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By C. Pichler, S. Luidold, C. Wagner, C. Sagadin, D. Kreuzer

Engineers and scientists have been combating the attack upon refractory materials of molten metals/matte and slags for hundreds of years. The details in many cases are still questionable or at least debatable. The corrosion is a major concern for furnace operators as refractory wear or failures inevitably results in reduced production efficiency and furnace reliability. Also the cost to industry is considerable and only a thorough understanding of all the complexities of the process will help to minimize that cost. One of the critical questions to overcome is the correct selection of refractories for the individual process steps to provide long and predictable refractory life together with high furnace availability. To understand the nature of the reactions involved in refractory corrosion, it is crucial to determine the complex thermo- chemical equilibria of the reactions occurring between the refractory materials and the process phases. A simulation model coupled with commercial software like FactSageTM is demonstrated aiming to understand the corrosion mechanisms between refractories and the molten process phases and draw implications for improving the performance of refractories and refractory lifetime. INTRODUCTION The extraction or recycling of valuable materials, e.g. metals, can be done by two main routes, pyro- and/or hydrometallurgical processing, depending on the chemical behavior of the used ore, scrap or pre-treated concentrate. Sometimes it is also necessary to use both process routes for the extraction or the recycling of valuable materials. In the case of a pyrometallurgical treatment, the usage of refractory materials is inevitable. This is mainly caused by high temperatures, prevailing during processing. The interaction between refractory material and slag, metal or matte leads to different reactions and interactions. As a main result corrosion of the furnace lining (refractory material) takes place. Hence, recurring furnace shutdowns occur for renewing the refractories. This leads to reduced production efficiency. Such refractory lifetimes are between some hours and decades, depending on the processes.

Jan 1, 2019

By Per Hedvall, Jan-Eric Ståhl

"The main objective of this study is to introduce the new Sandvik’s production cost-model within Crushing & Screening (C&S) technology. So far, there have been different ways of determining different production costs in the industry, however, the previously published and presented methods have not been very efficient in calculating the costs per product and metric ton. Accordingly, the current study has been planned and started in collaboration with Lund University to provide an accurate and easy to implement cost estimation program to determine the costs for crushing and screening plants worldwide.The proposed model has been adapted to fit the C&S processes of different rocks/ores fractions. The result is presented as cost per ton of the end product(s).Within this paper the cost estimation results for 3 different crushing and screening plants are presented based on the information obtained from the following sources: a) documents at Sandvik SRP, b) Sandvik’s crushing & screening internal/external machines/plants data and information, c) literature studies, including the use of Sandvik’s internal/external simulation and software programs, d), visiting the crushing and screening plants ,e) interviews, information systems’ data, and, f) testing and observations by ourselves.In order to improve the level of accuracy and the validity of the attained results, simplistic Monte-Carlo simulations have been used, where needed. The achieved results, so far, have proven the reliability of the model. The calculated cost estimations have shown an accuracy over 80% when they compared with real cost data obtained from plant practices.The current cost calculation model, will offer the possibility of:•,Calculating the production costs in proposed and/or existing C&S plant.•,Making detailed cost analyses for the end product(s) in proposed and/or existing C&S plants.•,Determining the profitability of each finished product when it’s required.•,Cost optimization by potentially cutting the cost for part of C&S plant with an existing plant practice"

Jan 1, 2016

By S. A. Kenzap

Risk & Uncertainty ? Uncertainty about a situation can often indicate risk, which is the possibility of loss, damage, or any other undesirable event. Most people desire low risk, which would translate to a high probability of success, profit, or some form of gain. Risk = Likelihood x Consequence Risk is the possibility of loss, damage, or any other undesirable event.

