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Application of Agitated Leaching for Iron Removal from Silica Using Sulfuric and Hydrochloric Acid In this research, iron removal from silica used in glass industry was investigated using agitated leaching method. Silica sample was provided from silica concentrate originating from Chalchoog Silica Mine located in Abhar, Iran. The sample contained silica, iron oxides and clay minerals. For characterization of samples XRD and XRF analysis and atomic absorption method were applied. Silica and iron oxide (Fe2O3) grade of head sample was 98.41 per cent and 0.067 per cent respectively. Two inorganic acids (sulfuric and hydrochloric acid) were used in agitated leaching tests. Two series of L9 orthogonal array of Taguchi design with replication were used to determine the effect of parameters including acid dosage, leaching duration, ambient temperature and solid content on iron removal. The statistical calculations and analysis of variance (ANOVA) were carried out by means of DX7.0, Minitab14.0 and Winrobust1.02 softwares and also statistical calculations were checked manually using Excel software. Also multivariate regression was applied in order to forecast Fe2O3 conent of final product. The optimum conditions for leaching tests which sulfuric acid was employed are as follows: 40 minutes leaching time, temperature of 85¦C, 40 g/L acid concentration and solid content of 20 per cent. Under this condition the amount of iron oxide in silica was decreased to 0.042 per cent. The optimum conditions for leaching tests which hydrochloric acid was employed are as follows: 80 minutes leaching time, temperature of 75¦C, 30 g/L acid concentration and solid content of 20 per cent. Under this condition the amount of iron oxide in silica was decreased to 0.035 per cent.

Sep 13, 2010

By Buisman C. J N, Koch R. O

Soil and groundwater beneath the Budelco zinc production plant at Budel-Dorplein (The Netherlands) are contaminated with metals and sulphate. To avoid contamination of nearby drinking water aquifers in the very distant future, a geohydrological containment system (GCS) and a microbial treatment plant for extracted contaminated groundwater have been developed. As a first step in the design of the system groundwater data from over 150 wells and geological profiles were used to model geohydrological conditions beneath the site. Several configurations of water-extraction wells were deduced from the model. Data gathered during additional fieldwork were then used to improve the model. Finally results that were calculated for the various configurations were used to select an optimal groundwater containment system. Currently some 5000 m3/day groundwater are extracted from a combination of 12 shallow and deep wells. Heavy metals and sulphate have to be removed from the extracted water before it can be discharged into the river system or used as process water. Several water treatment methods have been studied and pilot-tested at the site. The preferred and selected process is based on the activity of sulphate reducing bacteria (SRB) and combines sulphate removal and heavy metal removal in one single step. The anaerobic bacteria reduce the sulphate to sulphide resulting in the precipitation of metal sulphides. A pilot plant gave promising results and a commercial-scale plant has been designed. The proposed design has been tested in a demonstration plant which included all main process units. Test results for all process units are presented. The collected information was then used to optimise the design of the commercial-scale plant. Special attention was paid to automation and safety items. Construction of the plant was finished in May 1992. Start-up, commissioning and operational experience are reported. The concentrations of metals and sulphate in the effluent of the SRB water treatment plant are well within the limits set by the authorities for discharge to public waters.

Jan 1, 1993

By B Whiteley, B Gee

The Northside Storage Tunnel is a TBM driven rock tunnel system designed to collect and store sewage from four major storm overflow points along the existing Northern Suburbs Ocean Outfall Sewer. At present, sewage overflows during wet weather are the main source of pollution for Sydney Harbour. The tunnel system comprises a 16 km long by 3.8 m to 6.5 m diameter tunnel from Lane Cove to the North Head Sewage Treatment Plant and a 4 km long by 6.3 m diameter branch tunnel from West Chatswood. The tunnel will have a typical rock cover of about 50 m to 150 m. Most of the tunnel alignment is contained within the Hawkesbury Sandstone Formation which is generally an excellent tunnelling stratum, and offers few geotechnical constraints. However, the tunnel is required to pass beneath incised palaeochannels at Middle Harbour and Manly with each palaeochannel containing about 70 m of sediment.Innovative geotechnical and geophysical investigations were undertaken to examine the tunnel route and characterise the rock beneath the palaeochannels. These investigations have located zones of poor quality rock beneath one palaeochannel in particular, suggesting significant stress relief had taken place in the rock at times of lower sealevel producing structural features indicative of valley bulging. This paper presents the geotechnical model developed for the tunnel, and the models and constraints for tunnelling beneath the palaeochannels.

