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By J. M. Turnbull

THE primary objective of the young graduate, after the war, will be to obtain a suitable position within the Industry, with adequate pay and opportunity to advance. The positions available to meet this demand will depend on the magnitude and organization of the industry. The size of the mining industry, in particular, will depend on a number of factors, including depletion; new discoveries of mineral deposits; beneficiation of new kinds of mineral deposits, based on research; technical improvements, also based on research, enabling the mining of lower grade deposits; and complex social factors. The organization of the industry will depend on its control and management, which may be greatly affected by social conditions and changes, and may include a wider or a narrower use of technical services. The corresponding training or qualifications of graduates, to meet these conditions, calls for a consideration of educational requirements and facilities in relation to the conditions that are likely to occur. Some forecast of the probable future of the Industry, after the war, based on consideration of. the above factors, is necessary as a basis of discussion, since the graduate must find his place in the industry of that time, and find his work in maintaining and improving it, within the existent social framework. Social factors are pressing and? important at present and their future impact is uncertain. In considering these, a few quotations and extracts may be in order. "A new economic order, based on free access to the sources of raw materials, means free use of the world's wealth by all civilized nations" (The Pope. Also advocated by Churchill and Roosevelt in the Atlantic Charter). "Every citizen should have a voice in the conduct of business or industry which is ?carried on by means of his labour" (Archbishop of Canterbury).

Jan 1, 1943

By M. Jahazi, M. Brochu

This paper describes the advantages/disadvantages of electron beam freeforming using two different types of filler metal: (1) brazing paste and (2) solid wire. Sound buildups were obtained from both filler metal. The freeforms produced with the brazing paste showed a certain level of porosity, which was reduced by successive melting. In comparison, the solid wire buildup was practically free of pore. When compared with the solid wire filler, the brazing paste produced narrower buildups but a larger scattering of the width.

Jan 1, 2004

By C. W. Hancher, B. D. Patton, W. W. Pitt

"There are a number of nitrate-containing wastewater sources, as concentrated as 30 wt % NO3 and as large as 2000 m3/day, in the nuclear fuel cycle. The biological reduction of nitrate in waste water to gaseous nitrogen, accompanied by the oxidation of a nutrient carbon source to gaseous carbon dioxide, is an ecologically sound and cost-effective method of nitrate waste disposal. These nitrate-containing wastewater sources can be successfully biologically denitrified to meet discharge standards in the range of 10 to 20 g N(NO3-)/m3 by the use of a fluidized bed bioreactor. The denitrification bacteria are a mixed culture derived from garden soil; the major strain is Pseudomonas. In the fluidized-bed bioreactor, the bacteria are allowed to attach to 0.25- to 0.50-mm-diam. coal fluidization particles, which are then fluidized by the upward flow of influent wastewater. Maintaining the bacteria-to-coal weight ratio at approximately 1:10 results in a bioreactor bacteria loading of greater than 20,000 g/m3,This paper describes the results of a bio denitrification R&D program based on the use of fluidized bioreactors capable of operating at nitrate levels of up to 7000 g/m3 and achieving denitrification rates as high as 80 g N(N03-) per day per litre of empty bioreactor volume. IntroductionThe discharge of wastewater containing nitrate at concentrations greater than stipulated by the Environmental Protection Agency (EPA) creates an environmental hazard and constitutes a civil and/ or criminal legal liability.(I.2) At present, we have three options: (1) recycle and reuse of nitrate streams the total economic and technical balance should be Closely examined; (2) use of an alternative acid, which may pose an entirely different set of problems ; or (3) disposal of nonreusable nitrate sources by an environmentally acceptable procedure."

