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By Elisabeth Kolar, Rik Catthoor, Frederik H. Kriel, Rossen Sedev, Gareth Hatch, Army Research Laboratory, Craig Priest, Scott Middlemas

"This paper reports solvent extraction of rare earth elements (REEs) carried out using a microfluidic device and considers the REE loading limit of the organic phase under laminar flow. The microfluidic device contacts aqueous and organic phase streams for a precisely defined contact time (subsecond resolution) and then separates them for offline analysis. Experiments are reported examining the effect of contact time on extraction. We focus on three REEs: one ‘light’ (Nd), one ‘mid’ (Dy), and one ‘heavy’ (Yb) REE, which are extracted using Cyanex® 572. It appears that loading limits may be locally exceeded in the organic phase near to the liquid-liquid interface, where third phase deposits are observed. Third phase formation was also observed close to the liquid-liquid interface in two-dimensional confinement, showing similar third phase adsorption on glass plates. It is also shown that, under microfluidic flow, a typical first ‘split’ between heavy REEs and light REEs can be carried out without exceeding loading limits.INTRODUCTIONMicrofluidic solvent extraction has emerged as a useful tool for studying extraction of metals in a mineral processing context (Ciceri, Mason, Harvie, Perera, & Stevens, 2013; Ciceri, Perera, & Stevens, 2011; Kriel et al., 2015; Mason, Ciceri, Harvie, Perera, & Stevens, 2013; Priest, Zhou, Klink, Sedev, & Ralston, 2012; Priest et al., 2011). The main advantages are the extremely well-defined and tunable flow behaviour, large surface-to-volume ratios, short contact times, and minimisation of sample and reagent amounts. Two main flow configurations have been studied to date: droplet-based and co-flowing streambased extraction. In the former, droplets are formed at a microchannel junction (usually a T-junction or flow-focusing junction) and flow downstream as plugs or ‘free’ droplets. In our case, stream-based extraction, the chip is a plate (often glass) with embedded microchannels (i.e. with cross-sections of tens of micrometres) that carry the aqueous and organic phases in contact without forming droplets. Thus, these chips play the role of a mixer in a conventional mixer-settler and phase separation takes place by branching the streams or collection in a vessel at the chip outlet. Stream-based extraction requires stable streams that are usually supported by a particular channel geometry (e.g. guide structure or small ‘pillars’) or surface chemistry, and flow parallel bounded by the liquid-liquid interface(Aota, Nonaka, Hibara, & Kitamori, 2006; Hibara et al., 2005; Hibara et al., 2002). Phases are disengaged downstream at a Y-junction, which is a qualitative difference between microfluidic and bulk extractions."

Jan 1, 2016

By Avinash Kandalam, Markus Reuter, Jörg Kleeberg, Michael Stelter

The Top Submerged Lance (TSL) technology has obtained significant importance in the pyrometallurgy industry for nearly four decades. One of the advantages of TSL furnace is its high reaction rate, which is caused by splashing and turbulence of the melt. In contradiction, this phenomenon stands as a barrier for conducting experimental investigations to validate the simulation models. The highly turbulent and splashing environment in the TSL furnace is caused due to the immersion of the lance into the slag layer and thus the effect of the flame structure is directly related to the splashing, turbulence, reaction kinetics and life-span of the lance. Moreover, the material properties such as viscosity, density and the surface tension will also influence the flame structure. As a first step to understand the flame structure, attempts are made to generate a stable flame of the lance in an open environment. INTRODUCTION Top Submerged Lance (TSL) technology was invented during the 1970s at Commonwealth Scientific and Industrial Research Organisation (CSIRO), Australia by Floyd and Denholm. This technology was later commercialised and currently, there are about 100 TSL plants around the world commissioned by various licence holders such as AUSMELT (Outotec) and ISASMELT (Xstrata- Glencore Technology). Copper is the most produced non-ferrous metal followed by lead and zinc, see Hunt (2005). Today, a wide range of primary, secondary, and complex recycling materials are used as a feed material in the TSL, Alvear et al. (2010), Kaye et al. (2008). The working principle of TSL technology lies on inserting and submerging a lance from the top of a vertical cylindrical chamber into the slag layer. The lance is considered as the heart of the furnace, where the air and fuel are transported through two concentric tubes and are mixed in a combustion chamber, which is approximately 7 cm from the tip of the lance (considering the pilot-scale TSL furnace at the Institute for Nonferrous Metallurgy and Purest Materials - INEMET). The TSL furnace is very flexible with the type of fuel, feed material and the air input. The fuel can be natural gas/heating oil/fine coal particles and the air could be enriched with oxygen (Figure 1). The general mechanism of the TSL furnace lies on feeding the material from the top of the furnace and the material is pulled into the molten bath due to the high turbulent atmosphere, which results in high reaction rates. The thermocouples installed in the furnace (i.e. in the ceramic linings) allow the operator to know the temperature of the melt. For example, in the case of copper production the tapped material (i.e. matte/metal) can be transported to a settler for further processing or directly used.

