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By J. C. Griffiths

There are two kinds of problems concerning the elements of a population : the first is to estimate the proportion of some specific kind of element in the population, e.g. the amount of gold in a block of ground (equals population) or the proportion of mercury in a sample; the second is to estimate the length, breadth, volume, etc., of a specific kind of element, e.g. the grain size of quartz grains in a beach sand or the size, shape and arrangement of lenses of ore in an ore deposit. Given a specific objective, a bounded population, identified elements and the element characteristics of interest, it is then necessary to select a sample of the elements from the population and the problem of sampling requires a decision on how to select the sample. It is also necessary to establish, either by heuristic analysis or empirically, based on long experience, the model frequency distribution of the desired element characteristics: in general, constant-probability models are used as models, the binomial or Poisson for count data and the normal distribution for measurements (or their transformed equivalents). The objective of sampling then becomes to obtain an appropriate statistical estimate of the desired population parameter: for example, the estimators may be the mean (X) and variance (a2): these should be unbiased sufficient estimators of their corresponding parameters (u, a2, respectively). Statistical tests are performed in order to determine that the estimators are of the appropriate kind: all statistical tests are designed to test against bias of a specific kind, although they are stated as tests against randomness. Given a random sample of some population, the estimators are usually stable and adequate to solve the sampling problem. Random samples are simple to define but exceedingly difficult to achieve in practice: in selecting a sample, if every element in the population has an equal chance of occurring, then the sample is a random sample. Interaction between the arrangement of elements in a population, i.e. its structure, and the sample selection process frequently introduces bias—that is, some elements have more chance than others of appearing in the sample and, hence, the sample is not random. An algorithm for dealing pragmatically with this aspect of the sampling problem offers one way of achieving random samples and, therefore, adequate estimators. Examples of the use of this algorithm on various kinds of geological populations, in both field and laboratory, illustrate the requirements for solving sampling problems and the achievement of appropriate estimators.

Dec 1, 1971

By III, Peter J. Rogers, J. Gordon Ogden

A study is described which attempts to identify the chemical factors of common concern to environmental and exploration geochemistry as indicated by recent work in both disciplines in Nova Scotia. Cores taken in lake sediments define geochemical baselines for the modern and pre-industrialisation periods. The investigation of lake and stream drainage indicates the presence of numerous chemical and organic factors that can be attributed to man's activities, such as construction and energy consumption. Geochemical surveys of lake and stream sediments are used to locate potentially toxic, high risk areas in Nova Scotia. Rapid change occurs in most surface drainage systems with the possibility of numerous chemical reactions taking place. It is found that spatial and temporal variations in the chemistry of modern and recent sediments are of interest to exploration and environmental surveys.

Jan 4, 1992

By L. T. Matthews, C. E. Loo, R. P. Williams

The behaviour of iron ores and fluxes in the high temperature zone of a sintering bed is extremely complex. Following a review of current knowledge, an attempt is made to define relevant terminology to describe the processes that occur in this part of the bed. A deformation temperature is used to quantify the initial formation of melt, which is produced predominantly by reactions between fine particles in the sinter mix. The subsequent assimilation of larger particles is considered to depend on the reactivity of the melt and the assimilation resistance of these particles. Novel laboratory experimental techniques are used to quantify these parameters. Results demonstrate that the properties of the raw materials used have an extremely important influence on the initial processes of melt formation and assimilation and also on the nature of the sintering reactions and sinter-bonding phases.

Jan 4, 1992

By J. K. Brimacombe, F. D. Richardson

Studies have been made of interfacial turbulence occurring in reactions in which indium, zinc and cadmium, dissolved in amalgams, are oxidised into aqueous phases by ferric or mercurous ions. It has been found that this turbulence occurs when the concentrations of oxidising ions in the aqueous phase become sufficiently great. These concentrations are the same as those at which the mass-transfer coefficients in the aqueous phase increase sharply when both phases are stirred by gas bubbles rising through them. The effects of gas flow rate on the mass-transfer coefficients for zinc in mercury have been established, and the oxidation of pure mercury has been investigated. The relevance of the work to processes involving liquid metals is discussed

Dec 1, 1971

By Hardwick F. W., O'Shea L. T.

