Search Documents

By G. F. Vander Voort

Over the past twenty years, steelmakers have introduced improved practices for reducing the inclusion content of steels. The success of these practice changes can be monitored in a variety of ways. Chemical analysis of the bulk sulphur and oxygen contents provides a relatively simple means to assess the impact of these changes. However, microscopical test methods are still needed to assess the nature of the inclusions present. Traditional chartbased measurement methods have wide acceptability, and their data are well understood by both purchaser and producer for heat acceptance purposes. However, these methods do have inherent weaknesses which limit their usefulness for quality control, SPC, and database applications. Image analysis-based chart measurements are an improvement over manually generated chart ratings, but the data still do not lend themselves to databases and statistical comparisons. ASTM Committee E-4 on Metallography has developed a stereologicallybased image analysis standard test method, E 1245, which provides the necessary data in a form which is easily databased and analyzed statistically. This paper describes E 1245 and shows how data from different heats and melting practices can be compared statistically to ascertain valid test differences.

Jan 1, 1998

By Isabel C. B Rodrigues, Flávia D. Reis, Versiane A. Leão, Rosa M. F. Lima

Attention has been focused in recent decades upon the precipitation of metal sulphides from acid mine drainage (AMD) and pregnant leach solutions, due to the advantages of the sulphide precipitation process over traditional methods employing hydroxides. The aim of this work was thus to explore technologies for copper precipitation using either Na2S or biogenic sulphide. The recovery of copper sulphide was improved when the initial pH of the solution containing each metal was 4 or excess sulphide was employed. In such, a condition the removal efficiency was 99.9%, corresponding to a residual level of 0.1mg/L for copper in solution. Kinetic parameters for precipitation were determined from the particle size distributions using the method of moments, where the growth and nucleation rates, as well the agglomeration kernel, were calculated. The biogenic sulphide was a suitable alternative to sodium sulphide for copper removal as either sodium sulphide and biogenic sulphide can be utilized to precipitate such a metal allowing the effluent to be compliant with environmental legislation.

Jan 1, 2014

By D. Farrish, W. A. Grell

"IntroductionMost base metal mines sell their concentrate to a custom smelter. The two parties concerned therefore draw up a contract which would detail the conditions under which concentrate sales will take place. The contract will identify treatment and marketing charges (including escalations), deductions for metal losses in the smelter, pricing formula, timing of payments, penalties for deleterious elements, etc.An understanding of the smelter contract is important to the mineral processor, for it will determine how he operates the plant to maximize economic return.Description of Contract ClausesUsing copper concentrate as an example, the smelter contract generally contains the following three basic charges:I. Metal Deductions- as the smelting process does not recover all the metal contained;2. A Smelting Charge- expressed per ton of material to cover costs on the bulk material such as receiving, unloading, thawing in winter, sampling, roasting to drive off sulphur, smelting through the matte and blister stages to recover mostof the copper and precious metals;3. A Refining Charge- expressed per pound of copper.The following is a review in some detail of a number of clauses which could be considered typical of a treatment and marketing type of copper concentrate sales contract. Most normal considerations in an agreement could be covered by the following types of clauses.Terminology- covers definitions, units of measurement to be used (e.g. short tons, troy ounces, etc.), currency (Canadian dollars). The term ""unit"" may be defined - l OJo of a ton of concentrate, e.g. one unit of copper means 20 pounds of copper per short ton of concentrate."

Jan 1, 1989

By P. Nelson, B. Salt, J. A. Scott, H. Shang

ABSTRACT In a nickel smelting process, large amounts of off-gas emissions are generated, which can cause serious environmental and plant hygiene problems if not properly treated. With increasingly stringent environmental regulations, an enhanced understanding of well-controlled, off-gas cleaning systems is vital. In this paper, dynamic models for an industrial smelter, off-gas system tackling hazardous sulphur dioxide, carbon monoxide, and carbon dioxide are developed using mass continuity, momentum, and energy conservation laws. The effect of air in-leakage is explored under different operating conditions. The developed models provide an enhanced process understanding and a necessary basis for highperformance control analysis of smelter off-gas systems.

