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Autogenous-Carrier Effect and Gangue Influence in Fine Particle Flotation of Ilmenite/Titanaugite System

Sep 13, 2010

By Lynch A. J

Comminution within rod mills has been investigated by use of a matrix analysis of breakage processes. A parameter, the number of breakage stages, has been introduced and comminution within all rod mills has been expressed in terms of the number of grinding stages and a function which describes the feed rate, mill diameter, and mill speed. The effect of variation in feed rate, feed sizing analysis and mill speed on the number of breakage stages is discussed, but no general relation is proposed because more study is needed.INTRODUCTIONRod mills are normally used as the first unit of multi-unit systems for the grinding of metalliferous ores and the cost of operating rod mills may be considerable. For both economic and metallurgical reasons, it is therefore necessary that the mills should be operated efficiently and that a knowledge of the mechanism of the size reduction process within rod mills should be as complete as possible. While a qualitative assessment of the process may be of some value, a quantitative assessment gained by describing the process in mathematical terms can be of much greater use because it may also be used for design and control purposes.In this paper, an empirical mathematical model is postulated to describe the size reduction process within rod mills and it is used to analyse the effects of variations in both rates and size distributions of the feed to the mills.GRINDING CHARACTERISTICS OF ROD MILLSMyers (1953) discussed the grinding characteristics of rod mills and suggested that a pronounced screening effect, resulting in the preferential grinding of the coarser particles, occurs within the mills. This is illustrated in...

Jan 1, 1964

By E Selvapandian, R Barr

Arrium (previously OneSteel) initiated a desktop study into the performance of its hematite ore beneficiation plant in early 2010. The beneficiation plant utilises jig concentrators and spirals to upgrade low-grade hematite recovered during mining at the Iron Duke (ID) mine site located 60 km south-west of Whyalla. The study, conducted in conjunction with Mineral Technologies, identified a number of opportunities for improvement, which were validated by a series of sampling campaigns and a pilot plant trial. One of the major recommendations was to upgrade the ultra-fines processing circuit from a single-stage spiral circuit to a three-stage circuit. The upgrade of the ultra-fines circuit was estimated to provide a significant increase in fines production and grade.In order to capitalise on the strong iron price at the time of the project, Arrium decided to utilise a fast-tracked approach to design, construct and commission the processing equipment required to achieve the improvements identified. This decision introduced the risk of missing critical steps in the project development process, which could have potentially resulted in major issues in latter stages of the project. In addition to the challenges introduced due to the expedited time line for project completion, this project presented unique challenges due to its brownfield nature. One such challenge faced was the integration of the new equipment and control system software.Furthermore, the importance of the ID ore beneficiation plant (OBP) contribution to the companyÆs export commitments meant the upgrade work had to occur while minimising disruption to normal operation. This decision presented a set of new challenges to an already complex project. One such challenge was the need to build and commission the new spiral circuit in isolation from the operating plant.The aim of this paper will be to highlight some of the challenges faced in a complex brownfield project such as the ID OBP upgrade and discuss how they were managed to enable the successful commissioning of the process in early 2012.CITATION:Selvapandian E and Barr, R, 2013. Managing challenges faced in the brownfield commissioning of an ultra-fine hematite processing circuit at ArriumÆs Iron Duke ore beneficiation plant, in Proceedings Iron Ore 2013 , pp 533-538 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

By Greenwood J. N

This is the fourth paper in the series on Australian w,ar materials and the work was undertaken as part of the programme for producing hard carbides. It had been intended to determine the influence of tantalum and columbium' carbides in mixtures with tungsten carbide. Owing to other, urgent developments, it has not been possible to proceed with that programme.1. THE PROCESSING OF A TANTALITE ORE(a) The OreThe minerals in which tantalum and columbium most commonly occur are tantalite and columbite. These two minerals are the end members of an isomorphous series of tantalates and columbates of iron and manganese, but in nature the series grade into each other.Some of the best deposits of tantalum and columbium ores in the world occur in the north-west of Australia. Until recently tantalite low in columbium was the only mine~al in demand but discoveries of extended uses for columbium, e.g., addition of ferro-columbium to high chromium I steels inhibits intergranular corrosion (weld decay), have created a demand for columbite low in tantalum as weB. Both of these types of' ore occur in the Pilbara district in Western Australia and most of the ore mined is exported to America after a preliminary grinding and concentration by gravity.A sample from the Bynoe Harbour locality, west of Darwin, was used in this investigation. It consisted of coarse lumps of tantalite with quartz in minor amounts. Cassiterite w.as also present. A recent investigation!l) gave the analysis as:

Jan 1, 1943

This paper aims to collate the metallurgical test work undertaken on the Barrytown mineral sands deposit. It is intended to serve as a summary of mineral dressing work undertaken by all interested parties up to the time of writing. Areas requiring further investigation are: in situ grades and recoveries of accessory minerals,the question of 'rank' of ilmenite within the deposit,flow sheet development for the recovery of gold and monazite, andcost analysis to investigate the relative worth of other minerals; notably rutile. Flow sheet development with respect to the Accessory Minerals cannot be accurately defined until the importance of each mineral in terms of grade, recovery and expected revenue is determined. To date, ilmenite and zircon flows are well documented. Further work is needed to quantify recovery's and flows of the other minerals; notably monazite, gold and rutile.

Jan 1, 1989

By T de Wit, S Meyer

The location of seismic events in mines is traditionally calculated based on the arrival times of P- and S-waves for a given velocity model (homogeneous or heterogeneous). This technique is successful when the sources of seismic events are sudden and localised (eg episodes of fracturing in solid rock or dynamic slip along a plane of weakness) and thus the radiated seismic waves have clear arrivals. In massive mining operations such as block caves, strong seismic signals often originate from the movement of loose rocks on the perimeter of the fracture zone. These signals are easily recordable but do not contain easily identifiable direct P- and S-waves, making the estimation of location through traditional methods more complicated. This problem has been approached by using a ‘brightness’ location method that estimates the origin of seismic waves based on travel times of envelopes of seismic energy. This tool is extended to be applicable in a heterogeneous velocity environment that now accounts for the presence of a cave or other strong velocity perturbations. The suggested method is particularly important when caving occurs in low-stress environments (eg close to the surface).CITATION:Meyer, S and de Wit, T, 2016. Location of seismic events associated with caving using brightness method, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 225–236 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

By Burns W. G, Muceniekas E, Whitcher I. G, Hughes F. E

No iron ore deposits were reported before 1961 from the Hamersley Ranges, Western Australia, although low-grade bedded iron formations, associated with ferruginous jaspers and cherts, were known to occur in the local Nullagine Series of Precambrian age.In January-March 1961 preliminary investigations in the area drained by the Turner River, Duck Creek and Serpentine Creek revealed the presence of over 1000 million tons of dense botryoidal or pisolitic limonite, forming flat-lying orebodies with 50-57 per cent iron.Large bedded hematitic orebodies were also discovered in the same area in August-October 1961. These have a porous, biscuity texture and an iron content of 60-61 per cent. They occur at a welldefined stratigraphic level (Brockman Iron Formation), normally in synclines where they have been upgraded by circulating meteoric waters during an old cycle erosion.In 1962 systematic geological studies and mapping, together with sampling and scout drilling, indicated larger reserves of biscuity hematitic ore and led to the discovery of massive hematite deposits at Mt. Tom Price. These were extensively drilled in 1963, proving the persistence of' high-grade mineralisation to a depth of 200 ft and over.To date the total indicated reserves of the Hamersley deposits, within the area held by Hamersley Iron Pty. Limited, are of the order of 4960 million tons and thus rank among the more important of the world. The reserves are composed of 600 million tons of bedded dense hematite ore with 64-66 per cent iron, 2900 million tons of bedded biscuity hematite-limonite with 60-61 per cent iron, 1360 million tons of limonite (goethite) ranging in grade from 50 to 57 per cent, and 100 million tons of canga (conglomerate) iron ore containing 53-63 per cent iron. In all cases harmful impurities are comparatively low.

