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By Keith Kern, Joseph P. Matoney, Kenneth E. Harrison

INTRODUCTION "When there is an economic need for cleaning fine coal to low ash, the technical difficulties will be solved. The utilization of fines below 28 mesh will determine the degree to which beneficiation will be carried. Whenever these "fines" will be processed into smokeless fuels or used as new materials for the chemical industry or for hydrogenation, a higher degree of cleaning will be economically justified”.(l) This quote from the 1943 edition of Coal Preparation correctly anticipates the use of fines as "smokeless" fuel or as a future component of boiler fuel and a1 so as a raw material for the chemical industry or possible new uses such as for internal combustion engines. Fines utilization depends upon an economic need and possibly neglects to say an environmental need or a government funded development program as the prime mover for development. In any event, this conference is faced with the "need" to beneficiate fine coal and undoubtedly among the processes that will be discussed are the unit processes of future coal preparation facilities. HISTORY OF DEVELOPMENT It is interesting to look at where we have been, where we are now and where we possibly will be in the future. In order to put some limitations on this presentation, we will for the most part confine our remarks to this century and particularly developments since World War II. We also will limit our remarks to the preparation of bituminous coals in the United States, and for the most part, to wet processes. In the 1943 edition of Coal Preparation, clues to the processes being used to beneficiate coal are contained in the Chapter Titles. An extensive treatment of "Hand Picking" was contained in Chapter 8. Chapter 7 contained a description of methods for "Preparation at the Face". Chapter 18 dealt with "Slurries, Sludges, Slimes and Water Treatment" and defined this size of coal as being the size at which "Jigs and Chance Cones are usually dispensed with and other methods such as the hydrator, tables, and froth flotation are employed. Generally the limit is 1.7mm to 3.4mm. In the days before World War I1 the then modern bituminous coal preparation plant contained jigs or Chance Cones for the coarse material +6.35mm, concentrating tables, launders or some classifier type of coal washer for the fines (6.35 x 0.15mm), and froth flotation as the only method of cleaning minus 0.15mm coal which was used very sparingly.

Jan 1, 1988

By Robert L. Sundeen, Richard V. Wenberg

Overshot loaders are loading machines which fill a front-mounted bucket by crowding and bucket lifting, passing the loaded bucket over the machine and throw¬ing the load into a haulage unit to the rear. The load is retained in the bucket as the load mass is accelerated in its path over the machine. At the point of discharge, the bucket is stopped suddenly and the load leaves the bucket, following the throw trajectory past the rear of the loader. Fig. 1 shows a typical overshot loader of this type. Overshot loaders were developed for loading in nar¬row drift headings and drawpoints, where it is impossible to place or pass a haulage unit alongside the loader. Haulage access is to the rear of all overshot loaders. The first overshot loader was developed in the early 1930s. The early machines were rail-mounted, air¬powered, and had small loading capacities. To this day, the same basic design configuration exists, and all suc¬cessful overshot loaders still use compressed air. Bucket sizes range from 0.14 to 0.59 m3 (5 to 21 cu ft). The most commonly used machines are rail-mounted, al¬though crawler versions are popular for special applica¬tions, particularly shaft sinking. Rubber-tired machines have found some application where a greater travel distance is required between the loading and discharge points. CONDITIONS INFLUENCING APPLICATION Roadway Type Rail-mounted loaders are used where soft bottom requires rail support or where the long haul is ac¬complished with rail. This situation usually occurs in civil tunnels or in mine drifts that will continue to utilize rail-bound main haulage after development work is completed. Crawler and rubber-tire mounted loaders are used where the roadway surface is rough and lateral travel beyond the range of rail-bound machines is required. Work Area Dimensions The largest rail-bound loaders can clean roadways as wide as 4 m (13 ft) from a single track. Wider headings require multiple trackage. Headroom require¬ments are dependent upon the path described by the bucket as it passes over the machine. The largest over¬shot loader requires approximately 3.4 m (11 ft) of headroom. It follows that the largest heading that can be driven by overshot loaders from a single set of rails is approximately 4 m (13 ft) wide and a minimum of 3.5 m (11.5 ft) high above the rail. The smallest rail-bound loaders can work efficiently in headings as small as 1.8 m (6 ft) wide by 1.8 m (6 ft) high above the rail.

