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By Jürgen Antrekowitsch, Thomas Griessacher

"Heavy metal containing residues are typically hazardous wastes because on the one hand, a deposition gets more and more complicated and on the other hand, the large amounts of metals like Zn, Cu, Fe and Pb represent a significant value. Thus, a post-treatment of these materials with the recovery/recycling of the metals and stabilization of the waste is not only ecological but often also economical. The therefore typically applied recycling processes utilize pyrometallurgical steps, where carbon or carbon monoxide from fossil coal and coke is used as a reducing agent, which results in large amounts of CO2 emissions. An alternative option is the application of a hydrogen-rich gas emitted in biomass utilization processes as a carbon-neutral reducing agent. Investigations in a retort process which were done at different temperatures and times showed excellent results concerning the achievable reduction rates and final contents of the heavy metals for various residues.IntroductionNowadays heavy metal containing residues like electric arc furnace dust (EAFD), dust from cupola furnaces, waelz slag, etc. are declared as hazardous wastes in a growing number of countries due to the leachability of the heavy metals in these residues. For that reason it is no longer possible to landfill these materials or use them for road construction or disposal works. Some land filling activities, carried out until now, have only been realizable because of some process modifications or cost intensive post-treatment steps of these residues. But the disposal capacities for such materials are decreasing, therefore increasing the prices. The second point for the growing disposal limitations is the stringent environmental legislations and regulations, which restrict the number and amounts of materials which can be dumped [1 – 5].From the other point of view these heavy metal containing residues usually have high contents of zinc, lead, iron, etc., which represent a significant value and therefore a big potential to recover these metals. This is why in recent years the number of recycling processes and the amount of recycled heavy metal containing residues have continuously increased. These recycling processes have the target to recover the valuable metals from the residual materials in the form of a saleable product as well as the stabilization of the slag produced in these processes [5, 6]."

Jan 1, 2011

By Xie Zhang, Chongyang Zhao, Qingyun Huang, Bing Xie, Xiaopeng Zhen

"Extracting vanadium from vanadium containing hot metal into vanadium slag by BOF is the main vanadium production process in China. In this paper, the influence of Si content in hot metal on the quality of vanadium slag is analyzed. Synthetic vanadium slag with different SiO2 content were melted at 1673 K and then cooled to 303K at the cooling rate of 3?/min. Optical microscopy, SEM, EDS and XRD were used to analyze the mineralogical phases and crystallization behavior of vanadium slag. The results show that vanadium slag mainly contains spinel phase and silicate phase; V is enriched in the spinel phases while Si is concentrated in Fe2SiO4 CaFeSi2O6 and (Fe,Mn)2SiO4 as silicate phase. The melting point of slag increases gradually with the addition of SiO2; whereas viscosity decreases with an addition of 15~19% SiO2 and increases with an addition of 19~27% SiO2.IntroductionVanadium is an important element which is used almost exclusively in ferrous and non-ferrous alloys. The major vanadium products include FeV, V2O5, V2O3, VN and Al-V-Ti alloy. Furthermore, vanadium slags are mostly produced by oxidizing the elements in V-containing hot metal during a duplex refining process. Therefore, the process of removing vanadium from hot metal has its significance on the subsequent process[1].The extraction of vanadium is greatly affected by the mineralogical composition of vanadium slag[2], the distribution of the elements between the spinel and silicate phases and its physic-chemical properties. These characteristics of vanadium slag have been studied in some details. It has been reported that Si mainly exists mainly in the form of silicate which wraps the spinel crystals while small amount of Si stands as phosphorus quartz or diopside[2]. Chen et al.[3, 4] points out, when SiO2 content in vanadium slag increased every 1%, V2O5 decreased 1.48%. Moreover, silicate phases would embarrass the oxidation of V-containing spinels through decreasing the exposing probability[5]. Meanwhile, melting point and viscosity of vanadium slag has been greatly influenced by the SiO2 content. Therefore, this work attempts to analyze the above-mentioned questions systematically."