Jan 1, 1964

By I Thin, L Morizzi, C Seymour, G Mungur

Olympic Dam has been investigating mine design options for the South Mine Area (SMA), which will continue using the existing sublevel open stoping (SLOS) method. The SMA is an undeveloped mining area, located south of the existing underground mining areas currently in production at Olympic Dam. The SMA study reached the stage where geotechnical inputs were required for stope design, infrastructure location and ground support forecasts. A large database of geotechnical data was collected to inform open pit designs for the ODX (Olympic Dam expansion) project (resulting from 659 drill holes). This geotechnical data has since been reprocessed to align with design inputs required for the SLOS mining method. The result has been the construction of a preliminary three-dimensional mining rock mass model (MRMM) that has been incorporated into preliminary stope mine design and infrastructure layout assessments, which have taken into account the predicted prevailing ground conditions.As with any model, it is necessary to improve the confidence in its predictability; therefore the model must be calibrated. The preliminary SMA MRMM was no exception. First pass calibration was possible with results from underground geotechnical window mapping from exposed rock mass conditions in the lateral development and surface geotechnical holes for ventilation shafts.The SMA project continues to advance and has started a program of resource drilling. Selected holes have been identified that target data limited areas. This will ensure that the data gaps are infilled in order to maintain the required data density required to improve the model confidence. In addition, further underground window mapping in the SMA will provide ‘mine scale drill hole’ data that can be used to either update the MRMM or as part of planned future calibration. Stope performance data from stopes will provide further valuable data for calibration purposes.The proposed paper will present the process and findings that have been followed in order to establish a well calibrated geotechnical model that can be used with an acceptable level of confidence in the ongoing refinements of the mine design and planning process for the SMA.CITATION:Thin, I, Morizzi, L, Mungur, G and Seymour, C, 2016. Building and calibration of a geotechnical model for sublevel open stope design at Olympic Dam, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 523–532 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

IN this paper an attempt is made to describe the sluicing operations on the tin fields of north-eastern Tasmania. No claim is made to completeness, for much of the ground has already been covered, and nothing is to be gained by needless repetition. On this account some portions of the subject have obviously received but attention in order that others may be rather more fully dealt with; for instance, referring to the accuracy of various methods of valuing alluvial deposits, particulars of efficiencies, and water duties on both overburden and drift; also, the system of recording water distribution, &c. The plans of the tin-streaming shed, sluice and feed race, and overburden tail-race represent types of the most modern design.GEOLOGY. The principal alluvial dcposits being worked at the present time are situated either in the ancient or modern bed of the Ringarooma River or its tributaries. This river flowed in a north-easterly direction, receiving numerous tributaries on either bank...

Jan 1, 1910

Flat jack stress determinations in selected colliery roadways have revealed a range of measured stress from 330 lb/sq. in. tension to 3,750 lb/sq. in. compression. Photoelastic examination of loaded plastic and actual rock model mine openings has shown that the primary horizontal stress required to attain these measured stresses would be from one to three times the superincumbent vertical load.Examination of roof movement with a borehole extensometer and a series of anchors at various horizons to 30 feet in a vertical roof borehole showed that when a standing face was advanced the roof movement was practically confined to the lower two feet. The majority of this movement occurred during the 36 hours after mining at this face commenced.The use of a radioactive isotope and a scintillation counter in a pair of parallel boreholes is a sensitive and accurate method of roof bedding plane crack detection.INTRODUCTIONA knowledge of strata stresses is required to understand the deformation of an underground opening and, in particular, the roof behaviour. It is the aim of investigations currently being conducted by Australian Coal Association (Research) Ltd. to determine the stress existing around mine openings and the location and magnitude of roof movement.STRATA PRESSURE MEASUREMENTMost measurements of strata stress are performed at the surface of underground openings and the majority measure the change of strain resulting from stress relief. The accuracy of the measured value of stress depends upon knowledge of the rock modulus of elasticity. The flat jack method has the advantage that strain relief is restored by a measured stress applied directly by the jack. The rock modulus of elasticity can also be determined.

Jan 1, 1963

By P Staples, G Lane, S Morrell

The design of semi-autogenous grinding (SAG) mill based comminution circuits for the treatment of competent ores, similar to those at Geita and Boddington, involves the same process of sample selection, test work, data analysis and data modelling/interpretation as that used for 'average' competency ores. However, over the past couple of years a number of issues have arisen that are common to the design of circuits for the comminution of 'highly' competent ores. The impact of these issues on project viability is generally more pronounced when treating hard ores than average to soft ores due to the greater impact on capital and operating costs. The issues encountered have included: standard test procedures have been modified; test equipment has worn or been damaged; different procedures yield different data and varying interpretation; and modelling and empirical calculations have been based on poor benchmarks, or used incorrectly in the case of JKSimMet, yielding misleading outcomes. The purpose of this paper is to present, discuss and clarify some of the issues associated with conducting test work and designing comminution circuits for the treatment of 'highly' competent ores in order to reduce thelevel of conflict arising from interpretation and application of test work data. Specifically, the issues associated with the bond crushing (impact) and rod work indices measurement, the various SAG mill specific energy tests, and the interpretation of the resulting data will be discussed in the context of case studies.

