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By Adam Turcotte

Mining operations consume a considerable amount of energy, and while reduced energy consumption is desirable, it is not always clear how to achieve this goal. Understanding the opportunities to optimize energy consumption is crucial, and the key to understanding is visualization. One option is the Sankey diagram, which has been used for over 100 years to visualize the flow of energy, materials, or cost through various processes. However, there are drawbacks to this approach that must be addressed. In a Sankey diagram, each flow is represented by an arrow possessing a width proportional to the magnitude of the flow it represents. The diagrams show input flows, how energy is converted and into what form, and also output flows. As per the first law of thermodynamics, the total energy output is equivalent to the total energy input, so any energy that is not transferred to another process is considered to be wasted. These waste flows are depicted in Sankey diagrams and make it straightforward to associate energy sources, sinks and waste flows. Unfortunately, Sankey diagrams do not convey all information required to support practical decision making for redirecting individual energy flows. Based only on a Sankey diagram, it may become evident that a significant flow of waste heat is of the appropriate grade (temperature) and volume to meet an on-site heat demand currently being met with paid-for, possibly carbon intensive fuel. However without augmenting the Sankey diagram with 3D spatial, true geometric analysis, the practicalities of the concept or idea may not be fully appreciated. Another issue with a Sankey diagram is that the magnitude of the energy flowing between processes may have temporal fluctuation or variability on different timescales (diurnal, seasonal, interannual). Currently, Sankey diagrams only provide a static picture of energy conversion and consumption, so that, for example, 4 separate diagrams could have to be prepared for each season. A new energy flow visualization technique which we have called Sankey Trees has been developed. Process locations are defined within a 3D model of the site being studied, and the magnitude of the flow between each pair of processes considered is replaced with a time series. Branches of sustained and diminishing flows are represented through variation of the geometric properties of the branches of the trees. These branches are animated to indicate the direction of flow, and branch joints are used to indicate that a process is transporting one form of energy to multiple processes.

Aug 1, 2013

By J. P. Morgan, D. B. Stewart

"AbstractLoad-haul-dump machines equipped with. a torque converter and hydraulic pumps have been field tested by means of an engine monitoring instrumentation package. It was found that owing to parasitic losses in the ancillaries and drivetrain, maximum available useable pourer may peak at less than full engine speed. Simple reduction of engine speed may save 15 to 25 percent on fuel consumption, with no significant loss of available power. On some machines, speed reduction will require modification of the torque converter . The cost of this modification, when necessary , would be offset by reductions in exhaust emissions, ventilation requirements, fuel consumption , heat, noise and hydraulic system maintenance, and by increased life of rotating components and filters and machine availability.IntroductionTHE CANADIAN EXPLOSIVES ATMOSPHERES LABORATORY, in conjunction with Deutz Canada Limited, has designed, constructed and field tested a portable instrumentation package. This package monitors diesel engine performance in underground mining machinery by continuously recording engine speed and volumetric fuel delivery. During tests designed to determine the engine load and speed conditions for the various segments which constitute actual underground operation of a Deutz F6L 714-powered 4-yard load-haul-dump machine, it was discovered that an unexpectedly large percentage of the engine power was required to overcome the ancillaries and drivetrain drag (1). That this large component of engine power is functionally related to engine speed rather than the operator's needs was verified by repeat tests of the used 4-yard machine and by testing of a new 5-yard machine powered by a Deutz F 8L 714."

Jan 1, 1977

By D. C. Rance

"The Quintette Coal Limited property is located in the northeast coal area of British Columbia.A basic agreement with the Japanese steel industry was executed on January 27, 1981 for the sale of 69.5 million tonnes of Quintette metallurgical coal over a 14.5-year period. This contract period can be extended by five years by mutual agreement. Sale agreements have also been signed for the sale of 19.4 million tonnes of oxidized coal over a 15-year period.Work started on site development in the late summer of 1981, and at present, two of the four eventual pits-the McConkey and Frame-are under development.The pits are currently in a prestripping phase. These pits are notable for the stripping volumes that have to be removed from relatively small pit areas. In order to provide for the required detailed rapid short-range planning of these pits, engineering will be computerized, as will the truck dispatch system.The mining area lies 21.1 km from the plant site by road and the transport of raw coal to the plant is by means of a high-speed conveyor system which has a total length of 13.4 km with a vertical drop of 740 m.The surface plant facility was designed on a modularized basis to facilitate maintenance, and is designed to enable the use of gravity f low of raw coal and heavy media in the plant to minimize the use of pumps.The construction of the plant and mine site facilities is ongoing, and the first coal production is scheduled for early December 1983.IntroductionQuintett e Coal Limited is a Canadian company incorporated in the province of British Columbia in 1971. Denison Mine s Limited is the manager of Quintette's activities. Equity in Quintette Coal Limited is held by several shareholders, with interests as follows: Denison Mines Limited, 50%; Charbonnages de France International S.A., 12%; and Japanese interest, 38%."