Jan 1, 2019

Caterpillar Inc The world's largest manufacturer of construction and mining equipment, diesel and natural gas engines and industrial gas turbines. Technology leader in logistics, construction, transportation, mining, forestry, energy and electric power generation.

Aug 1, 2013

By A. -I. Abenhaim, I. Sasu, C. Perron, I. Mantegh, S. Larose

Manufacturing long shafts, such as those used in turbine engines, normally involves with drilling inside them in order to take the excessive mass out. Concentricity between the shaft axis and that of the drilled hole is very crucial as it impacts the mass distribution around the axis of rotation. It is important that the shaft mass be well balanced around the central axis in order to minimise the centrifugal forces on the bearings and supporting structure as well as any unwanted vibrations. The eccentricity problem, mostly in long shafts, comes due to machining limitations. It is difficult in long shafts to maintain the concentricity tolerances while drilling inside the shaft. In this work, we address the problem of correcting this eccentricity problem, i.e., when the axis of the inside hole deviates from the central axis. The presented work is based on a threepoint bending method and investigates its effect on the residual stresses and plasticity regions induced on the shaft. A full finite element model is presented that can used to design the solution parameters (bending load, location, etc.) and predict the effect. Limited experimental results are also presented to validate the finite element modelling.

Jan 1, 2006

By O E. Weightman

This paper describes the methods used for the ventilation of raises, sublevels and drawholes at Cominco's Sullivan mine. The problems involved in ventilation during blasting, drilling and scraping operations are first re-viewed, and then the air mover, a piece of equipment developed at the Sullivan mine, is described. The design of this device is discussed, along with the operating procedures used. Some figures are given to show the effectiveness of the method. THE Sullivan mine, located at Kimberley in the southeast corner of British Columbia, is owned and operated by The Consolidated Mining and Smelting Company of Canada Limited. Current daily production is approximately 10,000 tons. The mine is developed by sixteen levels over a vertical range of 2,000 feet. The total ventilation requirements, which amount to approximately 1,000,000 cubic feet per minute, are handled through a network of fresh air intake and foul air exhaust circuits. In addition to the many development and production headings, there are three crushing chambers and an extensive conveyor system which must be ventilated.

Jan 1, 1965

By Zainelabdin Khalid Zainelabdin Elfaki

The influence of partially replacing cement with marble waste on the workability and compressive strength of concrete bricks was investigated. Three replacement percentages, 10%, 20% and 30% weight marble waste, were used with different curing times of 7, 14 and 28 days. Two specimens were prepared for each percentage and curing time. For this study, marble powder from the Mining House Company in Saudi Arabia was used. It was observed that the replacement of cement in Concrete brick with marble waste enhanced the loading strength and the workability of the prepared concrete bricks. It was also observed that 20% replacement of cement with marble waste was the best replacement percentage compared to the other replacement percentages tested. Marble waste from manufacturing companies, either in powder, sludge or slab form, has negative impacts on the environment. In contrast, reusing marble waste has both economic benefits (i.e., selling the marble waste) and lessening the need for raw resources.

Jan 1, 2014

By T. S. Wanne

Tunnel sealing experiment (TSX) was conducted between 1997 and 2004 in the Canadian URL located in Manitoba. In the experiment, a tunnel was excavated parallel to the maximum principal stress direction, filled with sand and sealed with bulkheads at both ends. It was then pressurized and heated by injecting hot water. The rock mass response was monitored with seismic methods. The main interest in the numerical simulation was the damage formed during the heating phase. The large-scale PFC2D models replicated a central plane- strain section of the TSX chamber. The models captured the first-order phenomena observed in-situ displaying the difference in the damage in the roof and floor regions, respectively. This difference was due to the filling material confinement of about 100 kPa on the tunnel floor, which occurred in the course of the heated experiment.

