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By B. Z. Weiss, N. R. Comins, F. Blum

The effect of microstructure on the deformation and fracture properties of 3CR12 steel was investigated at different strain rates in the temperature range -196 to 200°C. The yield stress of the as-received steel, showing a banded dual-phase microstructure, was much lower than that of the flake-like dual-phase microstructure produced by heat treatment. The heat treatment also resulted in an increase in the volume fraction of martensite. The fracture toughness of the as-received 3CR12, on the other hand, was significantly higher than that of the heat-treated material. These changes in both yield stress and fracture toughness were attributed to the effect of microstructural parameters on the constraints imposed on the deformation and subsequent failure of the ferritic phase in the as received and heat-treated steels. The exceptionally low resistance to crack extension in a plane parallel to the roiling plane of the as-received material was ascribed to the delamination process, which is typical for controlled-rolled steels. The yield stress and fracture toughness were found to depend on temperature and strain rate. The appearances of the fracture surfaces were found to be consistent with the mechanical properties.

Jan 1, 1992

By U. C. Galimidi, J. M. Stewart, A. J. Van Rensburg

The effect of body movement on convective heat transfer from a man performing a block-stepping task was investigated experimentally by direct measurements of convective heat transfer. A series of experiments was conducted in which a nude man was required to stand at rest or to block step at 12 and 24 steps per minute. Wind speed, which was kept constant during each experiment, spanned the range 0,5 to 3,5 m/so Air temperature was kept constant at 43 °C in all the experiments. The results showed conclusively that the convective heat-transfer coefficient depends on the stepping rate. The effect of body motion can be regarded as being equivalent to an increase in the velocity of the free stream. The equivalent increase in air speed was found to be 0,36 and 0,77 m/s for 12 and 24 steps per minute respectively. Data from various sources, including the present study, indicate that wind speed should be increased by about 0,30,0,55, and 0,80 m/s to account for low, moderate, and vigorous body movements respectively. These findings are of direct relevance to the practical assessment of heat stress.

Jan 1, 1979

O.F.S. Branch Minutes of the Committee Meeting held in the Committee Room at the St. Helena Club at 4.45 p.m. on Wednesday, 3rd September, 1975. Book reviews JONES, M. J. (ed.). Minerals and the environment. London, Institution of Mining and Metallurgy, 1975. Mining Companies of the world.. 1974/75. London, Mining Journal Books Ltd (15 Wilson Street), 1975. £12. 303 pp. NIM reports Report no. 483 Summary of the mineralogical investigation of pegmatites. (11th April, 1969; re-issued October 1975). Report no. 1697 A petrographic and mineralogical investigation of silica samples from the farm Elandskraal 470JQ, Rustenburg district. (24th Jan., 1975; reissued October 1975). Report no. 1761 The determination, by atomicabsorption spectrophotometry, of minor elements in anode sludges and residues. Report no. 1762 The determination, by instrumental neutron-activation analysis, of some elements in the NI M ROC standard reference materials. Report no. 1770 The spectrophotometric determination of vanadium in chromiumbearing materials. Foundry conference An international foundry confcrence, spomored and organized by South African Institute of Foundrymen, will be held in Johannesburg from 23rd to 27th February, 1976. The themes for each day are follows: Coordination chemistry A symposium on coordination chemistry in extractive metallurgy is to be held in Kelvin House, Johannesburg, on 18th and 19th March, 1976. Practical jet cutting The third international symposium on jet-cutting technology to be organized by BHRA Fluid Engineering will be held in Chicago from 11th to 13th May, 1976, in conjunction with the lIT Rese:uch Institute of Chicago. Hydraulic transport The fourth international conference on the hydraulic transport of solids in pipes (Hydrotransport 4) is being organized by BHRA Fluid Engineering.

