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By D Thornton, B Smith, S Demey

Mine to Mill (MTM) optimisation, a total systems approach to the reduction of energy and cost in mining and mineral processing operations, is well-established technology. However, successful applications of MTM optimisation have been largely confined to gold, copper and lead/zinc semi autogenous grinding (SAG) operations, where the goals of tweaking the blast design to increase fines and hence throughput through the mill have been relatively easy to meet. The application of MTM optimisation in a more demanding environment, like that of a multi-stage crushing and screening aggregate operation, was conceived as part of a Department of Energy (DOE) initiative in 2004, aiming to reduce the energy consumption in the US aggregates industry. Two quarries operated by the Luck Stone Corporation of Richmond, Virginia, were selected for the demonstration sites. Dealing with ore variability and a requirement to maintain a fixed feed size distribution to the tertiary plant, whilst still aiming to increase yields of saleable products, presented some unique challenges. Despite these variables, the implementation of the MTM approach at Luck StoneÆs aggregate plant in Pittsboro, North Carolina, has led to a tangible improvement in productivity, particularly in the primary and secondary plants. The successful outcome was dependent upon several key factors, including reliable blasting and processing models, careful analysis of the rock conditions and plant configuration, understanding and buy-in from the Luck Stone operations staff, excellent collaboration with Virginia Tech staff and students, and long-term monitoring made possible through comprehensive PLC logging. This paper presents a review of the work conducted at the Pittsboro quarry and highlights the key reasons behind the successful implementation of the MTM approach in a complex plant environment.

Jan 1, 2007

Solar Salt, Lunar Ambitions I Bauerti The title of this paper is `Solar Salt, Lunar Ambitions'. It is largely the result of a lack of imagination and a tight deadline. I was seeking a catchy title to convey the image of being 'here' and wanting to get `there', with `there' being a long way away and our being held 'here' by powerful gravitational forces. I tried `Solar Salt, Lunar Landings', but that implied we had already reached `there' when, on reflection, we had not. A colleague suggested 'Solar Salt, Luna Park' which is a fun park in Sydney and, I must admit, there was appeal in the image of having embarked on a wild roller coaster ride with stomach-wrenching twists and turns and the only reward being a pair of sweaty palms, and a feeling of nausea. That's sometimes how it feels when you launch into change. In the end I settled for the more sedate `Lunar Ambitions'. It contained that suggestion of hope and continual striving which are central to the idea of best practice. I will discuss our experiences in this area shortly, but I would firstly like to provide some background to our business. The salt industry is steeped in history and tradition. As one learned commentator observed, common salt is 'a substance seemingly too ordinary to think about, yet it is the oldest of man's raw materials and the basis of some of his newest inventions' (Multhauf, 1978). From ancient times, salt was recognised as a key necessity of life and it has played a role in the rise and fall of governments throughout history. The Romans recognised its importance when they gave their soldiers money regularly to purchase salt, hence our modern word 'salary'. Today, while culinary use remains important, the main consumer of salt is the chemical industry (Figure 1).

Jan 1, 1995

A broad zone of intra-plate volcanism occurs for some 3000 km along the E. Australian coastal regions, extending from far northern Queensland southwards to Tasmania, westwards to western Victoria, and into southeastern South Australia. The age range, taken over the whole region, extends from Eocene to Holocene. Wellman & McDougall (1974) recognised the occurrence of three distinct types of volcanic occurrences: (a) Lava field provinces, dominantly basaltic and commonly strongly undersaturated, but of variable size. Large lava fields are especially exemplified by the younger provinces in northern Queensland (e.g. Nulla, McBride), and western Victoria. (b) Central volcano provinces, in which a reasonably well defined volcanic edifice is discernable. Such provinces are built of mildly undersaturated to saturated mafic lavas, but are also characterised by felsic volcanism (and often substantial mafic and felsic intrusive phases). Examples are the Springsure-Minerva Hills province, the Tweed and Focal Peak Shields (southeastern Queensland to northeastern N.S.W.), and the Nandewars, Warrumbungles, and Canobolas volcanic centres (N.S.W.). (c) A single leucitite province in N.S.W. Wellman and McDougall (1974) were able to show that the central volcano provinces exhibit a remarkably regular southward age migration pattern, the calculated migration rate being 66 + 5 mm yr , and these authors interpreted this in terms of the northward passage of the Australian plate across a fixed 'hotspot' within the upper mantle. The leucitite province also fits this migration pattern. The lava field provinces apparently exhibit more erratic regional age distribution patterns, but Sutherland (1981) has interpreted the data in terms of a multiple 'hotspot' model. It is noted, however, that the youngest areas of volcanism (Pleistocene 1. Department of Geology and Mineralogy, University of Queensland, St. Lucia, Brisbane, Queensland

