Search Documents

The AJ Parker Cooperative Research Centre for Hydrometallurgy is the focus of a world-class effort in providing technical solutions to the minerals industry. The 85 FTE staff are drawn from the CentreÆs five joint venture research partners comprising universities (Curtin, Murdoch and Qld) and government research agencies (CSIRO and WA Dept of Industry and Resources). There are also 12 industry partners, representing most of the leading mining companies in the world. Around 45 postgraduate students, mainly PhDs, make a significant contribution to the research effort. Total annual expenditure on R&D is around $17 million.Hydrometallurgy activities encompass both fundamental and applied research across the alumina, gold and base metal sectors. The Centre is now growing its client base into overseas markets, particularly North America, South Africa and Europe. Quality, strategic R&D by the Parker Centre is seen by the industry as an attractive investment. A recent survey of the industry revealed an estimated ten-fold return based on direct costs of research to the client. In addition, the Parker Centre has a strong commitment to education of postgraduate students wishing to enter the mining industry as well as providing specialist courses for those technical professionals already employed in the industry. The wide range of employment opportunities in the mining industry is reflected in the diversity of the disciplines amongst the CentreÆs research team, eg extractive metallurgy, chemistry, biotechnology, physics, engineering, molecular modelling, microscopy, geology and computational fluid dynamics. How does an atomic force microscope and molecular modelling improve our ability to control gypsum scaling or understand crystallisation of alumina in a Bayer plant? Can a biologist contribute to the problem of the slow leaching of copper from chalcopyrite? Why are computational fluid dynamics and lasers the basis of understanding how to make thickeners work more efficiently. Can you combine a PhD or Honours degree with industry experience? What is crud and why is nickel stressed? These are typical examples of the CentreÆs research activities and demonstrate the contributions of its multi-disciplinary teams which keep the Australian mining industry at the cutting edge of advanced global technology.

Jan 1, 2003

By T Tan, C P. Holmes, C E. Hartford

Transportation of iron ore from the mine to the plant is critical to business success. Ore from the mine may have to be transported across states, countries and even continents to get to the processing plant or export facilities, and ultimately to the client. Numerous transportation steps may result in potential logistical difficulties. Companies are continually seeking ways to increase production rates, decrease delivery times and reduce operating costs. Transportation cost is a major component of the total cost of mining iron ore and therefore requires effective use of transport systems.Bottlenecks in iron ore transport systems, due to material handling issues, can result in loss in profit in the order of millions of dollars per hour. Bottlenecks can be seen anywhere in the transport system where the desired flow rate cannot be achieved. These bottlenecks occur for various reasons such as increasing throughput in a transport system originally designed for a lower throughput resulting in plugged transfer chutes, changing material characteristics (eg finer material, increased moisture content), changing to a new type of material or blend that again alters handleability, or changes in operational philosophy due to equipment availability or process utilisation.Stockpiles may have limited live capacity such that an adequate amount of ore may not be readily reclaimed when required (eg to fill a complete train’s railcars). In bins and hoppers, material may discharge through a central flow channel resulting in the formation of a stable rathole, which can then collapse causing material to flood the downstream system and cause significant downtime for clean-up (eg railcars beneath train load outs). In transfer chutes, bottlenecks can be caused by pluggages or downtime required for the change-out of liners due to excessive wear. In ship loading, long settling or de-aeration time, or material exceeding its transportable moisture limit (TML) may result in further bottlenecks. These bottlenecks all have associated costs because of the need to address their causes and because of the lost opportunities for throughput.This paper will discuss how bulk material technology and proper understanding of material flow characteristics can be applied to mitigate bottlenecks. It will discuss how to predict potential bottleneck locations through a scientific method of analysis and evaluation to determine if an increase in throughput of an existing transport system is possible, as well as whether or not a new material will flow reliably through an existing system.CITATION:Hartford, C E, Holmes, C P and Tan, T, 2015. De-bottlenecking iron ore transportation from mine to plant, in Proceedings Iron Ore 2015, pp 393–398 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