Jan 12, 1975

By H. M. Krieg, M. J. Ungerer, C. G. C. E. van Sittert, D. J. van der Westhuizen

"The transition metals tantalum (Ta) and niobium (Nb) are of significant importance, for example in the nuclear energy sector where they are used as cladding materials, as well as in capacitors and specialized materials. For these applications a high-purity metal is needed. The separation of Ta and Nb is always a challenge since they are found together in nature and have similar chemical and physical properties, resulting in costly and laborious separation processes. A technology that has been used successfully for the separation of these metals entails solvent extraction (SX)1. While separation was achieved in a previous SX study using a sulphuric acid (H2SO4) medium with the extractants diiso-octyl phosphinic acid (PA) and di-(2-ethylhexyl) phosphoric acid (D2EHPA), due to the absence of speciation data for Ta and Nb it is not clear how the separation occurred.One method that might be suitable for determining the speciation of a reaction is molecular modelling. Calculations based on the densityfunctional theory (DFT) are now used not only for light elements and small molecules, but also metal complexes, heavy metals, and especially metal separation in SX2. In this study the aqueous phase used during SX was investigated by studying periodic systems of Ta, as a metal and in salt form, when it is in contact with H2O and H2SO4. The results were used to predict the reaction mechanism occurring during SX. Results showed that (i) in a 1:1 acid-water ratio, the deprotonation of H2SO4 was endothermic, (ii) in a 1:5 ratio deprotonation was exothermic forming HSO4 -, and (iii) in a 1:10 ratio double deprotonation occurred to form SO42- exothermically."

Jan 1, 2017

By S. Curry

The Objana Cement Plant is located in central Nigeria, approximately 200km south of capital city Abuja (figure 1). It is the second largest cement plant in Africa, and the fifth largest in the world [1]. The selected mining location is unique as it has all the major raw materials (except gypsum) in close proximity. This includes limestone, clay, marl, laterite soil, and laterite iron. [ ] The plant has a capacity of 5 million metric tones per year (~15,000 tones per day). A 135 megawatt gas-fired power plant, with 90 km of natural gas pipeline, was constructed to power the plant. The total project cost is approximately 1.2 billion US dollars. The lifeline of the plant is two overland conveys totalling 7.7km in length. The first 800m conveyor is relatively mundane. The second conveyor however, is unlike any other troughed belt conveyor in the world. It 6.9km length transports 2,400 T/H and operates at 5.0 m/s. Its ?snake? profile consists of 11 vertical cuvees, and four horizontal curves. The last of which is 2,000m in radius, has a length of 2.2km, and is located at the high tension head end of the conveyor. Although these specifications are noteworthy, the unique feature of this system is that it is entirely elevated from head to tail using a triangulated truss gantry structure (figure 2).

Jan 1, 2008

The AK6 kimberlite is situated 25 km south of the Debswana Orapa Mine in Botswana and was discovered by De Beers geologists in 1969 during the follow-up of geophysical targets in the Orapa area. The kimberlite was not extensively pursued at the time as the initial bulk sampling indicated it to be of limited size and low grade, factors largely contributed to by the basalt breccia capping. Completion of high resolution integrated geophysical techniques and drill bulk sampling to depth recovered 97 tons of kimberlite during 2003 and 2004, which led to the increased size and grade estimates. Bulk sampling by Large Diameter Drilling (LDD, 23 inch diameter) commenced in 2005; 13 holes were drilled to a cumulative depth of 3,699 m and 689 carats of diamonds were recovered. In July 2006 the De Beers Mineral Resource Classification Committee classified these Phase I LOO results at a High Inferred level with an average grade of 24 carats per hundred tonnes (cpht) at a bottom cut-off of +1 mm, and a modeled average diamond value of 150 dollars per carat. A second phase of LDO drilling was initiated in 2006, and bulk sampling by trenching commenced in 2007 in order to deliver a resource estimate at indicated level. An Indicated Resource of 11.1 million carats at an average grade of 22 cpht was declared for the deposit mining lease application lodged in 2007.

