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By N. Geoffroy, E. Benguerel, G. P. Demopoulos

In the late 1990s, a chemical process to remove mercury and selenium from weak sulphuric acid solutions was patented and implemented in the CEZinc refinery in Valleyfield, Quebec. The CEZinc process comprises two stages. In the first one, sodium sulphide is added to the weak acid solution in order to precipitate the soluble mercury. The solution is then treated with sodium dithionite in order to reduce the selenium to elemental form. Because of recent changes in the composition of the industrial solution, a project to study the background chemical reactions was started. In this paper, a review of the background chemistry is presented on the basis of several eh-pH diagrams on one hand, while on the other experimental results are reported dealing with the reaction of selenium (IV) species with either dithionite, sulphide or a combination of the two. According to this work, elemental selenium enjoys a wide pH-eh range stability with selenium sulphide being metastable. Selenium (IV) in single metal synthetic solutions was found to be reduced - to elemental state - at ambient temperature down to ppb range with dithionite as long as the stoichiometric ratio (dithionite/selenium) was in excess of two and the pH < 1.7. Under these conditions the reaction was very fast reaching completion within one minute. Sodium sulphide proved equally effective in reducing selenium (this time as selenium sulphide) to ppb range from single metal solutions. However, in mixed Se-Hg solutions deviations from this "ideal" behaviour was observed resulting in higher levels of residual soluble selenium left in solution.

Jan 1, 2008

By E. Gaucher, D. C. Gagnon

"The paper refers to methods and concepts used in the computer treatment of banks of geophysical, geochemical and geological data, relating to the exploration of massive sulphides. In particular, a data bank of 400 drill holes on independent conductors can be used to calculate probability levels of intersecting a certain quantity of sulphides according to the characteristics of the conductor. Inversely one can, using the data bank and some cost assumptions, simulate and optimize the cost of intersecting a certain quantity of sulphides by selecting drill targets among conductors according to conductivity, magnetism or gravity. Problems of noise, inherent in any simulation, are illustrated in this paper by the results of a study of the nomenclature of volcanic rocks of 27 drill holes by forty geologists. Compilations of data banks are long and timeconsuming, and it would help to standardize to allow exchange of data. We believe that such efforts may result in the discovery of more mineral deposits and at a lower cost. The present study is supported jointly by SOQUEM The New Jersey Zinc Co. and Cominco Ltd."

Jan 1, 1973

By A. Mukherjee, C. Kelly, B. Markovich, G. E. Agar, G. E. Robertson, F. Khan, B. Shea

"Laboratory batch flotation tests were performed on a sample of bulk slow cooled converter matte (Cu:Ni = I) to optimize the time in each of the separation stages. Numerical simulations were carried out to estimate a continuous circuit material balance for the conditions selected. An experimental simulation of a continuous circuit (locked cycle test) readily came to steady state and there was reasonable agreement between the numerical and experimental results. The use of nitrogen as the flotation gas and the addition of collector to the grinding mill minimized the oxidation of chalcocite, which has previously resulted in increasing circulating loads, and led to a stable circuit with very low weights in the recycle streams.IntroductionINCO Limited developed a flotation process for separating the components of copper-nickel matte [Sproule, Harcourt and Rose 1945; Sproule, Harcourt and Renzoni 1960] in 1945 to replace the Orford process and continues to use the flotation process in almost the original mode to this day. Initially the matte processed was the result of smelting a nickel concentrate that analyzed about 12% nickel and 2% copper and all of the recycle material that was generated in the smelting process. The matte generated analyzed about 25% copper and 53% nickel, roughly 2: 1 nickel to copper. This matte was blown in Pierce-Smith converters to be sulfur deficient in order to produce a metallic phase that collected the precious metals contained in the smelter feed [Wilson and Stratton-Crawley 1991]. This process continued with little change until 1994 when the separation of chalcopyrite from pentlandite in the Copper Cliff mill was discontinued after 63 years of operation. As a consequence of the elimination of the primary separation of chalcopyrite from pentlandite in the milling process a bulk concentrate was produced for smelting. Bulk concentrate smelting came into practice in 1994 as part of the initiative to meet government legislation that restricted the emission of sulfur dioxide to the atmosphere. Previously, the copper concentrate was smelted in an INCO oxygen flash furnace which resulted in the capture of a high strength sulfur dioxide stream from which liquid sulfur dioxide was produced. Nickel concentrate was smelted in reverberatory furnaces that produced low strength sulfur dioxide gases which were difficult to treat. The action taken by INCO to meet the environmental constraints was to smelt a bulk concentrate in oxygen flash furnaces which would produce gases suitable for the production of liquid sulfur dioxide and another stream that was high enough in sulfur dioxide to be readily converted to sulfuric acid [Bell et al 1990]. The end result of this decision was that all the copper-nickel separation would be done in the matte separation plant."

