturally sensitive. People must be better off in terms of their economic circumstances, their social conditions and the quality of their natural environment not only during the life of the mines, but after mines close. Stakeholders, all those who are directly or indirectly affected by a mining project, should be able to participate in decisions which affect them. The development of sustainability strategies, the monitoring of sustainability performance and the implementation of sustainability programs are best done in partnerships with governments, communities, nongovernmental organizations and multilateral development institutions. Ultimately, the success, if not the survival of mining, will depend on our ability to get the sustainability equation correct.

Jan 1, 2000

By V. G. Papangelakis, G. P. Demopoulos

"Recovery of gold from refractory ores and concentrates presently constitutes one of the most important, challenging, and exciting areas of R&D activity in the gold processing industry. New technologies are being tested for the treatment of refractory gold materials, some of which have been advanced to the level of commercial operation. In this paper, some recent technological developments in the hydrometallurgical processing of pyritic matrix-refractory gold ores are highlighted. Key operational steps of each of the alternate hydrometallurgical technologies are analyzed and potential advantages and drawbacks are identified. The processes which are reviewed are: hydro chemical oxidation, biochemical oxidation and pressure oxidation. INTRODUCTIONOver the years the term ""refractory"" has been applied in gold ore processing to denote situations in which straightforward cyanidation failed to yield high gold recoveries. A number of mineralogical and chemical factors may be responsible for this ""refractoriness"" problem. A systematic classification of the different options for their treatment has been discussed in a recent review paper. In this paper, the pretreatment of the submicroscopic gold encapsulated within the matrix of pyrite and arsenopyrite minerals is considered. This type of gold is the ultimate refractory material because complete breakdown by reaction of the host mineral structure is required.The method which has been traditionally applied for the treatment of pyritic-type refractory gold ores is an oxidation roast (single stage or double stage depending on the As content) of a flotation concentrate to produce a porous calcine, the latter being more amenable to cyanidation. Despite its established practice, oxidation roasting is not considered particularly attractive with today's standards for high product recovery and clean environment. Roasting is known to be very sensitive to heating parameters and feed composition and deviation from optimum conditions can result in reduction in permeability which is translated to incomplete gold liberation."

Jan 1, 1989

By F. Duan, J. Pfarr, J. M. Goris

"The U.S. Bureau of Mines, in cooperation with the Homestake Mining Co. and the University of Utah, is conducting a field demonstration to evaluate the behaviour of rock masses supported with cable bolts. One of two rock masses being studied is supported with both conventional and birdcage cables. This rock mass is located between the 6500 and 6650 levels of the 45-48N stope, 21 ledge. The second rock mass is the hanging wall of the D-limb stope between the 3500 and 3650 levels near the Ross Shaft and is supported with conventional cables. The primary objectives of the project are to monitor the behaviour of the two rock masses during mining using extensometers and cable support strain gauges, after which the rock will be modelled using the finite-element code UTAH III. Field data will be used to verify the modelling. In addition, a comparison between the effectiveness of conventional and birdcage cables will be made.45-48N StopeThe 45-48N stope is located in the 21 ledge between the 6500 and 6650 levels and contains about 233 000 short tons of mineable ore. The orebody lies within the Homestake Formation and is very irregular being approximately 200 ft long and 75 ft wide. Between the 6500 and 6650 levels, it dips from 35 degrees to 60 degrees east with a near-vertical plunge to the south. Mineralization is characterized by arsenopyrite and pyrrhotite with minor gold. The contact between the Homestake and the overlying Ellison Formation creates a plane of weakness along localized graphitic layers. The footwall dips at approximately 60 degrees but between 100 ft and 120 ft above the 6650 level , the hanging wall flattens to almost 20 degrees causing a significant mining problem."

Jan 1, 1991

By D. Lauzon, H. de Ruiter

"In 1988a decision was taken to design and install a computerized mine monitoring and control system. This system had to monitor and control all pumping and ventilation underground. The operation of the mine air heating, using waste heat from the mine water and compressors, was to be part of the system. It ultimately also had to interface with the four existing Canadian General Electric Series 3 PLC's which controlled the No .3 shaft loading pockets. Beside operational control and trouble shooting, the system is a valuable tool in energy management and ultimate savings are estimated at $50,000 per year.The final equipment selection was a General Electric Series Six PLC on surface with a total of 17 Series One Plus and Juniors PLC located underground. Data is transferred through a two-pair shielded cable using modems. Both analog and digital functions are being utilized.The basic monitoring and control system was commissioned during 1989and, due to a higher level of technology today, further improvements have been planned for the future. The system was designed by Walter Dow together with Gordon Champion of D.G. Champion Engineering Ltd. of Toronto. Advice for the ventilation part of the project was obtained from Maurice White, Independent Ventilation Consultant.The Ministry of Energy, Mines and Resources and the Ministry of Energy of Ontario approved this project together with the waste heat recovery project to qualify for a grant of$135,000 under the Enerdemo-Canada program.IntroductionThe Macassa mine is a narrow vein gold mine situated about 2 km west of the town of Kirkland Lake in northeast Ontario. The mine has been in continuous operation since 1933 and a total of about 3.0 million ounces have been recovered out of 6.6 million tons of ore ."

