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By Hoberg H, Schnieder FU

The disposal of residues from coal preparation and processing will to an increasing extent require investigation and consideration of the environmental problems resulting as a consequence of this. Different authors (Diingelhoff and Plankert, 1983; Hasenpatt, 1985; Szczepanska and Twardowska, 1987) have concentrated primarily on the content and the mobilisation of inorganic contaminants such as chlorides, metals and heavy metals from spoil tips, while no publications have yet been found on the question of a possible emission of organic contaminants (PCB, PAH, HC HC) from processing residues. Here the flotation residues in particular are able to bind larger quantities of organic contaminants by physi-sorptive means because of their large specific surface and, after disposal, to be re-emitt than into the environment. The flotation agents used in coal flotation are mixtures of technical distillation products with a correspondingly fluctuating composition. As Hey, 1986 showed, they may contain, in addition to the main components (n-alkanes, alcohols, surfactants), over 50 individual trace substances. In conjunction with the structural-chemical similarity of the individual components, this complicates the quantitative analysis of individual components considerably. For the analysis of hydrocarbon content of flotation products by means of extraction with organic solvents in accordance with DIN 38408, H18, the difficulty arises, besides the insufficient sensitivity at low concentrations, that geogeonic hydrocarbons are extracted from the coal as. well and the analysis results are thus falsified. These problems were overcome by the application of the 14C radiotracer method where certain components of the flotation agents are marked with radioactive carbon (14C). By measurement of the radioactivity of solid and liquid samples, the concentration of the marked substance can be measured very sensitively and precisely, whereby the accumulative measurement of similar organic substances is ruled out. Thus the reaction path of certain substances in complex reagent mixtures such as flotation agents can be traced excellently and the conceivable environment burden resulting from flotation tailings disposal can be estimated. In this paper, the adsorption behaviour of typical components of coal flotation agents are investigated for different coals and types of gangue material, the reagent content of flotation concentrates and tailings, as well as the mobility of the reagents adsorbed onto solids. The knowledge of adsorption and desorption mechanisms of unpolar hydrocarbons emulsified in water to solids are also of particular interest for the understanding of processes of organic soil contamination and for the further development of washing processes for oil-contaminated soils.

Jan 1, 1993

The decrepitation technique is a rapid means of measuring abundances, temperatures and to some extent the fluid compositions, of fluid inclusions in transparent and opaque minerals. The method has been used to investigate the hydrothermal fluid systems associated with gold mineralisation in the Tennant Creek, Pine Creek and Halls Creek Goldfields. At the Enterprise Mine, Pine Creek, several different stages of quartz veining are distinguished and within these, gradational changes in fluid temperatures and compositions help to define the centre and nature of the thermal system responsible for the mineralisation. In the surrounding Pine Creek region and at Tennant Creek and Halls Creek, the results were applied on a regional scale to characterize outcrops and aid in the discrimination between potentially mineral- ized and barren outcrops. The decrepitation method involves the heating of a small (lgm) sample of crushed and sized grains up to as high as 800 degrees celsius. During the heating the fluid inclu- sions within the grains develop sufficient internal pressure to physically burst, the temperature of such bursting being dependent on the type of fluid and the prevailing tem- perature at the time the inclusion was originally trapped. The resulting tabulation of the number of inclusion bursts per 10 degree temperature interval is plotted as a histogram of decrepitations versus tempera- ture and called a decrepigram. The decrepi- grams frequently show several distinct peaks at different temperatures which are caused by different populations of inclusions in the sample. The areas of the peaks indicate the abundances of inclusions in each population while the shape and mean temperature of the peak provides a guide to the type of fluids involved. Of particular importance in this study is the presence of decrepitation peaks at fairly low temperatures (around 2000 C. These are characteristic of C02 rich fluids which build up internal pressure very quickly when heated. The Enterprise Gold Mine at Pine Creek comprises a number of overlapping quartz vein systems hosted by Burrell Creek Formation sediments. The geology of this mine has been described at this conference by Dann and Delaney, who have defined several distinct stages of quartz veining based on structural, mineralogical and physical features of the veins. For this decrepitation study, 19 quartz samples from the mine and environs, including some from each stage of veining were collected. These results suggest that there are 4 major vein types, within 3 of which additional small variations can be discerned which are due to gradational changes in the temperatures and fluid compositions in the mine area.