Jan 1, 2010

1. New books Extractionmetallurgy'81. London, Institution of Mining and Metallurgy, 1981. 441 pp. $40. Structures and properties of engineering alloys, by W. F. Smith. London, McGraw-Hill, 1981. 512 pp. R89,65. Rock and mineral analysis, by W. M. Johnson and J. A. Maxwell (editors). 2nd ed. New York, Wiley, 1981. 424 pp. $40. Mining methods and equipment, by Mining Information Services. London, McGraw-Hill, 1981. 218 pp. International directory of acronyms in library, information and computer sciences, by P. M. Vaillancourt. New York, Bowker Publishing Co., 1980.516 pp. 2. New journals Trends in analytical chemistry (TRAC), Amsterdam, Elsevier, 12 issues per year. Subs. for Volume I (16 issues) D.H 95.50. Engineering management international, Amsterdam, Elsevier, 4 issues per year. V.S. $32.50, D.H. 70.00. 3. Mineral policy sector publications Mineral Bulletin MR 188. Vanadium: an imported mineral commodity. $3.60. Mineral Bulletin MR 190. Canadian mines: 1980 perspective. $3.00. Canadian mineral survey 1980, by the staff of Mineral Policy and Energy Sectors. $1.00. 4. NIM reports Report 2090 Observations made during the dig-out of a 48 MV A ferrochromium furnace. Report 2110 The investigation of a fracture on one side of a skip bridle in a mine shaft. Report 2111 Pilot-plant tests for the recovery of chromite and the noble metals from the UG-2 Reef at Maandagshoek. Report 2112 The behaviour of UG-2 chromite concentrates during smeUing. Report 2113 M uUivariable control of a milling circuit at East Driefontein Gold Mine. Report 2115 Estimation of material variation in powdered materials Report 2116 Optimum operation of a direct-reading spectrometer with excitation by a 5 kW inductively coupled plasma torch. Report 2121 Five robust indicators of central value. Report 2124 The direct determination, by differential pulse anodicstripping voUammetry at the thin mercury-film electrode,of cadmium, lead, and copper. Report 2127 The preparation of a reference material of South African zirconium concentrate from Richards Bay. Report 2128 The determination, by differential pulse anodic-stripping voltammetry at the thin mercury-film electrode, of cadmium and thallium in six NIMROC reference materials Report 2130 The organizing of conferences. Research grant The Board of Directors of International Precious Metals Institute in conjunction with Gemini Industries, Inc., a California-based refiner of precious metals, recently announced a Gemini Research Grant of $3000 will be awarded annually to a graduate student who is pursuing studies in metallurgy, chemical processes as it pertains to precious metals, or materials sciences, and who is performing or planning research studies in the precious metals. Accidents and diseases The Third International Colloquium for the Prevention of Occupational Accidents and Diseases in the Iron and Metal Industry is to be held on 15th and 16th June, 1982, in Palma de Mallorca, Spain.

Jan 1, 1981

By J. van der Merwe, C. Phetolo, V. Matjeke

The mechanical properties and microstructure of AlSi10Mg alloy samples that were printed by selective laser melting (SLM) were studied to determine the effect of processing parameters and building orientation. After printing, the alloy was stress relieved at 250°C for 2 hours. The microstructures were analysed by optical microscopy and scanning electron microscopy (SEM) to determine the alloy phases and distribution. Phase transformation characteristics of the material were evaluated using differential scanning calorimetry (DSC). Mechanical properties were determined by subjecting the XY- and Z-built samples to tensile and nano-indentation testing. The samples from the tensile tests were then used to perform fractographic analysis by SEM. The microstructural properties in each orientation revealed a non-homogeneous microstructure which was characterized by a semi-elliptical tract and fine silicon precipitates, which were found to be softer along the fusion zone. The DSC thermograms revealed that the material underwent two phase transformations during the first heating cycle. The mechanical properties revealed a higher UTS, higher yield strength, and a lower percentage elongation in the Z orientation than in the XY orientation. Fractographic analysis showed that crack initiation in both orientations started from the surface in a brittle manner due to surface flows, and then propagated via microvoid coalescence.

