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By Liu Tao, Wang Wei, Liao Wenjiang, Yang Weiyan, Tang Bin

Side-blown Furnace technology is a developing technology and was developed very quickly in China in recent years, dozens of reference smelters can be found for the treatment of copper concentrate, copper slag, Lead slag, zinc leaching slag and different kinds of slurry. This paper introduces the working principle of the technology, displays the innovations and specifications of China Nerin's SBF technology, gives examples of the typical reference smelters, and looks ahead to future applications. INTRODUCTION Side-blowing furnace smelting process The side-blowing furnace smelting process (SBF process) is one of the bath smelting process with independent intellectual property rights of China Nerin. This process was originally applied to treat copper concentrate and high-lead slag. The SBF process includes two categories, i.e. to treat copper concentrate and to treat industrial solid waste. Up to now, the SBF process has been applied in around 5 million tons of copper concentrate processing capacity and 20+ plants with high-lead slag reduction process. In recent years, SBF process has been gradually used in zinc leaching slag, electroplating sludge, industrial solid waste (e.g., various metallurgical slag), and electronic waste disposal. The basic principle of SBF process is that the material to be treated is directly charged to bath through charging hole with crushed coal and flux, then, enriched oxygen air would be sent to slag level (Vanyukov/Jifeng style furnaces)or matte level (Baiyin style furnaces) via primary tuyere. In this case, the material completes matte/slag metallurgical reaction of gas-liquid-solid interaction under vigorous mixing, and separate matte and slag at the bottom of furnace hearth. With the help of secondary tuyere, the low-pressure air or enriched oxygen would be provided for secondary combustion in the freeboard. The core of SBF process is process parameter control and engineering design of SBF. Presented as a fixed rectangular type, the SBF is a metallurgical furnace consisting of copper water jackets and refractory material. The SBF is consisting of hearth, middle of furnace and furnace top with the sequence from bottom to top. The middle of furnace itself can be further divided into bath area and post-combustion area with primary tuyere and secondary tuyere at both sides. The furnace hearth is made of refractory bricks, which are fused and rebonded Mg-Cr brick, Mg-Cr brick and clay brick from inside to outside. The furnace top adopts a steel water jacket with charging hole and uptake shaft. The water-cooled partition wall is placed at uptake shaft and near charging hole.

Jan 1, 2019

By Li Qihou, Liu Zhihong, Liu Zhiyong, Yao Wei

Black copper sludge, which mainly contains copper, arsenic and a little antimony, bismuth, selenium, tellurium, is an important recyclable secondary resource. In this paper, selective removal of arsenic from black copper sludge by alkaline oxidative pressure leaching was studied. The influences of alkali concentration, leaching time, leaching temperature, oxygen pressure, liquid-solid ratio and other variables on the leaching rate of arsenic, copper and tellurium were investigated. The results were as follows: when the leaching process was conducted at initial alkali concentration of 1mol/L, liquid-solid ratio of 10, stirring rate of 500r/min, leaching temperature of 140°C for 5 h and oxygen pressure of 2.5MPa, the leaching rates of arsenic and tellurium were 85.43% and 59.7% respectively, and copper, antimony, bismuth were not leached. Hence, arsenic has been removed effectively from black copper sludge, while the valuable metals such as copper, antimony and bismuth remained in the residue that can be further recovered easily. INTRODUCTION Black copper sludge is a byproduct in the purification process of copper electrolyte. Arsenic, antimony and bismuth are major harmful impurities in copper electrolytic refining system. The accumulation of these impurities will cause adverse effects, such as the increase of electrolyte resistance and power consumption and deterioration of cathode copper quality (Wang, Liu, & Zhang, 2001). Hence, electrolyte purification is an essential part of the electrolysis process (Liang, Chen, & Guo, 2009). Electrolyte purification methods include electrowinning (Davenport, King, Schlesinger, & Biswas, 2002), solvent extraction (Navarro, Simpson, & Alguacil, 1999), ion exchange (Arroyo et al., 2017), coprecipitation (Wang et al., 2003, 2018; Xiao et al., 2007; Xiao, Cao, Mao, Shen, & Ren, 2014), activated carbon adsorption (Navarro & Alguacil, 2002), electrodialysis (Cifuentes et al., 2015), redox process (Zhou, Peng, Zheng, Ma, & Cui, 2011; Peng, Zheng, Zhou, & Chen, 2012; Zheng, Peng, Ke, & Chen, 2013), among which the electrowinning method is simple in operation and effective in impurities removal, making it the main process for current electrolyte purification. Some copper ions can react with harmful impurities to form complex black copper sludge by controlling the operation conditions of electrowinning process. Based on the estimated data provide by Davenport et al. (2002), an annual output of 400,000 tons cathode copper could produce 432-2168 tons of black copper sludge by electrowinning method. Black copper sludge contains 30~50% copper, 15~30% arsenic and a small amount of rare elements such as selenium and tellurium. Thus, recovery of valuable metals can bring huge economic interests. Moreover, arsenic in these sludges could cause significant environmental pollution. Therefore, effective removal of arsenic from these sludges is urgent and significant.

