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By M. Sengupta, A. A. de Gast

"With rapid deterioration in the urban environment caused by air pollution, the possibility of chemical reaction between dimension stone and the industrial waste gases present in the ambient atmosphere remains. The chemical reaction can cause expensive damage to building stone; it is essential that a stone evaluation for use in construction should assess the possibility of this type of decay. This paper endeavours to develop testing procedures for evaluating stone decay in polluted environments. Such tests can accompany other standard tests used in dimension- stone evaluation."

Jan 1, 1972

By Jochen Petersen, Jean-Paul Franzidis, Allan Nesbitt

This study presents a method for the determination of intra-particle diffusivities in ion-exchange resins for the purposes of evaluating the state of resin degradation during service. The method uses a zero length column (ZLC) in a closed circuit with variable speed pump and reservoir. The intra-particle diffusion is determined from absorption data by using the Nernst-Plank approximation along with the ‘mass transfer factor’ - which is a product of the mass transfer coefficient (kf )and the concentration of the adsorbing ion in the liquid at the surface of the resin - in a computer algorithm fitting simulated curves to experimental data.. Through this approach the changed intra-particle diffusivity, of a gel-type acid resin, over a 1000 loading and elution cycles, is shown.

Jan 1, 2014

By T. Bhambhani, Mukund Vasudevan, Partha Patra, D. R. Nagaraj, P. Somasundaram

Selective Ni separation from ultramafic ores rich in serpentines has been a huge challenge in the mineral processing industry, and therefore highly inefficient. Analysis of the root causes of the challenges and consequent development of robust processing solutions were the main goals of the Cytec-Columbia. University-Vale Joint Development Program. In this context, the subject of this paper is limited to one of the key findings of this research program which is the influence of fibrous serpentines on grade-recovery characteristics. Specifically, the poor flotation behavior is characterized by an atypical reverse C-shaped grade-recovery curve.

Jan 1, 2011

By S. B. V. Stewart, W. W. Forsyth

"Since the Mathew's method for open stope design was first proposed by Golder Associates in 1980 it has been applied at a number of mine sites in Canada. The initial hypothesis was based on a relatively small amount of data and the intervening period has allowed the collection of a significant amount of new data to test the validity of the method.This paper examines a brief history of the evolution of rock mass classification systems to provide background and emphasize their empirical and non-rigorous approach. It also presents the new data which appear to indicate that the initial hypothesis was reasonably good. The modification to the original graph proposed by Potvin is discussed as well as the applicability of the method to predicting the onset of caving. The original graph has been updated and has been subdivided into four zones described as ""stable""; ""potentially unstable""; ""potential major failure""; and ""potential caving"". The method is recommended as a useful open stoping design tool provided it is recognized that it is not a rigorous design method.Finally the paper proposes a recommended approach for application of the method by would-be users and addresses some typical pitfalls that may be encountered."

Jan 1, 1995

By P. Burke, V. Vuaroqueaux, A. Doyle, C. Petit, Kipouros. G. J.

Magnesium and its alloys are attractive for use in automotive and aerospace applications because of their low density and good mechanical properties. However, difficulty in forming magnesium and the limited number of available commercial alloys limit their use. The present work reviews the efforts to improve the attractiveness of magnesium through non-traditional processing, and presents results of current work on producing magnesium alloys via powder metallurgy (P/M). P/M can be used to alleviate the formability problem through near-net-shape processing, and also allows unique chemical compositions that can lead to new alloys with novel properties. The surface layer formed on the Mg powders during processing acts as a barrier to diffusion and sintering is problematic. The layer contains oxides, hydroxides and carbonates of magnesium, formed by reactions with the atmosphere. There are several means to possibly overcome this barrier. Alloying additions have been identified that may promote surface layer disruption during sintering. Processing variables such as sintering atmosphere may reduce the layer or allow the formation of less detrimental compounds. Post-sintering processes such as hot working may disrupt the layer and improve density. The experimental effect of all these processing parameters is presented in this paper.

