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By J. Mosher, G. Banini, J. Hollow, A. Villanueva

Prior to installation of High Pressure Grinding Rolls (HPGR) at PT Freeport Indonesia (PT-FI) a series of laboratory tests were carried out to determine the design parameters and also determine key performance indicators (KPIs) for the industrial unit. The design parameters derived from the lab test work were then scaled up to estimate the industrial capacity of the HPGRs to be installed. These parameters include specific power draw, specific throughput, and specific force, rolls speed, product size distribution and wear rate of the rolls. This paper compares the performance of the scale-up procedure against the installed industrial size HPGR. Overall, the specific throughput of the industrial size HPGR is higher by a minimum of 30% compared to the expected scale-up value. As a result of the high specific throughput, the specific power draw and grind sizes are below the scale-up expectations in the commercial application. The impact of these factors also contribute to a lower than expected wear rate on the industrial rolls. Installed rolls achieved a service life in excess of 18,500 hours relative to the target of 6,850 hours predicted from the laboratory testing.

Jan 1, 2012

By A. Vervoort

The concepts of geostatistics are commonly difficult to understand for students, even for those with a strong mathematical background. A main problem is certainly the link between the variation of the parameter value in space or time, and the calculated experimental semivariogram as a function of the interdistance, but over the entire area. Another problem is to differentiate between directional and omnidirectional semivariograms and the way they have to be interpreted. Furthermore first time users of geostatistics often do not want to struggle through different books with the whole geostatistical background before using it. Too often this leads to using geostatistics as a black box with all the risks linked to it. That is the main reason that we developed some interactive tools based on the free public domain software R. We aim by developing three different modules to assist individual first time users, but also regular students and teachers to get a feeling of the importance of the various aspects in conducting a good geostatistical study. The modules show directly e.g. the impact of deleting, moving or adding data points, of changing parameters of the semivariogram model and of the geometrical parameters during kriging. The first module allows making the link between the variation of the parameter values in one direction and the calculated experimental semivariogram, and this for different given datasets. The second module covers two dimensional datasets and apart from calculating the semivariogram values, models can be fitted to the calculated data. A distinction can be made between omni-directional and directional semivariograms, including the effect of the tolerance on the angle and lag-distance. The third module focuses on ordinary kriging of point values in two dimensions. The aim of the interactive tools developed is limited to educational purposes only, i.e. to visualize some basic concepts for different pre-selected types of spatial variation. They do not intend to do a geostatistical study on a certain dataset (for this purpose there exists already a broad spectrum of good software packages). The original intention of developing the three modules was aimed at users with no or a limited amount of geostatistical experience. However, these modules seem also very useful to remain critical for experienced users. One should never forget that in a real application one does not have a complete view of the phenomenon studied. The geostatistical interactive modules can be accessed through: www.bwk.kuleuven.be/geostatistics . We compiled a manual to facilitate the use of the modules and to guide the user we formulated several questions to be solved for each module.

Aug 1, 2013

By E. R. Olson

The introduction gives not only a historical background but also touches on shaft sinking and surface construction and gives some general information on the Potash Conservation Regulations which the Saskatchewan government introduced in 1969. It also gives information on the corporate and local organization of Alwinsal Potash.

Jan 1, 1972

By W. A. Padgham, J. A. Brophy

About 85 % of the 350 tonnes of gold produced by 25 mines in the onhwe t Territories (NWT) since 1935 has come from the Yellowknife-area mines, Con and Giant , which exploit shear zones in Archean mafic volcanic of the Slave Structural Province. Four percent of the total production has been from Archean iron formation-hosted depo its, mainly from Lupin Mine, which today produces more gold than Con and Giant combined and has been primarily responsible for the increase of WT gold output from 5 to 12 tonne per year since 1981. The remaining gold ha been won from the following deposit typesall but the last being in Archean rock : sedimentary-volcanic contact depo its uch a Discovery and Salmita (10 %); turbidite-hosted quartz-vein depo its uch a Camlaren and Ptarmigan (1%); Proterozoic deposits such as Shear Lake and Fox (1#) . All but I% of WT gold has come from the Archean Slave Structural Pro ince, which is also the premiere exploration area for gold deposit types that have yet to be productive in the NWT. These types include stratabound gold in mafic and in felsic volcanic rocks (eg. , at Indin Lake and Courageous Lake, respectively) as well as gold in plutonic rocks (eg. Anialik Gnei Complex). Deposits similar to those in the Slave have al o been found in the Archean Ennadai Belt of the Churchill Structural Province. In the Cordillera. there is potential for placer gold and for gold associated with Cretaceou intrusions.