Oct 1, 2010

By J. Erik Scheel

Overview ? About Hard Creek Nickel ? Turnagain property ? Proposed power line ? Recent Preliminary Assessment ? Favourable economics ? Property Geology ? Mineralization and metallurgical characteristics of major lithologies ? Development of the acNi (ammonimum-citrate H2O2) technique ? Overview of necessary steps ? Results of the technique ? Conclusions

May 1, 2008

By LeRoy A. Thorssen

The use of lightweight aggregate as a constituent of concrete is not a recent development. Pumice was used by the early Romans, in pozzolana cement concretes, in the construction of many of their works. However, the recent development of manufactured lightweight aggregates, such as the expanded shales, vermiculite and perlite, has created a possible use for a whole new group of Portland cement concretes. Concrete can now be produced with unit weights ranging from 30 to 150 pounds per cubic foot and with various insulating, fireproofing, acoustical and structural properties. The tonnage of such materials being used has increased considerably in each of the past ten years, and can be expected to increase for the next several years as availability of the aggregates becomes more widespread and the properties of such concretes become more thoroughly investigated and more generally known. LIGHTWEIGHT aggregates of many types have become avail-able to the construction industry in most localities on this continent

Jan 1, 1963

By R. W. Seedsman

In 1984 and 1985, two 7.6m diameter TBM tunnels were driven from the Donkin-Morien peninsula in Nova Scotia to access the Harbour coal seam. The design of the ground support was based on identifying zones of rock failure through the application of the Hoek Brown failure criterion and the early use of finite element analyses. In 1992, the mining project was abandoned and the tunnels allowed to flood. Monitoring data from the tunnel was subsequently used as a case study in the development of the concepts of brittle rock behaviour. In 2007, the tunnels were pumped out as part of a feasibility study into the reintroduction of longwall mining into the coalfield. There is a good match between observations of the collapse zones in the roof and sides of the tunnel and a simple elastic analysis using brittle parameters, a spalling limit of 5, and a low independent shear modulus. The brittle analyses form the basis of the design for the resupport of the tunnels.

May 1, 2009

By A. Mukherjee, C. Kelly, B. Markovich, G. E. Agar, G. E. Robertson, F. Khan, B. Shea

"Laboratory batch flotation tests were performed on a sample of bulk slow cooled converter matte (Cu:Ni = I) to optimize the time in each of the separation stages. Numerical simulations were carried out to estimate a continuous circuit material balance for the conditions selected. An experimental simulation of a continuous circuit (locked cycle test) readily came to steady state and there was reasonable agreement between the numerical and experimental results. The use of nitrogen as the flotation gas and the addition of collector to the grinding mill minimized the oxidation of chalcocite, which has previously resulted in increasing circulating loads, and led to a stable circuit with very low weights in the recycle streams.IntroductionINCO Limited developed a flotation process for separating the components of copper-nickel matte [Sproule, Harcourt and Rose 1945; Sproule, Harcourt and Renzoni 1960] in 1945 to replace the Orford process and continues to use the flotation process in almost the original mode to this day. Initially the matte processed was the result of smelting a nickel concentrate that analyzed about 12% nickel and 2% copper and all of the recycle material that was generated in the smelting process. The matte generated analyzed about 25% copper and 53% nickel, roughly 2: 1 nickel to copper. This matte was blown in Pierce-Smith converters to be sulfur deficient in order to produce a metallic phase that collected the precious metals contained in the smelter feed [Wilson and Stratton-Crawley 1991]. This process continued with little change until 1994 when the separation of chalcopyrite from pentlandite in the Copper Cliff mill was discontinued after 63 years of operation. As a consequence of the elimination of the primary separation of chalcopyrite from pentlandite in the milling process a bulk concentrate was produced for smelting. Bulk concentrate smelting came into practice in 1994 as part of the initiative to meet government legislation that restricted the emission of sulfur dioxide to the atmosphere. Previously, the copper concentrate was smelted in an INCO oxygen flash furnace which resulted in the capture of a high strength sulfur dioxide stream from which liquid sulfur dioxide was produced. Nickel concentrate was smelted in reverberatory furnaces that produced low strength sulfur dioxide gases which were difficult to treat. The action taken by INCO to meet the environmental constraints was to smelt a bulk concentrate in oxygen flash furnaces which would produce gases suitable for the production of liquid sulfur dioxide and another stream that was high enough in sulfur dioxide to be readily converted to sulfuric acid [Bell et al 1990]. The end result of this decision was that all the copper-nickel separation would be done in the matte separation plant."

