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By T. Watanabe, S. Hayashi, M. Hayashi, K. Nagata, H. Fukuyama

Chemical states of fluorine in CaO-SiO2-CaF2glasses in a composition range of CaO/SiO2=0.5?1.3 and 5?25 mol%CaF2have been investigated by 19F solid-state NMR with and without MAS. The isotropic chemical shifts of the glasses are close to those of cuspidine crystal (59.4 and64.3 ppm with respect to C6F6) and CaF2crystal (58.6 ppm). The fluoride ions are coordinated with four or less than four calcium ions in this composition range. The chemical shifts move to the lower frequency with an increase in the CaF2content, whereas those are not affected by theCaO/SiO2ratio. The ionic distance between calcium and fluoride ions increases with an increase in the CaF2content. The chemical state of fluorine is not disturbed by the degree of polymerization of the silicate network. Comparing the MAS and static NMR spectra, the second moment attributed to 19F-19F dipole-dipole interaction has been estimated. The values of the glasses range over 3.1?7.3107Hz2andthose are larger than the calculated value of cuspidine crystal. This indicates that fluoride ions form Ca-F clusters in the glasses and that the size of clusters increases with increasing the CaF2content. Keywords: chemical state of fluoride ion, CaO-SiO2-CaF2glass, solid state 19F NMR spectroscopy

Jan 1, 2004

By Xu Ronglie

This paper looks back on the developments and achievements of deep foundations, on the basis of the complex geological conditions and environments in China. It sums up advances in theoretical and applied researches, engineering constructions, practical experiences, case histories, and problems and developing prospects of piles and deep foundations in recent years in China.

Jan 1, 1991

By Magno Rodrigues Ribeiro, Alexandre Cabral Stelzer, Cacio José da Silva, Leonardo Nogueira Ferri, Marcelo Ciminelli Mendes, Christophe Bouché, Marco Aurélio Soares Martins, Evenilson Soprani Lopes, José Xavier da Silva Filho, Sérgio Luiz Dalvi

Since 2001, CVRD is carrying out a modernization project in it’s pelletizing plant’s automation systems, that comprehends instrumentation, control and information systems. In addition, the project includes implementation of advanced control systems, using artificial intelligence techniques, including fuzzy logic, expert systems and dynamic physical models, to increase production, reduce fuel and energy consumption and improve quality. This paper reports CVRD’s experiences in carrying out an optimization project.

Jan 1, 2005

By R. S. Dean

[In E;encralt the I~8:al:ul',~,C,-J. Div:'sion conducts in\'8stigations relat-ing to the treatment of OrGR o.nd L!\3tallurl..'"lcal prod tctR froJ] t~e condi tion in :hich they are Itinod to t!1e refi!l(,u r.etal, . ' th 'the ob,icct of conserving natmal' resources .e..nd 81:mir..3.tin~ wacte by furn.i:::hir..g :nforInf'_tiou on current methods of metal11:.rgical practice, Tfu'..:.kir..g fund T!l;ntal .;;.otudie'" of metal-lurgical processe~, and de~eloping ~e~ proc6sses O~Q lloys to the point of dewonctrati:r:g the:'..r practicab'lity or va.lue}

Jan 1, 1941

By Robert Stefanko

This report, rather than attempting to replace previous annual reports, supplements, and more importantly, coordinates and summarizes the entire effort. Even with such restrictions, the report is voluminous and, therefore, a decision has been made to divide it into two parts. The first volume is basically narrative and includes tabular results and analyses. The second volume is in appendix form giving detailed information. Together, they permit a logical discussion of all aspects of the project (Volume I) without cumbersome distractions but, at the same time, provide all the details to permit others to evaluate and explain the results or develop similar research programs (Volume II). The aim of the original proposal was basically to develop instruments and techniques and then make measurements of suitable power parameters, ground fault currents and ground resistance beds. With such information available, it was possible to develop a meaningful simulator which would permit investigating electrical systems and components on paper without costly trial and error procedures in the third year, a cable splice testing program was added to the project. While there were the usual delays attendant in such original research, these objectives were achieved.