Jan 1, 2019

By P. C. Holloway, M. J. Collins, K. R. Buban

Historically, there has been little incentive to process copper-arsenic concentrates by leaching, rather than via established smelting operations. However, with ever tightening environmental emission standards and more arseniferous concentrates being produced, increasingly sophisticated and upgraded off- gas handling facilities are required in smelting operations, generating greater quantities of challenging metallurgical dust. In this context, oxidative pressure leaching offers distinct advantages. The current state of pressure leach technology delivers high extractions from copper concentrates, while producing an environmentally stable process residue, without atmospheric emissions of sulphur dioxide or arsenic. However, as was shown in an earlier study, copper extractions and environmental leach residue stability are impacted negatively by arsenic levels above 2.5 to 3.0 wt%. In further studies on pressure leaching of copper concentrates, Sherritt has developed process conditions that allow even highly arseniferous (> 7 wt% As) feed materials to be converted into environmentally stable residues, with excellent copper extractions. At the same time, pressure leach residues can be generated that are amenable to silver recovery via direct cyanidation, without pre-treatment by lime boiling or hot curing. The results of pilot plant test work are discussed. INTRODUCTION As the production of copper has expanded over the years, resource exploitation has extended beyond relatively clean, high grade and easily accessible ores, and copper sulphide concentrates increasingly come with higher levels of contaminants, such as As, Hg, Sb and Bi, and lower copper and sulphide sulphur concentrations. However, as concerns on the impact of the emission of such contaminants into the natural environment have mounted, import/export restrictions have made the trading of copper concentrate more difficult, and, in particular, the export of concentrates with greater than 0.5 wt% As; under ever tightening environmental emission standards, these lower quality concentrates can be a significant strain on the off-gas handling facilities in smelting operations. The processing of arsenic bearing copper concentrates is, therefore, an increasing challenge as copper producers seek to exploit more complex mineralization and to extend the life of their operations. In this environment, processing arsenical copper concentrates with high temperature pressure leaching (>200°C) must be considered as an alternative to pyrometallurgical processing. Leaching kinetics for copper minerals at these temperatures are rapid and acid is generated for potential use in heap leach operations. Pressure leaching of copper concentrates eliminates gaseous emissions of arsenic and sulphur, while generating environmentally stable residues, as measured by the Toxicity Characteristic Leach Procedure (TCLP) (Kalanchey et al., 2007). Both medium and high temperature pressure leaching of copper concentrates have also proven themselves technically on an industrial scale (Marsden et al., 2004) with high copper recoveries.

