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By B. J. Dalton

The Bureau of Mines Helium Research Center has as a long-range objective the development of an equation of state for helium that will allow all of the thermodynamic properties to be calculated within the accuracy with which they are known. If this objective is to be realized, a method of calculation must be known. This report gives the principles of the method we use in such problems. A computer program was developed for predicting these properties, including those at the critical point, that is perfectly general and applicable to any equation of state. To demonstrate the efficacy of our method, this computer program was used to evaluate thermodynamic properties of a Redlich-Kwong fluid in the two-phase region. Expressions for calculating various thermodynamic functions specific for this particular equation of state are derived. Numerical values are tabulated and graphs are presented for all functions calculated. It is shown that for a Redlich-Kwong fluid there are finite discontinuities in (1) the second temperature derivative of the Gibbs free energy or chemical potential at the critical point, (2) the second derivative of the vapor pressure curve with regard to the temperature on passing through the critical point, and (3) the measured heat capacity at constant volume on passing through the critical temperature when the calorimeter is filled to the critical density. It is also shown that the heat of vaporization is infinite for a Redlich-Kwong fluid at absolute zero.

Jan 1, 1969

By Michael D. Fenton

Detailed comprehensive assessment of the performance of Afghanistan's mineral industry during 1987 is virtually impossible, owing to the paucity of reliable published information. It was evident, however, that the level of civil disorder, now in its eighth year since the arrival of significant numbers of Soviet troops, was in actuality little removed from open civil war. Insurgents controlled substantial areas of the country and imperiled any industrial activity in many places. Assistance programs by the U.S.S.R. and other Eastern European nations were directed at developing the country's meager mineral industry, but the economy was generally viewed as chaotic. The inflation rate was somewhere between 20% and 30%; major food shortages contributed to the discontent of the population, and numerous villages were devastated by Soviet and Afghan Government campaigns to destroy the insurgents and cut their supply routes. Moreover, proposals by the Soviets and the Kabul Government aimed at reducing tensions with the rebels and scaling down the warfare seemingly were taken by the opposition as signs of weakening by the Soviet-backed Government, and rather than reducing aggressions, seemed to heighten insurrectionist activities. Efforts to entice the substantial number of Afghans who have fled to nearby areas of Pakistan and Iran to return to their country seemingly were failures, and indications near yearend that the Soviet Union might soon begin withdrawal of its occupation force of nearly 120,000 did little if any to reduce disorder.

Jan 1, 1989

By W. D. Dietzman

This Bureau of Mines report presents a continuation of statistics pertaining to distribution of petroleum reservoirs (or fields), wells, and production by depth and producing rate classification in the United States. These statistics show the change that has occurred since results of a similar study were published by the Bureau of Mines in 1967. Data are presented in tabular form by State for the 18 principal oil-producing States and by subdivision for the two larges t oil-producing States, Texas and Louisiana, Tabular summations and graphical illustrations are presented for the Nation. The data are classified by 4-barrel-of-oil-per-day rate increments up to 36 barrels and one increment of greater than 36 barrels of oil per day and by 2,000-foot depth increments up to 8,000 feet and one depth increment of greater than 8,000 feet. The overall average producing rates for States and the Nation have been published for many years; although such rates are useful, they are very general descriptions of producibility. A breakdown of production, wells, and reservoirs by various depths and rates and by State or by State subdivision provides a more detailed description of producibility.

Jan 1, 1976

By John Durkin

Field studies have been conducted in a large number of coal mines throughout the U.S. to determine the effectiveness of electromagnetic techniques in locating men trapped underground following a mine disaster. Data from these tests have been used to generate models of expected signal and noise distributions as found above mines throughout the coal fields. These distributions have aided in placing the expected performance of a through-the-earth electromagnetic communications technique into a probabilistic framework. Results indicate an expected 45% probability of detecting a miner's signal from a depth of 1,000 ft, a depth which exceeds 903 of the coal mines within the U.S. and a 90% probability at a depth of 500 ft, a depth which exceeds 50% of the mines.