Jan 1, 1973

By Thomas L. Ochs

The stripping of iron-laden solvent with hydrochloric acid in the iron-removal step of the clay-hydrochloric acid process for the extraction of alumina from calcined kaolinitic clay results in a loaded ferric chloride stripping liquor. Treatment of this stripping liquor at boiling with calcined kaolin to form insoluble Fe203(s) and a dilute A1C13 solution was undertaken by the Bureau of Mines to characterize process problems and to aid in sizing of solids-liquid separation equipment. Variables identified as important in the chemical reaction were calcined kaolin particle size, ratio of calcined kaolin to FeC13, and reaction time. These parameters were tested for significance and their interactions investigated. Fine calcined kaolin (-65 mesh) at a greater than 1:1 mole ratio of contained acid-soluble A1203 to Fe203 equivalent of the FeC13 in the stripping liquor required less reaction time than coarser (-16 mesh) material. Solids-liquid separation of the reacted slurries by both settling and filtration requires flocculation.

Jan 1, 2011

By Greg Hendon

Various methods have been used to evaluate the effectiveness of shields in place. The most common method used is static recording of leg pressures by visually examining pressure gauges. In an effort to more closely examine the shield cycle and therefore the shield effectiveness, Jim Walter Resources has implemented a program of monitoring utilizing a polycorder system which is capable of recording convergence and pressure measurements on a continuous basis. This paper will discuss two longwall panels at Jim Walter Resources which have been monitored.

Jan 1, 1990

By N. Kuyucak

"Acid mine drainage (AMD) is one of the most significant environmental challenges facing the mining industry worldwide. It occurs as a result of natural oxidation of sulphide minerals contained in mining wastes at operating and closed/decommissioned mine sites. AMD may adversely impact the surface water and groundwater quality and land use due to its typical low pH, high acidity and elevated concentrations of metals and sulphate content. Once it develops at a mine, its control can be difficult and expensive. If generation of AMD cannot be prevented, it must be collected and treated. Treatment of AMD usually costs more than control of AMD and may be required for many years after mining activities have ceased. Therefore, application of appropriate control methods to the site at the early stage of the mining would be beneficial.Although prevention of AMD is the most desirable option, a cost-effective prevention method is not yet available. The most effective method of control is to minimize penetration of air and water through the waste pile using a cover, either wet (water) or dry (soil), which is placed over the waste pile. Despite their high cost, these covers cannot always completely stop the oxidation process and generation of AMD. Application of more than one option might be required.Early diagnosis of the problem, identification of appropriate prevention/control measures and implementation of these methods to the site would reduce the potential risk of AMD generation. AMD prevention/control measures broadly include use of covers, control of the source, migration of AMD, and treatment. This paper provides an overview of AMD prevention and control options applicable for developing, operating and decommissioned mines."

Jan 1, 2002

I am wearing two hats today. When the invitations went out to participate in this forum, two were received in the head office of the Department of Lands and Survey - one addressed to the Director-General of Lands and one to the Chairman of the National Parks Authority. It seemed logical that as the department is responsible to the Government for the administration of the National Parks Act 1952, we should respond by providing one speaker to cover both the department's interests and those of the National Parks Authority. I hope, however, that this will not blur the clear distinction which exists in the context of the mineral industry between Crown land on the one hand administered by the department for the statutory Land Settlement Board and national parks and allied reserves on the other hand which are the responsibility of the National Parks Authority.

Jan 1, 1976

By Nicolas Denies, Gust Van Lysebetten, Bart Lameire, Jan Maertens, André Vervoort, Noël Huybrechts, Flor De Cock