Jan 1, 2019

By Changmiao Liu, Dong Dong

"Magnesite is a major mineral resource in China, whose output and export are massive and quite important to the world. Flotation performances of eight anionic collectors on magnesite were studied to find the proper ones. Micro-flotation results indicated that collectors of HOl, SDBS and AEP had outstanding flotation performances on magnesite, with the recovery ratio all reaching above 90% in a wide range of alkaline pulp. Solution chemistry calculation, Zeta potential and FTIR measurements were employed to reveal the interaction mechanism between anionic collectors and magnesite surfaces. Solution chemistry analysis indicated that the main active components of HOl, SDBS and AEP were anions and association complex anions in alkaline pulp. Magnesite surface was negatively charged in the alkaline pulp. The active sites on magnesite surface were mainly the components of MgOH-, Mg (OH)2, and MgCO3 when the pulp pH was over 8. Anionic components of HOl, SDBS and AEP reacted with Mg in magnesite surface to make the insoluble anionic salts. And the chemical adsorption was confirmed by the FTIR measurement evidences.INTRODUCTIONAs an important industrial mineral, magnesite has been widely applied in metallurgy, building materials, chemical industry, agro-pasturage and other fields (Hu et al., 2006). It is a major mineral resource in China with abundant reserves. Its output and export are massive and quite important to the world. Liaoning province is rich in magnesite, whose reserves and production both come first in China. So far the proven reserves have reached 2.91 billion tons, accounting for more than 90% of total reserves in China, and more than 25% in the world (Li et al., 2012).Magnesite ores in Liaoning province mainly contain crystalline magnesite, and the gangue minerals of quartz, dolomite, talc, tremolite, chlorite and carbonaceous materials. Some ores also contain a little pyrite, chalcopyrite, hematite and apatite. Most of the ores must be preprocessed to separate the useful parts from the large amount of gangue minerals, so that their value and industrial application can be enlarged and promoted.Flotation is commonly used to process the magnesite ores, and the conventional flotation methods include anionic and cationic flotation. In the former, gangue minerals of silicates were separated by using amine type cationic collectors. After the impurity minerals were removed, high qualified magnesite concentration could be gained. For the cationic flotation method, it had some drawbacks of lower recovery ratio and poor performance in the lower temperature pulp (Li et al., 1995)."

Jan 1, 2016

By M. S. Moats

"The effects of commercial copper electrorefining additives (glue and thiourea) on the electrochemical removal of bismuth are of importance in copper production. It was found that Bi(III) electrodeposition occurs readily from acidic sulfate solution via a diffusion-controlled quasi-reversible reduction. The diffusion coefficient of Bi(III) was measured and found to be less than reported values of copper in similar solutions. The presence of thiourea and/or glue was found to accelerate or de-polarize Bi(III) reduction on stainless steel as compared to the inhibition or polarization of Cu(II) reduction. The additives also inhibited the dissolution of the Bi-Cu co-deposit during cyclic voltammetry. During short term deposition studies, the additives increased the concentration of Bi in co-deposited Cu-Bi products from solutions with low concentrations of Cu (<2 g/L). Bi deposition was significantly suppressed by increasing the Cu(II) concentration in the solution. The formation of a copper layer on the stainless steel electrode appeared to significantly suppress the reduction of Bi(III). This study demonstrates that glue and thiourea depolarize the deposition of bismuth on stainless steel. Therefore, the additives could be used to improve Bi impurity removal during third stage liberation.INTRODUCTIONThe production of high purity copper has been steadily increasing due to the wide application of the metal and its alloys in electrical and electronic products, infrastructure construction, industrial machinery and equipment, general products and transportation (Moskalyk et al., 2003). Most high purity copper is manufactured from copper sulfide mineral concentrates and/or scrap via a pyrometallurgical process followed by electrorefining (Navarro et al., 1999). During the electrorefining process, cast anodes of 99-99.5% purity are electrochemically dissolved into an acidified copper sulfate solution while high purity copper (>99.99%) is plated on stainless steel blanks or copper starter sheets (Davenport et al., 2002). The control of cathode deposit growth (purity and morphology) while maintaining a high current efficiency is of significant importance for copper refining (Ilkhchi et al., 2007). At typically applied current densities for industrial copper electrorefining, mass and charge transfer play important roles in the quality of cathodic products (Hiskey et al., 1998). If the real current density at some surface points is substantially higher owing to uneven current distribution, then rough spots can and will grow faster leading to nodules (Suarez et al., 1992). Nodulated deposits tend to capture solution and anode impurities (slimes) resulting in unacceptable cathode quality (Afifi et al., 1987). Furthermore, these nodules can grow until they eventually contact the anode leading to short circuits and current efficiency reduction (Ilkhchi et al. 2007)."