Jan 1, 1996

By J. B. Heslop, D. S. Bubar

"The Gondor Zn-Ag-Pb-Cu deposit is a stratabound massive sulphide lens occurring within Archean volcaniclastic rocks of the Yellowknife Supergroup. The deposit is located in the west-central portion of the Slave Structural Province, approximately 350 km north of Yellowknife.Initial diamond drilling at Gondor has outlined a steeply dipping, L-shaped, folded, massive sulphide body, which may be traced over a strike length of approximately 800 m, and to a depth of 350 m. True widths of up to 40 m have been intersected in the thickest part of the deposit. Preliminary estimates suggest that the deposit contains a minimum of 7.5 million tonnes grading 6% Zn, 50 g/tonne Ag and less than I% combined Cu and Pb. In addition, significant gold, grading up to 2.8 g/tonne, occurs in some parts of the deposit. The mineralization is open both down-dip and along strike.The Gondor deposit lies conformably within a predominantly east-west striking, north-facing sequence of felsic to intermediate volcaniclastic rocks. Coarse fragmental rocks are abundant in the hanging wall, whereas ash and lapilli-tuffs predominate in the footwall. The main structural feature in the area is a large-scale, steeply northeast-plunging, Z-shaped fold. The sulphide mineralization lies within the synformal portion of this fold, with the thickest part of the deposit coinciding with its hinge zone. Several episodes of faulting have also affected the local stratigraphy.The wallrocks of the Gondor deposit were hydrothermally altered prior to the onset of medium-grade regional metamorphism. A halo of altered rocks surrounds the massive sulphide lens, with no apparent difference in the degree of alteration between the hanging wall and footwall strata. The alteration zone is characterized by the addition of MgO and K20 and by the depletion of Na20 and CaO. These changes are reflected in the mineralogy of the altered wallrocks by local enrichment in chlorite, biotite, muscovite and cordierite.The mineralized zone is medium- to coarse-grained, well-banded and is composed largely of pyrite, quartz, and sphalerite with subordinate galena and chalcopyrite. Preliminary studies of metal distribution indicate that a lateral zonation is present, with lead enrichment in the central part of the deposit, and copper enrichment toward both ends. Stringer-type copper mineralization has not yet been discovered in the footwall of the Gondor deposit."

Jan 1, 1985

By Chandrakala Kari, Divyang Shah, Lakshmi Kanth Reddy, Kaushik Vakil, Sanjay Sarkar, Bhavin Desai

