Search Documents

By S. Yalcin, S. Chang, M. Oliazadeh

"Present day ferrochrome demand is on the rise, as more steel products require this material as an alloying element. It is projected that the stainless steel demands will grow by about 6% per year to 2020; as such, the supply and demand for ferrochrome appears promising. Chromite is the only economical source of chromium, which is commonly upgraded by gravity techniques and used to produce ferrochrome. The gravity separation methods are not able to treat particles finer than 0.1 mm efficiently. Therefore, in processing chromite ore, a large quantity of fine tailings; some 25% of the mineral values have been reported as lost in slimes during processing. The chromite content of these tailings is typically 10-20% Cr2O3 and accumulates into a large stockpile/pond. A chromite concentrator project in Canada, considers a cut-off grade of 20% Cr2O3. This indicates further processing might be required to recover chromite from low-grade stockpile when the high-grade deposits are depleted. Low-grade ores normally indicates disseminated chromite ores with low liberation and consequently fine comminution. This paper reviews the techniques for treating chromite from fine material and provides some examples of successful operations in fine chromite recovery. Beneficiation techniques for fine particles include gravity separation, magnetic separation, and flotation. Several case studies are presented here that used one of the aforementioned methods or a combination of them.INTRODUCTIONChromium is one of the essential element and important material for production of ferrochrome alloys and special steel. Chromium occurs as chromium spinel, a complex mineral with chemical composition of (Fe, Mg) O (Cr, Al, Fe)2 . Chromite ore is exclusively found in ultramafic igneous rocks. Major associated gangue minerals are talc, quartz, serpentine and iron oxides.Chromite is a heavy mineral, with a specific gravity in the range of 4-5, relative to associated gangue minerals in a chromite ore, which makes gravity concentration a suitable process. This is generally true for coarse particles, ranging from 1 mm to 100 mm. Typically, the ore is prepared by crushing (and grinding if necessary) to a suitable size and the material is sized for the appropriate beneficiation techniques. It is common to use heavy medium separation (e.g. dense media drums, dense media cyclones, or Dyna Whirlpool) to treat coarse size and intermediate size particles (1 – 100 mm). Intermediate and fine particles (20 – 0.1 mm) could be treated by jigs. Spirals, shaking table, sluices, and Reichert cones can upgrade fine particles. Figure 1 shows a typical chromite beneficiation process flowsheet. As can be seen, it consists of three major sections: feed preparation (crushing, screening), de-sliming, and concentration. Beneficiation recoveries range from 80 to 85%, although the ratio of upgrading is only 2 to 3."

Jan 1, 2013

By B. G. Cousins, B. O’Rourke, C. Spence

"Some non-flotation chemistries are added to flotation circuits directly and indirectly to control issues such as scaling and dust. Since the dosage levels are generally not very large, a standard laboratory float test may not be able to determine the effect a specific chemical has on the productivity of the flotation circuit. Hudbay and Ashland Water Technologies developed a laboratory testing protocol that uses kinetic float studies to test the effect of normal to extreme doses of antiscalant and dust chemistries (5 ppm to 500 ppm). Laboratory results indicate that this protocol helps to predict the potential interference that a particular chemistry will have on the flotation circuit.INTRODUCTIONFrom a chemical perspective, flotation is a very complex system involving more than the reagents used for flotation. Along with collectors, frothers, modifiers, suppressants and activators, there can be antiscalants for water treatment, dust suppressants used in the mining process, residual flocculants from recycled thickener overflows, grinding aids, and many other types of chemicals that are added upstream of a flotation circuit. Although these other chemicals are usually used at very low doses, it is important to know if they affect the flotation process detrimentally in the event of a spill or a build up from recycled water.Laboratory flotation testing of these chemicals characterizes their effects, but testing at expected doses in the float can mask the effects of the chemicals in the plant. Also, simple tests that do not measure the kinetics of flotation do not reveal the effects the other chemicals have on the flotation circuit. Thus, a new flotation protocol was needed to expose the full effects of chemical additives and to assist in choosing the chemical with the lowest potential for a negative effect.FLOTATION KINETICSMeasuring recovery kinetics in a laboratory flotation cell is a well-established procedure: analyzing concentrates taken in a timed sequence to determine the recovery rate of individual cells in a flotation circuit. The recovery from the early flotation cells are a true measurement of how well a flotation chemical is performing. The principles of kinetics can be mathematically determined by the following functions (Houston, 2006):"

