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By V. S. Sastri, M. Elboujdaïni

"Corrosion rates of silicon brasses, highzinc yellow brass, low-zinc yellow brass, leadedtin bronze and silicon bronzes in both permanent-mold and sand-cast conditions were determined in soft water of pH 3, 5 and 8, and hard water of pH 8 at 70°C by electrochemical polarization technique. The alloys in permanent- mold condition showed greater corrosion resistance than sand-cast condition. Corrosion rates obtained from weight loss measurements showed no observable trend of a difference between permanent-mold and sand-cast alloys.The corrosion rates decreased with increasing pH of the medium. Silicon bronze and silicon brass showed high corrosion resistance while leaded-tin bronze showed the least resistance. Addition of small amounts of aluminum improved the corrosion resistance of silicon bronzes and silicon brasses. Alloys in permanent- mold condition showed greater resistance to dezincification than sand-cast alloys when average pit depth parameter is considered."

Jan 1, 1997

By J. C. Underwood

"The wear performance of grinding balls under conditions of impact and abrasion is affected by their chemical composition and structure. The selection of appropriate analyses and heat treatments that will provide both abrasion and impact resistance takes into account the effects of certain elements on structure and harden-ability, as well as the over-all effect of composition and hardness penetration on the residual stress pattern developed through heat treatment. Direct quenching from forging temperatures substantially increases hardenability over that obtained in reheat-quench practices, and can be done without undue risk of damage to the ball provided that the harden-ability bears the correct relationship to ball diameter.Average volumetric hardness and percent hardened volume are convenient parameters for quantitatively expressing the response to heat treatment and indicating anticipated wear properties. A number of factors which can lead to reduced wear life as a result of material or processing problems are reviewed and illustrated."

Jan 1, 1959

By Roger J. Higgins

Papua New Guinea is a country on the cusp of development, struggling to find a balance between the demands of national and regional growth, landowner expectations and the maintenance of cultural identity. Ok Tedi Mining Limited is the single largest contributor to PNG?s economy, representing about 10 percent of the country?s GDP. OTML is demonstrating that business and country risk can be managed through effective, respectful partnerships with local communities. OTML?s relationships with the communities of PNG?s Western Province are multifaceted. Communities have borne the brunt of the mine?s environmental impact, yet have benefited enormously from the development that the mine has brought. Importantly, the PNG economy is now the ultimate beneficiary of more than four-fifths of the dividends from the mine, the majority of which are held in trust for long-term sustainable development projects. The paper describes how OTML works with the Western Province communities to create a secure operating environment that recognizes the people?s aspirations for development and self-determination.

May 1, 2002

By P. G. Thornhill

EARLY in 1951, Falconbridge undertook a research program aimed at the development of a sulphate roasting process for the recovery of the non-ferrous rnetals from the nickeliferous pyrrhotite fraction of Falconbridge ore, in order to reduce the tonnage of iron entering the srnelter. Such a method, it was hoped, would permit a high recovery of the nickel from pyrrhotite otherwise entering the smelter feed, thus not only raising the grade of the latter and reducing its iron content, but also providing an iron oxide residue useful as a source of by-product iron ore. At an early stage in the exploratory laboratory test work it was found that the degree to which the nickel could be solubilized by the sulphating roasting treatment was limited by particle size and the ex-tent to which the pyrrhotite concentrates were freed of the nickel occurring as physically separable pentlandite, a mineral relatively difficult to roast. ( 1) Thus the program