Jan 1, 1980

By J. Bigu, M. G. Grenier

"Dust size distribution and aerosol size distribution measurements have been carried out in several Canadian underground uranium mines. In addition, dust samples have been analyzed for long-lived radioactive products of the U-238 and Th-232 natural decay chains using ex-spectroscopy and -y-spectroscopy techniques.From the data collected one may summarize: (a) most airborne particulates are of size below I u-m and 50% by mass are found above 1 u-m; (b) dust clouds are bimodal; (c) preferential deposition of radon (thoron) daughters takes place on airborne particulates in the sub -micron range at about 0.1 u-m; (d) deposition of radon (thoron) daughters is proportional to particle surface area; and (e) ex-spectroscopy and -y-spectroscopy of dust samples reveals the presence of U-238, Ra-226 and some of their short-lived and long-lived decay products.IntroductionExtended inhalation of airborne radioisotopes poses a potential health problem to occupational workers. Because of this, monitoring of radiation and dust levels for dose exposure calculation purposes is not only recommended but in most cases mandatory.CANMET (Energy, Mines a nd Resources Canada) has long since been engaged in a comprehensive monitoring program aimed at determining dust concentrations in the respirable size range, aerosol concentration in the sub-micron range, and in the radioactivity associated with these particulates in underground uranium mines. Measurements have been carried-out with gravimetric dust samplers, dust size selectors (including a horizontal elutriator , a fineparticle spectrometer and Nuclepore* filters of different pore sizes) and a condensation nucleus counter(1 – 6). Inactive and active working sites have been monitored according to some typical mining operations. A summary of these data has been given elsewhere(3- 5)."

Jan 1, 1984

By Roger C. Parsons

"The problems presented by ice formation and interference with processes, structures and mechanical operations in the mining industry can be expected to increase sharply as more of our mineraI needs are supplied from the far north. A process of rapid ice destruction is presented which lends itself to the effective removal or penetration of ice. Suggestions are offered for applying the system to problems related to mining activity in cold environments. The system can be readily adapted to large-scale operation, the reactant components being transported in crystalline form and volatilized on site.IntroductionThe number of operational mines in northern environments, relative to the number of mines in the temperate zone, will increase in the years ahead. This is not surprising, because:(a) in the past, those mines closest to centres of commerce had minimum transport charges and hence were more economic to develop;(b) great centres of commerce were far removed from northern environments;(c) the exhaustion of ores and lowering of grades in temperate zones now offset to some degree the extra transport costs applied to northern ores;(d) the abundance of excess energy in the north in the form of oil, gas and hydropower attracts mining as a means to justify its development; (e) assuming that the frequency of mineral occurrence north of the 52° N latitude is no different than south of it, there are many deposits waiting to be developed.As a result of current and projected activity in northern environments, we are faced today, and will be increasingly so in the future, with mining problems rarely encountered before-problems related to below-freezing temperatures. Engineering activity in permafrost regions will increase as new mining ventures are developed north of the 52° N latitude, roughly coinciding with the -1.1 ° C isotherm in Labrador, the upper temperature boundary for permafrost."

Jan 1, 1982

By William Petruk, Donald Leroux, Michael Cooper

"Brunswick's primary flotation circuit (CuPb) produces a low grade concentrate containing considerable amounts of undesirable sphalerite and pyrite. To determine the cause of the poor selectivity, a series of Quantitative Mineralogical Analyses (QMA) were performed on several CuPb circuit streams. It was observed that significant fractions of sphalerite and pyrite reporting to the concentrate was liberated, meaning that their depression was not complete. The study highlighted the need for some R&D efforts to be spent in sulphide flotation fundamentals.IntroductionThe viability of many mining projects strongly depends on the performance of their concentrators. More than ever, competitive grade concentrate and high metal recoveries are criteria of paramount economic importance. The selectivity of solid/solid separation processes used in concentrators must be maintained at high levels or continuously improved.Flotation is the solid/solid separation process used by most base metal producers. In spite of its low operating cost, flotation remains a very complex process. To make it selective, precise reagent dosages and electrochemical conditions must be maintained. The difficulty in controlling flotation lies in the numerous heterogeneous reactions that can take place between the different solid, liquid and gaseous phases involved. This complex chemistry makes flotation selectivity difficult to understand and, therefore, to improve from a theoretical point of view.Brunswick Mining and Smelting, near Bathurst N.B., operates a 10500 tpd concentrator which produces four concentrates through five stages of sequential flotation (Figure I). Various reagents are added at key process stages while the ore undergoes different electrochemical conditions. Although the selectivity is important at all stages, the performance of the very first separation, the CuPb circuit, is the most critical. It is here where mineral misplacement to the wrong stream has the greatest economic consequences."