Jan 1, 2009

By D Kavanagh, C Michaud

"A continuous improvement initiative was identified at Kalgoorlie Consolidated Gold Mine’s (KCGM) Fimiston open pit with the goal of reducing bench turnover time and increasing shovel digability by improving fragmentation around previously mined-out stopes. In the past, a higher number of blasts than normal would be required to get through a single excavation area where stopes were present. This is due to the limited reach capability of the drilling fleet from safe ground into restricted areas requiring the drilling of the shot to be done in a staged manner. In addition, the holes that were able to be drilled in the area did not remain open long enough to be loaded with explosives as a result of the poor ground conditions surrounding the stopes.Over the last 18 months, KCGM has trialled drill additives to improve blasthole stability, as well as introducing a remote drill rig allowing holes to be drilled in areas previously inaccessible by manned drill rigs. This has resulted in improved penetration rates in bad ground conditions, improved drill hole stability, better shovel digability, and an overall reduction in bench turnover of at least ten days on the benchmarked 126 days average per bench. KCGM is now in the final stages of the improvement project with the installation of a drill monitoring system on the fleet to allow live data transfer back to the office for analysis, as well as providing improved accuracy on drill holes in restricted areas.Citation:Michaud, C and Kavanagh, D, 2016. Reducing Bench Turnover Time and Improving Shovel Digability, in Proceedings Ninth AusIMM Open Pit Operators' Conference 2016, pp 19–27 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Nov 15, 2016

In 1961, West Australian Petroleum's Eneabba No. 1 bore encountered 22 seams of coal totalling 40 ft in thickness between the depths of 6373 ft and 6441 ft. On analysis, this coal had a similar calorific value (8000-HOOO B.T.U./lb, assuming 20 per cent water) to the coal from the Collie Coalfield, Western Australia's only known area of commercially exploitable coal. Being buried to depths in excess of 6000 ft, the coal at Eneabba had developed weakly-coking properties, and thus, although much younger than the Permian coals of Collie, gave promise of being a major potential source of power for Western Australia.West Australian Petroleum undertook a programme of stratigraphic drilling and shallow test drilling to determine whether this coalhorizon persisted into the outcrop of the Lower Jurassic sediments in the Hill River district, 140 miles NNW. of Perth, and, if it was present, if the quality and quantity of the coal would warrant development of the deposits by open cutting. The coal horizon was identified in the near surface, but the poor quality of the coal and the complexity of the structure made development (in the area examined) uneconomic at the time.A strong seismic reflection in the Eneabba area occurs at the same depth as the Jurassic coals. This event originates within the upper beds of the Lower Jurassic and it is probable that the velocity contrast between the higher velocity siltstones and the very low velocity coals enhances this very strong, distinctive seismic reflection.This event can be followed on continuous seismic data over a large area of the northern Perth Basin, from 13 miles SE. of Dongara to 20 miles SW. of Coorow. It can be followed from a depth of 4000 ftnear Dongara to over 17,000 ft to the SE., so development of thisvast potential source of power will depend on the economics ofprocesses being developed for the production of power from theburning of coal seams in situ.INTRODUCTIONThe discovery of 22 seams of economically useable coaltotalling 40 ft in thickness in the Lower J urassic sedimentsof the Eneabba No. 1 bore (Fig. 1) led to the search forthese seams at economically workable depths. The Ministerfor Mines in Western Australia granted to West Australian1. Supervising Geologist, West Australian Petroleum Pty. Ltd.Manuscript received at The Institute, 25th May, 1964. and presented to the 1964Annual Conference.

Jan 1, 1964

The dissolution of gold in cyanide has been studied, using both chemical and electrochemical techniques. The electro-chemical studies have confirmed that gold may become passive in cyanide solution if its potential becomes more positive than -O· 5 V v. saturated calomel electrode (S.C.E.). The results of the conventional solution rate tests suggest that, although the solution rate is controlled by the rate of diffusion of oxygen at low oxygen and agitation levels, when these are increased the gold may become passive and its solution rate approach a steady value, or even decrease with increasing oxygen level. The passivity of gold has been shown to be of importance in the solution of small spheres of this metal, and in the extraction of gold from a calcined auriferous pyrite concentrate.INTRODUCTIONAlthough it has been appreciated for many years (McLaurin, 1893, 1895) that dissolved oxygen is a necessary adjunct to the solution of gold by the cyanide process, attempts to quantitatively assess its effect have led to conflicting results. For example, Barsky, Swainson, and Hedley (1934) reported that an increase in oxygen concentration improved the solution rate, but Beyers (1936) claimed that such an increase would reduce the rate at which the gold dissolved.By using an electrochemical approach Kudryk and Kellogg (1954) showed that the diffusion rate of either the cyanide or the oxygen was a controlling factor, and that, if the mole ratio of cyanide to oxygen concentration was greater than 10, the solution rate was proportional to oxygen concentration.These results, although they represent some of the most careful work available, were in direct contradiction to the findings of Mills (1951), who found that gold may become passive in cyanide solution, with a resultant decrease in solution rate.