The survey covers: coal-mine lighting prior to the invention of the safety-lamp, including candles, the flint-and-steel Spedding mill, and mirrors; the growth in knowledge of firedamp; the Society in Sunderland for Preventing Accidents in Coal Mines; Dr. Clanny's blast lamps and steam lamps; George Stephenson's tube-and-slider lamp, triple-tube lamp, punched-plate lamp and gauze Stephenson lamp; Sir Humphrey Davy's lamps; the controversy over invention priority, and other early forms of safety-lamp; 1816-1835 developments including the lamps of Upton and Roberts, M.Mueseler, John Martin, Dr. Clanny (new 4th lamp), M. Agre, John Newman, Gossart and Roberts, Francis Ellis, John Dillon and Mr. Wood (refrigerating lamp); 1836-1843 developments, notably of Mueseler lamps; 1844-1866, including lamps of the Davy, Clanny, Boty, Eloin and other types; 1867-1879, including the Gray lamp; 1880-1887, including the Marsaut lamp; and 1888-1913. Detailed reference is made to the findings of various relevant Royal Commissions and appendices include a list of the safety-lamps described in an appendix to the 1886 report and a publications list. The paper was prepared for the International congress of mining, metallurgy, applied mechanics and economic geology to have been held in London in July 1915. Discussion (p.718-724) includes a brief comment by Blackett W.C. and a longer contribution by Ashworth J., with the authors' response

Dec 1, 1916

By J. Temporal

An introduction to the conference material in this issue is given together with the issue contents list, closing remarks by its chairman Dr. J. Temporal, the list of contributors and their companies, and the information that the 26th Sir Julius Wernher memorial lecture had had to be presented by the lecturer's wife, M. Biggart, in his absence due to site problems on the Storebaelt project

Jun 16, 1905

By Simons W.

The object of the paper is to describe the standards of quality that should be specified in ordering material ordinarily required for colliery use, and also the qualities most suitable for particular purposes. Tables are presented of British Standard tests for wrought iron grades A, B and C, Admiralty tests for iron in chain, the quality of material for wheels and axles, and the composition and mechanical properties of wrought iron, Armco (ingot) iron and drawbar-gear steel. (Paper presented at the North Staffordshire Institute of Mining and Mechanical Engineers' general meeting held in Stoke-on-Trent, March 27th 1916, Mr. John Gregory, President, in the chair)

Dec 1, 1916

By J. D. Appleton, J. Ridgway, K. B. Greally

Paper presented at the 28th International Geological Congress held in Washington DC, July 1989 (International geochemical mapping sessions). The results suggest that meaningful geochemical maps can be produced from very low-density surveys, and that existing data sets could perhaps be incorporated into such a map series with the use of a system such as Uniras software. There are still many problems to be resolved, however, including the compatibility of data derived from different analytical methods, and the precise methods to be employed will necessarily require international agreement. Sampling densities should be chosen on the basis of the scale of the geochemical and geological features to be distinguished and will vary from region to region. Reanalysis of selected samples from archives to increase the range of elements determined or to unify analytical methods is only likely to be effective if the original survey was at quite a low density

Jul 1, 1991

By R Adamian, F. T. Da Silva, D. H. Gameiro

Schytill and Geldart diagrams were developed for the TiO2-C-Cl2 system at 1 073 and 1 273 K, so as to define the hypothetical relations between particle sizes and chlorine velocity for simultaneous fluidisation of mixtures of anatase concentrate and charcoal for carbochlorination. It was concluded that the operating limits on chlorine gas velocity will be controlled by the behaviour of the reducing agent, mainly because of its lower density. An increase in temperature from 1 073 to 1 273 K will have only a small influence on the fluid-dynamic behaviour of the mixture. For bubble fluidisation, the maximum sizes 0.413-0.478 mm for anatase and 0.529-0.611 mm for charcoal will be adequate. When the particle size distribution is large, fluidisation will be feasible only if conducted in two stages, otherwise the residence time of the small particles in the reactor will be very short. New diagrams will be needed for the gaseous chlorides in the second stage