Jan 1, 1996

By L Gill

The four basic types of electric motors -squirrel-cage, wound rotor, synchronous and D.C. -are de-scribed, with particular reference to speed-torque characteristics. The three classifications of squirrel-cage motors, C.E.M.A. B, C and D, are compared, and methods of selection for specific drives are outlined. Wound rotor and synchronous motors are covered from the viewpoint of construction details, methods of operation and control required. The application of these motors to crushers, conveyors and ball mills is described and reasons for their selection are given. The application of D.C. motors to haulage equipment and mine hoist drives is included, and the basic principles of a variable voltage drive are illustrated. Efforts have been made through-out to provide specific examples of motor selection, with particular reference to the mining industry. THIS paper will attempt to answer the question -"which motor should be used for a specific drive?" Although it is impossible to cover the complete subject of electric motor application here, we hope to give some idea of the types of motors available and why certain types are used on specific applications.

Jan 1, 1963

By C. G. Anderson

Alkaline sulfide leaching technology (i.e. ASL) has been studied, presented and published throughout the literature and utilized in some current engineering studies. Yet, the actual industrial applications are very few and the knowledge about these is very limited. Hence, a large gap between the laboratory, publications, engineering studies, and the actual industrial plant exists. Recent studies of ASL applied to copper enargite concentrates definitively bear out this dichotomy. Hence, this paper will seek to dispel the common misperceptions that continue to surround the selective industrial ASL hydrometallurgical technology. For edification of the reader, a listing of ten common misconceptions and myths is listed. As well, ASL history, fundamental aspects and a new flowsheet application for simultaneous gold and high purity antimony oxide production from low grade materials is included. The associated estimated economic considerations are also included to heighten enlightenment about the application of this industrially proven technology.

Jan 1, 2014

By J. G. Speight

Laboratory studies indicate that autogenous heating of low-rank coal can be prevented by a prior treatment which involves immersing the coal for short (5-15 min.) periods in an inert liquid at temperatures between ~ 350° and 400°C. Such "carbonization" effectively reduces the accessible pore volume of the coal to levels at which heat generation through subsequent sorption of moisture and oxygen is too slow to cause significant temperature rises in a stockpile. In addition, this treatment also irreversibly removes most of the moisture held in the raw coal and raises its calorific value by as much as 10-12%.

Jan 1, 1973

By Philippe V. Scheers

Polycrystalline gold, glassy carbon and gold-activated glassy carbon electrodes were compared for the production of hydrogen peroxide by the cathodic reduction of dissolved oxygen. Gold was deposited on glassy carbon by sputtering with a sputter coater and by electrodeposition from a diluted KAuCl4 solution using short potential steps. The sputtered gold particles were not adherent enough, but there were no adhesion problems with the electrodeposited gold particles. The gold coverage of the glassy carbon surface could be varied by applying a different number of potential steps. The overpotential for the electroreduction of oxygen to hydrogen peroxide decreases with increasing gold coverage of the glassy carbon surface, and for gold coverages exceeding about 16 %, the overpotential is close to that observed on polycrystalline gold.