Jul 1, 2021

Scrap printed circuit boards were selectively smelted at 1 200°C to produce a metallic alloy having three phases. These phases were identified as a lead-rich phase, a low tin content alpha bronze phase, and a high tin delta phase. Electrochemical leaching studies on this alloy were done in 1 mol/dm3 sulfuric acid or in 2 mol/dm3 hydrochloric acid (adjusted to an ionic strength of 3 mol/dm3). The lead rich phase was more strongly passivated in sulfate media, and in this medium the high tin content delta bronze was more resistant to corrosion than the lower tin alpha bronze phase. In chloride medium the lead phase and both bronze phases corroded readily, but with current densities about an order of magnitude lower than in sulfate medium (static conditions) for the bronze phases. The high tin delta bronze phase was found to form a passivating layer in sulfate media. A similar layer was not seen in chloride medium. The leaching studies in sulfate medium also showed the existence of an alpha bronze phase of lower tin content in the centres of the alpha phase grains. This phase was quite resistant to leaching in sulfate medium.

Jan 1, 2009

By P. Horrell, K. Rhodes, G. Harrison, J. Dean, D. Sammons, M. Stander

Anglo Platinum have perceived a need to increase the rate of reef development both for new mechanised stoping technology and on conventional new developing mines. The Research and Development Division of Anglo Platinum therefore initiated an experimental reef raise project with a tunnel boring machine (TBM) at Bafokeng Rasimone Platinum Mine (BRPM). The scope of the trial was for the boring of a reef raise 340 metres in length on the Merensky Reef. The boring phase of the trial took place over six months and the average rate of penetration of the TBM was 0,47 metres/hour. TBM utilisation was 22%. The TBM used in the trial was a Jarva MK6 manufactured in 1972 and its design with its backup system was not considered to be an ideal machine for reef development. However it was the intention of the trial to prove the concept of developing with a TBM on reef. In this respect the trial was unequivocally a success. There were many problems and long delays did occur during the boring phase. Nevertheless there is every confidence that a new TBM can be designed specifically for this type of work that will achieve high rates of advance up to (say) 400metres/month and with a more flexible steering system in order to negotiate reef changes. It can therefore be expected that TBMs will be used in the future for reef development on South African platinum mines.

Sep 1, 2001

By NONEn NA

1. Book reviews . Rudiments of mining practice, oy C.E. Gregory.Clausthal-Zellerfeld (West Germany), Trans Tech Publications.OS$24.Reviewer: A.N. BrownProfessor Gregory has had a wide experience of hardrockmetalliferous mining throughout the world, beinga well-known academic who has taught at many universitiesin the Western World. His basic training was obtainedin his native land of Australia. In this publication he identified the need for a basic, simple book on miningpractice to provide new students of mining with a backgroundto their studies. He also designed the book to providea background to persons operating on the fringesof the industry such as students of economics and journalists.The text extends to only some 120 pages, and containsa sufficient number of monochrome sketches, diagrams,and photographs. It is written in a straight-forward, easyto-read style. The book contains an index and elementarytable of conversion from imperial to SI (metric) units,and there is also a glossary of mining terms that mostreaders would find useful.The author has succeeded in keeping the contentssimple, as indicated by the title. However, after each chapter, there are references to further recommendedreading. The book could be useful in the South African context, although the coverage of coal and opencast mining operations is slender.