Jan 1, 1961

By K. Hawboldt, J. E. Halfyard, C. Bottaro, I. A. Harrison

"The removal of elemental sulfur from leach residues derived from massive sulfide concentrates via hydrometallurgical routes has been demonstrated in a laboratory setting by converting water-insoluble sulfur to water-soluble polysulfides. The approach was applied to leach residue from Vale's nickel hydromet demonstration plant in Argentia, Newfoundland, which contained significant amounts of elemental sulfur. This technique offers an alternative treatment protocol for residues with a sulfur component not amenable to standard flotation/hot filtration processes. The practical considerations of a proposed flow sheet will be discussed including the impact of other sulfur species (e.g. thiosulfate and sulfides) and key process variables. INTRODUCTIONPresently, large scale elemental sulfur extraction from hydrometallurgical leach residue is performed by Teck Resources using a process of sulfur flotation followed by hot filtration (Chalkley et al., 1993). As mentioned, the technique proves viable for residues derived from specific concentrations - in this case zinc - whose residues constituency is primarily elemental sulfur itself. However, problems arise when this constituency is altered as happens when, for example, a mine containing one particular concentrate is mixed or replaced with a differing concentrate from a second mine. Such cases can often strain the effectiveness of current sulfur removal processes (D'Odorico, 2004). If hydrometallurgical residue containing elemental sulfur cannot be effectively treatment by flotation, the residue is stored subaqueously as is the case in some 'grass roots' hydrometallurgical plants (those not coupled with smelting operations). Hydrometallurgical processing of concentrates involving pressure leaching is becoming increasingly common throughout the mining world, the genesis of which can be found in research performed by Sherritt in Fort Saskatchewan since the 1950’s (Ozberk et al., 1995).The investigation of elemental sulfur removal by means other than flotation includes the uses of sulfide salts (NH3S or Na2S) effecting the conversion of hydrophobic elemental sulfur to hydrophilic polysulfides. The work of Kunda et al. (1974) and Olper et al. (2007) shows that elemental sulfur can be quantitatively removed from hydrometallurgical leach residue via the formation of a mixture of polysulfides."

Jan 1, 2012

By I. Haskett

ABSTRACT The Redwater pool, in north-central Alberta, was discovered in October, 1948, and at the end of 1950 was about 85 per cent developed. Production is from a Devonian coral limestone reef and is found at an average depth of 3,150 feet. The pool has an estimated .productive area of 37,000 acres, and a maximum oil zone thickness of slightly over 200 feet. Wide variations exist in both type and values of porosity, with the average value determined for the reservoir being 6.16 per cent. The total stock tank oil in place is about 1.24 billion barrels. The crude has a saturation pressure of 485 psig, com-pared to the original value of 1,050 psig for the reservoir, and the principal recovery mechanism so far has been the natural water drive. Cumulative production to January 1st, 1951, has been about 15.5 million barrels. These withdrawals resulted in a reservoir pressure decline of slightly over 100 psi. Predictions of future behaviour indicate that the water drive will not be of sufficient magnitude to maintain the reservoir above saturation pressure past 1953, and that, with natural depletion, the pool will be produced largely by a solution gas drive. Pressure maintenance by water injection has been considered and the possibility of raising the pressure to the original value of 1,050 psig is also discussed. INTRODUCTION WITH the discovery of the Lewduc pool, early in 1947, the Devonian limestone became the major geological formation contributing to Western Canada's rapidly growing petroleum reserves. Redwater, discovered in October, 1948, is now the largest known Devonian pool in Canada, with a recoverable reserve estimated at approximately 500 million barrels. Until recent years, the knowledge of the nature and characteristics of this type of limestone reservoir has been comparatively limited.

Jan 1, 1951

By Maureen Jensen

For mining companies looking to establish a strong North American presence, raise their profile or finance and position themselves for future growth, there is no other destination in the world that can offer a mining company the same opportunities as Canada whether you are an established blue chip or promising junior. Despite historically poor world commodity markets and shaky investor sentiment towards junior explorers caused in part by fallout from the high profile Bre-X fraud, Canada continues to shine as the undisputed mining finance capital of the world. Our natural riches and mining history go a long way to explain Canada's international prominence in mining finance. Canada has actively created and maintained one of the most integrated national frameworks to support mining ventures of all kinds. Our diverse industry, from one-person grass-roots explorers to mining industry giants, is one of our main strengths whether your company is Canada-focused or internationally active. The mining industry continues to be a vital contributor to the Canadian economy, contributing $26.2 billion in 1997 or 3.8% of national GDP, and is the second largest earner of foreign exchange. Industrial mineral companies are a very important part of this strength. These companies require a continuing access to capital to ensure that they can continue to compete and the globalisation of the Canadian mining industry has affected this industry just as much as it has affected every other industry in Canada.

Jan 1, 2001

The major factors limiting the establishing of vegetation on the shale and sandstone wastes at Minto are high exchange acidity and low pH (shale pH 4-5, sandstone pH < 4). In the first revegetation program (1967-74), 3.8 million trees were planted without grading on 4,000 acres (red, jack and scots pine and black locust). White dutch and sweet clover, birds-foot trefoil and red top were established in selected areas, and ponds were stocked with brook trout. In the second phase of reclamation, beginning in 1979, a comprehensive plan will be initiated which will allow for forest production, wildlife development and recreational activities.

