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By Paul Guliov

Potash dominates the industrial mineral scene in Saskatchewan accounting for 44% of total provincial mineral production in 1981. More than 7 million tonnes of potash have been produced annualy in recent years; ten underground mines are presently (1983) active. Sodium sulphate and cement are also important mineral products. Construction aggregates, clay products, bentonite, salt, peat moss and sulphur complete the list of industrial mineral products.

Jan 1, 1984

By R. Alarcón Sch., R. Abel F.

For many years, copper cathode quality has been a priority for end consumers, since it affects the variety of products that can be obtained from them. From the beginning, physical and chemical quality of the wire bars was controlled, as this product was used to obtain wire rod and other forms of copper by wire drawing. At that time, all the electro refined cathodes were melted and casted as wire bars. Subsequently, in the 80’s, with the introduction of continuous casting furnaces, it was possible to directly produce wire rod from cathodes. From then on, cathodes quality standards were consistently increased, by the introduction of uniform criteria, among which we can identify ASTM and British Standards as well. Also, producers began to use more demanding internal standards than the existing specifications, in order to differentiate their cathodes as high quality products among customers. Today the physical aspect of cathodes, including nodules, cracks, sulfates, or others, is the first element used by end customers to assess their quality. This paper aims to show a brief vision of the evolution of quality specifications for products used to manufacture copper wire. INTRODUCTION From the beginning of refined copper production for industrial purposes, mandatory minimum quality conditions were established. These quality conditions were used as the main element to determine prices and discounts of the respective sales contracts. Reviewing the copper development history, we can appreciate that its quality requirements had been constantly evolved, so that currently refined copper has an extremely high quality standard, that allows its direct use in the production of ultra-thin cables and other products applied in the industry. In each stage, refined copper production has fostered the development of technology used in their treatment. Similarly, cathode processing technology has been evolving to minimize treatment costs in order to generate a wire rod for several uses, ranging from power cables to super conductors. In this sense, to the already known type of fusion processes of the Southwire or Asarco type (capacities over 80 kt / year), wire rod production processes of the Upcast or Rautomead type (capacities between 20-50k t / year) have been added. They immediately deliver oxygen-free wire rods. In both cases, we can conclude that the clients' requirement had evolved from a chemical criteria focus, to considering more subjective aspects, such as visual control as the first stage of inspection.

Jan 1, 2019

The effect of superficial gas rate distribution (Jg profile) on down-the-bank metallurgical response was tested in the rougher-scavenger bank (eight 10-m3 tank cells, 4 roughers and 4 scavengers) at Highland Valley Copper Mine's Cu/Mo separation circuit. Three Jg profiles were tested: (a) as found (i.e., typical practice), (b) increasing decreasing (i.e., increasing from cell 1 to 4 and decreasing from cell 5 to 8), and (c) decreasing-increasing (i.e., decreasing from cell 1 to 4 and increasing from cell 5 to 8). The Jg profile approach proved to be of considerable value. Profile (b) gave the best metallurgical results, i.e., the highest down-the-bank grade/recovery (increase in grade at constant recovery was approx. 3-4% compared to the as found case) and the most efficient Cu/Mo separation (cumulative Cu recovery was reduced by almost half - approx. from 20% to 12%, at 99% Mo recovery). The success of the evaluation prompted the implementation of profile (b). Detailed gas dispersion characterization tests (Jg and Db (bubble size)) showed significant discrepancies between the Jg measured directly (using the McGill University sensor) and the Jg calculated from field instrument readings (volumetric gas flowmeter) and machine dimensions (cell cross-sectional area). Tests were designed to reveal the source of disagreement. It was observed that a significant number of bubbles were not able to float (i.e., they were entrained with the tailings), the evidence appearing to be a significant number of very small bubbles (approx. 200-300 µm) which did not have sufficient buoyancy to rise. Consequently, rather than relying on the field instrument, the evaluation depended on the McGill University Jg sensor, which collects bubbles in a tube near the pulp-froth interface, thus providing significance to the data as the measurements were obtained from bubbles that almost certainly floated.