"Abstract Originally developed for ground improvement works, the deep mixing method (DMM) has increasingly been applied in recent years for the realization of soil and water retaining structures and as alternative to traditional foundation solutions. From practice, there is a real need for practical guidelines dealing with the execution, the design and the control of such applications. With the aim of developing such guidelines, the BBRI ‘Soil Mix’ project was initiated in 2009. Within this research project, deep soil mix (DSM) material from 38 Belgian construction sites has been tested. In spite of the large advances in the mechanical characterization of the DSM material, one major issue remains the representativeness of the typical core samples in comparison with the real scale behavior of the soil mix elements. There is among others the question of the influence of the unmixed soft soil inclusions on this behavior and the issue of the scale effect which must be considered in the design. In order to investigate these questions, 8 large scale UCS tests and 17 large scale bending tests have been performed on excavated soil mix elements. The present paper discusses results of this experimental campaign, presents some research perspectives and highlights different aspects related to the design of soil mix elements for the realization of retaining wall or foundation solution.INTRODUCTIONSince several decennia, the deep mixing method (DMM) has been used to improve the strength and deformation characteristics of weak soils. In recent years, deep mixing has increasingly been applied – in Belgium and in other countries – for the realization of soil and water retaining structures and alternative foundation concepts. With regard to the execution of the DMM, one can refer to the European standard EN 14679 on deep mixing (2005) that was elaborated under the umbrella of CEN TC 288 “Execution of special geotechnical works”. However, from practice, it has been experienced that this execution standard does not provide enough pragmatic information and guidelines, in particular for the more recent applications of the deep mixing method (with retaining and bearing functions). The same need by the sector for guidance rules linked to design aspects in the context of Eurocode 7 was experienced as well. With the aim of developing such guidelines and in order to provide feedback to the European standardization platforms, the Belgian Building Research Institute (BBRI) has initiated the BBRI ‘Soil Mix’ project (2009-2013) in collaboration with the KU Leuven and the Belgian Association of Foundation Contractors (ABEF), the Belgian branch of the EFFC. Within this research project, deep soil mix (DSM) material from 38 Belgian construction sites, with various soil conditions and for different execution processes (CVR C-mix®, TSM and CSM), has been tested (Denies et al., 2012)."

Jan 1, 2014

By B. Law, M. Menabde, B. Baird

Blasor is a new mine planning tool which is being used in the long and medium-term optimization of multi-open-pit operations throughout BHP Billiton’s Base Metals and bulk commodities portfolio. It is not just a scheduler, nor even only a schedule optimizer—although this function lies at the heart of the tool’s functionality—but a pit development plan optimizer, used from ultimate pit design and process plant capacity sizing right through to mining phase design and optimal panel scheduling. The tool uses a mixed-integer-linear-programming optimization engine to determine when material should be excavated and where it should be sent to optimize discounted operating cash flow over the life of operation. The core software design concept of Blasor is to provide a tool which is intuitive and flexible enough so that a competent mine planner can perform a pit development plan optimization without assistance from optimization specialists. To this end, a generalized graphical user interface has been implemented which allows full configuration of the optimization problem, including the definition of all inputs and constraints, specification of the material flow topology, bin and destination class definitions and full specification of the economic model encompassing prices and costs. This paper describes the capability of Blasor and outlines the design concepts underlying its design philosophy.

Jan 1, 2007

By L. C. IlsLey

"There is an old saying that ""It is too late to lock the stable after the horse is stolen"". Is not this just what is being done by many mine operators today when it comes to buying safe electrical equipment for gaseous and dusty coal mines?The ""open type"" of electrical equipment or even the ""half safe"" type represents the unlocked stable. After the mine disaster, and after men have lost their lives, the lock is put on - that is, safer equipment is installed.For example, an open type of electric coal drill was used in a gaseous mine in West Virginia, This was the probable cause of the death of 27 men. A half safe type of electric coal-cutting machine was used in a gaseous mine in Pennsylvania. This was likely the cause of the death of 36 men. An unapproved, unsafe type of flame safety lamp was used in a gaseous and dusty mine in Utah. This was the all¬eged cause of the death of 171 men. All three disasters happened within the last six months, and seem to have been avoidable if proper equipment had been used.It is understood that more rigid requirements will be enforced in West Virginia. The committee of State mine inspectors made definite recommendation for im¬proving the conditions in the given mine in Pennsylvania. The Industrial Commission of Utah have already issued new orders which will remedy the use of unsafe lamps in that State.These acts and recommendation are all good and will help prevent accidents in those States in the future. Is it not a pity that such recommendations and order were not made a little earlier before the tell of life had been exacted? Is it not a pity that other States will not take these lessons to heart and safeguard their mines before and not after disasters take place?Electric current can cause accidents in five general ways as follows: (1) By shock to persons; (2) by igniting powder; (3) by igniting gas; (4) by igniting coal dust; and (5) by setting fire to inflammable material such as timber and coal. A great many accidents from these causes are preventable if proper care is taken. Most of the accidents caused by sparks and flashes from electrical apparatus would not take place if approved electrical equipment was used. By approved equipment, the writer means equipment that has been tested and formally approved by the Bureau of Mines. So far as known, up to the present time, no disasters have been caused by sparks or flashes from equipment having the Bureau's approval."

