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By E. W. Davis

THE large iron-ore producers on the Mesabi Range are able to maintain the silica in their shipping products at from 8 to 10 per cent by mixing ores of various grades, some assaying 4 per cent silica and some as high as 18 per cent silica. For each ton of 4 per cent silica ore mined, a ton of 14 per cent silica ore can be mined and mixed with it and the average grade maintained at 9 per cent. This mixing operation has made possible the utilization of large cluantities of ore too lean to be used alone. and herein lies the advantage of the producers who operate a number of mines at the same time. As the grade of the ore from one of the properties falls off, a little high-grade ore from another property can be mixed with it and the average maintained, while if one property alone were being operated all of the ore below grade would be left behind.

Jan 1, 1930

By John Jermain Porter

The chief purpose of this paper is to indicate the laws governing the fuel-economy of the cupola, to examine the feasibility of some of the proposals for increasing its fuel-economy, and to show that the conditions limiting fuel-economy here are altogether different from those prevailing in the blast-furnace. The two methods available for studying the thermal efficiency of the cupola and determining the factors limiting fuel-economy are: 1, by the determination of the total heat-balance; and 2, by the application of the theory of critical temperatures. The case selected as an example represents a cupola operating under fairly efficient conditions. The data are as follows : Cupola, GO in. in diameter, 15 ft. high to the charging-door, with a 9-in. lining. Bed-charge, 2,000 lb. of coke and 4,000 lb. of iron. Subsequent charges, 400 lb. of coke and 4,000 Ib. of iron. Total number of charges, 20. There was 800 lb. of coke recovered from the drop, hence the total coke burned is 8,800 lb., or 0.11 lb. of coke per Ib. of iron. Coke contains 90 per cent. of fixed carbon and 2 per cent. of moisture. 300 1b. of kindling-wood is used in lighting. 80 lb. of limestone (95 per cent. of CaCO,) is used per charge, or 0.02 lb. per Ib. of iron. Melting-loss, 4 per cent.; distributed thus : Fe, 3.5; Si, 0.25; Mn, 0.25 per cent. Average analysis of top-gases : CO2, 15.1; CO, 10.0 per cent. Average temperature of top-gases, 1,600" F. Temperature of air and stock charged, 60" F. Dew-point of air, 50 F. The items entering into the total heat-balance and their calculation are as follows: 1. Heat of combustion of fuel.—Total heat evolved = 14,580 x lb. of carbon burned + 7,200 X Ib. of wood burned. Hence B.t.u. per lb. of iron charged =

Jan 1, 1913

HAVING previously told you about lodestone, azure, emery, and manganese, things that perhaps belong more properly to the stones than to the metals, the desire has come to me to describe rock crystal as well and, with this, some of the better-known gems, although they are things that are not classified with metals, as far as I know, or even with the serniminerals. In truth, they are neither one nor the other, but they are stones and have the nature of stones. But let them be what they may, in order to avoid straying from the subject we have begun, we shall say that they have mineral properties in their species, as for instance, in respect to their colors. It would seem an error to me if, while I am giving you information on so many other useful things, I did not give you this as well, if for no other reason than because it is a fine accomplishment for a gentleman to have some knowledge concerning gems. Thus since I have proposed to do this, beginning to speak of crystal, I tell you that it is a lustrous, transparent, and limpid stone, composed by Nature with a predominance of wateriness. Thus, contrary to the order of natural things, it has been believed by many that Nature has generated it of pure water by means of a powerful and continuous coldness that always exists in those mountains and places where it is found, for the waters and snows can never melt there because of the great cold. They have tried to prove this opinion of theirs by saying that crystal still retains the nature of frozen water, and that this is. shown not only in its appearance but also in the fact that, like ice, it floats without sinking to the bottom when it is put in water. They also say that it is customary to put it under the tongues of the thirsty on account of the, coldness and moistness which it gives, and that it quenches the dryness of their thirst. But even if all these things were true, as they are not, they do not upon consideration bring us to the conclusion that it is water, because the diamond and the beryl would do the same. Therefore it does not seem to me credible [391 that it is as they claim, for it is a stone generated as such by Nature. And then, if this were true in those places where it rains often and many snows are formed, and these should freeze and never melt but

Jan 1, 1942

By S. Robinson Brainard

In 1957 the pay of chief executives in the nonferrous metals industry was well above average when compared with other major industries. Furthermore, it continued to rise last year while sales declined 8.2 pct and profits plummeted 32.7 pct on the average. Compensation of Chief Executives: One of the primary objectives of the survey is to measure year-to-year changes in top-management total compensation as it relates to company size and industry characteristics. Total compensation includes salary, bonuses, and the value of deferred contingent compensation awards.