Jan 1, 2007

By Gary Walters, Matthew White, Thomas W. Gonzales

The copper smelting industry has transitioned into the 21st century compliant with environmental regulations, new smelter installations and brown field expansions. The industry faces new challenges as copper in concentrate grades have decreased while contained impurities have increased. A new benchmarking survey was undertaken to update the last survey of 2016 for operating copper smelters in the world. The information collected was separated based on primary smelting technology rather than by geographical location and supplemented from published literature. Each smelting technology’s unique use of specialized process equipment, concentrate smelting capacity, and impurity flexibility are discussed INTRODUCTION The 20th century was a remarkable time for the growth of copper smelting. Electric, blast and reverberator furnaces dominated the smelting technology well past WWII. In the 1970s, SO2 regulations and high energy cost drove the development of new primary smelting technology. Technological advancements decreased energy consumption and enriched sulfur dioxide concentrations of the process off-gas to levels where sulfur capture in sulfuric acid plants was economically viable. The new smelting technologies began to replace reverberatory and electric furnaces starting in the late 1940s. A new paradigm in copper smelting was established and the enabler was then Outkumpu’s® flash smelting technology from the 1940s through to today. Now, Outotec had become the dominant primary smelting technology with over 44 copper flash smelting furnace installations world-wide. Figure 1 shows the historical installation statistics of primary smelting technologies over the last 70 years (ICSG 2018). The dominance and acceptance of the Outotec® smelting technology from the 1940s to current can be seen. Isasmelt® technology for copper was introduced in the 1970s and did not see advancement in new installations until the 1990s through today. Isasmelt® has 12 world-wide copper furnace installations to date. Mitsubishi® also introduced continuous smelting and converting technology in the 1970s, but had no new installations until the 1990s with a total of 5 copper smelters. Outotec Ausmelt® smelting technology had 3 installations in the 1990s and totals 10 furnaces. Most recently the Chinese technology of Bottom Blown and Submerged Lance Smelting began commercial operations in 2005 for total installations of 11, mostly in China. Other technologies, such as, El Teniente, Noranda, Inco, and Vanyukov furnaces have contributed to the overall global smelting capacity, but have not penetrated the smelting industry to challenge the existing dominant smelting technologies. The technology distribution in Figure 1 also shows flash smelting technology for sulfide concentrate domination untill 2000, bottom blow technology has become the preference in China. Currently, China is the only country building new smelting capacity. Isasmelt® technology also seen a large increase in installations in the current decade.

Jan 1, 2019

Over five decades ago Kitchener et al. in England and La Mer and Healy in the US were advancing our understanding and application of flocculants, primarily related to water treatment and filtration of sludge. This paper identifies the beneficial uses of flocculants in the mining industry and revisits some less common applications. Flocculants are used in unique ways in the mining industry: (a) to increase the effectiveness of sediment ponds to achieve discharge compliance; (b) to eliminate air emissions and costs associated with concentrate drying; (c) to reduce soil loss by applying a flocculant to erodible soils, and reducing wind and water erosion; (d) to remove/thicken metal precipitates in acid rock drainage treatment; and (e) to enhance clarification and thickening in mineral processing. The mechanism of how flocculants, coagulations and potentially-determining ions function is described and how their use can be controlled and optimized. The potential toxic effects of flocculants and coagulants when used to achieve effluent permit discharge compliance for suspended solids is discussed. A review of numerous best management practice (BMP) guidelines for the design and operation of sediment ponds treating mine site runoff to remove total suspended solids (TSS) and turbidity revealed an absence of a predictive methodology to address regulatory discharge compliance for TSS concentration, turbidity and flocculant-induced toxicity. An essential component of pond design is the need to determine whether flocculants and/or other settling aids are required based on the site-specific soil particle size distributions upslope of the pond. Procedures are provided to predict the need for settling aids and estimate pond discharge quality and downstream impact for TSS, turbidity, toxicity and sub-lethal toxicity. The need to develop BMP guidelines are discussed for (a) the application of flocculant to surface soils to reduce erosion, (b) the application of flocblocks to increase the ?sediment control? aspects of erosion and sediment control, as part of the mine site erosion control plan strategy and (c) the application of flocculant to silt socks to treat mine site runoff.