Jan 1, 2013

By A. Vien, B. C. Flintoff, R. P. Edwards

"A major thrust in industrial automation over the past few years has been the exploration and incorporation of higher level (supervisory and optimizing) control strategies aimed at more fully exploiting the existing control system infrastructure. There is little doubt that this is worthwhile pursuit, however, one must not lose sight of the maintenance and development requirements of the basic control system. Statistics on loop performance indicate that this too is an area of considerable potential. In this paper the authors look at some of the less elegant, but arguably equally important issues in mineral processing plant control. The focus is on controller structures, loop tuning, sampling, filtering, and some of the other principal components of the regulatory control foundations. In many cases significant improvements in control performance can be achieved by getting back to the basics.IntroductionEvery modem concentrator has a state-of-the-art computer control system in place. Several of these are contemplating installing, or have installed, advanced control systems, such as expert systems, but the foundation of their control system remains the PI controller. Although the authors are not aware of any survey or published information for the mineral processing industry, it is reasonable to assume that it would be similar to the pulp and paper industry. ""The average [pulp] mill has some 2000 control loops of which 97% use PI control. This means that PID, dead time compensation, adaptive controllers, specialized algorithms, ... , constitute only 3% of the installed base."" (Bialkowski [1992]).Bialkowski [1992] also stated that ""If you have been keeping score, only 20% of the loops surveyed actually decrease variability in automatic over manual mode of operation, in the short term."" He attributed the problems to: poor tuning (30% of all loops), control valve problems (30% of all loops) and process problems (20% of all loops). There appear to be a serious need to go back to basics and review the existing control system."

Jan 1, 1998

By Brad E. Melanson

Because mine haul trucks consume considerable quantities of fuel, they are ideal candidates for the adoption of cleaner and cheaper fuels like natural gas. Impressive fuel cost savings will be realized in regions where liquefied natural gas (LNG) has cost advantage to diesel fuel, while also providing significant reductions of air contaminants and greenhouse gases. High Pressure Direct Injection (HPDI) of natural gas utilizes the diesel cycle combustion process and therefore retains the diesel engine?s high performance and efficiency characteristics. HPDI has been demonstrated in on-road Class 8 trucks since 2001 accumulating almost 10 million kilometres to date. The supply of LNG fuel will be an essential parallel aspect in the introduction of HPDI to mining. LNG can be transported to site as diesel is today, or may be produced on or near mine operations that have access to methane sources or pipelines.

May 1, 2006

By Andrew Bamber

The introduction of pre-concentration technology into the underground narrow-vein mining scenario has the potential to change the entire economics of utilizing bulk-mining methods in these situations. An idealized integrated underground mining and processing system, comprising elements of bulk mining, underground preconcentration and backfill systems is presented. Through simulation and a systems engineering approach, the implications of enabling the utilization of bulk mining methods in a narrow vein deposit through the adoption of this technology is considered. Parameters considered include orebody characteristics, ore mineralogy, grade, metal value, mining rate and cost.