Jan 10, 1958

HAVING demonstrated to you above the practice of bringing silver to its ultimate fineness and perfection, it now remains for me to describe how the two kinds of metals that are found in the smelting product that you made from the ores are to be brought to their end: One is copper and the other lead, and perhaps a third is gold, if per-chance the silver that you refined in the cupeling hearth contained any. It would be almost impossible that it should not contain any, because either a little or a lot is almost always found as an admixed substance not only in silver but in. every one of the other metals as well. But in order to continue in sequence, you must suppose that there is some gold and that, of the two materials you have that I mentioned above and told you to save, one is the matte (calling it according to the usage of Germany, * since I do not know a more exact or better word for describing it to you) and the .other is the litharge that you took from the cupeling hearth. In addition, the hearths themselves are saturated and full of lead. If these things should remain in their present condition they would be useless bodies without any perfection. First, taking one of the three said parts, as a material of greater quantity and also as a thing that needs greater labor, and because, being reduced to the point I have told you with smelting and evaporation, it is nearer to its end, I shall tell you what must be done in order to bring it to pure copper. As I have told you, there are two materials on hand, one of which is the matte and the other the litharge. Each at first sight seems a half-burned thing; one has already been finished metal and the other is to be, but in my opinion the matte is nearer to its end than is the litharge because the latter has been dried by the power of the fire and re-formed from another body. Now leaving aside the discussion of this thing, after the matte has been well evaporated and reduced, it is taken and put on a forge. In front of the tuyère a receptacle is made of stones that neither calcine nor melt, or of coals and powdered clay, in the form of a little cradle that is longer than it is wide and not very deep. Its length should be about one and a half

Jan 1, 1942

By W. R. Jones

composition, he cannot reasonably asl; the manufacturer to guarantee that this composition shall give certain physical results. W. R. Jones, Pittsburgh, Pa. : The question that naturally occlun to me is this: Has Dr. Dudley in his inveatigtrtions been aiming to prove a theory, or has he been guided by an earnest desire to discover what are the proper elements in the composition of a good-wearing steel rail ? Unfortunately, for correct chemical information, he has omitted in his analgw two very importnat elements,—sulpbur and copper. Now, before we will even begin to admit the correctnets of Dr. Dudley's conclusions and the formula he prescribes, we will at the start question the propriety of any chenlist or scientist prescribing a formula for making steel when he has iguared such important ele ments as sulphur aud copper. I, for one, will not accept any such formula. Are we sure, or is Dr. Daclley sure, that the chemical analyseq embodied in his paper are correct? This may seem a presumptuous queetion, yet, with my experience with chenlists, I naturally doubt the correctness of the analyse8, and, before I will accept them as correct, I will ask that comparative tests of phosphorous and man ganese be made by the Pennsylvania Railroad chemists and the chemists of the leading steel-works in the country. Let us first verify the correctness of the analyses before we consider the con clusions. I can enumerate a great number of instances in which chemists have differed very widely in their determinations of phos phorus and manganese. A prominent iron fitam made a contract with the Edgar Thomson Steel Company to deliver pig metal guar anteed to be between 0.07 and 0.08 phosphorus; an analysis by our chemist resulted in phosphorus 0.148 and 0.152,—a rather startling difference! Again, a sample bar of steel, in which our chemist reported phosphorus 0.11, was tested by a chemist of au other Bessemer works, ana his determinations were phosphorus between 0.07 and 0.08: A leading engineering establishmeut of Pittsbdrgh bought iron claimed by a chemical analysis to contain 0.08 phosphorus; our Mr. Ford found phosphorus 0.145. A chem ist connected with an open-hearth works reported manganese in a piece of steel, 1.14; in a second determination from the same piece of steel, by the same chemist, manganese was reported 0.43. The chemist was kept in ignorauce of the fact that both samples were from the saw piece of steel. Two dctermiuations for manganese