Jan 1, 1984

By Brathwaite RL

The gold-scheelite-quartz lodes of the Wakamarina valley were the most productive of the mesothermal gold-bear in the Marlborough Schist. Most of the production came from the Empire City and Golden Bar mines which worked tug, Golden Bar lode. Only 134 m of its 1800 m strike length are accessible, in the No. 2 level of the Golden Bar Mine. A fau I has downthrown the Golden Bar Mine section by 2 47 m and displaced it left-laterally by 18 m. The lode is a typical ribbon-banded mesothermal vein, averaging c. 1.75 m wide, and enclosing narrow horses of schist country rock. It i composed of bands of milky "buck" quartz with thin laminae of schist. Scheelite occurs in short strings of grains withi quartz on the footwall side of the lode and also in small quartz-carbonate veinlets in the foot wall and hanging wall schist The lode quartz contains only localised traces of pyrite and arsenopyrite. They are more abundant in the wall-rock schist.

Jan 1, 1995

IA )W cli',hla cn1cnt fault 7011(-s 0 11Cn cOrnprise a nrc,II of inrcIIinkc(I faults, cvtcnqonal shear and In]rck cxtcnsir>nal vein- fractures. Hydrothermal mineralisation localised around such structures testifies to their importance as conduits for fluid flow. Mesh structures are most commonly developed in situations approximating bulk pure shear but predominantly simple shear meshes also occur. They appear to develop through the infiltration of pressurised fluids into a heterogeneous rock mass with varying material properties. In some circumstances, mesh formation appears to be a precursor to the development of major throughgoing faults. Mesh formation generally involves hydrofracturing (Pf> a3, at least locally) and the condition Pf - 63 to be maintained for the mesh to remain a high permeability conduit, requiring fluid overpressuring at other than shallow depths in extensional-transtensional regimes. The volumetric character of earthquake swarm activity appears to result from the passage of hydrothermal fluids through mesh structures, representing a form of distributed fault-valve action along suprahydrostatic hydraulic gradients arising from magmatic intrusion, compaction overpressuring, metamorphic dewatering, etc.

Jan 1, 1995

By Jimbo I, Ogawa O

A series of experiments was carried out to investigate the solubilities of copper, arsenic, antimony and bismuth in silica-saturated iron silicate slags under controlled oxygen partial pressures at 1200 and 1250¦C. Molten copper containing each of the above elements was kept in contact with a slag in a silica crucible for 24 or 48 hours to attain equilibrium. No me- chanical entrapment of metal into the slag was observed. The appearance of the magnetite phase in the slag was avoided by holding oxygen potentials at substantially lower values than that evaluated from available data on iron silicate slags. Solubilities of copper, arsenic, antimony and bismuth in slags were plotted against oxy- gen potentials and both oxidic and atomic types of dissolution were found, except in the case of arsenic, from the dependencies of the solubili- ties on the oxygen potential and from positive intercepts of regression lines when extra- polated to zero oxygen potential. The dissolu- tion of arsenic seemed mostly oxidic. Distri- bution coefficients of arseò,ic, antimony and bismuth between copper and slag are also Discussed.

Jan 1, 1980

Western Mining Corporation (W.M.C.) operates a nickel refinery at Kwinana, 30 km south of Perth. The refinery commenced pro- duction in May 1970, with a rated capacity of 15 000 tpa of nickel metal. A hydrometallurgical route was chosen as the most expedient way to produce nickel metal at a time when world demand for nickel was outstripping the supply. Later events dictated that an increase in production from the refinery be achieved. To this end, matte produced from Kalgoorlie Nickel Smelter, which was commissioned in 1972, was used in varying proportions as a complement to the concentrate initially utilised as input to the refinery. The effect of matte addition was to increase the capacity to 30 000 tonnes of nickel per annum. This was accompanied by other benefits which were 1. reduction in energy consumption per unit of nickel produced, 2. improved metal extraction, 3. improved precious metal recovery, 4. reduced production of ammonium sulphate by-product. Refinery operating results for the years 1970 to 1983 show how matte feed has improved refinery performance in these areas.

Jan 1, 1984

The cost-effectiveness of blasts involving radiating blastholes is cur- rently restricted in the following ways. (a) Significant percentages of potential explosion energy are not being liberated; the collar sections of some charges are being dislocated and/or desensitised by the detonations of adjacent earlier-firing charges. (b) If the minimum charge spacing is too small, detonation of an early- firing charge can initiate an adjacent charge sympathetically, thereby eliminating the benefit of any intended inter-charge delay. (c) The overall distribution of energy is poor. Appreciably better fragmentation would be achieved if current drill- ing patterns were to be replaced by staggered fans/rings having a toe spac- ing : burden ratio of about 4 : 1. This wide-spaced pattern would enable a higher percentage of the potential energy to be released, would reduce the incidence of sympathetic detonation and would provide a superior overall distribution of this liberated energy. If improved fragmentation is not required, the proposed fan/ring design should allow a significant expansion of the blasthole pattern with consequential cost savings in drill- ing, explosives and initiation.