Oct 1, 2003

By J. Baumbach, H. Bombach, M. Stelter

"Today technical electro-refining processes for copper exclusively use sulfuric acid, for silver refining nitric acid electrolytes are used. Sulfuric acid is characterized by very good chemical and electrochemical stability, good conductivity and low cost. The disadvantages of sulfuric acid are the precipitation of fine-grained cathodes with smooth surfaces only by using additives like glue, thiourea and chloride. In case of silver the electrolyte is electrochemical unstable and bears the risk of the formation of toxic NOx when pH is too low. A second disadvantage is the form of electrodeposition of silver as dendrites with their removal from the bottom of the Möbius cells.This paper reports the results concerning the application of an alternative electrolyte in copper and silver electro-refining. At first the electrolyte was characterized by the determination of current density potential curves. Electrolysis experiments were performed in laboratory scale using technical anodes for copper and synthetic anodes for silver. During the copper tests the solubility of contaminations from the anodes and the amount and chemical composition of the anode slimes were determined. Moreover the influence of current density, electrolyte temperature and the effect of several additives on the precipitation and chemical purity of the cathodes were investigated. In all experiments cell voltage as well as anodic and cathodic polarization was measured and current efficiency and specific energy consumption were calculated. A comparison with the results with those of tests using conventional sulfuric acid electrolyte shows the advantages and disadvantages of both systems, additionally the technical application chances and limitations for the new electrolyte. This electrolyte enables the precipitation of smooth copper cathodes with low silver and sulfur concentrations even at lower temperatures without any additive. For silver refining the electrodeposition of compact silver sheets is possible, that can be stripped comparable to those in copper electro-refining."

Jan 1, 2016

By Adam Turcotte

Mining operations consume a considerable amount of energy, and while reduced energy consumption is desirable, it is not always clear how to achieve this goal. Understanding the opportunities to optimize energy consumption is crucial, and the key to understanding is visualization. One option is the Sankey diagram, which has been used for over 100 years to visualize the flow of energy, materials, or cost through various processes. However, there are drawbacks to this approach that must be addressed. In a Sankey diagram, each flow is represented by an arrow possessing a width proportional to the magnitude of the flow it represents. The diagrams show input flows, how energy is converted and into what form, and also output flows. As per the first law of thermodynamics, the total energy output is equivalent to the total energy input, so any energy that is not transferred to another process is considered to be wasted. These waste flows are depicted in Sankey diagrams and make it straightforward to associate energy sources, sinks and waste flows. Unfortunately, Sankey diagrams do not convey all information required to support practical decision making for redirecting individual energy flows. Based only on a Sankey diagram, it may become evident that a significant flow of waste heat is of the appropriate grade (temperature) and volume to meet an on-site heat demand currently being met with paid-for, possibly carbon intensive fuel. However without augmenting the Sankey diagram with 3D spatial, true geometric analysis, the practicalities of the concept or idea may not be fully appreciated. Another issue with a Sankey diagram is that the magnitude of the energy flowing between processes may have temporal fluctuation or variability on different timescales (diurnal, seasonal, interannual). Currently, Sankey diagrams only provide a static picture of energy conversion and consumption, so that, for example, 4 separate diagrams could have to be prepared for each season. A new energy flow visualization technique which we have called Sankey Trees has been developed. Process locations are defined within a 3D model of the site being studied, and the magnitude of the flow between each pair of processes considered is replaced with a time series. Branches of sustained and diminishing flows are represented through variation of the geometric properties of the branches of the trees. These branches are animated to indicate the direction of flow, and branch joints are used to indicate that a process is transporting one form of energy to multiple processes.