Jan 1, 1983

By J. S. Roper

"IntroductionSNOW LAKE is situated in northern Manitoba at latitude 54° 55 and longitude 100°, 400 miles northwesterly of Winnipeg, 80 miles northeast of The Pas, 80 miles east of Flin Flon. A 38-mile road from Wekusko, on the Hudson's Bay railway, serves the community.The mine is located in and close to the southern edge of the Precambrian Shield in typical low-relief muskeg and lake country.The Howe Sound Exploration Company, Limited optioned the property from Nor Acme Gold Mines, Limited, after preliminary diamond drilling had outlined two orebodies of low-grade arsenical gold ore.Following the examination and study of geological data and of 50,000 feet of diamond-drill core, and metallurgical tests made during 1942 to 1945, a decision was made to develop the mine and build a 2 ,000-ton mill concurrently. This development has been described by G. C. Lipsey in a paper entitled The Development of a Mining Operation from Diamond-Drill Data which was published in the August. 1952, issue of Mining Engineering.Geological Features of the OrebodiesThe orebodies at Snow Lake occur in volcanic rocks of acid to basic composition and, to a lesser extent, in intrusive hornblendite. The hornblendite is a massive, uniform, .coarse-textured rock except in the immediate vicinity of the ore zone, where it becomes sheared and carbonatized. The acid volcanics have been converted to quartz-garnet-biotite gneiss, and the basic volcanics to amphibolite gneiss. Orebodies have been formed by the replacement of all three rock types."

Jan 1, 1955

By E. Busse, J. E. Burgener, J. G. Eacott, M. C. Robinson, P. E. Burgener

"This paper presents a preliminary assessment of the technical and economic feasibility of a caustic leach - electrowinning process for the recovery of zinc and lead from electric arc furnace baghouse dust at a mini-steelplant. Recent studies and literature are referenced briefly as they pertain to the formation and characterization of dust, toxicity considerations and alternative dust treatment and disposal options.Laboratory testwork results, published data, pilot plant experience and anticipated influences resulting from recycling residues are used for the purpose of developing a conceptual design for a caustic leach - electrowinning plant to treat 15,000 tonnes/year of dust at a one million tonnes /year capacity steelplant in Canada.Target economic studies, comprising preliminary estimates of capital and operating costs, revenues and rate of return are presented. Economic and commercial considerations concerning the relative merits of dust treatment at a centralized facility compared with an on-site plant are discussed.IntroductionThe treatment or disposal of mini-steelplant electric arc furnace (EAF) baghouse dust has been given increasing attention in recent years for two principal reasons. Firstly, the dust is now classed as a hazardous waste material under V.S. EPA regulations which prohibit its disposal in dumps other than controlled landfill sites. Secondly, the dust contains certain metal values, notably zinc and lead, which may be economically recoverable, depending on the costs associated with disposal resulting from enforcement of the EPA regulations. Other metallurgical dusts and waste materials, from both ferrous and non-ferrous operations, may require the same considerations as EAF baghouse dust.Several studies have been carried out to examine various aspects of dust treatment but few commercial plants are in operation. Technology employed uses pyrometallurgical techniques. Commercial-scale hydrometallurgical plants are not known to exist although small-scale plants are frequently more economically attractive than their pyrometallurgical counterparts which generally require economies of scale to be viable.The concentration of mini-steelplants in northeast V.S.A. and southeast Canada merits study to determine whether or not dust treatment for metals recovery is a commercially feasible alternative to disposal.This paper examines the technical and economic feasibility of a caustic leach - electrowinning process for the recovery of zinc and lead from EAF baghouse dust at an on-site ministeel plant processing carbon steel scrap and discusses economic and commercial considerations pertaining to dust treatment at a larger, centralized facility."

