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By Thomas M. Drown

AT the meeting of the Institute in New York,, in February, 1880,* I described a process of determining sulphur in metallic sulphides, with especial reference to the determination of pyrites in coal. The process, as then described, is as follows : A solution of sodium hydrate, of 1.25 specific gravity, is saturated with bromine. If an excess of bromine is used it must be neutralized by the addition of a :little more sodium hydrate. The pulverized mineral or coal is moistened with 25 c.c. of this solution and heated, then hydrochloric acid is added cautiously to just acid reaction. This operation is repeated with another 25 c.c. of the alkaline solution, and again rendered acid. The mixture should be kept hot. The contents of the beaker or dish are then * Transactions, American Institute of Mining Engineers, vol. viii, p. 569.

Jan 1, 1881

By E. E. Malouf

Rapid depletion of the world's mineral deposits combined with the expanding demand for metals places great pressure on our ability to provide technologically and economically feasible processes to recover greater amounts of metals from progressively lower grade sources. Chemical mining is one area in which expanding research and development can provide new processes or refinements to existing ones. These new techniques could result in increased production of metals from materials now considered uneconomic to process by current technology. To mine by chemicals requires the interaction of such disciplines as hydrometallurgy, microbiology, chemistry (both organic and inorganic), fluid flow, mineralogy, geology, and of course, economics. One of the least understood areas but one which may end up being an essential part of any chemical mining process is microbiology, i.e., the role of microorganisms in altering minerals and metals in solution.

Jan 1, 1971

By Charles M. Bayer

Reading in the AIME annual reports that certain activities have been financed by the Rocky Mountain Club Fund, less senior members of the Institute may wonder. "What's the Rocky Mountain Club?" Less youthful members will not have to wonder. They will recall the Club as an intriguing, almost fantastic organization, largely of western mining men, that flared across the New York horizon, flamed brilliantly for a little more than two decades, then sputtered out of existence- glorious even in its last flash. It was the only product of its mold, a fabulous group of magnanimous men who unhesitatingly sacrificed a cherished dream for which they had raised millions of dollars so that the money, instead of creating a magnificent club house, could be used instead to save the lives of starving Belgian children in World War I.

Jan 12, 1964

By Joseph M. Chelini

A cash-flow factor is any figure acquired in an evaluation that effects the cash flow potential of an eventual operation. Table I is a list of some of these cash-flow factors. There are more, such as, the payments and penalties in a smelter schedule if the concentrate would be sent to a smelter. During an evaluation it is necessary to maintain a two-way flow of communication between the evaluation people and financing people. To accomplish this, it is necessary to translate the vocabulary of the evaluating people into the vocabulary of the financing people, or geologic and engineering jargon into dollars and cents. This is done by cash-flow studies in which cash-flow factors are input, which when logically manipulated using accepted rules and procedures of accounting, provide an output in dollars and cents.

Jan 5, 1972

C. Q. PAYNE, New York, N. Y. (written discussion*).-The method adopted by Mr. Lennox is a very interesting test of the practical application of Mr. Gates' crushing-surface diagram to a greet variety of gold and copper ores. His method of dealing with the material below 200-mesh is also a distinct contribution to the subject, although, as he suggests, it seems likely that some microscopic measurement of this material may be advisable before the mesh reciprocals of its group particles can be dealt with as accurately as can those coarser than 200-mesh. In examining the general results shown in Table 3, it is somewhat puzzling to perceive why Calumet &, Hecla jig tails should show a crushing resistance 3 - times greater than that of the ore from the Ray Consolidated copper mine. The latter is, I believe, an altered. Pinal schist

Jan 10, 1918

By Robert H. Richards

It will hardly be worth while to spend time over the discovery of this mine, how lumps of galena were picked up and brought to town, and how legends were told of an old mine from which Revolutionary bullets were made. This is an entirely new mine, with no evidences of former or ancient workings in its immediate vicinity to guide or attract the prospector. The first pit was opened in May, 1874. In August I made a visit to this pit, which was 6 feet wide in the northwest direction, 12 feet long north 80° east, and 6 feet deep..About 4 tons of a galena carrying gray copper, siderite, and quartz, had been taken from this pit. The lumps were all of them evidently float specimens, and varied from 8 to 12 inches thick, and showed very distinct indica-

