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By K. Janghorban

Multilayered ceramic-metal composites were produced by solid state diffusion bonding of polycrystalline alumina and three Al alloys containing 1 to 2%Sr, 2% Mg and Mg + Si (5057 Al alloy), The multilayered structures were fabricated at 610°C under a compressive stress of 3 MPa for 2 hours in He-5%H atmosphere, The ceramic-metal interfaces were studied by SEM and TEM equipped with energy dispersive spectrometer (EDS). Addition of 1 wt % Sr to Al promoted good adhesion, without producing any interfacial products, while the Al-2%Sr was poor in this regard due to the presence of dispersed A14Sr which is an intrinsic phase in the Al-Sr phase system, The Al-2%Mg alloy produced a continuous film at the interface, which was characterized to be MgAl2O4. Al alloys containing Mg and Si (5057 commercial alloy) produced not only the spinel structure (MgAl2O4), but another phase rich in Mg and Si (close to Mg2Si), These latter interfacial reaction products were not the intrinsic phases in Al-Mg alloys, and were reaction products at the Al2O3 ?Al alloy interfaces.

Jan 1, 2005

By Larry J. Hulbert, Louis J. Cabri, John L. Campbell, Gilles Laflamme, Chris G. Ryan, Soey H. Sie, Rolando Lastra

"Abstract- The mineralogy of samples from the Wellgreen Cu-Ni-Pt-Pd deposit, Yukon Territory, is complex and the metals of interest are contained within fme-grained minerais which vary in size and mineral associations from sample to sample.The major Ni carriers are pentlandite and violarite; the major Cu carrier is chalcopyrite. About 700Jo of the major Ni carriers and 78% of the major Cu qmier will be liberated at a grind of 80% -'}f,.7 J.Uil (-500 mesh) for typical low-grade gabbro (West zone, sample No. 1). For typical ""clinopyroxenite"" (West zone, sample No. 2) and typical ""clinopyroxene-rich peridotite"" (East zone, sample No. 3) the liberation would be 71""lo and 65% for Ni, 74% and 60% for Cu, respectively. Fine grinding, however, cannot liberate the Ni contained in silicates and pyrrhotite, estimated to total24.5% for typicallow-grade gabbro (West zone, sample No. 1), 15% for typical ""clinopyroxenite"" (West zone, sample No. 2), and 12% for typical ""clinopyroxene-rich peridotite"" (East zone, sample No. 3).The principal Pt carrier (sperrylite) varies considerably in grain-size between samples and fme grinding, required to liberate the major Ni and Cu carriers, may be counterproductive in samples where sperrylite is relatively coarse-grained, as sorne would then be unrecovered (e.g. sample No. 1). In addition, sperrylite in samples No. 2 and No. 3 is closely associated with magnetite.Palladium occurs in diverse ways. It occurs in the form of several Pd minerais (e.g. sudburyite, testibiopalladite, merenskyite), as a replacement for Ni in several tellurides, antimonides and tel­ lurantimonides (e.g. melonite), or as very low concentrations in pentlandite (up to 34 ppm), chal­ copyrite (up to 9 ppm), and pyrrhotite (up to 5.6 ppm). Palladium minerais and Pd-bearing minerals are strongly associated with chalcopyrite in sample No. 1 and will thus report to a Cu concentrate. However, 22% of the total Pd is in solid solution in pentlandite in this sample and will thus report to the Ni concentrate. In samples No. 2 and No. 3, less Pd occurs in solid solution in pentlandite, and the PGM are distributed mainly among pentlandite, chalcopyrite, and magnetite in sample No. 2, and among pentlandite, pyrrhotite, chalcopyrite, and magnetite in sample No. 3. Therefore, the feasibility of magnetic concentration should be investigated for samples like No. 2 and No. 3, in order to improve Pt and Pd recoveries.Rhodium was found to occur as rare hollingworthite, in sparse cobaltite (up to 2.7%) and, as low concentrations in chalcopyrite (to 10 ppm) and pentlandite (to 12 ppm) by proton microprobe. Iridium occurs in hollingworthite (up to 7.8%) and very rarely as the native metal or in an undefmed Re-Ir-Os-Ru alloy. Ruthenium was determined by proton microprobe analyses to occur in pentlandite (up to 13 ppm) and chalcopyrite (up to 10 ppm), in addition to rare laurite and Re alloy."