Jan 1, 1977

By J. Cayouette, C. Bolduc, P. Blatter

"The LaRonde mill was commissioned in 1988 and began treating ore from the Penna shaft in 2000. The mill has been expanded to accommodate 7,500 t/day, but ramped down to 6,000 t/day since the deep extension began. The process recovers gold, silver, and base metals. In 2008, the Goldex plant began trucking gold-pyrite concentrate to a treatment plant feeding pulp to the LaRonde mill, increasing gold output by 40,000 oz. In 2009, the high-grade Lapa ore processing facilities were annexed to the LaRonde plant, increasing gold output by 120,000 oz. This paper outlines the metallurgical considerations related to the treatment of different ore types.RÉSUMÉ Le concentrateur de la mine LaRonde a été mis en service en 1988 et a commencé à traiter le minerai du puits Penna en 2000. La capacité du concentrateur a augmenté afin de permettre le traitement de 7 500 tonnes de minerai par jour, capacité qui est retombée à 6 000 tonnes par jour (tpj) depuis le début de l’extension en profondeur de la mine. Ce procédé permet de récupérer de l’or, de l’argent et des métaux communs. En 2008, l’usine de traitement Goldex a commencé à transporter par camion du concentré de pyrite et d’or vers une usine de traitement alimentant en pulpe le concentrateur de LaRonde, augmentant ainsi la production d’or de 40 000 onces. En 2009, les installations de traitement du minerai à haute teneur de Lapa ont été annexées à l’usine de traitement de LaRonde, augmentant la production d’or de 120 000 onces. Cet article passe en revue les considérations métallurgiques liées au traitement de différents types de minerai.INTRODUCTIONThe LaRonde metallurgical plant in the Abitibi region of Quebec, Canada, evolved into a mature milling site following expansions in 2000–2003, thanks to improved processes, manpower, and water treatment capabilities that better accommodate the complex constituents of the LaRonde ore. The ore requires a sequence of grinding, copper- lead and zinc flotation, and precious metals leaching, ending with a carbon-in-pulp (CIP) gold recovery. A portion (35%) of the tailings is sent back underground as paste backfill after being treated with the SO2-air cyanide destruction process. The tailings area has a dedicated cyanide destruction and metal precipitation area through which the used water passes before returning as recycled water. A biological water treatment plant was built in 2004 to address water toxicity in the final effluent. The water toxicity was the result of the high sulfide content of the LaRonde ore (from thiocyanate or stable cyanide species buildup) and the use of 90% recirculated water in the mill. The water treatment plant uses bacteria to transform thiocyanate into nitrates and precipitate phosphorus from the water before it is discharged into the environment."

Jan 1, 2017

By P. D. R. Maltby

"The Canadian Institute of Mining and Metallurgy has undertaken to host the XIV International Mineral Processing Congress to be held in Toronto at the Royal York Hotel from October 10 to 16, 1982. The theme of the Congress will be ""Worldwide Industrial Application of Mineral Processing Technology."" The program will include 10 sessions and numerous field trips to the different mining areas of Canada.For prospective authors, the preliminary program includes sessions on,1. Flotation - plant practice, equipment design, simulation, control and economics.2. Comminution - plant practice, equipment, design, simulation, control, wear, energy consideration and economics.3. Round table seminar on large grinding mills.4. Round table seminar on modern and future plant design.5. Mineral processes to recover precious metals.6. Mineral processes to recover energy minerals (coal, uranium).7. Mineral processes to recover industrial minerals.8. Round table seminar on the environment and ecology and how the different countries cope with associated problems.9. Materials handling with an emphasis on agglomeration techniques ereconentration methods, solid-liquid separation.10. Open session to deal with topic emerging from general demand."

Jan 1, 1980

By D. Yuan, L. Yan, R. Kalanchey, M. J. Collins, I. M. Masters

Pressure oxidation tests have been conducted by Sherritt for a refractory gold-silver project located in China. The feed contained 39 g/t Au and 970 g/t Ag; the major gold-bearing minerals were pyrite and arsenopyrite. Since the feed contained a significant amount of silver, which can be refractory to cyanide leaching after pressure oxidation due to the formation of argentojarosite, the test program included investigation of methods to enhance silver recovery. The "lime boil" process proved successful and was incorporated into the flowsheet. Gold extraction from the lime boil product solids was 95 to 98%; silver extraction was up to 94%.