Jan 1, 2011

By F. Baerhold

Recycling of hydrochloric acid from the pickling of mild steel using pyrohydrolysis is a state-of-the-art technology. Recent developments have focused on the production of a high value iron oxide by-product, where the chemical purity and physical properties are the main issues. New processing routes, especially for TiO2 and Ni production, use leaching operations with hydrochloric acid. The feasibility of those processes depends on the availability of an economic and reliable process for the recovery of the acid. Depending on the level and type of impurities and the required specification of the by-product, pyrohydrolysis in a fluid bed or in a spray roast reactor can be the ideal solution. In stainless steel annealing and pickling lines, a mixture of nitric and hydrofluoric acids is used to remove the scale from the surface after heat treatment. Nitrate emissions from the pickling and the rinsing processes have to be avoided because of more stringent environmental regulations. An annealing and pickling line that is totally wastewater-free was developed, where not only the nitric/hydrofluoric acid but also the rinse water, is completely recycled. New developments to increase the HNO3-recovery rate and to obtain a metal oxide by-product that is easier to recycle are presented.

Jan 1, 2006

By H. J. McQueen

Aluminum was hot worked at 400 - 500°C and strain rates (e ) of 0.004 -0.1s-1, under reversing strains (c) of 0.5 to 0.2 or 0.5 to 0 and also advancing from 0.5 to 1 or 0.5 to 5. Under similar test conditions for different parts of the strain paths, the average measured flow stresses are found to agree with each other. In the forward and backward strain path tests, the almost identical steady state plateaus affirm the occurrence of dynamic recovery (DRV). On reversal of strain direction at constant e , there was generally negligible Bauschinger effect. In specimens annealed at 400°C, static recrystallisation (SRX) was followed microstructurally. mainly by disappearance of elongated grains with serrated boundaries because the new grains were only little a finer than the old due to low strain energy. The only influence of reversing strain path observed was the effect of change of grain boundary area as grains elongated or returned towards equiaxed. In optical microscopy, elongated grains with serrations and deformation bands confirmed DRV in forward path specimens. In reverse path specimens, equiaxed grains were gradually restored with retention of serrations and bands. In low magnification polarized optical microscopy, grain alignment increased with strain for forward path specimens; whereas it decreased in reverse path ones, supporting DRV. Orientation imaging microscopy (OIM/SEM) revealed that elongated grains are broken up as deformation bands rotate during the forward path and that grains return to equiaxed appearance on backward straining. Comparative studies using optical microscopy in polarized light (POM), OIM/SEM and transmission electron microscopy (TEM) revealed that while subgrains remain equiaxed and constant in size and character during the forward and backward paths, the fraction of low angle facets decreased while that of high angle grain facets increased with increasing strain; these are coupled with a fairly low fraction of medium angle boundaries. The results contribute to the understanding that dynamic recovery in aluminum maintains sub-boundaries with low misorientation but as grains elongate and more subgrain become adjacent to grain boundaries the fraction of high angle boundaries rises (with backward straining it was vice versa).

Jan 1, 2007

By E. O. T. Simpson

"IntroductionAS COMPARED with coal mines in the United States, and even with some of those in eastern Canada, the coal mines of western Canada, generally speaking, :have made little progress toward mechanization at the working faces. So far as Vancouver island is concerned, there are three main reasons for this : ( 1 ) in some areas, conditions• easy for hand-loading but unsuitable for mechanical loading make high outputs per man •possible by the former method; (2) faulting of the coal seams in ..some areas precludes long-term planning and the introduction and efficient use of expensive equipment; (3) thinness •and other characteristics of the seams in many areas favour hand-loading.No. 8 MINENo. 8 mine of Canadian Collieries (Dunsmuir), Limited, is located in the Cumberland sub-area of the Comox coalfield on Vancouver island about 90 miles west-northwest of Vancouver. The geological structure of this coalfield has been described by J. D. McKenzie. The seams occur in the Comox formation, a subdivision of the Upper Cretaceous Nanaimo Group. The formation is of near-shore origin and was laid down on an irregular surface of' older rocks. The irregular generally have a northeasterly dip, modified by gentile folds and by a •few large, and a number of smaller, faults.Four seams have been worked in the Cumberland area and all vary in thickness and in the amount and number of interstratified bone and rock •bands."