Jan 1, 1881

By F. S. McNicholas, M. S. Walker, V. C. Rogers

During the year of 1944 and the first half of 1945, the Climax Molybdenum Co. made a study of some of the problems in block and panel caving, with the use of a scale model. The experiments dealt essentially with the type of rock and conditions at Climax, but some experiments were carried out to simulate conditions found in other mines. Most of the previous experiments on the caving characteristics of rock have dealt with sedimentary or broken igneous material. The series of experiments described here was designed to show the caving action of unbroken igneous rock. Con- siderable difficulty was experienced in duplicating unbroken material in the model. The results obtained are believed to be relatively correct, but verification must necessarily come from future mine operation. Observations in the mine and glory hole, together with statistical data, were used as criteria for creating similar conditions in the model. In 1913, George R. Lehman' experimented with broken material in a model for the Inspiration Consolidated Copper Co. and, more recently, P. B. Bucky2 experimented with broken material with a capping of mill tailings. Mr. Lehman's model represented a maximum ore height of 70 ft. capped by 55 ft. of waste. He varied the draw-hole spacing from 6¼ ft. to 8? ft. and 12½ ft. The material used graduated from fines to 30-in. maximum size. Some of his conclusions were: "(I) The less the distance between chute centers, the greater the extraction (Fig. I); (2) the higher the ore column, the greater the extraction; (3) the less the amount drawn at a time from each chute, uniformly, the greater the extraction of clean ore before the capping appeared, but not the greater the total extraction to a I per cent copper final product." (Fig. 2.) Professor Bucky concluded, in part: "(I) Drawing of ore may take place at any time from any finger and in any amount without affecting materially: (a)

Jan 1, 1946

By Kendall E. Born

Production of crude oil in Tennessee during 1940 was slightly more than 15,000 bbl., a decrease from 1939 of about 36,000 bbl. This sharp decline has been caused largely by curtailed activities in the shallow pools in Clay County, where approximately 3000 bbl. was marketed off the lease during the year as against more than 37,000 bbl. in 1939. The flashy production found in 1938 in the Celina area has been short-lived and the area is essentially abandoned. Failure to find steady production has been the major factor retarding developments in the northeastern Highland Rim area. The Mississippi lime production in Scott and Morgan Counties continued to show a steady decline. The Tennessee production by counties is shown in Table I. Table i.—Oil Production in Tennessee it1 1940 Production. Bbl. Number of County Wells Pumped 1939 1940 Scott............ 4 4,332 3.596 Morgan.......... I: 6,479 5,751 Fentress.......... 3 I,2XX 1,5xz Pickett........... 1 1.2XX Clay............. 8 37.200 3,XXX Developments There were 32 wells spudded in during 1940, four of which were drilling or only temporarily suspended on Dec. 31, 1940. Twenty-eight wells were completed during the year, four of which were commercial producers. The total footage drilled was 3I,214 ft. The more important wildcats are listed in Table 2; the distribution of 1940 oil and gas tests according to physiographic divisions is given in Table 3. Cumberland Platenu.—Thcre was one completion in the coal area of the state, a test that attempted to extend the Mississippi lime production in the Coon Hollow pool to the southeast in Morgan County. This test encountered only slight shows of oil in the producing horizons of the near-by Coon Hollow and Boone Camp pools. Some surface work was carried on by private interests during the year in Scott and Morgan Counties and two wells were spudded in early in 1941 The revival of interest in the Kentucky portion of the plateau will probably result in increased activity in this part of Tennessee during 1941. Several sizable blocks of acreage, some by major oil companies, are held in Scott, Morgan, and Cumberland Counties. Middle Tennessee.—The northeastern Highland Rim continued to be the most active area in the state with 20 completions, although this figure is about one third of the number drilled in 1939. Four oil wells, none with initial productions of more than I00 bbl., were completed in Clay, Fentress, and Pickett Counties. The producing horizons discovered in Pickett and Fentress Counties were in the "Sunny-brookJ' pays of Trenton age. The Clay County producer was an old test drilled deeper in which oil was found at 671 ft. in the upper part of the Stones River group of limestones, a common pay in this area. All four wells were drilled in or close to old shallow production. Deeper testing into the Knox dolomite group in this area was not particularly encouraging, although one well in Fentress County encountered some saturation at 1860 to 1869 ft. in the upper