Aug 1, 2013

By R. J. Mitchell

"Centrifuge modelling of earth structures is a well-proven technique for evaluating the performance of prototype structures using physical models. The applications of this technique have increased dramatically during the last decade such that even the modelling of dynamic responses in structures has been accomplished.This paper presents the first model test results used to design a mine backfill. The models were tested using a 3 m radius 30 g-tonne geotechnical centrifuge which was constructed at Queen's University specifically for model studies on mine backfill stability and subsidence. The models represent the first production blast-hole stope to be mined at Westmin Resources Ltd. 's H. ~ Mine on Vancouver Island. This paper includes photographs of:model failures in the centrifuge and correlations of model test results with analyses based on unconfined and triaxial test data.IntroductionDuring the feasibility study and development stages for the H.W. Mine, Westmin Resources Ltd. conducted a comprehensive rock mechanics and backfill engineering program. The results of these studies indicated the need for assurance of backfill stability during pillar recovery on the initial blast-hole mining block. The cemented tailings backfill had to be free standing for heights up to 25 m and the potential for surcharge loading from a weak hanging wall zone, the potential for fill block sliding down-dip and the potential for seismic loading had to be considered in the design of the fill strength. The basic questions to be answered were: what cement content is required and will the resulting backfill costs be economic relative to the proposed mining method and sequence? Figure I shows a typical cross-section through the first mining block . The up-dip stope is to be mined first and backfilled with cemented tailings . The down-dip stope would then be mined and filled. Depending on ground conditions encountered, the complete intervening pillar could be recovered and the void backfilled with uncemented tailings or it could be recovered in small sections by exposing limited back and wall areas, backfilling with waste rock and I or cemented tailings . This latter method is commonly referred to as the Avoca method"

Jan 1, 1987

By Kazuteru Tozawa, Robert G. Robins

"The stability of calcium arsenate is discussed in relation to the possible misuse of lime in the treatment of gold processing waste waters. Stability diagrams have been derived and experimental results cited to show that calcium arsenate has a higher solubility in neutral to alkaline solution than has previously been recognized and this solubility is further enhanced by the presence of carbon dioxide, bicarbonate or carbonate.IntroductionThe removal of arsenic from gold mine waste waters has been of interest for more than thirty years, but with the recent emphasis on clean water standards there has been renewed activity in relation to that problem. The processing of gold-bearing sulphides which contain arsenopyrite and other complex arsenic sulphides is well established. Initial roasting to oxidize the sulphides leaves the arsenic in the form of both arsenic and arsenic, in which forms it is soluble in the subsequent leaching stage. Further oxidation of the leach liquors is required before the well-established procedure of precipitating calcium arsenate with lime, which is carried out despite an immense lack of knowledge of the calcium-arsenic-water system.The solubility product and free energy of formation for Ca3(AsO4)2, which are to be found in recent and reliable sources of data, originate from the work of Chukhlansev, whose experimental determination of the concentration of calcium from the solubility of calcium arsenate in solutions of various pH yields the results plotted in Figure 1. This is the work which has resulted in a wide acceptance of the ""insolubility"" of calcium arsenate and the use of lime to stabilize arsenic in that form.Laguitton attempted to further elucidate the chemistry of the lime addition method for treating arsenical waste waters from gold processing operations. The low solubility product for Ca3(AsO4)2 was the basis for his examination of likely chemical equilibria in the system. Laguitton and other workers have not considered atmospheric carbon dioxide as an important component in this system."

Jan 1, 1982

By H. Bannach

"This paper focusses on what seem to be the leading indicators of prosperity in the minerals industry during this decade: the geographical distribution of deposits, environmental impact, capital allocation and acid consumption. There is a potential for meeting environmental criteria at a reasonable profit margin, but those with limited acid demand within economic range will face hard times to meet growing environmental concerns, resulting in additional mine closures. At the other end, those with old waste dumps who are thinking about smelting capacity additions will need capital influx at a much larger rate than ever before. All things considered, a change should be made in the way the world's copper reserves are computed, because there is a growing need to internalize these effects back to the ore blocks before a meaningful estimate of reserves becomes available.IntroductionThe copper industry has undergone several changes during the past decade, many of which were expected to take place because they rel1ect the economics of ageing mines. However, many others took place that shocked the industry because they were not completely under control. The focus of this paper is to rel1ect on those changes, and on market expectations for this decade that somehow depend on their impact.To review the prospects for new mine developments and expansions from an industry perspective to a full extent, it would be necessary to consider not only the deposits themselves, but also geographical constraints, environmental constraints, labour composition, technology development and use, the availability of capital, ownership issues, and integration within the industry. This paper, however, will concentrate on only some of the key elements that are believed to playa major role in shaping the market in the decade that has just begun. These elements, all interconnected, are:"

Jan 1, 1992

By Rodgers Peale

The Waite mine, as it is locally termed, is situated in the Rouyn district, in the townships of Duprat and Dufresnoy, Quebec, and lies about 340 miles north of Toronto. Due to the impetus given prospecting in the Rouyn district by the discovery, some years ago, of copper-gold ore on the Horne claims, many exploration parties were put into the field. Early in 1925, J. H. C. Waite, C. H. Ackerman, and T. Montgomery staked the claims which now comprise the mine beating their names. Trenching and diamond drilling soon disclosed an ore-body of commercial size and grade, and by the end of 1928 a shaft had been sunk 300 feet and the mine was producing 150 tons of direct-smelting copper ore a day. In the summer of 1925, Dr. H. C. Cooke, of the Geological Survey, made a reconnaissance survey of the property (1), and since that time work of the same nature has been done by several others. MacGregor has published some interesting data on the Amulet mine (2). Using as a background a summer's work on the Horne claims at Noranda, the writer spent the summer of 1929 at the Waite.

