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By A. Galip Ulsoy

This review paper is intended to provide, the mineral process engineer with an introduction to the concepts, terminology and practice of mineral process control. It also provides an extensive sampling of the vast body of literature relevant to this topic. The topics discussed include the principles of automatic control, instrumentation, mineral processing unit operations, process modeling and simulation, and process and plant control.

Dec 1, 1981

By A. E. Hall

"This paper summarizes findings of a two-month investigation in Zambia and Zimbabwe and a one-month visit to Britain in1990-1991. United States contacts have supplied information about that country.Zambia's political unrest and severe devaluation, combined with developments in Namibia and South Africa, enhanced staff recruiting problems in the School of Mines. Zimbabwe has a strong and developing mining department. The departments of mining in the United States and Great Britain are readjusting and contracting due to the reduction in the scale of the industry.The above factors are reviewed and their impact on the countries evaluated.IntroductionCanada trains the majority of its mining engineers domestically but a significant number are recruited from other countries. Examination of the qualifications of 200 professional engineers registered in the mining discipline in British Columbia showed that125 received their first degree from a Canadian university, 33 graduated from institutions in the United States and 42 from the rest of the world including 30 from the United Kingdom. This is a rough and-ready sample but it indicates that developments in the education of mining engineers in the United States and in Britain are relevant to the Canadian mining industry.The recent changes in the world economy and political structure have significant implications for the mining industry and for the supply and training of engineers. Change in eastern Europe coupled with the downturn in mining, especially in the European coalfields, has enabled many engineers to travel freely to the West. The low gold price and the legislative changes in Africa that have improved access to education for Africans with the ability to fill responsible positions, have reduced the South African mining industry’s overseas recruitment to a minimal level. The Australian recession has also lowered their recruitment of mining engineers from other countries."

Jan 1, 1993

By Wang Wenqian, George W. Poling

"Devices and flowsheets for recovering fine placer gold are reviewed. Inefficiencies of gravity processing techniques are documented and discussed. Prospects of combining gravity and froth flotation techniques are presented. Possibilities of using other separation techniques, such as magnetic and electrostatic devices are also discussed.IntroductionSeveral new methods for beneficiating different types of placer ores have been developed in the last two decades. Improved efficiencies in the recovery of fine particles have been achieved by improving gravity flowsheets and machines as well as by developing multiple treatment techniques involving flotation, magnetic and electrostatic separations. Placer gold processing, however, has been an exception to some extent. Gravity concentration using riffled sluices accompanied by mercury amalgamation is still the main method in use today. Because of this, the recoveries of fine gold and the other associated values are often similar to those achieved several decades ago. For example, very few sluice systems recover significant placer gold finer than 100µm in size.Only a few proposals for using alternatives to simple gravity methods for recovering fine placer gold can be found in the published literature. The fixed, low gold price discouraged research in this field for many years. Development of more efficient processes has not kept pace with the recent rapid escalation in the price of gold. Froth flotation for saving fine placer gold might now prove economic, for example. This paper reviews literature published on the recovery of fine placer gold over the period 1907 to 1980. Suggestions for improving the performance in this field, based on the authors' current testwork, are also presented."

Jan 1, 1983

By J. George Gregr

"This paper gives a brief review of grinding mills installation procedures with special emphasis on future maintenance. The importance of cooperation between the customer, construction contractor and manufacturer's representative is discussed, as well as the imparlance of complying with standards, specifications and the keeping comprehensive installation records.Fundamentals of mill maintenance are explained with the aim being to maximize the equipment availability and to minimize unscheduled downtime. The paper also includes development of wear items design, based on operating conditions, drive components and bearings, and how to keep large gears healthy thus eliminating surprise failures.Experience with installation of a large gear on a 34-foot diameter mill in Lornex and successful application of a computer program for the gear alignment on the mill are given.IntroductionSuccessful operation of a concentrator begins with the engineering of the project and continues through selecting the right equipment, its installation , start-up period, and ends with final tuning of the process. machinery and the human factor into an efficient and viable industrial complex.The following is a brief review of grinding mill installation procedures with special emphasis on future maintenance. Fundamentals of mill maintenance are discussed with the aim being to maximize the equipment availability and to minimize unscheduled downtime, with some specific points on key grinding mill components such as bearings and drives.Finally, the experience is recounted with the installation of a large ring gear on a 34-foot diameter mill at Lornex, and the successful application of a computer program for the gear alignment on the mill."