Oct 1, 2004

By S. Belair, V. Weigel

As a growing mining company, ERAMET is looking for new positions on the strategic metals market. In this context, the Gabonese Maboumine pyrochlore deposit is currently being studied for the recovery of niobium, tantalum, rare earth elements (REE), and uranium. This ore shows mineralogical and chemical characteristics that make it challenging to process by already known practices, from both technical and economic points of view. In this context, ERAMET has developed since 2008 an innovative hydrometallurgical process which has been successfully operated at a pilot plant scale. While the upstream part of the process aims to dissolve the valuable elements in sulphuric acid, the downstream part of the process aims to recover them separately in a marketable form. The focus here will be on the recovery of the REE. The ore deposit contains approximately 1.4% of REE including 87% of light REE and 13% of medium-heavy REE. The challenge in this process lies in the fact that the major elements in the matrix are iron and aluminum. An innovative process has been developed in order to recover all of the REE in these unfavourable conditions, described in this paper.

Jan 1, 2014

By Euler De Souza

Backfilling in Canadian mines has been practised for close to 100 years and evidence anticipates the application of mine fill technology at an increasing rate during the foreseeable future. The evolution of backfill technology is closely related to the advancement of modern mining methods and the development of new backfill technology continues to evolve. The authors, after conducting extensive surveys of backfill practices in underground mines across Canada, have concluded that, because backfill operations employ large quantities of cement and experience large costs associated both with backfilling practice and cement use, opportunities exist for reducing backfill energy costs and enhancing the application of alternative cementing agents in backfill. Consequently, the authors have developed an alternate, equally effective and lower cost binder agent replacement for cement, and incorporated waste glass into the development of a lower cost backfill (glassfill). This paper presents the results of two design stages associated with the development of glassfill: strength development and flow performance. The advancement of this technology has reached a stage that should promote industrial implementation within the Canadian mining industry. A number of Canadian mining operations exhibit potential for plant optimization through possible binder source replacement, and might thus realize associated reductions in backfill and energy costs.

Apr 1, 2005

By J. W. Austin

"Introduction The Brenda dust collection system was originally designed to handle air at the 5000 ft. elevation with less than 1 grain of dust per cubic feet of air handled. The temperature variation is from 32°C in the summer to -20°C in the winter.DUST COLLECTIONOriginal Equipment 1. Primary Crusher 2 compartment baghouse, shaker type design capacity - 17,000 cfm2. Primary Screening 3 compartment baghouse, shaker type design capacity - 30,000 cfm3. Secondary Crusher 4 compartment baghouse, shaker type design capacity - 45,000 cfm4. Secondary Screening 4 compartment baghouse, shaker typedesign capacity - 60,000 cfmThe original dust collecting equipment was designed using a napped terylene fabric at an air to cloth ratio of 5:1. The ducting was designed to handle the dust laden air at 3200 ft. per minute with all elbows and blast gate sections rubber lined. The hoods and the pickup velocities were designed to handle the anticipated low dust counts."

Jan 1, 1976

By Johnna Muinonen

"The Thompson Mill processes ores from the Thompson and Birchtree Mines. While the Thompson ore has very little magnesium containing gangue, the Birchtree orebody consists of veins of massive sulphide in a rock matrix that contains a high proportion of magnesium silicate minerals. A significant fraction of the magnesium is floatable, which lead to MgO levels varying from 3-11 wt% in the Birchtree concentrate. The magnesium in the concentrate causes a higher operating temperature in the smelter, reducing furnace life.Birchtree ore represented 20-30% of the mill ore receipts prior to October 2003. Since then the fraction of Birchtree ore has increased to 50%. A reduction of the MgO in concentrate to less than 3% in the total mill concentrate was required to allow safe and economic smelter operation.In October of 2002 a miniplant was set up to simulate the Birchtree plant circuit. Several flow sheet modifications were tested that led to a proposal for a circuit having increased cleaning capacity for the scavenger concentrate and a recleaner on this concentrate. Addition of CMC in rougher cleaner feed was also found to be required. The solution was confirmed through pilot plant testing in the mill in December of 2002. A full-scale installation was designed, engineered, and installed between February and September of 2003 with commissioning in September and October of 2003. Target metallurgy was achieved one week after start-up on slurry to coincide with the Birchtree Mine tonnage increase. This paper highlights the development, design and commissioning stages of the project.The new MgO rejection circuit has successfully allowed the processing of Birchtree ores producing concentrate consistently below 3% MgO. In addition, the new circuit increased overall nickel recovery in the mill.INTRODUCTIONThe Thompson Nickel Belt located approximately 700km north of Winnipeg was discovered in the early 1950’s. Inco first produced nickel from the area in 1960. Over the years the mill has processed several ores from different ore bodies in the area. Currently the Thompson Mill processes two significantly different ores from two mines, Thompson and Birchtree. The Thompson ore is a massive sulphide orebody hosted in schist, containing feldspars, quartz and biotite. Thompson Ore is characterized by high nickel recoveries and clean, low MgO containing concentrates (<2.5% MgO). The Birchtree ore is ultramafic and contains a high percentage of Mg-silicates such as serpentine, chlorite, biotite, amphiboles and talc. Some of these Mg-silicates report to the nickel concentrate and prior to commissioning of the MgO rejection circuit the Birchtree nickel concentrate typically contained 5-8% MgO"