Jan 1, 2016

By N. Bartie

Realising the circular economy (CE) is faced with some significant challenges. Process metallurgy and its infrastructure play key roles at the heart of making the CE work. Therefore, the enabling role of process metallurgy within the CE will be central to the discussion in this paper, touching among others on product and system design as well as the key metallurgical and other process fundamentals that need to be investigated and understood to make the CE a reality. The central role of materials and its processing will be discussed in an integrated circular cities perspective. A key focus will be a discussion on designing a resilient “Smart Materials Grid” using and innovating metallurgical process engineering tools, which will manage the flows through Sustainable Circular Cities. The discussion will be using copper as leitmotiv of the discussion i.e. from copper ore, to metal, to complex products, recycling, product design and simulation and its impact. INTRODUCTION The transformation of our economies from linear to circular models in which waste materials become resources is the focus of the Circular Economy (CE) paradigm. Its important intentions: to take control of the damage we have been doing to the planet to ensure its livability and the welfare of future generations. This can only be achieved through careful utilisation of human, natural and economic resources. The concept is derived from several others (Beaulieu et al., 2015), of which Cradle-to-Cradle, Extended Producer Responsibility (EPR), Industrial Ecology, and Life Cycle Thinking are just a few. Other relevant concepts include resource efficiency (RE), design-for-recycling (DfR), and various others discussed by Blomsma and Brennan (2017) and Homrich et al. (2018), as well as various R-hierarchies e.g. Reduce, Reuse, Recycle (3R). However, does society comprehend these concepts, the actors and actions that influence them and how they interact? Do we know the limits of CE? Does society understand the key role of Copper and other metals to rendering the CE operable? True life cycle and systems thinking, focussed on simulation-based, process and metallurgical design are required to answer these questions. Lieder and Rashid (2016) identify nine widely-varying fields that study the concept ranging from sustainability sciences and engineering to economics, business, law, and social sciences. Overlap between questions addressed highlights the need for interdisciplinary collaboration (Nanz et al., 2017) in the assessment of the current status, and further steps needed to transform to CE. This doesn’t apply just in academia, but also in industry where concrete implementation of CE needs to occur at multiple levels, thus necessitating cooperation between government, civil society and other stakeholders (Beaulieu et al., 2015).