Gases rich in sulfur dioxide generated as a by-product of smelting and converting operations of copper concentrate contain selenium apart from zinc, lead, copper, cadmium, bismuth, antimony, and arsenic. The gaseous stream is heat exchanged in waste heat boiler, dust collected in electrostatic precipitator followed by cleaning in reverse jet scrubber to remove fumes, halogens and fine dust before passing to DCDA Monsanto catalytic converter to produce commercial grade sulfuric acid. The gas cleaning section of the acid plant uses water to scrub the smelting gases. During scrubbing, precipitated solids, known as sludge, settles at the bottom of the reverse jet scrubber containing 30 to 40 wt% copper and selenium up to 40 wt% selenium. In the existing process, the sludge collected during scrubber cleaning process is directly recycled to the smelter for copper recovery. However, the selenium is expected to again vaporize due to high oxidation potential during smelting and converting, causing accumulation of selenium in sludge. In present investigation, a roasting process has been developed to recover the selenium from acid plant sludge before charging it to smelter for copper recovery. Selenium is associated with copper in acid plant sludge as copper selenide, as determined by X-ray diffraction and electron microscopy. Thermodynamic and thermo-gravimetry study revealed that the copper selenide phase present in the sludge was amenable to oxidation at 600°C forming oxides of copper and selenium (Cu-Se-O). However, the dissociation of selenium from the copper oxide was made possible by sulfatation using sulfur dioxide between 450°C to 600°C, resulting into the formation of CuSO4(s) and SeO2(g). Lab scale experiments were carried out in vertical tubular furnace to determine the optimum roasting conditions with respect to roasting time, temperature and molar ratio of O2:SO2. Using these optimum conditions, selenium up to 90 wt. % in the form of SeO2 vapors could be recovered from the acid plant sludge in a large scale commercial roaster. Roasted sludge free from selenium and containing oxides and sulfates of copper could now be recycled in the smelter for copper recovery. INTRODUCTION There is an increasing demand for minor metals due to their use in innovative technologies. Similarly, the increase in demand for selenium is expected due to disruption in sectors related to renewable energy and photovoltaic battery. Selenium is a chalcogen and a non-metal with black or red crystalline appearance. Selenium is used in the glass industry to decolorize glass and to make red-colored glasses and enamels. It is also used in solar cells and as a photographic toner. Selenium is used as a brasses in stainless steel to improve its machinability. Selenium sulfide is used in anti-dandruff shampoos. In spite of the toxicity of its compounds, selenium is also an essential trace element for humans and animals. Selenium occasionally occurs free in nature, but more often occurs as selenides of iron, lead, silver and copper. There is an urgent need for the development of new methods for selenium recovery from the existing resources. Commercially, selenium is obtained only from anode mud produced during electrolytic refinery of copper.

Jan 1, 2019

By W. L. Uglow

In recent years, the microscope has come to be recognized as a valuable aid to engineers whose business is the discovery, development, concentration or reduction of metallic ores. In many of the large treatment plants microscopical research has already an important status; and in the hands of efficient operators the microscope has indicated methods of solving ore problems resulting in the saving of thousands of dollars that otherwise might have been lost in tailings, or expended in freight rates or smelter charges. Failure to procure all the information that the microscope can supply concerning the physical and mineralogical characteristics of complex ores has in many cases led to the construction of unsuitable concentrators, just as the failure to investigate in detail the geological conditions of an ore deposit has often results in the squandering of money on shaft sinking, and mechanical installations which subsequent development of the deposit failed to justify. The great progress recently made in the selective separation of minerals by means of the various processes of flotation and leaching brings strongly to our attention, the scope of the field in which microscopical methods may be advantageously employed. The microscope enables one to observe the minute details of rock, ore, gangue, concentrate, tailing, matte, slag and metal, that are invisible to the naked eye. Furthermore, the technique of microscopal research has been so highly developed that a microscopist can not only observe, but deter-mine the compositions and measure the diameters of the mineral constituents in the ore to be treated. Magnifications of these constituents up to 3,000 diameters may be produced by the proper combination of eyepiece, objective, and projection apparatus, and the images thus viewed may be photographed through the microscope, and permanent records made of them.

Jan 1, 1924

By J. H. Bernard, K. Žák

The three traditional types of Variscan vein Pb-Zn-(Ag) mineralization recognized in the Bohemian massif from historic paragenetic studies are confinned by modem metallogenic studies. Stable C, S, and O isotope data, as well as Pb and Sr isotopic ratios of the deposits, indicate a predominantly crustal origin of the constituents in all three types. Although the data also suggest differences in temperature and pressure of formation, and the oxidation conditions and nature of the hydrothermal fluids, nonetheless they are consistent with prevailing metallogenic classifications of the vein mineralization

Jan 1, 1992

By Bradford P. Simser

The theoretical capacity of various ground support components can be misleading, especially in bursting ground where the failure mode is often in the retainment system. Wire mesh screen seams often peel open rather than breaking the wire strands, fractured rock often un-ravels around the bolts rather than breaking the bars. If a weak link(s) in the system fails prematurely, then the potential capacity of the system may never be fully realized. Underground observations are used to show how some support systems behave in the field. Various combinations of wire mesh screen with friction bolts, rebar, modified conebolts, cablebolts, shotcrete and mechanical rockbolts are considered. A short case history is used to contrast the performance of ?just-intime? development in a high stress faulted area versus a tunnel subjected to multiple stress changes in a similar environment. The latter proved to be a serious ground support problem when the well developed fracture zone around the opening was subjected to dynamic loading from a large seismic event causing a severe rockburst. In such cases an improved mining strategy may be more relevant than higher capacity support systems.