Jan 1, 1993

By K. Purazrang, P. Musavi Garavi, P. Sh. Naseri, P. Abachi

The fracture behavior of high strength Al7050 alloy was investigated at room and elevated temperatures using small size, V-notched tear (called Kahn specimen) and compact tension, CT, specimens, respectively.To study the elastic-plastic behavior of the alloy, the tensile test was also performed on the sub-sized cylindrical tension test specimen. The microstructure of the alloy was examined using optical- and scanning electron- microscopy. The rupture mechanisms and crack path were also studied by examination of specimens' fracture surfaces using SEM. The microstructure examination revealed equiaxed grains and some elongated grains in rolling direction, with the areas of partial re-crystallized grains where coarse intermetallic particles are mostly found.In general, fracture surfaces were indicative of dimpled ductile type. Considering the fractographs of tensile specimens, the void growth mechanism is also dominant in fracture of these specimens. Nevertheless, in some regions, smooth areas can be observed due to the friction during rupture process. The results of mechanical tests at RT made the evaluation of tear strength to 0.2 % tensile yield strength ratio, as a measure of notch toughness, available. According to elevated temperature, 150°C, test results and plots of log da/dt vs. log KI , the crack propagation behavior over discrete ranges of crack growth rates could be assumed linear and then be obeyed as a power law equation in the form of da/dt = A (KI)n .

Jan 1, 2015

By SANDVIK WHITE

The mining industry produces approximately 4-7% of global greenhouse gas (GHG) emissions. It is fundamental for mining operations to take immediate sustainable action to actively contribute to an emissions-free future for the next generations. The mining industry has traditionally relied heavily on diesel technology and transitioning to more sustainable solutions requires change management to drive cultural acceptance and new product development. Sandvik was interested to find out the lifetime emissions of a single drill rig and to compare similar application diesel and BEV drill rigs with same use profile to each other. That led the calculation and pondering towards comparing different countries and mine sites as well

Jan 1, 2023

By G. P. Demopoulos

The solubilities of calcium sulfate in HCl-CaC1z-H20 solutions up to 100°C were successfully modelled with the aid of OLI software after bringing proper modification to it. Modelling, more specifically, was carried out with the help of the Environmental Simulation Program, V-6.6.0.4 (www.olisystems.com). New model parameters were obtained by regressing the solubility data. A private databank was established by adding the newly defined model parameters and the calcium sulfate hemihydrate phase that is not included in the original OLI database. The McGill-modified OLI software was successfully applied not only to modelling solubilities but also the transformation of the various CaS04 phases, namely dihydrate, hemihydrate and anhydrite. In this paper, the modelling methodology will be discussed along with a comparison of the capabilities of the newly developed model vs the original OLI model.

Jan 1, 2005

By Norman A. Jull

"Factors which affect the separation achieved in a hydrocyclone are discussed and illustrated with graphs of some mathematical relationships.Definitions of separation and sharpness include comment on use of elutriation devices.A plea is made for better evaluation of field data prior to their reporting or use in calculations. Methods of evaluation are suggested, with samples of the relevant calculations.An example of the effect of percent solids errors is given, with computer printout and plotted corrected recoveries.INTRODUCTIONThe range of interest in cyclones runs from a simple demand for classification results to a detailed study of published equations defining cyclone characteristics. Probably this group covers as broad a range and, in an attempt to offer something for everyone, I will begin with general operating comments, then move on to more analytical topics. Ideally, an author would compose his paper after the discussion period, when he would have a better idea of the areas of special interest to his audience.Sor'1e of you may share our incurable fascination with classification, especially as performed in cyclones. It is amazing that such a simple device could be in use for more than 20 years and retain as much mystery as it does. Substantial parts of the mystery have been solved but some remains, to keep up our curiosity. There is at least one valid reason: the unusual compactness of this device, which makes internal observation very difficult. What other unit can you think of which performs such a complex separation between particle sizes, shapes and specific gravities at such high capacity? Retention time in a cyclone is typically 3 seconds!Mutual Agreement - In a cyclone, every parameter of geometry and of operation interacts with every other. In an orderly discussion of individual parameters it would be necessary to repeat, in every section, 11 if all other factors are equal"". Could we agree now, for our mutual convenience, that that phrase is clearly understood between us during the remainder of this paper?"