Jan 1, 1953

By J. E. Moran

A groupd of French capitalists, La Compagnie Française des Mines d'Or du Canada, has undertaken the considerable task of developing Otter creek, in the Atlin district, B.C., by hydraulic mining methods. It has long been known that the gravels of this stream carry sufficiently high values in gold to make it attractive as a mining venture, but it was impossible to ignore the existence of formidable natural obstacles to hydraulicing them, and these needed to be taken into serious account before embarking upon any costly programme of development. The tide to the Otter Creek leases was originally held by Mr. H. Maluin, a French engineer well known throughout the north, to whom was to fall the task of financing whatever programme might be decided upon. It was he, too, who would have to assume the responsibility of finally passing judgment upon the practicability of the various devises for overcoming the adverse natural conditions. With an infinite attention to detail, which I believe to be a characteristic of the French people generally, he studied his problem and was finally able to submit to his financial backers a programme which left the very minimum possible to the hazard of accident or chance. Dr. Mandy, on his visit to Otter creek this season, expressed the opinion that our method of opening this difficult creek presented certain features which might be successfully applied in placer operations elsewhere in British Columbia, and it is largely for this reason that the present paper has been prepared. I shall set forth, as well as I can, the practices which have enabled us to overcome rather easily some of the obstacles which nature had unkindly placed in the path which we must take. The natural flow of water in Otter creek is far too little to deal success-fully with the rather excessive amount of glacial drift overburden which lies directly over the gold-bearing gravels. For this natural defect, the only remedy was to procure more water. This we have clone through a system of flumes and ditches, totalling between ten and eleven miles in length, which bring to the mine a supply of water adequate for our needs.

Jan 1, 1932

By K. B. Young

Possibly the most complex fatigue problem associated with the development of the axial-flow 'gas turbine is discussed in its broader aspects from the metallurgical viewpoint. Reference is made to nodal patterns, interference diagrams, etc. The use of such data in analysis of a turbine :blade failure is illustrated. Special attention is given to the influence of some metallurgical variables affecting fatigue strength and, in particular, heat treatment is shown to have a pronounced effect on .the relative fatigue and creep strength properties of a nickel-chromium-cobalt base alloy suitable for turbine blade applications.

Jan 1, 1958

By M. Kawata, T. Amano, T. Miyamoto, K. Shibayama

"The High Pressure Acid Leach (HPAL) plant of Taganito HPAL Nickel Corporation (THPAL), located in Taganito, Philippines, with a nameplate capacity of 30,000 Ni-t/year started commercial operation on October 2013. The plant load was smoothly ramped up and it achieved monthly production equivalent to 33,000 Ni-t/year in 2016. Partial improvement of the plant capacity for the achievement of 36,000 Ni-t/year, as evaluated from the current operation progress of each system is planned for 2017. In this paper, aside from presenting the progress of the plant ramp-up, research and development activities such as the reduction of nickel loss and the improvement of filtration capacity which was achieved by particle size control of ZnS precipitates in the Zinc Removal system are also discussed.INTRODUCTION Taganito HPAL Plant Project History of THPAL Taganito HPAL Nickel Corporation (THPAL) was incorporated in August 2008, as a joint venture of three (3) companies, namely Mitsui Corporation with 15% share, Nickel Asia Corporation (NAC) with 10% share and Sumitomo Metal Mining Corporation (SMM) with a controlling stake of 75%. Aside from its capital share, NAC’s Taganito Mining Corporation (TMC) supplies the ore for the HPAL plant located in Taganito, Claver, Mindanao, Philippines. The objective of THPAL is to produce 30,000 MT of nickel and 2,600 MT of cobalt as mixed (Ni/Co) sulfide by treating nickel laterite ore in the Philippines and exporting to Japan as raw material for SMM’s Niihama Nickel Refinery (NNR) for the next 30 years. In other words, 1.15 wt% of nickel in ore is refined to 99.99 wt% nickel in electrolytic nickel. The mixed (Ni/Co) sulfide is shipped to NNR and SMM provides the technology and management personnel to THPAL plant as well as sulfuric acid which is the main reagent for HPAL process. Figure 1 shows the location of THPAL and current relationship between the stake holders.The Characteristics of THPAL Plant In terms of plant design, a 2-train system is applied for the HPAL circuit considering the reliability of the process, facility and avoidance of whole plant shutdown due to HPAL troubles. The technical data, operation know-how and improvements gained from the successful operation of Coral Bay Nickel Corporation (CBNC) which was established in April 2002 were reflected in THPAL’s plant design. As for the H2S plant, a more economical design was considered which is different from CBNC."