Jan 1, 2010

By H. Jung

The microstructures and grain sizes of nanocrystalline Co and Co-1.1 wt % P alloys were characterized by X-ray diffraction. The corrosion properties of as-deposited and annealed Co-l.l wt % P alloys and pure nanocrystalline Co were studied in a deaerated 0.1M H2SO4 solution using electrochemical measurements and XPS surface analysis. Potentiodynamic polarization testing and impedance measurements revealed that an addition of P to pure nanocrystalline Co improved the anodic-corrosion resistance, however, this enhanced corrosion resistance was compromised by the heat treatment process at 350 and 800°C. The corroded surface of annealed nanocrystalline Co-1.1 wt % P at 350°C exhibited a more porous P-enriched layer compared with the as-deposited case. A sample annealed at 800°C corroded uniformly showing second-phase precipitates. The enhanced corrosion resistance of as-deposited nanocrystalline Co-1.1 wt % P was attributed to the elemental P on the surface that acted to hinder the anodic dissolution kinetics of surface Co following an initial selective dissolution of Co. However, at a higher anodic overpotential region, the superior corrosion resistance of Co-l.l wt% P alloys did not last because of the formation of a non-protective surface film consisting of mainly hypophosphite and phosphate as well as elemental P.

Jan 1, 2005

By P. E. Cavanagh

THIS REPORT is not intended to be a ?comprehensive survey of the steel industry in Europe. For the past ten years the Ontario Research Foundation has been interested in several developments in the steel industry in Europe which it was felt would be of particular interest in Canada and might possibly find application in this country. This is an account of the present status of some of these developments. The economies of steel making in Canada are somewhat different than in the United States because of the nature of the market and the relative costs and availability of such raw materials as metallurgical coke and electric power. There are cases in Europe where a great deal of effort and money has been spent in trying to make steel profitably by methods which take advantage of locally available and cheap raw materials by modifying standard practices. ln cases wl1ere the investigations have been successful and the data are available to allow translation of the results into Canadian conditions, it is felt that such information may be of great benefit in the future in Canada and at !east should be known to all those in the steel industry in this country. The field to be covered in this report only comprises the steps from concentration and treatment of iron ores to production of iron and is only concerned with those commercially operating processes well known to us and judged to be of present interest in Canada.

Jan 1, 1957

By C. M. Díaz, P. J. Mackey, P. Coursol

In a recent paper [1], the present authors discussed calculated energy consumption numbers in copper sulphide concentrate smelting for four different smelting technologies. For the present study, from among these technologies, they selected the Noranda/Teniente continuous bath smelting followed by Peirce Smith (PS) converting route to investigate the impact on total energy requirement of some key process variations, such as tuyere injection of dry concentrate vs. slingering of wet concentrate over the molten bath, continuous converting vs. conventional batch PS converting and commercially proven slag cleaning alternatives. In their calculations, the authors used the same thermochemical model and methodology used in their earlier paper. This approach to explore plant design options provides an interesting basis for evaluating flowsheet modifications that could lead to significant copper smelting energy savings. The METSIM software was used in the present paper to carry out heat and mass balance computations for 8 different flowsheet configurations. The results are presented and discussed in the paper with respect to copper recoveries, energy requirements and CO2 emissions.

Jan 1, 2011

By Jie Deng, Wenliang Xiong, Binyan Chen

"With falling rare earth metal prices, low cost beneficiation of rare earth minerals is essential. The “Flotation-Agglomeration-Magnetic” (FAM) separation process is a newly developed technology by IMUMR to economically recover rare earth elements from different types of deposits. The theory of FAM process is to selectively agglomerate rare earth particles and separate from gangue minerals by bubble flotation process. The flotation product is further upgraded by magnetic separation. The FAM process has been successfully applied in industrial production on the Dalucao rare earth ore, Sichuan, China. The average REO grade of rare earth concentrate is 65% in the latest 12 month production run, with an average recovery of 55%.INTRODUCTIONRare earth elements (REEs) include fifteen lanthanide elements coupled with two chemically similar elements (yttrium and scandium). These elements are split into two sub-groups, La to Sm are classified as light rare earth elements (LREEs) and the remaining elements including yttrium are heavy rare earth elements (HREEs) (Kumari & Panda, 2015). The demand of rare earth elements surged in recent years due to their increasing usage in diverse industrial aspects including high strength magnets, phosphors, clean energy, polishing compounds and catalysts (Goley &Scott, 2014).More than 250 REE-bearing minerals have been discovered, but many minerals are with very low concentrations of REEs, varying from 10-300 ppm (Adam &Ping, 2013). The most common rare earth minerals mined are bastnaesite, monazite, xenotime and ion-adoption REE (Chelgani & Rudolph, 2015; Kanazawa & Kamitani, 2006). Before the 1960s, most rare earth resources were extracted from monazite in the beach placer, with the exploiting of Mountain Pass in the United States and Bayan Obo mine in China, bastnaesite became the chief mineral source of rare earth resources (Klinger, 2015). These minerals are commonly separated with gangue minerals by froth flotation, gravity concentration, magnetic separation, or any combination thereof based on their specific physical characteristics (Zhou & Wang, 2014; Adam & Richard, 2014; Yang & Satur, 2015; Xia & Brian, 2015a,b)."