Aug 1, 2013

By C. M. Acuna, M. Sherrington

In high temperature processes thermodynamic equilibrium is assumed and therefore chemical potential of elements, among the condensed phases, have to be the same. In such situation impurities distribute accordingly and their fractional distributions are affected by the masses of the coexisting phases. It has been claimed Teniente Converters perform quite well for smelting high impurity concentrates, especially in respect to volatilization and/or slagging. Production of high matte grade near white metal composition, requiring moderate oxygen enrichment in the process air, results in a huge mass of gas and therefore a high fraction of impurities report to it. Similarly, by recycling different sources of slag, flue dust or other materials, the mass of the final slag is increased and so do the masses of impurities reporting to the slag. Nevertheless, above a certain level the recycling of smelter byproducts is no longer feasible and the cycle has to be halted, unless higher impurity mattes are accepted. Although the process might be continued during converting and refining, lengthy and expensive measures have to be taken if suitable anode copper for electrolytic refining is to be achieved. In the present study samples of high arsenic matte grade and slag were obtained on a pilot scale. The matte samples, on the order 75%Cu, were equilibrated with slag at varying ratios in magnesia crucibles under CO/C02 atmospheres at 1523 K. After 24 hours equilibrium matte and slag were rapidly solidified and analyzed by copper, sulfur, iron and arsenic. Furthermore, industrial samples of matte and slag, in the order 75%Cu at 1523 K, were obtained via a special quenching sampling device to determine the association of copper and suspension of matte and copper in slag. Based on the results, the distribution coefficient of arsenic between slag and matte was evaluated along with copper species in slag and the fractional distribution of arsenic, in the coexisting phases, was determined as a function of the ratio mass of slag to mass of matte.

Jan 1, 2007

By Richard Wells

Peabody Energy is the largest pure-play publicly traded coal company in the world. We have been in business 129 years and like most of the coal mining companies in the United States, since 1969 the majority of our safety improvement efforts had been driven by compliance with the various versions of the Federal Mine Safety and Health Act and the supporting federal regulations. In 2004 Peabody Energy management came to the understanding that in order to achieve our goal of zero incidents, that focus must change. This paper will describe the elements of the journey we began at that point to make the transition to a behavior and systems-based approach to safety management and our efforts to win the minds and hearts of our employees. This journey is undertaken with the goal of making safety truly a way of life for all Peabody Energy employees.

Aug 1, 2013

By J. R. Kish, J. Dabrowski

"The susceptibility to intergranular corrosion modes is a major technical issue preventing widespread utilization of higher strength welded AA7xxx extruded beam profiles, in the peak-aged T6 condition, in automotive bumper assemblies. A study was undertaken to evaluate the relative exfoliation corrosion resistance (ASTM G85-A2) as a function of joint design parameters, namely the base alloy composition, heat-treated condition and beam orientation after exposure to a cyclic acidified salt spray test. This paper documents the major findings extracted from this study.INTRODUCTIONBumper systems play a predominant role in the passive safety of an automobile, since they are one of the main structures for absorbing the collision energy in the event of an automobile crash. Heattreatable AA6xxx-series (Al-Mg-Si) and AA7xxx-series (Al-Zn-Mg) Al alloys, with relatively high strength, toughness, energy absorption, weldability and formability, make it possible to design costcompetitive bumper systems to crush in a controlled fashion. In this context, Cu-lean AA7xxx extrusions, such as AA7003 and AA7108, which exhibit higher strength than AA6xxx extrusion, such as AA6082, represent an attractive light weight material from which to fabricate bumper assemblies (Clausen et al., 2000; Pedersen et al., 2008; Chen et al., 2009).Arc welding is a key joining process for AA7xxx alloys within the transportation industry. A major technological issue preventing widespread utilization of arc-welded AA7xxx joints is the susceptibility to severe localized corrosion (Kent, 1970, Reboul et al., 1985; Holroyd et al., 1987). It generally occurs as exfoliation corrosion within a heat affected zone (HAZ) a few millimeters from the weld bead, or a type of stress corrosion cracking (weld-toe cracking), which initiates at the weld toe and propagates into the interfacial region between the weld bead and the HAZ (so called “white zone”). In addition to the micro-galvanic cell activity induced by the intermetallic compound constituent and strengthening particles present, there is strong evidence that macro-galvanic cell activity between the weld bead and base AA7xxx alloy may be playing a controlling role. Electrochemical profiles taken across fusion welded joints, in cross-section, during exposure to saline solutions suggest that a significant potential difference exists across the AA7xxx arc-welded joint (Shumaker et al., 1967; Grauer and Wiedmer, 1980; Tuck, 1985, Onoro and Ranninger, 1993). These studies consistently show that the HAZ and base alloy are more electronegative with respect to the weld bead (arc-welded with AA5xxx filler wire). Despite this initial important work, the majority of the recent corrosion research effort on welded AA7xxx alloys has focused on the performance of friction stir welds (Lumsden et al., 1999; Wadeson et al., 2006; Hatamleh et al., 2009)."