Jan 1, 1987

The results expected from a longwall face can best be estimated from the ideal production rate, determined by the capacity of the equipment and the conditions in which it is installed, the effective operating hours, and the utilisation.The effective operating hours are determined by a number of scheduling factors which include the proportion of manned time to calendar time, the effective shift factor (effective time to manned time) and the move times.Analysis of the results achieved on the last 121 completed longwall panels in Australia (1984 onwards) shows a significant trend between 'actual tonnes/manned hour' and 'ideal production rate' (the measure of the capacity of the installation).Using 1982 'state of the art' longwall equipment, (the average in use in the seven year period), it should be possible to produce around 2.7M tonne/year ROM from a mine with one longwall. Few mines are achieving this.A review of production scheduling factors and general natural hazards affecting some mines suggests three things.1. Whilst some increase in average effective hours has followed the CIT decision, further improvement is possible at many installations.2. Many mines subject to general natural hazards, such as high gas make and high general stress, have found effective solutions and achieve the same utilisation as the overall average.3. A small number of faces within such mines have been severely affected, some less so. The most severe effects of natural hazards appear to be very site specific. This emphasises the need for detailed investigation of the causes, and development of means of predicting their presence. Only then can either satisfactory technical solutions be found to overcome the problems or prior decisions be chosen not to mine badly affected panels.

Jan 1, 1991

By Bezuidenhout M, Moolman D. W

In the minerals industry numerous problems cannot be solved by conventional mathematical models owing to their complexity or a lack of phenomenological understanding. Neural networks provide one way of mapping the ill-defined relations between process variables and functions for such ill-defined problems. Consequently, processes such as leaching and froth flotation are mostly controlled in an empirical way by using rules of thumb. In addition, these processes involve so many independent and dependent variables that the plant operator finds it difficult to visualise or even observe a change in process conditions. The structure of froths developed on the surfaces of industrial scale froth flotation cells has a significant effect on both the grade and recovery of valuable minerals in the concentrate. Although these effects are well known at the process operational level, where considerable heuristic knowledge is available, little work has been reported on a detailed characterisation of the mechanisms and the visual characteristics of the surface froth. Recent results from an on-line observation of froths in several plants have proved the relationships between image features representing froth behaviour and metallurgical results. It will be shown how supervised and unsupervised neural nets are being used on operating plants to interpret computer vision data. In froth flotation the operator is supposed to visually observe process changes from the appearance of the froth, which is an unreasonable demand under industrial conditions. The system described here determines textural parameters on-line, and tracks the changes in process conditions via a Self-Organising Map (SOM) neural net. This monitoring system warns the operator about fluctuations in reagent addition, and gives an idea of the type of froth encountered. In another example, changes in the mineralogical characteristics of gold ores are represented on an SOM map, based on the diagnostic leaching behaviour of such ores.