May 1, 2009

"Sink-float analysis is often used to obtain yield-ash and density partition curves in the coal industry. These provide a valuable tool for evaluating the performance of a separation process. However, for dense minerals, obtaining complete grade-recovery and density partition curves is more difficult due to the lack of heavy liquids available with the required densities. This paper examines a potential solution to this problem which is to perform batch fractionation of mineral samples in a laboratory-scale REFLUX™ Classifier using high viscosity fluidising liquids. The REFLUX™ Classifier is a gravity separation unit consisting of a system of parallel inclined channels positioned above a vertical fluidised bed. Operated in semi-batch mode, a charge of particles is fluidised from below and particles up to a certain density are elutriated from the top of the system. The fluidisation rate is then increased incrementally to fractionate the sample at progressively increasing densities. Previous work by Hunter et al. (2014) and Iveson et al. (2015) has shown that this method provides excellent agreement with yield-ash and partition curves for coal, especially when glycerol solutions are used as the fluidising liquid. This approach has now been extended to obtain the grade-recovery and density partition curves of high density mineral samples. This method has the potential to provide the minerals industry with an effective tool to evaluate the performance of unit operations separating at cut points higher than the available heavy liquids.INTRODUCTIONMeasuring efficiency and effectiveness is of key importance in the continuous improvement of mineral processing plants. For density based separation, one way the performance of a process can be evaluated is the measurement of density-based partition curves. Currently, this is done in the coal industry using the sink-float method, where heavy liquids are used to fractionate particles into discrete density intervals. However, with high density minerals such as iron ore, liquids of sufficient density are rare, and in most cases also pose serious health and safety concerns to laboratory operators. Most commercial laboratories do not perform sink-float separations above a density of about 4400 kg/m3, the maximum density of Clerici solution without operating at excessive temperatures (Koroznikova, Klutke, McKnight & Hall, 2007; Rosenblum, 1974)."

Jan 1, 2016

By Sarah Belair, Gauthier Deblonde, Valerie Weigel, Alexandre Chagnes, Gerard Cote

"Niobium and tantalum are strategic metals for electronic and alloys industries. They are produced by pyrometallurgy and hydrometallurgy but most of the niobium and tantalum production processes are not environmentally friendly. For instance, in the hydrometallurgical route, niobium and tantalum separation can only be achieved by liquid-liquid extraction in the presence of hydrofluoric acid by taking advantage of the difference in niobium(V) and tantalum(V) speciation in fluoride-based media. Therefore, the environmental footprint of hydrometallurgical processes for the production of niobium and tantalum could be clearly lowered by replacing HF or NH4F by greener media such as alkaline solutions in which high solubility of niobium(V) and tantalum(V) can be achieved.The development of such new efficient and environmentally friendly hydrometallurgical processes requires a fine description of the physicochemistry of niobium(V) and tantalum(V) in alkaline solutions. Unfortunately, literature data show a huge discrepancy on niobium(V) and tantalum(V) speciation in such media. This paper gives a brief overview of the niobium(V)-tantalum(V) production processes and paves the way to the development of alternative processes in alkaline media by presenting and discussing recent advances in the physicochemistry of niobium(V) and tantalum(V) in these media.INTRODUCTIONNiobium and tantalum are strategic metals since they are used for the production of alloys and super alloys, capacitors and magnets in strategic industries such as electronic, aeronautics and automobile. The main sources of niobium and tantalum are given in Table 1."