Jan 1, 2011

By A. G. Doll

The Bond low energy impact (crushing) work index test is specified to be performed on rock specimens between 50 mm and 75 mm in effective diameter. NQ-diameter drill core, frequently used in mineral exploration programs does not meet that specification, it being 45 mm diameter or less. This paper reports the effect of performing the impact test on contiguous sections of HQ diameter and NQ diameter core, exploring the hypothesis that the contiguous intervals give equivalent results in spite of the core diameter difference.

Jan 1, 2012

By D. A. Grieve

"Mineable coal seams in the East Kootenay region belong to the Mist Mountain Formation of the Jurassic -Cretaceous Kootenay Group. Three structurally separate coal fields (Crowsnest, Elk Valley and Flathead) are recognized, all of which are characterized by compressional tectonic features such as f aiding and thrust faulting, and by /ate-stage normal faulting. Tectonic history has greatly influenced coal mineability and quality. Coals range in rank from low to highvolatile bituminous, and reactive maceral content ranges from less than 60% to greater than 90%. A wide range of metallurgical and thermal coal qualities is found. Measured reserves (up to 1981) include 1.03 billion metric tonnes metallurgical and 165 million metric tonnes thermal coal. Introduction a) Location -Coal fields of the East Kootenays region occur in the Front Ranges of the Rocky Mountains, within 30 km of the Alberta -British Columbia boundary (Fig. 1). They extend over 175 km north from near the U.S. border, and occupy the regions of the Crowsnest Pass and Elk and Flathead River drainages. The deposits are accessible from Highway 3 (Fig. 1) and various secondary roads. The towns of Fernie, Sparwood, Elkford, Coleman and Blairmore serve the coal industry. East Kootenay coal deposits are contained in three structurally separate coal fields, the Crowsnest, Elk Valley, and Flathead coal fields (Fig. 1). Coal is currently being produced by B.C. Coal (now Westar Mining Ltd.) at Sparwood, by Fording Coal 20 km north of Elkford, by Crows Nest Resources at Line Creek 15 km southeast of Elkford, and by Byron Creek Collieries at Corbin. Westar Mining has also constructed a new mine on the Greenhills Range 8 km northeast of Elkford. Pre-requisite engineering and environmental studies have been carried out on the Elco Mining property, 35 km north of Elkford, and on the Sage Creek coal property near the U.S. border (Fig. 1). b) Coal land tenure -Coal rights in the East Kootenays are either held as freehold land, or are licensed from the provincial government. The former category includes lands acquired under the Railroad Act of 1890. Shortly after this the federal government also obtained 50,000 acres of coal-bearing lands from the Crown Provincial, the so-called Dominion Government Coal Blocks. Major holders of coal rights in the area are Westar Mining and Crows Nest Resources. Large blocks are also held by Fording Coal and related companies, Sage Creek Coal, and Canada Permanent Trust Company as trustee for Elco Mining, and small blocks are held by Byron Creek Collieries and Coleman Collieries. In addition the provincial government holds an area in reserve for possible future use of B.C. Hydro at the extreme north end of the Elk Valley coal field."

Jan 1, 1985

By A. Ducastel, S. Connemann, A. Stark, F. Bouillot, C. Fricke-Begemann, LSA, H. Knapp, L. Horckmans

"Refractory materials are essential for all high-temperature applications in industry. Depending on the position in the furnace and specific process requirements, refractories are produced from several raw materials, such as dolomite, magnesite, bauxite, graphite or chromite. Most of these raw materials are not rare but strict quality requirements limit the producers of refractories to only a few deposits in the world. Thus, raw material supply is a critical factor for the production of refractories and accounts for 40-50 % of the total costs of refractories.A possible way to lower dependency on raw material supply is recycling of spent refractories. Main challenge in recycling is the separation of different brick types from each other and the removal of impurities, such as steel or slag. The European FP7 project REFRASORT aims to apply sensor-based sorting for separation of spent refractories. Sensor-based sorting is known from food industry, recycling and mineral processing and has proven its reliability. Nevertheless, some adjustments are necessary compared to applications in mineral processing because of other sensor-types and a higher number of products in one sorting step. This paper presents the results of feasibility tests for sensor-based sorting of refractories with near infrared spectroscopy and laser-induced breakdown spectroscopy (LIBS). Both sensors showed the potential to identify different brick types but the most promising results were obtained using LIBS technology. INTRODUCTIONRefractories are solid, ceramic products, which can sustain temperatures of more than 1500°C, without losing their stability or shape. Bricks of refractories have to withstand corrosion in contact with liquid steel or slag. Various high temperature applications, such as the production of glass, steel, copper or cement, require high quality refractories. The quality requirements of refractory bricks are strict, because small impurities can lower the thermal strength significantly."