Jan 1, 1997

By T Goswami, M Edmondson

Henry Walker Eltin (HWE) are the mining contractors for Gloucester Coal at Stratford mine, which is in an environmentally sensitive area in the Avon Valley, NSW, Australia. Normal blasting at Stratford is done in a æstand upÆ or æbox cutÆ mode to suit the truck and shovel operations. Recently an opportunity of doing a throw blast became available when part of a ramp had to be blasted to accommodate changes to the pit design while not damaging the remainder of the ramp. The objective was to maximise throw into the void in order to minimise excavation costs by reducing the amount of overburden to be moved by the excavation fleet. It was necessary that the best result be achieved while staying within the vibration and airblast limits at a neighbouring property and nearby township. Both objectives were achieved through the application of OricaÆs knowledge of blast design, modelling and i-konTM electronic detonators. The i-kon system was used because of its known benefits in cast blasting and environmental control. The i-kon system provides the blaster with much greater accuracy, control and the flexibility to tailor blast designs. It has been found previously to enhance blast throw and provide cleaner high walls (Brent, 2002). The blast was a success, producing a muckpile with a high degree of looseness and consistent fragmentation, with an average throw to final spoil position of 37.5 per cent. This was achieved without any environmental exceedance. In addition, high speed filming showed that the coal edge had remained largely in place, indicating minimal coal loss. The results exceeded the expectations of HWE Stratford and the overall cost savings to HWE Stratford from this blast were recognised to be substantial. Further throw blasting opportunities at Stratford have been followed using the i-kon system to maximise benefits.

Jan 1, 2003

By F J. Rios

In the eastern high-strain domain of the Quadrilßtero Ferrffero, Brazil, hard and soft high-grade hematite ore may occur as schistose bodies in shear zones mainly related to the Cambotas-Fundpo thrust system. These orebodies are almost entirely constituted of oriented specularite platelets that develop both as a product of crystal-plastic deformation of hematite and solution-precipitation processes. Both mechanisms interact in the partitioning of the strain, while solution-precipitation is responsible for the precipitation of hematite and localised leaching of silica resulting in the formation of syntectonic ores. The analyses of fluid inclusions from specularite crystals of the Conceitpo and Timbopeba deposits, located in the northern and southernmost areas of the eastern high-strain domain of the Quadrilßtero Ferrffero, were studied using infrared microthermometry and Synchrotron x-ray fluorescence. The results indicate the participation of highly saline aqueous H2O-NaCl fluids containing other additional cations (Ca, Fe, K and probably Ti) in solution and homogenisation Temperature (Th) averaging between 130¦ - 190¦C. However, the partial fusion of metastable saturation phases indicates crystallisation temperatures of approximately 400¦C. The mineralisation process produces high-grade orebodies as well as Fe-rich specularitic itabirites that are explored in that area. The shear zones are related to thrust faults mapped and interpreted as related to the PanAfrican/Brasiliano Orogeny that affected the Quadrilßtero Ferrffero, thrusting the Paleoproterozoic platform sequence of the Minas Supergroup over Mesoproterozoic quartzites of the Espinhato Supergroup. They intersect and even overprint an early metamorphic and tectonic fabric of Paleoproterozoic age (Transamazonian Orogeny). The geological and fabric relationships lead to the conclusion that the fluids involved in the mineralisation were most probably of external origin, of still unknown source (possibly igneous), during the closure of the Spo Francisco Craton.

Jan 1, 2005

Iron formation-hosted iron ore deposits account for the majority of current world iron ore production and consist of three classes: unenriched primary iron formation with typically 25 to 45 wt per cent Fe; martite-goethite ore formed by supergene processes, with abundant hydrous iron oxides containing 60 to 63 wt per cent Fe; and high-grade hematite ores thought to be of hypogene or metamorphic origin overprinted by subsequent supergene enrichment with 60 to 68 wt per cent Fe.Individual iron ore deposits range from a few millions of tonnes to over two billion tonnes at >64 wt per cent Fe, although most are within the range of 200 to 500 Mt. In the Hamersley Province of Western Australia, martite-goethite ores are largely developed in the Marra Mamba Iron Formation, although high (>0.08 per cent P) phosphorous mineralisation is also well developed in the stratigraphically higher Brockman Iron Formation. Whilst the vast majority of high-grade microplaty hematite ore is best developed in the Brockman Iron Formation, this paper provides the first textural evidence of locally significant microplaty hematite mineralisation in the Nammuldi Member of the Marra Mamba Iron Formation, in the Chichester Ranges at the Christmas Creek, Cloud Break and Mount Nicholas prospects. Petrographic studies have identified a high-grade Fe texture composed of nanometre scale plates of hematite in mineralised sections of primary microplaty hematite deposits in the Pilbara and elsewhere, well below the normal depth of weathering or dehydration. The population of nanometre to micrometre scale hematite plates is interpreted to represent various stages of nucleation, crystallisation and progressive growth of hematite from the primary ore-forming fluid in areas that were once iron-rich carbonates or silicates in the BIF.