Jan 1, 1991

By Marc Lavigne

"The Lac Knife graphite deposit was estimated, as part of a feasibility study, using a geostatistical ore reserve estimation method: ordinary kriging. Based on the geology and its interpretation, the results of a variogram study, and the statistical parameters of the grade distribution of the core samples and the composites through the mineralization, the deposit was divided into three separate zones (west, centre and east), and each of these zones was then analyzed and kriged independently.The geological ore reserve estimation results of ordinary kriging are compared to the results of a conventional method (sections) used previously. The two methods gave almost similar reserve figures. The conventional method provided a +2% estimation for tonnage and + 10% for grade because it ignored the spatial relation between sections and samples, and ordinary kriging gave a more accurate longitudinal definition of the deposit.Finally, the paper concludes with the advantages of proceeding with ordinary kriging, namely: higher flexibility (change of cut-off grade), better deposit resolution and enhanced selectivity for the design of the open pit.IntroductionWithin the context of a complete feasibility study for the Société d' Exploration Minière Mazarin Inc., specialists of the Mines and Geology Division of Roche Ltd., Consulting Group, defined a modelling method appropriate to the graphite deposit of the Lac Knife property near Fennont. Many patterns were considered. Based on the geology of this deposit, the planned mining method, the statistical parameters of grade distribution and the variogram study, the process of reserve estimation retained was to use the ordinary kriging in a selective way. It was required because the geometry of the deposit is such that it was unthinkable to apply ordinary kriging without restrictions.This paper gives a detailed explanation of the observations and interrogations which led to the choice of this ore reserve estimation method, and the calculation procedure itself."

Jan 1, 1991

By Douglas G. Jay

"Transfer points on belt conveyors have long been a source of problems for both designers and users. Conveyors are generally given a low priority in new equipment layout, thus designers are often forced to compromise due to space limitations. Consequently, for this reason as well as for reasons of initial economics, many conveyors are supplied with less than adequate transfer points.Although not intended as a cure-all, a number of existing installations have been modified with the result that spillage has been reduced to a minimum and belt life has been extended. The most striking modification consisted of replacing conventional rigid frame idlers with five-roll catenary idlers.Although catenary idlers can be traced back to the early 1900s in North America, with a patent having been issued in Washington, D.C. as early as May 29, 1907, the practical application of this concept has only recently reached North America. Major installations include applications at St. Lawrence Cement in Oakville and Iron Ore Company of Canada in Sept-Iles, as well as belt conveyors at Stelco's Nanticoke plant and yard conveyors at Syncrude in Alberta. These installations were part of major capital expenditures for new facilities and included complete conveyor systems.However, this article will discuss the use of catenary idlers on existing rigid frame conveyors for the purpose of absorbing the energy of falling lumps, protecting conveyor belts and reducing spillage. We will deal specifically with an installation at Inco Metals Company in Sudbury, Ontario, where approximately 40 five-roll catenary idlers were installed on a 42-in.-wide belt conveyor handling ore located under the railroad car dumper at the Clarabelle Mill. Before-and-after photographs clearly show the tremendous improvement in the cleanliness of the location, and the savings in maintenance costs and extended belt life have prompted Inco to consider modifying other conveyors."

Jan 1, 1982

By Xu Feng, Han Shufeng, Zhu Bin, Wang Mingming

Due to urban subway tunnels mostly built in the cities with highly density buildings, the geological and construction conditions is complex, especially certain sections of the subway tunnel will pass through from the foundation of the overpass, therefore the stability and surface deformation control of that section’s tunnel excavation is particularly important. Taking Xi'an Metro Line Three interval tunnel as a research object, we have used FLAC3D simulation to analyze the tunnel’s surrounding soil deformation and tunnel lining stress distribution under bridge foundation with shallow buried covered excavation method. Analysis results show: (1) After the excavation of the tunnel right line, due to the bias of the upper bridge foundation the right of the tunnel showed relatively large deformation. In order to ensure the construction safety, we recommended using the grouting anchor reinforcement on the right side wall to further control the deformation zone. (2) The maximum vertical displacement of the ground occurred in the right wall of the tunnel portion which was due to the intensity of soil outside the grouting range of the arch is low, as a result the deformation is larger; this position requires special attention, strengthening the monitoring measurements of this part is necessary to avoid the large deformation and other adverse effects of the upper portion of bridge foundation. (3) The maximum vertical force area of the initial lining of the tunnel is in the middle of the side wall, while the second lining in this part of forces is smaller, thus at the beginning of the construction of the liner, attention should be paid to this area. On-site grouting or steel bracing reinforce support may be used if necessary.