Jun 21, 1905

By D. J. Burdon, Anthony Caplan

"(1) The radiological appearances of pneumokoniosis on the Kolar Gold Field is described in detail. The characteristic abnormality is the. presence of a diffuse, fine annular and punctate mottling. (2) The frequency of symptoms could not be determined with any degree of accuracy, but it is believed that symptoms are absent and there is no incapacity until profuse radiological mottling is present, i.e., after long exposure to dust. (3) There is an increased predisposition to tuberculosis, which, if it occurs, affects the prognosismost unfavourably.(4) Pathological examination shows that the radiological mottling is due to the presence inthe lung of numerous small dust-cdll aggregates (up to T5 mm. in dia.) deposited around the smaller bronchioles and blood-vessels.(5) The dust-cell aggregates are relatively acellular but when tuberculosis is superadded thereis an excessive cellular and fibrotic reaction.(6) The difficulties of defining the radiological and pathological appearances of early pneumokoniosisare discussed.(7) The incidence of pneumokoniosis in 7,653 workmen with 5 or more years’ undergroundservice was 43-75%, but it is suggested that in future the incidence will be appreciably lower.(8) The methods of- dust production and the chemistry of mine dust are described. It isshown that the free silica-content of air-borne mine -dust is relatively low.(9) The aetiology'of the pneumokoniotic lesion is discussed."

Jan 1, 1947

By J. A. Finch, Zhenghe Xu, Z. A. Zhou

A particle-bubble collision model was used to investigate the minimum recovery zone height, H(r,min) required for flotation columns. The criterion used to define H(r,min) is that height which gives unit collision probability. It is shown that H(r,min) is determined by particle and bubble size, gas hold-up and bubble-bubble interaction. Under typical operating conditions, for flotation of particles less that 10 micrometres in size H(r,min) is greater than 10 m, but it reduces to less than 1 m for particles greater than 100 micrometres

Aug 1, 1995

By R. M. Cooper, H. K. Herbert, D. N. Phillips

A study was carried out to determine the effects of adding CaCO3, Fe, Al and CaSi2 to the ladle, rather than to the raw materials, in order to increase the concentration of Ca, Fe and Al in the final product to meet customer specifications at Simcoa's Kemerton plant in Western Australia. LA-ICP-MS, SEM-EDXRA and ICP-AES analysis of samples and controls showed that the technique is suitable for controlling minor element concentrations. Iron was successfully added, while calcium silicide with aluminium proved better than limestone with aluminium for controlling Ca and Al concentrations in the silicon

Jun 19, 1905

By P. A. Davies

Paper presented at the conference: Risk assessment in the extractive industries, held in Exeter, UK, 23-24 March 1994, and first published London: IMM, 1994, preprint volume, 11pp., 15 refs. Hazards such as vibration, dust emission and fragment projection can result in an area called the Danger Zone being set around a blasting site. Traditionally Danger Zones have been set solely on the basis of consequences (e.g. based on the maximum distance of rock projection or expected ground vibration plus a defined safety margin). Advances in risk assessment and its growing acceptance as a safety management tool have led to the setting of Danger Zones based on both consequences and frequency of occurrence. This allows distances to be optimised on the basis of acceptable risk levels rather than the potential consequences of infrequent events. The setting of a flyrock Danger Zone is used to demonstrate a risk-based approach compared with a traditional consequence approach

Aug 1, 1995

By G. S. Pauley

Paper presented at a meeting on: Artificial intelligence in the minerals sector, held in Nottingham, UK, 20 April 1993 (original title: Case-based reasoning can be a catalyst for improvement). A new computer software technology known as Case Based Reasoning (CBR) can be used to produce small decision support systems that are economically viable. This is because the knowledge that they contain can be owned and maintained by their users. A CBR tool has been used to perform a pilot study with Anglesey Aluminium Metal Ltd. The results are encouraging. They suggest that a combination of CBR and participative design and implementation techniques (such as Checkland's Soft System Methodology) can achieve sustainable improvement in mineral processing functions. An explanation is presented of why traditional, rule based systems are often an ineffective way to implement support systems. It is shown that CBR may provide an appropriate technology solution. Methods of achieving sustainable benefit are indicated. The pilot study with Anglesey Aluminium Metal is used as a practical illustration of the development of a CBR application. A review of potential application areas and some observations about the implementation are presented