Jan 1, 2005

By K Kinnunen

A strong correlation between the reduction degradation index (RDI) of production sinter and the titanium content of the sinter mix was identified at the Ruukki sintering plant between 2000 and 2004. The titanium distribution in different mineral phases was studied using samples from pot sintering tests. Titanium additions were made using two different materials: rutile and crushed titanium-bearing haematite pellets. While both titanium additions clearly increased the RDI, titanium seemed to favour secondary haematite. The study focused on the effect of titanium in haematite, because haematite is reduced to magnetite in the RDI test. During the haematite-magnetite reduction, reduction degradation was observed. To increase accuracy, the phenomenon was investigated first by sintering and then reducing synthetic minerals under controlled laboratory conditions at the University of Oulu. The effect of titanium oxide in solid solution in magnetite on the magnetite to haematite transformation rate was studied first in order to simulate the final stage of the sintering process. In other experiments, haematite samples doped with 0.5, 2.0 and 5.0 wt per cent titanium oxide were studied using thermogravimetry under a controlled gas atmosphere (CO/CO2/H2/N2). Sintered samples were reduced using the same gas composition as in the RDI test. Polished sections for optical microscopy and SEM-EDS analysis were prepared from both reduced and oxidised samples and unreduced sintered samples. The titanium oxide content of haematite had a clear effect on reduction degradation of the samples. Furthermore, increasing titanium oxide content in solid solution in magnetite radically accelerated the oxidation rate. Similar observations regarding the effects of titanium have been reported earlier, but this was the first time the effect of very small additions of titanium were shown to deteriorate blast furnace burden quality and a reason suggested behind the process.

Jan 1, 2007

There are two mechanisms in the flo- tation process by which particles are transported from the pulp to the con- centrate: bubble-mineral aggregation and entrainment. It is the chemical processes which occur in the pulp which are critical to the success of flotation since they control the floatability of different min- erals and the selectivity which can be obtained. However, these chemical pro- cesses are so complex that metallurgists are still limited in their ability to predict the floatability of particles in industrial circuits by consideration of the minerals present and the chemical environment. The alternative approach to understand- ing flotation is to examine the behaviour of minerals in industrial flotation pro- cesses, to recognise similarities and differences, and to define the "laws" which appear to apply. Using this ap- proach it has been found that minerals float at a rate which is proportional to their concentration in the pulp, and that the rate of flotation of different min- erals is influenced by variables which' affect the pulp or the froth phase. The ultimate application of this approach is the use of models for circuit simulation purposes. It is this alternative approach which is the theme of this paper. One of the most important problems in understanding the technology of flotation has been in defining the characteristics of the particles being floated. Particles entering flotation vary widely in size and mineral composition, and different par- ticle types float at different rates. These rates do not change uniformly as operating variables change. It has been conventional practice to assess flotation performance in terms of the metal contents of total streams because no better method has been available, and this procedure has obscured important effects which occur in