Jan 1, 2015

By W. A. Crosby, W. K. Smith, K. L. McDonald

"IntroductionThis paper describes how the introduction of two blasting techniques and the resuItant development of new dragline digging methods have increased the productivity of single- and double-seam dragline operations at the Rietspruit opencast mine.LocationRietspruit , one of South Africa's largest opencast strip mines, is situated some 11 5 kilometres east of Johannesburg in the Witbank coal field.BusinessRietspruit is a joint venture between Transvaal Consolidate d Land and Exploration Company (T.C.L.) and Shell, South Africa. Rietspruit is administered and managed by Rand Mines, the Mining division of Barlow Rand, transportation and marketing being the responsibility of Shell. The total saleable coal product, approximately 5,5 million tons per annum, is exported via Richards Bay.Presplitting and Throw BlastingPresplitting was initially introduced in September 1980, as a means of dewatering t he overburden and mid burden to facilitate the use of dry-mix explosives a s opposed to slurry explosives.The utilization of the throw blasting technique arose as a direct result of observed ground movement after the successful introduction of presplitting. The first trials commenced in March 1981 on the double-seam operation. The methods, economics and resulting advantages are fully described elsewhere. A brief description follows.Method of PresplittingAfter determining the desired presplit line, 250-mm holes are drilled to top of coal at 4-m to 6-m intervals, dependent on the competency of the rock overlying the coal. A single 60-kg charge of slurry explosives is located at the bottom of each hole, no tamping is used and all the holes are detonated simultaneously. The results are a competent, straight, vertical highwall. This enables accurate control of the first row of blast holes closest to the highwall, which is a prime requisite for successful throw blasting."

Jan 1, 1983

By John E. Udd

"Mining research at CANMET is delivered by the Mining Research Laboratories Division (MRL), with facilities in Sydney, Nova Scotia; Bells Comers, Elliot Lake, and Sudbury, Ontario; and Val d'Or, Quebec. This paper gives an overview of the work of the Division as of early 1993. An addendum, at the end of this paper, describes the organizational changes that will take place in April 1994. IntroductionCANMET, the acronym for the Canada Centre for Mineral and Energy Technology, is the name by which the organization founded in 1907 as the federal Mines Branch is presently known. The name was changed in 1974, in order to give recognition to the importance of both minerals and energy technologies in the activities of the Branch. Further reorganizations have taken place since 1987. As a result of these, CANMET has assumed the status of a Sector (equivalent to the Geological Survey of Canada) and has been organized into four branches.The organization as a whole functions in an environment of semi-matrix management. Some of the ""line"" Divisions report to Directors-General for the appropriate branches while other, larger divisions, report directly to the Assistant Deputy Minister.The second dimension of the organizational matrix is composed of a number of ""staff' divisions which report to the DirectorGeneral for Policy and Planning. Each of these Divisions performs a function which is common to all of the ""line"" divisions. For example, the Research Projects Office is responsible for monitoring the range of research activities of CANMET and for recommending allocations of funds for both research contracts and operating budgets. The Library and Documentation Services Division is responsible for CANMET publications and information services. Likewise, the Engineering and Technical Services Division provides support through, among other services, the construction of specialized laboratory equipment."

Jan 1, 1994

By Jose Alberto Gonzalez, Said Sharif Mahboob, Jeffrey L. Shepherd

"During the industrial electrowinning of zinc, uneven growth can cause short-circuits and make the deposits more sensitive to the presence of impurities that can significantly impact current efficiency. To produce levelled zinc deposits, additives such as glue, licorice and sodium silicate are often added to the electrolyte. Even in the presence of additives, uneven zinc growth still takes place because of the combination of hydrodynamic and electrolysis conditions in the cell house. Recent advancements in imaging spectroscopy and scaling analysis have opened an avenue to further study the effects of additives on zinc growth morphology. In this study, Atomic Force Microscopy (AFM) and scaling analysis have been used to monitor zinc growth characteristics including roughness, periodicity, aspect ratios and growth mechanisms as a function of electrolyte composition as well as deposition time. Zinc was electrodeposited from an industrial electrolyte containing a host of additives onto an aluminum cathode with a platinum wire serving as the anode. AFM images of the samples were collected to obtain 3D topographical information on which scaling analysis was performed to extract details on root-mean-squared (rms) roughness, periodicity (grain size), aspect ratio of surface features and growth mechanism. This analysis provided information on the mechanism by which the previously mentioned variables can impact short term growth and also provided a prediction of expected growth at long deposition times.INTRODUCTIONElectrowinning is one of the final stages in the industrial production of zinc metal. It is during this process where dissolved zinc ions undergo electro-reduction from an acidic electrolyte onto an aluminum cathode and are later recovered by stripping the zinc metal from the substrate. However, due to the nature of zinc growth as well as the various operating conditions, zinc deposition may occur unevenly, sometimes causing short-circuits that can cause electrode damage and reduced zinc production."

Jan 1, 2016