Jan 1, 1987

By J. O. Roux

The Impala Platinum Limited Base Metals Refinery in Springs, South Africa, refines convertor matte containing base metals and PGM?s (platinum group metals) using a hydrometallurgical process. In addition to a PGM-rich concentrate that is further refined, the Base Metals Refinery produces nickel (in powder or briquette form), copper cathodes and cobalt powder. Five leaching stages are utilized to remove the base metals and impurities from the PGM concentrate. The project described in this paper involves a radical redesign of the second stage leach autoclave with the aim of reducing maintenance costs and downtime, increasing throughput and ensuring a safer working environment. The second stage leach process at the Base Metals Refinery, produces a PGM-rich residue through the extraction of copper and any remaining base metals from the first stage leach solid residue material. Leaching is performed in an autoclave operating at a pressure of 600 kPaG and a temperature of 140°C to 150°C. Concentrated H2SO4 is added to the feed to produce a solution with a free acid content between 10 and 30 g/L and a pH of less than 2. Oxygen is passed into the 1st and 2nd compartments of the autoclave. As a result of the aggressive, highly oxidizing conditions within the autoclave, the original design utilized a heavy wall carbon steel shell with lead lining and two layers of acid bricks. The bricks acted as a wear resistant material and ensured a low surface temperature at the skin of the lead lining, whereas the lead lining acted as a corrosion barrier to protect the steel shell. These brick lined autoclaves were heavy, maintenance intensive and prone to catastrophic failure. A radical autoclave redesign was needed to reduce the high costs of manufacturing, installation and operation. Finite element modelling was used to optimize the design and various high alloy materials were investigated for the application. Based on extensive test work, the carbon steel shell was replaced with duplex SAF 2205 stainless steel in the new design. The use of this highly corrosion resistant material, eliminates the need for the lead and brick linings and reduces the wall thickness requirements substantially, resulting in an increase in the available volume for the same external shell dimensions. The vessel is welded in circular sections to form an elongated, impermeable, cylindrical body, with several agitator nozzles and compartments. The first new duplex stainless steel unit has been in continuous operation for more than 24 months and its performance has exceeded the highest expectations. The design was so successful that a patent has been registered. The major benefits of the new stainless steel design include increased throughput, improved performance, less downtime and a safer working environment. Lead has been eliminated and replaced with a more environmentally safe material, and the total lifespan of the vessel has been extended. In addition, the autoclave project has made significant developments in advancing the field of welding and optimizing the integrity of welding quality standards in South Africa.

Jan 1, 2009

By S. C. Essack

"Tenova Pyromet has designed a slag flow control valve that throttles the flow of slag in order to control the tapping rate. In addition, the valve has proved to be a reliable tool for closing the furnace during normal operation as well as emergency conditions. The valve makes use of a water-cooled copper element that is hydraulically operated and attached directly to the slag tap-hole. The equipment is compact, simple to maintain, and cost-effective to purchase and install. It can be retrofitted to most existing slag tapholes with minimal modifications.During the development phase, finite element method (FEM) and computational fluid dynamics (CFD) software was extensively used to model predicted operating conditions and to optimize the design. By using CFD, it was possible to understand the flow patterns inside the copper and to optimize these to improve overall performance.The slag valve was installed and commissioned in 2011/2012 on a 12 MW furnace as part of a new mineral wool plant in the USA. It has performed well since its installation despite operating under conditions in excess of the original design criteria. During the first 6 months of operation it quickly became the preferred method of closing the furnace, although the design intent was for occasional use during emergency shutdown conditions only. Since replacing the mudgun as the main method of closing the tap-hole, a few minor changes have been made to the installation in order to cope with the increased heat load and much higher frequency of use."

Jan 1, 2014

By F. S. Hoseinian, D. Deglon, L. leal Filho, M. Safari, T. C. Souza Pinto

This paper investigates the effect of chemical and physical operational parameters on the reverse flotation of Timbopeba itabirite iron ore in a pilot-scale pneumatic flotation cell. Operational parameters include collector and depressant dosages, feed rate, superficial gas velocity and solids concentration. Results show that increasing collector dosage results in an increase in quartz recovery, particularly for the coarser quartz where recovery increases by nearly 30%. Increasing depressant dosage results in a decrease in both quartz recovery and hematite loss, for the coarser hematite particles. Increasing the feed rate has no effect on quartz recovery or hematite loss, suggesting that the pneumatic flotation cell is not residence time constrained. Increasing the superficial gas velocity results in an increase in quartz recovery to an optimum at a Jg of around 0.6 cm/s after which it decreases significantly, particularly for the coarser particles where recovery decreases by as much as 50%. Decreasing the solids concentration does not affect quartz recovery but results in significant decreases in hematite loss. Here, fine and coarse hematite loss decreases from around 25% to 12% and 10% to 2% respectively. Superficial gas velocity and solids concentration are operating parameters which have the largest effect on the flotation performance of the pneumatic flotation cell. Results suggest that this flotation cell should be operated at relatively low superficial gas velocities and solids concentrations. However, these are pilot-scale findings and would need to be tested at an industrial-scale where different operating conditions may be optimal. Keywords: Operational parameters, reverse froth flotation; entrainment; iron ore