Jan 1, 2016

By Y. Hou, E. Arinaitwe, L. Tong

A series of dense medium separation (DMS) tests were performed on four low-grade copper ores from Mount Polley mine in order to determine their amenability to pre-concentration. The tested ores contained disseminated sulphides, mostly chalcopyrite with low copper grades (0.15% - 0.2%) and relatively high iron grades (4.76% - 5.63%). The samples were screened into different size fractions ranging from 9.5 mm to 50.8 mm and DMS tests were performed on each size fraction at various separation densities. The pre-concentration efficiency at different size fractions and separation densities was evaluated in terms of metal upgrading and distribution. Mineralogical tests were also performed on selected DMS sink and float samples in order to understand the influence of mineralogy on the pre-concentration efficiency. The results showed that significant copper upgrading was achieved for intermediate size fractions only at the highest separation density tested. The copper recoveries generally increased with particle size at all separation densities. However, it was impossible to upgrade the copper content in the ores and achieve acceptable recoveries and mass rejections at the same time. Copper recoveries and grades showed a strong correlation with iron recoveries and grades indicating that it is possible to pre-concentrate copper by recovering magnetite and other iron-containing minerals in the ore. Overall, the results suggest that the optimum separation density and pre-concentration efficiency is a function of particle size, and that the ore mineralization properties limit the performance of DMS as a pre-concentration technology for such low-grade disseminated ores.

Jan 1, 2014

In terms of throughput, product size and power draw, grindcurves provide a measure of the response of the mill performance to changes in mill operating parameters – usually mill filling. Since presenting the principle in 2006, grindcurves have been applied to a wide variety of AG and SAG mills. Mill response has been carefully measured for variations in: mill fillings from 15% to 40%; throughput by a factor of two; power by 50%; feed blends; liner profile; and mill speed from 65% to 80%. The outcomes of this extensive program of work are presented as the measured grindcurves. How they have enhanced our understanding of mill operation and how they may be applied to practical daily mill control is discussed. It is proposed that this technique provides a viable and valuable mill control tool that may find extensive application in the industry.

Jan 1, 2012

By W. V. McKnight

The paper discusses the equipment and methods used to establish some of the characteristics of a braking system. Some typical tests are described and an explanation of the approach used to derive information from the recorder charts is given.

Jan 1, 1966

By T. Belem

In-stope backfill will cure under effective stress, which develops due to a combination of mechanical consolidation (free draining material) and ??chemical consolidation?? (self-desiccation mechanism). A good knowledge of all the drainage and consolidation characteristics of cemented paste backfill is crucial for a better design of underground backfilling sequencing. From many of the existing results and studies done by various authors, as well as the availability of some in-stope backfill pressure data measurements during and after filling, it is possible of developing a procedure of backfilling sequencing. Hence, the objective of this study is to provide a guide for underground backfilling sequencing in the view of preventing the development of excess pore pressure that will affect both the stability of the barricades and the strength development of the backfill. This will be possible by considering the interaction between consolidation/drainage rate, filling rate and binder hydration rate.

Aug 1, 2013

By S. Suzuki, C. Tokoro, S. Owada, T. Sakakibara

Acid mine drainage (AMD) has been actively treated by neutralization from about 80 abandoned or closed mines in Japan. More efficient and cost effective treatment processes has been demanded for AMD due to the government investment of billions of yen every year to protect the environment from these discharges. In this study, quantitative modeling was conducted for actual AMD to predict pH or residual concentration of toxic elements after neutralization/co-precipitation process. Simple chemical equilibrium calculation was not adequate for quantitative prediction of pH after neutralization, because residual concentration of major elements of AMD, such as Fe or Si, could not be quantitatively calculated. When oxidation rate of Fe(II) to Fe(III) and precipitation rate of kaolinite were added to the model, quantitative prediction of pH and Fe or Si concentration was achieved. Surface complexation at the interface between hydroxide such as ferrihydrite or aluminum hydroxide and AMD was the most important mechanism for removal of dilute toxic ions. When surface complexation model at the interface of ferrihydrite was added to the model, residual As (V) and Pb (II) concentration after neutralization/coprecipitation process was successfully calculated. On the other hand, surface complezation model of aluminum hydroxide was also necessary for quantitative prediction of residual Zn(II) concentration after neutralization/co-precipitation process.