Jan 1, 2006

By A. J. Magerowski

Energy consumption is a main component of operational costs for the comminution of mineral bearing ores. Reduction of energy consumption has continually been addressed by mill operators and equipment manufacturers. Our testing over the last few years strongly indicates that the overall energy needed to comminute a mineral bearing ore can be brought down significantly, if more work is done in the crushing stages of the comminution circuit.This calls for uprating of the conventional crushing equipment into a new generation of crushing equipment to produce finer products. This will result in the emergence of new ideas in the design and application of equipment and corrnninution circuits.

Jan 1, 1986

By I. R. Ward

"The need for energy conservation has been of increasing concern since the early 1970's, when the cost of petroleum based energy began to escalate rapidly and security of supply became uncertain. The cost of energy from alternative sources has also increased due to development costs and environmental restrictions.These developments have had a serious impact on the mining industry, which is energy intensive. The impact is magnified as lower grade ores are treated, and more energy is consumed per unit of product. In many cases increased operating cost is not compensated by the rise in product selling price.The magnitude of energy consumption in the mining industry is indicated by recent studies conducted in the U.S.A. and Canada. Based on 1970 figures, it was reported that the production of 1 ton of copper in the U.S.A. required 111. 8 x 106 BTU of energy, of which 60. 7 x 106 BTU (54.3%) was consumed in mining and processing (l)The survey of Canadian mills, conducted by CANMET and reported to the CMP meeting of 1978 (2), showed the following milling energy consumption figures (approximate averages):"

Jan 1, 1981

By Pierre Beaudoin

"This paper deals with the repairs made on two damaged mills. It investigates briefly the causes of the damage, explain its nature and the design of the repair. It explains the detrimental effect on operation and the solutions implemented to reduce them. Finally, to review the follow-up required for such repairs. LOCATIONThe Holt McDermott Mine is located 75 kilometers Northeast of Kirkland Lake and 30 kilometres west of the Quebec border in Northeastern Ontario. The town of Kirkland Lake is located approximately 500 kilometres north of Toronto. HISTORYThe discovery of gold in Holloway Township dates back to early 1920. In 1984 Barrick Resources, which amalgamated with Camflo Mines, acquired more claims on the property and initiated an extensive drilling program. By 1985, the drills indicated reserve increased to 2,500,000 tonnes grading 6.8 g/mt. In 1986 a production decision was made and in 1988 the mine was officially opened.As of December 31, 1998, 4,691,507 tonnes grading 5,66 g/tonnes have been milled from 4 ore-bodies. The mill started up in June 1988."