Jan 1, 1984

By Balint F

The Izok massive sulphide deposits are located in the Northwest Territories of the remote western Canadian Arctic. Together they represent one of the highest grade undeveloped zinc-copper resources in North America. Metall Mining Corporation is presently engaged in a feasibility study on developing the Izok property as well as actively exploring for additional reserves. The Izok deposits are Archean-aged, volcanogenic massive sulphide (VMS) bodies hosted within and near the top of a thick sequence of predominantly felsic pyroclastic rocks. The hangingwall package includes additional felsic volcanoclastics, dacitic and basaltic flows, thin sulphide-rich iron formations, and turbiditic sediments. The felsic volcanics are intruded by syn- to late-hydrothermal dacitic dykes and sills and post-hydrothermal gabbroic dykes and sills. Both intrusives are interpreted to be volcanic feeders to overlying flows. All lithologies are cut by much later irregular granitic pegmatite dykes and regionally metamorphosed to pyroxene homfels grade. The deposits occur within a large kilometre-scale soda-depleted alteration zone. The immediate footwall and hangingwall rocks to the deposits are characterised by zones of muscovite-biotite (with or without sillimanite), lesser chlorite-biotite-cordierite (with or without anthophyllite), and locally intense silicificified and albitised zones. All lithologies have been affected by a later calcic metasomatic alteration. As currently defined, the Izok Zn-Cu-Pb-Ag deposits comprise a cluster of four complexly-zoned composite lenses: the Northwest, North, Central, and newly discovered Inukshuk deposits. The first three deposits are amenable to open pit mining while development of the Inukshuk deposit will require underground methods. The combined mineral inventory of the Northwest, North, Central and Inukshuk deposits at present totals 15.6 million tonnes with a grade of 2.4 per cent Cu, 13.8 per cent Zn, 1.4 per cent Pb, and 74.6 g/t Ag.

Jan 1, 1993

By S Long, A J Koen, D MacKay

The Mt Wright Underground Mine is located near the town of Ravenswood in North Queensland and is operated by Carpentaria Gold – a wholly owned subsidiary of Resolute Mining Limited. Following the evolution of the mine plan through a number of stages, the ‘sublevel shrinkage (SLS) with continuous fill’ mining method was implemented in 2010 to extract the Mt Wright orebody. The production front in this mining method is similar to a sublevel cave (SLC) operation; however, backfill is placed into the top of the production zone as opposed to requiring the overlying strata to cave.Continuous fill to replace the void created by extracting the ore was required to manage the potential risks associated with the proximity of infrastructure to the footwall, associated long-term stability and air blast potential due to the limited ‘cavability’ of the material within the cave zone. The available fill material was sourced from a disused waste dump from a previous open pit operation, which introduced further technical and economic risks associated with dilution from ‘no grade’ broken material. Procedures and processes to manage these risks have been incorporated into the operation of the mine.Despite encountering a number of challenges, the SLS method has been in use for approximately three years at Mt Wright and has proven to be viable economically, technically and operationally. This paper will discuss the challenges encountered and what was done to overcome them, the operational and financial performance to date, along with the outcomes of some successful continuous improvement projects that have improved the efficiency of the operation.CITATION:Mackay, D, Long, S and Koen, A J, 2014. Sublevel shrinkage – the Mt Wright story, in Proceedings 12th AusIMM Underground Operators’ Conference 2014 , pp 205–216 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Mar 24, 2014

By A Whaanga, A Doecke

The internal stratigraphy of the Marillana Creek palaeochannel Tertiary channel iron deposits (CID) in the Hamersley Province of Western Australia was initially defined in the 1980s and redefined as the Marillana Formation in the early 2000s. Recent drilling, open pit mining and field observations in the Western deposits at BHP Billiton Iron OreÆs Marillana Creek tenements have revealed some additional details on the extent and detail of some units of the Marillana Formation stratigraphy in this area. The drill hole data at Western 1 South has identified a number of features either not previously documented in this area or whose significance has not been adequately recognised, including a denatured zone at the base of the Upper CID of the Barimunya Member, and variations in the lithology within the Munjina Member at the base of the channel. Additionally, the Western 4 pit walls show evidence of a significant near-surface clay horizon and overlying CID, which are suggested to be the equivalent of the Iowa Eastern Member in the Eastern deposits. The deposition of this unit was most likely driven by a regional climatic disruption rather than a change in sediment source area alone. The nature of the Weeli Wolli Formation-derived goethitic peloids in the Western deposits may explain the more extensive denaturing in the Western Lower CID of the Barimunya Member. In contrast, the more robust nature of the haematitic-cored pelletoids in the Central and Eastern deposits has resulted in a less denatured Lower CID in these areas. Such work reveals the value of and need for geologistsÆ ongoing face mapping observations and detailed drill hole logging, and cautions against not querying previously accepted interpretations.