Jan 1, 2014

By A. L. Hinde, H. Dong, J. T. Kalala

"The High Pressure Grinding Roll (HPGR) is gaining acceptance in the mineral processing industry and has become a competitive technology in reducing the specific energy consumption in Mineral processing plants. The amount of samples required for HPGR amenability testwork and HPGR wear tests is usually high and often cannot be available at early stage of projects were only a few drill cores are available.Although HPGR was initiated from small scale piston die compression tests, the development of small scale piston die test to predict the performance of HPGR has been slow.The objectives of this paper was to present the designs, operating procedure of piston-die press and operating conditions which have resulted in similar particle size distribution obtained from a piston die test and HPGR Labwal unit starting from the same feed size distribution. Testwork were conducted using a 2 MN piston-die press and a Labwal HPGR unit on major South African ore types, viz, gold, platinum and iron ores. The results obtained show that piston-die test can generate data to predict energy consumption, product size distribution, and even to evaluate the edge effect."

Jan 1, 2012

By P. Radziszewski

Industrial practice in mineral processing shows that an important problem in understanding and monitoring in-mill parameters is due to the lack of fundamental knowledge and appropriate sensors. With the development and growing use of DEM charge motion simulators for mill optimisation and design, it is possible to describe the fundamentals of grinding mill behaviour, in improving the understanding of internal grinding mill dynamics and in developing solutions to industrial practice. The main challenge to bringing this DEM technology to the mill operator however was the need for substantial computing power and time. However, what about a simplified DEM charge motion model running in real-time? What about the use of sensor technologies to correct any possible drift in simulator prediction? Could such a technological system be used to predict mill performance and eventually be used for mill control and optimisation? Some of these questions are answered with the development of an "on-line" DEM charge motion simulator package (SAGTools?) along with that of a number of sensor technologies (liner wear, acoustic, instrumented ball) that can contribute to simulator precision. With the objective of bringing this modelling and sensor technology into the concentrator control room to assist operators, this paper aims to describe the main elements of this emerging and developing technology and discuss how it can lead to online mill performance prediction and eventual control.

Jan 1, 2007

By Rolf Andreas Lauten, Guy Kluck

"Formation of scales may have important detrimental effects in many mineral processing applications. A well-known problem is the need for frequent maintenance to remove scale from processing equipment. Another challenge may relate to encapsulation of valuable minerals in precipitating scale. In this work, we explore the ability of some crystal growth inhibitors to prevent or lower the degree of scale precipitation. In many situations pregnant leach solutions contains substantial concentrations of calcium, magnesium, sulfate and carbonate in addition to dissolved valuable elements, e.g. gold, copper, zinc. Together with non-dissolved gangue minerals, some slurries may also contain particulate gold, copper etc. During normal processing of the pregnant leach solution it may be exposed to temperature gradients or similar promoting precipitation of various scales. Valuable minerals may become entrapped in precipitates and thus become inaccessible to the lixiviant. Use of a crystal growth inhibitor may lower the degree of encapsulation of valuable elements.Using a simple model system, supersaturated with respect to gypsum, the effect of some crystal growth inhibitors on the prevention of scale is evaluated in terms of amount precipitated gypsum, the particle size of the precipitated gypsum and the carbon gold loading capacity.INTRODUCTIONGold bearing sulfide ores are often roasted or pressure oxidised prior to leaching. The purpose of this unit operation is to prevent loading the leaching circuit with sulfides that consume cyanide. Pressure oxidation or roasting chemically converts the sulfides into sulfates and at the same time, the pH of the slurry ends up in the acidic range. Typically, lime addition is the preferred means to raise the pH to around 10 where gold leaching takes place. Combination of large amounts of calcium ions from the lime with sulfate ions from the ore induces precipitation of gypsum. Compounds like calcium carbonate may also precipitate if carbonate ions are present in the slurry. Depending upon the composition of the ore, compounds like calcium carbonate and other types of scale may also precipitate on gold surfaces on the slurry particles. A layer of scale on top of exposed gold surfaces will prevent dissolution in the cyanidation that takes place during leaching. Naturally, such a precipitation may lower the gold recovery."

