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By Yues Bertube

Molybdenite and chalcopyrite are two often-associated minerals. In Quebec, the Gaspe Copper Company, a subsidiary of the Noranda group, currently operates a molybdenite flotation circuit to recover a one percent trace of this mineral in the chalcopyrite concentrate. The low levels of molybdeni 2 preclude the use of flotation to remove molybdenum directly from the ore while scavenging of chalcopyrite concentrate for molybdenite yields a concentrate of the latter of somewhat inadequate quality. Such a situation could possibly best be solved by hydrometallurgical means, if molybdenite could be leached selectively from the chalcopyrite concentrate. Work in the field of extractive metallurgy was initiated about 22 years ago in the laboratory of the department of mining and metallurgy at Laval University, Quebec. Following a literature search, two objectives were selected. The present talk will outline some of the results obtained to-date and it is hoped the ensuing discussion of the paper can raise questions of immediate assistance to us for the future. First, as an immediate objective of-practical use, the oxidation rates for molybdenite and chalcopyrite in alkaline media would be studied under conditions of possible industrial application. Secondly, the kinetics of mass transfer of gases in pressure reactor are to be studied. Solubility data for various gases in aqueous solutions have been gathered by a few investigators, to mention the work of Pray1, Wadsworth2, Pawlek3 and Gerlach. Scattering in experimental results and discrepancies between authors are ominously present. Kinetics of mass transfer have somewhat been more neglected. A systematic investigation by the school of Berlin has greatly helped in the design of impeller most suitable for gas dispersion, without much reference however to the solid dispersing ability of the various designs. Variables affecting rates of gas transfer to the solution have not been studied. Studies on the aqueous oxidation of sulfide minerals are much more numerous. While molybdenite has been relatively less studied, work has been carried in two areas namely in alkaline oxidation of MoS2 , work performed by Dresher2 and Wadsworth, and in the hypochlorite leach of molybdenite by Bhappu4 and co-workers, These two methods showed appreciable rates of leaching for molybdenite. In general, comparisons between rates of oxidation of this sulfide with that for chalcopyrite have not been made.

Jan 1, 1972

By Robert S. Foote

The U.S. Energy Research and Development Administration (ERDA) is currently conducting a national program to survey for uranium the conterminous United States and Alaska by 1980 using airborne and surface techniques. This paper discusses the techniques used and some of the results of airborne surveys conducted to date by Geodata International, Inc. Airborne gamma radiation and the earth's magnetic field data are measured to provide data leading to regions potentially more favorable for the exploration and discovery of uranium ore. High-sensitivity radiometric and magnetic field data have been gathered from an aircraft with an average surface altitude of 400 feet (Figure 1). Under most conditions, data are usable up to an aircraft surface elevation of about 1250 feet where limitations will be discussed. Results of data analysis under GJO-1632, GJ0-1644, GJO-1654 and GJO-1663 will be discussed.

Jan 1, 1976

By R. M. Hernandez

The Bureau of Land Management (BLM) constructed four passive biochemical reactor systems (BCRs) to treat mining influenced water (MIW) in the Bunker Hill Superfund area near Coeur D?Alene, Idaho between 2002 and 2003. Initially, the BCRs operated very effectively. However, in the past couple of years, the zinc removal effectiveness of the four BLM BCRs has declined [1]. The central objective of this study was to characterize the microbial communities and substrate present within the BLM BCRs and to use these factors to propose strategies to promote sustained sulfate reduction levels. Microbial communities were characterized by quantifying total bacteria and sulfate reducing species. Substrate was characterized by quantifying the percent organic, acid soluble organic, acid insoluble organic, and bioavailable material within the BCR. The results suggest the depletion of bioavailable organic substrates is the primary cause of the decline in zinc removal and not the microbial community structure. The ability to assess the amount of bioavailable organic substrate and microbial community is important to the understanding of the sulfate reducing capacity of the BLM BCRs and developing strategies to facilitate performance enhancement of the current BLM BCRs. The characterization of organic substrate and microbial community structure are also important to improving design of future passive treatment systems for mining influenced waters.