Jan 1, 1941

By Kendall E. Born

Production of crude oil in Tennessee during 1940 was slightly more than 15,000 bbl., a decrease from 1939 of about 36,000 bbl. This sharp decline has been caused largely by curtailed activities in the shallow pools in Clay County, where approximately 3000 bbl. was marketed off the lease during the year as against more than 37,000 bbl. in 1939. The flashy production found in 1938 in the Celina area has been short-lived and the area is essentially abandoned. Failure to find steady production has been the major factor retarding developments in the northeastern Highland Rim area. The Mississippi lime production in Scott and Morgan Counties continued to show a steady decline. The Tennessee production by counties is shown in Table I. Table i.—Oil Production in Tennessee it1 1940 Production. Bbl. Number of County Wells Pumped 1939 1940 Scott............ 4 4,332 3.596 Morgan.......... I: 6,479 5,751 Fentress.......... 3 I,2XX 1,5xz Pickett........... 1 1.2XX Clay............. 8 37.200 3,XXX Developments There were 32 wells spudded in during 1940, four of which were drilling or only temporarily suspended on Dec. 31, 1940. Twenty-eight wells were completed during the year, four of which were commercial producers. The total footage drilled was 3I,214 ft. The more important wildcats are listed in Table 2; the distribution of 1940 oil and gas tests according to physiographic divisions is given in Table 3. Cumberland Platenu.—Thcre was one completion in the coal area of the state, a test that attempted to extend the Mississippi lime production in the Coon Hollow pool to the southeast in Morgan County. This test encountered only slight shows of oil in the producing horizons of the near-by Coon Hollow and Boone Camp pools. Some surface work was carried on by private interests during the year in Scott and Morgan Counties and two wells were spudded in early in 1941 The revival of interest in the Kentucky portion of the plateau will probably result in increased activity in this part of Tennessee during 1941. Several sizable blocks of acreage, some by major oil companies, are held in Scott, Morgan, and Cumberland Counties. Middle Tennessee.—The northeastern Highland Rim continued to be the most active area in the state with 20 completions, although this figure is about one third of the number drilled in 1939. Four oil wells, none with initial productions of more than I00 bbl., were completed in Clay, Fentress, and Pickett Counties. The producing horizons discovered in Pickett and Fentress Counties were in the "Sunny-brookJ' pays of Trenton age. The Clay County producer was an old test drilled deeper in which oil was found at 671 ft. in the upper part of the Stones River group of limestones, a common pay in this area. All four wells were drilled in or close to old shallow production. Deeper testing into the Knox dolomite group in this area was not particularly encouraging, although one well in Fentress County encountered some saturation at 1860 to 1869 ft. in the upper

Jan 1, 1941

By JOHN R. SUMAN

TONIGHT I want to speak of the current problems and the postwar difficulties facing American industry. American industry has done an outstanding job in adjusting its operations to wartime necessity. The national income for 1942 was nearly $120,000,090,000 and of this outlay approximately $55,000,000,000 went for war material. The enormity of the expenditures for war material is indicated by the fact that the expenditures for war purposes alone were greater than the annual gross national income in the period 1931-34. This tremendous production job in turning out a record output of war products was accomplished by industry in spite of a large number of restraining and hampering influences, and I want to mention several of the more important problems.

Jan 1, 1943

By A. L. Mular

Two equations express the integral rate at which fines are produced from a homogeneous material: It has been demonstrated that the Gaudin-Meloy distribution for single fracture is equally applicable to multiple fracture and is related to the Gaudin-Schuhmann distribution at least when the distribution modulus a is close to unity. A, xoY was found to be independent of starting mass over the range studied when particle size was held constant. The equations are related to the input energy to the mill. In an earlier paper,' it was shown that when Mo g of uniformly sized homogeneous material is ground dry in a batch rod mill, the energy-size reduction equation is expressed at any time by the mass of unbroken starting material left at time t, ku is the size modulus of the portion Mo - Mt, and P is a constant that is generally equal to the distribution modulus a. If the power to the mill is constant, Et is proportional to time and Eq. 1 is rewritten where (Mo -Mt)/t is actually the integral rate at which fines are produced from a parent material, and A, is another constant. The size modulus, k,, is determined from the Gaudin-Schuhmann equation:2 where y is the cumulative fraction finer than any size x. Recently, Gaudin and Meloy derived a distribution equation for single fracture on the assumption that the random fracture of a homogeneous material produces daughter particles of similar shape. Their equation is given by where y is the cumulative fraction finer than size X, x, is the size of the unfractured parent, and r is designated the size ratio. Although Eq. 4 is derived for a single event, it should also approximately hold for a series of com-