Jan 1, 1982

By J. D. Miller

Fluid flow phenomena and therefore the flotation efficiency of air-sparged hydrocyclone (ASH) flotation are strongly dependent on operating and design variables such as air and slurry flow rates, underflow and overflow opening areas, percent solids of the feed, reagent levels, particle size and ASH length. Time-averaged multiphase flow characteristics, as determined by X-ray CT (described in a previous publication), are used to understand and explain the steady-state ASH flotation of quartz. A detailed parametric study of quartz flotation by a nominal 2in. diam. air-sparged hydrocyclone (ASH-2C) revealed the influence of these variables on the flotation response, which is discussed in terms of the multiphase flow characteristics. Thus, a phenomenological description of quartz flotation has been established to assist in the further development and utilization of the ASH technology.

Jan 1, 1996

By E. Peuraniemi, S. Strömberg, S. Jyrkönen, A. Jokilaakso

Several sulfidic raw materials have been flash oxidized in a laboratory furnace in oxidizing atmospheres at temperatures of 500-1100°C. Chemical analysis was used to determine the oxidation degree, and optical and scanning electron microscopy combined with energy dispersive analysis were used for characterization of the reacted particles. The studied materials included both Cu and Ni concentrates and mattes. In fixed conditions, the temperature dependence of sulphur removal rate was found to be equal for all the copper concentrates studied. Nickel concentrates and Cu- and Ni-mattes were, however, found to be less reactive. Most of the particles were found to spheroidize and to fragment to small droplets under intensively oxidizing conditions. The product particles were frequently found to be iron oxide cenospheres or dense spheres with a composition of mixed Cu-(Ni-)Fe oxides.

Jan 1, 1998

By G. Belardi, G. Marruzzo, P. Plescia

This paper presents the results of grinding tests performed on magnetite from Kiruna (Sweden) and on chromite from Skoumtza (Macedonia. Greece). Stresses were measured by XRD, which determined the variations in the characteristic structural spacings of the minerals both before and after, grinding in a HSM/250 Herzog laboratory ring mill. Anal Isis of the magnetite and c hromite crystallinstallin was performed hi measuring the broadening of the strongest diffraction peak (311). .Also, structural analysis on chromite was carried out using the Mikheev model. Ultrafine-grinding tests on the magnetite and chomite demonstrated that this type of treatment can induce profound variations m the surface-stress state. These included plastic variations of the cell followed by "chemical" stress with oxidation front the stricture to form hydroxide or carbonate, films. This can have a great influence on the mineral reactivity to flotation reagents

Jan 1, 1996

By C. R. Zegarra

Extraction of manganese, gold, and silver from a low-grade manganiferous-silver ore was investigated by thiourea leaching followed by standard cyanidation. The levels of reagent concentrations in this investigation were 0.0 -1.0 M thiourea and 0.0 -1.0 M sulfuric acid. Temperature and agitation speed were maintained at Z5 °c and 300 rpm, respectively. The dissolution of gold, and silver was shown to be dependent mainly on sulfuric acid and thiourea concentrations. In general, 50.0 % Ag, 98.0 % Au, and 75 % Mn were recovered from a Mn-Ag ore by thiourea leaching. Overall silver extraction of 98.0 % was obtained by cyanidation after thiourea leaching. Thiourea leaching of sodium bisulfite leach residues was also studied, and the total extraction of gold and silver were 97 % and 40 %, respectively. Finally, a two-stage thiourea leach was also investigated.

Jan 1, 1988

By B. J. Scheiner, D. A. Stanly, P. M. Brown

The Bureau of Mines has developed an equation that describes the dewatering of clay slurries with poly- ethylene oxide. This dewatering equation is: A[ ] = KC + b where n, k, and h are empirical constants and C is the concentration of polymer solution used for dewatering. The minimum amount of polymer required for dewatering, A, is determined by titration of the clay slurry with a polymer solution. In this report, the dewatering equation is applied to data obtained for a polyacrylamide dewatering sequence. Fundamental similarities between the dewatering properties of clays and the viscosity of polymer solutions were observed. These similarities were explained by correlating an equation describing polymer configuration in solution with the dewatering equation. This correlation showed that the amount of polymer required for dewatering and polymer solution viscosity are both the consequences of the frictional interaction of entangled polymer coils.