Jan 1, 2010

By Robert A. Irvine

Traditionally, cost effective gains in the capacity of material handling systems were a result of increases in equipment size. In general, the use of maximum capacity components in a system optimizes the production "costs per ton." The trend-"Bigger is Better" will continue in material handling equipment. Since it is rare for plant operators to lament an over abundance of screening capacity, one can safely predict that vibrating screens will follow this trend. Large Vibrating Screens - The Challenge Large vibrating screens represent a unique challenge for Manufacturers, Plant Designers, and Plant Operators. The inherent mode of operation for vibrating screens is self-destructive. More often than Manufacturers admit, Designers plan for, or Operators staff for, a vibrating screen succeeds and self-destructs. This is a problem. It can magnify with larger vibrating screens.

Jan 1, 1983

By B. N. Thompson

The main industrial minerals produced are non-metallic - clay, dolomite, limestone, pumice, salt, serpentine, and silica sand. The other minerals, some with minor production, include diatomite, feldspar, magnesite, sulphur, asbestos, and perlite. Energy and metallic minerals and aggregate are excluded from this account. These industrial minerals occur in a wide range of rock types and geological ages. For example clays are known from the weathering products of Cretaceous rhyolite and leaching of Eocene coal measures; from Quaternary weathering of contemporary loess and shallow marine sediments, and of greywacke of Triassic-Jurassic age; and from the hydrothermal alteration of Late Cenozoic acidic volcanic rocks.

Jan 1, 1982

By S. Odell

The Bureau of Land Management (BLM) has constructed two biochemical reactor systems (BCRs) to treat mining influenced water from the Forest Queen Mine near Silverton, CO. The bioreactors coupled with a natural wetland provide treatment to the Forest Queen Mine drainage. The central objective of this paper is to review the performance of the bioreactors and wetland treatment system. The bioreactors have been in operation for nine years and along with the natural wetland are still removing a high percentage of the influent metals.

Jan 1, 2010

By E. Ashworth

A thermistor probe has been developed to measure in situ temperature profiles underground. A full description of the probe is given. Data collected from the probe has been used to compare the actual profiles with those predicted from a finite element analysis using laboratory measured thermal properties of the different rock types. This comparison indicates the applicability of laboratory measured parameters in modeling the real conditions. Factors such as applied pressure, moisture content and anisotropy on laboratory measurements is discussed.

Jan 1, 1983

By N. J. Themelis

Autogenous grinding, broadly defined as the self-comminution of ore in a cylindrical tumbling mill without using auxiliary grinding media, was first applied in the early thirties in the so-called Hadsel mills (Figure 1) mainly used in gold mines on the U.S. West Coast. A number of these mills were built in sizes of 20 to 24 ft. in diameter and five-six feet in length but were later abandoned because of operating and maintenance problems. Further development of autogenous grinding led to the Hardinge wet grinding mill (Figure 2), the Aerofall dry grinding mill and others. A tabulation of all known autogenous and semi-autogenous installations around the world was sent recently to the authors by Hr. G. J. Kushner of the Koppers Mineral Processing Division. In the size range of 24 to 32-ft. in diameter, it lists a total of thirty mills used in the processing of copper ores. An additional 120 units are listed in the same size range for the processing of iron ores and other minerals. The largest mills in existence are 36-ft. dia X 15-ft. long mills in Minnesota, powered by 12,000 hp. motors and used in taconite beneficiation. It is indicative of the phenomenal growth of this technology that none of the above one hundred and fifty mills was in operation prior to 1964.