Jan 1, 2012

By M. Omneya El-Hussaini, M. Galal Abdel Wahab, A. Mohamed Mahdy, M. Fathi El Shahat

"Um-Gheig Pb-Zn representative sample was collected from the main adite of Um-Gheig mine along Red Sea coast in Egypt. Its chemical analysis shows that, it contains 16% Zn, 2.3% Pb, 0.1% Cd and 0.1% B as elements of interest. After H2SO4 agitation leaching, the chemical composition of Um- Gheig Pb-Zn deposit ore residue assayed 2.26% Pb, 1.5% Zn, 0.085 % B and 0.01% Cd. This residue was leached with 20% HCl at S/L ratio 1/3 for 2 hours at 80o C. The chloride leach liquor was found to contain 18 g/l Pb, 13 g/l Zn, 0.1 g/l Cd and 0.75 g/l B with the corresponding leaching efficiencies 79%, 86%, 100% and 88% respectively. Lead was precipitated from the chloride leach liquor using concentrated H2SO4 to obtain PbSO4 with precipitation efficiency 96%. While boron was extracted by the selective resin Amberlite IRA743 with loading efficiency of 80%. On the other hand, Zn and Cd were precipitated using Na2S solution with 86.7% and 100% recovery efficiencies respectively.IntroductionLead-zinc ores occur in Egypt in a few localities distributed along the Red Sea coast between El Qusier and Ras Banas.. The reserve of the ore deposits has been estimated by Soviet and German Experts to be about 900,000 Ton, [1]. Onal et al., [2] recovered Pb from Pb–Zn sample containing 10.17 % Pb and 10.98 % Zn from Aladag in Turkey. El-Sherif, [3] used concentrated HCl to leach lead-zinc ore sample of Um-Sammuki area in Egypt. As had been published by Marchioretto et al. [4], the precipitation of heavy metals with lime, sulfide and caustic soda are the most commonly used economical methods for metal removal. Lead was completely removed from the anaerobically digested sludge by precipitation with NaOH and Na2S at waste water treatment plants. Mahdy et al., [5] had successfully extracted boron from the bittern solution of Qaron Lake by ion exchange resin (Amberlite IRA 743). The extraction of boron was mainly depending upon the pH value. They extracted 80% of boron at pH 5.5, while at pH 3.9 about 74% boron was extracted. Kabay et al. [6] used the column-mode to remove 1g/l of boron from geothermal waste water of the Kizildere-Geothermal Power Station by using Diaion CRB 02 Nglucamine- type chelating resins. In this regard, the removal of lead, cadmium and boron allow the residue to be reclassified as non hazardous material."

Jan 1, 2008

By Jorge Alberto Soares Tenório, Romano Espinosa, Felipe Fardin Grillo, José Roberto de Oliveira, Denise Crocce

"The aim of this work was evaluation of the recovery of Zn and Fe of the EAFD added to the hot metal in the form of briquette at temperature of 1500°C. The EAFD was agglomerated by cold briquetting and introduced in the hot metal. This study utilized a bench-scale equipment to melt, during this process to kept a flow rate of inert gas above the bath. Were collected periodically metal samples and the samples were analyzed for determination of the content of total silicon and carbon by chemical analysis. Zinc oxide, zinc ferrite and other oxides were reduced and were volatized and collected by a cleaning system of dust (baghouse) located on top of the oven. More than 98% of iron were recovered from EAFD during the test. It was possible to produce a dust containing about 68% zinc by means of adding of EAFD.IntroductionIn the first semester of 2010, steel production was about 706 million tons, 27.9 % more than in the first half of 2009. Not a significantly increase if 2010 data is compared with the first semester of 2007 (only 7.2 % higher), before the world’s economic crises. Steel production is divided into two main routes. The first one, and most used, is the Basic Oxygen Furnace Process (BOF process), which in 2008 accounted for approximately 67.1 % of steel production. The second route is carried out in the Electric Arc Furnace (EAF) that in 2008 represented 30.6 % [1 ].Electric arc furnace dust (EAFD) is a solid waste generated during the steel making process. It is classi?ed according to NBR 10004 as dangerous solid waste-class I, because the elements Pb e Cd leach in water exceeding the maximum limits permitted by the NBR 10004 [2 ]."