Jan 1, 1972

By G. Whittle, R. Peevers, P. Moryoussef

Enterprise optimization is a relatively new optimization approach to mine planning used to jointly consider all aspects of a mining operation affecting the mine planning process and related valuation. In this paper, it is applied at SEMAFO's Mana operations in Burkina Faso, consisting of several open pits and a proposed underground mine. The surface-minable ore is relatively shallow, and the pits are long and linear. The underground operations, as currently envisioned, will consist of a stoping operation accessed by two ramps from the surface. Power is a concern at this property due to local power being produced largely by diesel generators, and it has become one of the key optimization constraints. Other important parameters are the mining and processing rates, underground configuration and cutover elevation. Enterprise optimization was found to improve net present value for the Mana Operations property by simultaneously optimizing multiple parameters and constraints to arrive at an optimal pit and mining phase design, optimal cut-off grades over time, and optimal ore feed based on ore hardness, power constraints, and head wades. Reserves were expanded several times over the course of the study to improve the valuation of the mining operation and put SEMAFO in its present enviable position of ongoing reserve increases.

Jan 1, 2011

By J. Walker, G. E. Kim

Since May of 2000, Mogas Industries, in partnership with F.W. Gartner Thermal Spraying Co. and using the services of Perpetual Technologies, has invested time, energy, and resources towards developing novel ball valves for high-pressure acid-leach (HPAL) service. In addition to developing new valve designs, an aggressive coatings development effort has been undertaken to improve the protective quality of the coatings so as to enhance the performance and extend the life of valves in severe HPAL conditions. In 2001, Mogas Industries qualified and applied a nanostructured titanium oxide (n-TiO2) coating for gold and nickel/cobalt HPAL services. The n-TiO2 coating provided dramatically superior protection against abrasive and erosive wear, fared very well against high-pressure autoclave corrosion testing, and has performed well in HPAL service.

Jan 1, 2004

By A. McLean, W. Q. Chen, W. Yan, M. Barati, Y. D. Yang

In order to maximally remove the harmful impurities phosphorus and reduce the loss of valuable elements from Si-based alloy for production of solar-grade silicon, thermodynamic properties of the Si-based alloy were studied. In this work a new model, the Molecular Interaction Volume Model (MIVM) derived from statistical thermodynamics, was successfully used in the Si-based and Si-Fe-based alloy. The calculation started from binary Si-Fe, Si-P and Fe-P systems, then the thermodynamic parameters of ternary systems could be derived based sub-binary systems. Using the activity coefficients of the elements in the Si-based alloys and the saturated vapor pressure of the pure substance of the components, mass fraction of P during vapor-liquid equilibrium can be calculated. The calculated thermodynamic parameters were compared with experimental data available in different publications, and it is found that the thermodynamic parameters calculated using MIVM model are in good agreement with the measured results. The calculated result shows that the mass fraction of phosphorus during vapor-liquid equilibrium of Si-Fe-P melt increases with the increasing phosphorus content and decreasing temperature. This is an important direction for experimental practice in vacuum or low-pressure EML refining of ferrosilicon for potential production of solar-grade silicon without significant vaporization loss of valuable element.