Jan 1, 2016

By A. Dubé

Introduction It is common experience that on re-heating a fully martensitic steel below the Ac, point, a softer and tougher structure is formed as the tempering temperature is raised. The mechanism of tempering of plain carbon and low-alloy steels has been the subject of many investigations. In a very comprehensive study, Cohen and associates have recently established three different tempering stages, the last of which reaches completion at about 700°F., with heating rates of 5°F. per minute. This latter stage has been established ta be the carbide-forming stage, so that the steel consists of a mixture of ferrite and carbide, which are the metastable equilibrium phases. Any subsequent changes which take place at higher temperatures below the Ac, point in the absence of graphitization or carbide lattice conversion normally consist of agglomeration of the carbide particles. This naturally results in the softening of the steel. However, in many cases the Ac, point, as determined by dilatometry, thermal analysis, etc., only gives a rough estimate of the temperature where the reaction, ferrite plus carbides to austenite, is initiated. This appears to be especially true in the case of alloy steels in which three phases can co-exist in certain temperature ranges. Bain has given data on the three-phase equilibrium in both manganese and nickel steels. In these steels, the formation of austenite at temperatures just above the AeIL apparently involves the diffusion of the alloying elements to the first pools of austenite, thereby making the process very sluggish. As a consequence, the critical Ac points determined by ordinary methods at normal rates of heating can be quite distant from the true equilibrium Ae temperatures.

Jan 1, 1946

By Davood Moradkhani, Maryam Rasouli

"The present study reports solvent extraction and separation of zinc from concentrated nickel sulfate solution. In our previous study, Zn and Cd in cold filter cake (CFC, 45-55% Zn, 11-16% Cd, and 2.5-4% Ni) were extracted by alkaline leaching followed by electrowinning processes respectively. The strip solution from electrowinning process, was a pregnant liquor solution (PLS) containing 16.8 g/l Ni and 4.2 g/l Zn. In this work, PLS is subjected to the solvent extraction process for separation of traces of Zn from high grade nickel. The zinc free raffinate containing 16.6 g/l Ni sulfate solution will flow to nickel electrowinning plant for cathode production. Di-(2-ethylhexyl) phosphoric acid (D2EHPA) is the organic phase used in this study. The effects of various parameters such as organic phase concentration (10- 40 % v/v), pH (1.5-3), and temperature (25 and 45°) are investigated. Zinc over nickel separation factor increases by increasing pH from1.5 to 3. The results show that 98.7% of Zn was loaded at25°C O/A ratio of 1, pH 3, and 10% vol. D2EHPA. A 10 M NaOH is used for pH control. However, replacement of pH controlling agent with ammonia solution (25%. v/v) results in interesting observations. Ammonia addition, reduces the solubility of Ni2+ cations in solution. Nickel starts to precipitate from raffinate in a crystalline bluish-green form. The obtained crystals are characterized by XRF and identified to be nickel-bearing analog of boussingaultite, a rare sulfate mineral of nickel with chemical formula of Ni (NH4)2(SO4)2.6H2O. The crystallization rate of crystals is studied. It is a slow precipitation process with 75% in 4 days.INTRODUCTION Annually, many hydrometallurgical processes such as electrowinning, solvent extraction and leaching are applied to waste filter cakes in Zanjan, Iran. These additional processes on filter cakes are critical from both environmental and economic points of view. CFC (cold filter cake) is a toxic but valuable filter cake (45-55% Zn, 11-16% Cd, 2.5-4% Ni, and 0.2-1.5% Cu) produced in many zinc production plants. Our research group at Research and Engineering Company for Non-ferrous Metals (ReCo.), developed a series of hydrometallurgical methods for extraction of zinc, cadmium and nickel from CFC (Moradkhani, & Rasouli 2012). The recovery of zinc and cadmium with alkaline leaching and electrowinning was successfully studied. The strip sulfate solution from cadmium electrowinning unit, contains high concentration of nickel with some traces of zinc impurity. This pregnant liquor solution (PLS) was analyzed and reported to contain 16.8 g/l Ni and 4.2 g/l Zn. In this work, PLS is subjected to the solvent extraction process to separate Zn from nickel (Fig. 1). The organic phase stripping solution containing 4.2 g/l zinc and 200 ppm nickel can be circulated and used in the acidic leaching step. This generates nickel solution with high purity suitable for nickel cathode production."