Jan 1, 2017

By M. Staite

This paper analyzed the feasibility of converting a 5kW natural gas SOFC power generator system designed to operate on natural gas to be fuelled by methanol. The analysis included laboratory methanol fuel processing experimentation, methanol reformate SOFC cell testing, and SOFC system mass and energy balance modelling. Methanol fuel processing experimentation indicated that theoretical reformate compositions can be achieved for high temperature (600-900°C) methanol steam reforming. A 6% open circuit voltage decrease and a 10% peak power current density decrease between cell operation on humidified hydrogen and methanol reformate was observed. SOFC system mass and energy balance modelling indicated that a natural gas SOFC system can be converted to operate on methanol fuel with minimal (1%) efficiency impacts, however the systems' thermal integration can be impacted.

Jan 1, 2005

By W. Dingley, G. R. Hoey

"AbstractWear of six types of grinding balls was compared with and without corrosion inhibition in grinding Ni-Cu sulphide and hematite ores in laboratory ball mills. Forged steel balls (Rc 60 to 65) and three types of white cast iron balls (Rc 50 to 65) were susceptible to corrosive wear and two types of stainless steel balls [AISI Type 440C (Rc 65) and AISI Type 302 is; 35)] were relatively immune. The relative wear rates of the five types of hard balls (Rc 50 to 65) were dependent on the corrosivity of the ore. Ranking of the hard balls with respect to wear resistance was consistent for the sulphide and hematite ores in the presence of corrosion inhibition, whereas their ranking was different for the two ores in the absence of inhibition.The electrochemical potential of the grinding balls was measured during grinding and was found to be a useful measurement for assessing the susceptibility of an alloy to corrosive wear. Reduction of ball wear for forged steel and white cast irons with corrosion inhibition was concomitant with a shift of ball potential to less active values. Ball potentials in the presence of inhibition were indicative of non-corroding metal surfaces.IntroductionA PREVIOUS STUDY by the authors (1) showed that corrosion inhibitors - sodium nitrite, sodium chromate and sodium metasilicate - reduced wear of forged steel grinding balls by up to 49% in grinding Ni-Cu sulphide ore. Although the mechanism of wear reduction was not elucidated, it was concluded that corrosion must play a significant role in the wear of grinding media. Remark and Wick (2) of Battelle Pacific Northwest Laboratories have also evaluated corrosion inhibitors for the reduction of metal wear using abrasive and n on- abrasive te sting procedures. Their research was sponsored by 16 companies throughout the world. Preliminary results indicated that anodic inhibitors prevent from one-fourth to one-half of the loss due to corrosion."

Jan 1, 1977

By K. D. Peaslee

Slag splashing is an important development that has dramatically improved BOF vessel campaign life and reduced operating costs. This paper highlights research from physical modeling work using a 1/8-scale room temperature model BOF and slag characterization studies from several plants in North America and China. In the model studies, gas flow rate during blow and viscosity of the liquid were found to be two of the most important factors to changing the overall rate of liquid splashed onto the vessel sidewalls. When the flow rate was increased or viscosity decreased, the lower regions of the walls were splashed at a much greater rate. It was also shown that by changing the lance height, more liquid was deposited in the upper regions of the vessel at the expense of lower regions. Reducing the number of nozzles was found to be the most effective method of selectively coating a particular vertical section of the wall. Studies of BOF's using slag splashing in North America and China showed a difference in the melting characteristics of the final slag. Generally, slag splashing is successful when the melting point of the slag is 220-270°C below the tap temperature to maintain a balance between fluidity and refractoriness.