By James E. Hill

In the course of exploratory drilling during World War II by the Bureau of Mines under the Strategic and Critical Minerals investigations Program, a problem arose as to the ultimate disposal of the drill core resulting from that program. The difficulties experienced in obtaining factual information to evaluate mineral deposits examined (during that program) influenced the Bureau in a decision to catalog and store the drill cores for future reference. Initially, the drill cores were stored at the nearest Bureau of Mines station that had space available for the purpose. Recently the Bureau stations at Minneapolis, Minn., and Denver, Colo., were designated as the locations of permanent drill-core storage facilities. Drill cores that are retained from Bureau of Mines mineral-exploration projects are stored at these two locations and are given preference in selecting cores for storage. Drill cores are accepted also for storage from other Government agencies, State agencies, private companies, or individuals on the basis of available facilities and consistent with the significance of the core in relation to Bureau of Mines objectives and national interest. Selection and acceptance of such drill core are determined by the Bureau of Mines. The drill cores stored at the two locations are available for inspection by any person having a legitimate interest in the mineral deposits represented by the cores. Approximately 1,850,000 feet of drill core can be stared in the facilities now available to the Bureau of Mines. Approximately 475,000 feet of drill care is stored or scheduled for storage at Minneapolis, Minn., and 240,000 feet of core stored or scheduled for storage at Denver, Colo. A list of drill core now in storage at the Bureau of Mines core-storage facilities at Denver and Minneapolis is included as appendix A.

Jan 1, 1957

By Manuel Gomez

A computerized moving average technique was developed to interpolate coal seam characteristics between sample points. The interpolative method coupled with multivariate regression analysis and simulation procedures was used to forecast coal properties not readily obtained from an analysis of drill core samples. Coal property forecasts were of two kinds: (1) specific mine property forecasts that are suitable for mine product control and yield a good approximation of the local variation along both the vertical and horizontal axes of the seam, and (2) regional estimates where much of the local seam variation is smoothed out, but the general trends are maintained. Forecasts of the volatile matter, ash, total sulfur, and the heating value for part of the Pittsburgh seam located in Ohio, Pennsylvania, and West Virginia were in good agreement with independent evaluation data. Spatial configuration for preparation characteristics, particularly, the effect of crushing on sulfur release, low-and high-temperature carbonization properties, the Hardgrove grindability index, the coal hardness index, gasification variables, and hydrogenation factors were constructed for the same area of the Pittsburgh seam. These forecasts may be developed from drill core data collected in the exploration phase of mining. The results, which may take the form of a series of maps, are useful to mining, chemical, and combustion engineers, to economists and mine managers, as well as to coal users for mine design, economic analyses, energy forecasts, utilization studies, mine product control, and environmental control and programming.

Jan 1, 1974

By Peter F. Steidl

As part of the Bureau of Mines methane control program, the Upper Free-port coalbed was studied in Fayette County, Pa., where this coalbed lies about 650 feet below the Pittsburgh coalbed and contains the largest remaining reserves of any coalbed in the county. Coal and overburden isopachs, structure and joint pattern maps, and a fence diagram were prepared using data from gas and oil exploration logs and coal outcrops. These maps will aid in deter-mining the need and/or feasibility of degasifying the Upper Freeport coalbed in the study area. Much of the coalbed in this area is under 600 to 1,400 feet of overburden. By correlation with data from the Pittsburgh coalbed, the gas content at depths of this order is estimated to be between 140 to 300 cf/ ton of coal, for a total of 190 to 400 billion cubic feet of methane in this coalbed in Fayette County.

Jan 1, 1977

By H. G. Wolfhard

The mode of propagation of explosions through narrow passages is important for understanding flameproofed equipment employed in mines. Narrow channels have been used in this investigation that connected between a small explosion chamber and a large chamber containing fuel-air mixture. The oxygen index of the mixture in the small chamber was determined which caused an explosion in the outer chamber. Preliminary measurements have already been given in Bureau of Mines Report of Investigations 5457 and suggested that) flames do not pass through narrow channels. The hot, burned gases from the explosion in the small chamber, however, are able to ignite the mixture in the large chamber by a process of hot-gas ignition. Systematic measurements are reported in the present paper that cover the influence of channel length and diameter and the properties of the gas mixtures in the large chamber on the transmission of explosions. The influence of such properties as quenching diameter and flame temperature is also discussed. This paper concludes the work on this problem and presents a theory that describes in detail parameters that influence transmission of explosions through narrow channels. INTRODUCTION Flameproofed equipment in mines is usually provided with flanges. A gap between the opposing flanges allows ventilation and release of pressure. The safe gap width has been determined for a number of flange lengths by Smith4/