Feb 1, 2008

By Lloyd Buckingham

"The operating cost of a gold mine employing granular activated carbon to recover gold can be greatly affected by the condition of in-circuit carbon and its attrition losses. To accurately identify and quantify carbon losses requires careful study. Carbon attrition in the mill can be attributed mainly to physical or mechanical breakage due to the transfer of carbon in the circuit and to carbon oxidation and thermal fracture occurring in the carbon reactivation kiln. Of the equipment involved in carbon transfer, the water powered eductors are the major cause of abrasion and should be replaced with pumps or alternate methods that can serve the purpose. This paper also reviews the impact of carbon stripping and washing on overall operations.IntroductionHolt-McDermott Mine operates a 1360 tonnes per day Carbon-in-Leach (CIL) mill to recover gold. The relatively high carbon consumption and high remaining gold values on carbon after stripping were viewed as a challenging project for research. Extensive metallurgical testwork was initiated to reduce these values. Figure 1 below indicates the carbon flowchart prior to any significant changes in the carbon handling procedures.Carbon consumption after commissioning which was as high as 10""/o of carbon eluted, has been brought down to less than 5%. Changes that brought about this 50% reduction in carbon consumption are:1 ) Improvements in kiln operation2) Elimination or replacement of eductors3) Reduction in tonnes of carbon eluted"

Jan 1, 1994

By J. P. Bennett, K. S. Kwong

Slagging gasifiers are used to produce chemicals and/or electricity from feedstocks such as coal and/or petroleum coke. A gasifier environment includes pressures from 400 to 1000 psi, temperatures from 1250-1550°C, are cyclic, reducing gases of CO and 112, and molten ash that interacts with the refractory liner materials. The high Cr2O3 refractory liners of gasifiers fail within 3 to 24 months. Gasifier users seek materials with increased reliability and service life. This paper discusses causes of refractory failure and efforts to increase refractory service life.

Jan 1, 2004

By Laxman (Lucky) Amaratunga, Hisham Madi

Final disposal of mine wastewater neutralization sludge continues to be one of more pressing problems in the mining industry. The disposal of mining and metallurgical waste products into underground reduces the environment impact and improves the safety of the mining operation and the economics of the enterprise. This current research focuses on an investigation of utilization of mine wastewater neutralization sludge obtained from Kidd Creek Mine site, as a supplementary material for their proposed deep mine pastefill system. Their proposed pastefill consist of combination of rock aggregate in a matrix of imported sand and tailings with binder (Portland cement + Slag cement). Pastefill mixes containing various percentages of the waste sludge 0 (control mix), 1, 2, 3, and 5% by weight as replacement to the fine sand were prepared and tested with different percentages of binder. Hypothesis behind this approach is to study the behavior of sludge as replacement of sand in matrix as well as its ability to act as a binder. Compressive strength, percentage of sludge, binder dosage, slump, water to cement ratio, percentage of solid, and curing time are being observed. The results indicated that sludge can be incorporated into the pastefill and enhance its strength without compromising the pastefill quality and integrity.

