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By C. L. Xiao

With reference to the test report carried out by Guangzhou Nonferrous Metal Research Institute in 1983, the mineral process flow sheet of Yichun Tantalum-niobium mine is determined based on the characters of ores and successful experiences in light of the problems in the existing flowsheet: The ore is desilted before crushing; the primary slime is separately treated; the staged grinding process used while the fine slime is collectedly treated with tantalum and niobium as the main recoveries and lepidolite and feldspar powder as the secondary. The flowsheet is featured by comprehensive recovery, low investment and low energy cost.

Jan 1, 2014

By H. J. Wu

The optimum performance in mineral processing plants usually demands the optimum size reduction, which is frequently achieved by a closed grinding circuit. Due to the difficulty associated with fine size classification, the size separation efficiency in closed grinding circuit is usually very low, which leads to huge circulating load and significant overgrinding. Recent development of Der-rick Stack Sizer has made an efficient fine size separation down to 200 mesh with a satisfactory screening capacity. With the efficient fine size separation with Derrick Stack sizer, the problems commonly associated with typical closed grinding circuit, including high circulating load and over-grinding, have been eliminated. Feedback from numerous Stack Sizer applications in iron ore industry indicated that, compared with conventional fine size classification equipment, the circulating load achieved by Derrick screen was usually decreased from approximate 300% down to 60% or so, while the iron recovery has been increased by 6% to 8% only by more efficient size separation in the closed grinding circuit. To study this phenomenon, this paper discusses the relationship between size classification, circulating load and mineral recovery in the closed grinding circuit. A simulation model to predict the improvement in the grinding circuit from more efficient screening is also introduced with this paper.

Jan 1, 2014

By B. Das

The separation of iron values from a typical Indian iron ore slimes containing 57.2% Fe, 5.81% SiO2 and 7.05% Al2O3 by wet magnetic separation and selective magnetic coating is investigated. The iron phases, which are mostly paramagnetic in nature, have been coated with magnetite or colloidal magnetite in presence of surfactant by manipulating the surface properties of the minerals. The studies have indicated that an iron concentrate containing 62.32% Fe with 66.5% iron recovery can be obtained at medium magnetic intensity of 7.8 kG which is much less compared to normal magnetic intensity of 13 kG to14 kG required for hematite-goethite separation. The performance of this technique with respect to both grade and recovery is superior to conventional magnetic separation or flotation of iron ore slimes.

Jan 1, 2014

By T. Wajima

We tried to convert paper sludge ash (PSA) into zeolitic product with high cation exchange capacity (CEC) through acid leaching. Typically, PSA from incineration of paper sludge contains a high percentage of calcium in the form of anorthite (CaAl2Si2O8) and gehlenite (Ca2Al2SiO7). It is difficult to convert the ash with a high Ca content into zeolites, or at least into more desirable zeolite phases. Acid leaching with HCl was applied to reduce the Ca content to synthesize zeolitic product with high CEC. The raw ash was treated with 1 M, 3 M, and 5 M HCl solution for 0.5~24 hours (the ratio of the ash to volume of HCl solution was 1/4), and then zeolitic product was synthesized from leached ash through the reaction with 2.5 M NaOH solution at 80 oC for 24 hours. During acid leaching, gehlenite is readily dissolved in a lower HCl concentration solution than anorthite. With increasing HCl concentration, the amounts of Ca, Mg, Si, Al, Fe and Ti extracted from the ash increased. Ca and Mg contents were easily extracted from ash than other elements. The contents of Ca and Mg extracted rapidly at initial stage, and then levelled off. The saturation times of Mg and Ca are almost 0.5 h using all concentrations of HCl solutions. After the synthesis from leached ashes, zeolite-A and -P were synthesized from ash leached in 1 M HCl solution, and 3 M and 5 M HCl solutions, respectively, regardless of leaching time. With in-creasing HCl concentration, the Ca content eluted from the product decreased, due to the removal of Ca via acid leaching before the synthesis, while the Na content eluted from the product increased to 3 M HCl and then decreased, which was almost similar to the CEC of the product, due to the ion exchange of Na-type zeolitic phase in the product. The change of zeolite phases in the product and the CEC of the product depend on the concentrations of Si and Al in the solution during the synthesis. The highest CEC of the product is about 220 cmol/ kg, which was synthesized from the ash leached in 3 M HCl solution.