Jan 1, 1931

By The Staff

Development of the Eldorado Mine THE pitchblende-silver deposits of Great Bear lake, Northwest Territories, were discovered by Gilbert LaBine in 1930. The property owned by Eldorado Gold Mines, Limited, consists of 53 claims situated, for the most part, on LaBine point, on the northeast shore of the lake. The Company also holds a group of 10 claims on Dowdell point, 7 miles to the southeast of the main group and across Echo bay. The fractures traversing the ridge on LaBine point can be readily seen from the air. Lack of overburden and the scantiness of vegetation leave rock exposures which are visible for miles. The years 1931 and 1932 were spent largely in staking, prospecting, and examination of the outcrops. A small Diesel plant was shipped to the property in 1932 and underground operations were started. Entry was made into the ore-body by means of an adit. A 20-ton mill was completed in the winter of 1933-34, and since then operations have been continuous, except for temporary shut-downs for additions to the mill. TRANSPORTATION The mine is situated 28 miles south of the Arctic Circle and is reached by an air route of 1,140 miles from Edmonton. The water route follows the course of the Mackenzie River system from Waterways, Alberta, the end of steel, and is approximately 1,450 miles in length. Two portages, at Fort Smith and on the Bear river, respectively, are necessitated by the occurrence of fast water. Transportation was one of the major problems to be solved, and Eldorado Gold Mines, Limited, found it necessary to embark upon both water and air freighting on its own account. The Company now operates a Bellanca 'plane with a payload of 4,400 pounds, and a complete water transportation system. The latter was established some years ago by the Northern Transportation Company and it is still operated under that name, but the Company is now a subsidiary of Eldorado. Modern steel boats, oil tankers, and barges were added to the fleet this season. The greater part of the ore shipments are made by water, aircraft being used for this purpose only when occasion demands. Freight rates have been greatly reduced by direct ownership of carriers. For example, water-borne freight is now quoted 'to the mine at $ll0 per ton, as compared with $240 per tan four years ago.

Jan 1, 1938

By L. McFarlane, D. Rollwagen

"Madawaska Mines produces a uranium precipitate (83-85% u3o8) using a magnesium oxide slurry to precipitate the uranium from solution. The solution, at approximately 9""0 g/l u3o8 is neutralized to a pH of 7.0. At the Eldorado Nuclear Refinery in Port Hope, the precipitate is not acceptable as a single feed to the refinery process. It was discovered that a 2% silica impurity caused emulsion problems in the solvent extraction column.After extensive studies of possible solutions, such as two-stage precipitation and solvent extraction, an acceptable solution was found. The selective precipitation of uranium at a pH of 3.5-4.0 using Hydrogen Peroxide produces an almost silica free product of higher purity (90-93% u3o8) to that of straight magnesium oxide precipitation. Introduction Madawaska Mines Limited is located four miles southwest of Bancroft, Ontario. The annual production of u3o8 is approximately 610,000 pounds. To produce the final product or yellowcake, nine separate steps are required. These are (1) grinding, (2) dewatering, (3) leaching, (4) acid filtration, (5) clarification, (6) ion exchange, (7) precipitation, (8) washing, and (9) drying and packaging. To illustrate these steps, a complete flowsheet of the mill is displayed on page three.The yellowcake is sent to Eldorado Nuclear Limited in Port Hope, Ontario for further concentrating and refining. As part of their routine specification check, a test called the amenability test is performed. This test indicates how a particular dissolved yellowcake product reacts to solvent extraction. The Madawaska yellowcake did not pass the test."