Jan 1, 1984

By J. S. Kirkaldy, W. J. Slater, G. R. Mason

Activation analysis for copper and manganese in 10 mg samples machined from aluminum-base diffusion couples has been used in the study of ternary diffusion in the Al-Cu-Mn system. The accuracy, economy and convenience of the method are considered to be very competitive with other methods for analysis of such small samples. Neutron-activated aluminum-zinc alloys in the range from 10 per cent to 100 per cent zinc have been equilibrated with a known volume and the vapors subsequently condensed and collected. The vapor pressures relative to pure zinc (the thermodynamic activities) have been determined at 550°C' by recording the relative count of /'-rays from zn65 in the collected samples. The method is a sensitive one, although subject to serious obstacles to experimental accuracy.

Jan 1, 1961

By Y. Serres

In the past, conventional reflection seismic techniques were not very successful when applied to typical mining exploration: they lacked resolution in the shallow range or were not cost effective. By combining a light earth tamper source, special geophones and field procedures, a stacking process of the returning seismic events using a microprocessor system, and a sophisticated sequence of adapted digital data processing, Mini-Sosie achieves high resolution in the 100-ft to 4000-ft range. Additional advantages result from the very quiet nature of the source and flexibility of the system. Although Mini-Sosie might be used in the refraction mode, or for well velocity logging, it has found its main applications with the reflection technique.

Jan 1, 1978

By Roy T. Bowles

This paper focusses on technological developments which occurred in the village of Deloro, Ontario between 1868 and 1919. These developments illustrate the manner in which improved metallurgical processes linked Ontario mineral resources to industrial expansion. Overview of Deloro The village of Deloro is in Hastings county, about 5 miles from the village of Marmora, the site of the old Marmora iron works and the more recent Marmoraton iron mine. In this area, the Canadian Shield meets the Great Lakes lowlands. The first settlement in the vicinity occurred in the 1820s and was associated with the Marmora iron works. Settlement grew around agriculture. Gold was discovered in Hastings county in 1868. Deloro - the name derives from gold - developed as a concentrated settlement in proximity to several gold mines and the related processing activities. By 1901, substantial smelting works were successfully producing gold and arsenic from local ores. The village was developing as a company town within the framework of benevolent paternalism. For reasons associated with markets and with local ore supplies, the Deloro mills were idle for a period beginning in 1902. Developments in later periods connected Deloro to world events. In 1903, silver was discovered at Cobalt, Ontario. By 1907, M.J. O'Brien, who owned mines at Cobalt, had purchased the Deloro works and was using them to process Cobalt-area ores*.

Jan 1, 1999

By Frank S. Palkovits

Over the past 30 years, underground paste backfill systems have been implemented across the globe in many configurations, each with a primary focus of providing high quality backfill to enhance mine operations. However, a number of key design drivers are not always well understood within design engineering firms that occasionally undertake this work, leaving opportunities on the table. Perhaps not always obvious to those newly embracing paste technology, identifying key drivers and opportunities attainable through a paste backfill system is generally not straightforward, requiring innovative approaches to securing higher productivity, availability, performance, maintainability, and operator health and safety. This paper describes a number of applications and audits of paste backfill systems for several challenging mine operations. Key challenges include iterative design aspects of availability of good backfill materials, plant location and configuration, general arrangement, and binder receiving/storage systems.

Oct 1, 2010

By George B. Saunders

It is the purpose of this paper to point out conditions as they exist in the merchandizing of coal, to compare these conditions with methods in use by competitive producers of coal substitutes, and to present briefly some suggestions which may help the individual operator to market more coal in the immediate future, while we are waiting for the scientist and research worker, who are now busy on coal betterment , to produce in a practical way the results which they now write about in such glowing terms. While it may be unnecessary to call the attention of coal operators to the present deplorable condition of the industry, it might be well to impress upon our members in other branches of mining, as well as upon the public at large, the seriousness of the situation. Emerging from the war and the period of reconstruction that followed, the coal industry found itself with too many mines and too many men for normal conditions. To make matters worse, the interruptions in deliveries caused by strikes, the unfavourable publicity caused by socialistic propaganda, and the repeated governmental investigations, made the market a fertile field for coal substitutes which were not so handicapped. These substitutes were well advertised, and were marketed in an up-to-date manner, furnishing an example from which the coal operator could well profit. Now, whether or not there is agreement as to the cause or causes of this condition, there can be no doubt that we are today face to face with the fact that the sale of coal has not kept pace with the sale and use of other commodities. Had it done so, we would ere this have been able to take care of the surplus labour and work our mines at least approximately full time.