Jan 1, 1985

By H. Craig Boyle, Craig H. B. Leitch

"The Trout Lake stockwork molybdenum deposit is located in the Selkirk Mountains of British Columbia, 50 km southeast of Revelstoke. The property is being explored by a joint venture between Newmont Exploration of Canada and Esso Minerals Canada.The deposit is associated with a small granodiorite stock of Upper Cretaceous age (76 Ma) which has variably altered the surrounding schists, argillites and marbles of the lower Paleozoic Lardeau Group to hornjelsic biotite schists and skarn. The intrusive is composed of a small stock and an intersecting network of northeast- and northwest-trending dykes at surface that coalesce downward into a larger stock. There are two main phases of intrusion, with an earlier quartz porphyritic granodiorite cut by an intra-mineral ""quartz diorite"" porphyry. A strong sub-vertical north-trending fault controls the distribution of the mineralized stock work and displays post-mineral movement.Molybdenite, accompanied by pyrite and pyrrhotite, is mainly present along the margins of veins in a well-developed quartz stock work, but occasionally is strongly disseminated in microfractured intrusives. The stock work is strongest in and around the contacts of the intrusive and its apophyses, and occurs over a vertical range of more than 1,000 m. As defined by the 0.10% MoS] contour, the main mineralized zone is up to 300 m long by 200m wide. Preliminary drill-indicated reserves, currently being revised, are approximately 50 million tonnes of 0.23% MoS2, within which are several zones of higher-grade material. Hydrothermal alteration, as defined by quantitative X-ray diffraction studies on composite core sections, is composed of a central quartz/K-feldspar/albite/minor biotite zone coincident with molybdenum mineralization, which is overlapped by a slightly later, antipathetic quartz/ sericite/pyrite zone. Ankeritic carbonate is also a common alteration mineral, but only traces of fluorite, and no topaz or sulfosalts, have been observed. Analysis for trace elements such as Sn, W, Bi, Sb, As, Hg, U, Ag, Au, Mn, Cu, Pb, Zn and F has been limited except for Sn and W, which appear to be zoned inside and outside the Mo zone respectively; the other elements do not show detectable patterns thus far."

Jan 1, 1983

By H. R. Banks

SHORTLY after the commencement of operations at the Sullivan concentrator, the use of a pilot table was instituted in order to present a visual control of various products by showing the amount of galena still present in the tailing from several stages of flotation. Among the products so treated, the final tailing was later included. It was sratifying to note that very little free galena was escaping, but a fine streak o a whitish mineral appeared at the concentrate zone. This mineral was identified as cassiterite. The amount was small and the newly recognized component in an already complex ore was considered primarily as of academic interest. However, the problem of recovering a usable metal was intriguing and, as opportunity presented itself in temporary lulls in research on Sullivan and other ores, the concentration of tin was a useful 'bit of knitting' to go on with. It was recognized from the start that the bulk of the mill tailing would have to be floated and the residue subjected to gravity treatment. Since one of the predominating features of Sullivan concentration operation has been the necessity of fine grinding, the problem of gravity concentration was thereby intensified. Several batch runs were made, and sufficient pulp was treated to produce about one ton of final tin concentrate assaying 67 percent tin. The overall recovery was under 30 percent and the estimated profit at full tonnage was only marginal. Testing was resumed several years later, when the price of tin again appeared attractive, in an attempt to develop a more compact plant with better recovery of tin. The weakness of the original plan of concentration was the large number of tables required to treat a feed so low in tin.