Jan 1, 1959

By Frank E. Cash

"INTRODUCTION The producing iron-ore ranges in the Lake Superior district are the Marquette and Menominee in Michigan, the Gogebic in Michigan and Wisconsin, and the Cuyuna, Mesabi, and Vermilion in Minnesota. These ranges produce about 85 percent of the iron ore mined in the United States. The accident experience in connection with this production is better than that of the regions producing the remaining 15 percent. Production and shipments vary slightly from year to year owing to stockpiling underground ore during the winter, or nonshipping, season but closely approximate each other over a period of years. This information circular supplements, combines, and continues the data contained in Information Circulars 7321 3/ and 7410 4/, including statistics for 1946 and 1947.Whereas the title ""Accident Experience"" is used for uniformity and logical indexing throughout this report, ""injury"" will be used as a general term to apply to disabilities of all degrees.During the 8-year period 1940 to 1947, inclusive, 619,054,023 long tons of iron ore was shipped from the Lake Superior district. 5/ Michigan and Wisconsin shipped 117,828,939 tons, or 19.03 percent of the total, and employed approximately 9,260 men. Minnesota shipped 501,225,084 tons, or 80.97 percent of the total, and employed an approximate annual average of 12,260 men. The tons produced and shipped per man employed in Minnesota is much greater than in Michigan and Wisconsin, owing to the large open-cut production in Minnesota."

Jun 1, 1949

Capture airborne coal dust generated by a continuous mining machine to reduce workers? dust exposure and to improve face visibility. Approach Develop a low-profile dust collector system which can be mounted on the boom of a continuous miner. How It Works When coal is mined with a milling head continuous miner, a substantial amount of coal dust (respirable and non-respirable) escapes the dust suppression sprays at the cutter head. This can cause poor visibility around the cutting head and can expose the workers to high levels of respirable dust. A practical means of removing this dust is with a scrubber mounted directly on the mining machine. Under a Bureau of Mines contract, a low-profile, machine-mounted dust collector (MMDC) was developed to avoid adding extra height to the continuous

Jan 1, 1983

By Fred A. Williams

The cause of many deaths and extensive property damage in coal mines resulting from explosions and mine fires has been directly attributable to electric cable failures (including splice failures). The Federal Bureau of Mines data show that out of 355 underground coal mine fires investigated from July 1952 to January 1960, 103 (29 percent) were directly related to trailing cables. These cable failures resulted in the death of 7 men and injuries to 37 others. These potential hazards have become greater, obviously, through the widespread adoption of mechanized mining methods with electric-driven machinery powered through trailing cables according to Young,4 68.1 percent of the total bituminous and lignite production of the United States was mined underground in 1959. About 85 percent of this production was attained by mechanized loading methods. A large majority of the mines using the hand- loading methods also used equipment with trailing cables such as cutting machines, drills, and gathering locomotives. The problem of minimizing the loss of life, resources, and equipment from cable failures should be of concern to the management of all coal mines. It would be misleading to imply that no consideration has been given to the problem and its associated hazards. Through research cable manufacturers have endeavored to develop trailing cables that will withstand the severe service imposed by underground mining conditions. Technical research groups have undertaken studies for determining improved procedure and materials for field splices. Coal companies have instituted cable maintenance programs with a view toward the reduction of cable failures and consequent improvement in safety and efficiency of operations. Safety agencies are alert to unsatisfactory cable handling practices, poor workmanship in field splicing, mechanical

Jan 1, 1962

By J. R. Hoskins

A recent survey of 23 vein-type metal mining operations in several western states discloses that some of the more serious deficiencies in ventilation technology are associated with inordinately high levels of mine resistance. This problem has progressively increased over many years of operation (without adequate remedial action) as mines have become extended in depth. Where two shafts form the downcast and upcast airways of a relatively deep mine, the whole of the mine air volume must pass through each shaft in turn. Since at least one of these shafts contains hoisting equipment, structural members are necessary to support the rigid guides and shaft walls. These offer high aerodynamic resistance. In some deep mines, a single shaft of this nature may represent upwards of one-half of the total mine resistance. The second shaft, depending upon its design, may represent an additional one-third of the mine resistance. Therefore, the various working levels throughout the mine contribute only the small remaining amount of the total mine resistance.

Jan 1, 1972

Table 1.-Salient aluminum statistics (Thousand short tons and thousand dollars) [ ]

Jan 1, 1967

By S. P. Sandoval, A. E. Clark, S. W. Yopps, J. S. Gomer

The U.S. Bureau of Mines conducted Cu exchange tests for six common clays under simulated in situ leaching conditions. Regression equations were obtained from the data expressing the Cu exchange capacity as a function of Cu concentration, pH, and temperature. Using these equations, an analysis was made of the impact each clay could have on overall Cu recovery. The results suggest that Ca and Na montmorillonite clays could have a major impact on Cu recovery and that attapulgite and illite clays could have a smaller, but still significant, impact. Kaolinite and ripidolite clays pose little threat to loss of Cu from in situ leaching solutions.