Jan 1, 2020

By J. Rowe

The attrition of activated carbon, and the loss of gold associated with it, is of significant economic importance to the operation of a CIP/CIL circuit The focus of this study was on activated carbon recovered from an elution circuit which was deemed too fine for reuse. Results of cyclosizer and laser particle size analysis identified that most of the carbon was contained in the larger size fraction suggesting formation by abrasion. Digestion and AAS analysis of the individual size fractions identified a disproportionate concentration of gold in the finer size fractions which was identified by scanning electron microscopy to be due to the presence of fine metallic gold formed as a result of the acid washing process. Attempts to strip the remaining gold using sodium hydroxide or sodium sulphide based solutions proved unsuccessful due to poor elution efficiencies and re adsorption of gold. Upgrading of the material by froth flotation was also investigated using various conventional flotation reagents which had some success in concentrating the free metallic gold, however, grade and/or recoveries were considered less than desirable. Greater success was ultimately found in the transfer of gold from the fine carbon material onto coarser virgin activated carbon using a caustic cyanide solution. Sodium sulphide, sodium chloride and ammonium chloride based solutions were also trialled but proved less successful owing to their inability to mobilise metallic gold or gold cyanide species. Repetition of the transfer process proved capable of stripping 97% of the gold contained on the carbon fines for abed volume ratio of 6:1.

Jan 1, 2009

By A. P. Cook

Gas samples were taken from a wide range of target areas on dumps arising from coal mining activities. Some of the dumps had largely burned out, some were still burning, some were in the process of rehabilitation, and on others rehabilitation was essentially complete. It was found that rehabilitation was very effective in reducing emissions to tolerable levels. Even incomplete rehabilitation reduced the CO2 emissions to less than about 1 kg/m2/a, whereas some unrehabilitated areas showed emissions of over 100 kg/m2/a. Some areas where there was active combustion taking place were also sampled, and they showed as much as 7 000 kg/m2/a, but the areas concerned were very small and their total contribution accordingly low. Analyses were also made for SOx, NOx, NH3, and CH4, but these were generally (and unexpectedly) at very low levels. The mines sampled represented 53 per cent of all surface coal mining activity. Accordingly the estimated total emissions were scaled up, to arrive at estimates of 1950 000 ± 350 000 t/a C02, 2040 ± 580 t/a SOx, 306 ± 85t/a NOx, and 31 ± 9 t/a NH3 for all surface mines. Methane was detected only from burning coal, and due to the difficulty in sampling, no reliable estimate could be made of these methane emissions.

Jan 1, 2012

By Y. Jiao, V. S. Thompson, D. W. Reed, Y. Fujita, J. E. Aston

Rare earth elements (REE) are vital components in modern electronics and green technology products. Supply is tight and global demand is expected to increase, leading to high risk for the economic and national security of countries largely dependent upon foreign supplies. Recycling of REE from consumer and industrial waste materials is a possible way to help meet demand. We have shown previously that biohydrometallurgy can play an economically and environmentally sustainable role in REE recycling, particularly if agriculture or food wastes are used to produce organic acid bioleaching agents. A challenge for organic acid-based bioleaching is the incomplete conversion of the carbon substrate to an optimal organic acid biolixiviant with high REE extraction capability from a variety of REE-containing feedstocks (e.g., mining wastes, magnets from end of life products, spent batteries, etc.). To help meet this challenge a metabolic model was developed for Gluconobacter oxydans to identify options for improving sugar conversion to organic acids. Model predictions were consistent with laboratory data for the microbial consumption of glucose and production of gluconic acid, and suggested that providing growth conditions with relatively high C:N molar ratios could result in lower pH biolixiviant production and thus improve bioleaching. Keywords: Gluconobacter oxydans, bioleaching, metabolic modelling, rare earth elements summaries 2019: U.S. Geological Survey, 200 p., https://doi.org/10.3133/70202434.