Jan 1, 1962

By P. W. Bakarian, C. H. Mathewson

THE greater part of the literature on the plastic behavior of magnesium dates back to that active period of research in crystal mechanics immediately following the widespread preparation of isolated metallic crystals large enough for the application of conventional methods of mechanical testing. These investigations, performed on single crystals, revealed an analogy between zinc and magnesium with respect to their fundamental mode of deformation, in the operation of glide and twinning, respectively, on crystallographically similar planes. Mathewson and Phillips (1928)1 by geometrical analysis identified the {102} ? plane in magnesium as the twinning plane, Schiebold and Siebel (1931)2 confirmed this twinning plane, established the basal plane as the plane of slip, and a digonal axis I as the slip direction. They also reported twin formation in a secondary role on the {101} plane. Schmid (1931)3 summarized and discussed the earlier evidence and presented the results of his own experiments on the effect of temperature and small amounts of soluble elements. From X-ray studies on extended wire single crystals, he concluded that slip along the basal plane in the direction of the digonal axis I closest to the stress direction was the sole slip system operating at atmospheric temperature. This conclusion was based on experiments with crystals of many different orientations relative to the stress axis. Special attention was directed to the basal plane and the digonal axis I, as the plane and direction of greatest atomic density. Determinations of resolved shear stress at the onset of plastic yielding-i.e., the critical resolved shear stress-were also made; the average of these calculations showing 82.9 grams per sq. mm. This value varied only slightly up to 300°C., at which temperature it was found to decrease to 70.5 grams per sq. mm. The extension of his crystals at temperatures above 225°C. further disclosed the presence of new slip systems. After the original specimens of circular section had been

Jan 1, 1943

By C. H. Mathewson, P.W. Bakararian

The greatcr part of the literature on the plastic behavior of magnesium dates back to that active period of research in crystal mechanics immediately following the widespread preparation of isolated metallic crystals large enough for the application of conventional methods of mechanical testing. These investigations, performed on single crystals, revealed an analogy between zinc and magnesium with respect to their fundamental mode of deformation. in the operation of glide and twinning, respectively, on crystallographically similar planes. Mathewson and Phillips (1928)' by geometrical analysis identified the plane in magnesium as the twinning plane. Schiebold and Siebel (1931) confirmed this twinning planc, established the basal plane as the plane of slip, and a digonal axis I as the slip direction. They also rcported twin formation in a secondary role on the {IOI} plane. Schmid (1931)³ summarized and discussed the earlier evidence and presented the results of his own experiments on the effect of temperature and small amounts of soluble elements. From X-ray studies on extended wire single crystals, he concluded that slip along the basal plane in the direction of the digonal axis I closest to the stress direction was the sole slip system operating at atmospheric temperature. This conclusion was based on experiments with crystals of many different orientations relative to the stress axis. Special attention was directed to the basal plane and the digonal axis I, as the plane and direction of greatest atomic density. Determinations of resolved shear stress at the onset of plastic yielding-—i.e., the critical resolved shear stress—were also made; the average of these calculations showing 82.9 grams per sq. mm. This value varied only slightly up to 300°C. at which temperature it was found to decrease to 70.5 grams per sq. mm. The extension of his crystals at temperatures above 225°C. further disclosed the presence of new slip systems. After the origince specimens of circular section had been

Jan 1, 1943

By C. H. Mathewson, P. W. Bakararian

The greatcr part of the literature on the plastic behavior of magnesium dates back to that active period of research in crystal mechanics immediately following the widespread preparation of isolated metallic crystals large enough for the application of conventional methods of mechanical testing. These investigations, performed on single crystals, revealed an analogy between zinc and magnesium with respect to their fundamental mode of deformation. in the operation of glide and twinning, respectively, on crystallographically similar planes. Mathewson and Phillips (1928)' by geometrical analysis identified the plane in magnesium as the twinning plane. Schiebold and Siebel (1931) confirmed this twinning planc, established the basal plane as the plane of slip, and a digonal axis I as the slip direction. They also rcported twin formation in a secondary role on the {IOI} plane. Schmid (1931)³ summarized and discussed the earlier evidence and presented the results of his own experiments on the effect of temperature and small amounts of soluble elements. From X-ray studies on extended wire single crystals, he concluded that slip along the basal plane in the direction of the digonal axis I closest to the stress direction was the sole slip system operating at atmospheric temperature. This conclusion was based on experiments with crystals of many different orientations relative to the stress axis. Special attention was directed to the basal plane and the digonal axis I, as the plane and direction of greatest atomic density. Determinations of resolved shear stress at the onset of plastic yielding-—i.e., the critical resolved shear stress—were also made; the average of these calculations showing 82.9 grams per sq. mm. This value varied only slightly up to 300°C. at which temperature it was found to decrease to 70.5 grams per sq. mm. The extension of his crystals at temperatures above 225°C. further disclosed the presence of new slip systems. After the origince specimens of circular section had been