Jan 1, 2015

By Robert Drummond

Away back in the eighties of the last century, when Sir Charles, then Doctor, Tupper, was not only a prominent but a dominant figure in the political life of Nova Scotia, his opponents brought the railing accusation against him that he was the foremost of egotists because of his frequent use of the personal pronoun. I heard Tupper speak and had no sympathy with the railers, because I could not well see how the pronoun could be dispensed with without laying himself open to a charge of affectation. I shall make reference in what follows to incidents in which I have taken part, and shall be at no pains to dispense with the pronoun, even though thereby I lay my-self open to the charge of being a pupil of the deceased states-man. EVENTS LEADING UP TO THE ORGANIZATION OF THE PROVINCIAL WORKMEN'S ASSOCIATION The Springhill Mining Company began development work at Springhill in the early seventies of last century. So vigorously was the work prosecuted that in 18 7 4 two slopes, the east and the west, were in active operation, with a considerable. output, the east slope on occasional days producing 800 tons. The President of the Company, the late Senator McFarlane, was a Nova Scotian, the other directors were mainly merchants from St. John, N.B. From the first the enterprise was an .astonishing success, due in the greatest part to its geographical position, and in large part to the untiring vigilance of the directors, a majority of whom visited the collieries at short intervals, thereby keeping the manager, much of the time, on tenter hooks.

Jan 1, 1924

By N. Samman, S. N. Lau

"A series of new, grease-based, solvent free open gear lubricants were developed to meet the demanding service requirements of mining equipment. The use of these products has resulted in better performance under conditions of temperature extremes and in terms of longer component lives. They have gained widespread acceptance within the mining communities for such applications as the lubrication of mining shovels, draglines and ball mills.These products are WHMIS non-controlled and are environmentally acceptable. The benefits and advantages of using this type of product to lubricate mining equipment as well as the field evaluation and experience will be discussed."

Jan 1, 2002

By Mike Dry, Rod Dry

If humanity is truly serious about reducing emissions of carbon dioxide into the atmosphere, today’s power plants burning fossil fuels will have to be replaced by power plants that do not emit CO₂. Unless carbon capture/sequestration becomes practical, the new power plants will be hydroelectric, wind, solar or nuclear installations. Hydroelectricity requires the appropriate geography. Solar installations can only deliver power as and when sunshine is available, and wind installations when the wind blows. Therefore, power from these sources will be intermittent, but the demand for electricity does not follow the patterns of sun and wind. That will require large-scale electricity storage and/or load following by the remaining power suppliers, increasingly so as the use of fossil fuelled power generation declines. Modern nuclear power plants are designed for demand following. However, operating at lower than design output has a negative impact on the economics of nuclear power plants because the overall cost of the electricity they generate is dominated by capital cost. Primary (blast furnace) iron smelting is responsible for a significant part of global CO₂ emissions because the reagent used is carbon. Were it available in sufficient quantity (and at a low enough cost), hydrogen could replace carbon in the manufacture of raw direct reduced iron (DRI), using technology such as modified HYL (Tenova Hyl, 2018) or Midrex (Ravenscroft, 2017). This paper examines a scenario in which, instead of demand following, nuclear power stations are operated at their design capacities and surplus power is used to generate hydrogen in off-peak periods. This hydrogen is then used to replace carbon in the manufacture of raw steel.