Jan 1, 1978

By Dr. Jagdish C. Agarwal

Kennecott Copper Corporation has developed a new hydrometallurgical process for extracting nickel, copper, cobalt and molybdenum from maganese nodules. This process (KCC Cuprion Process) utilizes a reduction leach operating at atmospheric pressure in the temperature range of 45 C to 50 C and has been successfully demonstrated in a continuous pilot plant processing 800 lbs of nodule ore per day. The chemistry, basic flow sheet and operating characteristics are presented and discussed.

Jan 1, 1978

By Mark J. Logsdon, Barbara Basse

Mississippi Valley Type Pb-Zn deposits are widespread in the midcontinent U.S. and have been mined from the 1800's to present. Some tens of thousands of acres of mined land in the Tri-State District have been designated as Superfund sites as a result of surficial mine wastes and ground waters with elevated levels of metals. EPA considers the surficial mine wastes to be hazardous and a major source of acid mine drainage fAMD) that degrades water resources and threatens human health and the environment. To mitigate potential risks at one site near Galena, Kansas, a group of mining companies who had been identified by EPA as Potentially Responsible Parties IPRPs) proposed subgrade disposal of the mining wastes in shafts and subsidence features. However, this proposal was challenged by the Agency on grounds related to AMD and the potential for degradation of ground water quality. The PRP team developed a program of materials characterization, laboratory-scale leaching, and finally large-scale, pilot testing in the field. Static and dynamic leaching tests at both laboratory scale fusing artificial rainwater under both variably and fully saturated conditions) and field scale (using pH 4.5 ground water) showed that the surficial wastes do not produce acidic leachate and are not a long-term source of metals. Laboratory chemical and mineralogical tests show that the mine wastes contain substantial carbonate, but very limited iron sulfides, consistent with the leach test results. EPA "characterization" tests fEP Toxicity and TCLP) compare very poorly with tests simulating the expected leaching conditions. While these tests would classify the surficia1 wastes as "hazardous, they do not characterize the behavior of the high-volume, low-concentration, coarse-grained materials with respect to environments and disposal options of interest. To be meaningful, characterization of mining wastes must be performed in a manner that simulates the environmental conditions that are actually of interest with respect to a specific decision, such as subgrade disposal in the saturated zone.

Jan 1, 1991

By James L. Evers

The development of hydraulic mining in the United States has had an uneven record of progress. The shifting of coal extraction from one government agency to another has not provided an environment for a focused national research program. This paper presents an update on hydraulic mining research in the United States. A comparison is made between the development of the technology in this country and the state of the art in other parts of the world.