Jan 1, 2019

By Gabriel Zarate

"Los Bronces had two ROM dump leach operations designated Leach I and Leach II. Leach I was commissioned in 1998 and stopped in 2014 due to the mine requirements. Leach II plant, commissioned in early 2002, was built to treat around 700 million tons of marginal ROM ore averaging 0.45 % total copper. The mineralogy of this material was estimated to be 70% chalcopyrite, 20% chalcocite/covellite and the balance oxides.The original electrowinning plant design capacity for copper production was nominal 19,500 tonnes per year at a current density of 276 A/m2 and a current efficiency of 92%. Presently, Los Bronces San Francisco plant typically operates at current densities between 390 and 440 A/m2, much higher than the average in the industry, with current efficiencies around 93% and a maximum copper cathodes production of 37,200 tonnes per year.In order to accomplish these achievements, a number of modifications in the process conditions, in the cell hardware and in the operational procedures have been implemented. In the first case, the specific flowrate, copper concentration and temperature of the electrolyte were modified to accommodate the operational requirements facilitating the increased current density. Associated with the cell hardware, a six cells expansion was added, upgraded equipotential inner cell busbars were installed and the cross section of the cathode hanger bars was enlarged for increased current carrying capacity. Documented operational procedures like short circuit detection and cathode weight control were improved.The modifications implemented and the results obtained are discussed in this paper.INTRODUCTIONLos Bronces Division of Anglo American Chile is located up in the Andes Mountains, northeast of Santiago. It had two cathode plants, Los Bronces at an altitude of 3500 meters above sea level (m.a.s.l.) commissioned in 1998 and closed in 2014 and San Francisco at an altitude of 2800 m.a.s.l. and in operation since 2002.The process is leaching run off mine (ROM) low grade copper sulphide ore in dumps. The mineralogy of this material was estimated to be 70% chalcopyrite, 20% chalcocite/covellite and the balance oxides. The average grade is 0.45% total copper (Cut).At Los Bronces dump, Leach I plant, the pregnant leach solution (PLS) was collected and stored in an underground reservoir. From there, it was fed to a solvent extraction plant with a series-parallel configuration in two extraction stages and one stripping stage. The electrolyte produced was fed to the electrowinning plant having 30 cells and 60 cathodes per cell. Maximum capacity of this plant was 12,000 tonnes per year (tpy)."

Jan 1, 2016

By K. E. Haque

"Radium is selectively leachable from uranium ores with various types of lixiviants. Among a number of lixiviants tried on Midwest Lake uranium ore, KCl provided the highest per cent of radium extraction (60%-65%). Leach results further confirmed that a certain portion of Ra is not amenable to KCl leaching. More than 99% of the dissolved radium could be removed by treating the KCl leach liquor with barite or with radium selective complex resin (XFS-43230 resin of Dow Chemical Inc.) or by precipitating as RaBaSO4. Uranium leachings from the Ra-preleached uranium ores indicate that radium leaching prior to uranium may be applied as an extension to the conventional or alternative (i.e. acid chloride) leaching process of uranium ores in order to yield environmentally acceptable tailings (in terms of radium in the solids).IntroductionAt present, radium is considered as an environmental issue, particularly for uranium ore mine mill operations, rather than a commercial commodity. Radium was once a highly priced commodity ($180/mg during the first great war) but now it hardly has any commercial value. Its principal applications were in the field of cancer treatment and in the manufacturing of lwninous dials for watches. Nowadays readily-available synthetic radioisotopes are finding applications in place of radium.Because of scarcity and high toxicity, further commercial applications have never been explored.Radium was first discovered and extracted from uranium ore by P. Curie, M. Curie and G. Bement in 1898. Radium is widely distributed in nature but in exceedingly minute quantities. It is one of the daughter products of uranium or thorium and its maximum concentration is 3.3 x 10-7 part/part of U(21). Because of its short half-life (approximately 1620 years) in a geological time scale, its occurrence in nature as a distinct mineral is most unlikely.The details of the original radium leaching process developed by the Curies and Bernont are in the literature. This process essentially involved the roasting of uranium ore with caustic. carbonate followed by sulphuric acid leaching. The precipitated RaSO4 and BaS04 were treated with boiling Na2CO3 to convert them into the corresponding carbonates which later were dissolved in HCI. RaCI2 and Ba02 were separated and concentrated from the chloride liquor by fractional crystallization. But, in the course of time several modifications were made or proposed to the original process. Regardless of the process employed 226Ra extraction from the uranium ore was seldom better than 90%, and further as much as 20% 2URa loss took place during the concentration and purification process."