Jul 1, 1924

By R. Leithner

The need/wish to sequestrate CO2is based on the assumption of the International Panel of Climate Change (IPCC), that CO2 maybe the major driver in climatic changes, i.e. especially the anthropogenic CO2emissions due to the combustion of fossil fuels like coal, oil and natural gas will increase the atmospheric CO2-content, which will lead to higher temperatures in the atmosphere. The 0.03% CO2in the atmosphere have a 22% share of the natural greenhouse gas effect of 33 K necessary for life on earth. The main share of 62% has the water vapour in the atmosphere. Only if one concentrates on the greenhouse gas effect of the gases beside water vapour, CO2 becomes most important with 58% influence. In addition there are other influences on the climate like: • Eccentricity of earth’s orbit, precession of orbital plane, obliquity and precession of earth’s rotation axis (Milankovitch’s theory) • Sunspots and magnetic field of the sun • Changing streams in the ocean • Volcanic activities • Distribution of continents on the surface of the earth • Impact of meteorites • Change of insulation by interplanetary dust [Muller, R.A. 2000] etc. To answer the question, if the CO2-content in the atmosphere has an important or exclusive influence on the earth atmospheric mean surface temperature, one should look into history. Figure 1shows the mean temperature of the atmosphere and the atmospheric CO2-content time histories 1 billion years back; no correlation can be found between them. Nevertheless a lot of countries have committed themselves to reduce their CO2-emissions.

Jan 1, 2004

By Wern-ping (Nick) Chen

In concrete lined tunnels, formwork removal timing may be controversial. Contractors seek to strip the form as soon as possible, and designers seek to keep the formwork in place as long as practical to protect the fresh concrete. Formwork removal timing is normally specified as a function to its insitu concrete strength. This approach may work for smaller diameter tunnels, but fallacy occurs when applying this approach to larger diameter tunnels, since a larger diameter would experience more displacement than a smaller diameter tunnel from its own weight. Excessive deformation may fail a tunnel to meet its roundness criterion and overstress the lining causing cracking or falling from the crown. This paper presents a contractual mechanism to mitigate this issue.

Jan 1, 2008

By Rafael C. Castro

As part of its risk management plan, the South Central Connecticut Regional Water Authority (RWA) is assessing the condition of its system of raw water conveyance tunnels and connecting pipelines. In 2006, the RWA inspected one of the system?s main tunnels, a 4-mi, 1950s-era tunnel that had not been inspected since its construction. The inspection team prepared extensively for the unknown conditions in the tunnel, and the inspection was completed safely and successfully. This paper describes the team?s pre-entry preparations, dewatering and ventilation efforts, surface-to-tunnel communication, access, physical inspection of the tunnel, and the lessons learned throughout the process. Additionally, this paper will preview planning for the subsequent inspections.

Jan 1, 2008

By George A. Savanick

An experimental hydraulic jetting device intended to operate in a 16-in-diam borehole was designed, fabricated, and used to cut coal and simulated coal samples. This device consisted of two 0.107-in-diam nozzles that rotated in a plane perpendicuIar to a 50-inch length of high-pressure tubing. Experi¬ments were also conducted with stationary jets issuing from a single 0.142-in-diam nozzle. Numerous experiments were performed using systematic variations of jet parameters coupled with assessments of cutting rates. These Bureau of Mines tests showed that when operated at 4,000 psi pressure and a 40-gpm flow rate (1) the device can fragment coal up to a distance of 8 feet from the nozzle, (2) 4,000-psi jets cut more effectively than lower pressure jets with the same nozzle diameter, (3) stationary jets do not cut as effectively as moving jets, (4) interkerf breaking occurs when the kerf spacing is less than 2 inches, and (5) if the kerfs are spaced <1/2 inch, the jet is deflected and thereby reduces cutting effectiveness.