Jan 1, 1982

By Jun Shan

The preparation of poly(N-isopropylacrylamide)-monolayer-protected clusters (PNIPAM-MPC) of gold nanoparticles was carried out in a homogeneous phase using three ways, in which three types of PNIPAM ligands were employed. The first type comprised of PNIPAMs with narrow molar mass distributions, synthesized by reversible addition-fragmentation chain transfer (RAFT) polymerization and thus, bearing a dithiobenzoate at the chain end. These polymers were used directly to passivate the gold nanoparticles upon the Schiffrin reaction in a one-pot synthesis. The second type of ligands was derived from the first one through hydrazinolysis, and they therefore contained a thiol end group. The third type of ligands was PNIPAMs obtained through conventional radical polymerization, post-modified to contain thiol end groups. The PNIPAM-MPCs were characterized by high-resolution transmission electron microscopy, and by dynamic light scattering. The one-pot synthesis utilizing the ligands of the first type turned out to be a simple and facile method, compared with the other two ways, with which the size of the gold nanoparticles can be easily manipulated mainly by adjusting the molar ratios of PNIPAM / HAuCl4. PNIPAM is a more efficient ligand to stabilize the gold nanoparticles in water and in organic solvents than alkanethiols. The surface density of PNIPAM chains ranged from 1.8 to 3.6 chain/nm2, which is much lower than that typical for alkanethiols. The thickness of a PNIPAM monolayer bound to the gold core is somewhat larger than the size of the random coil of corresponding free PNIPAM in aqueous solution, which suggests that the conformation of a PNIPAM chain bound to the gold core is to extended.

Oct 1, 2003

By G. S. Hume

THE Plains of east-central Alberta herein described embrace an area from Viking east to the Saskatchewan boundary and from North Saskatchewan river south to Coronation and Monitor (Figure 1). By far the greater part of this area is deeply drift-covered, and .outcrops of bedrock are relatively few and often widely separated. Within the area there are large morainal hills and others of considerable extent that superficially have all the characters of morainal hills but contain a core of bedrock. These latter, then, were hills when the ice sheet traversed the country and only have been modified by glacial agencies. In many places on them, the drift is but a thin veneer, as is certainly the case in part of the Neutral hills (Figure 2) northeast of Coronation and north of Monitor. In other cases, however, as in the Blackfoot hills, southwest of Lloydminster, the drift is sufficiently thick to conceal practically all the bedrock and in many places no information is available as to whether a bedrock core, representing a pre-glacial hill, is present. There is no question, however, that the larger river valleys, as for example those of the North Saskatchewan and Battle rivers, are in part at least pre-glacial. Proof of this can be demonstrated in many places, because obviously the valleys must have been present in pre-glacial times to allow glacial deposits to have accumulated in them. It is also known that inter-glacial deposits occur. At one locality in Battle River valley, in sec. 30, tp. 45, range 2, west of the 4th mer., the following section occurs( l ): 15 feet of boulder clay with granite and other boulders. 56 feet of stratified sands, clays, and gravels containing pebbles of Precambrian rocks and fresh-water shells. From this it is apparent that the 56 feet of stratified sands, clays, and gravels must have derived their Precambrian pebbles from a previous glaciation of which the overlying boulder clay represents another ice advance in this area. Thus, although the river valleys contain glacial and interglacial deposits, they have not been filled by them to such an extent that the drainage has been diverted, and in many places, especially in the case of Battle river and some smaller streams, the size of the valley is altogether out of proportion to the size of the stream it now contains.

Jan 1, 1937

By I. Farr, P. Quinn, H. Mani

"Difficulties in the flotation of Inca's ultramafic ores at the Thompson Mill are related to the presence of serpentine slimes and some floatable rock minerals. Serpentine slime coatings depress pentlandite recovery while rock flotation decreases concentrate grade. Carboxy methyl cellulose (CMG) has been shown to promote sulphide flotation and to reject floatable rock.To improve ultramafic ore flotation, CMC addition in the rougher stage was studied in a laboratory scale column. Batch tests were conducted in the lab and followed up with continuous testwork at the Thompson mill. At 0.5-1.0 g CMG per kg ore, pentlandite recovery is increased by 5-10% in rougher flotation, pentlandite/rock selectivity is improved and pentlandite/pyrrhotite selectivity is unaffected.IntroductionAt Inca's Manitoba Division, two distinctly different sulphide ores are processed at the Thompson Mill, primarily by froth flotation. The sulfide ores are contained within the Thompson Nickel Belt and currently there are two operating mines, Thompson and Birchtree. Sulphide mineralization in both mines is simple, consisting of pyrrhotite (both monoclinic and hexagonal), pentlandite, and minor chalcopyrite. Both deposits are hosted by metasedimentary and metavolcanic rocks with variable ultramafic rock associations. Ultramafic rocks are mostly serpentinites: magnesium rich rocks composed predominately of serpentine. There is little serpentinite at the Thompson mine, while mineralization at Birchtree is closely associated with significant ultramafic rocks.Excellent recoveries of pentlandite (Pn) and chalcopyrite (Cp) are achieved at the Thompson Mill when processing ore from the Thompson mine. In treating the ultramafic associated Birchtree ore, nickel recoveries are some 6 to 8% below that achieved with Thompson ore. Furthermore, a typical concentrate from Birchtree ore contains more rock and is higher in MgO content. The presence of rock in the concentrate is related to free floatable rock species as well as rock locked with sulfides. The reason for the difference in flotation responses of these two ores has been the subject of on-going re-search."