Mining epitomises the challenge of sustainable development, because few sectors have such a direct impact on the natural environment, yet few are more important to the economic and social health of almost every region in the globe. In a global industry, with increasing competition for exploration and mining investment dollars, sustainable development must also be resolved within an international competitiveness framework. In formulating a response to the challenge of sustainable development, the State and Federal Governments do not fully appreciate the extent to which technology drives the solution on a range of issues. In some cases` a dangerous fatalism about the state of science has led to an unhealthy æstop productionÆ attitude that puts our industry and economy at risk. As a technical institute representing the professionals in the minerals sector, The Australasian Institute of Mining and Metallurgy (The AusIMM) sees one of its roles as being to highlight the way in which industry innovation can facilitate solutions. The AusIMM is currently evolving a greenhouse gas emissions policy. As a case study it throws into sharp relief the way in which irresponsible ælimits to growthÆ policies could have a negative impact on the sustainability of the sector, as well as the importance of a technology- based solution. With 80 per cent of greenhouse gas emissions in the next twenty years projected to come from developing economies, such as India and China, major reductions will only be achieved if cost-effective, low emissions energy technologies are deployed in developing countries, and more energy efficient processes of producing key commodities for them are brought online. As a supplier of the key energy resources and materials that will be in high demand to feed developing economies, and with knowledge intensive industries with excellent R&D links across mining and manufacturing, Australia is well positioned to contribute to develop key low emissions technologies. However, we will only be able to take advantage of this position if the Federal Government commits to a holistic greenhouse emissions policy that does not penalise industry. We need effective æpushÆ polices aimed at leveraging investment in low emissions R&D that are closely linked in to æpullÆ policies aimed at stimulating technology uptake.

Jan 1, 2006

By H M. Parker, G Verly, T Postolski

Assessing the uncertainty and risk in mineral resource estimation is required for best practice and is implied by the public reporting codes in the categorisation of mineral resources and reserves. One industry best practice is quantifying the risk on future production for a given period, which can be done using two geostatistical approaches: conditional simulation and drill hole spacing studies based on estimation variances. Conditional simulation can provide a more complete and flexible answer to the problem, but it takes a fair amount of time to complete. Drill hole spacing studies are simpler, faster and can provide reasonable assessments of mineral resource uncertainty.This paper is a presentation of the principles, theory and practice of drill hole spacing studies. Various types of risk assessment are considered. Difficulties encountered in practice are discussed, and solutions are proposed. The important parameters impacting the results are reviewed. Examples of results and sensitivities are shown.CITATION:Verly, G, Postolski, T and Parker, H M, 2014. Assessing uncertainty with drill hole spacing studies – applications to mineral resources, in Proceedings Orebody Modelling and Strategic Mine Planning Symposium 2014, pp 109–118 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 24, 2014

By T Wambeke, J Benndorf

A risk-robust development of a heavy mineral resource requires an assessment of the geological uncertainty and spatial variability of the key factors impacting the mining and processing operation. Attributes of interest are the total heavy mineral grade, the slime content and the amount of oversized particles. The modelling of a mineral sand deposit presents two main challenges. Firstly, the exact location of the geological boundaries are obscure due to the complex interaction of the deposit formation processes. Secondly, the properties of interest exhibit a rather complex transitional behaviour across the so-called soft boundaries. Traditionally, the modelling exercise is restricted to a consecutive stochastic simulation of distinct geological facies and orebody properties. This results in different zones separated by hard boundaries, ignoring the typical transitional behaviour.This contribution presents an alternative approach which models the entire sand body as a single domain while accounting for the complex trends present. Error curves are used to infer covariance model parameters without the need of a prior removal of the trend. The principle is based on minimising the differences between empirical and theoretical errors resulting from two methods of prediction calculated for different rings of influence. The added value results from the unambiguous decomposition of the spatial variation into a deterministic trend and a stochastic residual. The trend model neither overfits nor underfits the data. The calculated residuals are thus unbiased and the uncertainty can be correctly assessed.The effort results in a characterisation of the resource uncertainty which provides a more realistic image of the spatial variability of the key properties in and across the geological domains of an existing heavy mineral sand deposit.CITATION:Wambeke, T and Benndorf, J, 2014. Optimal inference of modelling parameters to simulate complex trends across soft boundaries – a case study in heavy mineral sands, in Proceedings Orebody Modelling and Strategic Mine Planning Symposium 2014 , pp 73–84 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 24, 2014