Jan 1, 1941

By D. M. Morrison

"Microseismic systems at five mines in the Sudbury Basin provide the basic data for Falconbridge Limited's rockburst research. Daily and long-term analysis of this data as well as underground observations has confirmed the fault-slip mechanism of rock bursting at three mines. A detailed analysis of the complete history of Falconbridge Mine is being conducted and Distinct Element numerical models are being used to simulate both the stick-slip behaviour of faults and the dynamic effects of the induced vibrations on rock and backfill. University research includes acoustic tomographic imaging of the rock mass based on seismic wave propagation and collection of full micro seismic waveforms to allow application of advanced seismic and statistical analysis techniques. INTRODUCTIONFalconbridge Limited currently has five mines operating in the Sudbury Basin: East, Lockerby, Onaping, Fraser, and Strathcona Mines, which along with the Falconbridge open pit produced 2.8 million tonnes of ore in 1986. The underground mines range from about 600 m to 2000 m below surface and one of the consequences of mining at these depths is the occurrence of rockbursts.Research into rockburst phenomena at Falconbridge began over 25 years ago and research is continuing in an effort to avoid the problem by improved mine design, to protect mine openings from damage by design of effective support systems and to better understand the processes which precede a major fault slip rockburst. Since the early 1980s, significant progress has been made due principally to micro seismic monitoring and advances in microcomputer technology coupled with detailed underground investigations.It is now possible to identify the fault-slip mechanism as the cause of many of the rockbursts which occur at Falconbridge mines. By gaining an understanding of effect of mining-induced stresses on the pre-existing geological structures, areas which may experience rock bursting can be identified and can be protected against severe damage by appropriate support techniques."

Jan 1, 1989

By Michael Hopp

The beginning of the electroforming technology dates itself on the beginning of the industrial revolution 1800 to 1820 approximately. Basis was the existence of electricity in order to be able to drive the electro-form-process. With the development of the electroforming, big names of the science-history, like Michael Faraday (1791? 1867), Sir Humphry Davy (1778?1829), Max Schlöter (1878?1946), Werner von Siemens (1816?1892), and many others. Already about 1840, the first monograph originated to electroforming (38). While in the first years the electro-forming most extensive only to the coating of art - or other usefulness-objects was used. At the beginning of the 20th century the formation of objects from pure metals became more and more, later also from alloys to application. One of the first bigger electroforming factory, the ?Württembergische Metallwarenfabrik? was working 1894 in Geislingen / Steige, Germany. In the industrial application, the electroforming-technology is to be imagined away for miscellaneous coatingtasks and the form-body-preparation no longer today (18). A little bit confusing is the german name ?galvano-technology?. It based on the Italian physiologist and naturalist Luigi Galvani (1737 ? 1798). This technically seen is however wrong, right, the name is electroforming. The physical bases were founded mainly by Michael Faraday and Sir Humphry Davy.

Oct 1, 2003

By B. Karnath, K. Guha, S. Tandon

At Jhagadia Copper Ltd (India), Copper is produced through secondary route using Top Blown Rotary Converter (Kaldo Furnace). The basic raw material being treated includes Matte-slag Reverts, Copper Cakes, dross & Cement, Oxide Ore, Low S bearing Concentrates & various metallics along with high grade copper scraps. The plant has capability to refine & produce Blister grade copper from Kaldo furnace as well as PS Converter . Blister is fire refined in Anode furnace & electro refined in Refinery to produce cathode copper. Our product , Copper Cathode , has already been established in the market as its quality is better than 'LME Gr'. The paper deals with the experiences encountered during commissioning & stabilization of the plant.

Jan 1, 2007

By S. Parkash, A. J. Szladow

Vigorous agitation of suspensions of coking coals in water (or light mineral oils) will often result in catast rophic loss of caking properties. It is shown that this deterioration is not a consequence of oxidation of the coals (by dissolved oxygen), but that it can be qualitatively connected with internal "solid-state" reactions which appear to derive their activation energies from cavitation of the liquid.