Jan 1, 1986

By C. O. Aksoy

Operating the underground marble quarries effectively, it is important to evaluate the deposit blocks economically which are affected by the suitability of the topography and configuration of bedding. The joint sets within the deposit and the spacing between these discontinuties are also of great importance. In this study, the marble deposits that could be geomechanically eligible for underground excavation have been selected throughout Turkey and these selected reserves have been classified accordingly by Q-Rating System. These classified marble deposits that forms groups of 1,2, and 3 (groups were determined by evaluating the O-rating, topography, quarry situation, cracks, joints etc.) are convenient for this type of production. Nevertheless, when the auxiliary factors (topography, location, production method etc.) regarding the deposit have also been investigated, the most convenient sub-group of deposits (Afyon Tiger Skin, Burdur Beige, Diyarbakir Pink and Mugla White) have emerged. The sizing of the pillars have been performed utilising Bieniawski?s stress profile. The LAMODEL software, developed by National Institute for Occupational Safety and Health (NIOSH), USA and run under the laminated displacement discontinuity method, has been used to size the pillars. This work brings in a novel opportunity to Turkey, in which no underground marble quarry has been attempted up-to-date similar to its several examples in Italy, USA, etc. This study serves as a reference for the marble operators and for the pioneering application of laminated displacement discontinuity method in hard rocks.

Apr 1, 2005

By Lyall J. Lichty

THE property of New Calumet Mines, Limited, is on Calumet island, in the Ottawa river, about sixty-six miles northwest of Ottawa. Lead and zinc orebodies were discovered here in 1893. A gravity concentration plant was built in 1912 but was not a success metallurgically, and the plant was later destroyed by fire. A programme of diamond drilling on the property, started in 1937 and continuing to 1942, indicated ore reserves amounting to 1,300,000 tons averaging 2.75 per cent lead, 8.82 per cent zinc, and 0.041 oz. gold and 6.24 oz. silver per ton( l ). These orebodies have been developed underground by cross-cutting and drifting from a three-compartment vertical shaft, sunk to a depth of 745 feet. 'The ore is a contact metamorphic deposit occurring in rocks of the Grenville series, on or near the contact between biotite gneiss and an overlying calcareous amphibolite(2,3). It consists chiefly of iron-bearing sphalerite, galena, pyrrhotite, pyrite, and minor amounts of chalcopyriteand argentite. The gangue minerals closely associated with the ore are calcite, quartz, and various lime-silicate minerals.

Jan 1, 1945

By E. H. Henderson

MR. R. V. NEILY stated that he had at one time operated at Goldenville. The practice and results are much the same now as in the olden days. Inside plates were then found to be a source of trouble and had been removed. At the Libbey mine, Queen's county, the sulphides carried considerable gold, and $45.00 to $60.00 per ton had been recovered from the concentrates by roasting and chlorinating. Later, concentrates were treated with bromocyanide. Following that practice, a cyanide leaching plant was installed, which did not require concentration of the tailings. Cyanidation brought a recovery of around 95 per cent, with but $300 worth of plant. In Nova Scotia, the ore of each locality presents an individual problem of its own as to treatment required. Ma. W. B. Timm stated that, in the majority of Nova Scotia gold ores, more than 75 per cent of the gold content is free-milling and, naturally, stamps are most efficient for collecting and amalgamating this gold. In Ontario and the West, they had got away from stamps, and perhaps the main reason was that the supply of battery-men, who came from Nova Scotia, had died off. Ball-mills had been installed, which required smaller space and handled large tonnage, even though, as far as amalgamation goes, the stamps were probably more efficient. If concentration is to be done, ore from stamps is usually in better shape for recovery in passing over the tables, as there is no slime. With the ball-mill, flotation is necessary. The better practice, undoubtedly, is to take out what gold is possible before it is all smashed up, as in the ball-mill, though recent developments in the ball-mill make it possible to trap and take coarse gold directly from the mill. In this way, cyanidation is speeded-up, due to saving of the time the coarse gold would take before going into solution. PROFESSOR A. E. FLYNN found it unusual in these days to read anything in favour of the stamp mill, and thanked Mr. Henderson for the excellent paper in which he upholds the stamps and backs his opinion with facts from actual operations. For the typical Nova Scotia ore, containing coarse gold, stamps are un¬excelled. It used to be said that the virtue of stamps is that they brighten the gold for amalgamation. Although this saying is almost classical, it is not true, for gold is never brighter than in the native, untouched state. Any hammering that gold gets makes it more difficult to amalgamate.