Jan 1, 1992

By P. F. Sands, Michael Sokaski, M. R. Geer

The purpose of this investigation was to determine the advantage of using either a conventional sieve bend ahead of a vibrating screen or of attaching a sieve - bend screen surface onto a vibrating screen to serve as a scalping deck when dewatering or draining dense medium from fine coal . In dewatering , use of either the sieve bend or scalping deck increased the capacity of the vibrating screen tenfold and the recovery of coal finer than 0.5 mm threefold , with no sacrifice in the moisture content of the oversize product . In dense -medium drainage , either the sieve bend or the scalping deck reduced the amount of magnetite retained on the product of the vibrating screen , particularly when the medium was as dense as that characteristic of the underflows from dense - medium cyclones . The sieve bend was slightly superior to the scalping deck in dewatering , but the scalping deck was clearly superior in dense -medium drainage . Additional advantages of the scalping deck are lower cost and a substantial saving in headroom.

Jan 1, 1963

By Donald S. Colby

CARBON-BLACK shipments, which had declined in the latter art of 1953, remained low in 1954 until after settlement of the labor strike that occurred in the rubber industry in July and August. The production of new model automobiles in the last quarter of the year spurred the demand for rubber tires and consequently the demand for carbon black. Total shipments of 1,498 million pounds for the year were 4 percent below 1953.

Jan 1, 1958

By Ivan F. Avery

OUTPUT of carbon black in 1959 increased in all producing States except New Mexico. The national increase was 20 percent. Domestic sales and exports increased 22 percent and 16 percent, respectively, resulting in a 21 percent gain in sales. Sales to the rubber industry, which purchased 95 percent of the domestic output of carbon black, increased 23 percent. Sales to all other major consumers also increased. Stocks decreased 82 million pounds during the year. [ ]

Jan 1, 1960

Provide reasonably priced, reliable fire protection for large walking draglines. Approach Fire hazards on large draglines were analyzed, then appropriate automatic fire sensing and suppression systems developed and in-mine tested. How It Works Five fire hazard areas identified for special attention are: electrical control room, high voltage transformer enclosures, circuit breaker rooms, collector ring/roller path area, and the automatic lubrication rooms. Automatic fire sensing and suppression systems were separately designed for each area. The design of each system was tailored to the hazards and equipment protected. Spot thermal sensing and Halon 1301 suppression were specified for the electrical

Jan 1, 1981

By R. E. Head, Virgil Miller

"INTRODUCTIONRecent investigations at the Intermountain Experiment Station of the Bureau of Mines at Salt Lake City indicate that metallurgists have given little attention to the occurrence of jarosite minerals in the oxidized ores of lead and silver. These investigations have also emphasized the importance of knowing when these minerals occur in the oxidized ores, especially those containing lead, silver, and gold, as their presence is a material factor in selecting a suitable kind of treatment. Since the question of the occurrence of jarosites in oxidized ores has come to the attention of the Bureau of Mines, investigation has indicated that plumbojarosite and argentojarosite are quite common. These two minerals appear to be widely distributed and probably escaped recognition by persons who had attempted to treat certain oxidized lead ores in which the jarosite minerals represented a material portion of the metal content.Consideration of the physical characteristics of the jarosites also indicates that in many cases failure to treat some of the oxidized lead ores with success has been directly due to the fact that the greater portion of their lead and silver content was present as plumbojarosite and argentojarosite. The data and the description of these minerals given in the body of this paper indi¬cate that attempts to recover lead and silver from ores in which appreciable amounts of the metals occur as plumbojarosite and argentojaeosite would be unsuccessful if confined to gravity methods of concentration. There are un-doubtedly considerable tonnages of oxidized lead ores in the various mining regions of this and other countries, and it is quite probable that in some of these ores the metal content of lead and silver may be largely anglesite (lead sulphate) and cerussite (lead carbonate) but that they will also contain cerargyrite (silver chloride), argentojarosite, and plumbojarosite. The treatment of such ores therefore presents an important problem, since a product is discarded from ores from which the recoveries of lead and silver have been below 70 per cent which is probably too low-grade to warrant aftertreatment by any process now in use."

Apr 1, 1928

By J. R. Hauger, P. A. Romans, W. J. Niebuhr

With suitable instrumentation and techniques it is possible to determine the presence of tantalum in columbium to 20 ppm . This paper discusses the selection of X- ray spectrographic instrumentation and describes a technique for accomplishing the low level determination of tantalum . An ion- exchange method of separating tantalum from columbium is also described .

Jan 1, 1964