Jan 1, 2004

By S. Nafisi

Permanent mould casting may be regarded as a near net shape manufacturing process where simple to very complex shaped engineering components are fabricated with high degree of precision in a metallic mould, In this group, High Pressure Die Casting (HPDC), have attracted more attention because of its production rate, where both liquid and semisolid metals (SSM) can be cast with high degree of precision and versatility. The SEED process, Swirled Enthalpy Equilibration Device, the new process for semi solid metals slurry production route, consists of two steps: The initial step involves extracting specified amount of heat from the molten metal to generate liquid-solid slurry, i.e, mushy structure, followed by drainage of remaining liquid to produce a compact free standing feedstock for rheocasting operation. In this paper, microstructural evolution during the process and some initial casting results of automotive components an also reported.

Jan 1, 2005

By F. H. Samuel, H. Tahiri, S. Valtierra, H. W. Doty, A. M. Samuel

L'affinage des grains dans les alliages d'aluminium consiste à augmenter le nombre de sites de cristallisation de la phase a-Al afin d'obtenir une structure fine. Les alliages mères de type Al-Ti-B sont largement utilisés comme raffineurs des grains. Cette étude a pour but d'établir des mécanismes convenables d'affinage des grains dans l'alliage A356 en utilisant cinq alliages mères et deux températures de coulée (750°C et 950°C). Les résultats montrent que la phase a-Al prend une forme selon l'alliage mère ajoute; les échantillons coules a haute température montrent une taille de grain plus grosse; les températures de germination et de croissance augmentent avec I' augmentation du Ti ou du B et la taille des grains diminue. L'alliage mère Al-4%B montre une puissance remarquable en comparaison d'autres alliages mères. Pour cet alliage mère, le titane résiduel dans l'alliage A356 réagit avec le bore pour former TiB2 qui, par la suite, agit comme un germe actif pour la phase a-Al.

Jan 1, 2006

By Lex L. Udy

External-detonation-generated plasmas, highly ionized zones of reacting material ejected from the surface of detonating explosive charges, are shown to be the cause of channel desensitization, i.e., the self-quenching of a detonating explosive column loaded in a borehole with an air annulus between the explosive and the borehole wall. The effects of this phenomenon on several explosive compositions and types are demonstrated and discussed. The explosives tested include aluminum-sensitized and explosive-sensitized slurries, ANFO, liquid explosives and dynamites. Various techniques are described that can be used to reduce or eliminate the plasma effect.

Jan 1, 1979

By Chris Twigge-Molecey

Demand for metals will continue to grow as global population numbers and prosperity levels steadily increase. Consequently, there will continue to be a need to design and construct new metallurgical plants. Business success in general requires projects to be financially successful and return appropriate value to their owners. However, in the metals industry, private and public sector financing sources have become very sensitive to the perceived inability of projects to contain costs and meet other business objectives. Thus, the capital for projects has become more difficult and expensive to obtain. It is instructive to note that Ernst and Young (2011) identified that: “Delivery of predictable project results bestows competitive advantage and market confidence to those corporations who successfully instill this discipline”. The implication for future projects is that they must be systematically developed to minimize perceived risks—and more importantly—to demonstrate that the risks are managed to achieve the business case. Then, provided that the project has been developed in a well-structured way, project success can again be defined as a project with: a final cost within 10% of the budget approved at the end of FEL3, when the project is properly defined and the permit conditions are agreed upon; a start-up date within three months of the definitive, scheduled startup date; production levels at 85% of design capacity within a year of starting commercial operation; production meeting the target environmental restrictions; and with zero lost time accidents during construction and startup. The plant design is one of many integrated activities required to achieve these objectives. This book represents a valuable link between the existing engineering literature that encompasses a wide range of engineering fundamental textbooks and design manuals and the project management literature such as the Project Management Body of Knowledge, or PMBOK® (Project Management Institute, 2014). It is evident throughout this book, that the design team is a small but essential part of a much larger project team comprising the project management, construction management, and construction contractor staff. Design activities must be regarded and managed as part of the integrated whole, with two fundamental links throughout the design process:

Jan 1, 2015

By G. I. Mathieu

"An experimental study was carried out to evaluate the performance of column flotation versus conventional flotation for the recovery of molybdenite from a Newfoundland ore. The objective was to verify the claims made by the inventors of the flotation column, Messrs. Pierre Boutin and Remi Tremblay, that their apparatus reduces the entrainment of fine gangue and other mineral impurities in the froth product. The research included a factorially designed series of tests to determine satisfactory operating conditions of the column. These provided a basis for comparative flotation tests with column and Denver cells. In the course of the work, the action of a few depressants was studied. Results indicated greater selectivity in the column and reduced reagent consumption."