Jan 1, 1963

By A-A Latscha, C Boyle

Geological modelling has historically been done using sectional interpretation of paper sections or on a computer screen. Boundaries of geological units or grade shells are interpreted by a geologist section by section and the shapes are drawn onto paper to be digitised later or they are directly digitised into a computer. This approach is referred to as explicit modelling. Such methods are time consuming if there are many section lines or boundaries to be interpreted. The number of metres drilled and resource models made is increasing each year and it will be difficult to keep up using explicit modelling methods. Alternatively, it is possible to use information carried in the drill holes, known geological relationships and point estimation methods in two or three dimensions, to create similar geology boundaries, while eliminating or at least greatly reducing the need to manually interpret and digitise detailed sectional interpretations. Such methods are referred to as implicit modelling and are available in a number of software packages. Implicit modelling approaches have been used in iron ore and found to significantly reduce the time needed for modelling while producing results that are comparable or better than standard explicit modelling approaches. A number of case studies have been undertaken of implicit modelling in iron ore deposits. Stratigraphic surfaces of bedded, folded and faulted iron ore deposits have been modelled in various deposits by Leapfrog Geo, GOCAD (with SKUA) and Vulcan Integrated Stratigraphic Modelling. Leapfrog Mining was used to model iron grade shells at particular cut-off grades. The modelled surfaces are of a high standard equivalent to those that could be produced by traditional explicit modelling but the time required by the implicit methods is far less. Implicit geological modelling is an active area of software development and improvements in software are likely.CITATION:Boyle, C and Latscha, A-A, 2013. Implicit geological modelling of iron ore deposits, in Proceedings Iron Ore 2013 , pp 57-66 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

By J J. Batchelor, J B. Metson

Titanium (ilmenite) concentrate was extracted from a New Zealandilmeno-magnetite deposit. Tailings from the existing processing line at the Waikato North Head ironsand concentration plant were used as a raw material feed. The titanium bearing mineral extracted was defined as intergrowths of ilmenite and hematite in the size range below 150 um. The Owen-Honda equation was used to determine the conditions forilmenite/hematite magnetic separation. Three distinct regions of magnetic field strength for the mineral separation have been defined. Theoretical estimates from this calculation have been confirmed experimentally. Ilmenite concentrate was obtained using medium field magnetic andelectrostatic separation. The final material contains 40.6 - 42 per cent TiO2 and 39.1 - 39.8 per cent Fe (total). The actual yield from extraction was about seven per cent of the Zircon, leucoxene and monazite were found as byproducts of thetitanium concentration process. Preliminary experiments have shown the viability of industrial zircon benefication.

Jan 1, 2000

By C Spandler, S W. Richards G Rosenbaum, R J. Holm

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.The recent and active magmatic arcs of eastern Papua New Guinea (PNG) and the Solomon Islands are well endowed with sulfide mineralisation and include deposits such as Ladolam, Panguna and Solwara 1. The majority of the mineral systems in this belt are younger than four million years old, with some deposits remaining active to the present day as exemplified by active hydrothermal systems on the island of Lihir. The geodynamic setting that led to the formation of these deposits is still unresolved, with, for example, both the Pacific and Solomon Sea plates considered responsible for the formation of the Ladolam deposit on the island of Lihir under different models. In order to understand and characterise the formation of south-west Pacific mineral deposits, we must first reconstruct the complex geodynamic evolution of the region. New kinematic reconstructions show that while mineral systems in eastern PNG and the Solomon Islands are hosted within a single arc related to subduction at the New Britain and San Cristobal trenches, variable and discrete geodynamic settings exist within both the upper and lower plates throughout this region, which give rise to distinct mineralised corridors. Most notably, this region is host to: the Solwara 1 deposit, which occurs within a major transtensional corridor in the eastern Bismarck Sea the Ladolam deposit (Lihir), which is interpreted to have formed above but in relation to tearing of the subducting slab the Panguna deposit, which is related to structure in the subducting slab marginal to the actively spreading Woodlark Basin.An evaluation of the nature and variability of these diverse geodynamic settings through time can provide us with a better understanding of the relationship between the active south-west Pacific magmatic arcs and mineral deposit formation. It may also provide insights into the diverse array of deposit settings at ancient convergent margins, with applications in mineral prospectivity studies.CITATION:Holm, R J, Richards, S W, Rosenbaum, G and Spandler, C, 2015. Disparate tectonic settings for mineralisation in an active arc, eastern Papua New Guinea and the Solomon Islands, in Proceedings PACRIM 2015 Congress, pp 165–170 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