Jan 1, 2014

By Z. Kwela, A. Manhique, W. W. Focke, W. van der Merwe

"The main features of the de Wet improved alkali fusion process for the manufacture of AZST are: Fewer process are steps necessary; radioactivity is removed by leaching rather than by precipitation; fewer waste streams are generated; there is less waste to discard and alkali reagent is recovered in the form of a sodium silicate solution that is essentially free of radioactivity.Here we report on our efforts maximize the alkali recovery in the sodium silicate product stream: Milled zircon, d50 ˜ 9 µm, was fused with caustic soda pearls in open reaction vessels at temperatures between 650°C and 850°C. Fusion times of 1, 2, 4, 24 and 336 hours (with intermittent milling) were investigated. The fusion products were characterized by infrared spectroscopy, X-ray diffraction and by wet chemical analysis.For prolonged fusion times the fusion products approached equilibrium compositions. However, the phases Na2ZrSiO5 and Na4Zr2Si3O12 observed at 850°C did not form at 650°C. Since these compounds do not hydrolyze in water they limit the recovery of alkali in the sodium silicate product stream. For 2-hour fusions a broad spectrum of non-equilibrium reaction-products, that are rich in sodium silicates, is formed."

Jan 1, 2003

By Sami Makni, Ahmed Bouajila

"To remain competitive in an open market, mining companies are more and more requested to optimise their complex and highly multivariate processes. The increasing amount of process data, brought about by intensive use of instrumentation and the progress in computer data acquisition, enhances the need for more and more powerful and robust tools for the analysis and modelling of the process data. Now, with the emergence of multivariate data analysis (MDA) techniques, on-line clustering of mineral process behaviour is possible and could help in the extraction of valuable process operation indicators. MDA can be used in different mineral processes such as flotation, grinding, smelting etc.In this paper, we focus on grinding process considered as the most costly and power consuming node of the mineral processing scheme. Different objective-oriented levels of data clustering will be addressed.First, the evaluation of grinding operation taking into account data and constraints from all processes before (e.g. blasting, crushing) and after (e.g. flotation, leaching, etc.) the grinding node. The second level deals with process diagnosis by differentiating operation level and identifying behaviour drifts. Control and optimisation are two other levels concerned here with the selection of optimum trajectories in the drift correct.Industrial plant data are processed in order to illustrate the feasibility and the potentiality of MDA applications in addressing the clustering and interpretation of grinding mill behaviour."

Jan 1, 2003

In the present work, the flotation behaviours of zircon, rutile and ilmenite using sodium oleate as collector in absence and presence of depressants were thoroughly investigated. The maximum in the flotation recovery of any of the above minerals falls within similar pH ranges. A range of inorganic and polymer depressants were examined in order to improve the separation of zircon from rutile and ilmenite. Optimum values of conditioning pH and depressant concentration to achieve maximum recovery and best selective floatability of zircon were obtained. Selective flotation of zircon from Ti-bearing minerals was anticipated from single mineral experiments under different pH values, depressant and collector conditions.