By P Ramsaywok

The use of saline water for mineral beneficiation in arid regions is general practice and also the case with Exxaro Namakwa Sands, situated on the west coast of South Africa. Although it is ‘cost effective’ to use sea water for mineral beneficiation, downstream process separation efficiencies may be negatively affected. This is more specific to surface dependent separation techniques such as electrostatic and high tension (HT) separation. If minimal fresh water is available then, proper washing is often neglected. Salt crystals can form on particle surfaces during the drying process before electrostatic separation.This paper describes a study that has been conducted to determine the effect of upfront salt water processing on downstream electrostatic/HT separation. The study indicated that minor quantities of salt can cause the separation efficiency to decrease substantially.

Oct 5, 2011

By Corbett GJ

The Bulolo Graben represents an intra-arc rift formed by activa- tion of transfer structures in an extensional setting formed be- tween the eastern and western sectors of the New Guinea Origin. Crustal thinning has facilitated the emplacement of dacitic Edie porphyry intrusions, locally as flow dome complexes, phreatomagmatic (diatreme) breccias and the Bulolo ignimbrite/ agglomerate as an extrusive equivalent of the Edie Porphyry. Gold mineralization is localized along intra-graben structures, com- monly at the intersection with cross structures and occurs in sub- sidiary dilational fractures and not the localizing major structures. Gradations are apparent in the styles of mineralization according to the degree of erosion of the hydrothermal system. Hamata occurs as the deepest mineralization of the quartz-sul- phide style Wau, Hidden Valley, and Edie Creek are dominated by carbonate-base metal styles. Kerimenge grades from quartz sulphide through carbonate-base metal to epithermal mineraliza- tion, the latter style also being present in the periphery of Edie Creek. Here, pre-existing fractures of the Edie Creek Structural Corridor have been reactivated by movement on NS structures to form the ore-hosting dilatant lodes. Fluid flow may have been from the vicinity of the Nauti diatreme margin and along the vein System.

Jan 1, 1997

By J Levett, O Rondon, I Glacken

Reporting Codes are not prescriptive on methodologies to report or classify Mineral Resource Estimation results, but the assessment of risk and uncertainty is required, and is likely to be increasingly important in future Code updates. The 2012 JORC Code indicates that relative confidence in tonnage-grade estimations should be considered for classification, and that there should be a discussion of relative accuracy and confidence levels in the Mineral Resource Estimate. These considerations are also relevant to the drill hole spacing required for various classification categories, along with other geological and data quality criteria. This paper summarises the theory, principles and current practice of various drill hole spacing analysis techniques for both achieving a desired level of resource categorisation and for optimising grade control or resource drill-out costs. The authors provide practitioners with a guide in their use to assess uncertainty and relative accuracy, as illustrated by a number of case studies. While all drill hole spacing studies rely on the assumption of consistency of the continuity model from current to future drilling, the range of methods available provide much more objective outcomes than previously adopted ‘rules-of-thumb’.

May 24, 2023

For the last 4 years political leaders have found a new subject on which they can safely generalize wihout creating opposition. That sub- ject is commodity prices. Since the four-fold increase in OPEC crude oil prices, public atten- tion has focussed as never before on the subject of commodity prices. To advocate stabilizing com- modity prices is akin to supporting motherhood or peace or better schooling. Everyone gives lip service to the concept that stable commodity prices are desirable. It is easier to state the principle than to achieve it. Prices that are stable in terms of one currency may be clearly unstable in terms of a different currency. This has become a troublesome matter since 1971, when the world's leading trading currencies were set free to float in relation to each other. To illustrate: consider copper prices in the interval between the end of 1974 and the end of 1977. During those 3 years, the copper price in pounds sterling on the London Metal Exchange rose by 25 per cent. During that period, however, in terms of the USA dollar equivalent, the price was unchanged. And during that period, in terms of the German mark equivalent the price shrank by 13 per cent while the Japanese yen equivalent f.11 1k