Jan 1, 2016

By William M. (Bill) Shaver

"The author will review the early history of shaft sinking as well as focus on the improvements made in shaft design and construction over the last fifty years (1970 to 2019) to predict how shaft sinking will change over the next fifty years and describe what the shaft sinking world might look like in 2070. INTRODUCTION It is a great honour to be one of your keynote speakers for the Fourth International Conference on Shaft Design and Construction being held in Toronto in November 2019. This is one of the opportunities we have to thank the Mining Companies of the world as well as the industries and companies we serve for their support of the mining contracting and shaft sinking business of Canada and the world at large. Many of these companies are represented here today. Without your support many of the innovations we will talk about today would not be possible. We would also like to thank all the companies that work with us in our business including all the contractors and suppliers who provide the various services we require. These include equipment manufacturers, engineering companies, project management companies and suppliers large and small who cater to our every need as quickly as possible. Without all these partners we would not be as good as we are. Many of these companies are our sponsors this week. Thank you from all of us! This is also an appropriate time to pause and think about those Shaft Sinkers we have lost and those who have been injured on our projects around the world. Please bow your head and remember the Shaft Sinkers you have worked with, who did not return home or those who returned home injured. Think about how we can continue the work of making shafts safer every day as we go forward with our projects so everyone goes home to their families safe and sound. Pause for a minute and thank you. The subject matter we have chosen to discuss today is “Shaft Sinking in the Next Five Decades”. How will the work be done, how fast will it be done, what will it cost, and why we think this may occur? It is appropriate to consider this over the next few days with this auspicious group we have assembled. Today, we will look back at all the advances that have been made over the last many years and look ahead to the future to attempt to predict what shaft sinking will look like in 2070. When I look around the room I recognize that many of us will not be around then so we need not worry about being wrong. Suffice it to say that the next 50 years will be very interesting and exciting for the shaft sinking business."

Jan 1, 2019

By S Sokhanvaran

Electrodeposition of silicon from a cryolite based electrolyte at a relatively low temperature (1000°C) is a promising approach to generate high purity silicon. In order to obtain fundamental data pertaining to electrowinning of silicon from Cryolite?SiO2 melts, density and electrical conductivity measurements were made. A range of temperatures and SiO2 contents was studied for each property. It was found that while density has an inverse relationship with temperature, the dependence for electrical conductivity is direct. Increasing silica content up to the saturation limit (~ 5 wt%) increases the density whereas further increase in SiO2, lowers the melt density. On the other hand, the conductivity is lower for the melts with greater SiO2 content, at any temperature.

Jan 1, 2011

By J. E. Hawley

Abstract Spectrographic methods for the analysis of minor constituents such as platinum-group metals, gold, silver, and silica in palladium and platinum refinery sponge are described. These involve the conversion of the sponge metals to the black form by reduction with high purity aluminum filings in either acid or alkaline media. Standards of known composition are prepared in the same manner from either refinery or spectrographically standardized sponge metals. Samples of the black metals are mounted in pellet form and a multisource spark discharge used for excitation. The range of concentrations of impurities studied are those common to refinery samples. Excellent reproducibility of intensity ratios using major constituents as internal standards, is demonstrated and two methods have noted by which the accuracy of the procedures are shown to be of the order of 3 per cent, on the basis of synthetic preparations. Introduction During the past two years an investigation has been carried out in the Spectrographic Laboratory, Queen's University, to determine the suitability of modern spectrographic techniques for the precise analysis of the platinum-group metals palladium, platinum, rhodium, iridium, and ruthenium in the form of refinery sponge analyzing about 99 per cent of the major constituent.

Jan 1, 1951

By A. L. Mular

"This paper summarizes the present-day usage of computers in the mining-metallurgical industry. The industry appears to be following a path taken by other industries in improving the operation of processing plants, production schedules, grade control and haulage performance. A reduction in the cost of computers and computing has been a significant factor.An attempt is made to forecast the future of computers in our industry. Such developments as time-sharing, mini-computers, and easy-to-understand process-oriented languages will lead to wider usage. Considerable strides have been made in the use of computers for laboratory data acquisition. In general, the implementation of new methods, new techniques and new equipment will require plant personnel to develop new skills. The universities are meeting this challenge by re-structuring curricula and offering special courses. Most vendors of computers already offer special courses within their own facilities at a customer's plant."