By Peter L. Swanson

A microcrack process zone is frequently suggested to accompany macrofractures in rock and play an important role in the resistance to fracture propagation. Attenuation of surface waves propagating through mode I fractures in wedge-loaded double-cantilever beam specimens of Westerly granite has been recorded in an attempt to characterize the structure of the fracture process zone. The ultrasonic measurements do not support the generally accepted model of a macroscopic fracture that incrementally propagates with the accompaniment of a cloud of microcracks. Instead, fractures in Westerly granite appear to form as gradually separating surfaces within a zone having a width of a few millimeters and a length of several tens of millimeters. A fracture process zone of this size would necessitate the use of meter-sized specimens in order for linear elastic fracture mechanics to be applicable.

Jan 1, 1984

By Stuart M. Buck

THE term "splint" seems to have been adopted to describe the fracture of the hard bituminous coals of West Virginia. It is not a scientific name,, but rather a trade term, and does not indicate a correspondence with English splint. At present it is a popular word, and is very loosely applied to coals of various qualities, in the desire to improve their sale. The Kanawha splint is distinguished by its hardness, dull lustre, coarse fibrous structure, its purity, and especially its resistance to atmospheric influence. It kindles very readily, burns with a bright flame, but does not cake, so that a lump when half consumed, may be broken by a slight blow in its plane of cleavage, though 'it will resist a' strong blow in any other direction. I have seen pieces that have been exposed to frost and sun

Jan 1, 1882

By Stuart M. Buck

The term "splint" seems to have been adopted to describe the fracture of the hard bituminous coals of West Virginia. It is not a scientific name, but rather a trade term, and does not indicate a correspondence with English splint. At present it is a popular word, and is very loosely applied to coals of various qualities, in the desire & improve their sale. The Kanawha splint is distinguished by its hardness, dull lustre, coarse fibrous structure, its purity, and especially its resistance to atmospheric influence. It kindles very readily, burns with a bright flame, but does not cake, so that a lump when half consumed, may be broken by a slight blow in its plane of cleavage, though it will resist a strong blow in any other direction. I have seen pieces that have been exposed to frost and sun

Jan 1, 1882

[ARTICLE I. NAME AND OBJECT Section 1. This Society shall be known as the Society of Petroleum Engineers of the American Institute of Mining, Metallurgical, and Petroleum Engineers, Inc. Section 2. The object of the Society of Petroleum Engineers shall be to furnish a medium of cooperation among those interested in the petroleum-natural gas industry an to promote the advancement of this branch of mineral technology through meetings to stimulate the preparation, reading, discussion and circulation of papers connected therewith. ARTICLE II. MEMBERS Section 1. Any person who is a member of AIME may become a member of this Society by the specified process. Section 2. Local organizations may be formed by the Society of Petroleum Engineers as subsidiary units, the membership of which shall be subject to and in accordance with the by-laws of the Institute.]