Jan 1, 2007

By S R. Grano, M Vera

This paper deals with two separate case studies investigating the froth phase performance and characterisation of two industrial rougher/ scavenger flotation circuits. Froth phase performance was quantified using a mass balance approach to estimate froth zone recovery. Measured characteristics of the froth phase included frother solution concentration determined by gas chromatography, and the time taken for an equilibrium froth sample to decay to one-half of its original froth height. The latter measurement is referred to as the æfroth half-lifeÆ and is strongly linked to froth stability. Special methods and techniques developed to preserve frother in solution and to measure froth half-life are briefly described. The frother type in the first case study was a mixture of straight and branched alcohols, whilst the frother type in the second case study was a mixture of alcohols, aldehydes and triethoxybutane. The first case study focussed on a flotation circuit treating a low-grade ore containing only a small fraction of floatable copper sulfide minerals, while the second case study focussed on a flotation circuit treating a higher grade complex sulfide ore containing significant quantities of chalcopyrite, galena, sphalerite and pyrite. It was found that froth zone recovery of valuable mineral generally decreased down-the-bank of the two industrial rougher/scavenger circuits. Moreover, decreases in froth zone recovery significantly limit the overall cell recovery of valuable mineral achievable from the plant scavenger cells. However, the decrease in froth zone recovery could not be linked to the removal of frother from the pulp solution to the concentrate product in the preceding rougher flotation stages. Measurements of residual frother in solution suggested that, approximately, only five to ten per cent of the added frother was removed into the rougher/scavenger concentrate, with the remainder appearing in the scavenger tailings. This finding suggested there was apparently adequate frother in solution in the scavenger stages.

Jan 1, 2005

This paper presents a review of heat illness in mining, including reference to several recent investigations by the author. Heat illness is a collective term, covering the conditions of heat stroke, heat exhaustion, heat cramps and miliaria rubra. Heat stroke is life-threatening and is by far the most serious condition. It is rare in mining, if appropriate control measures are instituted. Heat exhaustion is primarily due to hypohydration, following prolonged sweating in hot conditions. Symptoms include fatigue, headaches, dizziness, anorexia, nausea, vomiting, shortness of breath, or brief syncope. Confusion, ataxia, prolonged unconsciousness or convulsions are strongly suggestive of heat stroke. Heat cramps are painful involuntary contractions of skeletal muscle associated with work in hot conditions. The limbs are usually involved and the spasms typically last a few minutes, during which the affected part of the body is incapacitated. Heat cramps tend to occur in heat exhaustion, when hypohydration becomes marked. Miliaria rubra is a skin rash caused by extravasation of sweat into the skin, as a result of obstruction of the sweat glands. It occurs after prolonged and profuse sweating in hot environments. It can take three to four weeks of sedentary duties, in an air-conditioned surface environment, for the condition to resolve. Heat illness would be unlikely in underground mining, if the thermal environment was sufficiently well controlled by ventilation and refrigeration. This is however, often not practicable. Where engineering controls alone cannot provide sufficient control of risk, the residual risk can be assessed using an appropriate heat stress index. While procedural controls may further reduce the residual risk, it is important to remember that these are less reliable than engineering controls and cases of heat illness may still occur. Procedural controls include the application of heat stress limits, education, hydration, self-pacing, early symptom reporting, medical advice, acclimatisation procedures, air conditioned accommodation, support to achieve a healthy body mass index, and an effective emergency response capacity.