Jan 1, 1998

By Corby G. Anderson

"Laboratory testing using industrial electrowinning solutions was performed to determine the best Faradic cell efficiency for copper cathode recovery. The variables tested were solution flow rate, recycle ratio, reagent addition combinations of guar and thiourea, and addition amount of acid mist suppressant CAL FAX DBA-70. The ideal flow rate was determined to be 37.85 litre/min. Additionally, the ideal recycle ratio was determined to be 10:1. The reagent addition scheme from testing which showed the highest efficiency was with 680 g/tonne guar of cathode copper won and with 135 g/tonne thiourea of cathode copper won. These values for reagent addition only reflect the best efficiency and should not be assumed to be the best reagent concentration for copper purity. The amount of foaming agent that showed the best efficiency was the test with 2 ppm of foaming agent. Again this amount of reagent is based on efficiency and should not be taken as the amount of reagent that does the best acid mist suppression. Additional proprietary surface characterization work indicates these additives may have enhanced the cathodic reduction surface morphology of some noble minor impurities. Subsequently, these operating parameters were introduced into the plant operation and proved successful after their implementation.BACKGROUNDCopper electrowinning has become a dominant technology for the production of marketable high grade copper cathode products. The literature is robust with applications, optimizations, additives and developments in this field (e.g., Classens & Harris, 1990; Pfalzgraff, 1999; Tozawa, Su, & Umetsu, 2003; San Martin, Otero, & Cruz, 2005; Houlachi, Edwards, & Robinson, 2007; Romero, Avila, Fester, & Yacher, 2007; Marsden, 2008; Beukes & Badenhorst, 2009; Vainio & Weatherseed 2009; Bender, 2010; Joy, Staley, Moats, Perkins, Uhrie, & Robinson, 2010; Khouraibchia & Moats, 2010; Moats, 2010; Rutledge & Anderson, 2015).Tests of forty hours duration and at room temperature were performed for this project using samples of actual industrial electrowinning solutions. These industrial solutions were comprised of 60 g/L Cu plus 65 g/L Ni, 3 g/L Fe, and 30 g/L free sulfuric acid. Other confidential minor impurities were also present including some solubilized precious metals. The testing apparatus utilizing stainless steel anodes and cathodes is illustrated in Figures 1 and 2."

Jan 1, 2016

By A. R. Laplante

"In this paper, the performance of the Knelson Concentrator and of the batch and continuous Falcon Concentrators are compared. The units are based on different operating principles, and as such they perform quite differently. The Knelson yields very high free gold recoveries over a wide size range of both the recovered and rejected species. It is ineffective in recovering very fine ( <15 µm) or flaky gold, as encountered in flotation feeds, concentrates or tails. It is the: preferred unit for gold recovery from grinding circuits. The batch Falcon is effective in the fine range, typically less than 37 µm for gold. Its recovery zone is quickly saturated when there is significant heavies in the feed. It works best as a pre-concentration unit. The continuous Falcon is a versatile unit which is capable of recovering fine heavies (density down to 5 g/cm3 ), especially from coarser gangue. INTRODUCTIONThe purpose of this presentation is to describe the mode of operation of two Canadian centrifugal concentrators, the Knelson and Falcon. It is hoped that it will prove informative to prospective users in the selection, testing and optimization for applications of either machine. The work is based on testwork both in Canadian mills and at McGill. I am indebted to many colleagues at these locations. Appropriate references will be made to articles further describing the work, either already in the open literature or in preparation.Although this work is meant to be more practical than scholarly, it is appropriate to begin by considering how the two units achieve selective recovery. This will become useful in establishing a suitable testing methodology, which will then be described, and interpreting typical results. In the last section I will attempt to define appropriate applications for the two units. This is a thankless task, as I am likely to miss some applications or to make projections based on partial results, as much of the work is still in progress. In deference to the reader and both manufacturers, areas where reasonable doubt still remains will be identified."