Jan 1, 2014

By L. Y. Feng

The percentage of leached zinc in massive zinc oxide ores (11.7% Zn, >2 mm) is up to 73.3 % in 120 days. Alternatively, crushed to -0.154 mm, mixed with cement 5% (wt), pelletized and solidified. The diameters of the pellets obtained are between 5 mm to 8 mm. When the pellet solidification periods are 3 days, 10 days and 45 days respectively, the alkaline leaching rates of zinc in the pellets are up to 95.8%, 89.1% and 76.4% respectively. Decreasing the solidification time can re-duce reaction time, increase dissolution of zinc in pellets and lower the effect of initial zinc concentration on leaching rate. The experiment results show that the minimum solidification time is three days, and the kinetic study indicates that alkaline leaching of the low grade zinc oxide pellets is controlled by the diffusion of the leach liquor through the gangue layer in the whole leach process, and the apparent rate constants are 3.33×10-2 day-1, 9.18×10-3 day-1, 5.82×10-3 day-1 respectively.

Jan 1, 2014

By E. Vahidi

In this study, a hydrometallurgical treatment involving solvent extraction of zinc using D2EHPA (di-2-ethylhexyl phosphoric acid) has been investigated to recover zinc from an industrial zinc leach residue. The residue was leached with sulfuric acid producing leach liquor which was subjected to solvent extraction for enrichment of zinc and removal of impurities. Operating variables for the zinc extraction process, such as pH of the mixed solution (0.5~5.0), concentration of D2EHPA (5%~40%, w/w), temperature (25~60°?C), A/O volumetric phase ratio (1/2~4/1), concentration of tri-butyl phosphate (TBP) as modifier (3%~7%, w/w), concentration of NaR2RSOR4R in aqueous phase (0.05M, 0.1M, 0.2M) were also studied. Practically all zinc was extracted from the aqueous solution at pH 2.5 with 20% w/w D2EHPA in kerosene. At this operating condition, zinc could be extracted at one theoretical stage at A/O phase ratio of 1/1, as calculated by the McCabe-Thiele method.

Jan 1, 2014

By C. Y. Wang

Based on Slurry Electrolysis, and combined with the problems of extraction antimony, lead and their separation from complicated antimony-lead concentrate, a series of tests have been done in this paper. Using Slurry Electrolysis to treat complicated antimony-lead concentrate, antimony and lead can be separated in one step. And 2# metal antimony can be achieved in cathode directly at the same time. Lead in concentrate is restrained still in the residue at the form of PbCl2. After converting the residue with ammonium carbonate and removing sulfur with kerosene, the high quality of lead concentrate (Pb is above 45%, S is below 15%) and pure sulfur can be achieved, respectively. The recovery of all in Slurry Electrolysis process is as: Sb 95%, Pb 95%, Ag 80%, S 60%.

Jan 1, 2014

By A. Tolentino, J. Bravo, M. A. Corona-Arroyo, C. Quintero, R. Zarate, A. Lynch, L. Carillo

"This paper presents the performance of the flotation circuit of Minera Fresnillo PLC, Mexico. A plant survey was carried out on the lead banks and a size-by-size assay on the samples was conducted. The results indicate that the plant is treating fine particles in the flotation circuit. At least 30% of the particles in the feed are finer than 8 microns and that high amounts of Pb, Au, Ag and insolubles are in this particle size. It was also found that higher percentage of insolubles in the -8 micron particles are recovered in the final concentrate rather than being rejected in the tails. The presence of high amounts of insolubles in the concentrate is an issue of the company. The result of the plant survey provided valuable information for effective reduction of the insolubles in the concentrate and for plant optimization. The work conducted is part of the training of the students involved in a mine placement in the Alban Lynch Student Venture. INTRODUCTION Minera Fresnillo is one of the operating mines and the main contributor to the silver production of Fresnillo PLC group, the world’s leading producer of silver from ore. It is located in the mining district of Zacatecaz, Mexico, approximately 650 kilometers from Mexico City. The major minerals that make up the ore are galena, sphalerite, tetrahedrite, pyrargyrite, proustite, polybasite, pyrite and pyrrhotite. Minera Fresnillo has a capacity to treat 8300 tonnes of ore per day. The plant consists of semi-autogenous mill - ball mill – hydrocyclone circuit for primary grinding followed by silver-lead flotation then zinc flotation circuits. This paper reports the plant audit conducted in the silver-lead flotation circuit (Figure 1) of Minera Fresnillo. The circuit includes rougher, scavenger and two stages of cleaning. The tails from the scavenger goes to the zinc flotation circuit while the second cleaner yields the final silver-lead concentrate. The feed to the circuit has a particle size of 90% finer than 75 microns and generates a concentrate with grade of about 35% Pb, 5700 g/ton Ag, 16 g/ton Au and recoveries of 90% Pb, 90% Ag, 64% Au, respectively. Although the plant achieves their target concentrate grade and recovery, the concentrate also contains significant amount of insoluble materials which is about 18%. These insoluble materials consist of gangue minerals. The plant audit was conducted primarily to determine the possibility of further reducing the amount of insoluble materials present in the silver-lead concentrate."