Jan 1, 1996

By Shawn Harvey

HIGHLIGHTS of STAR DIAMOND PROJECT Initial underground bulk sample 4,048 ct / 25,253 tonnes: US$135/carat: 3,050 ct March 2005 $116 million financing: Newmont takes 9.9% SGF Prefeasibility study commenced on Star Merger with Kensington: 42.245% FALC-JV Voting agreement with Cameco in FALC-JV November 2005 $120 million financing: Newmont maintains 9.9% SGF Diamond valuation: 5,950 ct/ 36,529 tonnes: US$135/carat

May 1, 2006

By I. H. Warren, F. A. Forward, A. Vizsolyi

"Observations are reported on the pressure leaching of material produced by subjecting chalcopyrite to two types of heat treatment. Calcination of the mineral at 825°C, in the absence of oxygen, induces some sulphur loss by volatization, producing a material from which copper can be leached more rapidly than from chalcopyrite. Treatment of the mineral with elemental sulphur at 475°C leads to sulphur uptake accompanied by a change in mineralogical structure of the chalcopyrite. Copper is prefer-entially and rapidly leached from the sulphur-treated material. A tentative explanation of the sulphur-chalcopyrite re-action is presented."

Jan 1, 1968

By L. Trytten, S. Bass, P. Nawrocki, J. Mercer

The Sherritt Fort Site nickel refinery and fertilizer plant has been operating continuously since 1954. The ammonia leach process uses ammonia and sulphuric acid, producing nickel and cobalt and an ammonium sulphate byproduct. One of the features of an ammonium sulphate based process is the aggressive nature of ammonium sulphate to concrete and structural steel. After six decades of operation, portions of the structural steel and concrete at the Sherritt facility have become degraded. Infrastructure replacement programs started in earnest more than a decade ago with pipe racks and electrical infrastructure, and have now progressed into building steel. Replacing and repairing this infrastructure within the tight constraints of an operating plant poses several difficult challenges. This paper will outline the approach taken to accomplish this difficult work, and discuss key learnings from the ongoing program.

Jan 1, 2015

By V. I. Lakshmanan, I. G. McColl

"Heap leaching of gold ores in permafrost conditions is feasible provided certain criteria are met. These criteria include relatively short heap leach residence time and the availability of waste heat.This paper describes the conceptual design of such a system for a mining operation in the North West Territories of Canada. The design includes the concept of continuous countercurrent leaching in enclosed ore heaps.Indicative capital and operating costs are given.INTRODUCTIONIn April 1984, Acres Davy McKee Engineering Inc. (ADM Eng.) in association with Ontario Research Foundation (ORF), was invited to carry out a preliminary design, cost estimate and financial analysis to assess the viability of gold heap leaching in a permafrost region in North West Territories, Canada.An orebody was being explored which could, by nature of its mineralogy, be upgraded substantially by crushing and screening in the size range of 1/4 in. to 3/4 in. It was proposed to process the screen undersize through an existing gold mill on site and to treat the oversize material in a heap leach facility to be constructed adjacent to the existing mill.Despite the formidable challenges imposed by isolation, permafrost and harsh winter conditions, the heap leach project was considered worthy of examination because of the relatively high grade of the heap leach material (> 0.1 oz/ton), very short leach times (in the range of 1 to 4 days) and the availability of substantial quantities of waste heat from the diesel generating station on site.Design challenges included the necessity to maintain the permafrost in frozen condition, to prevent freezing of ore and leach solution, to limit size of construction materials to that which could be carried in a Hercules freight plane and to contain water usage at an absolute minimum level."