Jan 1, 2017

By F. T. Mooney

Introduction The Flin Flon mine of the Hudson Bay Mining and Smelting Company, Limited, is on the interprovincial boundary between Manitoba and Saskatchewan, about four hundred miles north of the Canada-United States boundary. The orebodies are gold, silver, zinc, and copper replacement deposits occurring as irregular lenses of massive sulphides, arranged en echelon, and irregular masses of disseminated copper sulphides in chlorite. The country rocks are of Precambrian age, dominantly lava flows. Development of the Mine The mine is opened by two vertical main shafts- the North Main and South Main shafts- 3,800 feet apart. The North Main shaft has a depth of 2,210 feet and the South Main shaft is completed for stoping operations to the 3,250-foot level (see Figure 1). These shafts are connected by main haulages driven, on the footwall side of the orebodies, at 520-foot intervals down to the 2,210-foot level. No. 3 (subsidiary) shaft is on the footwall side of the orebodies at a point between the North Main and South Main shafts, 2,400 feet south of the former. It has a depth of 3,250 feet and connects with all main haulage levels- with both Main shafts down to the 2,210-foot level and with the South Main shaft on the 2,750-, 3,000-, and 3,250-foot levels. Other openings tO the mine include B North fan raise, the opening due to the recovery of the open pit sill pillar, and several back-fill raises.

Jan 1, 1949

By G. B. Harris, C. W. White

Cyanide has been used for the recovery of gold since the mid 1800s, but several jurisdictions have already banned its use, and environmental pressures are increasing to finding an alternative. Gold also forms chloride complexes similar to those of cyanide, but the use of chloride has never achieved widespread acceptance. This paper describes a chloride-based flowsheet, wherein the key unit process is the recovery and recycle of chloride ion. It is shown that the chloride-based flowsheet is competitive economically with the conventional cyanide-based flowsheets, and that it has a number of other advantages, particularly environmentally.

Jan 1, 2011

By Angus D. Campbell

Introduction In the Twentieth Annual Report of the Mcintyre Porcupine Mines, Limited, for the year ending March 31st, 1932, the General Manager, Mr. R. J. Ennis, said: "During the period under review, the plans outlined in last year&apos;s report have been completed, and all operations have been centralized in the new plant adjacent to No. 11 shaft. The new mill went into operation on May 27th and attained its rated capacity of 2,000 tons per day on November 15th. The new shops, warehouse, change-house, and general offices were occupied on December 1st, consummating the change from the old to the new plant ... "Silicosis is now definitely recognized as an industrial disease, and progresses rapidly when associated with tuberculosis. In an effort to combat its prevalence and progress, the new change-house was designed to build up the men&apos;s resistance to this and other forms of disease. It provides for a complete change from underground to street clothing, with a shower bath and solarium treatment in the interval. &apos;Unfortunately, in almost every goldmine, a very small percentage of the work-men are not adverse to taking some of the high-grade ore for their own purpose. This, in turn, tends to cast suspicion upon the honourable as well as the dishonorable employees. The new change-house routine discourages this practice and eliminates unjust suspicion, to the satisfaction of all concerned with the Company&apos;s operations".

Jan 1, 1933

By S. Nikolic

"Calcium ferrite slags are currently used in a number of copper-converting processes. Despite the industrial importance of this system the phase equilibria have not been fully investigated. Characterization of this slag system is necessary to improve the control of process parameters, including fluxing and operating temperatures. Recently, a modified experimental method has been developed; this involves rapid quenching of slag samples equilibrated at high temperatures with the resulting phase assemblages analysed using electron probe microanalysis (EPMA). In the present study, experiments were completed under controlled temperatures and oxygen partial pressures using CO/C02 or H2/C02 gas mixtures. The investigated slags were supported during equilibration by a substrate of the primary phase. This technique removes the limitations arising from the use of crucibles and facilitates rapid quenching of the melt. Experiments were carried out at 1200°C and 1250°C (1473 Kand 1523 K) and in the composition range 0-40 wt.% Cu20, 0-25 wt. % CaO and 45-80 wt. % Fe203. Liquidus and solidus data are reported for the primary phase field of spinel between the oxygen partial pressures of 10-4.5 to 1 o- 6-5 atm. The analyzed compositions of liquids and solids are used to construct the phase diagram of ""Cu20"" -CaO-""F ez03"" system in equilibrium with metallic copper at fixed oxygen partial pressures."

Jan 1, 2007