Jan 1, 1971

By Brian Hart, Stamen S. Dimov

"The naturally occurring carbonaceous material (CM) in gold bearing ores often exhibits strong-preg-robbing properties. It can adversely affect the process of gold recovery during the cyanidation due to its ability to adsorb, or preg-rob gold from the cyanide leach solution.Treatments of carbonaceous ores with chemical surfactants as blinding agents to limit preg-robbing have shown promising results but at the same time have demonstrated that, if not properly used, could have a strong detrimental effect on the gold recovery process. High dosages of surfactants used as passivating agents for carbonaceous matter could lead to unwanted partial passivation of the activated carbon added during the CIL process and severely impact the gold recovery. Optimal dosage for various surfactants would strongly depend on the ore mineralogy and the parameters of the pulp (temperature, pH, surface area and maturity of the carbonaceous material, etc).This paper describes an experimental study on the effectiveness of various commercially available blinding agents used to minimize the preg-robbing capacity of naturally occurring carbonaceous matter. The scope of the study was to: i) establish the optimum addition of blanking agent (surfactant) to minimize the preg-robbing capacity of the CM in the ore, and ii) establish maximum threshold amounts of blanking agents to be used before it negatively impacts the preg-robbing capacity of the activated carbon used in the CIL process. The study procedure involves standardized doping tests to evaluate the maximum preg-robbing capacity of treated CM, coupled with surface analysis with ToF-SIMS to monitor the presence and the degree of loading of these chemical surfactants on both the naturally occurring CM and the added activated carbon.INTRODUCTIONNaturally occurring carbonaceous material (CM) in gold bearing ores often exhibits strong-preg-robbing properties. Thus, it can adversely affect the process of gold recovery during cyanidation due to its ability to adsorb, or preg-rob gold from the cyanide leach solution. The preg-robbing properties of this naturally occurring carbonaceous matter can vary widely between ores, and within a single ore body (Dunne et al.,2013;Helm et al.,2009;Miller et al.,2005). The degree of preg-robbing related to the CM within an ore is defined by several parameters: total organic carbon (TOC) content, surface area, maturity (i.e., crystallinity) of the CM and the presence of various functional groups on the surface of the CM. Preg-robbing gold ores continue to be a significant challenge because of the lack of a single or universal solutions."

Jan 1, 2016

By Patricia J. Dillon

Established in 1997, Prospectors and Developers Association of Canada Mining Matters (PDACMM) is a registered charitable organization dedicated to providing Earth Science education to grade school students. Through the development and distribution of educational programs and materials, PDACMM informs students of Canada?s geology and mineral resources as well as promoting awareness of the importance of rocks, minerals, metals and the mining industry. PDACMM also co-ordinates with other charitable organizations and government agencies to provide support or to work in tandem with them and reach as many young people as possible. Although PDACMM became a charitable organization in 1997, it actually has its? roots in 1994 when the Grade 7 program Mining Matters/Une Mine de Renseignments was developed to help teachers bring geology and mining into the classroom. Over 2100 of these resource kits were distributed to teachers across Ontario during the period 1995 to 1998. This unit won national recognition when it received the prestigious Partnership Focus award from the Conference Board of Canada for ?promoting science literacy for the world of work?. Due to the phenomenal success of these kits, a Grade 4 kit entitled Deeper and Deeper/Aller au Fond Des Choses was developed in 1998 in response to the opportunity provided by the new Ontario curriculum released at that time. Over 2600 of these kits were distributed throughout Ontario and there is a substantial waiting list of teachers hoping PDACMM will be able to raise enough money for another print run.