Jan 1, 1987

By M. Elmadagli

Wear mechanisms of two commercial aluminum alloys, namely a spray formed and extruded Al-25%Si alloy, and a sand cast A390 alloy (18.5 %Si) that are known to be successful in cylinder bore technology were studied to have a better understanding of the requirements for wear resistant aluminum alloy design. From durability point of view these alloys are known to be successful for engine bore applications. It is interesting to compare the wear mechanisms in these alloys because they have significantly different silicon content and microstructures, and were produced using different techniques. The wear tests were done using a block-on-ring configuration, in controlled air atmospheres (5 % relative humidity). In spite of the differences in silicon content and microstructure, the wear mechanisms were similar and consisted of formation and destruction of hard tribolayers that are either formed by either mechanical or chemical interactions on contact surfaces. The differences in the wear rates between the two alloys arose from the differences in the hardness of the worn surfaces, and the alloy&apos;s ability to sustain the tribolayers on the worn surfaces.

Jan 1, 2004

By D. J. McLaren

"Arctic Canada is one of the largest undeveloped terrains remaining in the world, and is in many ways unique. The ecological balance of the region is more delicate than tropical or temperate regions of similar size. This region is likely to be developed by research for and production of resources, primarily petroleum, in the immediate future. As well as sensitive terrain surface caused by permafrost in some areas, many large and small mammals and birds are also in a delicate balance with the environment. Small changes in this balance can have large effects.The probability of finding petroleum in different regions varies widely, but already there are good indications on the mainland and in the Islands that both oil and gas are present. Geophysical work in the offshore, particularly the Beaufort Sea, suggests further promising potential. Possible reserves in the Islands and mainland Arctic may amount to 50 or more billion barrels.A responsible approach to problems facing exploitation in an Arctic environment includes the careful monitoring by industry of likely effects of their activities. The Mackenzie Valley Pipeline Research Association test loop at Inuvik provides an example of such monitoring. Outside Canada, the operations at Prudhoe Bay on the north coast of Alaska show how major companies may operate responsibly and reduce environmental interference to a minim'.::at. Nevertheless, four variables must affect any decisions to be made concerning energy resource exploitation in the Arctic. These are man's need for energy, economic and industrial pressures to develop energy sources, the desire to preserve a deteriorating environment, and the role of government as representing all individuals in the country and their several points of view. Factors that must be taken into account in making any decisions include the importance of Canadian oil in a world picture, the need for alternative sources of energy in the near future, the depletion of nonrenewable resources at an accelerating rate and the increasing awareness that the major problems facing man have no direct technical solution and that social or political decisions must precede further techno-logical development."

Jan 1, 1971

By Fathi Habashi

Poland has a unique copper industry. Copper sulphide concentrates are smelted in six shaft furnaces to produce matte and in a flash furnace directly to blister copper. Anodic slimes from electrorefining are treated by a modern technology to recover the precious metals. INTRODUCTION Poland&apos;s copper industry began in 1950 when the old and relatively small mines Lena and Konrad, located in Lower Silesia, were drained and recommenced production. In 1957 the industry entered a period of rapid development with the discovery of a rich ore body in the vicinity of Lubin and Polkowice which was the basis for the establishment, in 1961, of the Copper Mining and Smelting Combine (KGHM). In 1991 the Combine was restructured into a state-owned, joint-stock company under the new name of KGHM ?Polska Miedz? (KGHM ?Polish Copper?). It consists of three mines, three smelting and refining plants, and one rolling mill, and produces about 4% of the world?s copper and about 7% of the world?s silver.

May 1, 2001

By Ainul Akhtar, Steve Cockcroft, Daan Maijer, Carl Reilly, Lu Yao, Jun Ou

A coupled thermal-fluid flow-multicomponent model has been developed to aid in understanding the melting/dissolution behavior of solid Al-rich Material (TiAl) in a liquid titanium pool produced by an electron beam. The model is capable of accounting for the significant phenomena present affecting heat, mass and momentum transport including thermal and compositional buoyancy and Marangoni forces, Darcy attenuation, evaporation, melting and solidification, and the associated release or absorption of latent heat. The modeling results have indicated the compositional fluid flow driving forces (compositional buoyancy and Marangoni forces) contribute significantly to the melting/dissolution process. The model is waiting for validation against empirical data.