Jan 1, 1983

By Albert Hofstra, Joel Leventhal

The gray, dark gray and black colors of the sediments and the presence of pyrite in the Carlin, Jerritt Canyon, Horse Canyon, Betze, and Gold Acres sediment-hosted disseminated gold (SHDG) deposits indicate that these rocks are not oxidized with respect to carbon and iron sulfide. Both ore and non-ore host rocks generally are dark colored. Analyses for noncarbonate carbon (usually called organic carbon) in samples from SHDG deposits and related unmineralized rocks indicate that these rocks contain from a few tenths to a few percent carbon. We use the term noncarbonate carbon because, strictly speaking, organic carbon denotes carbon that is bound to hydrogen. However, the carbon present in SHDG deposits and related rocks has very little hydrogen chemically bound to it. Rocks with less than 2% organic carbon are usually gray in color. The dark colors in our samples are due to the relatively high temperatures that these rocks have experienced relative to organic matter maturation. We confirm the results of Nelson et al. (1982) that previous reports (for example, Radtke and Scheiner, 1970) were incorrect in reporting significant amounts of humic acids, extractable hydrocarbons (bitumen) or "carbonaceous" material. We believe these reports had problems with contamination or misdirected emphasis. Our samples consisted of unweathered rocks, collected mainly from mine cuts (benches, trenches, cores) and put into glass containers or wrapped in aluminum foil to avoid contamination. Only a few samples were collected from natural outcrops. We were careful to avoid samples in proximity to blast holes that were packed with ammonium nitrate and diesel fuel ("ANFO"). Contamination by ANFO may explain some of the previous reports of hydrocarbons, pyrobitumens, humic acids and anomalous nitrogen. When we were collecting samples, it was apparent that in addition to lithologic and color differences, the surface appearance of the rocks was distinguishable: "preg robbing" material that had a sooty surface; "graphitic" rock with a shiny surface; and more ordinary rocks that had a flat gray or black appearance. [Preg robbing is a term for ores that adsorb gold from the milling circuit; the graphitic material had not been x-rayed to actually identify graphite.] We hoped that laboratory study of these samples would show some fundamental differences that we could relate to ore genesis. Even though these sample types appeared different in the field, we could not distinguish any differences in thermal maturity (see below). Normal petroleum/organic geochemical laboratory procedures (solvent extraction, Rock-eval, pyrolysis-gas chromatography) failed to yield much information because the carbon was over-mature relative to oil and gas generation. Rock-eval results show less than 20 (± 20) mg of pyrolizable hydrocarbons per gram organic carbon (and an indeterminate Tmax) indicating that the organic matter in these deposits is burned-out relative to petroleum generation [with an H/C (atomic) ratio of less than 0.41. Because of the non-definitive results from standard organic geochemical methods, x-ray diffraction (XRD) and Raman spectroscopy were used to characterize the carbon. Prior to XRD, samples were treated with HCl and HF acids (1) to remove quartz that has a peak near 26° [20] at the position of the 002 peak of graphite and (2) to concentrate the carbon to a level detectable by XRD. The residue was put on a colodion mount and analyzed by XRD. The XRD analyses yielded a broad peak at 26° [20]. The shape of this peak indicates that the carbon is more thermally mature than anthracite rank coal but less mature than crystallized graphite. Based on XRD results from the literature (Landis, 1971) that are calibrated to metamorphic facies, results from our samples correspond to pumpellyite-actinolite to lowermost greenschist facies conditions, probably

Jan 1, 1990

By Xun Luo, Yi Duan

A field trial of by distributed optical fiber sensing (DOFS) technique was conducted at a longwall coal mine in Australia. This investigation was designed to assess the applicability of DOFS for microseismic monitoring in mining. The experiments used commercially available optic fiber cables, geophones and associated data acquisition instruments – a fiber interrogator and a seismic recorder. The fiber cable was deployed in a 300m deep hole and in trenches of approximately 3.5 km long on the ground surface around and across the longwall panel being mined. The results obtained from the experiments have shown that DOFS is able to acquire microseismic data with quality that is comparable to geophones. It has been proven that DOFS can achieve higher spatial resolution for seismicity sensing and higher accuracy for locating events than a geophone network. These characteristics are particularly useful for using DOFS to monitor ground vibrations associated with ground caving processes and rock fracturing events induced by mining and civil engineering. It was also found that far more additional seismic events were recorded by the fibers than by the geophones. Automated data discrimination and processing methods must be developed in order to utilize DOFS for real-time applications.

Apr 26, 2022

By T. Kawashima

The expanding volume of maritime coal transportation is intensifying the problems concerning large vessel service port construction, transshipment and environmental control. The major problem is the transshipment of coal. Customary methods for bulk transfer must be improved and/or new systems developed. Slurry unloading has a key role in the new systems. The present report reviews progress in slurry transportation research which has been done in Japan since the 1960s when large scale experiments for domestic transportation were done. Experiments on the effects of vibration on the slurry cargo and on reslurrying are discussed.

Jan 1, 1982

By J. Iannicelli

Spray drying is the principal drying method used in the production of over six million tons annually of beneficiated kaolin in Georgia. Thirty-three dryers in the Georgia Kaolin belt comprise the highest concentration of large tonnage spray dryers in the world. The steady growth of spray drying in the U.S. kaolin industry is paced by advances in design and development of large spray dryers which have led to large scale new applications in mining and related industries.