Jan 1, 1988

German coal mining suffers from rock temperatures up to 600C which are the same as in South Africa at 3000 - 4000 m of depth. Therefore cooling plants have increased in the last decade and today a cooling power of nearly 200 MW is installed in the total Ruhr District. Cooling a mine is a little bit different from cooling a bottle of beer in a refrigerator in the kitchen because the heat taken from the bottle of beer is delivered to the kitchen some centimetres away; in mining the cooling-problem is more difficult: here the bottle of beer corresponds to the airflow at the coal face and the kitchen to the surface, So it is necessary to transport the heat or the "coldness" a long distance. In the address by Ieuan Morris some systems for transporting heat from the coalface to the evaporator of the cooling machine and further from the condenser of the machine to a return airflow were described. The following is a short idea of the way this problem is treated in Germany.

Jan 1, 1983

By Borgelt B. V, Perry A. J, Wellington H. K

There has been little change in the lead smelting practice at Mount Isa since 1939 when the metallurgy and general practice were outline by Raney and Blott.The purpose of this paper is to descriqe some of the operational details that have influenced the overall production. The slag fall hns been increased by the lowering of the lead content of the concentrate. Further, as it is the practice to include iron on the furnace charge and carry a higher lime content in the slag, both factors have produced notable results in furnace operations.All blast furnace gases are filtered in a baghouse and this unit is. being further extended to take all smelter gases, thus eliminating the existing Cottrell plant handling Dwight-Lloyd gases.The lead smelter was closed down from April 1943, to May 1946, during which time blister copper was produced.The report is subdivided as follows:-1. Filtering and Mixinga. Effect of calcium sulphate on cloth.b. Dwight-Lloyd charge composition.c. Main mixer.d. Return sintel sizing.2. Blast Furnace Operationsa. Introduction.b. Use of orehearth.

Jan 1, 1953

By Abdalla MH

The deformation resulting from the presence of a tunnel may signifcantly affected, nearby structures and need to be considered during design of both tunnel and structure. The aim of this paper is to study the effect of different factors which may affect the interaction between the tunnel and the str- ucture. These include; the depth of both tunnel and foundation level of the structure ( z and t ), distance between C.L. of tunnel and loads, breadth of the loaded area, Diameter of tunnel and lining of the tunnel. The problem is studied as a two dimensional plane strain model by the boundary element technique. The results of this study indicated that the presence of a cavity/tunnel increases, in general, the vertical displacement on the ground surface and at the foundation level as well as the horizontal and vertical stresses in the cavity/tunnel level. The effect of eccentricity is increasing as e/D decreasing. For pile foundation there is a quite different- influence of the presence of cavity/tunnel in both cases of friction pile and end bearing pile type of foundation.

Jan 1, 1987

By Muir D

A review of the various methods of degrad- ing cyanide either from gold processing liquors or electroplating baths is presented with some discussion on their relative merits or problems. Whilst alkaline chlorination is common practice in many U.S. and Canadian plants it poses particular problems for certain plants. Alter- native methods include electrolysis, hydrolysis and air oxidation with activated carbon as catalyst which are also integral steps in the carbon-in-pulp process. A basic study of the degradation of cyanide ion has been carried out therefore to determine the effect of temperature, oxygen and carbon. It is shown that carbon is an excellent catalyst for degradation by air and likely to lead to higher losses of cyanide in a C.I.L. circuit. Degradation by hydrolysis is important at high temperatures and high pH such as employed in the Pressure Zadra or Anglo elution processes. Carbon catalysed degradation of cyanide by oxygen in effluent streams may be an environmentally acceptable alternative to conventional chlorine degradation.

Jan 1, 1987

Compared with modern longwall coal mining systems, automation has not been developed very far in the underground metal minin industry. One of the main reasons for this is that present har rock mining systems do not produce ore with a controlled degre of fragmentation. The often poor fragmentation from the stopescauses large extra costs and precludes material which 1-ends itself to automationThe paper investigates the possibility c technology for automatic loading and trapconveyor belt to a shaft dump pocket. With this concept, it will be necessary to control the maximum fragment size by careful blasting design. The degree of fragmentation will have to be finer than is common to-day. The study shows that the belt conveyor mining con-cept with controlled fragmentation may be economically competitive with conventional cyclic loading and transport, even for an annual production as low as 0.5 mill. tonnes.. Fragmentation design and cost calculations have been based on a combination of the Kuznetsov relationship between blasting parameters and mean frag-ment size, and the Rosin-Rammler formula for fragment size distribution.