Jan 1, 1970

By Victor F. Hollister, Robert W. Hodder

"The petrology and mineralogy of porphyry copper deposits are thoroughly described in recent literature and cited as the definitive characteristics for this type of deposit. The magmatic-hydrothermal aspect of genesis is also dealt with in detail. However, descriptions of their internal structure and regional setting are not as rigorous, and the genesis of this structure is simply stated as the release of high fluid pressures in a cooling magma emplaced along large fault zones. Genetic relationships between internal structure, regional setting and the tectonic evolution of continents has been alluded to infrequently in the past, but can now be considered together within the developing concept of orogeny at the margins of drifting crustal plates.Tensional structures, on both local and regional scale, and a Triassic to Tertiary age are described for porphyry copper deposits. We contend that such structure and age are distinct and unifying characteristics for this type of deposit and are genetically related to major crustal movements. British Columbia has porphyry copper deposits contemporaneous with plutons 180 to 200 million years old and 40 to 60 million years old. The former age group correlates with early stages of the continent's westward drift, and the latter group with a change in tectonic style during late development of the Canadian Cordillera. Hence, one can in British Columbia reflect on the genesis of a deposit's structure in the broader context of tectonic evolution. Such consideration should lead to more definitive criteria for area selection in exploration."

Jan 1, 1972

By A. F. Matheson

"Bankfield Consolidated Mines, Limited, and Tombill Gold Mines, Limited, in the Little Long Lac area, Ontario, mined an orebody that was common to both. The discovery' of this orebody was made by surface prospecting in May, 1932, on Bankfield ground, following an original discovery made in the same manner on the same property on a small reef in Magnet lake in October, 1931. The production from the two mines between 1937 and 1942 was approximately 135,000 oz. gold from about 420,000 tons of ore, an average grade of 0.32 oz. a ton. Production was nearly equally divided between the two properties. Both mines are now closed, the ore exhausted.""The ore is mainly sheared and fractured greywacke and porphyry impregnated by silica and small amounts of metallic minerals. To a lesser extent there are definite quartz veins in the ore zone""(l). The metallic minerals present were principally pyrite, arsenopyrite, pyrrhotite, and native gold .As at other mines in the Little Long Lac area, an elongated, broad, deep trough of folded, steeply dipping volcanic and sedimentary rocks, striking roughly east-west and surrounded by younger granite, is host to the orebodies of the Bankfield and Tombill. In the immediate area of the two mines iron formation and conglomerate bands occur nearby both north and south of an intrusion of porphyry-Cliorite, suggesting repetition of beds and folding. Although considerable drag folding is in evidence, folding on the above scale has neither been proved nor disproved."

Jan 1, 1954

By C. D. M. Chisholm

IN discussing stope filling, or backfilling, at the Sullivan mine, at Kimberley, B.C., a brief description of the problem will first be presented. The Sullivan orebody is a replacement in quartzite, with the ore con-forming, for the most part, with the bedding. The dip of the vein, apart from local irregularities, averages about 15 degrees near the outcrop in the southwest section of the mine, and steepens to almost 40 degrees at the northeast end of the mine. The thickness varies from a few feet to over 200 feet at the widest sections. The mineable length along the strike has averaged about 4,000 feet between the 4,600 and 3,900 levels-the section under discussion in this paper. To date, 28,000,000 tons of ore have been mined by the room-and-pillar method. Prior to 1930, all ground opened up had been supported by ore pillars, left during mining operations. From that time, the recovery of the ore from these pillars has been given serious consideration. Backfilling, as being carried on today, is the result of this study and is being done for two reasons: (1) to allow extraction of the ore pillars, and (2) to minimize subsidence of the hanging-wall rock, except where forced caving is found desirable. PRELIMINARY DEVELOPMENTS LEADING TO BACKFILLING When the Sullivan orebody was first opened up, early in the century, there appeared to be low-grade sections of the vein sufficient in extent to serve as permanent support for the roof. However, as mining extended into sections of the vein that showed continuous ore over greater areas, wooden cribs, filled with waste and low-grade ore, were erected. In some stopes, these cribs were as large as 40 ft. by 100 ft. in plan and from 50 ft. to 60 ft. in height, but it was soon realized that this method of support was inadequate. As mining progressed, it was found necessary to leave ore pillars, which eventually became the sole system of support. At first, these pillars were left at irregular intervals, but later they were laid out at definite locations on the mine plans, and these locations were adhered to as closely as mining would permit.