Jan 1, 2001

By Kristie Tarr

Portland cement is primarily used to solidify backfill in underground mine workings and it represents a major cost in mining operations. CANMET-MMSL has invented an alternative binder technology that does not contain any amount of Portland cement and is made using waste materials, such as development rock and smelter slag. The technology has been successfully tested with many types of base metal and ferrous slag. Research conducted in collaboration with several mining operations in Canada has shown that the CANMET-MMSL binder has considerable potential as a replacement for Portland cement in mine backfill. An integral part of the overall mining operation, backfill is used for two main purposes: safety and environmental remediation. Depending on the mining method used, backfill provides a working surface, stabilizes stope and pillar walls, as well as the surrounding rock mass, and controls caving of stope backs. There are several benefits associated with the replacement of Portland cement in backfill, including reductions in (i) the footprint by placement of slag waste underground, (ii) the environmental effects and long term liability resulting from disposal and containment of slag waste on surface such as acid rock drainage, (iii) GHG as a result of reduced Portland cement usage (the production of 1 ton of Portland cement produces 1 ton of GHG), and (iv) the significant costs associated with reduced Portland cement usage.

Oct 1, 2010

By H. R. Bullis

"Abstract- This paper discusses what appears to be a flaw in the current belief, widely held within the gold mining industry and investment community, that the creation of ever-larger gold mining companies is desirable for mining companies and investors alike. The basis of the flaw is in the underlying assumption that very large gold producers can discover or acquire new gold deposits of the size necessary to replace extracted reserves on a year-on-year basis over the intermediate to long term (i.e., five to ten years and longer). As it will be noted in this paper, deposits of the size required to replace annual production of very large gold producers (VLGPs) are relatively few in number. Although discoveries of new gold deposits continue to be made, they are predominantly in the 0.5 to 2.0 million ounce range. Data represented here suggest that, although gold production from individual VLGPs continues to increase, the change is due to merging or acquiring other companies or projects with similar reserve life profiles. Therefore, the reserve life profiles of VLGPs have remained flat or have decreased.The paper will note recent changes in the industry and the remarkable increase in gold production reported by individual mining companies over the past several years. It will provide an overview of the geographical and geological distribution of known gold deposits and the range of deposit sizes. Finally, the paper will discuss the challenges that face large gold producers in replenishing their reserves that are being depleted at an ever-increasing rate. Unless otherwise stated, all production and reserve data have been taken from company documents in the public domain or publicly available information."

Jan 1, 2001

By Norman O. Lotter, André R. Laplante

"The pursuit of concentrator surveying for purposes of metal accounting or process optimization has not yet connected with the well-published realm of geostatistics. The reality of lognormality in time has seldom been discussed. One publication by Krige, 1962, examined such effects for a gold concentrator in South Africa, towards an information system that would provide feedback to the mining and surveying teams on grade control of ore mined.During present studies which are designing and testing a new survey model, called statistical benchmark surveying, it was found that the distributions of feed, concentrate and tailings bear significant residual signs of the parent lognormality in space. The multiple hosting of paymetals in different mineral species complicates the understanding of these distributions. These features have to be recognized and treated in order to perform appropriate quality control on the diagnostic sampling performed in the pursuit of statistical benchmark surveying.It is shown in this paper that the above two features can actually be used to advantage in the diagnosis of continuous periods of operations data ahead of such surveying, including the estimation of recoverable paymetals in flotation tailings from a graphical method.INTRODUCTIONAssessment of Concentrator PerformanceMilling and flotation, sometimes accompanied by gravity separation, are well-established unit processes, which have traditionally been used to treat ore that has been mined. This is because these processes liberate, then separate, the valuable minerals, which contain paymetals, from host gangue. This is often done by a combination of crushing and grinding processes, or autogenous grinding, to liberate the paymetal minerals, followed by gravity separation and/or flotation, to separate these valuable minerals into a concentrate, or several concentrates. These concentrate(s) have a lower bulk than the parent ore from which they are derived. Further, they contain a high percentage of the valuable minerals. Accordingly, they are more economically treated in subsequent beneficiation processes than the ore from which they were produced."