Jan 1, 2020

By M. A. Rabah

This study aims to recover europium, yttrium metals, some valuable salts or oxides from the white powder (apatite) coating the inner surface of spent florescent lamps (SFLs). Pressure leaching using sulphuric/nitric acid successfully dissolved the metals of interest. Europium or yttrium metals were obtained by hydrogen reduction of their oxides. Addition of potassium thiocyanate converted the dissolved sulphates to thiocyanates. Selective separation of Eu and Y was then carried out by solvent extraction from the thiocyanate solution. The used solvent was trimethyl-benzylammonium chloride. N-trihutylphosphate in 1 M nitric acid was used to strip the metal loaded in the organic phase. Results showed that the quality of the cleaned glass tubes of the SFL met the standard requirement for the lamp manufacture. The white powder (WP) is composed of calcium sulphate 35.2%, phosphate 61.5% and oxides of europium and yttrium 1.65%wt. respectively. Autoclave digestion of the WP for 4 h at 120°C and 500 kPa in sulphuric acid/nitric acid mixture dissolved 96.4% of yttrium and 92.8% of europium. The conversion rate of sulphate to thiocyanate was favoured at low temperature. Stripping of Eu and Y from the loaded organic phase behaved in an opposite way. A metal separation factor of 9.4 was obtained. ate recovered europium and yttrium salts were selectively separated using ethyl alcohol or dilute nitric acid. Yttrium was very soluble while europium was not. Europium and yttrium metals were obtained by hydrogen gas reduction at 850°C and 1575°C respectively.

Jan 1, 2004

By J. Nesset, F. Rosenblum, P. Spira

Sulphide concentrates may exhibit self-heating to various degrees during storage or shipping, the worst cases presenting a serious hazard from fire and SO2 emission. Based on measurements of heating rates on a wide variety of concentrate samples in a special apparatus, combined with field experience, a methodology has been developed which allows concentrates to be rated for their heating potential. This has proven to be very useful in practice, for example, in deciding on the need to take preventive measures. Oxidation under ambient conditions in the presence of moisture initiates heating locally within a stockpile. In the case of highly active materials, such as those that contain abundant pyrrhotite, heating may progress through three stages to temperatures well above 500°C. However, most concentrates show little or no propensity to self-heat. Heating rates were used to estimate values of the heat output, or self-heating capacity (in joules per gram), which sustains the process at each stage. Thermal data from differential scanning calorimetry are also reported. Variables which affect self-heating are discussed and an actual case of heating control on a stockpile by covering is described. A simple apparatus which can be used to simulate stockpiling conditions has been tested successfully and is proposed as a convenient test system.

Jan 1, 2001

By Hans Lundberg

Introduction Today, geophysical exploration is recognized as a special science wedged between geology and mining. Universities and technical institutes have special professors teaching geophysics applied to oil and ore prospecting. The list of literature on geophysical exploration has grown from practically nothing at all some twenty-five years ago to ~ several thousands of books, some of them very imposing volumes. Most of the methods now used have been developed since the first World War, and very large systematic exploration campaigns have been carried out in many places, in many countries. It has been rather difficult to obtain enough information as to what is going on in Canada. However, since the Associate Committee on Geodesy and Geophysics of the National Research Council became more actively engaged in promoting geophysical research, it may be easier to obtain information and, in the future, the quarterly issued Canadian Geophysical Bulletin may throw considerable light on the current geophysical activities in Canada. Some twenty crews have been engaged the last few years in geophysical prospecting for ore. In the United States, between 500 and 600 crews are employed exclusively in geophysical prospecting. Most of these, however, are engaged in oil exploration. During the winter 1942-1943, the German Government employed some fifty crews on geophysical exploration, and some ten crews were working for private enterprises.

Jan 1, 1948

By L. Bloomquist

This paper describes how Automated Mining Systems (AMS) is evolving the state-of-the-art in guidance systems for autonomous underground vehicles. The techniques, trade-offs, and lessons learned from these systems are described, including the safety regime that has been implemented. First generation autonomous guidance systems for underground vehicles relied on infrastructure for the vehicle to follow. However, there are additional costs associated with that approach. The current generation uses a pair of laser range finders as its only guidance sensors. This system uses a minimum of infrastructure, in the form of a redundant system of location referencing. Advanced steering and drive control algorithms are incorporated into this generation of system. The next generation of infrastructureless guidance systems will be based on a 3D vision sensor, which was originally developed for autonomous Mars rovers and is being adapted for underground mining use. Results of early underground field trials are presented, along with a description of this emerging technology.