May 1, 2002

By G E. Craig, W. M. Williams

A simple, easily constructed apparatus suitable for the zone refining of iron and other reactive materials is described. After eight passes at one inch per hour, the iron produced showed a marked drop in hardness to 49 Brinell. In addition, an arbitrarily -defined recrystallization temperature was lowered by about 35°C and the rate of grain growth greatly increased. CERTAIN materials, of which iron is one, are so reactive that they cannot be zone refined in any known container without becoming contaminated. For such substances, the floating zone method ( 1) may be used. In this method, the specimen is supported vertically in an inert atmosphere and the molten zone supports itself by its own sur-face tension. The method was first applied to silicon (2) and has since been used for other reactive metals such as zirconium and titanium. Smith and Rutherford (3) have previously reported on the floating zone refining of iron; the efficiency of the method for reducing the car-bon content was demonstrated on

Jan 1, 1962

By V. Vorontsov

Catalysts Mo-Ni-S were prepared by combining MoS2 and NiS in weight ratios 1:1, 1:2, 1:4 and 2:1, each of which was admixed with 5%wt Ag and 5%wt YSZ to increase three-phase boundary surface area of the electrode. For comparison catalysts comprising Co-Mo-S in weight ratio of 1:1 of CoS to MoS2 admixed with 5%wt Ag and YSZ and pre-sulfided NiMoO4 were made. The catalysts were examined for electrochemical oxidation of hydrogen sulfide in solid oxide fuel cells (SOFC) at 850°C temperature. The catalyst prepared from 1:1 (wt. %) NiS:MoS2 demonstrated highest performance. Current density up to 1,330 mA/cm2 and power density up to 300 mW/cm2 were achieved using pure H25 gas, which are the highest among the reported H2S-powered fuel cells ever published in the literature. Anode materials of different NiS:MoS2 ratios have been characterized by means of X-ray diffraction (XRD), simultaneous TG/DSC analysis and Neutron Activation Analysis (NAA). TG/DSC and NAA results show that addition of NiS and Ag increases fuel cell performance due to improved structure/integrity of the anode. It has also been demonstrated that MoS2 is a suitable anode material in H2S-powered SOFC, with high activity towards H25 oxidation and thermally and chemically stable up to 850°C.

Jan 1, 2005

By C. Boudreault, M. Fortier, S. Fafard

In the forging industry, the increasing trend is to use DC cast billets as forging stock to replace extruded stock. However, there is little technical information available in open literature. In order to gain a better understanding of the behaviour of cast stock during deformation, a study was initiated to evaluate the impact of an homogenisation treatment on the billet prior to cold forging. Axisymmetric upsettings of cylindrical samples machined from DC billets were achieved in order to evaluate and compare flow stresses, crack initiation and propagation. Results show a 30% decrease in flow stress after homogenisation. Observations of the deformed samples show major cracking for the as-cast material. Optical microscopy and SEM observations have related the crack initiation to decohesion around ß -AlFeSi particles and subsequent growth along the constituent path. Homogenisation effectively breaks up and transforms the ß phase, present as platelets in the cast product, into smaller spherodised a-AlFeSi particles. This has the effect of preventing crack growth in the forged product. The homogenisation treatment also resulted in the reduction of Mg and Si in solid solution. The softer matrix generated 29% less die wear when compared to the as-cast structure. Based on the results of this study, it is thus recommended to homogenise cast billets prior to cold forging.

Jan 1, 2006

"The Val d'Or Division now comprises the Lucien C. Beliveau Mine and Concentrator (formerly the Pascalis, described below) and the Chimo Mine. Cambior acquired an initial 50% interest in the Chimo Mine in May 1989 and the remaining 50% in April 1990. Cambior's share of 1989 production was 2121 ounces; the company expects to net 23 750 ounces from Chimo in 1990. Pascalis MineUPDATERenamed the Lucien C. Beliveau Mine at its official inauguration in September 1989, the mine is exceeding forecasts, producing over 11 500 ounces of gold in the first half of 1990. Cambior expects 1990 production to total 34 000 ounces.IntroductionThe Pascalis Mine is located 16 miles east o f Val d'Or, Quebec, and is accessible by a three mile gravel road off highway 117 (Fig. I).The property is wholly owned by Cambior.The Pascalis gold deposit consists o f a sub-vertical diorite dyke 1000 ft long by 30 ft wide containing quartz and tourmaline veins with inclusions of pyrite and native gold . Three vein systems ca n be seen in the deposit , the most important being tensile veins oriented at a right angle to the direction of the dyke and inclined at 40 degrees. These overlapping veins vary in thickness from 4 in. to 40 in. and occur at intervals of six to ten ft. The deposit is, therefore, very difficult to evaluate; a complete evaluation would require drifts over the whole width of the dyke combined with relatively short drill holes (Fig . 2)."