Jan 1, 2016

By G. Heinrich

Size by size recoveries and pentlandite liberation data from image analysis were used to evaluate plant tests of pentlandite flotation and pentlandite/pyrrhotite middlings flotation from pyrrhotite in a circuit treating low grade magnetic intermediates at the Strathcona Mill. Raising the pH with lime gave improved selectivity for liberated pentlandite but there were major losses of middlings unless the circuit was pulled hard indicating the need for finer regrinding. However, size by size recoveries at the normal regrind showed that, while the pentlandite recovery improved in the finer ranges, the pyrrhotite recovery also increased leading to little selectivity in any size range. A much finer regrind gave greatly improved selectivity in all size classes suggesting that 'surface polishing' as well as liberation effects were being seen. Using liberation data from image analysis of the products, surface polishing accounted for over 99 % of the improvement in selectivity. Unreasonable recoveries of more highly liberated particles were observed for liberation analysis by volume fraction but showed the expected trend in recovery when the analysis was based on surface liberation. The surface liberation data showed that the improved pentlandite recoveries after finer regrinding were to more than 90 % caused by improved liberation with the remainder contributed by surface polishing effects. The practical implications of this work are that i) the comparison of particle grades with product grades allows to estimate the effect of regrinding on co-flotation/entrainment, ii) surface liberation models should be used for evaluating recoverabilities by flotation and iii) regrind circuits may be set up to ensure that all particles go through the mill or that only the coarse fraction is reground depending on the surface scrubbing found to be required.

Jan 1, 1993

By Zorigtkhuu Davaanyam, Fisher Wang, Bern Klein, Amit Kumar

"The High Pressure Grinding Roll (HPGR) is an increasingly popular energy efficient solution for comminution of competent ore deposits that primarily competes with conventional crushers and tumbling mills. A significant barrier to increased adoption of HPGRs is the requirement for large amounts (one tonne or more) of sample for pilot testing which may not be feasible for most early staged projects.Various researchers have worked towards developing piston-die and JK drop weight tests to model and predict the energy requirements for an HPGR. Two small scale laboratory test procedures (the SMC test (Morrell, 2009) and the piston press tests (Davaanyam, 2015)) have been developed in recent years to provide necessary information to size an HPGR.These two methods were used to estimate the required specific energy for an HPGR unit and compared to HPGR pilot scale test results from a copper deposit. The comparison provides insight into the benefits and limitations of these tests.INTRODUCTIONHigh pressure grinding rolls (HPGR) have gained popularity in recent years because of their energy efficiency in comminution. Various researchers have suggested that approximately 50–80% of the total energy consumed in a mineral processing plant is used by the comminution equipment (Haque, 1999; Abouzeid & Fuerstenau, 2009; Wang, 2013). Haque (1999) showed that the efficiency of grinding equipment can be as low as 1%. Due to the energy intensive nature of comminution, mining industry has been forced to explore alternative energy efficient processes.An HPGR based circuit has been shown to be 10–25% more energy efficient than a conventional SABC circuit (Von Michaelis, 2009; Wang, 2013). A significant barrier to the increased adaptation of HPGRs is the requirement for a large amount of sample for pilot testing (up to 5 tons), even on a prefeasibility level. Numerous studies have been performed to utilize piston press test to analyze the performance of the HPGR circuit and to predict the energy consumption for an industrial application. This paper uses two small scale laboratory test procedures, the SMC test and a piston press test, to compare the energy requirement to the pilot HPGR data."

Jan 1, 2016

By Jaroslaw W. Drelich

Despite the success of DLVO and extended-DLVO models that have been developed for homogeneous and smooth surfaces, a vast majority of practical surfaces encountered in mineral ore beneficiation are typically rough at various scales; they are also typically heterogeneous. The interactions of gas bubbles with particles having rough and heterogeneous surfaces are much more complex than the commonly used DLVO or extended-DLVO models predict. The effects of surface roughness on flotation and colloidal interactions have been reported many times in the past, although a clear understanding of their origins has been lacking. To explain differences in colloidal interactions for spherical hydrophobic particles, a theoretical analysis of the interaction potential was carried out for a model rough particle interacting with a bubble surface in an electrolyte solution in this study. The attractive hydrophobic interaction potential was added to repulsive retarded van der Waals and repulsive electrical double layer interaction potentials. The rough microscopic particles were modeled as spheres decorated with nano-sized asperities. Parameters that reflect common flotation separation systems were selected for testing this theoretical model and computation of the energy barrier applicable to particle – flat bubble surface interactions. It was found that hydrophobic asperities with the height of only several nanometers can reduce the repulsive interaction energy by an order of magnitude. Theoretical analysis also reveals that surface coverage of microscopic particles by nano-sized asperities is important as well. The findings of this research suggest that manipulating and engineering the particle surface topography could lead to better control over flotation separation.

Jan 1, 2016