Jan 1, 1987

By Lawrence Devon Smith

"The Management and Economics Society has undertaken a survey of industry practice in the evaluation of mineral projects. The survey addresses a number of issues relating to evaluation techniques, discounted cash flow methodology, and risk. Completed during the spring and summer of2005, the results provide a record of opinion at an active and vital time in our industry.The 2005 survey questionnaire was distributed by e-mail to groups and organizations around the world. There were 22 respondents out of several hundred questionnaires distributed (we gather this small proportion of respondents is typical for such surveys). The responses, although a small number, show a consistency that suggests that the survey has captured the views of the industry. The results of the survey are summarized below in series of tables and graphs.The reader is cautioned that the results are a snapshot of industry practice at a point in time as represented by a small sampling of the industry's practitioners. These results should be viewed as indicative values."

Jan 1, 2003

By T. M. Ahmed

Sherritt International Corporation experienced corrosion failures with the 316L stainless steel tubing in a high-pressure still condenser employed for ammonia recovery. A detailed failure analysis was conducted on the condenser tubing to determine the mode and the root cause of the failure. The analysis included both optical and scanning electron microscopy (SEM) of the inner and outer surfaces of the tube as well as characterization of the corrosion products using energy-dispersive X-ray spectroscopy (EDX). Results revealed that the corrosion attack was confined to the first ?100 mm of the tubing at the inlet where the tube was connected to the top tubesheet. The tube suffered both external stress-corrosion cracking (SCC) and crevice corrosion from the shell side (water side), and wall thinning of the inner surface (the tube side) due to erosion corrosion. It was evident that failure of one of the tubes occurred due to SCC that penetrated the whole wall thickness and resulted in a leak failure. Some prevention measures are proposed to avoid this type of corrosion attack in the future.

Jan 1, 2005

By J. Shibata, N. Murayama

"Rare earth elements are present in more than 100 minerals, of which monazite, bastnaesite and xenotime are typical. Rare earth elements have excellent chemical and physical properties for industrial use in functional materials such as phosphors, magnets, electronic components, abrasives and catalysts. China produces more than 90 % of the world’s rare earths, and Chinese trends significantly influence the demand and price of rare earths. From the viewpoint of resource securement, it is desirable to separate and recover rare earth elements from low-grade resources and wastes. Phosphate gypsum, which is a by-product of wet phosphoric acid manufacturing, contains low concentrations of rare earth elements. In this research, the separation and recovery of rare earth elements from phosphate gypsum were investigated. A series of recovery methods including washing of phosphate gypsum, leaching of the rare earth elements with sulfuric acid, adsorption and desorption of rare earth elements by using ion-exchange resin, and precipitation of rare earth oxalates were carried out. The separation of rare earth elements from Ca2+ simultaneously leached from phosphate gypsum was also investigated."

Jan 1, 2014

By E. Ghali, B. Arsenault

Aluminum alloys play an important role in the manufacturing of air and ground vehicles. However, with such alloys, corrosion damage is often found on structural components subjected to fatigue loading. The alloying provides large benefit in terms of the high specific tensile strength (ultimate strength/density ratio) to the aluminum alloy but causes the aluminum alloy to be more sensitive to localized corrosion due to complex microscopic heterogeneities such as secondary phases. This paper investigates thermal spray coating namely arc spraying to evaluate the protection against environmentally assisted cracking (EAC) and localized corrosion on Aircraft structural 7075 T651 aluminum alloys. In particular, EAC and pitting corrosion at the interface coating-substrate are a challenge for thermal spray protective coatings on aluminum alloys under cyclic load and immersion. To address these issues, different surface preparation techniques prior to arc spraying were considered such as chemical de-oxidation, laser ablation, shot peening and grit blasting. Results indicate that surface preparation and improved coating process parameters play an important role to provide a coating conferring a protection against both localized corrosion and EAC.