Jan 1, 2012

By K. D. Peaslee, V. L. Richards, C. H. Rawlins, S. N. Lekakh

"Steel-making processes generate carbon dioxide air emissions and a slag co-product. The aim of this project was to develop a functional sequestration system using steelmaking slag to permanently capture carbon dioxide emitted in steelmaking offgas. A possible parallel benefit of this process would be rapid chemical stabilization of the slag minerals with reducing swelling or leaching.This paper summarizes the original results of the project, including mineralogical and structural features of carbon sequestration with steel making slag, mathematical modeling of reaction phenomena using a modified shrinking core model, METSIM modeling of several possible industrial applications, a thermo-gravimetrical study of the reaction between slags and different gases, and design and testing for a lab scale apparatus consisted of two reactors.1. IntroductionThe U.S. produces 9-14 Mt of steelmaking slag annually, which represents approximately 10-15 wt. % of crude steel output.1,2 Primary uses for steelmaking slag include high quality mineral aggregate, Portland cement, unconfined fill, soil conditioning, and pH neutralization of abandoned mine drainage.3,4 The key factor prescribing slag use is the alkaline-earth metal (e.g. Ca and Mg) oxides content, which contribute to overall basicity and cementitious strength. However, as-produced steelmaking slag is chemically unstable. Calcium and magnesium oxides readily form hydroxides and carbonates through reaction with atmospheric gases. Both hydroxide and carbonate formation produce substantial mechanical swelling leading to heave failure in confined construction applications, thus many states dictate stockpile aging for 3-6 months prior to commercial use.5,6 Sequestration of carbon dioxide is a natural corollary to forced carbonation. The conversion of CaO/MgO to carbonates serves both to stabilize the slag, and permanently capture and store the CO2."

Jan 1, 2008

By R. J. Wesely

The paper describes the various methods which are currently being used or considered to refine gold and silver. These methods are then compared on a technical and economic basis. Conclusions are drawn on the factors which might influence the choice of process for different feed stocks and economic constraints

Jan 1, 1990

By Animesh Jha

"Fine ceramic powders (<500 nm) exhibit exceptional physical and mechanical properties in engineered structural ceramics. The production of fine powders, in particular the non-oxide ceramics, via a cheaper route than the organic solvent route has been rather elusive. This paper examines the physical chemistry of sub-oxide vapour-phase reduction reaction for the nucleation of non-oxide ceramic phase. Well known vapour species eg SiO and BO in the production of technical ceramic powders (SiC, BN) are particularly discussed for understanding the nucleation process of SiC and BN ceramic phases respectively. The regimes of partial pressures and temperatures are particularly 'identified. The calculated nucleation rate as a function of the temperature is compared with the experimental results on powder morphology. The production of amorphous and nanocrystalline h-BN powders is discussed in the context of substrate structure and thermodynamic parameters.IntroductionThe physical and mechanical properties of ceramic components are strongly dependent on the powder particle size and morphology used for their fabrication. For example the strength (Os) of the structural ceramic components increases with decreasing average grain-size (d) in accordance with the Hall-Petch relationship: Os = 0""0 + k/(d)1/2. Here k is an empirical constant which can be established from the graphical relationship. However as the particle size approaches submicrometer-size range, the dependence of strength on the particle size becomes more complex [1]. The design of ceramic components based on nanometer-size particles have recently become an important field which can offer ceramic materials with properties comparable to their metal counterparts. Several materials based on these concepts have been developed and reported by Niihara [2]. For example, the Al2O 3-SiC nanocomposite, having average B-SiC grain size 0.3-2um with intragranular SiC particulates of 5-10 nm has unusually high strengths (1100 MN/m2) at low and elevated temperatures combined with enhanced fracture toughness (> 4 MN-ml.5) which is an unusual combination in structural ceramics. Besides mechanical properties, as the particle size of ceramic powders approaches the nanometer-size range, the charge transport properties also improve by many times. The effect of particle size on the electrical conductivity of Si3N4-TiN composites has been well documented [3.4]. The size of ceramic particulates without doubt plays a pivotal role in determining the properties of ceramic components."