Jan 1, 2018

By C. R. Mambote

One of the processes developed for vanadium recovery from the fly ash of crude oil is through acid leaching. In the process, iron is one of the impurities that should be removed before vanadium precipitation, due to the fact that iron tends to co-precipitate with vanadium. The mechanism of iron precipitation is understood in terms of ferric hydrolysis, followed by the dimerization and subsequent polymerization of the crystalline iron compound. In order to develop a new approach for the fly ash processing, in the present paper the precipitation of iron from the liquor after the leaching process was studied with addition of NaOH or NH4OH in the presence of H2O2 or Na2C2O4 at 80°C. The objective was to investigate the feasibility of the selective precipitation which could be applied to vanadium and nickel recovery from the fly ash. The experimental results show the difficulties of removing iron by precipitation without co-precipitating nickel and vanadium.

Jan 1, 2014

Electrochemical behaviors of synthetic and natural enargite in buffer solutions have been investigated using open circuit potential, stationary polarization and cyclic voltammetry as functions of solution pH, scan direction, scan range, scan rate and dissolved O2. The results indicate that the electrochemical behaviors of synthetic and natural enargite are very similar; solution pH, scan direction, scan range and scan rate have remarkable effects on the electrochemical behavior of enargite while dissolved O2 has little effect on the electrochemical behavior of enargite. The potential range in which enargite possesses the ability of passivation is from ?0.9 V to + 0.83 V vs. SCE. Enargite is most stable in neutral and alkaline solution around potential ?0.2 V vs. SCE. The main oxidation products on enargite surface in alkaline solution are Cu(OH)2 while the potential imposed on it is within the range of ?0.2 V to 0.33 V vs. SCE and Cu(OH)2 + S0while the potential applied is higher than 0.52 V vs. SCE.

Jan 1, 2014

By F. A. V. Guimarães, A. M. Costa

"The moisture in sintering is a very important parameter for the performance of the process. It allows that the granulation takes pace in an efficient way making the water bridges between the bigger particles used as nucleus and the finer particles that perform the coating of those coarse particles. The formation of the micro pellets is extremely important to prevent loss in permeability of the bed in the sintering grate, avoiding excessive fuel consumption and producing a quality sinter. The aim of this project is to use some of the methodologies for determine the saturation degree on ores and coal to determine the optimal moisture for sintering. In the sinter pot grate series, 3 to 4 assays in a series of 10 are required to determine the optimal moisture for the process. The saturation degree curve test has shown that is really viable to use this technique to skip those tests and go directly to the series to determine productivity and the coke / anthracite consumption. In an industrial scale can be used to adjust the water addition in the conventional mixing methods used in the sintering plants to increase productivity in the process.INTRODUCTION Sintering Sintering is a high temperature agglomeration process in which iron ore fines are partially melted and bonded together using fluxes and a source of fuel, usually coke breeze. The agglomerated product, sinter, has improved metallurgical properties making it an ideal ferrous burden that enable the passage of hot gases in the iron-making blast furnace. The sintering process is normally carried out over three basic stages: granulation, ignition/sintering, and product sizing. In the granulation stage, iron ore fines (usually a blend of selected ores), sinter return fines, fluxes and fuel, and are mixed with water and micro-pelletised in a drum or disc before being introduced in the main granulation circuit. (Wang, Teng, & Wang, 2017)."