Jan 1, 2014

Safety Leadership The management and leadership of a mining operation is a challenge at all times. The pressure to make production, safety, and environmental goals is intense. At some point mining cycles will put every operator into periods of time where economic issues seem to over-ride all other concerns. This is when leadership is most needed.

May 1, 2009

By W. F. Baker

Location and History God&apos;s lake is in the northeastern part of Manitoba, about 400 miles northeast of Winnipeg, or about 250 miles due north of Red lake, Ontario. The lake is quite large, having an overall length of 54 miles and a maximum width of 18 miles. There are numerous islands in the lake, the largest of these, known as Elk island, being about 15 miles long and 3 miles wide in the widest part. The accompanying map (Figure 1) shows the location of God&apos;s lake and of the mine. The God&apos;s Lake area has long been regarded as promising country for the prospector, but, due to its inaccessibility, practically no prospecting was done prior to 1927. In the years 1927-1931, inclusive, a few prospectors visited the area, but no discoveries were made. In 1932, Bob Jowsey and Archie McDonald entered the area from Island lake. They first prospected in the vicinity of Knife lake, which is immediately south of the main part of God&apos;s lake, and then moved on to the latter lake, heading for the north shore of Elk island. The first afternoon on God&apos;s Lake, when looking for a place to camp on the north shore of what is now known as Jowsey island, Jowsey discovered a quartz porphyry dyke which was cut by a number of gold-bearing bluish quartz stringers. On the strength of this discovery, he and McDonald began at once to stake the Reno group of claims. Rumours of the discovery brought in other prospectors, and other groups of claims were staked to the east, along the north shore of Elk island. A second discovery was soon made by Dan McCrea on his Gold Standard claims, three and a half miles to the east of the original discovery. Staking still continued to the east, along the north shore of Elk island, and Bob Brown and Harvey McKenzie staked the Akers group on a discovery approximately two miles east of McCrea&apos;s discovery. Through the efforts of Jowsey, the Reno, Rand, Elk, and Cona groups, belonging to the original syndicate for which Jowsey and McDonald staked, were combined with the Gold Standard, Greenstone, and Akers groups, and the Company known as God&apos;s Lake Gold Mines, Limited, was formed. Several additional groups of claims were later taken over by the Company and a considerable area of adjoining ground was staked to round-out the property.

Jan 1, 1935

By A. M. Martinez, L. Melis, R. C. Peláez, L. G. Garcia

Orovalle Minerals S. L. operates a copper/gold mine in the Asturias region of northern Spain, with the operation dating back to December 1997. The feed to the El Valle mill, consisting of oxide/sulphide (skarn) mineralization, is highly variable, even on a shift by shift basis and presents challenges to the mill operating staff on a daily basis. The mineralogical characteristics of the ore are quite complex with copper present as native copper and sulphides as well as copper minerals with deleterious elements. Gold is present as native gold and electrum. The mill circuit includes SAG/ball mill grinding, gravity recovery of native copper and gold, flotation of copper concentrate, carbon-in-leach gold recovery and SO2/air cyanide destruction. The paper will provide a description of the different unit operations and present operating data of the mill operation.

Jan 1, 2019

By S. Ando

The fatigue crack growth behavior of magnesium single crystal has been investigated, CT (compact tension) type specimens with different notch orientations were prepared. In the case of notch plane and direction are (1-210) and [10-10], fatigue crack propagates parallel to notch, From TEM observation, it is found that pyramial slips occures at the crack tip. When notch is normal to basal plane, a fatigue crack propagates [0001] and parallel to basal plane depending on stress intensity factor range, In the case of notch parallel to basal plane, a fatigue crack propagates through straight route with some {10-12} twin, Fatigue crack growth rate, da/dN of A- and B- specimen is lower than F-specimen with crack parallel to basal plane.