Jan 1, 1978

By R van Berkel, J Lay, D van Beers

The development of regional resource synergies in intensive areas with concentrations of minerals processing industries provides a significant avenue towards sustainable resource processing. Gladstone (Queensland) and Kwinana (Western Australia) are two of AustraliaÆs major heavy industrial areas. There are a number of successful regional synergies in both areas. In addition to the existing regional synergies in both areas, more potential synergy opportunities appear to exist which, upon implementation, could benefit industry, the environment and the community. To further enhance the development of such potential regional synergies, the Centre for Sustainable Resource Processing (http://www.csrp.com.au) commissioned research projects to facilitate the identification of potential synergies and assist with their implementation in both regions. This paper presents a selection of specific examples from both regions to illustrate the sustainability benefits from regional synergy developments. Although the composition of industries in the Gladstone and Kwinana regions is different both in terms of geography and industry diversity, similarities in synergy developments for both regions are apparent. Consequently, the examples discussed in this paper are organised around the key themes of water, energy and inorganic by-products. Comparison on a theme basis highlights success factors of successful synergies and demonstrates the range of benefits resulting from their implementation.

Jan 1, 2006

By B R. Bittencourt, D A. B Pasin, D Pi

Three main genetic types of hematite can be recognised at Quadrilßtero Ferrffero (QF): Micaceous or schistose hematite derived by metamorphic/metasomatic process during regional metamorphism, increasing eastward, formed under temperatures ranging from 250¦C to 500¦C in CO2-rich aqueous carbonic, high- to medium-salinity fluids. Hematite in shear and mylonite zones, showing a wide variation of fluid and temperature conditions, between metamorphic and hydrothermal conditions. Deformed quartz-specular hematite veins formed during the late phases. Hydrothermal, compact and isotropic hematite developed during a brittle-ductile regime, forming the cement of the boudinage-kink breccia and jacutinga-type of gold mineralisation, under temperatures ranging from 80¦C to 140¦C in aqueous, low- to medium salinity, oxidant fluids, resulting from the interaction of meteoric and metamorphic/metasomatic fluids. Quartz-carbonate-sulfide veins were formed slightly later, through reducing fluids.

Jan 1, 2005

By B Belle

In a deep, gassy predrained coalmine, ventilation and goaf drainage systems act as critical controls to manage longwall (LW) panel return gas levels. The goaf capture efficiency of most LW panels ranges from 45 to 85 per cent based on the gas domain at respective workings. Recent operational experiences have indicated that 50 m goaf hole spacing is optimal for management of high production retreat gassy LW panels, where the probability of goaf hole failures are frequent. Due to the horizontal stress direction geotechnical issues, goaf hole failure just behind the LW face is a recurring challenge resulting in significant and immediate increases in LW panel return gas levels. This paper presents a successful implementation of an innovative LW tailgate (TG) road cut through seal goaf fan/venturi system. The system incorporated a 17' (400 mm cased) hole drilled to 320 m deep in a perimeter roadway on a retreating LW TG road drawing the working seam horizon goaf gas behind the perimeter of seals. The surface goaf fan/venturi system was aimed to safely exhaust the LW deep goaf gas and thus withhold the goaf stream spillage to TG drive area and reduce the panel gas load by controlled operation of the system using continuous monitoring of CH4, CO and O2 levels. This control philosophy was made operational without impacting the use of the perimeter inbye ventilation shaft used for mine cooling and providing additional ventilation dilution capacity. The instantaneous reduction in TG gas levels of up to 0.3 per cent was observed even when the LW was 300 m away from the c/t seal goaf hole. Success of this concept TG seal goaf gas control system used even when the LW was 1300 m outbye has become an inventory of additional control for future deep and long LW blocks. This paper attempts to share the design process in addressing other risks and desired outcomes in managing the LW gas levels.CITATION:Belle, B, 2015. Innovative tailgate mobile goaf gas management in two gate road longwall panels – concept to implementation, in Proceedings The Australian Mine Ventilation Conference, pp 31–40 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 31, 2015

The global economic, political, sociological, and technical environment has become extremely volatile and unpredictable. Price and demand patterns for fuel and non-fuel minerals have become highly variable. Increasingly militant environmental movements now have a material effect on the price, cost and availability of energy sources and indirectly also on non-fuel minerals.The pace of political change in the U.S.S.R., Eastern Europe, and China has accelerated. Western Europe, Japan, and the U.S. are reacting to these changes with varying degrees of confidence or timidity.Technical and economic developments continue to have a substantial effect on the fortunes of the mineral industries. However, they are increasingly influenced by social and political factors. Supply, demand, and trade patterns in the Pacific Rim Region will continue to be influenced by developments in other regions, such as southern Africa