Jan 1, 2012

"Batch flotation testwork demonstrated that a low-grade chromite ore from Bird River, Manitoba, was best floated at pH 2 using Armac C (coco amine acetate) collector and sulphuric acid as pH modifier. A grind of 100% minus 150 um was necessary for liberation, and flotation selectivity was greatly enhanced by prior desliming. A concentrate analyzing 24.2% Cr203 with a recovery of 90.2% was obtained, after three cleaning stages, from ore grading 6.05% Cr203. Total rougher collector concentration was 500 g/t and cleaner collector concentration 380 g/t. Similar grade and recovery were obtained during the pitot-plant evalualion, when a concentrate analy zing 22.3% Cr203 with a recovery of 93% (based on deslimed feed) was obtained for a total collector addition of 630 g/t.Selective flotation in a region of positive surf ace charge implies anionic activation, and a possible flotation mechanism is suggested.IntroductionIn an earlier study(1) of the beneficiation of chromite ore from Bird River, Manitoba, several methods of beneficiation were explored. These included ore sorting, heavy-media separation, and gravity concentration with flotation using Armac C (coco amine acetate) collector at pH 2, and sulphuric acid as pH modifier. Because flotation was not fully evaluated, a laboratory study was undertaken to determine the optimum parameters of chromite flotation. Optimization of parameters was established first on a laboratory scale followed by confirmation a t the pilot -plant level. Flotation of chromite using Armac C and sulphuric acid as a pH modifier has been reported as being selective for low-grade chromite ores(2)."

Jan 1, 1990

By Jae-Chun Lee, Sadia Ilyas

We investigate the technical feasibility of bioleaching of metals from low grade sulphidic ore. Experiments were conducted with an adapted consortium of Sulfobacillus thermosulfidooxidans and Thermoplasm acidophilum in batch bioreactors (1.5 L), small columns (10 kg ore load, 8 % S0 sludge) and large columns (80 kg ore load, 12 % S0 sludge). Approximately 83 % Ni, 85 % Cu, 55 % Fe and 81 % Zn was leached out in batch mode while 93 % Ni, 89 % Zn, 81 % Cu and 65 % Fe was leached out in column reactors. Bioleaching potential improved by acid pre-leaching, adaptation of microbial consortium and periodic bleeding of effluents.

Jan 1, 2014

The tensile test results of as-cast A356.2 grain-refined alloy castings show that the tensile strength can be improved by strontium modification (`SrM'), superheating at 900°C OM, and melt thermal treatment of the Sr-modified alloy melt (`SrMTT'). Both SrM and SrMTT processes can greatly improve the ductility (percent elongation) of the as-cast alloy. During solution heat treatment at 540°C, eutectic Si particles undergo fragmentation, spheroidization, and coarsening, thereby affecting their morphology. The effects of solution heat treatment on the tensile properties of the variously treated A356.2 alloy castings can be summed up as follows: the yield strength of the castings is significantly improved after 8 h solution heat treatment due to the precipitation of Mg2Si, after which it remains more or less the same with the further increase in solution treatment time up to 80 h; the ultimate tensile strength is also greatly improved within the first 8 h of solution heat treatment and then remains at the same level thereafter, up to 80h of solution treatment. The improvement in UTS is attributed to Mg2Si precipitation, dissolution of Si within the aluminum matrix, and changes in the Si particle morphology (spheroidization). The ductility of the as-received grain refined non-modified (`NM'), grain refined and superheated at 900°C (`SH'), and melt thermal-treated grain refined (`MTT') A356.2 alloy castings can be improved considerably with solution heat treatment e.g. from ~6% in the as-cast non-modified casting to ~10% after 80 h solution treatment.