Jan 1, 2018

By Y. B. Zhang

China is rich in iron ore resources, but most of these ores are low-grade, polymetallic and refrac-tory ones. Furthermore, with the rapid development of chinese iron & steel industry, the comprehen-sive recovery of these ores is becoming more and more important. The tin, zinc-containing complex iron ores are typical polymetallic and intractable ones, and great reserves of them are found in China. At present, they have not been efficiently utilized. In this paper, based on the investigation of basic physicochemical properties of the tin, zinc-bearing iron concentrates, taken from a mineral processing plant, the mineralogy reason that these concentrates are so intractable and refractory is found out, using advanced microscopic testing methods, such as optical microscope (OM), Scanning Electronic Microscope (SEM), X-ray diffrac-tion (XRD), etc. It is found that the symbiotic relationship of iron, tin and zinc metallic minerals are very complicated, and magnetite in the concentrate is closely symbiotic or enwrapped by fine cassi-terite and sphalerite. So it is difficult to separate tin and zinc completely from the iron concentrates by simple regrinding and physical separation method. This investigation provides theoretical guid-ance for developing new approaches for utilizing these concentrates.

Jan 1, 2014

By Yang Zhao, Tao Xiu-xiang, Chen Song-jiang

"China is rich in low-rank coals that account for 45.68% of existing coal reserves in China. The clean and efficient utilization of low rank coals is of great significance for ensuring the effective energy supply and promoting economic development and environmental protection. In order to solve the difficult problem in flotation of low rank coal, it has become the focus of research in the related field that oily bubbles instead of air bubbles are taken as a carrier in flotation to improve the attachment efficiency and recovery of low rank coal. In this paper, low rank coal slime collected from Shendong mining area was used as the experimental material, and it focused on the characteristics of oily-bubble flotation process of low rank coal. Additionally, difference in conventional flotation and oily-bubble flotation was discussed. The induction time between air bubbles, oily-bubbles and fine low rank coal particles was measured. The results indicated that the induction time between oily-bubbles and coal particles was obviously lower than that of air bubbles. By comparing the foam height of air and oily bubbles, it was found that the amount of oily bubbles is less than air bubbles, causing relative low flotation rate of oily-bubble flotation at initial stage. Besides, the maximum foam height and half-life of air bubbles and oily-bubbles were measured respectively. The results showed that the stability of oily-bubbles was higher than that of air bubbles, which is benefit for the enrichment of concentrates. The clean coal water recovery of oily-bubble flotation is lower than that of air bubble flotation, which indicated oily-bubble flotation is lower in water entrainment. INTRODUCTION China is the largest energy consumer in the world, accounting for 23% of global energy consumption in 2016 and 27% of global energy consumption growth. Whereas coal is taken as the major primary energy source and its share of China’s primary energy consumption is 62% in 2016, in which the low rank coals, such as lignite, long-flame coal, weakly caking coal, and non-caking coal, accounted for about 50% of total coal production capacity (China’s energy market in 2016, BP). Moreover, the exploitation and utilization of low rank coals and other coals that are difficult to float have been an important strategy for China’s sustainable development of the coal industry (Liu et al., 2014). However, the combustion of low-quality coals leads to a serious environmental pollution. In addition, the deterioration in geological conditions of coal resources, and the increasing improvement in the mechanization for mining significantly caused the increased amount of fine coal."