Jan 1, 1935

By J. Kang

There is increasing demand to utilize aluminium alloy sheets and their spot welds by the automotive industry. While traditional uniaxial tensile tests only determine mechanical properties to small strain, direct measurement of the constitutive behaviour of aluminium alloy spot welds at large strain remains a challenge. A technique was successfully developed using digital image correlation coupled with shear tests to directly measure the constitutive behaviour of an AA6022-T4 spot weld to large strains. The results show that the spot welding process not only decreases the yield strength but also lowers the work hardening rate of the nugget versus the base material. Details of sample preparation, experimental approach and results will be discussed.

Jan 1, 2011

By Z. Manafi

Bioleaching of a copper sulfide ore containing "activated pyrite", using a mixed culture of mesophilic bacteria, was studied. This type of copper ore had been found unsuitable for flotation because it produces a concentrate containing relatively high iron concentrations and, therefore, a low copper grade. Microscopic observations showed that pyrite particles had been activated by the formation of a thin film of chalcocite. Hence, a bioleaching process was considered as an alternative to treat this ore. Following shake flask and acid consumption tests, column tests of the crushed ore (75% -12.5 mm) were initiated and the effects of culture medium, agglomeration, and irrigation type on copper recovery were studied. The results showed that all the columns containing bacteria had copper recoveries around 90% compared to the abiotic control column with a recovery of 50%. It was concluded that bioleaching could be successfully utilized to process copper ores containing activated pyrite.

Jan 1, 2007

"THE OTTAWA BRANCH, CIM, each year holds a symposium on a subject of topical interest. The symposium this year was on Canada's Offshore Mineral Resources, at which papers were presented by: Dr. Donald G. Crosby, chief, Resource Administration Di-vision, Department of Energy, Mines and Resources, Ottawa; John A. Beesley, head, Legal Division, Department of External Affairs, Ottawa; and David W. Smith, man-ager, offshore exploration and production, Shell Canada Limited, Calgary. Because of the interest which this topic holds for our members, and because of the wealth and significance of information presented, the three papers -representing the first comprehensive review of our offshore resources -are reproduced herewith. The opening remarks of the Chairman, Dr. F. K. North, Professor of Geology, Carleton University, are also recorded, together with a few of the questions asked by the large attending audience. The symposium was held February 13th, and was organized by Dr. W. M. Tupper, chairman of the Branch Program Commit-tee. Differences in the extent of the continental shelf will be noted in the papers. These differences are related to slightly different definitions of the continental shelf by the authors."

Jan 1, 1969

By M. Ye. Shulgina, M. L. Bolotin, S. A. Prokopev, Ye. S. Prokopev

Iron ores concentration at Russia’s operations is carried out using conventional flow sheets. They comprise the two-four stage grinding followed by one-two stage magnetic separation. This results in the maximum recovery of magnetite to concentrate and the tailings generation. The final concentrate is generated only during the last stage of magnetic separation. Technologically, this flow sheet layout is not effective at recovering the liberated magnetite grains during grinding to the resulting concentrate. Advanced models of magnetic separators do not allow for the selective separation of the tailings and the portion of the resulting iron ore concentrate. Magnetic product which is the ore mixture of the liberated magnetite grains, high grade and low grade intergrowths is directed to the next grinding stage. In this case, regrinding of the liberated magnetite occurs. In addition, the performance of hydrocyclones during classification in closed grinding circuits is poor. Their classification efficiency does not provide the material separation in accordance with the size. In this case, simultaneous separation in accordance with the density occurs. The quartz particles with the size of 300 mm have similar velocity and trajectory like the particles of magnetite with the size of 60 mm. As a result, light and coarser intergrowths report to the overflow and free heavy magnetite grains report to underflow and return to regrinding (“the density effect”). This resulted in a significant increase of a mill circulating load, the decrease in the feed throughput and higher power consumption. In this connection, the development of iron ore concentrate stage recovery with the focus on gradual liberation of the intergrowths is getting much attention. Gravity concentration technique, particularly, spiral separation is effective at solving the problem of stage recovery not only the dump waste product but also high grade magnetite concentrates at the early concentration stages. This can be attributed to a significant difference in magnetite (4.9-5.2 g/cm3) and host minerals (quartz 2.7 g/cm3) densities, which is the principal during gravity concentration. The test work on concentration of various products samples from current operations (the mills discharges, concentrates from various stages of wet magnetic separation and cyclones underflows) was carried out. Spiral separators SV- 500 and ShV-500 manufactured by Spirit LLC were used for the test work. High grade iron ore concentrate (69.05% Fe) was generated during primary wet magnetic separation concentrate concentration using a spiral separator. During the concentration of mills discharges the content of iron in the resulting concentrates and middlings of wet magnetic separation II stage was 64.5% and 64.6%, respectively. The recovery of iron to the concentrates of spiral separation was 33.6-42.0%. The studies presented demonstrate that by using spiral separation for iron-bearing ores concentration, you can separate magnetite liberated grains at the early concentration stages, decrease their regrinding and circulating loads in grinding circuits. This process is able to improve the overall recovery and economics of iron ores concentration process.