Jan 1, 1993

By C. Matthews, A. Vo

Australia is one of the world’s leading exporters of bulk commodities and the extensive use of sampling equipment is key to the successful management of each mining operation. At the process plant, without a full understanding of the feed, product and tails, it is impossible to fully optimise the performance of the plant, such that the metallurgical balance is often open to error. At the port, a statistically correct, bias free and compliant sampling system is crucial to ensuring exported minerals are reflective of their true value and to avoid penalties. Over the last decade, as a result of the iron ore boom, there has been high demand for reliable, representative and standard compliant solids sample systems in Australia. This paper reviews several solids sampling applications at Australian mine sites, the challenges and experience gained and how the implementation of reliable representative sampling systems has provided better understanding of plant process performance, improved plant control and overall benefits to the operations. INTRODUCTION Mining is the primary contributor to the Australian economy with Australia ranking in the top 4 in economic resources for 21 primary industrial minerals in 2016 (Britt, et al., 2017). Australia is one of the world leaders in the export of the majority of its commodities including gold, copper and iron ore (Britt, et al., 2017). Therefore, a suitable and standard compliant sampling system is essential for evaluating plant performance and content verification. At the mine and at the port, the larger iron ore miners in Australia have developed stockpile models to predict the grade of their ore down to individual blocks of the stockpile. This allows the miner to create the right blend of material for sale to their customers and ensures they are not underselling their product or at risk of penalties for impurities or low grade. As an example, the average difference between the benchmark 62% Fe and low grade 58% Fe fines at the time of this report averaged US $20/tonne according to the Metal Bulletin Iron Ore Index (Fastmarkets MB, 2019). At a shipload of 180kt this would be a variation of US $3.6M. Whilst this is an extreme example, it highlights the economic importance of producing the correct grade product and a recognised representative sample of said product.

Jan 1, 2019

By S. Eckert, M. Reuter, O. Keplinger, D. Obiso, N. Shevchenko, M. Akashi

We report on laboratory experiments focusing on bubbling phenomena arising from gas injection through a top submerged lance (TSL) in a liquid metal layer. The objective of this study is to reveal the characteristics of the formation and behaviour of the particular bubbles at different gas flow rates and submergence depths of lance. Visualization was performed in the eutectic alloy GaInSn using X-ray radiography. Argon bubbles were injected through the injection positions at three different submergence depths. Essential parameters such as the bubble size, bubble shape, detachment frequency and the two- dimensional gas distribution in the flat vessel were obtained by image processing. The results show that the deep position of the submerged lance causes an asymmetric large-scale circulation inside the fluid vessel. Bubble detachment frequencies were calculated by Fast Fourier Transformation from fluctuations of the image intensity in the vicinity of the nozzle injection point. This frequency does not show strong variations with respect to changes of the gas flow rate and the submergence depth of the nozzle. An increasing gas flow rate results in an increasing two-dimensional projected bubble area and the occurrence of a significant number of small bubbles being trapped by the strong fluid flow in the liquid metal layer. INTRODUCTION The Top Submerged Lance (TSL) process has been an essential component of the metallurgical industry since the emergence of first concepts about 50 years ago (Floyd, 2005). The process, which is characterized by blowing reactive gas through the submerged lance into a liquid bath, was developed mainly for improving the tin smelting process and has been applied for waste treatment or the production of several metals such as copper, lead, nickel and zinc. The productivity of the reactor is determined mainly by the efficiency of the chemical reaction between the gas or solid particles and the liquid. To achieve a high efficiency requires good exchange between the gas-liquid phase and therefore a large interface area. The efficiency changes greatly with the number and size of bubbles injected from the nozzle and the extent of splashing on the free surface. The degree of turbulence in the bath plays a decisive role here. For the reason, the design of an efficient TSL process requires a profound knowledge of the fluid dynamics especially for complex multiphase flows.