Jan 1, 1929

By Orlando Rojas, Javier Pizarro, Romke Kuyvenhoven, Francisco Soto

"The concept of geometallurgy has been extensively mentioned and used in the mining industry in the past years. However, each mining firm has a different understanding of what geometallurgy means, and its actual value varies significantly from site to site. Even in the case of properly constructed geometallurgical models, it is fairly common to observe a sub-utilization of the model in the actual operation, because of its low production forecasting capability on the short term. This disconnect between the geometallurgical model and operations is typically caused by a lack of tuning between the original model and the actual plant operation. Also, the absence of procedures and other standards for reconciliation, affects the confidence and the predictive quality of the model. The geometallurgical model should consist of three different levels: (I) adequate capture of information, (II) data analysis and modelling, and (III) development of the block model. Once the geometallurgical in-situ model is finalized, a process model should be developed of the plant at industrial scale, in order to scale up the in-situ geometallurgical parameters from their base or standard condition, to the actual operating reality of the plant. Finally, the stage of reconciliation will close this process, assuring that any deviation between the geometallurgical model and the actual plant operation is not due to lack of tuning, but due to operational issues such as unattended maintenance requirements or poor process control in the operation. The methodology as described in this paper has been applied at several large mining sites in Chile. The paper presents the characteristics of the proposed methodology, and quantitatively describes its benefits with examples from actual operations.INTRODUCTIONIt probably is fair to say that geometallurgy became widely used in greenfield projects in the Andes region during the mining boom of the 90’s, when massive orebodies were studied and developed, and upfront metallurgical characterisation proved its use for accurate economic evaluation including estimates of plant throughput, energy consumption, final product quality and overall recovery. A few examples of such greenfield studies for concentrator plants in the 90’s are Minera Los Pelambres (Antofagasta Minerals, Chile), Minera Escondida, Laguna Seca (BHP Billiton, Chile), and Rio Blanco (then Montterrico Metals, Peru). Large size hydrometallurgical operations such as Cerro Colorado, Quebrada Blanca and Lomas Bayas (all in Chile), also recognised early on the importance and value of relating ore mineralogy, geological characterisation and metallurgical behaviour."

Jan 1, 2016

By Lifeng Yang, Xiang Zhang, Liang Yuan, Yonghui Wang, Bing Hou, Mian Chen, Rixing Zhang

Large-scale hydraulic fracturing technique has been widely applied to the development of shale gas reservoirs, where the interaction between natural fractures and critical fracture zones has substantial impact on the propagation of hydraulic fractures. Therefore, it is of significant importance to understand and experimentally verify such mechanism. To reach this end, tri-axial fracturing tests were implemented on 400mm×400mm×400mm block samples collected from Longmaxi shale outcrops. The interplay between hydraulic and natural fractures was investigated during the tests, factoring in the role of pump rate in affecting the created fracture network. Based on the experimental results, the critical fracture zone, defined as the weak formation zone nearby the wellbore created by staged pressure implementation that is observed rapid fracture propagation upon next stage of pressure increase, was thoroughly investigated. The analysis illustrates that given the high brittleness of the shale formation, abundant critical fracture zones are generated around natural fractures with pressure building up at a relatively low pump rate. As the pump rate increases, hydraulic fractures initiate and come into play with critical fracture zones, implying emergence of a large number of micro-cracks. A changing pump rate modifies the way of interaction between hydraulic and natural fractures and the subsequent formation of fracture network. Long term fracturing fluid injection with relatively low pump rate below the activation of critical zones is suggested. Also proposed is appropriate timing when applying a specific pump rate that will contribute to the improvement of hydraulic fracture propagation.