Jan 1, 2011

By B. Hart, D. J. Miller, J. T. Francis, M. C. Biesinger, Smart. R. St. C.

Diagnosis of the surface chemical factors playing a part in flotation separation of a valuable sulfide phase requires measurement of the hydrophobic and hydrophilic species that are statistically different between the concentrate and tail streams. Time of flight secondary ion mass spectrometry (ToF-SIMS) can be used to identify sufficient particles of a specific mineral phase for reliable statistics determining a mean value for each species with 95% confidence intervals (1). Using the region of interest (ROI) facility in the Tof-SIMS software, a mass spectrum from each particle, at 1-2 monolayer sensitivity, is recorded and stored. This analysis is reported for a chalcopyrite / pyrite / sphalerite mineral mixture conditioned at pH 9 for 20 minutes in order to study transfer of copper from chalcopyrite via solution to the other two mineral surfaces since this mechanism can be responsible for their inadvertent flotation in copper recovery. Analysis from mineral selection based on specific ToF-SIMS signals (eg. Pb, Zn, Cu, Fe, Fe/Cu) indicated no statistical difference in the copper intensities on pyrite and sphalerite after this conditioning. Principal component analysis (PCA) of the ToF-SIMS imaging data identifies combinations of factors strongly correlated (positively or negatively) in images or spectra from mass spectra recorded at each of 256x256 pixels in a selected area of particles. PCA is a better method of selecting minerals due to multi-variable recognition. It has clearly separated a statistical difference in copper intensities between the sphalerite and pyrite phases. The method has been extended to samples from an operating plant again with excellent phase recognition and diagnostic surface chemistry.

Jan 1, 2004

By R. St. C., G. E. Morris, M. Zbik, Smart

Effective flocculation and dewatering of slurry streams containing clays (particularly kaolin and smectites which are often <200nm in lateral dimension) is becoming increasingly urgent. Release of water (often >75 wt%), for recycle and reduced make-up water consumption, from slurries in tailings streams and dam beds is usually slow and incomplete. Changes in settling rates and solids density of tailings containing clays can be achieved in practice by changes in pH, dissolved cations and flocculant additions. To achieve fast separation of clays from water and minimization of retained water, individual particles need to be bound in the initial stages of thickening into large, high-density aggregates, which may sediment more rapidly with lower intra-aggregate water content. Quantitative STIMAN (STructural IMage ANalysis) cryo-SEM imaging, shows that the structure of aggregates formed before flocculant addition has a determinative effect on these outcomes. Without flocculant addition, 4 stages occur in the mechanism of primary dewatering of kaolinite: initially separate particles and aggregates are dispersed (<0.3GP, where GP is the gel point); a partially-gelled chain network then forms linking particles edge-edge (EE) still well below the OP but remains largely suspended; after an induction time, this network structure rearranges from EE to face-face (FF) contacts densifying, compacting and dewatering the aggregates with settling rates well above Stoke&apos;s Law estimates for >20µm particles or aggregates; the GP is rapidly reached during settling producing a network spanning the vessel with compressive strength. This sponge-like structure with EE oriented particles limits slurry dewatering because the steric effect in the resulting partially-gelled structure is much more dominant than the electrostatic effects predicted by DLVO theory. Van der Waal&apos;s forces at very close distances, as particles slide across each other, may be responsible for the EE to FF change in structure. In this way, the previously extended network contracts, and when the solid volume fraction is low, the continuous network breaks apart forming aggregates and aggregate associations as flocs which arc able to freely settle. These densified aggregates settle at increased rate, give lower bed density and retain less water after drainage. With flocculant addition, the internal structure and networking of the pre-aggregates is largely preserved but they are rapidly and effectively bound together by the bridging action of the flocculant(s). The STIMAN analysis shows that there is a inverse correlation of intra-aggregate porosity (and void permeability) with Darcian permeability (and extent of dewatering) whereas there is a strong positive correlation of Darcian inter-aggregate permeability with settling and primary dewatering rate.

Jan 1, 2004