Jan 1, 1999

By M I. Pownceby, A Torpy, C Johnson, N C. Wilson

To extract uranium from low-grade, calcrete-hosted uranium (CHU) ore is challenging owing to the presence of carbonate and swelling clay gangue minerals that require an alkaline lixiviant to be used. Western Australia possesses ~75 000 U3O8 t in CHU resources. Improvements to alkaline leach extraction practices would improve the economic potential of these deposits.A column leach study of CHU ore was run for 105 days using an alkaline carbonate-bicarbonate lixiviant. The uranium content of the liquor plateaued after 75 days at ~275 mg U/L; the calculated maximum solution capacity was 800 mg U/L. Spiked peaks and troughs were seen in the data set beyond the 60th day, where concentrations ranged from 220 - 290 mg U/L, indicating possible cyclic uptake and loss of uranium from the solution.Pristine and leached ore samples were geochemically analysed and mineralogically characterised at high resolution using a field emission gun-electron probe micro-analyser (FEG-EPMA). Results showed that leached ore samples from the top of the column contained less carnotite than pristine ore. In contrast, leached ore samples from the column base contained regions with more carnotite than pristine ore, indicating precipitation. Three carnotite grain micro-structures were identified in the leached ore; fan-spherulite, granular and core-shell cubes, with evidence for multiple growth phases.Evidence of carnotite precipitation was seen at the edge of and in pore spaces within montmorillonite and dolomite grains. The point of zero charge of both minerals is lower than the pH of the lixiviant (pH 10.8), thus the mineral surfaces are negatively charged and would not attract UO2(CO3)34- ions out of solution. Similarly, the decrease in the uranium content of the lixiviant is not attributed to super-saturation, as this was unlikely to have been achieved. Work is ongoing to understand the reason for carnotite precipitation and the fluctuations in the lixiviant uranium concentration that are seen.CITATION:Johnson, C, Pownceby, M I, Wilson, N C and Torpy, A, 2013. Microscale characterisation of pristine and processed ore - implications for leaching calcrete-hosted uranium ore, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013 , pp 303-316 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 29, 2013

Mining is an intensive resource development industry, where operations are often of relatively short duration and can result in dramatic impacts on the natural environment during the operational period and for many years post mining. An integral component of all mining operations is water û through exploration, resource definition, mine development and operation, rehabilitation and the long-term post-mining land use. Water is a basic requirement in the provision of worker amenities, in drilling, as a means of dust suppression, as a medium for washing or processing the mine product, and as an aid in establishing vegetation on post-mining landforms. Water also plays an important role in mobilising environmental contaminants and is the primary medium for the transport of contaminants off the mine or processing site into the wider environment. It is for this second reason that the mining industry considers water management as a key component of mine management. Cost-effective water management relies on planning that incorporates a total mine system approach commencing prior to exploration and continuing through to rehabilitation and decommissioning. One of the primary considerations that will provide confidence to both government and community at the time of mine closure and lease relinquishment, will be the evidence that any water originating from, or passing through, the mine site is of a quality that will not have any negative impact on the surrounding environs into the future. The role of vegetation in stabilising disturbances to a landscape is well known, as is the recognition of vegetation being a fundamental component of the water cycle through the physiological processes resulting in the transfer of water back to the atmosphere through transpiration. In terms of water management at a mine site, the two crucial issues are the æquantityÆ and æqualityÆ of water that enters a receiving æoff-leaseÆ catchment. In terms of tolerances of the receiving environment, the total load of potential contaminants becomes critical, a reduction in which can be achieved through reduced volumes of water discharged, reduced chemical and physical concentrations of contaminants in that water, and ideally, both. This paper examines the potential role of vegetation in reducing the quantity of water released from a site, and secondly considers vegetation in the role of influencing the quality of that water.

Jan 1, 2003

By Soldenhoff K, Levins D, Collier D, Day A, Secomb R, Brown S, Tapsell G, Bellingham A, Quan C

Bench and pilot plant studies were carried out at ANSTO to develop a process for rare earth recovery from the Mt Weld deposit near Laverton, Western Australia. This paper describes the development of the flowsheet, which is similar to conventional monazite processing, but with the introduction of several innovative steps to account for the complex rare earth mineralisation and the presence of specific gangue minerals. A unique feature of the flowsheet is the recovery of cerium by solvent extraction from a sulphate leach liquor. The process was tested continuously by the operation of a pilot plant at ANSTO's Lucas Heights Research Laboratories, Sydney in the first half of 1992. The plant, designed to treat 100 kg per day of beneficiated ore, confirmed the viability of the process, with rare earth products from the operation satisfying stringent buyer specifications.