Jan 1, 2005

By S. Kahraman, K. Develi, E. Yasar

Four hydraulic top hammers, one pneumatic top hammer, and three down-the-hole drills were observed in several rock types at quarries and highway construction sites to measure the performance data. At the same time, drill cuttings from each drill hole were collected for the determination of the coarseness index (CI), which is the sum of cumulative weight percentages of a particular size-graded sample of debris, and for the determination of median particle size (MPS), which is defined as the particle for which the quantity of particles equals 50% of the total of the cumulative distribution. After the sieve analysis was carried out on the drill cuttings in the laboratory, CI values were calculated and MPS values were obtained from the plots of cumulative undersize vs particle size. The performance data of the drills, CI values, and MPS values were analyzed using the least square regression method. It was seen that strong linear relationships usually exist between penetration rates and CI values, and penetration rates and MPS values for both top hammer drills and down-the-hole drills. Penetration rates increase linearly when increasing the CI and MPS values.

Jan 1, 2004

By R. A. Bergman, C. A. Pickles, J. M. Toguri

"Black calcium cyanide is utilized mainly as a reagent for gold extraction. It is produced by reacting calcium cyanamide, sodium chloride and calcium carbide at temperatures in the range of 1200°C to 1400°C in a smothered arc furnace. The equivalent sodium cyanide content of the product is in the range of 45% to 50% and the calcium cyanamide conversion efficiency is in the range of 90% to 95%. Since black cyanide contains impurities such as salt and lime and also because the conversion efficiencies are below 100%, the product contains unwanted materials which significantly increase the shipping costs.The impurity content of the raw materials can not be lowered without increasing their cost and/or the processes to produce them, and therefore the present research was focussed on studying those factors which affect the cyanide grade. The major variables investigated were: the heating rate, the reaction temperature, the salt to cyanamide ratio, the nitrogen content of the calcium cyanamide, moisture additions and calcium carbide additions. It was found that each of these variables had a significant effect on the product grade. The highest cyanide content of the product was obtained for salt to cyanamide mass ratios of 0.55 to 0.60. The salt reduces the decomposition rate of the cyanide and, therefore, at low salt to cyanamide ratios and at higher temperatures, the product grade is decreased. It is likely that the salt evaporates at the higher reaction temperatures and this decreases the cyanide capacity of the melt. High heating rates minimize the residence time and thus salt evaporation is reduced and higher grades can be obtained. As expected, the cyanide content increased with the nitrogen content of the cyanamide. Calcium carbide additions resulted in an increase in the product grade. The presence of small amounts of moisture in the charge caused a significant decrease in the cyanide content of the black cyanide. An equilibrium reaction is postulated in order to explain the black cyanide process and in particular the effect of calcium carbide on the product grade."

Jan 1, 2002

By H. Ewaschuk

"INTRODUCTIONRio Algom's involvement with the Enviro-Clear thickener began in May 1975, when tests on a laboratory waif were carried out by our Research and Development group. Commencing in June, further tests were carried out using a 3 foot diameter pilot unit. By December, a 30 foot full-scale thickener had been installed. In the near future, 3 more Enviro-Clear thickeners will be commissioned. With in the space of a year, almost $2.5 million had been committed to liquid/ solid separation facilities using the Enviro-Clear thickener. This paper briefly traces the extent and development of this commitment.BRIEF HISTORY OF QUIRKEQuirke Mine started operating in September 1956 at a rated capacity of 3,000 TOD. Because of market conditions, Quirke was shut down in December 1960. The facilities were re-opened at an increased capacity of 4,000 TPD in July 1968, by which time the demand for uranium had returned. Also, a second shaft was sunk, and by 1970, all of the ore treated in the concentrator was coming from the new Quirke II mine. The Quirke I stopes were allowed to fill with natural seepage. As well, acidic barren solution from the concentrator was pumped underground.With increasing demand for uranium, the capacity of Quirke will be further expanded to 7,000 TPD by 1978. Studies of how this expansion could best he carried out led to the consideration of a fairly new piece of equipment, the Enviro-Clear thickener, for certain operations in the concentrator. These operations are as follows:"