Jan 1, 1941

By E. Rezazadeh Azar

Dump trucks are the main mean for hauling earth material within and outside of the construction and open-pit mining jobsites. The real-time monitoring of the material transportation trips is beneficial for proactive equipment management, volume estimation, and productivity measurement. The traditional manual observation is tedious, non-real-time, and expensive; therefore remote sensing technologies, namely GPS and RFID, have been employed for this reason. Ordinary construction videos are another costeffective alternative to monitor dirt loading and hauling operations in real-time. A vision-based system has been developed to recognize and count hauling trips. This system has three modules including object detection, tracking, and action recognition. This system processes videos taken from access roads in which it recognizes dump trucks and then tracks them throughout the viewfinder. The action recognition module is designed to reject false alarms and also terminate tracking. This way, the system is able to count the number of hauling trips and also record the time between each trip. Several state of the art computer vision algorithms were employed to develop this system. Some of these algorithms were modified using spatiotemporal information to minimize the inherent errors of the vision-based methods. The experimental results showed considerable performance of the system for practical application in the construction and mining sectors.

Aug 1, 2013

By Q. F. Wang, M. H. Lai, T. Q. Liu, G. G. Dong

Compared with the traditional pre-treatment process, biological oxidation process has many advantages including higher gold recovery, less cost, easier operation. The bio-oxidation reactor is the most important equipment for biological oxidation process. In this paper, the characteristics of biological oxidation are investigated, and the design principles are proposed based on laboratory tests. Both increasing the tank height and taking new inflation system can enhance higher dissolved oxygen. The new type of large-scale industrial bio-oxidation reactor is designed, which is 9.5 m in diameter and 10 m in height. The bio-oxidation reactor metallurgical performance has been tested by industrial-scale experiment. The slurry of flotation concentrate is divided into two parts to feed two bio-oxidation reactors. The feeding rates of two reactors are adjusted on the basis of getting the same content of S, Fe, As in overflow. The result shows that the feeding rate of the new type of 700 m3 bio-oxidation reactor is 3.72 m3 per hour, and the feed rate of the conventional 700 m3 bio-oxidation reactor was 3.23 m3 per hour. The processing capacity of the former is 15.2% higher than that of the later, which demonstrates the new type of bio-oxidation reactor has higher oxidation rate.

Jan 1, 2015

By J. E. Gill

Introduction During the past summer, detailed geological mapping was extended to cover the entire group of 31 claims owned by Waite-Ackerman-Montgomery Mines, Ltd., and considerable new information was revealed by development and exploratory work underground. These new facts provide a more complete view of the lithology and structure of the area than has heretofore been available. They also necessitate revision of certain interpretations presented last year by Peale (l), and have served to straighten out some of the problems suggested by Porritt (2). The purpose of this paper is to outline in a broad way the relations as now understood and to discuss in detail certain points which should be of interest to members of the Institute. Maps and records by the mine staff have been freely used in arriving at the interpretation presented in the following pages. The writers are especially indebted to Mr. R. V. Porritt, the mine manager, with whom many of the problems touched upon were discussed on the ground and whose intimate knowledge of the geology of the underground workings aided greatly in testing various hypotheses. The writers have profited greatly, also, from close association with Dr. W. F. James during the course of the work. Permission to publish the included data has very kindly been given .by the management.

Jan 1, 1932

By G. Barrasso

REACH was proposed by the EU Commission in October 2003 and stands for the Registration Evaluation, Authorisation and Restriction of Chemicals. It requires that all substances identified as persistent, bio-accumulative and toxic, whether the risk of those chemicals being released is real or perceived, require registration prior to them being allowed to be imported into the European Union. An internal investigation by the metals industry indicates that almost all primary raw materials streams would be classified as hazardous due to the potential health or environmental hazard properties of one or more of their ingredients. REACH uses a wide definition for chemicals and metals and as such its implications greatly impact the entire supply chain of the metals industry. The process of registration would require the producer/ importer to produce a dossier. Initiatives along the same lines as the EU REACH are also coming up in other parts of the world. REACH requires registration of at least four substances manufactured by the aluminium industry: aluminium metal, including powder, aluminium oxide, and aluminium hydroxide. The proposed legislation permits the affected companies to band together to form a consortium to develop certain aspects of the registration application. The aluminium industry has established a consortium and testing is currently underway.

Jan 1, 2006