Jan 1, 2004

By L. Bloomquist, C. Arnoldi

"This paper describes how Automated Mining Systems (AMS) is evolving the state-of the- art in guidance systems for autonomous underground vehicles. The techniques, tradeoffs, and lessons learned from these systems are described, including the safety regime that has been implemented.First generation autonomous guidance systems for underground vehicles relied on infrastructure for the vehicle to follow. However, there are additional costs associated with that approach.The current generation uses a pair of laser range finders as its only guidance sensors. This system uses a minimum of infrastructure, in the form of a redundant system of location referencing. Advanced steering and drive control algorithms are incorporated into this generation of system.The next generation of infrastructureless guidance systems will be based on a 3D vision sensor, which was originally developed for autonomous Mars rovers and is being adapted for underground mining use. Results of early underground field trials are presented, along with a description of this emerging technology."

Jan 1, 2004

By F. Baczek, S. S. Rocks, D. Chaiko, C. Eyzaguirre, S. Asihene, T. Walters

The majority of efforts to improve primary copper sulfide leaching have focused on solution chemistry, temperature, O2 pressure, ultra-fine grinding, the use of catalysts, etc. Historically, very few studies have focused on the solid/solution interface. A new, patent pending approach to catalyzed, copper sulfide leaching has been discovered by FLSmidth that enables manipulation of the 2-D semi-conductor properties of chalcopyrite surfaces to the benefit of higher electrochemical reactivity. Copper dissolution rates are then further accelerated by incorporating a Stirred Media Reactor (SMRt) into the process. By using minute amounts of Cu2+ to "pre-activate" chalcopyrite, leach times have been reduced from >20 hours with incomplete Cu dissolution to <2 hours with 98+% Cu dissolution at 80°C. The pre-activation process takes only minutes to complete at temperatures of 80°C or less. The total atmospheric leaching process, incorporating the pre-activation and Stirred Media Reactor is compatible with existing SX/EW processes. Results of batch leach testing are presented and possible mechanisms are discussed.

Jan 1, 2015

By H. Ewaschuk

"INTRODUCTIONRio Algom's Stanleigh Mill in Elliot Lake began production in June of 1983. The highly instrumented mill treats uranium ore at an average rate of 3900 metric tons per day. To help ensure a good start-up and low operating costs, an extensive training program was undertaken prior to and during start-up. This presentation describes how an unconventional operating crew were combined to form an operating unit with a high efficiency in terms of production and labour utilization. I would like to point out at the outset that the operating philosophy, and the role of the supervisors and the operators as set up at Stanleigh is not unique. Indeed, I have seen the same results at a couple of small plants where efficiency meant survival. However, these situations appeared to be the exception, and it was not readily apparent how similar results could be obtained in a larger plant. A factor that existed at the time was low labour turnover. As in most parts of Canada, jobs were easy to get in the Elliot Lake camp in the late 1970's. This, and other factors, contributed to an unusually high labour turnover. This changed dramatically in the early 1980's. Indeed, Rio's two other operating mills, Quirke and Panel reduced crew sizes at this time to reduce operating costs. As a result all of Stanleigh's operators came from Quirke and Panel with experience varying from 4 to 7 years. The experience that operators had was obviously of benefit and served to reduce the scope of the training program from what would have been required with inexperienced personnel."

Jan 1, 1985

As a bubble travels through the pulp region of a flotation cell, it will collect the most hydrophobic particles of an intermediate particle size range, this being the primary source of true flotation selectivity. Despite its role on bubble-particle attachment, however, particle hydrophobicity is still missing a mathematical definition that can be used for plant simulation. In this paper, particle hydrophobicity is defined in terms of the induction time necessary for attachment and then linked to the mass of collector adsorbed per particle. This allows particle hydrophobicity to be written as a function of density of collector adsorption as well as particle size and mineralogy. The model is calibrated from the experimental measurement of the flotation rate constant. Liberation data from an industrial flotation rougher is used for model validation. It is demonstrated that the model can describe a broad experimental dataset by means of a minimal number of parameters. Main industrial application is in simulating the effect of the chemical environment upon plant metallurgical performance.

Jan 1, 2006