Jan 1, 1975

By G. R. Moulder

A device was developed that measures dynamic stress (ultrasonic energy) transfer through installed rock bolts, a measure that is directly proportional to the degree of grout bonding of the bolt to the mine roof structure and thus the ability of the bolt to bear static stress. The rock bolt bond tester (RBBT) is a hand-held portable device that shows three ranges of bolt bond condition; i.e., one-third (Bad bond), two-thirds (marginal), or fully bonded. These are shown respectively by a red, yellow, or green light that displays for 4 s. RBBT performance was verified with 2 1/2-to 8-ft bolts installed in various types 0f mine roof structures (sands tone, shale, and boney coal-mud), and 15 now being tested by the Bureau of Mines in mines across the United States. The unit is about the size of a five-battery flashlight and contains the transducer electronics, and battery pack. The RBBT is designed for extreme ease of operation, requiring only manual contact with the bolt and signal read-out. The batteries are rechargeable and the package is designed for durability in a mine environment.

Jan 1, 1983

By G. F. Kuncir

The analysis described herein evaluates the Bureau of Mines Program for Advancing Mining Technology - Oil Shale in terms of the economic benefits which may be derived for the Nation as a result of its successful research and development efforts. On the basis of postulated oil shale production scenarios, benefit-cost ratio indicators are computed for the program elements as they apply to surface, underground, and modified in situ oil shale mining systems. Eight value indicators are used to measure the Program&apos;s beneficial impact on the future oil shale industry in relation to planned research and development costs. These are: capital cost savings, operating cost savings, labor savings environmental quality maintenance cost reduction, reduction in production costs, byproduct production benefits, total production benefits, and additions to recoverable reserves. Program costs are aggregated from 1974 through 1987 and major benefits are accrued from 1982 through 2040. Both cost and benefit streams are discounted to mid-1975 present value.

Jan 1, 1977

By T. A. Ngcobo

Paper written on project work carried out in partial fulfilment of BSc Eng (Mining)degree The purpose of this report is to assess the risks faced by mines in dolomitic compartments in particular Kloof 8 shaft. The dolomites of the West Rand comprise one of South Africa?s most natural water resources, and overlie the reefs of the richest gold mines in the world. The pumping of water from the dolomitic aquifers to prevent flooding has caused the natural water table to subside, and the resulting cavities within the dolomite rock formations that overlie many gold deposits sometimes collapse, causing sinkholes. These impacts of the mining industry could worsen over time if preventative measures are not taken. This report discusses these impacts in detail, more specifically the risks to which operations in dolomitic compartments are exposed. A risk analysis was carried out to access the risks that the organization could face and it was this analysis that allowed one to examine the best methods to combat the problems. Other factors such as geological features and seismic events were also considered for the evaluation. To aid with the completion of this work various resources were utilized. A literature study was undertaken, information was gathered from various experts who specialize in dolomitic studies, evaluations were conducted and conclusions reached. The results from the project indicated that preventative measures should be implemented and correct procedures put in place to prevent any disasters.

Jan 1, 2006

By B B. Du, Y N. Lu, L X. Wang, S L. Wu

The cohesive zone in the blast furnace is largely affected by the softening and melting behaviour of ferrous burden because of its vital role in the blast furnace process. The Visual High Temperature Methodology (VHTM) has been given to study the softening and melting behaviour of sinter, two kinds of lump ores and acid pellet intuitively. Before softening, both two kinds of lump ore swelled and more serious for lump ore B because of its denser structure than lump ore A. The softening and melting temperature intervals are different from one another and this phenomenon contributed to the gas permeability of ore layer in the cohesive zone since the ‘ore window’ has formed. Besides, the softening and melting behaviour of mixed burdens have been studied, where it has been found that the softening and melting characteristics of mixed burden A (consisting of sinter and lump ore A) is better than mixed burden B (consisting of sinter and lump ore B) and mixed burden C (consisting of sinter and acid pellet) despite the poorest characteristics of lump ore A. The reason is that the high temperature interactivity between lump ore A and sinter is much better than lump ore B and acid pellet. The high temperature interactivity is mainly influenced by the chemical compositions, porosity and contact condition. This paper provides a new research method for the softening and melting behaviour of iron ore and an important technical basis for the optimisation of blast furnace burden.CITATION:Wang, L X, Wu, S L, Lu, Y N and Du, B B, 2017. The softening and melting behaviour of single and mixed iron ore burdens, in Proceedings Iron Ore 2017, pp 605–610 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017