Jan 1, 1985

The use of pipeline-c to carry crude'oil and petroleum pro-ducts is a reliable and economic*Way to transport large quantities of oil. The length and size of these pipelines have continued to grow throughout the world as the demand for petroleum has in-creased and as the price of other transportation-methods has risen. At the present time pipelines 'can move a barrel of oil a distance of 100 miles at an average cost of ,80.06 U.S. dollars.The major elements in pipeline design are discussed. Methods of calculating pressure drop and horsepower requirements are pre-sented. These are variations of standard equations.in which the elements of each equation are expressed in terms common to the petroleum industry. Major equipment is discussed., particularlyas it relates to operation and economics.Cost data are presented to aid in preliminary economic ana-lysis. Curves illustrate the cost of oil transportation at flow rates between 10,000 and 500,000 barrels per day and permit the selection of pipe diameter-which will result in minimum operating costs.

Jan 1, 1962

By L Hussey

Mt Keith concentrator treats low grade disseminated nickel sulfide ore supplied from the adjoining open pit mine. It is a traditional crushing, two-staged closed circuit grinding circuit (SAG & Ball Mills), followed by a complex split-size rougher, scavenger and cleaner flotation circuit. In 2016, 10.5 Mt was milled, at an average head grade of 0.54% Ni, yielding 35 000 nickel metal tonnes in concentrate.Historical analysis of the plant data indicated that of all the nickel lost in the fines rougher circuit tails stream, 25.6% was recoverable in an eight minute laboratory scale flotation test. These results implied that this fine nickel was readily available for recovery in the plant, either through operational improvements or additional flotation capacity. With operation optimisation ongoing, and capital within the business focused elsewhere, plant personnel were challenged to think differently about improving recovery.In 2012, a separate project to improve plant recovery when treating high talc ore was completed. Amongst other vessels, this project saw the installation of two 150 m3 Outotec Cells to the scavenger section of the fines rougher, middlings and scavengers (RMS 1) circuit. Since installation, the operation of these cells resulted in difficulties immediately upstream with instability in the scavenger cells. It was therefore decided that these cells would be better suited to treating the fines rougher circuit tails.The alterations required to divert these flows were minimal, with the capital project totalling $220 000.In the two years since installation, the fines rougher tailings nickel grade has dropped by 9.9%. The scavenger circuit has also seen a 2.8% reduction in tailings nickel grade, and instability issues were immediately resolved. This project serves as a lesson in how existing plant infrastructure may be better utilised to maximise recovery. Although this is especially applicable when capital constrained, such re-appropriation can be considered at any point to maximise return on existing assets. CITATION:Hussey, L, 2017. Repurposing flotation capacity at Mt Keith nickel concentrator, in Proceedings MetPlant 2017, pp 254–258 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 11, 2017

By Williams C

A stibnite concentrate from Golden Spec (WA) was subjected to a series of tests involving high pressure cyanidation and pressure oxidation followed by conventional cyanidation. The concentrate, whose gold content was 18.1 g/t, yielded only eight per cent of the gold when leached directly by a standard 24-hour cyanidation test. The recovery was increased to only 15 per cent when pressure cyanided under the following conditions: ambient temperature, 2000 kPa oxygen pressure, two hour retention time and 30 per cent w/w solids pulp density. This poor response to pressure cyanidation emphasised the refractoriness of the material. Evidence of the fine distribution of the gold through the concentrate, from measurements of the particle sizing distribution and the gold analyses of the individual fractions, also suggested that this concentrate was highly refractory. Pressure oxidation of the concentrate at elevated temperatures followed by cyanidation yielded recoveries as high as 94 per cent. However a preoxidation treatment under the following conditions was necessary: 230¦C, 2000 kPa oxygen pressure for a period of four hours.

Jan 1, 1992

By A S. Ray, P S. Thomas

The characterisation of the surface area and porosity of opals derived from Tintenbar, a volcanic environment, and Lightning Ridge, a sedimentary environment, using nitrogen gas adsorption at -196¦C is reported. Both opal types were found to have relatively low surface areas and displayed little porosity. The low surface areas observed is indicative of the ability of silica to infill voids and interstices. Thermogravimetric analysis of the samples before and after degassing was carried out to determine the amount of water removed by the degassing process. Negligible difference was found in the water content before and after degassing in the case of the Lightning Ridge sedimentary opal, while the Tintenbar volcanic opal was found to have lost more that 60 per cent of its water during the degassing process. These differences were ascribed to the differences in the silica structure of the opals with the Lightning Ridge opal having a denser cage structure, which traps the molecular water, while a more open structure is postulated for the Tintenbar opal, allowing the water to be relatively easily removed.