Jan 1, 2016

By K. B. Han, S. Winkler, M. J. Benoit, M. J. Worswick

"Automotive heat exchangers are fabricated by forming multi-layered aluminum (Al) alloy brazing sheets into the desired geometry and subsequently passing the assembly through a furnace for brazing. As manufacturers seek to use thinner gauge and higher strength sheet to reduce vehicle weight, forming of the Al alloy sheets has become a challenge. Warm forming has previously proven to allay these forming concerns, but no consideration was given to the effect of increasing the forming temperature on brazing. Recently, it was shown that annealed sheet was more susceptible to the detrimental phenomenon of liquid film migration (LFM) during brazing if formed above 150°C, while work hardened sheets showed no increased susceptibility to LFM with increasing forming temperature, up to 250°C. In the current study, the brazing performance of simulated battery cooling plates was investigated. The plates were fabricated both from fully annealed and work hardened sheets. Brazing was assessed by microstructural evolution during a brazing cycle. The post-brazed microstructure varied with strain and forming temperature in plates made from annealed sheets, while no variation in microstructure with location or forming temperature was observed in plates formed from work hardened sheets.INTRODUCTION Since the 1970’s, one common method of fabricating automotive heat exchangers has been by forming multi-layered aluminum (Al) alloy sheets, and subsequently brazing the formed components together in a controlled atmosphere furnace. The Al alloy sheets used are comprised of at least two Al alloys roll bonded together, but can consist of additional layers, depending on the application; at minimum, the sheets are comprised of a core and clad layer. The core layer, often an AA3xxx alloy, remains solid throughout processing and provides strength to the assembly. The clad layer is always one of the AA4xxx series alloys which, due to their high silicon (Si) content, have a melting temperature range well below that of the core alloy. When the sheet is passed through the brazing furnace, the clad alloy melts to provide the brazed joint filler metal throughout the assembly, while the core alloy remains solid. In order to achieve cost and weight savings, heat exchanger fabricators have used Al alloy sheets with reduced thickness. However, deformation and brazing of these increasingly thin components remains a concern (Zhao & Woods, 2013). Furthermore, springback has been observed after forming sheets of higher initial strength (i.e. work hardened conditions), leading to flatness issues of formed components. Consequently, the ability to form high quality brazed joints is difficult in components formed from higher strength brazing sheets."