Jan 1, 1961

By Klaus M. Zeitler

INTRODUCTION One cannot discuss the subject of "Raising Capital in the 1990s" without having a crystal ball and a reliable fortune teller. This discusses "Raising Capital for the 1990sW, which is what Metal1 Mining Corporation did in 1987. We raised (3166 million in an IPO (initial public offering) that was originally planned for only some (375 million. Why did we raise this money? How did we do it, and why was this IPO so successful? The answer to the first question requires a description of the promoter and principal shareholder of Metal1 Mining Corporation, Metallgesellschaft AG. This West Germany company was founded over 100 years ago in Frankfurt as a trading house for non-ferrous metals. It has developed into one of the world's leading firms in the non-ferrous metals industry. The company's worldwide activities in all areas of that business include mining, smelting and refining, the trading of ore, base and precious metals, the production of semi-fabricated and finished metal products, and the provision of engineering, construction and transportation services. Metallgesellschaft AG has also diversified into many other areas, the most significant of which are manufacturing, the production of chemicals, the development and application of technical and chemical processes, the planning and construction of industrial plants, and activities associated with finance, insurance, shipping and freight forwarding, and the provision of barter and countertrade services. The company maintains a network of more than 100 offices around the world; it employs some 25,000 people in its worldwide activities. [Selected financial data, as of September 30, 1987: (MetaUgesellschafl AG) Working Capital DM 8%.6 million CDNS 672.8 million Long Term Debt DM 568.0 million CDNS 426.2 million Sales DM 14.9 billion CDNS 11.2 billion Net Income DM 87.7 million CDN$ 65.8 million Market Capitalization at April 27, 1987: (Metallgesellschafi AG) Outstanding Shares ~,6oo,o0o DM 1,875 million CDNS 1,407 million] For the fiscal year ended September 30, 1987, Metallgesellschaft AG had, on a consolidated basis, net sales of DM13.3 billion, net income of DM100 million and total assets of about DM7.0 billion. Metallgesellschaft AG established the American Metal Company, a predecessor of AMAX Inc. one of the largest ventures undertaken by Metallgesellschaft AG then was the acquisition, through the American Metal Company, of a majority share in the Mexican Penoles mine, a large lead and silver deposit. METALLGESELLSCHAFT AG Figure 1 depicts an overview of Metallgesellschaft AG before and at the time the initial public offering of Metall Mining Corporation's shares took place. It shows that mining was far from the centre of Metallgesellschaft's activities. Therefore, it could not expect to receive an extraordinary amount of board attention. Thus, mining investments not only had to compare well with other mining opportunities, but were in fierce competition with projects from other divisions. In addition, mining was sub-divided into two separate departments -- domestic and international. These two departments had different management styles and diverging interests which resulted in a minimum co-operation between them. The domestic mining department was primarily interested in the survival of the local mines. These mines were characterized by rising operating costs and declining ore grades. It took a special commitment and continued ingenuity to develop and adjust to local conditions, and modern mining and processing technology, in order to remain competitive, or at least survive within the international mining industry. Local management

Jan 1, 1990

By Donald L. Katz, Leslie J. Noaker

Experimental data are presented for hydrate formation conditions for mixtures of hydrogen sulfide and methane. Vapor-solid equilibrium constants for hydrogen sulfide are also presented. Equilibrium constants, defined here as the ratio of the mole fraction of hydrogen sulfide in the vapor phase (dry basis) to the mole fraction of hydrogen sulfide in the solid phase (dry basis), were calculated using the vapor-solid equilibrium constants for methane presented in an earlier paper. The conditions at which a natural gas will form gas hydrates with water may be computed from its composition, when hydrogen sulfide is present in addition to carbon dioxide and the paraffin hydrocarbons. INTRODUCTION Many gases are known to form solid hydrates in the presence of liquid water at temperatures above 32°F. This hydrate formation is of importance to the natural gas industry inasmuch as most of the constituents found in natural gases will form hydrates. The attention of the industry was called to hydrates by Hammer-schmidtl0 in 1934. A number of papers have been written giving the temperatures and pressures at which these hydrates will form3,4,5,6,7,8,9,10,13,14,15,18,19 and a bibliography on the subject has been compiled13. Deaton and Frost4,5,6,7,8 report work for various pure gases and for some natural gases. Katz and co-workers3,4,13,14,18,19 have reported data for various gases at high pressure. They developed a method of predicting conditions for hydrate formation from equilibrium constants3,19 and from gab gravity." The effects of anti-freeze agents on the formation of hydrogen sulfide hydrate were reported by Bond and Nelson.' The hydrogen sulfide-water system, including hydrate, has been the subject of recent investigation by Sage and co-workers." Mixtures of hydrates behave as solid solutions and an equilibrium exists between the vapor phase and the solid phase that appears to be comparable to the equilibrium between vapor and liquid phases.3,10 By means of the vapor-solid equilibrium constants which have been published for methane, ethane, propane, iso-butane, and carbon dioxidel6 it is possible to determine the temperature and pressure at which hydrates will form for a specific gas mixture when water is present. Hydrogen sulfide which is frequently found in natural gases has a very strong tendency to form hydrate and must enter the solid solution when present in a natural gas forming a hydrate. To determine the effect of hydrogen sulfide when computing the conditions for gas hydrate formation, it is necessary to have the equilibrium constant giving the ratio of the concentration of hydrogen sulfide in the gas phase to the concentration in the solid phase. This paper presents data on hydrate formation for mixtures of hydrogen sulfide and methane and presents the equilibrium constants which were calculated from these data. EXPERIMENTAL PROCEDURE The apparatus used to determine the conditions of hydrate formation for the methane-hydrogen sulfide system was similar to that employed by previous investigators.3,18,19 A charge gas cylinder was used to supply the hydrogen sulfide-methane mixtures, called the charge gas, and to supply the pressure up to 1.000 psia. This