Jan 1, 1996

By A. V. Reddy, C. Beckermann

"The DC continuous casting of a grain refined AI-4.5%Cu round ingot with realistic boundary conditions is numerically simulated. Of particular interest are the effects of the transport of free solid in the form of equiaxed grains on the macro segregation patterns and the final grain size distribution. The study uses a previously developed two-phase model that incorporates descriptions of heat transfer, solute redistribution, melt convection, and solid transport on the system scale with microscopic models of solutal undercooling, microsegregation and grain impingement. The numerical results indicate that grain transport inhibits the formation of inverse segregation in the ingot shell and promotes negative centerline segregation. This is explained by the reduction in the solid coherency next to the mold and the advection of solute-lean grains towards the centerline. Comparisons with the experiments of Finn et al. [5] illustrate the need for considerable improvements in the model. IntroductionMacrosegregation continues to be one of the concerns in DC continuous casting of aluminum ingots. The variation in composition over the ingot cross section results in the need to adjust alloy composition in order to meet mechanical property specifications in finished products. The extent of macrosegregation is greatly affected by the casting conditions, such as casting speed, superheat, cooling rate, mold size, alloy composition, and grain refining practices. Thus, it is of great interest to develop a comprehensive mathematical model to simulate the casting process, enabling the selection of conditions that minimize macrosegregation while maintaining a high productivity."

Jan 1, 1994

By Scott R. Giese, Lucas Dix

"Recently, there is a growing trend in the aluminum foundry industry to develop· improved melting and casting processes to produce lightweight, high-strength, and thin-wall castings for the aerospace and transportation industry. One casting method that has demonstrated industrial potential for producing clean, thinwall castings is vacuum-assisted, counter gravity casting. This process has the benefit of expeditiously and quiescently filling the casting cavity with a dramatic reduction of furnace related and reoxidation inclusions. Additionally, lower casting temperatures can be utilized because the application of vacuum during filling overcomes the resistive internal cavity pressure resulting in a finer, as-cast microstructure. The paper explores and discusses the processing and design conditions in improving the mechanical properties of A206 casting alloy using the vacuum assisted, counter gravity casting process.IntroductionThe process of metal casting has been, over the centuries, the chief production technique for components used in everyday life. However, the casting process has certain inherent problems that can adversely effect the properties of a finished product. These problems are directly attributable to the gravity pouring technique used to transfer molten metal to the mold and to fill the mold cavity.A recent study for the American Metalcasting Consortium demonstrated reoxidation products created during the casting process are five times more likely to cause product rejects than entrapped molding aggregates, melt slag, or furnace lining materials1. Formation of nonmetallic and intennetallic compounds are more prevalent in aluminum and titanium alloys because of their reactiveness to furnace lining materials and their high affinity for oxygen. The incorporation of undesirable compounds can be attributed to four areas of the casting operation. The sources are charge materials, melting technique, pouring methodology, and casting cavity filling. Aluminum foundry men have addressed the first three areas by selecting high quality melt stock, non-stirring melting equipment, and the use of porous ceramic filters. Unfortunately, little consideration is given to the last, but yet tl.1e most important part of the casting operation, the actual fill mg of the casting cavity.The generation of inclusion defects during the casting process can be described by two methods. As the liquid metal flows in the gating network and casting cavity, abrupt changes in flow d1rect10n cause the metal to become agitated. This mechanism liquid metal splashing, is generated by instability of the advancing liquid metal interface from turbulence effects as schematically illustrated in figure 1a2 . The surface oxide film bursts under high velocity conditions, folds over, and becomes dispersed and incorporated in the bulk liquid. Additionally, fragmented liquid droplets ejected from the disturbed interface oxidize and become dispersed in the metal stream."