Jan 1, 1993

By S C. Dominy

Current and proposed methods of resource classification relate to the geological, economic and technical confidence in the estimated resource. Geological confidence is, however, only vaguely defined. It is largely related to the level of drilling and sampling, to the geologistÆs perceived level of confidence in his/her work and on the continuity of the mineralisation. Rarely has any real attempt been made to assess how well a deposit has been explored, sampled and evaluated and how accurate or realistic the geological model is for the deposit. This contribution reviews the impact of two of the potential sources of error, ie sample recovery and quality. The first of these parameters is measured during logging and assaying, but is often forgotten during grade and tonnage estimation, and resource classification. Preliminary studies have shown that modelling of this parameter is a valid exercise, which should accompany the evaluation of grade and other economic parameters. The sample recovery factor for an ore block can then be used to reassess the confidence in the block. It could, for example, downgrade the status of a Measured Resource to an Indicated Resource even though standard methods might indicate that the higher classification is applicable. A method is proposed by which this recovery factor could be incorporated into current resource classifications producing a more sophisticated and comprehensive measure of sample quality. A review of the sources of error naturally leads to the assignment of scores to each stage of the evaluation process, depending on the methods used and assumptions made. Sample recovery is one important factor, which is likely to appear at several stages. These scores can then be weighted and combined in a manner resembling that used in the CSIR Rock Mass Classification. This score will then allow the resource estimate to be rated on a scale from 0 to 100 per cent to produce a Quality Control Index (QCI). However, this index must then be modified using an Evaluation Difficulty Index (EDI), which reflects the difficulty of a particular style of mineralisation to accurate resource estimation. This results in the production of a Resource Reliability Rating (RRR), which can then be linked to international classifications, such as the 1999 JORC; 2000 CIM; and 2001 EURO codes. This will permit a more precise definition of geological confidence levels or, combined with estimation error, produce a classification system in its own right. This same rating can also be used as the basis for technical audits of mineral projects.

Jan 1, 2002

By J Champa

The mining industry internationally seems on the verge of a major underground support revolution as suppliers, mines, consultants and researchers develop, test and use thin support (structural) membranes (or superskins as they are commonly called) mainly as a replacement for screen/wire mesh. Thick membrane support in the form of shotcrete (sprayed concrete) has been used since the 1950s in underground mines. Shotcrete, in mines, is generally applied at a thickness between 25 and 100 mm depending on the need. Thin membranes are however applied at a typical thickness between 2 and 6 mm. Certain thin membranes have been available for several years (Tannant et al, 1999), but the intense interest in such supports has only grown in the last few years. The interest lies mainly in the potential to safely reduce the mining cycle time and hence improve productivity. There is however considerable confusion concerning such supports, and this paper attempts to clarify certain aspects and dispel certain misconceptions and myths about thin support membranes.

Jan 1, 2000

By Reimer TH

The model described in this paper has been developed for and in close collaboration with the Bong Mining Company Ltd, Liberia/West Africa. When working an irregular deposit a de- tailed short term production schedule becomes necessary in order to ensure an equal and homo- genous concentrator feed. If the irregularity of the ore body exceeds a certain degree, blen- ding facilities have to be provided between the mine and the concentrator, but even then sche- duling of the mine production is inevitable to meet the given requirements of the blending bed and to keep these conditions steady for at least some of the successive periods. To assist the planning department in set- ting up optimal production schedules a computer model has been developed using a linear pro- gramming approach. The deposit is divided into equally shaped blocks containing defined quali- ties and quantities of ore and/or waste; from which one has to select those quantities of ore which will meet the requirements of the blen- ding bed. The objective function of the model

Jan 1, 1977

By Horowitz F. G, Lamb P

As mining operations become larger and more complex, larger volumes of geological, geophysical, and production data must be manipulated and interpreted on a day-to-day basis. Because of the large volume of data, more sophisticated data storage strategies, interpretation tools, and visualisation tools must be used by exploration and mining operations in order to remain competitive. Critical to better practice is an understanding of the basic syntax and character of geological and mining data, expressed in the form of a data model. In the short-term, a data model can be used to implement or evaluate schemes for data storage or exchange. It can be used to evaluate software. In the longer term, a data model is essential to the design of the next generation of software for 3D geological modelling. In this and the related paper (Lin et al, 1995) the data model in use by CSIRO is presented, together with: 1. examples of the use of data transfer in the linkage of existing mining software; and 2. examples of the use of the data model in software design.