Jan 1, 1990

By Q Yu, G Ren, Z-Y Chen, J Yang

The wedge shape theory of the rock fragmentation range in bench blasting is presented according to the dynamic characteristics of rock fragmentation by blasting in open pit under the condition of hole-by-hole initiation. The finite element software ABAQUS was used to analyse the rock fragmentation mechanism. The rock mass stress contours, crack propagation and damage evolution of different moments were obtained. The results showed that the wedge shape theory of blasting is closer to the rock fragmentation in hole-by-hole blasting and is useful to the design and calculation of charge weight.CITATION:Yang, J, Chen, Z-Y, Yu, Q and Ren, G, 2015. The wedge theory of borehole charge design for bench blasting and its numerical simulation, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 169–176 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

Bacterial leaching of sulfide minerals are fairly well established in heap, dump and in situ leaching and the primary bacterial treatment of refractory gold concentrate using CSTR have gained industrial prominence in recent years. Three cultures, a mesophile T ferrooxidans (DSM583), a moderate thermophile Sulfobacillus acidophilus (strain YTF1) and a extreme thermophile (Sulfolobus strain BC65) were used for the biooxidation (pre-treatment) of the Porgera gold-bearing pyrite concentrate under optimum O2 and CO2 enriched air (30 per cent O2 and ten per cent CO2) based on volume ratios. The positive effect of using oxygen and carbon dioxide enriched air for the biooxidation of gold-bearing pyrite mineral was clearly demonstrated where an increase in Fe release rate by a factor of 2.8, 1.8 and 1.5 for DSM583, YTF1 and Sulfolobus respectively were observed compared with the shake flask tests. The lag phase observed with the other test conditions such as in shake flask or with air decreased by about 80 per cent for all three cultures. The average observed dissolved oxygen concentrations in the pulp for these tests were 8.7, 5.8 and 5.0 mg/L for DSM583, YTF1 and Sulfolobus respectively, indicating that O2 was not limiting in these tests. The pulp redox potential was observed to increase with time for all tests coincident with the leaching rate and reaching a maximum of 663 mV, however the maximum value differs for each strain, with DSM583 exhibiting the highest followed by YTF1 and Sulfolobus. Biooxidation of pyrite under optimum gas enrichment at different pulp densities showed near total Iron extraction occurred for pulp densities of three, ten and 20 per cent (w/v). At high pulp densities, more so at 40 per cent than 30 per cent (w/v), the leaching rate decreased rapidly for tests with YTF1 and Sulfolobus. Monitoring of dissolved O2 shows that O2 demand increased with increasing pulp density and the average dissolved O2 concentration observed for YTF1 and Sulfolobus at 40 per cent solids concentration was 1.0 mg/L and below, suggesting limiting oxygen and carbon dioxide conditions for these two cultures. The decrease in leaching rate observed at high pulp densities (30 and 40 per cent) under optimum gas enrichment was accompanied by low metal dissolution and low redox potential values which was attributed to shear stress due to attrition of cells by high solids concentration, toxicity of metal ions especially Ag and Fe and the formation of precipitates and jarosites as confirmed from XRD analysis of leach residues hence impeding the leaching process. Limiting conditions due to high pulp density and viscosity were only observed for YTF1 and Sulfolobus. The subsequent cyanide leaching for precious metals from the pre-treated pyrite concentrate in all cases shows the extent of gold and silver recovery increased with the degree of pyrite oxidation and Au and Ag recoveries in excess of 80 per cent were achieved compared with only 18.1 per cent and 35.9 per cent for gold and silver respectively when treated by direct cyanide leaching on the original, untreated concentrate.

Jan 1, 2004

By Y-B Kang, J H. Park, J Park

In order to understand the effect of oxygen injection into the molten metal on the valuable metals (VM) recovery and interfacial phenomena, several high-temperature experiments were conducted using a high-frequency induction furnace with a quartz tube as the reaction chamber at 1673 K. Copper-based waste printed circuit board (PCB) that contains some impurities was selected as the end-of-life resource. CaO-SiO2 based pre-fused slag and oxygen gas were used in present works. The composition change and microstructure of the samples were analysed. As oxygen was injected into the system, impurities were rapidly removed. After the removal of impurities, continuously injected oxygen lowered interfacial tension between liquid slag and liquid metal. Lowered interfacial tension induced Cu loss into the slag.