Jan 1, 2000

By R. Leiby

Prior to March 1992, the only component of the lead acid battery that was not recycled by East Penn Manufacturing Company was the sulfuric acid electrolyte. This acid was unusable in new batteries because the iron level was found to exceed new product specifications. The development of a liquid ion exchange process to remove the iron from the acid allows East Penn to currently recover over three million gallons of sulfuric acid annually. The process is based upon the use of an iron selective liquid ion exchange material or solvent to extract iron from the sulfuric acid electrolyte followed by regeneration of the solvent. Equilibrium and kinetic data for the extraction and regeneration steps were collected in order to scale up the process to commercial scale. An electrochemical process for the treatment of the acid used in the regeneration step was, also developed which significantly reduces the volume of strip acid required in the process.

Jan 1, 1995

By D. M. Hausen

The term "auriferous pyrite" relates to an association of gold with pyrite in a variety of textural forms that affect metallurgical treatment. Extraction of the gold depends not only on the grain size and distribution of the gold in the pyrite, but also on the crystal size and surface area of the pyrite. Occlusions of medium to coarse gold may be liberated by moderately fine grinding. The amenability of finely dispersed (submicroscopic) gold depends in part on the activity of the pyrite surface for oxidation. Two types of auriferous pyrite at Carlin, Nevada, have been examined by optical microscopy and SEM methods before and after aqueous oxidation test work to show how differences in morphological features can affect rates of oxidation and amenability to gold extractions by methods of chlorination and low temperature oxidation.

Jan 1, 1981

By Qingyu Deng, Shiwei Ma, Guibao Qiu, Hua Wang

"The flow behavior of the blast furnace slag bearing titanium, like viscosity, play an importance role during the iron-making process with the vanadium-titanium magnetite, which is a very special minerals in Panzhihua, China. The dependency of the viscosity on the chemical composition like TiO2, Al2O3, MgO, binary basicity (CaO/SiO2), temperature, reaction time were studied. The experiments showed that the viscosity decreased with the increase of TiO2, MgO content and binary basicity, and it increased with the increase of Al2O3 content and temperature. The viscosity showed a slight decrease within 60mins’ reaction with graphite crucible, however, it increased rapidly afterwards with the formation of Ti(C, N).IntroductionThe ordinary iron ore has been an essential part of raw materials for vanadium-titanium magnetite smelting in Panzhihua to avoid a series of problems, such as slag thickening, adhesive bond of slag and hot metal, etc. The ratio of vanadium-titanium magnetite has been decreased gradually since 1970s, and has down to about 65% now. However, with the substantial appreciation of price of imported ordinary iron ore, Panzhihua Iron and Steel Group aims to increase the ratio of vanadium-titanium magnetite and decrease the dependence on ordinary iron ore in order to lower the cost of smelting process."

Jan 1, 2012

By J. L. Johnson

Remediation of small-arms firing ranges is being investigated by the Naval Civil Engineering Laboratory and the U.S. Bureau of Mines. Scheduled closures of military installations, as well as the management of active ranges, require the development of methodologies for heavy metals removal to prevent their entering the surrounding environment. The impact berms contain high concentrations of metals, and the soil and vegetation surrounding the berms were found to have slightly elevated levels. The heavy metals characterized are in the form of whole bullets, a wide size distribution of free fragments, smeared lead on the surface of the soil grains, and very finely attached particles. Gravity beneficiation can remove liberated metal contamination effectively. Weak acetic acid leaching shows promise in lowering the final metal contamination to allow the soil to pass the Environmental Protection Agency&apos;s (EPA) Toxicity Characteristic Leaching Procedure (TCLP) criteria.

Jan 1, 1991

By C. Ek

In bismuth metallurgy, low-copper high-sodium mattes are by-produced. Different charges containing mixtures- of crude mattes, oxidized matte, and/or copper sulfide concentrate and/or copper silicate ore have been smelted to give a rich matte and a disposable slag, then converted to obtain blister copper with high recovery and a rich slag to be recycled.