Jan 1, 2019

By D. Hu, L. Matzar, J. Hampton, M. Gutierrez

Nanodarcy permeability is common in many oil- and gas-bearing formations requiring unconventional stimulation technologies, such as hydraulic fracturing (HF), which can connect the isolated hydrocarbon-rich pores with a wellbore through induced fracture networks. Even though a dense induced fracture network is capable of accessing economic amounts of hydrocarbons, much of the rock between and very close to the fracture network is still un-accessed and contains extremely low permeability. Inducing fracture networks into brittle rock can create large amounts of micro failures in surrounding regions that are not connected to the wellbore, as can be seen in Fig. 1(a) from the very wide acoustic emissions (AEs) cloud associated with a narrow fracture generation. It is possible in certain types of rock to increase the effective matrix permeability in localized regions based on the damage associated with the surrounding hydraulic fractures and subsequent high stress concentrations along localized pre-existing potential failure zones. To study this problem, laboratory HF tests were performed at true-triaxial stress state in brittle crystalline rock while monitoring AEs. The AE associated with HF was analyzed for source parameters using the moment tensor inversion method called Simplified Green’s Functions for Moment Tensor Analysis (SiGMA). Using the moment tensor for each individual AE event, the mode of failure was determined. Crack slip directions and crack face normal directions were also found, along with the relative volume of individual micro failures as well as a damage parameter. The associated source parameters were used to classify differing regions of damage in the sample induced from HF and correlate these regions of differing damage to the effective drainage region. Shown in Fig. 1(b) is a near-wellbore (NWB) region that contained three times larger average relative volumetric deformation of individual tensile AE events than the average tensile AE event volume from the entire sample. Because of the large difference in micro fracture volumetric deformation for the NWB region compared to the entire sample, predictions of HF induced damage must be included in reservoir drainage predictions.

Jan 1, 2015

By Minghao Hu, Hongbo Zhao, Jun Wang, Wenqing Qin, Rui Liao, Central South University

"In the present work, X-ray diffraction (XRD) analysis, X-ray photoelectron spectroscopy (XPS) analysis and electrochemical analysis were carried out to investigate the intermediate species and electrochemical dissolution process of chalcopyrite in the presence of sulfur and iron oxidizing microorganisms. For bioleaching of chalcopyrite by the sulfur oxidizing microorganism Acidithiobacillus caldus, the redox potential was always lower than the appropriate value and chalcopyrite was mainly directly oxidized to polysulfide (Sn 2-), thus resulting in low copper extraction. As for bioleaching of chalcopyrite by the iron oxidizing microorganism Leptospirillum ferriphilum, chalcopyrite was mainly directly oxidized to polysulfide at the initial stage where redox potential was lower than the appropriate value and resulted in low dissolution rate. At the middle stage where redox potential was appropriate (about 350–480 mV vs. Ag/AgCl), chalcopyrite was mainly transformed to intermediate species of Cu2S rather than polysulfide, thus resulting in high dissolution rate. At the later stage where redox potential was higher than the appropriate value, chalcopyrite was mainly directly oxidized to polysulfide which caused the later passivation of chalcopyrite. Finally, a model of electrochemical dissolution process of chalcopyrite in the presence of sulfur and iron oxidizing microorganisms was provided.INTRODUCTIONBiohydrometallurgy is considered as one promising mineral processing technique in processing low grade ores due to the advantages of simplicity, low cost and eco-friendly. Chalcopyrite (CuFeS2) is the most abundant copper-bearing resource, accounting for appropriately 70% of the known reserves in the world, while is recalcitrant to bio-hydrometallurgy mainly due to the coated passivation layer (Klauber, 2008; Li, Kawashima, Li, Chandra, & Gerson, 2013). However, the detailed dissolution and passivation mechanisms of chalcopyrite bioleaching are still uncertain. The microorganisms assisting chalcopyrite dissolution can be mainly classified into three types, including mesophilic microorganisms (e.g., Acidithiobacillus ferrooxidans, Acidithiobacillus thiooxidans and Leptospirillum ferrooxidans), moderately thermophilic microorganisms (e.g., Acidithiobacillus caldus, Sulfobacillus thermosulfidooxidans and Leptospirillum ferriphilum), and extremely thermophilic microorganisms (e.g., Metallosphaera sedula, Sulfolobus sp., Acidianus sp., and Sulfurcoccus mirabilis). Moderately thermophilic microorganisms have a better prospect in the future industrial application of chalcopyrite bio-hydrometallurgy (Olson, Brierley, & Brierley, 2003; Rohwerder, Gehrke, Kinzler, & Sand, 2003). Hence, investigating the detailed dissolution and passivation mechanisms of chalcopyrite bioleaching by moderately thermophilic microorganisms is of important significance, which will provide essential information for promoting chalcopyrite bioleaching by moderately thermophilic microorganisms in laboratory or industrial plant."

Jan 1, 2016