Jan 1, 2006

By C J. Coveney

This paper, after a brief introduction to the mineralization and structure in the mine area, outlines the methods now being employed for grade control at Bethlehem Copper Corporation. Sampling, subgrade drilling, blasting and the actual outlining of the ore are among the topics covered. The paper concludes with a summary of the results obtained, showing a reduction in dilution and an improvement in the grade of the copper ore going to the mill. Introduction T HE Bethlehem property is located in southern British Columbia in the Highland Valley about 30 miles southeast of the town of Ashcroft. The property is located within the Guichon batholith. The rock comprising the batholith is a massive, coarse-textured diorite, which, at Bethlehem, has been intruded by a younger quartz diorite, porphyries and breccia, referred to as the "Younger Complex." Mineralization, consisting of chalcopyrite and bornite with minor pyrite and molybdenite, occurs as disseminations, fracture fillings and coarse blebs. The ore zone lies close to the Guichon -Younger Complex contact where, prior to the development of the breccia, the rocks were shattered and jointed. Subsequent mineral

Jan 1, 1965

By Sandra L. Mesa-Espitia, Gretchen T. Lapidus

Gold present in arsenopyrite matrices is refractory and requires highly oxidative pretreatments in order to obtain acceptable degrees of extraction. However, these release many byproducts that are harmful to the environment. In the present work, a high-grade arsenopyritic ore was pretreated with different solutions, containing hydroxide ion, EDTA, oxalic, tartaric, or citric acids, to improve gold extractions in a posterior leaching step. The pretreatments were carried out at room temperature for 24 hours with a respective ligand concentration of 0.25 M. Once completed, the residue was leached in a thiosulfate solution to quantify the effect of the pretreatment on gold extraction. Only 29% of the gold content was leached, with very slow kinetics, in the untreated mineral. However, after pretreatment with tartaric or citric acid, the kinetics improved, although the percentage of gold extraction only reached 42-45%. The highest gold recovery, with very rapid kinetics, was found with the oxalic acid or the hydroxyl ion pretreatment (70 and 62%), respectively, but also corresponded to the most arsenic co-dissolution.

Jan 1, 2014

By R. M. Porter

PILLAR extraction at the Sullivan Mine bas been in progress for over twenty-five years and bas .involved progressively larger pillars. The largest pillar blasted to date exceeds one million tons and is described in this paper. This blast is believed to be one of the largest to take place entirely under-ground. The Sullivan Mine, owned by The Consolidated Mining and Smelting Company of Canada Limited, is located in the southeastern corner of British Columbia on the east flank of the Purcell range overlooking the twenty-mile wide Rocky Mountain Trench (Figure 1). The orebody is a bedded replacement deposit in argillites, varying in thickness up to 300 feet, but averaging about 80 feet. Above the 3900 Level, the dip varies from nearly horizontal to 40 degrees; be-low the 3900 Level it varies from 45 to 20 degrees (Figure 2). Pillar extraction follows a plan of retreating outward from caved areas. The size of each blast is determined by the effect which the removal of support

Jan 1, 1961

By R. K. Sidhu, N. L. Richards, M. C. Chaturvedi

Nickel base superalloy IN-738LC, strengthened mainly by the precipitation of y&apos; phase, is extensively used in hot sections of land-based and aero gas turbine engines. Fusion welding, which is one of the most commonly used joining techniques for the repair and fabrication of superalloy components, however, finds a very limited application in case of IN-738LC components, as the alloy suffers from HAZ cracking during welding and during subsequent postweld heat treatment (PWHT). The present paper reports on the two methods studied to reduce the HAZ cracking in as-welded and postweld heat treated GTA welded IN-738LC, viz., the use of various fillers during welding, and the use of appropriate heat treatments prior to welding. The results of the microstructural analysis and crack measurements indicated that the HAZ cracking in GTA welds of IN-738LC was significantly reduced by using age-hardenable fillers with Al+Ti concentration less than that in the base metal in conjunction with a preweld heat treatment developed by the authors.