Apr 1, 1994

By M. K. G. Whateley, W. Hatton

Paper presented at the conference: Risk assessment in the extractive industries, held in Exeter, UK, 23-24 March 1994, and first published London: IMM, 1994, preprint volume, 20pp., 31 refs. Estimates of coal tonnage on UK open cast mining sites often vary from the recoverable tonnage. This is because the estimates depend on the geological variability of the coal measures. Geological parameters, such as thickness, quality and disturbance of the seam, have a direct control upon this variance. Risk analysis techniques have been applied using commercially available software to combine each parameter's variability into a cumulative variance, resulting in a tonnage distribution. Sensitivity modelling has also been used to identify the geological parameters which have the largest influence on the variance of the simulated tonnage distribution. An understanding of the relationship between the tonnage and geological variability has helped to focus exploration more efficiently. A cost to risk relationship can now be monitored, helping management to avoid negative consequences on site

Aug 1, 1995

By A. D. Fowler, M. T. Anderson

A phenomenological model is presented that relates Pb-Zn mineralisation to proximal geopressure zones. Typically, geopressure zones (GPZ) consist of masses of undercompacted sediment encapsulated within impermeable shales and are characterised by high formation fluid pressures. Heat flow is perturbed in some GPZ on account of their insulating properties. Geothermal gradients as high as 150 degrees C/km have been observed over short distances in the sediments of the US coast of the Gulf of Mexico. Some modern geopressure zones are known to reach temperatures of 120-150 degrees C at depths of 2.5-3.5 km. It is demonstrated that the zones may act as proximal sources of hydrothermal fluids, thus explaining the high temperatures of mineralisation observed in the deposits, which are hosted in basins characterised by thick, rapidly deposited, shale-rich clastic sequences

Jan 1, 1991

Paper presented at the UK minerals industry conference and published in: Minerals extraction towards the millennium. UK minerals industry conference, 3-5 April 1995, University of Leeds. London: Institution of Mining and Metallurgy, 1995. The various types of risks that arise in minerals industry projects are usually financial, technical, or environmental, and the key to valid risk analysis is complete integration of all risks, both within and between categories. Geographical information systems (GIS) and geostatistical simulation methods can provide a means of integrating data and conducting realistic risk analyses. Risk can be quantified but there are limitations to numerical approaches to risk assessment. Realistic quantification requires adequate models of the processes that give rise to risk. Risk perception must also be taken into account when conducting risk assessment and reporting the results, especially in public forums. The modelling and visualisation capabilities of a combined GIS/simulation system can provide the means of dealing with perception in risk analysis

Jun 19, 1905

By A. M. Tunstall

Aspects of blast vibrations, damage mechanisms and the influence of rock quality on damage severity are reviewed and results presented from a monitoring programme in which the rock mass rating for six tunnels was determined. The peak particle velocity induced in the tunnels during open-pit blasting was measured and the tunnels were inspected visually for fresh damage after each blast. The results suggest that the quality of rock in which an excavation is situated has an influence on the level of ground vibration to which it can be subjected without sustaining damage. This means that the use of a single limiting value of peak particle velocity, as in the blast damage criteria for residential structures, is not ideal and may result in damage to excavations in poorer-quality rock masses

Jun 19, 1905

By K. C. Garner

The visit reported was made with support from the 1997 J.C. Boyle travelling scholarship. The management and control of hazardous gases released into the underground environment are an integral part of coal mining. The power-generations stations at Appin and Tower collieries, with a combined electrical output of 94 MW, have been operating for some time and have demonstrated a technology that is able to exploit the available gas fully. Contributory factors have been the development and introduction of directional drilling techniques, pre- and post-drainage of coal, relatively high seam permeability, a high gas content of the worked seam, high production rates and a willingness to embrace new ideas and technology

Jun 21, 1905

By S. G. Tsimas, A. K. Moutsatsou, G. K. Parissakis, M. A. Komiotou

For Greek kaolin producers, a considerable proportion of whose output is from deposits containing more than 4 wt% Fe2O3, the colouring resulting from iron oxide impurity represents a serious problem that necessitates upgrading of the ore to meet commercial specifications. Autoclave leaching with oxalic acid for 1 h at 120 degrees C and 5-6 bar was shown to reduce Fe2O3 by up to 90% without affecting the structure of the kaolin, which maintained its physicochemical properties. The iron oxalate product can either be removed from solution or precipitated as iron hydroxide with recycling of the oxalic acid

Aug 1, 1995