Jan 1, 2018

By R. J. Batterham

The science and practice of mineral processing has been driven for many years by the same set of challenges that shape the mining industry ? demand and supply, grades and their decline with time, mineralogy and the need to handle more complex ores, disposal and minimising of wastes and the availability of water, power, skilled labour and the like together with increasing expectations from the community, concerns on sustainability and safety and, as well, climate change forcing a more targeted approach on energy. In this paper, the author builds on previous reviews to the IMPC and suggests that while step changes are long overdue, the unprecedented demand mitigates against drastic changes. That said, the ?Mine of the Future? is already requiring some different approaches.

Jan 1, 2014

By Alex Heath, Andrew Barycki, Baladron. Javier

"Efficient flocculation is important to thickener performance, affecting the overflow clarity, solids settling flux, underflow density and operability. Many factors affect flocculation; from the material/flocculant type, dilution of the feed and flocculant solution, mixing, to the shear rate and shear history. The flocculant addition point (or points) can be used as a tuning method to alter the effective flocculation time in a feedwell, with addition further up the feed pipe increasing the residence time but making the aggregates more prone to breakup if they experience high shear later in the process. Conversely, adding the flocculant later, eg under the feedwell shelf decreases the mixing time but allows some free (unadsorbed) flocculant to be available at the feedwell exit. An extensive trial has been performed on an operating thickener comparing seven individual different flocculant dosing positions through a Vane feedwell, and some combinations of two dosing points simultaneously. Measurements of the velocity, solids concentration and aggregate size were made throughout the feedwell at the different positions, with the dosing points significantly changing the aggregate size and clarity, and also affecting the solids concentration at some positions. The results are accessed in terms of flocculation kinetics and used as CFD validation data."

Jan 1, 2014

This study examines the surface alteration and flotation behaviour of synthetic moncheite, PtPd(BiTe)2, in the presence of pentlandite. The telluride minerals contribute around 20% ~ 30% and up to 45% of the PGM present in the Platreef ore and are considered to be slow floating as there is evidence of these minerals reporting to the tailings. It was proposed that oxidation products from other minerals and grinding media would affect the mineral surface composition and floatability thereby causing inadvertent depression of moncheite due to precipitating ions. ToF-SIMS analyses (time of flight secondary ion mass spectrometry) was used to characterise the mineral surface as well as the extent of surface alteration. Microflotation was used to deter-mine the hydrophobicity of the synthetic minerals. Conditioning of moncheite in the presence of pentlandite reduced the flotation response of the + 38 -106µm size fraction from > 99% to 56%. This was due to pentlandite dissolution products (iron and nickel hydroxy species) which formed overlayers on the mineral surfaces thereby inhibiting the adsorption of collector. In addition, further grinding of these samples, with and without pentlandite conditioning showed a negative effect on recovery due to the fineness of the particle size distribution and there was no advantage gained from any possible exposure of fresh sites in the sample.

Jan 1, 2014

By Jihoe Kwon, Daeyang Lee, Mario Fujimura-Kashiwagui, Heechan Cho

"Calcium carbonate is one of the most widely used mineral in today's industries such as plastic, paper and pigment. There are many essential physicochemical properties required by each industry field but the most common requisite is size. One way to achieve appropriate size is grinding. Grinding is typically an energy intensive process, consuming about 40% of total energy cost in mineral process. Due to that reason, optimization of grinding process is a critical element to achieve price competitiveness. Two different type of grinding apparatus were hired to find out optimum condition in terms of energy efficiency. Utilizing samples containing 10, 20, 30 and 40% solids concentrations, a 1l batch type attrition mill was operated as the first grinding step at various operating speed with 1? to 5? grinding media in order to study the optimum operating conditions to reach submicron particles. Next, a 0.15l vertical beads mill was tested as next step with 100? to 500? grinding media to study the optimum conditions in the submicron range. Net energy and the specific energy input was measured to reach stated size ranges. Also, using a back-calculation based on the population balance model further operating conditions were studied. There were several competitive combinations which showed significant energy efficiency improvement when compared with the single step grinding."

Jan 1, 2014