Jan 1, 2020

By deur B. C. Alberts

Graduate engineers are a scarce and valuable resource. The situation is aggravated by the 2 years of national service, resulting in the elapse of 6 years after matriculation before a young engineer can start his practical training. After having started work, it is therefore imperative that employees in this category should be trained as effectively as possible in (1) the specialized activities of the employer and (2)the employer's specific work practices. Knowledge and experience of these two areas are vitally important for productive work performance by young engineers. Consequently, it is Iscor's primary objective to enable young graduates, in this case engineers, to obtain the knowledge and experience necessary for productive work in the shortest possible time. Iscor's training programme is therefore structured to enable the young engineer to - perform high-level engineering work and to make sound engineering decisions as soon as possible, - gain a thorough background of the employer's production processes, plant, and equipment, - become thoroughly acquainted with Iscor's work practices, policies, and procedures, - acquire a sound knowledge of Iscor's management techniques and philosophies, - do productive work during the training period, - obtain the following additional qualifications as soon as possible: . Government certificate of competency (legally required before appointment to certain positions) . registration as a professional engineer. Iscor's training programmes are no longer based on predetermined periods of time for each department and work practice. Neither is it a tour or visitors' programme. This contribution explains how Iscor, and more specifically its Mining Department, attempts to reach its objectives in this regard.

Jan 1, 1987

By H. M. Dus, D. J. Smith

Resistivity tests indicated that, at temperatures lower than 1450°C, reducing agents alone, as well as burdens consisting of high-carbon ferrochromium and reducing agents, exhibit wide differences in resistivity. These differences are less pronounced at elevated temperatures. The resistivity of a reducing agent and the volume fraction it occupies are important factors controlling the resistivity of burdens of high-carbon ferrochromium. A mathematical model is formulated to describe the dependence of the resistivity of mixtures of conducting and insulating particles on the particle sizes and the volume fraction occupied by the conducting phase. The resistivity of burdens of high-carbon ferrochromium is high if the particle size of the reducing agent is larger than that of the other components of the burden. A number of reducing agents showed small variations in their reactivity towards chromite ore in the solid state. However, with chromite ore in the liquid state, reduction proceeded more rapidly with reducing agents occupying larger volume fractions. During the smelting of manganese ore, high initial rates of reduction were observed for reducing agents that had a high reactivity towards carbon dioxide and a high content of volatile matter, and that occupied a large volume fraction. High liq'uid-state reactivities were observed for reducing agents occupying a large volume fraction and having a Iow degree of graphitization.

Jan 1, 1980

By J. Portal

One of the key products produced by the mineral sands industry is the titanium dioxide slag, a process that requires grinding of a coarse product down to a valuable saleable product. Traditional methods have included the vertical roller mill in tandem with dynamic air classifiers and, alternatively, two-stage grinding and crushing through an AG mill in closed circuit with a dynamic classifier and secondary gyradisc crushers. The products produced, commonly known as chloride and sulphate slag, are differentiated by the particle size distribution of the final product. The more valuable chloride slag must, by specification, be a product sized in the range between 850 and 100 microns?the more fines generated in the grinding process, the less higher valuable final chloride slag is produced. This paper will explore a technology that is new to both the mineral sands and to other mineral processing industries. Inter particle communition, or IPC as it is known, has been applied in the cement industry to improve the performance of clinker grinding mills. The principle is to create a process of material on material comminution under high pressure that fractures the material along the grain boundaries rather than breaking it smaller than a gap setting in the crusher. The process is now looked at for the TiO2slag producers because of the potential benefits of energy savings and with a minimal generation of minus 100-micron fines. Discussions will revolve around the design and functionality of the Rhodax® both from a process and maintenance perspective, a typical test regime and results on slag grinding. The development of the flowsheet necessary for the process will be examined, the ancillary equipment required and finally the scale-up from the test to an industrial plant will be investigated. Full-scale results of an operating plant will also be given showing the benefits that can be realized. A promising new flowsheet with fines reintroduction to the Rhodax® crusher will be presented.

Jan 1, 2007