Jan 1, 1977

By L. M. Gould

"Syncrude Canada operates the largest oil sands crude oil production facility in the world and produces over 13% of Canada’s total oil requirements. To achieve this, Syncrude mines the oil sands in open pits, extracts the raw oil known as bitumen from the sand using water-based processes and upgrades it into sweet light crude oil by fluid coking, hydroprocessing, hydrotreating and reblending. The final product, Syncrude Sweet Blend (SSB), is sent by pipeline to three Edmonton area refineries and then to pipeline terminals which ship the SSB to refineries in Canada and the United States.As parts of the Mildred Lake base mine reached their economic life, they were replaced with new facilities at the Aurora Satellite mine. Aurora is situated on Oilsand Leases 10, 12 and 34, 35 km northeast of the Mildred Lake facility (Fig. 1).In 2000, the first hydrotransport low-energy extraction production train started up at Aurora. A second production train is scheduled for start-up in 2003. Open pit mining at Aurora occurs using two hydraulic shovels, two cable shovels, and trucks ranging from 320-ton to 380-ton payload capacities (Fig. 2).Once the oil sands is excavated, the trucks dump the ore into a crusher designed to break up the big lumps of oil sands and rock at peak rates of 11 000 t/hr. The ore is then transferred by conveyor to a surge pile and then to a mixing box which combines the oil sands with hot water. Following bitumen separation in the primary separation vessel, froth is delivered to Mildred Lake for processing via the intersite pipeline (Fig. 3).The goal of this paper is to illustrate how high precision shovel GPS (HPGPS) is being used at the Aurora mine to aid in mine planning. This can be accomplished by first describing the function of the mine planning department, describing the Aurora orebody, and finally explaining how the HPGPS system functions and how it is employed at Aurora.The short range mine planning department ensures a steady supply of ore is delivered to the plant at the desired grade in a sequenced and economical manner. This is done by creating a mine plan that consists of shovel dig locations that require the shovels to mine in a specified area at a specified elevation."

Jan 1, 2002

By Carolyn Kenney, Jianjun Liu, Zhenghe Xu

"The flotation of fine particles has been a challenge to scientists and engineers in mineral processing. A novel concept of reactive oily-bubbles as carrier to float fine particles is described in this paper. The reactive oily bubble flotation is considered attractive for fine particle flotation. In addition to the role of fine particle agglomeration by oily films, the surface properties of air bubbles coated with a thin oil film can be better controlled for the desired selectivity by adding certain types and concentrations of water insoluble collectors into the oil phase. This approach can eliminate the addition of collector to the aqueous phase, avoid undesired synergetic interactions among collectors, activators, depressants and dispersants present in slurry, minimize undesired activation of gangue particles and significantly reduce the amount of collectors needed.The concept of using reactive oily-bubble to achieve selective flotation was demonstrated in contact angle measurement and by microflotation tests with fine sulphide minerals: sphalerite and galena in this paper. The flotation behavior of sulfide minerals can be radically modified with adjustment of solution pH, addition of depressant and activator as in conventional flotation. The successful separation between PbS/SiO2, ZnS/SiO2 and PbS/ZnS was demonstrated using mixed mineral systems. Compared with conventional flotation, the reactive oily-bubble flotation showed a stronger collecting power.INTRODUCTIONThe challenge for fine particle flotation has long been recognized and well documented (Fuerstenau, 1980). Because of drastic changes in surface properties of fine particles and associated physicochemical and hydrodynamic conditions of flotation systems, fine particles responded poorly to the conventional flotation processes. For instance, the small mass and hence low inertia of fine particles would result in a low efficiency of collision and attachment of fine particles with flotation bubbles. Large specific surface area of fine particles, on the other hand, would cause an increased reagent consumption. Dominating colloidal forces of fines may cause slime-coating, accompanying a low selectivity (Somasundaran & Arbiter, 1979; Fuerstenau, 1980; Sivamohan, 1990)."

Jan 1, 2003