Jan 1, 2008

By N N. Viswanathan, D Kumar, S Kumar

In secondary steelmaking, calcium treatment is practised to modify the solid alumina or spinel inclusions into liquid or partially liquid calcium aluminates. It has been seen that the dissolved calcium reacts with sulfur or oxygen present in the steel to form CaS or CaO type of transient inclusions. Post-calcium treatment these transient inclusions further react with pre-existing alumina or spinel inclusions and modify them. In addition, direct modification of pre-existing inclusions is also reported in the literature. In the present study, laboratory-scale induction furnace-based experiments are carried out to melt electrolytic iron in an alumina crucible followed by deoxidation with aluminium. The CaS-based composite material, prepared in-house, is added after the aluminium deoxidation to study the stability of CaS at the steelmaking temperature. Multiple steel samples were also taken to track the dissociation of CaS by means of sulfur pick-up in steel. Additionally, inclusion analysis of these steel samples was also performed to track changes in the chemical composition of inclusions in response to CaS addition. It has been seen that the CaS dissociates leading to a gradual pick-up of sulfur in steel. The scanning electron microscope – energy dispersive X-ray spectroscopy (SEM-EDS) analysis reveals that the alumina crucible and floated alumina inclusions are modified into calcium aluminates and the extent of modification depends on the contact time of CaS with the two sources of alumina mentioned earlier. However, the modification of alumina inclusions in the bulk steel did not occur during these experiments.

Jun 19, 2024

In late 1987 it was recognised that column flotation might have potential for improving the grade of the zinc concentrate produced at Pasminco's South Mine in Broken Hill. Intermittent test work was carried out during 1988 using a 90 mm diameter by 6 m high perspex column, built and initially operated by staff from CRA Advanced Technical Development. This column was found to have insufficient retention time so, during the first half of 1989, Pasminco constructed and installed a 200 mm diameter unit of the same height. Extensive testwork was carried out using this column during the latter half of 1989 and early 1990. It was clear from the results that a grade improvement of between 1 and 2 per cent (absolute) would be achievable. The effect of column cleaning on overall recovery was not established with the same degree of confidence, so the proposed new circuit is to include one of the existing banks of OK8 cleaner cells as a scavenger on column tailings. The test work provided sufficient data for preliminary design work to begin in May 1990 and commissioning of full scale zinc cleaner columns is planned for mid 1991. This paper summarizes the results and describes some of the experiences with column flotation at the Pasminco South Mine.

Jan 1, 1991

The report by Baker (1958, p. 27) of krennerite in contact with gold in a specimen from the 2500 ft level, Phantom South lode, Great Boulder mine, Kalgoorlie, led the writer to look into this further, since Cabri (1965) reported that the assemblage krennerite-gold was unstable between 238° and 356° C, and possibly down to room temperature.Dr. G. Baker very generously provided the writer with two chips from the same rock specimen (No. 14 as labelled from the mine) in which the krennerite gold assemblage was reported to occur. These were examined by polished section and x-ray diffraction techniques and returned to the classified collection of the Mineragraphic Investigations Section of CSIRO.One specimen, showing visible gold, was examined optically with a binocular microscope and telluride material was twice removed from contact with the gold for x-ray diffraction. This material proved to be petzite and so amends a statement by Baker (1958, p. 39) that no petzite was found in the Phantom lodes.The second chip was polished, and microscopic...

Jan 1, 1967

THE object of this paper is to offer some suggestions to assist metallurgists to supervise the operations of flotation plants. We do not yet thoroughly understand what "flotation" is or "why minerals float" and all attempts that have been made to explain the phenomena have been based on theory or imagination, and have not been capable of substantiation by practical demonstration, or even by laboratory tests; but it is wellknown that particular minerals will float in a liquid under certain specified conditions, and that some other minerals will not float under those conditions, and that, if a mixture of the two classes of minerals be subjected to those conditions, there will be separation of the minerals, of which one class will float and the other will remain unfloated as a residue. The duty of the flotation expert is to so control the operations and the conditions of the liquor as to obtain the best commercial result from the ore he is treating. The chief controlling factors in a flotation plant appear to fall under the following eight headings, all of which are important:1. Crushing.2. Rate and regularity of feed.3. Density of pulp.4. Temperature.5. Addition agents.6. Condition of circuit liquor.7. Agitation.8. Aeration.

Jan 1, 1920