Jan 1, 1955

Few people in the industry today are competent to comment on the O.G. system for vessel covers, but with papers as well prepared as Mr. Bradley's we will soon be well informed. I would like to direct these comments to Mr. Klaes of Ford Motor Company. Mr. Klaes' description of their steaming hood agrees with our experience at Weirton. We have been able to stay within design limits and, as a result, have had few problems with our auxiliary equipment. Our main problem, as with Ford, has been thinning of our vessel cover tubes. At Weirton, controlled circulation, high pressure boilers are in use as heat recovery units above the BOP vessels. The boilers are provided with "off cycle' oil firing equipment. A Venturi type wet gas scrubber follows the boiler to complete the vessel draft system.

Jan 1, 1972

By F. R. Morral

HOT-DIPPED heat-treated zinc coatings on sheet steel were examined with X-rays. The phases identified were compared with those listed in the modern literature of the zinc-iron system. The zeta (FeZn13) phase is shown to correspond to the phase found by Schueler (1925) in heat-treated zinc coatings. An investigation was undertaken to determine the phases present in hot-dipped FIG. I.-SYSTEM IRON-ZINC ACCORDING TO J. SCHRAMM.11 heat-treated zinc coatings on steel sheets and wire. This kind of coating on wire was studied some years ago by Schueler1 by microscopic and chemical methods. He reported a new phase, FeZn10. Later, Clark and Stillwell,2 using X-ray crystal analysis, identified a new phase in ordinary galva-nized wire, which was assumed to be the FeZn10 phase.

Jan 1, 1940

By Jack Fox

Three years ago we attended the V International Mining Congress in Moscow. This year we attended the VI International Mining Congress in Madrid. By almost any criterion, this was a most successful convention. There were 1717 registrants, not counting the ladies. I don't know how many of the latter there were, but they certainly made a welcome addition to the group. Once again, the International Organizing Committee put together a very impressive technical program which the Spanish National Committee backed up with a brand new Palacio de Congresos admirably equipped with simultaneous translation devices and an organization that provided an excellent social program, a tremendous set of post- meeting excursions, and very impressive opening ceremonies, entertainment and closing ceremonies. There was also an exhibit on the subject of Spanish and Spanish American mining history in the Palacio de Congresos.

Jan 1, 1970

By E. P. Jennings

(Read at the Amenia Meeting, October, 1877.) THE abundance and value of the tellurium minerals of Colorado is well known, but, as yet, few analyses have been made of them, and I offer these as a small contribution to the chemistry of these valuable ores. 1. Native Tellurium.-The specimens from which the analyses of this mineral were made are from the "John Jay" Mine, Boulder County, Colorado, where it occurs in quite large masses, though mixed with more or less silica and iron pyrites. It is usually a fine¬grained, tin-white mineral, but sometimes occurs in distorted, hexag¬onal prisms in cavities in the quartz. Before the blowpipe it gives the reactions for tellurium, sulphur and iron; by cupellation, it yields a small amount of gold. An analysis of a coarsely crystallized speci¬men gave the following results

Jan 1, 1878

By William P. Blake

In a former paper read at the Washington meeting of the Institute, February, 1881,' I presented a general view of the geology and veins of Tombstone as then developed. Considerable additions have been made to our knowledge of the oredeposits since that date, nearly all the mines having been worked down to the general wster-level of the district. This water was a bar to further progress in depth and costly pumps were erected at the Grand Central mine and at the Contention. By the united action of these pumps the water was gradually lowered, not only in these two mines, but in all the important mines of the district. Pending a consolidation of interests, or an equitable distribution of the cost of unwatering, both pumping-plants were destroyed by fire, and the mines were closed

Jan 1, 1904

By Freeman Bishop

This year the metal mining industry is in for some difficult decisions as the nation struggles to control inflationary pressures resulting from higher production costs and a money-squeeze policy. Re- clouding these problems will be campaign oratory as Congress seeks reelection. Charges will be hurled back and forth between a Republican White House and a Democratic Congress. Inflation and Vietnam will be the big one. Hut pollution i. coming on strong. President Nixon has formed a new Council on Environmental Quality although he already had named a similar unit within his Cabinet six months ago. Both are charged with bringing 1.0 bear all of the Federal Government's talents on the focal points of antipollution measures The biggest task will be to find out how many different "units" are currently mixed up in these efforts.