Jan 1, 2005

By R Herbert, M E. Malmstr÷, S U. Salmon

The study focuses on sulfide oxidation processes in unweathered pyrite-rich mine tailings from a soil-covered impoundment in northern Sweden. To simulate the oxygen-limited conditions in water saturated tailings two long-term column experiments were performed. Results are presented for the first 11 months of the experiments at room temperature. The tailings used in the experiments were of two different grain sizes (one coarse grained, in the range 0.02 - 0.6 mm with a grain surface area of 1.86 m2 g-1, and one fine-grained, in the range 0.0015 - 0.06 mm with a grain surface area of 10.00 m2 g-1) and with slightly different mineralogical composition. The S:Fe molar ratio in the leachates (1.0 - 1.5) indicates either that pyrrhotite is the main iron sulfide undergoing oxidation in our experiments, or, alternatively that the S:Fe molar ratio in the leachate is determined by pyrite weathering in conjunction with other processes releasing iron or immobilising sulfate. However, speciation modelling of the leachates indicates that ferrihydrite was close to saturation, suggesting that a ferric oxyhydroxide may have dissolved/ precipitated during the experimental period, thereby affecting the S:Fe molar ratio. Pyrite oxidation rates obtained from the two column experiments during æsteady-stateÆ were 2.25 + 10-13 and 8.45 + 10-14 mol m-2 s-1 in the coarse and fine tailings, respectively. Pyrrhotite oxidation rates, as an alternative, were 2.31 + 10-12 and 1.24 + 10-11 mol m-2 s-1 in the coarse and fine tailings, respectively. Natural microbial activity was confirmed in both the tailings and the leachates; therefore, the obtained oxidation rates are not strictly abiotic. It is thus concluded, based on the experimental results, that tailing heterogeneity will result in zones with different oxidation rates, related to their physical and chemical properties.

Jan 1, 2003

By W J. Bruckard

In Australia, ilmenite is produced from beach sand deposits. These deposits contain varying quantities of the valuable minerals zircon, rutile and ilmenite, along with a variety of other minerals. The valuable minerals are upgraded using combinations of gravity, magnetic and electrostatic processing techniques to yield high-grade products. One of the penalty elements present in ilmenite concentrates is chromium, present mostly as chrome spinels. This mineral is particularly difficult to separate from ilmenite, as the properties of the two minerals are very similar in relation to the traditional separation processes. While the deposits which have been treated in Australia in the past have had only low levels of chromium present, many of the newer deposits contain much higher levels of contamination and, thus, there is an increasing need to develop robust processes to separate chrome spinel from the ilmenite. Flotation, which is a unit process with the potential to solve this problem, has surprisingly received little attention for this application. The literature suggests the research effort to characterise the general flotation properties of chromite (chrome spinel with high chromium content) has been extensive and a substantial amount of data is available. However, the problem of separating a small amount of chrome spinel from a large amount of ilmenite requires a different approach to that from separating chromite from siliceous gangue, which has been the main commercial focus of chromite flotation in the past. Much of the work done has been fundamental in nature and the results obtained are fairly inconsistent, as is the testwork completed at batch and pilot plant scale. While these inconsistencies have been attributed to the variable composition of the mineral, there is little evidence supporting this premise. Just as chrome spinel and ilmenite have similar physical characteristics, the flotation response of both minerals is also similar. This paper reviews the literature relating to the flotation of chrome spinel and presents a considered approach to the development of a robust flotation method to separate chrome spinel from ilmenite.

Jan 1, 2001

By Y Peng, D J. Bradshaw, G Long

As copper reserves deepen, they are becoming increasingly less pure. Penalty elements such as arsenic, antimony and bismuth are occurring in increasing concentrations. Environmental issues with smelters are leading to increases in penalty rates for these elements such that some concentrates may become difficult to sell. Arsenic concentration in Rosebery copper concentrates during 2010 varied between 3000 and 8500 ppm. Arsenic levels above 5000 ppm can preclude import to some customer countries. Optical mineralogy has indicated that arsenic in Rosebery copper concentrates is most commonly associated with tennantite (Cu12As4S13) in solid solution with tetrahedrite (Cu12As4S13). In addition, silver reports to concentrate as freibergite (Cu12As4S13 ). A reduction in arsenic content will therefore lead to a concurrent reduction in the silver content.A literature review by Long, Peng and Bradshaw (2012) indicated that arsenic bearing minerals could be removed using potential controlled flotation. Some success in reducing the amount of arsenic had also been reported using either roasting or chemical depression using reagents such as lime and cyanide. Due to the location of the Rosebery concentrator adjacent to world heritage listed temperate rainforest, the use of a roaster or cyanide was immediately discounted. Lime is already used as a reagent in the Rosebery flow sheet, so could be considered as a potential arsenic depressant.In order to determine a method of separating out the high arsenic bearing minerals, two series of flotation tests were conducted. The first series investigated the effect of pulp potential on the recovery of copper, silver and arsenic minerals; a second series investigated the effect of pH, froth depth and regrind.CITATION:Long, G, Peng, Y and Bradshaw, D J, 2012. Production of a low arsenic copper concentrate at MMG Rosebery, in Proceedings 11th AusIMM Mill OperatorsÆ Conference, pp 347-354 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 29, 2012