Jan 1, 1995

By Bhattacharyya A. K

A strata parameter is introduced to include the deformation characteristics of the undermined strata in the prediction of subsidence movement. By using the strata parameter and mining factors as parameters, a nomogram for predicting the maximu

Jan 1, 1994

The Mineral Research Centre is located at Perth in the suburb of Waterford, adjacent to Curtin University of Technology and within a Technology Precinct which includes Technology Park. The Centre, constructed by the WA Government at a cost of $16 million and occupied in late-1994, comprises three separate buildings housing the CSIRO Division of Minerals, Curtin University's School of Chemical Engineering and the Mineral Processing Laboratory of the Department of Minerals and Energy. The emphasis on R&D at the Centre is primarily in hydrometallurgy as a result of staff expertise, extensive bench and pilot-scale facilities, track record with the industry and, very importantly, two of the occupiers being partners in the AJ Parker Cooperative Research Centre for Hydrometallurgy. Staff in the Centre have a long involvement with R&D agencies such as AMIRA and MERIWA. The hydrometallurgical focus of the Centre complements that of pyrometallurgy at the GK Williams CRC in Melbourne and the Centre for Mining Technology and Equipment in Brisbane, to ensure that the mineral processing industry in Australia has access to a complete range of expertise and facilities to serve its needs.

Jan 1, 1996

By M Rankin, F Medina, R Verburg

We conducted a preliminary assessment of an extensive deposit of historic tailings discharged over a period of 40 years to the shoreline along a Southern Peruvian coastline. The tailings formed an extensive beach approximately 2.4 km long and 300 m wide. The tailings consist principally of pyrite (37 to 59 per cent), hematite (nine to 20 per cent), magnetite (three to 13 per cent) and quartz (11 to 36 per cent). The present operating company was required to evaluate the feasibility of capping the ocean side tailings deposit, however, given the size of the undertaking and the potential to reclaim residual minerals from the tailings, it was prudent to first evaluate whether capping would in fact reduce the impacts to the marine environment. Therefore this preliminary assessment examined: 1. metals contamination in tailings, shoreline porewater and marine sediments; 2. reactivity of tailings and acid generation potential; and 3. the potential for biological effects from metal contamination in the uplands tailings (solid phase) and beach porewater. Based on mineralogy, column leach studies and chemical results, the upland tailings have a high geochemical potential to acidify and release metals, especially copper, nickel and zinc, should they be subject to oxygenated and aqueous conditions. But, the extreme arid climate results in very low potential for precipitation and virtually precludes the transport of acid drainage reaction products from the upland tailings towards ocean. Wind erosion caused by offshore winds is likely a small source of tailing transport to the ocean. Since some potential exists to reprocess the tailings in the future, capping does not seem justified at present.

Jan 1, 2003

For several years, the Geology Department of the University of Canterbury has hosted a series of postgraduate projects in the field of coal studies, supported principally by the Ministry of Energy and to a lesser extent by private companies. These projects have involved mainly West Coast Coalfields, and my own studies have focussed on inorganic geochemical aspects of West Coast coals. Because of the large number of potentially important analyte elements in coal, and the wide diversity of coals occurring in the West Coast region, this project has required a substantial amount of work to be spent on sample collection, sample preparation, development of analytical methods, and actual analysis. Considerable problems must be faced at the sampling stage: Can sufficient information be obtained from whole-seam composites, or should seams be sampled in plies. Ply analysis is preferable, but results of proximate analyses are usually available for composites only. Where multi-seam drillhole samples become available (eg Greymouth Coalfield, where some holes yielded more than six sampled seams), the ply option involves a dramatic increase in the number of samples. I have attempted to strike a workable compromise between geographical coverage of coalfields, and detailed sampling of individual seams at each locality. In many cases, sample material has been used jointly with Jane Newman who has carried out petrographic studies.

Jan 1, 1985

By Prosser A. P

A computer simulation is being developed for in-situ leaching of unbroken, Zn-Pb-Ag sulphide ore. Ferric chloride is the selected reagent. Experimental work showed that a diffusion control model of the kinetic aspects was better than a surface chemical reaction control model. Entrapped reactive grains were accessible to reagent in the samples tested. Precipitated sulphur did not seriously hinder the reaction.