Most mines in the Bundamba, North Ipswich, and Rosewood districts of the West Moreton coalfield of south eastern Queensland have installed washing plants during the last five years. Many problems were encountered in their installation, including the small size of washing plant required in many cases, the economical minimum ash content under present and future market requirements, production from a one-product washbox of large and small coal of quality to satisfy both markets, measures to avoid adding unnecessary moisture to the washed slack coals, and excessive middlings in some coals or soft clay in others.INTRODUCTIONIt was fortunate for Brisbane, which was to become the capital of a new State, Queensland, in 1859, and grow into a city of over half a million people by the time of its centenary, that coal was found in abundance almost on its doorstep near Ipswich, the first mine being opened at Redbank in 1843. This was followed by the opening of many more mines in that district and, some 40 years later, in the nearby Rosewood district where high-volatile gas coal was produced (Fig. 1). These discoveries ensured a supply of reasonably priced coal (currently about 85/- per ton delivered) in Brisbane, but the quality is inferior to that of other coals mined in Queensland beyond economic range of Brisbane.Various factors led to an increase in the average ash content of the West Moreton coals during and after the war. Between 1940 and 1952 the gasworks coals rose in average ash from 13 8 per cent to 23·9 per cent and the powerhouse coals from 17·1 per cent to 27·1 per cent. This drift was arrested by the installation of 28 screening and picking plants from 1952 onward, but it became obvious that mechanical cleaning of the coals was essential due to the competitive market for coal and the worsening quality of reserves.

Jan 1, 1963

By Linge HG, Fernandez PG, Hughes HC

Aqueous oxidation is a possible alternative to roasting for the processing of gold bearing arsenopyrite (FeAsS) concentrates. The reaction has been studied by voltammetry and this has shown, for the first time, that FeAsS can be readily dissolved without passivation at room temperature in dilute sulphuric acid at relatively modest oxidation potentials (0.7 V SHE). The reaction forms sulphur on the mineral surface and the oxidant consumption is thus minimal. Two practical modes of slurry oxidation are listed.

Jan 1, 1989

By Greenwood J. N

This work was commenced at a time when information on the manufacture of cemented tungsten carbide was urgently needed in Australia. Much information of a general type has been published, but many of the details of the processes used are still undisclosed. The aim of this research was to determine a satisfactory way in which cemented tungsten carbide could, be made, and to investigate the problems which are associated with the process. As the work proceeded, its ramifications grew continually, and it was necessary to limit the possible lines of investigation. After much experimental work, a 9% cobalt-tungsten carbide alloy was developed which had satisfactory properties when used as a cutting tip. The effect of certain variables on the properties of this particular alloy was investigated.The tungsten carbide was prepared in stages from King Island scheelite concentrates under strict laboratory control, whilst the cobalt (1) used was made from cobalt oxide prepared from crude cobalt oxide obtained from Eisdon.In order to clarify the detailed experimental work, a brief summary of the method used for the preparation of cemented tungsten carbide follows.Tungsten carbide and cobalt are prepared in a very finely powdered state, and are then thor,oughly mixed by a ball milling operation. The resultant mixture is pressed in a suitably shaped die into small compacts which are subsequently '''presintered,'' i.e., heated' in hydrogen between 800°C. and 1000°C. The final sintering is carried out in hydrogen between 1,400°C.and 1,600°C. for about half an hour. These "alloys" may contain from 3 to 13% cobalt, depending on the particular properties required of them.PREPARATION OF MATERIALSThe tungsten oxide prepared as described by Smithells (2) was extremely finely divided, and after a few hours' grinding in a ball mill, the powder consisted of material below 10 microns iJ;l size. The oxide was reduced to tungsten metal with hydrogen in a tube furnace. The reduction was carried out at 800-900° C., a rapid flow of hydrogen being maintained in order to remove the water vapour' formed as a result of the reactions:

Jan 1, 1942