Jan 1, 1970

By James Kemp

PostScript to a paper presented at the New York meeting, February, 1915, and printed in Bulletin No. 98, February, 1915, pp. 129 to 154. The writer looked over the quarry with care in the search for fossils, having in mind shells or corals of fairly large size. In the brilliant summer sunshine, none were observed on the glaring white ledges. The impression was gained that none were present and the statement to this effect was made in the edition of this paper published in the Bulletin' of the Institute for February, 1915, p. 136. On closer examination in the laboratory it has been discovered that the limestone itself is made up of minute organisms, which are clearly revealed by microscopic examination of thin sections. The principal component of the rock is a small foraminifer, 0.1 to 0.3 in. (2.5 to 7 mm.), of the genus Orbitoides, presumably an Oligocenic form. Figs. 1 and 2. illustrate it. The accompanying description has been kindly summarized by Marjorie O'Connell, M. A., Curator in Paleontology in Columbia University, who first detected the evidences of organisms in the rock. Orbitoides kempi O'CONNELL N. SP.1 The foraminiferan which makes up the Seboruco limestone is an Orbitoides of a Species new to North America. The only Orbitoides heretofore described from this country is 0. mantelli from the lower Oligocenic of the Gulf States. This form from Cuba, then, so different in all of its characteristics from the 0. mantelli, is of great interest as perhaps forming a basis of correlation over wide areas. The most closely related Species is 0. dispansa Sowerby, which occurs in the Nummulite limestone of the Eocenic of the Bavarian . Alps, in the Priabona beds of the lower Oligocenic of Massano, and elsewhere in Italy, as described by Gümbel.2 The age of the limestone in Cuba would thus Seem to be of upper Eocenic or lower Oligocenic age, probably the latter. The fossil has the form of a sphere Surrounded by a wavy rim of horizontal extent, the whole resembling two flat-brimmed, round-crowned hats placed base to base. The total extent of the Shell ranges up to 7+ mm., while the thickness of the central sphere is 2.5 mm. in one of the largest individuals. Like all of the other Species of Orbitoides, this form begins with a Single layer of chambers which multiply in one plane and assume a circular outline; but it is in the subsequent growth that the distinguishing specific characters appear, for the chambers at the central portion of the shell increase more rapidly than do those near the periphery and in consequence a Swelling is produced which finally gives the Spherical form which is so characteristic. The rim, on the other hand, shows little chamber-increase and remains thin. This is clearly Shown in the sections figured, where the central row of larger chambers forms the equatorial zone. Radiating from this row, in section, there appear, a number of solid cones alternating with broad reticulated ones. The solid cones mark the more dense structure forming the walls surrounding the reticulated or chambered cones. These appear upon the Surface as distinct pits, whereas the solid part appears as raised walls.

Jan 7, 1915

V. R. GARFIAS,* Palo Alto, Cal. (written discussion?).-Regarding the statement of Mr. Ordoñez, on page 1007, concerning the synclinal curving of sedimentary beds caused by the extrusion of volcanic necks, that "this phenomenon might occur, but it is not fully proved in our fields," I beg to reply that the funnel and anticlinal-ring structure is actually associated with igneous intrusions in the Mexican oil fields, as we were able to ascertain by plotting an underground contour map and making a structural model of the oil-bearing beds of the Ebano field. E. DE GOLFER, New York, N. Y. (written discussion?).-The paper under discussion is not only of interest in connection with its subject but it is a contribution of considerable importance to our knowledge of the possible effect of igneous rocks upon the accumulation of petroleum in the Mexican fields.

Jan 10, 1918