Jan 1, 1987

By E Villaescusa, C Drover, I Onederra

Development face destress blasting is a construction technique in deep mining, which aims to prevent, reduce the frequency, or manipulate the timing of violent, stress-driven rock mass instability at the face. This paper presents a destress blasting design concept that was optimised for the specific rock mass conditions of a deep mine using the Hybrid Stress Blasting Model (HSBM) software. The design was then implemented in an area of the mine where stress-driven instability of the face regularly occurred during development. An adjacent tunnel was constructed in parallel without destressing, within the same rock mass conditions, as a control. The rock mass response to each excavation was quantitatively compared using high-resolution local seismic monitoring. Visual observations of the fractures created by destress blasting were also made. The analysis indicated that destressing reduced both seismicity and the rock mass stiffness ahead of the face. This was inferred from the spatial broadening of the development seismogenic zone and the typically significant reduction in the spatial density of seismic events. Seismic source mechanism analysis also indicated that destress blasting generated a much wider variety of failure modes than conventional blasting. Most seismic source mechanisms following destressing were associated with natural joint structures. A relatively small portion were consistent with newly created blast-induced fractures. The greater diversity of rock mass failure modes associated with destressing implied a lower potential for stain-energy accumulation within the rock mass at the face, and thus a lower risk of hazardous instability. Observations of visible rock fracturing indicated that the major principal stress influenced the damage intensity on natural geological structures within the destressed zone, and that numerical predictions of radial fracturing limits made by HSBM analysis were realistic representations of the real blasting performance.

Nov 29, 2022

By W D. Ortlepp

Seismicity associated with deep block cave mining operations in hard rock can give rise to dynamic loading of the mining openings. A description is given of the source and damage mechanisms associated with such seismic events, and the possible demands placed on the rock support by the resulting dynamic loading. In addition, production level drifts are often subjected to large static deformations during mining. Appropriate support, able to sustain large static deformations, and capable of absorbing the energy released during dynamic loading, is described. The performance of these support types has been determined by means of large-scale dynamic loading tests, and large deformation static laboratory tests. Finally, a support system which is considered to be appropriate for extraction drifts in block cave layouts subjected to dynamic loading is described.

Jan 1, 2000

By T J. Sheer

Water vapour refrigeration (systems using water as the refrigerant) could potentially be used to provide chilled water at underground locations in mines, as an alternative to conventional refrigerators using refrigerants such as R-134a. The use of water as both the primary and secondary refrigerants is attractive in concept since direct-contact heat exchangers could be used, yielding higher coefficients of performance. The disadvantage of water is the very high specific volume of the vapour at low pressures, which leads to great challenges in compressor design, as has been reported previously in the context of slurry-ice plants for mine applications (Ophir and Koren, 1999). Steam ejectors have long been known as alternative compression devices for refrigerators, but no work has been done previously on the possibility of using ejectors powered by high-pressure water, which is readily available in mines from long pipe columns in vertical shafts. This paper presents the results of a laboratory investigation into the use of high-pressure water as the motive fluid in an ejector refrigerator. No previously reported liquid ejector system has achieved subcooling of the process fluid, ie a reduction in fluid temperature within the evaporator to a level below that of the motive fluid. In contrast, the present work demonstrated that subcooling could occur at motive water pressures above 5 MPa. Mine cooling applications were considered and it was concluded that while this concept would not be feasible as a mine-wide cooling source, there could be specialised applications where it would be beneficial. One application would be to cool backfill and thereby reduce the heat load at the working face. In this case the best performance would be achieved by using the ejector in combination with an energy recovery system such as a Pelton turbine or a three-chamber pipe feeder.

Jan 1, 2005

The paper explains the genesis of the Ballarat College of Advanced Education to its unique position in mining engineering education. A description follows of the development of the Graduate Diploma in Occupational Hazard Management which commenced in 1979 in the cooperative mode of four groups of three weeks full- time study followed by twenty-three weeks in industry. In particular an analysis will be given of the state of origin of students, ages and employing industries. Given the experience from the evolution of this course a similar process is described for the Graduate Diploma in Mining which has been accredited to commence early in 1987.

Jan 1, 1986

By B Bendtsen, L McQueen

The use of shotcrete as an efficient means of both temporary and permanent ground support has continued to grow over the last 30 years, with its use underground now commonplace around the world. However, the development of analytical design methods has lagged advances in material and application technologies. Historically, part of the reason for this was a lack of understanding of how shotcrete linings actually worked. Considerable progress has been made in this area in recent years and this paper attempts to summarise the current state of practice with respect to shotcrete lining design. It then concludes by summarising areas where the authors consider future research and development is still required.

Jan 1, 2008