Jan 1, 2004

By Joel Werner

Weak metal prices, declining head grade, and increased operational costs are forcing many open pit mining companies to look to their balance sheets for significant cost reductions in order to remain competitive. Maintenance continues to represent a significant proportion of the total operating costs in the mining industry. Compared with the other major cost components of the mining process very little effort has gone into maintenance optimization. The potential payoff from maintenance optimization on the cash cost of the commodity is enormous. A large percentage of these costs are incurred in unscheduled maintenance events, which typically cause serious disruptions to the production process. These maintenance induced production losses can be a significant contributor to the overall operating costs. A structured proactive maintenance approach using the latest advances in technology can achieve dramatic cost reductions and productivity improvements. Remote condition monitoring systems are becoming increasingly commonplace and have the potential to identify problems prior to failure. Detection of equipment degradation prior to failure will enable repairs to be scheduled thereby reducing costs and interruptions to production. Remote condition monitoring technology has evolved rapidly in recent years, with a host of new tools becoming available to assist mine operators in improving their maintenance operations. These tools have capabilities such as: remote real-time vital signs and performance monitoring, alarm/event handling, trend analysis, and maintenance workflow management. When these monitoring tools are used in conjunction with a mine management system the vital signs data can be integrated and associated with maintenance history, predictive maintenance data, operational information, and geographical information. This integrated approach to the management of vital maintenance data will help shift the mobile equipment maintenance paradigm from reactive to proactive. This paper will introduce a proactive approach to the management of the maintenance process and the tools required to facilitate this process.

May 1, 2003

By William E. Stanley

The paper examines the problems that arise in undertaking socio-economic impact studies to meet the requirements of environmental-impact legislation governing new mine development or expansion. An approach to undertaking socioeconomic impact studies is outlined, responses to specific problems are discussed and ways in which the mining company can use these studies to meet its general objectives are explored. The paper concludes by examining how a socio-economic study, as required by legislation, can be used to assist the mining company in achieving some general objectives it will have in developing a mine.

Jan 1, 1979

By D. S. Conochie

The world is poised for rapid growth in consumption as large, less developed economies acquire greater wealth. It might be expected that there would be a corresponding growth in waste generation, but this might not necessarily be the case. The metallurgical industry has an excellent record of process development which has allowed it to provide a high tonnage supply of low cost, high quality metals. Environmental challenges have been faced and indeed the recycling of scrap iron through the electric arc furnace has made a massive contribution to cleaning up obsolete structures and equipment of past generations. Issues in waste generation and processing still remain, and the expectation for cleaner processing and environmental performance continues to rise. The waste impact of key process developments of the last century and the recent developments in metallurgical waste processing in Canada will be outlined. The potential to use state of the art design tools to produce the next generation of zero waste processes will then be explored.

Jan 1, 2004

By Trevor McGiddy

"Australia's prosperity relies significantly on income generated from exports of resources and agricultural products. In 1989-1990, coal was Australia's most valuable export commodity, contributing. A $5.7 billion or 14% of all export income.The abundance and quality of its coal resources and the proximity of Australia to the rapidly developing economies of Southeast Asia were significant factors that encouraged export-oriented growth and investment and will continue to do so. On the other hand, the 1980shighlighted the sensitivity of the industry to international changes in supply and demand, currency and socio-political forces.Following many years of disappointing returns for investors, mainly as a result of falling Australian dollar coal prices, resolve will be necessary to maintain competitiveness with resource-rich nations. In recent years, operators, unions and governments have begun to embark on a long overdue rationalization of domestic issues in a bid to increase productivity and reduce costs.The nature of mining operations is also changing; deeper surface mines and the growth of longwall mining will require the development of new technology and skills. Other challenges emerging from the international environmental debate will require that Australia responds appropriately to demands for cleaner fuels, energy efficiency and environmental responsibility.The future development of the Australian coal industry will therefore be influenced by its own ability to become more efficient and mature in the production of quality coal products and through rational international response to environmental questions."

Jan 1, 1992

?NWCC has the highest number of Aboriginal students of any post secondary institution in BC and the region served includes 25 bands ? Chair of the Board of Governors is Irene Seguin (Hagwiloo K?am Saxwhl Giis) from Gitwinksihlkw ? FN council ? 39 First Nations Members * focus is to develop policy recommendations to increase student success rates

May 1, 2009