Jan 1, 1982

By E. S. Forbus

A process for producing reductive bleach in-situ in kaolin slurries has been developed. The bleach is formed by mixing an iron sponge powder (-325M) with slurry treated with SO2. The process has been successfully demonstrated in production, and applied to several grades. The color, brightness, and viscosity of the bleached product is equivalent to or better than that of product bleached with commercial sodium hydrosulfite . The tested products can be bleached at a cost, which is 38-54% of those associated with the use of commercial bleach.

Jan 1, 1993

By B. S. Hulvey

Thin support liners are becoming more accepted and being developed with improved properties because the mining industry as a whole has been offering underground safe test trial sites. This is because of the huge potential for such products. Recent developments tend to indicate that the technology is “coming of age” and these are discussed in this paper.

Jan 1, 2003

By Edmund C. Bitzer

The unit costs of dry crushing, within the efficient reduction ranges of equipment now available, are considerably less than those for the reduction of the same material in the same size range by wet mills using grinding media. This is a commonly recognized fact which cannot be disputed; still we find considerable imbalance in costs between the crushing and grinding sections of many operating mills. In other words, there are many instances where more reduction could be accomplished in the lower cost area of dry crushing. In addition, equipment is now available which enlarges this area and makes it possible to consider much finer crushing than has been heretofore economically feasible. There has been a tendency for the past two decades to utilize wet rod-¬milling in the reduction step. This actually amounts to a fourth stage of crushing in a size range formerly served by roll crushers which have fallen from favor on account of high operating costs, Some investigations have indicated that there is not sufficient difference in the operating costs of rolls and rod-mills to give a clear cut advantage to either method, There has for some time been a need and an opportunity for a dry crushing process to improve costs in the range now served by these two systems.

Jan 1, 1965

By R. E. Pennington

My subject this morning is coal liquefaction technology. Actually, coal liquefaction involves a number of technologies in a very complex system. The first slide shows the major components of such a system with arrows to indicate appropriate flows. The components are the facilities for coal feed preparation and handling; the coal hydrogenation or base liquefaction section; facilities for product separation and recovery, and in addition, facilities for the production of hydrogen from coal-based sources. A very rough break- out of the investments involved in these areas is given at the bottom of the slide. Investment is spread about equally among the three areas of operations Another way of looking at it is that the investments in what might be called support facilities are of the same magnitude as the base investment in the hydrogen facilities. Therefore, it is appropriate in a discussion of coal liquefaction technology to treat it as a system composed of a number of technologies. The next slide lists the various functions in the feed preparation section along with an indication of technology status. Storage, crushing, grinding, drying of coal all have been in commercial practice for a number of years. The slurrying and pumping of coal at least in water slurries, is practiced commercially also. The heating of coal slurries in oil to high temperatures under pressure is not in commercial practice and development and testing is going on by a number of people in this area. Some rather complex phenomena occur when coal oil slurries are heated to high temperatures.

Jan 1, 1975

By G. W. McMahon

Following the Sago Mine accident, the U.S. Mine Safety and Health Administration (MSHA) asked the U.S. Army Engineer Research and Development Center to study several possible methane explosion scenarios in the Sago coal mine. The study used a 0.3-m (1-ft) resolution map of the mine to produce a 3-dimensional (3 D) model of a portion of the mine, including the sealed area where the explosion occurred. An advanced 3 D computational fluid dynamics (CFD) code was used to calculate the explosion pressures within the sealed area, on the mine seals and in nearby regions of the mine. Based on the best available information on methane concentrations and assumptions on homogeneity and on layering and mix composition, three separate initial conditions of methane-air concentrations and location were studied. This paper discusses the CFD modeling technique, the results of the calculations, the challenges of conducting this type of modeling and the advantages and limitations of CFD modeling of accident investigations of mine explosions.

Jul 1, 2010