Jan 1, 2018

By L. Nastac, Y. Xuan

"The metal-matrix-nano-composite (MMNCs) in this research work consists of an A356 alloy matrix reinforced with 1.0 wt. % SiC 50 nm diameter nanoparticles that can be dispersed within the molten alloy matrix via ultrasonic stirring technology (UST) and induction melting and stirring processing. The necessary ultrasonic parameters to achieve the essential cavitation for adequate degassing and refining of the A356 alloy as well as the optimum fluid flow characteristics for uniform dispersion of the nanoparticles into the A356 alloy matrix have been investigated in this study by using computational fluid dynamics (CFD) modeling with a magneto-hydro-dynamics (MHD) model and an UST cavitation model.The MHD model accounts for turbulent fluid flow, heat transfer and solidification, electromagnetic field as well as the complex interactions between the solidifying alloy and nanoparticles by using ANSYS Maxwell and ANSYS Fluent Dense Discrete Phase Model (DDPM) and a particle engulfment and pushing (PEP) model.INTRODUCTIONAluminum matrix nanocomposites can offer outstanding properties, including low density, high specific strength, high specific stiffness, excellent wear resistance and controllable expansion coefficient, which make them attractive for numerous applications in aerospace, automobile, and military industries field (Bozic, 2010, De Cicco, 2009, Elshalakany, 2014, Goh, 2006, Jia, 2013 and 2015, Liu, 2014, Reihani, 2006, and Su, 2010).As shown in literatures (Aki, 1999 and Mussert, 2002), it is highly advantageous to use nano-sized ceramic particles to produce metal matrix nano-composites (MMNCs) since similar ductility and higher strength with the metal matrix can be achieved. Currently, there are several fabrication methods of MMNCs, including mechanical alloying with high energy milling (Chen, 1997) , ball milling (Filho, 2003), nano-sintering (Groza, 1999), spray deposition, electrical plating, sol-gel synthesis, laser deposition, etc. The mixing of nano-sized ceramic particles is normally lengthy, expensive, and energy consuming.Ultrasonic Stirring Technology (UST) has been extensively used in purifying, degassing, and refinement of metallic melt (Jian, 2005, Khalifa, 2008, Eskin, 2002, Xu, 2004, and Meek, 2006) mainly because introducing the ultrasonic energy into a liquid will induce nonlinear effects such as cavitation and acoustic streaming. SiC nanoparticles are widely used as reinforcement particles due to their relatively good thermal and chemical stability. Ultrasonic vibration can improve the wettability between the reinforced nanoparticles and the metal matrix (Lan, 2004, Cao, 2008, and Yan, 2011), which will assist to distribute the nanoparticles more uniformly into the metal matrix. Ultrasonic cavitation in liquids causes high speed liquid jets of up to 1000 km/h. Such jets press liquid at high pressure between the particles and separate them from each other (Hielscher, 2005)."

Jan 1, 2016

By G. Shen, W. R. Tyson

In most fracture toughness test standards, such as ASTM E 1290 and BS 7448, crack-tip opening displacement (CTOD) is measured by using three-point bend (SE(B)) or compact (C(T)) samples with deep cracks. The loading mode and crack depth in these tests sometimes are different from that of pipelines. Pipelines usually have shallow defects and experience tensile loading when the supporting ground moves. As a result, the CTOD measured by these samples is lower than that of pipeline in tension. Recent researches suggest using single-edge-notch tension (SE(T)) samples to measure fracture toughness for pipelines. In the present study, shallow and deep SE(T) samples under fixed grip loading were analyzed by using the finite element technique. An equation to relate the CTOD to the area of the load/plastic crack mouth opening displacement (CMOD) is proposed. With this equation, the CTOD of a SE(T) sample can be evaluated by measuring the area under the load/plastic CMOD curve of a SE(T) sample.

Jan 1, 2005

By Z. Trojanová

The deformation behaviour of ternary magnesium alloys AJ (Mg-Al-Sr) and AX (Mg-Al-Ca) were investigated in tension as well as compression tests. The samples were deformed at temperatures between 20 and 300 °C and at an initial strain rate of the order 10-4 s 1. The flow stress decreases with increasing temperature. The macroscopic work hardening rate decreases with increasing flow stress and temperature. The stress and temperature dependence of the work hardening rate is a result of the hardening and softening processes. Stress relaxation experiments were performed in order to reveal features of the thermally activated dislocation motion. Internal and effective stress components of the applied stress were estimated. A decrease in the internal stress was observed at elevated temperatures, which indicates recovery process (-es). A more detailed analysis of the estimated values of the activation volume and activation energy helped to interpret the thermally activated processes during plastic deformation. It is concluded that the deformation behaviour of the alloys depends on the activity of non-basal slip that is strongly influenced by temperature.

Jan 1, 2007

By Z. F. Lodhi, J. H. W. De Wit, H. A. Terry

Zinc and its alloys have been extensively used as replacements for Cadmium coatings in aeronautical and automobile industries. Zn alloys with low Co or Fe have been highly investigated but coatings with higher amount of Co are very difficult to achieve due to anomalism associated with these coatings. Anomalous Zn-Co-Fe alloy is a relatively recent addition to the family of Zn alloys. It is found that the addition of Fe in the electrolyte assist in overcoming the anomalism. In this research Zn-Co-Fe alloys especially with higher amount of Co (>15%) and Fe (~1%) are investigated, after overcoming the anomalism associated with its deposition, and the corrosion resistance is compared with pure Zn and Cd. It is found that an increase in Co to higher than 25 % accounts for a shift in the OCP to a level near Cd yet keeps it electronegative to steel. The coating shows superior corrosion resistance, in terms of its sacrificial and barrier properties in 3.5% NaC1 as compared to Zn and Cd.