Jan 1, 1943

Jan 1, 1886

By E. von Maltitz

In his highly interesting paper, Piping and Segregation in Steel Ingots,' Prof. Howe emphasizes the effect of successive phases of internal pressure in the ingot in the evolution of gas, and the consequent formation of blow-holes. From his statements in other places, it may be inferred that he does not here intend to ignore the other variable factor, temperature, but rather to discuss this one more particularly. At all events, it is my purpose not to engage in controversy with Prof. Howe, but, rather to contribute, towards the complete elucidation of this important subject which we all desire, my own views and experience. If, in doing so, I specially emphasize other factors than pressure, I need not be understood as denying what I do not think it necessary to discuss fully. Nor, in presenting my own original conclusions, need I be understood as claiming to be the first who ever reached or announced them. Many things are asserted or suggested upon inconclusive evidence; and to confirm such tentative propositions may be as valuable a service as to overthrow them. In the following passage, Prof. Howe adduces analogies, based upon the behavior of charcoal and of water, respectively, which seem to me questionable : "In general, the solvent power falls as the pressure falls ; and in general it rises as the temperature falls. Thus, to heat a solid, for instance charcoal, may expel part of its dissolved gas ; and a tumbler of water drawn cold from the faucet gradually evolves gas, as it stands and warms up on the sideboard." (p. 72.) Charcoal is a solid body, which has the property not only of absorbing gases in large quantities, but also of expelling the thus absorbed gases upon heating. A comparison between charcoal and iron as to the absorption of gases is scientifically not possible; the gas-content of charcoal is partly due to the

Jan 1, 1908

By S. F. Emmons

There is, in the southern part of the State of Illinois, a series of deposits of fluorspar and galena in which the former mineral occurs on a scale of magnitude unequalled, so far as I know, in any other part of the world. In June, 1891, 1 had an opportunity of visiting the region of their principal development, near Rosiclare, Hardin county, Ill., and examined such of the mines in the vicinity as were accessible at that time. A very large proportion of the mining shafts that had been sunk in this region were unfortunately abandoned for the time being, and full of water. Moreover, detailed maps of the region are unattainable, no surveys having been made there, apparently, since the original land-surveys' of the early part of the century. In spite of these disadvantages I was enabled, in the few days at my disposal, to ascertain with sufficient accuracy certain facts not hitherto published with regard to these deposits, which seem worthy the attention of the members of the Institute. Before proceeding to a description of the deposits in question, I will give a brief abstract of the little historical and geological information hearing directly or indirectly upon them, which I have been able to find in existing publications. Historical. That the mineral was known to the Indians, is proved by the discovery, in some of the pre-historic mounds of the region,* of fluorspar, shaped into ornaments. The earliest scientific mention of its occurrence is found in the first volume of the American Journal of Science (1818+), which describes specimens obtained in the vicinity of Shawneetown by Mr. Joseph Baldwin. Similar notices appear in the same journal in 1820 and 1821, but without mention of the exact locality. They remark on the fetid odor which characterizes the mineral and its association with galena. Schoolcraft, as early as 1819, note: the occurrence of fluate of