Jan 1, 2004

By Jim Cooney

Background ?1990s saw massive changes in South African mining industry ?over 100,000 jobs lost as the industry restructured; ?1999 ?Placer Dome purchased a 50% interest in South Deep (WAL), a mine located just outside Johannesburg ?This was the first major post-apartheid foreign investment in the South African mining industry The Situation ?Placer Dome decided to lay off 2560 mineworkers (one third of the workforce) from the South Deep Mine to restore the mine to economic viability. ?Unemployment in South Africa was over 25%, and the retrenched mineworkers had few skills with which to make a living. Policy Context ?Placer Dome was committed to: ?global corporate policy of Sustainable Development, ?demonstrating that its business contributes to the economic and social progress of host jurisdictions. ?Government of South Africa was committed to ?attracting foreign investment to its mining sector with a view to modernizing and enhancing its economic and social viability, ?ameliorating the negative social consequences of structural change without arresting the necessary process of restructuring. ?National Union of Mineworkers was committed to: ?working with the mining industry and the government in implementing a Code of Good Practice on Dismissals and a Social Plan to assist retrenched mineworkers (1999).

May 1, 2006

By F. Nava-Alonso, A. Uribe-Salas, C. Rodriguez-Rodriguez

Ozone has been proposed to pretreat refractory ores before the cyanidation process for precious metals extraction. As pyrargyrite is one of the silver species most common in Mexican refractory ores, the ozonization of this silver sulfide was studied. The effect of pH and ozone concentration on silver dissolution was evaluated by means of a factorial experimental design. Two levels of sulfuric acid concentration and ozone in gas concentration were evaluated: 0.18 and 0.72 mol/L of acid and 0.054 and 0.077 gO3/L, respectively. The highest silver dissolution was obtained when using the higher acid and ozone concentration.

Jan 1, 2011

By James J. Holmes

ACCIDENT prevention as we know and understand it today is of comparatively recent origin. As a matter of fact, the Industrial Accident Prevention Association of Ontario, which is the oldest organization of its kind in the Dominion, celebrated its thirtieth anniversary only this year. On the other hand, one could say that the history of accident prevention is almost the history of mankind itself. In a general sense, every forward step that man has made throughout the centuries has been largely due to two things: (1) a desire for increased comfort, and (2) the need for safety; and, always, the need for safety has taken precedence over the desire for comfort. While it is true that hundreds of volumes have been published, dealing with the many aspects of accident prevention work, you cannot go to a library and pick out a book that has all the answers in it. Such a book has never been published-we are still looking for some of the answers. However, a good deal of real progress has been made.

Jan 1, 1945

By Richard Simon

This paper presents an ongoing study on the use of borehole breakouts to estimate in situ stresses at depth in a Canadian underground mine. Breakouts were identified using an acoustic televiewer (ATV) probe. Rock samples were tested in a laboratory to determine their failure curve. Breakout analyses were performed using a 2D failure criterion and a multiaxial failure criterion. Analyses were carried out using both short-term (peak) and long-term strengths (the latter considered here as being represented by the damage initiation threshold DIT). The analyses have shown that the use of the longterm strength and a multiaxial failure criterion leads to results that are more consistent with stress measurements performed in the field, in the vicinity of the mine.

Jun 1, 2012

By Yi-xin Zhoa

The characteristics of coal bumps are analyzed based on the microseismic data from No.8935 workface in Xinzhouyao coal mine, Datong Mining Group. The geology of this workface is characterized by the thick sandstone roof and coal seam, both with relative higher stiffness and strength. In order to investigate the mechanism and precursors of coal bumps occurred in No.8935 workface, the locations of microseismic, the relationship of microseismic energy and frequency and the spectrum of microseismic signals are analyzed. The result shows that the coal bumps in No.8935 workface were mainly induced by the seismic caused by roof failure. The coal pillar near the goaf is more easily to bump. The statistics results indicate that the coal bumps were mainly occurred in the gate road near the pillar, less than 50m ahead of mining face and located in the hard roof adjacent with coal seam. Moreover, the frequency, energy, b-value and frequency spectrogram of microseismic events were found to decrease before coal bumps. It was found that the frequencies of the microseismic events before coal bumps mainly concentrate upon 5~60Hz. The sudden decreasing of frequency and increasing of amplitude of microseismic events can be regarded as a precursor of coal bumps.

Aug 1, 2013