Jan 1, 1991

By R. A. Wharton, Z. Yang, R. W. Smith

The electrokinetic and flotation behavior of the green alga Chlorella vulgaris was studied in the absence and presence of Pb(II), Al(III) and flotation collectors. It was found that the presence of Al(III) is necessary for good flotation of the organism, whether or not Pb(II) is present, when dodecylammonium chloride or sodium dodecylsulfate is used as collector. Best flotation using dodecylamine is at about pH 8, and best flotation when using sodium dodecylsulfate is at about pH 4. It appears because of the small size of the organisms that the Al(III) is necessary for flocculation to enhance bubble-cell contact and C. vulgaris removal from water. When N-dodecyl-2-aminopropionic acid is used as collector, good flotation occurs at about pH 4 without the addition of Al(III).

Jan 1, 1992

By Steve Kral

"Gold rush" is usually associated the western United States - California, Nevada, and Colorado. The southeast section of the nation is known more for its rice, textiles, tobacco, indigo, and cotton. This area, though, is where it all began with gold in this country. The United States' first gold rush, in fact, is said to have started with the discovery of a 7.7-kg (17-1b) nugget in the Piedmont section of the Carolinas in 1799, some 50 years before the rush to California. The Carolina gold rush continued intermittently through 1942 when the Federal Government shut down all gold operations. Strong gold prices throughout the early part of this decade and new extractive technologies spurred a small resurgence of gold operations in South Carolina. Mind you, this is not Nevada with its flood of geologists and mining companies. Nor are there any 7.7 kg (17 lb) nuggets being discovered. But Ridgeway Mining Co., a joint venture between Kennecott Corp. and Galactic Resources, has set about mining 51 Mt (56 million st) of low-grade ore containing an estimated 43.5 t (1.4 million oz) of recoverable gold. The open pit, carbon-in-leach operation is located near the town of Ridgeway in South Carolina, about 32 km (20 miles) north of Columbia. Carolina gold North and east of Ridgeway, Piedmont Mining Co. operates the historic Haile gold mine near Kershaw, SC. And Brewer Mining Co. operates the nearby Brewer deposit. Between 1829 and 1942, South Carolina gold mines produced 10 t (318,800 oz) of gold. It all began in 1799 when Conrad Reed, son of a German immigrant farmer, found the 7.7 kg (17 lb) nugget in Little Meadow Creek, NC. His father thought the rock was worthless and used it as a doorstop, so the story goes. It took nearly three years before Conrad's father decided his doorstop was indeed gold. Gold was later discovered in the Greenville district of South Carolina. And, in 1828, Benjamin Haile discovered gold in a stream that ran through his property in Lancaster County, SC. Haile's mine became South Carolina's most famous and most productive gold mine, producing more than 7.8 t (250,000 oz). At first, miners worked the stream beds of Haile's property. Later, lode deposits were discovered on slopes alongside the creeks. They would lease 4.6 ml (50 sq ft) lots and mine as deep as 7.6 m (25 ft). During the Civil War, the Confeder-

Jan 1, 1989

By Fathi Habashi

ION FLOTATION was introduced by F. Sebba in 1959. This technique permits the recovery of metal ions from solution through the introduction of an appropriate cationic or anionic surface-active agent into the solution. The surface-active agent, called a collector, is added in stoichiometric amounts in relation to the metal content of the solution. It reacts with the metal ion to form an insoluble soap, and is levitated to the surface by gentle bubbling of air to form a foam which collapses into an insoluble scum. The optimum conditions for the ion flotation with soaps of C10-16, fatty acids are shown in Table 15-1. Baarson and Ray (1965) found that once the metal was completely precipitated as the hydroxide, as little as one hundredth the stoichiometric amount of the collector was required to cause complete flotation of the [ ]

Jan 1, 1970

By D. Kelley

Due to pricing volatility and lack of availability of metals, the use of non-metallic materials of construction in metal extraction and refining processes has increased significantly in recent years Even though costs and availability of metals has improved recently, these factors are not expected to continue into the future as metal supplies once again fall short of global demand. One of the most common non-metallic materials of construction used in metal extraction and refining processes today is Fiberglass- Reinforced Plastic (FRP). These processes often require materials of construction that can resist acids and high concentrations of acid chloride salts. As shown in Table 1, FRP based on epoxy vinyl ester resin has the same chemical resistance to acid and better resistance to acid chloride salts than alloy C-276 and is superior to 2205 stainless steel in both cases.