Jan 1, 2015

By Sean Hillacre, Arthur Lieu

NexGen’s approach to uranium processing design including the crushing/grinding and leaching of raw ore through to yellowcake precipitation and tailings management focuses on minimizing surface footprint, freshwater consumption, and human radiation exposure. Applying the concept of best available technologies economically achievable (“BATEA”), NexGen continues to research, evaluate, test and validate various advanced technologies that can be incorporated into the Project design, including distinctive tailings storage techniques. Additionally, NexGen is proposing that tailings generated from the mill processes be used as cemented paste backfill of stopes, as well as stored in a purpose-built, Underground Tailings Management Facility (“UGTMF”) comprised of several dedicated chambers. The paste backfill method of tailings storage is used globally, however, constructing purpose-built tailings chambers in waste rock is a new concept in uranium mining, which would typically be cost prohibitive for most projects given the expense to develop non-economic material for the sole purpose of storing tailings. The Rook I Project is uniquely positioned to implement the UGTMF due to robust Project economics and favourable technical setting which provides NexGen with the opportunity to set an elite standard for tailings management. When compared to conventional surface tailings management facilities, storing tailings underground as cemented paste reduces geotechnical, geochemical, environmental, and human health risks associated with tailings management. Additionally, the UGTMF vastly reduces the area of surface disturbance and allows for progressive decommissioning during the life of mine operations.

Jan 1, 2020

By Thomas Kilpatrick

The liability created by building this railway is the great financial problem before the people of British Columbia at the present time. In dealing with the subject, I propose to divide it into three periods: The Past - The Present - and The Future. The Past The primary objects in building the railway were to provide an independent and direct route for the Grand Trunk Pacific railway into the city of Vancouver, and to open the central and north-eastern portion of the province.. This vast territory, almost one-half the entire area of British Columbia, has great wealth in fruit, agricultural, and grazing lands; timber, coal, water-power and minerals of all kinds, including some of the richest placer deposits in the world. Rivers and lakes teem with fish. Big game, including moose, elk, caribou, deer, grizzly and black bear, mountain goat and sheep, is plentiful and there is an abundance of small game and fur-bearing animals. In addition, its scenic attractions are unsurpassed in Canada. To develop these resources it was considered necessary to build a railway from south to north as a main artery of transportation and, if necessary, branch lines to carry heavy .shipments of coal or other commodities. Lighter freight may be handled by motor trucks from distant points to the railway.

Jan 1, 1925

By Yasser Mohamed

Daily field management of earthmoving operations requires quick and regular decisions for allocating available equipment to different jobs on a project. A general foreman?s day starts with matching several activities with a suitable set of available equipment to achieve the highest productivity and lowest unit cost. Usually, this decision-making process needs to be quick, and depends to a great extent on the foreman?s experience, which varies from one individual to another. Many analytical solutions with various degrees of sophistication and optimization exist to address such decisions. However, adopting any of these solutions is contingent on how accessible and easy-to-use the solution is. This paper discusses the development process of a webaccessible solution for evaluating earthmoving fleet composition and allocation scenarios. The solution relies on discrete event simulation and an optimization backend engine, but introduces the user with a simplified and easy-to-use interface that is accessible from any mobile device, and is customized to specific user?s needs. The developed system gathers most equipment and site-related input data from a company?s information systems to minimize user input. The user mainly needs to formulate equipment and job combinations and allocation scenarios (e.g. soil type, quantity, and hauling distance), according to equipment availability each day. Then the system will evaluate the productivity and unit cost estimates for each scenario, allowing the user to choose the most suitable one. It may also be used to automatically recommend the optimum solution given an available list of equipment. The paper presents the process followed in prototyping the proposed system in collaboration with a major Canadian earthmoving contractor, and customizing it to the user needs within the company. It also describes the overall structure of the developed system and its core simulation model.

Aug 1, 2013

By A. Danaei, A. McLean, M. Barati, C. Ravindran

"The aluminum industry generates about 90 million tonnes of red mud each year. Previous research shows it could be utilized as a refining flux with a high capacity to absorb phosphorus and sulphur from hot metal in the steel industry. The present study was undertaken to evaluate the melting properties of such fluxes, as it affects the effectiveness of the flux. The results show that the melting behavior of red mud is strongly affected by lime addition and the characteristic melting/softening temperatures reach minimum VALUES (at 32.7 wt% CaO. From these findings, a correlation was established between melting behavior and optical basicity. This allows one to adjust the composition of the flux based on the process requirements. INTRODUCTIONThe aluminum industry generates about 90 million tonnes of bauxite residues each year. This residue is usually red in color because it contains a substantial amount of iron oxide. The red mud, as it is called, is a solid waste with a high concentration of sodium oxide, high pH (10 to 13), and high alkalinity, and thus is harmful to many forms of life. Traditionally, the material is stored in large tailings ponds within the plant’s vicinity (Power, Grafe, & Klauber, 2009). Development of solutions for safe disposal or preferably using this residue for other industrial processes or applications could help restore polluted locations and eliminate a negative impact on the environment (Haake, 1988; Power et al., 2009; Yan & Xuegong, 2010).The mineralogy and chemical composition of red mud depends on the quality of the bauxite and refining process parameters. In general, it consists of iron oxide (Fe2O3), aluminum oxide (Al2O3), titanium oxide (TiO2), sodium oxide (Na2O), silicon oxide (SiO2), and calcium oxide (CaO) (Power et al., 2009). Like most ores and soils, bauxite can contain trace quantities of metals such as arsenic, beryllium, cadmium, chromium, lead, manganese, mercury, nickel, and naturally-occurring radioactive materials, such as thorium and uranium. Most of these trace elements stay in the residue (Power et al., 2009)."