Jan 1, 1990

Orebodies of the Renison Bell - Mt. Bischoff tinfield in Tasmania are stratabound, conformable lenses of massive cassiterite-bearing pyrrhotite, with underlying discordant, fault-fracture-controlled and more siliceous ore. The deposits occur in eugeosynclinal, trough-deposited sedimentary and mafic volcanic rocks which are stratigraphically equivalent to diff erentiated volcanic rocks that contain volcanogenic massive base metal sulphide deposits in a parallel arc to the east. Textures of the massive pyrrhotite ore suggest that it has undergone metamorphic recrystallization. Although the massive ore contains both monoclinic and hexagonal pyrrhotite, a study of a few samples from one orebody suggests that their distribution is stratigraphically controlled, with the monoclinic variety abundant only at the base. The distribution pattern of rare-earth elements in massive ore is similar to that of volcanogenic massive base metal sulphides in New Brunswick, and suggests that mixing of sea water with exhalative hydrothermal brines occurred during ore deposition. Tin is a common accessory element in many volcanogenic massive base metal sulphide deposits providing strong evidence that it, too, is transported and deposited by volcanic affiliated hydrothermal brines. Sedimentary rocks containing the massive orebodies are fine grained, thinly laminated, compositionally banded and of mixed chemical sedimentary-tuffaceous origin. They include finely recrystallized chert, carbonate-rich and pyritic varieties; and soft sediment deformation structures in these rocks suggest that dense sulphides deformed underlying, less dense chert prior to lithification. Close to ore the chert becomes massive and coarsely recrystallized, as does the carbonate, which is here strongly enriched in Fe and Mn. Apatite is present in pyritic, cherty and carbonate-rich beds and in the ore itself, in all of which it shows a similar pattern of rare-earth element distribution, suggesting that it is of marine sedimentary origin. These deposits have traditionally been considered as epigenetic replacements of favourable carbonate horizons by hydro thermal flu ids derived from later Devonian porphyritic intrusions. Some of these intrusions have associated tinbearing greisens. The above relationships suggest, alternatively, that, like massive base metal sulphides, the tin deposits were of original syn-sedimentary origin. Circulating hydrothermal brines generated during early Cambrian eugeosynclinal subsidence and tectonism rose through steep fault-fractures, there giving rise to the discordant orebodies, and were discharged on the sea floor, where the massive pyrrhotite lenses were precipitated with the associated cherts and carbonates. In some places, Devonian intrusions remobilized the earlier deposits, forming greisens and newepigenetic veins. Finally , the geologic selling of these deposits, in trough deposited sedimentary and mafic volcanic rocks, suggests another favourable environment for massive sulphide exploration which is quite different from the domal felsic volcanic environment so heavily favoured currently in North America

Jan 1, 1979

By Laxman M. Amaratunga

Laboratocy flarmnability tests were perfonned on dust samples from Fraser Mine in a 1.2 L Lindenburg horizontal tube furnace to detennine the percentage of sulphur oxidized during ignition. The explosion pot ential of sulphide dusts depends on their degree of spontaneous oxidat ion, which was measured by the quantitative analysis of so2 gas released during ignition. Test results indicated that dusts with low sulphur content could exhibit a higher degree of oxidation than a sample with high sulphur content. txlst characterisation using image analysis techniques suggests that the structure and the texture of dust are important factors influencing the explosibility of sulphide dust at ignition temperatures. Therefore for safe mine operations% sulphur content cannot be considered as a reliable single index that could be used to predict the potential of a sulphide dust explosion. Physical, chemical and mineralogical characterisation of dust plays an important role in the detennination of suitable indices for the prediction and prevention of sulphide ore dust explosions.