Jan 1, 2010

By Y. Gonzalez

The reaction kinetics of sulfuric acid leaching of brass foundry flue dusts were studied. As received flue dusts were separated into two size fractions, a coarse fraction (median size 103.5 microns) and a fine fraction (median size 3.4 microns). Experiments were performed on both fractions al-though most results are reported for the coarse fraction. Leaching experiments were conducted in a stirred reactor to determine those factors which govern the kinetic response of the sys-tem. The kinetics were followed by determining the increase in the concentration of dissolved copper with time. The effects of temperature, concentration and oxygen partial pressure on the rate of copper dissolution were examined. In addition, reaction residues were examined by SEM, EDAX and X-ray analysis. An activation energy of 4.8 kcal/mole (20.08 kJ/mole) was calculated. The rate was found to be significantly dependent on oxygen partial pressure and acid concentration. The order of the reaction with respect to oxygen partial pressure and hydrogen ion concentration was approximately 1.50 and 0.37, respectively. Results indicate that the dissolution reaction is limited by diffusion and can be described by the following mathematical expression where ~ is fraction of copper extracted in time t

Jan 1, 1988

By L. S. Harris

The application of briquetting in various chemical, mineral, mining and metallurgical processes has been rapidly increasing in the past two decades. This is, in part, due to the development of new, more economical and higher performance briquetting equipment. Some of these developments, which have reduced the operating and maintenance costs,, include anti-friction bearings, hydraulically applied pressure enclosed and sealed gearing and bearings, tapered predensification feed screws, water cooling and materials of construction capable of operating at temperatures up to 18000F, and control systems capable of maintaining optimum briquette quality control. The briquets can be formed into almost any desired size and shape, To date, with present rotary briquetting presses in the 25 to 500 ton force range, briquets from 1/4" to 6" length are presently being used, some of which are illustrated in Figure No. 1. In force fed rotary briquet machines, these shapes are produced by feeding the material in between a pair of counter rotating rolls, as illustrated in Figure No. 2. The rolls have forming dies indented into their circumferential surface, as illustrated in Figure No. 3.

Jan 1, 1973

By J. M. Stewart

The incidence of heat stroke in the South African gold mining industry is today small (less than 1 in 10 6 shifts worked). Acclimatization and selection procedures have been developed and applied throughout the industry, underground working conditions have, and are being improved, and personnel are to-day made more aware of heat stress and its consequences than ever before. Although these actions have, over the years, brought about a steady reduction in the incidence of heat stroke (see Figure 1) the small incidence of heat stroke which persists indicates that heat stress is still a problem. This realization provides the stimulus for the work presented in this paper, which has as its primary objective the development of reliable heat stress limits for men working in South African gold mines. [ ] In keeping with recent trends3I4 the approach followed in this paper is based on the physical principles of heat transfer. Detailed studies of heat transfer from humans have been undertaken,5-l1 and certain of the results form an important aspect of this Paper -

Jan 1, 1980

By J. M. Scharer, Bruce E. Halbert, Pettit. Carol M., Lysane Bolduc

The ratio of neutralization potential (NP) to acid production (AP) ratio is often employed for predicting acidic discharges from waste rock dumps. The available NP was evaluated in laboratory studies of limestone dissolution in simulated acidic mine water. The available neutralization potential strongly depended on the particle size. Using limestone particles of 114" (6.4 mm) or greater, less than 20% of the total neutralization potential was exhausted at the onset of acid conditions. Apparently, the dissolution of limestone became mass transfer limited. Under mass transfer limitations, the rate of pyrite oxidation may exceed the rate of neutralization by buffering minerals. The implications concerning the controls on limestone dissolution were examined using a geochemical predictive model for sulphide mineral oxidation in waste rock. The results have shown that in case of heterogeneous waste rock piles the NP/AP ratio is a reliable indicator for short-tam predictions only. Kinetic data on the depletion rate of the neutralizing minerals and geochemical modelling suggest that waste rock environments with NP/AP ratios as high as 5.0 may turn acidic in the long term.