Jan 1, 2006

By R. Farhat

Coating systems that yield a thermally grown oxide (TGO) protective layer have been proposed as a potential method for extending the lifecycle of components exposed to high temperature corrosion. This is particularly relevant to the petrochemical industry, where any reduction in corrosion rates can yield substantial cost reductions. The primary goal of this project is to develop a coating repair procedure and to investigate the oxidation performance of the repaired location. Electrospark deposition (ESD) was used to repair spalled segments of TGO grown on MCrA1Y substrates using various electrodes possessing mixed crystal structures. Specifically, electrodes of NiCoCrA1Y (BCC-FCC mixtures) and CoNiCrA1Y (FCCBCC mixtures), were deposited and oxidized to develop the TGO using a heat treatment of 24 hours at 1000°C in air. This presentation will focus on the microstructural evolution of the base metal and ESD repair on damaged area, in both as- deposited and oxidized forms. Results of SEM and XRD analysis will be presented.

Jan 1, 2011

By Robert S. G. Chapman, Kieran M. J. Downes

The Sulphide-Preview Lakes area is located 45 km northeast of La Ronge in northern Saskatchewan. It lies within the southern portion of the Proterozoic La Ronge Volcanic-Sedimentary Belt. Two styles of gold mineralization are present in the Sulphide Lake area , stratabound gold mineralization is intimately associated with a pyrite-pyrrhotite-arsenopyrite-bearing graphitic argillite unit within a sequence of intermediate to felsic volcaniclastics. Past operators established three mineralized zones along this horizon with combined reserves for two of the zones, of about 175,000 tons at 0.22 oz/ton Au. In the Preview Lake area , gold mineralization occurs in variably sheared gabbro/quartz diorite sills within a mixed sedimentary-felsic volcaniclastic sequence. Gold occurs with arsenopyrite, pyrite and minor chalcopyrite associated with quartz veins and stringers. A sulphidebearing graphitic argillite unit occurs in close proximity to the mineralized shears. Past operators delineated seven mineralized shear zones, two of which were drilltested. Average gold grades reported are in the 0.1 to 0.2 oz/ton range with erratic values up to 5.0 oz/ton.

Jan 1, 1986

By M. Boussuge

Ceramics and refractories have many common constituents and consecutively exhibit several analogous properties. For example, concerning the thermomechanical properties this paper will focus on, the type of creep that can be observed in both materials is often the same (kinematic hardening). Changes in microstructure (phase transformation, dehydration, sintering, crystallisation,...), induced by heating and/or cooling, can also drastically modify the mechanical behaviour of ceramics and refractories. But the coarse granulates, the porosity and the impurities contained in industrial refractories may lead to specific responses of this material to thermal and/or mechanical loadings. In particular, some differences can be observed with technical ceramics in the main type of damage observed in service : diffuse damage in refractories (microcracking) and localised damage in ceramics (macrocracking). In this paper, the possibilities of transferring a part of knowledge from ceramics to refractories will be discussed, in the field of thermomechanical properties : experimental characterization techniques, mechanical behaviour models. Finally, some problems caused by scale effects and by the integration of thermomechanical properties of refractories in the numerical simulation of industrial structures will be evoked.

Jan 1, 2004

In recent years, China and India have emerged as major players in the copper sector. Over the last decade, around 50% of additional global refined copper usage growth can be attributed to them. The paper provides an overview of the current and future copper supply and demand situation in both countries. Results from two market studies commissioned by the International Copper Study Group (ICSG) are complemented with recent copper statistics on North-East and South-East Asia, as well as further sectoral analysis. Developments and trends in copper mining and metal production, semis production, and major end use areas are highlighted. While providing insights into sectoral patterns and growth trends, the paper provides the basis for comparing structure and output of the copper sectors in some of the major copper-using countries in Asia. Afterwards, the current copper reservoir in use associated with infrastructure, buildings, industrial equipment, transportation systems and households is assessed using the ICSG Copper Flow Model. Finally, the identified copper flows are analyzed regarding the potential impact on the future world supply and demand situation.

Jan 1, 2007