Jan 1, 1983

By Arpad E. Torma

The identification and characterization of lithographic iron and sulfur oxidizing bacteria in the 1940&apos; s. opened up new possibilities and challenges for the mining and metallurgical industries. These were exploited during the 1950&apos;s and&apos; 1960&apos;s, when it was demonstrated&apos; that mining wastes and complex unused mineral resources could be economically treated by bacterially assisted heap and dump leaching processes?. During the 1970&apos;s this technology grew into a more structured discipline called "biohydrometallurgy". In the l980&apos;s efforts were devoted to the identification of a variety of organisms involved in naturally occurring leaching processes. Further efforts dealt with the elucidation, of leaching mechanisms; the leach ability of nickel, coban, zinc, and precious metals; the desulfurization of coal; and diverse biosorpion phenomena. The application of genetic engineering techniques for the improvement of microbial performance was also initiated?. Current trends in biohydrometallurgy include improvement of many of the techniques noted above, as well as application of leaching. technolog.ies to. environmental remediation scenarios. These activities afford considerable opportunities for research in the 1990&apos;s. For example, bioremectiation of abandoned mining and processing sites requires development of new and economically viable technologies capable of removing low concentrations of toxic metals from high volumes of solid and/or liquid wastes.

Jan 1, 1991

By S. A. Shuey

The present industrial practice used to separate aqueous cobalt from nickel is multistage solvent extraction processing. This paper describes a different but simpler treatment technology. The proposed technology has been applied to cobalt/nickel hydroxide intermediate solids produced from the treatment of Electrochemical Machining (ECM) waste sludge, The process consists of dissolving the cobalt/nickel hydroxides in basic cyanide solutions. Cobalt and nickel form aqueous .solution metal cyanide complexes. Nickel can be selectively precipitated from the solution as a nickellic hydroxide solid. Cobalt can be recovered from the leach solution by precipitation of a cobaltous/cobaltic cyanide double salt. The double salt product can then be subsequently treated to produce an appropriate cobalt product. The process chemistry, proposed fiowsheet and preliminary reagent costs are presented and discussed.

Jan 1, 1998

By Ian Baker, Xavier Pierron

"Iron aluminides hold great promise for intermediate temperature applications (to ~ 600°C) because of their excellent oxidation and sulphidation resistance and good strength. However, they have poor low temperature ductility, a feature which is exacerbated by water-containing environments. This paper presents an overview of the effects of environment on the ductility of iron aluminides, including the effects of iron aluminum ratio; ternary alloying additions, particularly boron; strain rate; and temperature. The mechanisms involved in water-induced embrittlement are discussed.IntroductionOver the last few years, it has became increasingly evident that the ductility and fracture toughness of many intermetallic compounds, particularly aluminides, are reduced dramatically if they are mechanically tested in either air or in hydrogen-containing atmospheres (1-5). For FeAI and Fe3AI, it has been shown that water vapor, for example in air at room temperature, can form atomic hydrogen by reacting with the Al atoms (1, 2). As a result in iron aluminides, the environmental embrittlement process is quite similar to traditional hydrogen embrittlement. This can be easily demonstrated by either testing an iron aluminide in an environment free of the deleterious species or by testing at high strain rates, both of which result in greater ductility. The purpose of this paper is to review recent progress in understanding environmental embrittlement in FeAI and Fe3AI, and to consider possible environmental embrittlement mechanisms. Greater understanding of this phenomenon will lead ultimately to remedies to this problem which is a major reason for preventing the practical application of these materials. First, some background on the iron-rich aluminides."