Jan 1, 2006

By Saeid Akhavan

Accumulative roll bonding (ARB) is a severe plastic deformation process for achieving ultrafine grains in metallic sheets without changing the sample dimensions. In this study, ARB process was carried out on 5083 aluminum alloy sheets up to 6 cycles. In this process, the surfaces of the strips to be joined are roughened and cleaned and then stacked. After stacking, the specimen is roll-bonded by rolling using a 50% reduction. The rolled specimen is cut into two halves, and the above-mentioned procedure is repeated for several times. Microstructural characterizations were analyzed by transmition electron microscopy (TEM). Tension and Vickers hardness tests were performed on produced sheets for evaluating their mechanical properties. Moreover the texture parameter of the ARB-ed samples was calculated using their XRD patterns and the related equation. Additionally, the texture evolution during the ARB process was demonstrate by analyzing the measured pole figures and orientation distribution functions (ODF) and skeleton lines. The results indicated that at the early stages of ARB process, grains were subdivided by deformation induced boundaries. After several ARB cycles continuous recrystallization resulted in a microstructure covered with small recrystallized grains with an average diameter below 100 nm at the end of four cycle. Texture analysis revealed fiber textures have been discovered with continiuose of the ARB process cupper. Brass, S and dillamor textures identify which their differences are in intensity of ARB process. Results indicated conformity between mechanical evolutions and texture evolutions during ARB process.

Oct 1, 2011

By G. Gagnon

"HistoryMining of the Schefferville iron deposits began in 1954 on completion of the 357 mile railway linking the mines and the St-Lawrence river port of Sept-Iles. Apart from crushing, no treatment of these ores was required before smelting. In the late 1950's, testwork began at schefferville to develop a process for upgrading the extensive lower grade deposits containing 51% iron with 15% silica (natural analysis). Engineering for a six million ton per year beneficiation plant using cationic silica flotation and the A-C grate kiln Began in 1970 and the first pellets were produced in mid-1973.Production requirements and operating difficulties have restricted capacity to approximately 85% of design but on going improvements are being made continuously to attain design capacity.GeologyThe sedimentary ore bodies of the labrador trough occur in a belt 5 to 10 miles wide and 60 miles long and contain 51 individual deposits varying in size from 1 and 60 million tons. The ores are classified into three main color groups."

Jan 1, 1981

By D. W. Davis, P. Landais, L. J. Robb

Nodules of carbonaceous matter have been observed in several Archaean peraluminous granites adjoining the gold- and uranium-bearing Witwatersrand Basin. These nodules, which resemble solid bitumen, usually replace uraninite or uranothorite and are paragenetically late. They show many similarities to kerogen seams and nodules associated with the conglomerate horizons in the Witwatersrand Basin, including composition, maturation, intimate association with uraninite, and a late paragenesis. U-Pb isotope ratios for granite-hosted and Witwatersrand kerogens define a single, albeit somewhat diffuse, Ph-loss discordia suggesting an upper intercept age of circa 2300 Ma. Carbon isotope analysis indicates lighter Ol3C values for the granite-hosted nodules than for the sediment-hosted kerogen seams. Raman spectroscopy indicates that granite-hosted kerogen is more highly ordered than Witwatersrand seam kerogen. A model is presented which links the granitoidand sediment-hosted organic matter to an event of oil generation in the Witwatersrand Basin circa 2300 Ma ago. Light hydrocarbons migrated through the sediments and into underlying/adjacent granitic rocks, undergoing polymerization and accumulation in response to radiation accompanying the presence of high-uranium phases.

Jan 1, 1994

By Lorna Ortiz-Soto

A series of titiania- and silica-supported Au, Pt and Pt-Au catalysts prepared through different synthetic routes have been investigated in terms of their structural properties, adsorption of CO, and catalytic activity for the selective catalytic reduction of NO by propylene and the oxidation of and CO. Catalysts prepared by incipient wetness impregnation from individual Pt and Au precursors, exhibited characteristics very similar to those of monometallic Pt catalysts. This behavior is consistent with a model in which the two metals remain segregated due to their miscibility gap, and only Pt participates in the adsorption of CO and the reactions under consideration. In contrast, catalysts prepared from a Pt2Au4(C=CtBu)8 organo-bimetallic cluster precursor exhibited different behavior both in terms of CO adsorption and their catalytic activity for the three reactions examined. The combination of the kinetic, spectroscopic and structural characterization data suggests that in this case Pt and Au remain intimately mixed in the form of Pt-Au bimetallic particles, and that the presence of Au modifies the behavior of Pt.

Oct 1, 2003