Jan 1, 2012

By Z. I. Zaki

Synthesis of TiC /A1203 Composite from TiO2, Al and graphite using combustion technique has been investigated at different initial temperatures; room, 400 and 600 °C. The effect of initial temperature on the composition of the product, wave velocity and combustion temperature of the reaction was studied. The measured combustion temperature and wave velocity were increased with increasing the initial temperature of the combustion reaction. The maximum wave velocity obtained was 5.9mms-1 when conducting the combustion reaction at initial temperature of 600 °C. Oxidation resistance of the obtained composite was also studied at the temperature range 300-800 °C. No oxidation is detected before 400 °C while it takes place effectively at 700 °C forming different titanium oxides. Wave velocity measurements method was used to calculate the activation energy of the reaction between the starting materials. It was found to be 316.34 kJ mol 1 at the temperature range that was studied.

Jan 1, 2007

By Raymond Dallaire

The Humphrey's spiral is a static gravity separation device which cannot be adjusted to match short-term variations that occur in the feed. Any disturbance in the feed grade, per cent solids or flow rate affects substantially the recovery and grade of concentrate. Such variations must be minimized in order to maintain the desired rate of production and quality of the product for which the installation has been designed. A study has been performed in which the foregoing assertions were quantified. The feed grade, per cent solids, flow rate and particle size were varied independently. Ore from Carol Lake, Nfld., was used throughout the experiments. This consisted of specular hematite and magnetite in a silica gangue.

Jan 1, 1978

Stellite-6 coatings were formulated on two Ni-base superalloys, namely Superni 75 and Superni 600, by a shrouded plasma-spray process, and the oxidation behaviour of these coatings has been investigated in air and in an aggressive environment of Na2SO4- 60%V2O5. Accelerated oxidation tests were conducted in a silicon-carbide tube furnace under cyclic conditions at an elevated temperature of 900°C for 50 cycles. Each cycle consisted of 1 h heating and 20 min cooling in air. A thermogravimetric technique was used to approximate the oxidation kinetics. The corrosion scales were characterised by XRD, SEM/EDAX and EPMA analysis. It has been observed that the coatings nearly followed the parabolic rate law of oxidation. Overall weight gain conceived in air was just 51% of that in the aggressive environment in the case of coated Superni 75, whereas in case of coated Superni 600, the cumulative weight gain in air was found to be one-third of that in the Na2SO4-60% V2O5 atmosphere. Furthermore, the coating showed very good adherence to both of the substrates during the course of air oxidation, whereas some superficial cracks were observed near the edges of the specimens during the molten salt induced oxidation. XRD analysis revealed the presence of phase-like CoO, CoCr2O4 and Cr2O3 in the oxide scales, which are reported be protective against high-temperature oxidation. The XRD results were further supported by SEM/EDAX and EPMA.

Jan 1, 2005

By M. B. Mansur, A. S. Guimarães, A. J. M. Santanilla, D. C. R. Espinosa, J. A. S. Tenório, R. A. Pini

The separation of Ni and Co from sulphate medium containing Mn, Mg, Cu and Ca was carried out by solvent extraction. The object of this study was to investigate the synergistic effect using phosphinic acid (Cyanex 272) and carboxylic acid (Versatic 10) and their mixtures in kerosene. The extraction percent of each metal ion was found to increase with increasing pH and extractant concentration. Co was preferentially extracted over Ni under the same extraction conditions. The separation factors of Ni/Co increased with the use of the synergistic systems investigated.

Jan 1, 2014