Jan 1, 1972

By Hong Zhong, Shuai Wang, Fangxu Li, Guangyi Liu

"The flotation performances and adsorption mechanisms of a-hydroxyoctyl phosphinic acid (HPA) to malachite, cassiterite and wolframite were investigated by micro-flotation tests and X-ray photoelectron spectroscopy (XPS) analyses. The micro-flotation results indicated that compared with styrene phosphonic acid (SPA), diphosphonic acid (DPA), benzohydroxamic acid (BHA) and salicylhydroxamic acid (SHA), HPA exhibited excellent collecting power to the three oxide ores. In addition, HPA showed superior selectivity against hematite, tourmaline, feldspar and quartz. The results of XPS analysis demonstrated that HPA reacts with active species (M) on metal oxide by formation of P-O-M or P-M bonds.INTRODUCTIONIn mineral processing, flotation has been the main process for separation and recovery of valuable minerals from complex ores (Mei, 2013; Zhou, 2014). One of the key requirements in flotation process is to increase selectively the surface hydrophobicity of the targeted minerals by surfactant (known as collector in flotation) adsorption so that these mineral particles can preferably attach air bubbles in a slurry or pulp (Bai, 2004; Hankins, 2004). To anchor a solid surface selectively, special functional group are designed to adjust the interaction between the surfactant and the active sites of solid surfaces (Wu, 2006; Huang, 2014).Organic phosphorous compounds have strong affinity toward metals or metal oxides because they form more stable metal complexes than metal carboxylates (Pazik, 2001; Zheng, 1998). In mineral engineering, phosphorous compounds have been exploited as metal extractants and flotation collectors (Alguacil, 2002; Sun, 2008). Ni (2012) and Zhang (1998) introduced diphosphonic acid (DPA) as an effective collector for flotation of fersmite and niobite. Liu (1999) found styryl phosphonic acid (SPA) was a superior collector for flotation recovery of finely disseminated rutile ores. Gruner and Bilsing (1992) thought SPA was one of the best collectors for flotation recovery of cassiterite which could obtain a high-grade concentrates of more than 40% with high recovery values. Bulatovic (1999) investigated the flotation performances of phosphoric acid ester (PAE) to perovskite, ilmenite and rutile and found that PAE was an impactful collector for selective flotation of titanium minerals from complex ores in the presence of petroleum sulfate. However, a-hydroxyoctyl phosphinic acid (HPA) as a flotation collector for recovery of titanium ores were hardly reported in the previous literatures."

Jan 1, 2016

By M. Mohan Rao

A Sievert ' technique was used. The few determinations made on 10 per cent and 20 per cent V alloys did not show any deviations from Sieverts' law up to I>N2 = 1 atmosphere. The same held true for alloys of 0.2 per cent Ti. Nitrogen absorptions in Fe-Ti alloys, containing from 0.50 to 0.77 per cent Ti at 1,600°C, follow Sieverts' law at low PN2 values, but, due to the formation of a delta titanium nitride phase, deviate from this law beyond critical values of PN2? There is evidence that this phase is Ti1.1N. The behavior observed can be described by the followmg equations: Ti,.,N(o) = 1.7Ti + N K = (fT; ? % Ti)1?7 (f;;.? %~_) = 0.0020 K = fN. %~ = 0.042 '\)-:>N 2 I NTRODUCTJON Nitrogen's solubility in liquid iron-vanadium alloys was investi-gated briefly by Brick and Creevy ( 1), and more extensively by Kash-yap and Parlee (2) and by Pahlke and Elliott (7). Nitrogen's solubility in liquid iron-titanium alloys

Jan 1, 1963