May 11, 1988

By W. Beres, R. E. Miller, B. Shiari, L. R. Zhao

A dynamic multiscale simulation method has been developed to study the material scratching processes on nanoscale single crystals. The model simultaneously captures the atomistic mechanisms near the free surface and the long range mobility of dislocations and their interactions, without the computational cost of full atomistic simulations. The method also permits the simulation of system sizes that are approaching experimentally accessible systems, albeit in 2D. Simulations are performed on single crystal aluminum to study the atomistic details, surface evolution, and generation and propagation of dislocations for a variety of scratching depths at room temperature. Simulations demonstrate the power of the developed method in capturing both long-range dislocation plasticity and short-range atomistic phenomena during tool advance. Variations of scratching normal and tangential forces are investigated and related to plastic deformation and dislocations generation during the simulation process.

Jan 1, 2006

By K. M. Deen, E. Asselin

Hydrometallurgical processes, i.e., Cu extraction from a mineral concentrate and Zn electrowinning, are coupled in a battery-like system. A naturally-sourced CuFeS2 concentrate mixed with activated carbon is used as a positive slurry electrode separated by a membrane from the negative compartment. The Zn is deposited on the negative Al current collector from the circulating solution containing 100 g L–1 Zn2+ in 0.2 M H2SO4. In this battery-like system, both CuFeS2 oxidation and Zn deposition are possible during the charging cycle. The additional benefit of this setup is the energy storage if discharged by re-dissolving the Zn in the negative compartment. Cyclic charge/discharge testing revealed oxidation of the mineral concentrate supported by the Zn2+/Zn redox reaction. The coulombic and energy efficiencies increased monotonically to 95.6% and 43%, respectively, with approximately 7% Cu extraction during the first 10 charge/discharge cycles (completed in 2.4 hours). The discharge energy density also increased from 2.7 to 36.2 mWh L–1. In the following 90 cycles, the low energy (~14%) and coulombic (~33%) efficiencies that were obtained confirmed the progress of irreversible reactions e.g. Cu extraction from the mineral concentrate. Overall, approximately 16% Cu was extracted from the mineral concentrate over 100 charge/discharge cycles (or about 12.2 hours). INTRODUCTION Chalcopyrite (CuFeS2) is the main economic copper-bearing mineral, which is generally processed through pyro-metallurgical methods to produce Cu. However, environmental challenges with smelting, depletion of high-grade ores and a large number of impurities (some toxic) have resulted in continued research aimed at the development of hydrometallurgical technologies to process CuFeS2. There are a number of different proposed hydrometallurgical routes in the literature to treat CuFeS2 concentrates, but only a few have attained commercial acceptance (Dreisinger, 2006). Zn is another commercially important metal that is mainly produced via acid leaching of roasted sphalerite (ZnS). The pregnant leach solution is rigorously purified to remove all the soluble metal impurities, particularly those that are electrochemically more noble than Zn and present large kinetic activity towards H2 evolution (Hu & Piron, 1992; Mackinnon, Brannen, & Fenn, 1987; Mureşan, Maurin, Oniciu, & Gaga, 1996). Metal impurities such as Cu, Co, Ni, Cd, Pb, Sb, As, Ge and Fe etc., if they exist in the leach liquor beyond the tolerance limits, can decrease the current efficiency during electrowinning and deteriorate the deposit quality (Alfantazi & Dreisinger, 2001). A complete flow sheet, describing the process steps of Zn metal production from mine site to pure metal is presented elsewhere (Brown, Meisenhelder, & Yao, 1983).

Jan 1, 2019