Jan 1, 1893

By M. J. Pool, J. R. Guadagno

THE relative partial molar heats of solution in liquid tin have been determined for phosphorous, arsenic, and antimony at 750°K. This work was carried out as part of an over-all program to determine the heats of formation of the III-V semiconducting compounds. A differential twin-type liquid tin solution calorimeter was used in the investigation. All three elements are endothermic upon solution in tin. The relative partial molar heats of solution go through a minimum value at arsenic. No concentration dependence of the heat of solution was found in the dilute (0 to 2 at. pct solute) solution range investigated. The measured heat effects and the calculated relative partial molar heats of solution at infinite dilution are listed in Table I along with the relative heat contents of the solutes calculated from the data of kelley.1 All of the values are referred to 750°K even though the calorimeter temperature fluctuated by *1°K during the course of the experiments. In this range of temperature change no variations were found which were outside the experimental error. This would be expected since the partial molar heat of solution is in general a very insensitive function of temperature. The limits of error given in Table I represent the standard deviation from the mean. The reported error estimates only apply to the estimated precision of the data and not the accuracy. Systematic errors could be present which would affect the absolute values given. This is especially true in the case of phosphorous and arsenic where vaporization could occur. If this were true, the experimental values reported here would be too high and the true partial molar heat of solution would be less than that given in Table I. Moreover, the heat-content data could be in error and this would also affect the calculated values. The relative partial molar heat of solution of phosphorous at infinite dilution in liquid tin is given in Table I. This value is based on eight drops at

Jan 1, 1965

By Pedro G. Salom

I HAVE had an opportonity, within the last few months, of making a large number of physical and chemical tests of steel for boiler and ship-plate, which has been, and is now being, used principally for the United States Government cruisers, now building in Mr. John Roach's yard, at Chester, Pa. Through the courtesy of the Messrs. Houston, of the Chester Rolling Mills, I have the honor to lay before the members of the Institate the results of these tests. These results have developed some points in regard to the nature of steel, which are more or less new, and which, I hope, will prove interesting. The original specifications, as regards the manner of testing, were so inipracticable (when their severity mas taken into consideration), that the keel of the first vessel, which will be launched next month, would, had they been carried out, probably not have been laid until next year. At my suggestion, in order to simplify and expedite the immense amount of testing that had to be done, the Naval Advisory Board was induced, after considerable discussion, to alter the specifications, so as to test each heat, instead of each lot of twenty plates, but reserved the right of making the quenching-test on a piece from each ingot, after it had been rolled. This relieved us from the anxiety of having a lot of plates rejected, after they had beell rolled and sheared, by reason of the presence of one or two plates which might have been injured in heating or rolling, or which might not have been able to stand the tests; while it insured the Government in obtaining a uniform quality of steel, and prevented the temptation to introduce a half-dozen or more had plates in a lot, and run the risk of their being selected as the testplates. I give below a portion of the original specifications, as prescribed

Jan 1, 1884

By R. E. Reed-Hill

The shear continuity conditions under which one mechanical twin may cross another are considered. Twin intersections usually involve various types of slip deformation in addition to twinning. Because the shear of the crossing twin may be partly transmitted through the crossed twin by slip mechanisms, continuity of the twinning shear vectors is not required at a twin intersection. It is concluded that analyses based on twin intersections should not he used as an independent method for deducing twinning elements in newly observed twinning modes. WHEN one mechanical twin passes through another, a twin intersection is said to occur. In the simplest form of intersection, Fig. 1, the crossing of one twin by another is accomplished with the aid of a second-order twin induced, in the twin that is crossed, by the crossing twin. The subject of twin intersections is significant to the field of deformation studies because it has been postulated by cahn1 that twin intersections should occur only under the following continuity conditions: 1) the traces of the primary and second-order twin must be parallel to each other in the plane of the crossed twin; 2) the direction 771 and magnitude, S, of the twinning shear must be identical in the crossing and second-order twins; also, the sense of shear must be the same. If these postulates are valid they constitute a valuable tool for determining twinning elements of newly observed twinning modes in metals. In his classic paper in 1953 on the plastic deformation of a uranium, Cahn1 used these continuity conditions to deduce twinning elements for several uranium modes. However, in the same year, pratt2 showed that both of Cahn's continuity equations were violated for (1012) twin intersections in zinc. Later, Kiho and Maruyama3, 4 showed that Cahn's second postulate was violated in {301) and (101) twinning in tin and (101) twinning in bismuth. In spite of this documentation that Cahn's second postulate is often violated, several recent papers5'6 have been published which have attempted to use the condition of continuity of twinning shear vectors for the evaluation of twinning elements. The primary purpose of this paper is to call attention to the possible ambiguity inherent in applications of Cahn's postulate, and to present additional information concerning the nature of twin intersections.

Jan 1, 1964