Aug 21, 2024

By Moorrees C

The end uses of magnesia are determined by both its chemical and its physical proper- ties. There is seen to be an increasing need for products of high chemical purity. Prod- ucts containing 90-95 per cent MgO can be routinely produced by physical beneficiation and calcination of most magnesite ores, the dominant source of magnesia. However, pro- duction of grades containing more than 98 per cent MgO with low impurity levels is not readily achieved physically. Such products can only be readily produced by chemical processing techniques. This presentation outlines the types of impurities present in magnesite deposits and the general concepts that are involved in chemically upgrading them. Of the potential leachants, only hydrochloric acid and aqueous carbon dioxide appear to be commercially attractive.

Jan 1, 1987

First of all, I should like to thank you for theopportunity to be with you tonight and tocongratulate the Kalgoorlie and Perth branchesof the Australasian Institute of Mining andMetallurgy in initiating this most importantConference.It could not have been better timed.Gold is riding a crest of the wave, leading theresurgence in the State's mining industry.The strong and stable economic policies whichhave been pursued both by the Burke LabourGovernment in this State and by the HawkeGovernment in Canberra, whilst they have ofcourse only been part of the reason for thestrong recovery in the mining industry - a l o tof it being due t o international factors - havecertainly assisted and ensured that the miningindustry in this state has been able to takefull advantage of the changed world situation.

Jan 1, 1984

Conditional simulation can be used to determine the probabilities of block iron-grades being above selected cut-offs. However, there are much faster alternatives that can produce acceptable results. In this paper blasthole data from a selected area of Joffre Member hosted ore of the Brockman Iron Formation at the Mt Whaleback orebody is used as the basis of a case study to assess alternatives to simulation. Iron grade, in per cent, is interpolated from a blasthole dataset into a block model using ordinary kriging. Samples are then removed from this blasthole dataset to produce data subsets. A complete distribution of iron grades for points or blocks is obtained utilising the data subsets and the following techniques: conditional simulation, median indicator kriging, the probability from conditional expectation and confidence intervals attached to the estimation of blocks in the framework of the discrete Gaussian model. The complete blasthole dataset is considered to represent the true iron grades at sample point support while the ordinary kriging estimate derived from these samples is considered to represent the true block grades. The distributions obtained from point estimates, block estimates and simulations are compared to each other and to the true estimates of iron grades using graphs and statistics. The conditional expectation technique reproduced the results obtained from conditional simulation extremely well and it is a viable alternative to simulation at point support. At block support the confidence intervals technique reproduced the results of the conditional simulation more closely than the median indicator kriging and in the data subsets tested the confidence intervals technique actually reproduced the true grade distribution more closely than the conditional simulation.

Jan 1, 2005

By Nguyen G. H, Graham J

A laboratory-scale fluidised-bed roaster has been used to examine the effect of temperature and duration of roast on the morphology of the calcine produced from a pyritic gold-bearing concentrate. Two mechanisms of oxidation, which depend on the roasting temperature, have been identified. For samples roasted below 550°C, direct oxidation of the sulphide occurred to form hematite with a porous fine-grained concentrically-layered texture. The surface area of the calcine increased with an increase in roasting temperature in the range 400 to 500°C. For samples roasted above 550°C, the first reaction was the evolution of sulphur vapour to produce pyrrhotite, which underwent increasing grain growth as the roasting temperature was increased. This had the effect of decreasing the surface area of the calcine. The pyrrhotite was subsequently oxidised to produce hematite.Leaching studies using cyanide solution indicated that gold extraction around 95 per cent was achieved at temperatures of 500°C and above, with optimum extraction, taking into account rate and cyanide consumption in the range 550 - 700°C. Hence recovery did not decrease with decrease in surface area of the calcine. Observed gold in leached calcines was mainly enclosed in thin oxide walls of the hematite, with minor quantities enclosed in quartz and silicate minerals.

Jan 1, 1995