Jan 1, 2000

By H. Soto, J. Jara, F. Nava, J. B. Hiskey, B. J. Scheiner

Laboratory tests showed that ozone can destroy free cyanide and weakly complexed cyanide (copper and zinc cyanides). The iron cyanide complexes were resilient to ozonation but they were effectively eliminated by precipitation with Fe (II) ions under controlled pH conditions. Tests carried out with effluents from a number of gold mills confirmed the results obtained previously in the laboratory. The industrial samples contained cyanide in the form of free cyanide and also complex copper, zinc and iron cyanides. Solutions that contained up to 184 mg/L total cyanide, after the ozone treatment analyzed only 2-3 mg/L dissociable cyanide and 50-90 mg/L CN(t) (accounted for by iron complexes). After precipitation with ferrous ions total cyanide was reduced below 1.5 mg/L. For most solutions ozone consumption ranges from 3 to 6 g per g of cyanide destroyed. However, certain impurities (such as SCN and S203 ), present in some effluents, increase ozone consumption and make it more difficult to reduce copper concentration to satisfactory levels.

Jan 1, 1993

By A. E. Hall, K. R. Mutama

The wind tunnel has been used extensively for mine ventilation research and continues to be a valuable tool. The advent of the powerful personal computer has reduced the use of wind tunnels because several flow problems car be simulated and investigated quickly. This paper describes the recent design and construction of a wind tunnel which is now being used for mine ventilation aerodynamic research and teaching purposes. The wind tunnel has a square cross section measuring 900 by 900 mm and is 8485 mm long from the entrance to where it joins the fan. The tunnel was designed as an open circuit suction type and is attached to a 7.5 kW variable pitch axial flow fan capable of producing over 6 m3/s of airflow. The entire length of the wind tunnel can be used for flow investigations and all activities are visible since the sides are made of plexiglass. Results are presented from the test program to show that even without honeycombs and screens air flow symmetry is achieved.

Jan 1, 1993

By K. A. Natarajan, J. M. Modak, B. Saha

Nonliving waste biomass consisting of Aspergillus niger attached to wheat bran was used as a biosorbent for the removal of copper and zinc from aqueous solutions. Copper and zinc uptake by the biomass obeyed Langmuir isotherms. The binding capacity of the biomass for copper was found to be higher than that for zinc. The metal uptake, expressed in milligrams per grain of biomass, was found to be a function of: •the initial metal concentration (with the uptake decreasing with increasing initial concentration), •the biomass loading (with the uptake decreasing with increasing biomass loading) and •pH (with the uptake increasing with increasing pH in the range of L5 and 6.0). The metal uptake was significantly affected in the presence of a co-ion. The uptake of copper by the biomass decreased in the presence of zinc and vice versa. The decrease in metal uptake was dependent on the concentrations of metals in the two-component aqueous solutions. The effect of copper on zinc uptake was more pronounced than the effect of zinc on copper uptake.

Jan 1, 1997

By A. M. Marabini, V. Alesse, Belardi. G.

An alternative flowsheet was designed for the flotation treatment of a complex sulfide ore from the Sotiel Mine in Spain. The ore contains 0.71% Cu, 2.24% Pb and 5.63% Zn. Two specially developed synthetic collectors, methyl-mercapto-benzoxazole (MMBO) and 6n-propoxy-mercapto-benzo-thiazole (PMBT), were examined. MMBO exerts a specific action on copper and zinc minerals after treatment with copper sulfate, and PMBT exerts a specific action on Pb minerals. Flotation operating variables (pH, frother type, frother quantity and feed particle size) were examined by means of rougher flotation tests to determine the optimum conditions for the new collectors. Once the optimum conditions were determined, a series of open flotation circuits were run on feeds of various particle sizes (obtained by different types of grinding). The objective was to obtain high-grade Cu and Zn concentrates. The results of the open-circuit tests demonstrated that a Cu concentrate grading from 18% to 23% Cu and a Zn concentrate grading from 40% to 48% Zn can be produced.

Jan 1, 1996

By Monica Pavlik, Thomas Wildeman

Water from the Forest Queen mine adit near Silverton, Colorado drains into a natural wetland. Because the pH of the water averages 5 and the iron concentration averages 18 mg/L, it was thought that the wetland might naturally treat the water. Of most concern with respect to the aquatic environment is zinc whose concentration averages 0.60 mg/L. Starting in October 1997, the surface waters, ground waters in the peat substrate, and the sediments in the wetland were sampled and analyzed four times over the course of four months. The adit water primarily remains as surface water where Fe, minor amounts of Al, and no Zn are removed. After the adit water enters the peat, then it is found that the pH rises to 5.8-6.5 and sulfate is reduced. The removal of Zn and A1 is caused by these two changes. However, Fe in its reduced state is quite soluble and may be remobilized in the reduced environment of the peat.

Jan 1, 2000