Jan 1, 1996

By M. Nilmani, H. Pham

"A mathematical model was developed for the dissolution of particles in gas-stirred liquid baths, linking the hydrodynamic flow field of the bath, the average particle trajectory and liquid-side mass transfer controlled dissolution kinetics. The model was validated by comparison with experimental data for the dissolution rates of urea particles in gas-stirred aqueous CaCl2 solutions measured during this study. The dissolution rates of urea. particles were measured using an image analysis system.The effects of operating conditions on the dissolution rates of urea particles were investigated. It was found that the key operating parameters influencing the utilisation efficiency of particles were the gas flowrate, particle diameter and lance submergence. An optimisation of the operating conditions for the model urea-aqueous CaCl2 system indicated that the utilisation efficiency increased with decreasing gas flowrate and decreasing particle size for a given lance submergence.IntroductionThe utilisation solid reagents in molten baths varies from one process to another, depending upon the rates and mechanisms of the reactions between the particles and melts, as well as the trajectory and residence time of the particles in the melts. Previous studies have not attempted to predict the utilisation efficiency of injected solids by coupling the motion of the particle with its dissolution rate. Instead, the particles have usually been assumed to remain suspended in the bath until completely dissolved, and the mass transfer coefficients were based on the average specific mechanical energy dissipation rates in the bath. Investigations of this nature relevant to the present study have been undertaken by Apelian et al. [1], Brucato et al. [2] and Langberg and Nilmani[3]. The objective of the present study was to develop a mathematical model, incorporating both the reaction kinetics between the particles and liquid and the particle motion simultaneously, to predict the dissolution rates and times of the particles. The mathematical model was validated by comparison with experimental dissolution rates of a cold model analogue system measured using an image analysis technique, and then applied to optimise the operating conditions in the model system."

Jan 1, 1996

By Bin Zhu, Mingmei Zhu, Hong Zhou, Xiaofei Dou, Bin Xie, Yu Wang, Tiancheng Lin

In this study, the formation of 2CaO·SiO2 and 3CaO·P2O5 solid solution (nC2S-C3P) in hot metal dephosphorization process is discussed. The variations of CaO and SiO2 mass, both in nC2S-C3P solid solution phase and liquid slag phase with increasing P2O5 mass in CaO-SiO2-FetO-P2O5 slags were calculated using Factsage software. CaO-SiO2-FeOt-P2O5 slag containing up to 18 % P2O5 was melted at 1823 K then cooled to 1673 K. The contents of CaO and SiO2 both in the solid solution phase and liquid slag phase of quenched samples were observed and analyzed by SEM/EDS. Both the calculated and experimental results show that the contents of CaO and SiO2 in the solid solution phase decreased, just opposite in the liquid slag phase, with increasing P2O5 content in the slags. Formation mechanism of nC2S-C3P solid solution in the slags was derived based on the ionic structure theory of molten slag. The SiO4 4- in the nC2S-C3P solid solution can be replaced by PO4 3- in the liquid phase resulting in the increasing of free Ca2+ and SiO4 4- in liquid phase.

Jan 1, 2015

By F. D. S. Marquis

An investigation of the mechanisms of formation of two types of porosity-primary and secondary-their characterization, evolution during processing, and effects on the mechanical behavior (fracture, fatigue, and failure) of 7X50 and 2X24 alloys has been conducted. The mechanisms of formation of three forms of primary or cast porosity were investigated, and each form was characterized: (a) macroscopic shrinkage porosity-MSP); (b) microscopic interdendritic porosity (MIP); and (c) hydrogen gas porosity (HGP) or primary hydrogen porosity (PHP). The mechanisms of formation of four forms of secondary or thermal/thermomechanical porosity were investigated, and each form of porosity was characterized: (a) high temperature oxidation (HTO). internal hydrogen precipitation (IHP), or secondary hydrogen precipitation (SHP); (b) preheating blistering porosity (PBP); (c) eutectic melting porosity (EMP);and, (d) dissolution micro void formation (DMF). The evolution and interactions of the primary and secondary types of porosity (w.ith special emphasis on PHP and SHP) during industrial and laboratory processing and their effects on the fracture and failure behavior of both types of alloys (with special focus on fatigue crack initiation and propagation) were investigated.

Jan 1, 1996