By J Garritsen, P F. Wells, M Xu

IncoÆs Clarabelle mill currently processes ores from eight mines in the Sudbury basin area in Ontario, Canada. The ore from the Garson mine contains a much higher concentration of arsenic than the other ores. Adding this ore into the feed to the mill has resulted in an increase in arsenic content of the Cu-Ni bulk concentrate to a level that significantly affects the smelter operation, and more importantly the efficiency of Cu-Ni separation in the Matte separation plant. The arsenic occurs mainly as gersdorffite (NiAsS), with a small amount being in the form of cobaltite (CoAsS). Extensive laboratory tests on depressing arsenic in Garson ore flotation have been conducted and two reagent suites have been identified as effective arsenic depressants. One is the so called MAA depressant which is a mixture of magnesium chloride, ammonium chloride, and ammonium hydroxide. This reagent combination was reported to depress other arsenide minerals such as arsenopyrite (FeAsS) and enargite (Cu3AsS4). However, in this study for the first time it has been shown to have a depressing effect on gersdorffite. The other reagent suite, a mixture of triethylenetetramine (TETA) and sodium sulfite, that has been reported as an effective pyrrhotite (Fe1-xS) depressant in pentlandite ((NiFe)9S8) flotation, has not been reported as gersdorffite depressant before. The effectiveness of both reagent suites is more pronounced when the arsenic minerals are oxidised through pulp aeration or the addition of hydrogen peroxide. With a flow sheet consisting of a magnetic separation, rougher- scavenger flotation, followed by regrinding and cleaning of combined magnetic and scavenger concentrate, the arsenic recovery to the final Cu-Ni bulk concentrate was reduced from 73 per cent in baseline test to less than 30 per cent with either reagent suite at no decrease in nickel recovery. The TETA/sulfite reagent combination has the advantage over the MAA suite in that pyrrhotite is also depressed, rather than being activated, and the copper and nickel concentrate grades are therefore increased.

Jan 1, 2005

By H R. Watling, W van Bronswijk

Of the various copper sulfides in the EarthÆs crust, chalcopyrite is by far the most common. This mineral is also the most difficult to leach, with hydrometallurgical extraction processes characterised by prohibitively slow kinetics. While a number of processes, including leaching at atmospheric pressure and temperature, pressure leaching at higher temperature, and bioleaching of concentrates in stirred tanks and whole ores in heaps have been demonstrated to some extent, there is currently no full-scale unit process for the hydrometallurgical extraction of copper from chalcopyrite ores. Titan Resources NL operated a test bacterial heap leach at Radio Hill, Western Australia in 2001, to extract nickel and copper from a mixed sulfide ore that contained significant amounts of chalcopyrite, pentlandite and pyrrhotite. A proprietary mixed bacterial culture was used to inoculate the heap, and the nickel and copper were precipitated from the resultant solution as mixed hydroxides. Although 65 per cent of the copper from the Radio Hill heap was eventually recovered, the rate of extraction followed an unexpected trend, as the initial rates of copper recovery were much slower than column tests had suggested. It was postulated that this was due to dissolved copper precipitating as covellite or chalcocite in the most poorly aerated zones within the heap, ie furthest from the aeration pipes at the base. It was further hypothesised that the lack of oxidants (oxygen, ferric iron) and the likely inactivity of bacteria in these areas limited the re-dissolution of such secondary copper precipitates. In this study the above hypothesis was tested in column experiments using the same mixed sulfide ore and a synthetic leach solution. One set of columns was aerated and another set was operated without aeration. Results showed that precipitation of copper occurred regardless of whether the column was aerated or not. The results suggested that pH of the leach solution played a significant part in the precipitation of the copper. Further column tests revealed this to be the case. These results are described here in detail.

Jan 1, 2004